Articles | Volume 9, issue 9
https://doi.org/10.5194/amt-9-4655-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-9-4655-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Phosgene in the UTLS: seasonal and latitudinal variations from MIPAS observations
ISAC-CNR – Istituto di Scienze dell'Atmosfera e del Clima, Via Gobetti 101, 40129
Bologna, Italy
Dipartimento di Fisica e Astronomia, Università di Bologna, Viale Berti Pichat 6/2,
40127 Bologna, Italy
Massimo Carlotti
Dipartimento di Chimica Industriale “Toso Montanari“, Università di Bologna, Viale del
Risorgimento 4, 40136 Bologna, Italy
Jean-Marie Flaud
LISA – Laboratoire Interuniversitaire des Systémes Atmosphériques, 61 avenue du Général de Gaulle, Créteil, France
Piera Raspollini
IFAC-CNR – Istituto di Fisica Applicata ”Nello Carrara”, Via Madonna del Piano 10, 50019 Sesto
Fiorentino, Italy
Marco Ridolfi
Dipartimento di Fisica e Astronomia, Università di Bologna, Viale Berti Pichat 6/2,
40127 Bologna, Italy
IFAC-CNR – Istituto di Fisica Applicata ”Nello Carrara”, Via Madonna del Piano 10, 50019 Sesto
Fiorentino, Italy
Bianca Maria Dinelli
ISAC-CNR – Istituto di Scienze dell'Atmosfera e del Clima, Via Gobetti 101, 40129
Bologna, Italy
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Laura N. Saunders, Kaley A. Walker, Gabriele P. Stiller, Piera Raspollini, Luis F. Millán, Marco Gai, Chris D. Boone, John Gille, Norbert Glatthor, Armin Kleinboehl, Anne Kleinert, Alyn Lambert, Donal Murtaugh, Patrick E. Sheese, Geoffrey C. Toon, and Gerald Wetzel
EGUsphere, https://doi.org/10.5194/egusphere-2026-4651, https://doi.org/10.5194/egusphere-2026-4651, 2026
This preprint is open for discussion and under review for Atmospheric Measurement Techniques (AMT).
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We present a comprehensive evaluation of nitrous oxide (N2O) measurements taken during the 2002–2024 period from five limb-viewing satellite instruments: ACE-FTS, HIRDLS, MIPAS, Aura-MLS, and SMR. Coincident measurements are compared between satellite instruments and with independent reference data from balloon-borne instruments. We show that ACE-FTS, MIPAS, and SMR constitute an excellent 23-year record of N2O measurements that could be used to create an ESA-funded merged dataset in future.
Martina Taddia, Federico Fabiano, Stefano Della Fera, Elisa Castelli, and Bianca Maria Dinelli
Atmos. Chem. Phys., 26, 5293–5311, https://doi.org/10.5194/acp-26-5293-2026, https://doi.org/10.5194/acp-26-5293-2026, 2026
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The evolution of the climate system is strictly related to its radiative response to changes in surface and atmospheric processes. Through the analysis of the Earth’s emission spectrum measured by satellite instruments, we show that the radiative response to El-Niño Southern Oscillation is wavenumber-dependent, highlighting the role of key climate variables. This makes this analysis particularly suitable for climate models evaluations.
Quentin Errera, Marc Op de beeck, Stefan Bender, Johannes Flemming, Bernd Funke, Alex Hoffmann, Michael Höpfner, Nathaniel Livesey, Gabriele Poli, Didier Pieroux, Piera Raspollini, and Björn-Martin Sinnhuber
Atmos. Meas. Tech., 19, 2601–2620, https://doi.org/10.5194/amt-19-2601-2026, https://doi.org/10.5194/amt-19-2601-2026, 2026
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The Changing Atmosphere Infra-Red Tomography Explorer (CAIRT) is a satellite mission concept developed to observe, among other, the gradient of ozone and water vapour in the upper troposphere and lower stratosphere where these species have their largest radiative impact. By simulating CAIRT observations and measuring their constrain on an atmospheric model using data assimilation, this study shows that CAIRT specifications are adequate to fulfil this objective.
