Articles | Volume 10, issue 4
https://doi.org/10.5194/amt-10-1445-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-10-1445-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
18 Apr 2017
Research article |
| 18 Apr 2017
Measurement of alkyl and multifunctional organic nitrates by proton-transfer-reaction mass spectrometry
Marius Duncianu
Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), UMR-CNRS 7583, Université Paris-Est-Créteil (UPEC) et
Université Paris Diderot (UPD), Paris, France
Marc David
Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), UMR-CNRS 7583, Université Paris-Est-Créteil (UPEC) et
Université Paris Diderot (UPD), Paris, France
Sakthivel Kartigueyane
Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), UMR-CNRS 7583, Université Paris-Est-Créteil (UPEC) et
Université Paris Diderot (UPD), Paris, France
Manuela Cirtog
Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), UMR-CNRS 7583, Université Paris-Est-Créteil (UPEC) et
Université Paris Diderot (UPD), Paris, France
Jean-François Doussin
Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), UMR-CNRS 7583, Université Paris-Est-Créteil (UPEC) et
Université Paris Diderot (UPD), Paris, France
Benedicte Picquet-Varrault
CORRESPONDING AUTHOR
Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), UMR-CNRS 7583, Université Paris-Est-Créteil (UPEC) et
Université Paris Diderot (UPD), Paris, France
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Francesco Battaglia, Paola Formenti, Chiara Giorio, Mathieu Cazaunau, Edouard Pangui, Antonin Bergé, Aline Gratien, Thomas Bertin, Joël F. de Brito, Manolis N. Romanias, Vincent Michoud, Clarissa Baldo, Servanne Chevaillier, Gaël Noyalet, Philippe Decorse, Bénédicte Picquet-Varrault, and Jean-François Doussin
EGUsphere, https://doi.org/10.5194/egusphere-2024-4073, https://doi.org/10.5194/egusphere-2024-4073, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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This paper presents an experimental investigation of the interactions between glyoxal, an important volatile organic compound, and mineral dust particles of size and composition typical of natural conditions. We show that their interactions modifies in a definitive way the concentrations of the gas phase and the properties of the dust, which could have important implications of the atmospheric composition and the Earth's climate.
Chiara Giorio, Anne Monod, Valerio Di Marco, Pierre Herckes, Denise Napolitano, Amy Sullivan, Gautier Landrot, Daniel Warnes, Marika Nasti, Sara D'Aronco, Agathe Gérardin, Nicolas Brun, Karine Desboeufs, Sylvain Triquet, Servanne Chevaillier, Claudia Di Biagio, Francesco Battaglia, Frédéric Burnet, Stuart J. Piketh, Andreas Namwoonde, Jean-François Doussin, and Paola Formenti
EGUsphere, https://doi.org/10.5194/egusphere-2024-4140, https://doi.org/10.5194/egusphere-2024-4140, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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A comparison between the solubility of trace metals in pairs of total suspended particulate (TSP) and fog water samples collected in Henties Bay, Namibia, during the AEROCLO-sA field campaign is presented. We found enhanced solubility of metals in fog samples which we attributed to metal-ligand complexes formation in the early stages of particle activation into droplets which can then remain in a kinetically stable form in fog or lead to the formation of colloidal nanoparticles.
Simone T. Andersen, Rolf Sander, Patrick Dewald, Laura Wüst, Tobias Seubert, Gunther N. T. E. Türk, Jan Schuladen, Max R. McGillen, Chaoyang Xue, Abdelwahid Mellouki, Alexandre Kukui, Vincent Michoud, Manuela Cirtog, Mathieu Cazaunau, Astrid Bauville, Hichem Bouzidi, Paola Formenti, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Christopher Cantrell, Jos Lelieveld, and John N. Crowley
EGUsphere, https://doi.org/10.5194/egusphere-2024-3437, https://doi.org/10.5194/egusphere-2024-3437, 2024
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Measurements and modelling of reactive nitrogen gases observed in a suburban temperate forest in Rambouillet, France circa 50 km southwest of Paris in 2022 indicate that the biosphere rapidly scavenges organic nitrates of mixed biogenic and anthropogenic origin, resulting in short lifetimes for e.g. alkyl nitrates and peroxy nitrates.