Liliana Guidetti, Erika Brattich, Simone Ceccherini, Michaela I. Hegglin, Piera Raspollini, Cecilia Tirelli, Nicola Zoppetti, and Ugo Cortesi
Atmos. Meas. Tech., 19, 167–184, https://doi.org/10.5194/amt-19-167-2026, https://doi.org/10.5194/amt-19-167-2026, 2026
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The Complete Data Fusion algorithm is applied to observations from the Michelson Interferometer for Passive Atmospheric Sounding and the Infrared Atmospheric Sounding Interferometer to generate and validate a new ozone dataset against ozone soundings across multiple latitudes. The fusion propagates stratospheric limb information into the troposphere. The dataset shows increased information content and lower uncertainty, improving the study of stratosphere–troposphere ozone intrusions.
Cecilia Tirelli, Simone Ceccherini, Samuele Del Bianco, Bernd Funke, Michael Höpfner, Ugo Cortesi, and Piera Raspollini
Atmos. Meas. Tech., 18, 5619–5636, https://doi.org/10.5194/amt-18-5619-2025, https://doi.org/10.5194/amt-18-5619-2025, 2025
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The Complete Data Fusion is an a posteriori method used to combine remote sensing products from independent observations of the same or proximate air masses. In this study, we extend the algorithm’s applicability to two-dimensional products, testing it with simulated ozone datasets from nadir and limb measurements. Our results show that the exploitation of the tomographic capabilities of future atmospheric sensors maximizes the information extracted from complementary datasets.
Karen De Los Ríos, Paulina Ordoñez, Gabriele P. Stiller, Piera Raspollini, Marco Gai, Kaley A. Walker, Cristina Peña-Ortiz, and Luis Acosta
Atmos. Meas. Tech., 17, 3401–3418, https://doi.org/10.5194/amt-17-3401-2024, https://doi.org/10.5194/amt-17-3401-2024, 2024
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This study examines newer versions of H2O and HDO retrievals from Envisat/MIPAS and SCISAT/ACE-FTS. Results reveal a better agreement in stratospheric H2O profiles than in HDO profiles. The H2O tape recorder signal is consistent across databases, but δD tape recorder composites show differences that impact the interpretation of water vapour transport. These findings enhance the need for intercomparisons to refine our insights.
Michael Kiefer, Dale F. Hurst, Gabriele P. Stiller, Stefan Lossow, Holger Vömel, John Anderson, Faiza Azam, Jean-Loup Bertaux, Laurent Blanot, Klaus Bramstedt, John P. Burrows, Robert Damadeo, Bianca Maria Dinelli, Patrick Eriksson, Maya García-Comas, John C. Gille, Mark Hervig, Yasuko Kasai, Farahnaz Khosrawi, Donal Murtagh, Gerald E. Nedoluha, Stefan Noël, Piera Raspollini, William G. Read, Karen H. Rosenlof, Alexei Rozanov, Christopher E. Sioris, Takafumi Sugita, Thomas von Clarmann, Kaley A. Walker, and Katja Weigel
Atmos. Meas. Tech., 16, 4589–4642, https://doi.org/10.5194/amt-16-4589-2023, https://doi.org/10.5194/amt-16-4589-2023, 2023
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We quantify biases and drifts (and their uncertainties) between the stratospheric water vapor measurement records of 15 satellite-based instruments (SATs, with 31 different retrievals) and balloon-borne frost point hygrometers (FPs) launched at 27 globally distributed stations. These comparisons of measurements during the period 2000–2016 are made using robust, consistent statistical methods. With some exceptions, the biases and drifts determined for most SAT–FP pairs are < 10 % and < 1 % yr−1.
Stefano Della Fera, Federico Fabiano, Piera Raspollini, Marco Ridolfi, Ugo Cortesi, Flavio Barbara, and Jost von Hardenberg
Geosci. Model Dev., 16, 1379–1394, https://doi.org/10.5194/gmd-16-1379-2023, https://doi.org/10.5194/gmd-16-1379-2023, 2023
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The long-term comparison between observed and simulated outgoing longwave radiances represents a strict test to evaluate climate model performance. In this work, 9 years of synthetic spectrally resolved radiances, simulated online on the basis of the atmospheric fields predicted by the EC-Earth global climate model (v3.3.3) in clear-sky conditions, are compared to IASI spectral radiance climatology in order to detect model biases in temperature and humidity at different atmospheric levels.
Marco Ridolfi, Cecilia Tirelli, Simone Ceccherini, Claudio Belotti, Ugo Cortesi, and Luca Palchetti
Atmos. Meas. Tech., 15, 6723–6737, https://doi.org/10.5194/amt-15-6723-2022, https://doi.org/10.5194/amt-15-6723-2022, 2022
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Synergistic retrieval (SR) and complete data fusion (CDF) methods exploit the complementarity of coinciding remote-sensing measurements. We assess the performance of the SR and CDF methods on the basis of synthetic measurements of the FORUM and IASI-NG missions. In the case of perfectly matching measurements, SR and CDF results differ by less than 1 / 10 of the error due to measurement noise. In the case of a realistic mismatch, the two methods show differences in the order of their error bars.
Gerald Wetzel, Michael Höpfner, Hermann Oelhaf, Felix Friedl-Vallon, Anne Kleinert, Guido Maucher, Miriam Sinnhuber, Janna Abalichin, Angelika Dehn, and Piera Raspollini
Atmos. Meas. Tech., 15, 6669–6704, https://doi.org/10.5194/amt-15-6669-2022, https://doi.org/10.5194/amt-15-6669-2022, 2022
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Satellite measurements of stratospheric trace gases are essential for monitoring distributions and trends of these species on a global scale. Here, we compare the final MIPAS ESA Level 2 version 8 data (temperature and trace gases) with measurements obtained with the balloon version of MIPAS in terms of data agreement of both sensors, including combined errors. For most gases, we find a 5 % to 20 % agreement of the retrieved vertical profiles of both MIPAS instruments in the lower stratosphere.
William G. Read, Gabriele Stiller, Stefan Lossow, Michael Kiefer, Farahnaz Khosrawi, Dale Hurst, Holger Vömel, Karen Rosenlof, Bianca M. Dinelli, Piera Raspollini, Gerald E. Nedoluha, John C. Gille, Yasuko Kasai, Patrick Eriksson, Christopher E. Sioris, Kaley A. Walker, Katja Weigel, John P. Burrows, and Alexei Rozanov
Atmos. Meas. Tech., 15, 3377–3400, https://doi.org/10.5194/amt-15-3377-2022, https://doi.org/10.5194/amt-15-3377-2022, 2022
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This paper attempts to provide an assessment of the accuracy of 21 satellite-based instruments that remotely measure atmospheric humidity in the upper troposphere of the Earth's atmosphere. The instruments made their measurements from 1984 to the present time; however, most of these instruments began operations after 2000, and only a few are still operational. The objective of this study is to quantify the accuracy of each satellite humidity data set.
Piera Raspollini, Enrico Arnone, Flavio Barbara, Massimo Bianchini, Bruno Carli, Simone Ceccherini, Martyn P. Chipperfield, Angelika Dehn, Stefano Della Fera, Bianca Maria Dinelli, Anu Dudhia, Jean-Marie Flaud, Marco Gai, Michael Kiefer, Manuel López-Puertas, David P. Moore, Alessandro Piro, John J. Remedios, Marco Ridolfi, Harjinder Sembhi, Luca Sgheri, and Nicola Zoppetti
Atmos. Meas. Tech., 15, 1871–1901, https://doi.org/10.5194/amt-15-1871-2022, https://doi.org/10.5194/amt-15-1871-2022, 2022
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The MIPAS instrument onboard the ENVISAT satellite provided 10 years of measurements of the atmospheric emission al limb that allow for the retrieval of latitude- and altitude-resolved atmospheric composition. We describe the improvements implemented in the retrieval algorithm used for the full mission reanalysis, which allows for the generation of the global distributions of 21 atmospheric constituents plus temperature with increased accuracy with respect to previously generated data.