Sergio Harb, Manuela Cirtog, Stéphanie Alage, Christopher Cantrell, Mathieu Cazaunau, Vincent Michoud, Edouard Pangui, Antonin Bergé, Chiara Giorio, Francesco Battaglia, and Bénédicte Picquet-Varrault
EGUsphere, https://doi.org/10.5194/egusphere-2024-3419, https://doi.org/10.5194/egusphere-2024-3419, 2024
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We investigated the reactions of α- and β-phellandrenes (from vegetation emissions) with NO3 radicals, a major nighttime oxidant from human activities. Using lab-based simulations, we examined these reactions and measured particle formation and by-products. Our findings reveal that α- and β-phellandrenes are efficient particle sources and enhance our understanding of biogenic-anthropogenic interactions and their contributions to atmospheric changes affecting climate and health.
Simone T. Andersen, Max R. McGillen, Chaoyang Xue, Tobias Seubert, Patrick Dewald, Gunther N. T. E. Türk, Jan Schuladen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Abdelwahid Mellouki, Lucy J. Carpenter, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 11603–11618, https://doi.org/10.5194/acp-24-11603-2024, https://doi.org/10.5194/acp-24-11603-2024, 2024
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Using measurements of various trace gases in a suburban forest near Paris in the summer of 2022, we were able to gain insight into the sources and sinks of NOx (NO+NO2) with a special focus on their nighttime chemical and physical loss processes. NO was observed as a result of nighttime soil emissions when O3 levels were strongly depleted by deposition. NO oxidation products were not observed at night, indicating that soil and/or foliar surfaces are an efficient sink of reactive N.
Diana L. Pereira, Chiara Giorio, Aline Gratien, Alexander Zherebker, Gael Noyalet, Servanne Chevaillier, Stéphanie Alage, Elie Almarj, Antonin Bergé, Thomas Bertin, Mathieu Cazaunau, Patrice Coll, Ludovico Di Antonio, Sergio Harb, Johannes Heuser, Cécile Gaimoz, Oscar Guillemant, Brigitte Language, Olivier Lauret, Camilo Macias, Franck Maisonneuve, Bénédicte Picquet-Varrault, Raquel Torres, Sylvain Triquet, Pascal Zapf, Lelia Hawkins, Drew Pronovost, Sydney Riley, Pierre-Marie Flaud, Emilie Perraudin, Pauline Pouyes, Eric Villenave, Alexandre Albinet, Olivier Favez, Robin Aujay-Plouzeau, Vincent Michoud, Christopher Cantrell, Manuela Cirtog, Claudia Di Biagio, Jean-François Doussin, and Paola Formenti
EGUsphere, https://doi.org/10.5194/egusphere-2024-3015, https://doi.org/10.5194/egusphere-2024-3015, 2024
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In order to study aerosols in environments influenced by anthropogenic and biogenic emissions, we performed analysis of samples collected during ACROSS (Atmospheric Chemistry Of the Suburban Forest) campaign in the summer 2022 in the Paris greater area. After analysis of the chemical composition by means of total carbon determination and high resolution mass spectrometry, this work highlights the influence of anthropogenic inputs into the chemical composition of both urban and forested areas.
Johannes Heuser, Claudia Di Biagio, Jerome Yon, Mathieu Cazaunau, Antonin Bergé, Edouard Pangui, Marco Zanatta, Laura Renzi, Angela Marinoni, Satoshi Inomata, Chenjie Yu, Vera Bernardoni, Servanne Chevaillier, Daniel Ferry, Paolo Laj, Michel Maillé, Dario Massabò, Federico Mazzei, Gael Noyalet, Hiroshi Tanimoto, Brice Temime-Roussel, Roberta Vecchi, Virginia Vernocchi, Paola Formenti, Bénédicte Picquet-Varrault, and Jean-François Doussin
EGUsphere, https://doi.org/10.5194/egusphere-2024-2381, https://doi.org/10.5194/egusphere-2024-2381, 2024
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The spectral optical properties of combustion soot aerosols with varying black (BC) and brown carbon (BrC) content were studied in an atmospheric simulation chamber. Measurements of the mass spectral absorption cross section (MAC), supplement by literature data, allowed to establish a generalized exponential relationship between the spectral MAC and the elemental-to-total carbon ratio (EC/TC) in soot. This relationship can provide a useful tool for modelling the properties of soot.
Ludovico Di Antonio, Matthias Beekmann, Guillaume Siour, Vincent Michoud, Christopher Cantrell, Astrid Bauville, Antonin Bergé, Mathieu Cazaunau, Servanne Chevaillier, Manuela Cirtog, Joel F. de Brito, Paola Formenti, Cecile Gaimoz, Olivier Garret, Aline Gratien, Valérie Gros, Martial Haeffelin, Lelia N. Hawkins, Simone Kotthaus, Gael Noyalet, Diana Pereira, Jean-Eudes Petit, Eva Drew Pronovost, Véronique Riffault, Chenjie Yu, Gilles Foret, Jean-François Doussin, and Claudia Di Biagio
EGUsphere, https://doi.org/10.5194/egusphere-2024-2175, https://doi.org/10.5194/egusphere-2024-2175, 2024
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Summer 2022 has been considered a proxy for future climate scenarios, given the registered hot and dry conditions. In this paper, we used the measurements from the ACROSS campaign, occurred over the Paris area in June–July 2022, in addition to observations from existing networks, to evaluate the WRF–CHIMERE model simulation over France and the Ile-de-France regions. Results over the Ile–de–France show to be satisfactory, allowing to explain the gas and aerosol variability at the ACROSS sites.
Ludovico Di Antonio, Claudia Di Biagio, Paola Formenti, Aline Gratien, Vincent Michoud, Christopher Cantrell, Astrid Bauville, Antonin Bergé, Mathieu Cazaunau, Servanne Chevaillier, Manuela Cirtog, Patrice Coll, Barbara D'Anna, Joel F. de Brito, David O. De Haan, Juliette R. Dignum, Shravan Deshmukh, Olivier Favez, Pierre-Marie Flaud, Cecile Gaimoz, Lelia N. Hawkins, Julien Kammer, Brigitte Language, Franck Maisonneuve, Griša Močnik, Emilie Perraudin, Jean-Eudes Petit, Prodip Acharja, Laurent Poulain, Pauline Pouyes, Eva Drew Pronovost, Véronique Riffault, Kanuri I. Roundtree, Marwa Shahin, Guillaume Siour, Eric Villenave, Pascal Zapf, Gilles Foret, Jean-François Doussin, and Matthias Beekmann
EGUsphere, https://doi.org/10.5194/egusphere-2024-2299, https://doi.org/10.5194/egusphere-2024-2299, 2024
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The spectral complex refractive index (CRI) and single scattering albedo were retrieved from submicron aerosol measurements at three sites within the greater Paris area during the ACROSS field campaign (June–July 2022). Measurements revealed the urban emission impact on the surrounding areas. The CRI full period averages at 520 nm were 1.41–0.037i (urban), 1.52–0.038i (peri-urban), 1.50−0.025i (rural). Organic aerosols dominated the aerosol mass and contributed up to 22% of absorption at 370 nm.
Patrick Dewald, Tobias Seubert, Simone T. Andersen, Gunther N. T. E. Türk, Jan Schuladen, Max R. McGillen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Chaoyang Xue, Abdelwahid Mellouki, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 8983–8997, https://doi.org/10.5194/acp-24-8983-2024, https://doi.org/10.5194/acp-24-8983-2024, 2024
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In the scope of a field campaign in a suburban forest near Paris in the summer of 2022, we measured the reactivity of the nitrate radical NO3 towards biogenic volatile organic compounds (BVOCs; e.g. monoterpenes) mainly below but also above the canopy. NO3 reactivity was the highest during nights with strong temperature inversions and decreased strongly with height. Reactions with BVOCs were the main removal process of NO3 throughout the diel cycle below the canopy.
Stéphanie Alage, Vincent Michoud, Sergio Harb, Bénédicte Picquet-Varrault, Manuela Cirtog, Avinash Kumar, Matti Rissanen, and Christopher Cantrell
Atmos. Meas. Tech., 17, 4709–4724, https://doi.org/10.5194/amt-17-4709-2024, https://doi.org/10.5194/amt-17-4709-2024, 2024
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Calibration exercises are essential for determining the accuracy of instruments. We performed calibrations on a NO3¯ ToFCIMS instrument to determine its sensitivity and linearity for detecting various organic compounds. Our findings revealed significant variability, over several orders of magnitude, in the calibration factors obtained. The results suggest that relying on a single calibration factor from H2SO4 for the quantification of all compounds detected by this technique is not appropriate.