Maya Ben-Yami, Hilke Oetjen, Helen Brindley, William Cossich, Dulce Lajas, Tiziano Maestri, Davide Magurno, Piera Raspollini, Luca Sgheri, and Laura Warwick
Atmos. Meas. Tech., 15, 1755–1777, https://doi.org/10.5194/amt-15-1755-2022, https://doi.org/10.5194/amt-15-1755-2022, 2022
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Spectral emissivity is a key property of the Earth's surface. Few measurements exist in the far-infrared, despite recent work showing that its contribution is important for accurate modelling of global climate. In preparation for ESA’s EE9 FORUM mission (launch in 2026), this study takes the first steps towards the development of an operational emissivity retrieval for FORUM by investigating the sensitivity of the emissivity product to different physical and operational parameters.
Luca Sgheri, Claudio Belotti, Maya Ben-Yami, Giovanni Bianchini, Bernardo Carnicero Dominguez, Ugo Cortesi, William Cossich, Samuele Del Bianco, Gianluca Di Natale, Tomás Guardabrazo, Dulce Lajas, Tiziano Maestri, Davide Magurno, Hilke Oetjen, Piera Raspollini, and Cristina Sgattoni
Atmos. Meas. Tech., 15, 573–604, https://doi.org/10.5194/amt-15-573-2022, https://doi.org/10.5194/amt-15-573-2022, 2022
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The FORUM instrument will look at the Earth's atmosphere from a satellite, covering a spectral range responsible for about 95 % of the radiation lost by our planet. FORUM helps to measure the imbalance between incoming and outgoing radiation that is responsible for the increasing average temperatures on Earth. The end-to-end simulator is a chain of codes that simulates the FORUM measurement process. The goal of the project is to study how the instrument reacts to different retrieval conditions.
Bianca Maria Dinelli, Piera Raspollini, Marco Gai, Luca Sgheri, Marco Ridolfi, Simone Ceccherini, Flavio Barbara, Nicola Zoppetti, Elisa Castelli, Enzo Papandrea, Paolo Pettinari, Angelika Dehn, Anu Dudhia, Michael Kiefer, Alessandro Piro, Jean-Marie Flaud, Manuel López-Puertas, David Moore, John Remedios, and Massimo Bianchini
Atmos. Meas. Tech., 14, 7975–7998, https://doi.org/10.5194/amt-14-7975-2021, https://doi.org/10.5194/amt-14-7975-2021, 2021
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The level-2 v8 database from the measurements of the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), aboard the European Space Agency Envisat satellite, containing atmospheric fields of pressure, temperature, and volume mixing ratio of 21 trace gases, is described in this paper. The database covers all the measurements acquired by MIPAS (from July 2002 to April 2012). The number of species included makes it of particular importance for the studies of stratospheric chemistry.
Paolo Pettinari, Flavio Barbara, Simone Ceccherini, Bianca Maria Dinelli, Marco Gai, Piera Raspollini, Luca Sgheri, Massimo Valeri, Gerald Wetzel, Nicola Zoppetti, and Marco Ridolfi
Atmos. Meas. Tech., 14, 7959–7974, https://doi.org/10.5194/amt-14-7959-2021, https://doi.org/10.5194/amt-14-7959-2021, 2021
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Phosgene (COCl2) is a toxic gas whose presence is a consequence of human activity. Besides its direct injection in the troposphere, stratospheric COCl2 is produced from the decomposition of CCl4, an anthropogenic gas regulated by the Montreal Protocol. As a consequence, COCl2 negative trends characterize the lower and part of the middle stratosphere. However, we find positive trends in the upper troposphere, demonstrating the non-negligible role of other Cl-containing species not yet regulated.
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Short summary
Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) measurements have been analysed to measure the vertical distribution of phosgene (COCl2) in the UTLS using new spectroscopic data. To highlight its seasonal and latitudinal variability, MIPAS measurements of 2 days/month during 2008 have been analysed. The results show a strong latitudinal variability of COCl2 with the largest VMR values observed in the tropical regions. The seasonality is fairly low, apart from the polar regions.
Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) measurements have been...