Anil Kumar Mandariya, Junteng Wu, Anne Monod, Paola Formenti, Bénédicte Picquet-Varrault, Mathieu Cazaunau, Stephan Mertes, Laurent Poulain, Antonin Berge, Edouard Pangui, Andreas Tilgner, Thomas Schaefer, Liang Wen, Hartmut Herrmann, and Jean-François Doussin
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2023-206, https://doi.org/10.5194/amt-2023-206, 2024
Publication in AMT not foreseen
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An optimized and controlled protocol for generating quasi-adiabatic expansion clouds under simulated dark and light conditions was presented. The irradiated clouds clearly showed a gradual activation of seed particles into droplets. In contrast, non-irradiated clouds faced a flash activation. This paper will lay the foundation for multiphase photochemical studies implying water-soluble volatile organic compounds and particulate matter formation during cloud formation-evaporation cycles.
Ludovico Di Antonio, Claudia Di Biagio, Gilles Foret, Paola Formenti, Guillaume Siour, Jean-François Doussin, and Matthias Beekmann
Atmos. Chem. Phys., 23, 12455–12475, https://doi.org/10.5194/acp-23-12455-2023, https://doi.org/10.5194/acp-23-12455-2023, 2023
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Long-term (2000–2021) 1 km resolution satellite data have been used to investigate the climatological aerosol optical depth (AOD) variability and trends at different scales in Europe. Average enhancements of the local-to-regional AOD ratio at 550 nm of 57 %, 55 %, 39 % and 32 % are found for large metropolitan areas such as Barcelona, Lisbon, Paris and Athens, respectively, suggesting a non-negligible enhancement of the aerosol burden through local emissions.
Clarissa Baldo, Paola Formenti, Claudia Di Biagio, Gongda Lu, Congbo Song, Mathieu Cazaunau, Edouard Pangui, Jean-Francois Doussin, Pavla Dagsson-Waldhauserova, Olafur Arnalds, David Beddows, A. Robert MacKenzie, and Zongbo Shi
Atmos. Chem. Phys., 23, 7975–8000, https://doi.org/10.5194/acp-23-7975-2023, https://doi.org/10.5194/acp-23-7975-2023, 2023
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This paper presents new shortwave spectral complex refractive index and single scattering albedo data for Icelandic dust. Our results show that the imaginary part of the complex refractive index of Icelandic dust is at the upper end of the range of low-latitude dust. Furthermore, we observed that Icelandic dust is more absorbing towards the near-infrared, which we attribute to its high magnetite content. These findings are important for modeling dust aerosol radiative effects in the Arctic.
Arineh Cholakian, Matthias Beekmann, Guillaume Siour, Isabelle Coll, Manuela Cirtog, Elena Ormeño, Pierre-Marie Flaud, Emilie Perraudin, and Eric Villenave
Atmos. Chem. Phys., 23, 3679–3706, https://doi.org/10.5194/acp-23-3679-2023, https://doi.org/10.5194/acp-23-3679-2023, 2023
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This article revolves around the simulation of biogenic secondary organic aerosols in the Landes forest (southwestern France). Several sensitivity cases involving biogenic emission factors, land cover data, anthropogenic emissions, and physical or meteorological parameters were performed and each compared to measurements both in the forest canopy and around the forest. The chemistry behind the formation of these aerosols and their production and transport in the forest canopy is discussed.
Axel Fouqueau, Manuela Cirtog, Mathieu Cazaunau, Edouard Pangui, Jean-François Doussin, and Bénédicte Picquet-Varrault
Atmos. Chem. Phys., 22, 6411–6434, https://doi.org/10.5194/acp-22-6411-2022, https://doi.org/10.5194/acp-22-6411-2022, 2022
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Biogenic volatile organic compounds are intensely emitted by forests and crops and react with the nitrate radical during the nighttime to form functionalized products. The purpose of this study is to furnish kinetic and mechanistic data for terpinolene and β-caryophyllene, using simulation chamber experiments. Rate constants have been measured using both relative and absolute methods, and mechanistic studies have been conducted in order to identify and quantify the main reaction products.
Spiro D. Jorga, Kalliopi Florou, Christos Kaltsonoudis, John K. Kodros, Christina Vasilakopoulou, Manuela Cirtog, Axel Fouqueau, Bénédicte Picquet-Varrault, Athanasios Nenes, and Spyros N. Pandis
Atmos. Chem. Phys., 21, 15337–15349, https://doi.org/10.5194/acp-21-15337-2021, https://doi.org/10.5194/acp-21-15337-2021, 2021
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We test the hypothesis that significant secondary organic aerosol production can take place even during winter nights through the oxidation of the emitted organic vapors by the nitrate radicals produced during the reaction of ozone and nitrogen oxides. Our experiments, using as a starting point the ambient air of an urban area with high biomass burning activity, demonstrate that, even with sunlight, there is 20 %–70 % additional organic aerosol formed in a few hours.
Hongming Yi, Mathieu Cazaunau, Aline Gratien, Vincent Michoud, Edouard Pangui, Jean-Francois Doussin, and Weidong Chen
Atmos. Meas. Tech., 14, 5701–5715, https://doi.org/10.5194/amt-14-5701-2021, https://doi.org/10.5194/amt-14-5701-2021, 2021
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HONO and NO2 play a crucial role in the atmospheric oxidation capacity that affects the regional air quality and global climate. Accurate measurements of HONO are challenging due to the drawback of existing detection methods. Calibration-free high-sensitivity direct, simultaneous measurements of NO2, HONO and CH2O with UV-IBBCEAS provide accurate and fast quantitative analysis of their concentration variation within their lifetime by intercomparison with NOx, FTIR and NitroMAC sensors.
Axel Fouqueau, Manuela Cirtog, Mathieu Cazaunau, Edouard Pangui, Jean-François Doussin, and Bénédicte Picquet-Varrault
Atmos. Chem. Phys., 20, 15167–15189, https://doi.org/10.5194/acp-20-15167-2020, https://doi.org/10.5194/acp-20-15167-2020, 2020
Axel Fouqueau, Manuela Cirtog, Mathieu Cazaunau, Edouard Pangui, Pascal Zapf, Guillaume Siour, Xavier Landsheere, Guillaume Méjean, Daniele Romanini, and Bénédicte Picquet-Varrault
Atmos. Meas. Tech., 13, 6311–6323, https://doi.org/10.5194/amt-13-6311-2020, https://doi.org/10.5194/amt-13-6311-2020, 2020
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An incoherent broadband cavity-enhanced absorption spectroscopy (IBBCEAS) technique has been developed for the in situ monitoring of NO3 radicals in the CSA simulation chamber at LISA. The optical cavity allows a high sensitivity for NO3 detection up to 6 ppt for an integration time of 10 s. The technique is now fully operational and can be used to determine rate constants for fast reactions involving complex volatile organic compounds (with rate constants up to 10−10 cm3 molecule−1 s−1).
Clarissa Baldo, Paola Formenti, Sophie Nowak, Servanne Chevaillier, Mathieu Cazaunau, Edouard Pangui, Claudia Di Biagio, Jean-Francois Doussin, Konstantin Ignatyev, Pavla Dagsson-Waldhauserova, Olafur Arnalds, A. Robert MacKenzie, and Zongbo Shi
Atmos. Chem. Phys., 20, 13521–13539, https://doi.org/10.5194/acp-20-13521-2020, https://doi.org/10.5194/acp-20-13521-2020, 2020
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We showed that Icelandic dust has a fundamentally different chemical and mineralogical composition from low-latitude dust. In particular, magnetite is as high as 1 %–2 % of the total dust mass. Our results suggest that Icelandic dust may have an important impact on the radiation balance in the subpolar and polar regions.
David O. De Haan, Lelia N. Hawkins, Kevin Jansen, Hannah G. Welsh, Raunak Pednekar, Alexia de Loera, Natalie G. Jimenez, Margaret A. Tolbert, Mathieu Cazaunau, Aline Gratien, Antonin Bergé, Edouard Pangui, Paola Formenti, and Jean-François Doussin
Atmos. Chem. Phys., 20, 9581–9590, https://doi.org/10.5194/acp-20-9581-2020, https://doi.org/10.5194/acp-20-9581-2020, 2020
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When exposed to glyoxal in chamber experiments, dry ammonium or methylammonium sulfate particles turn brown immediately and reversibly without increasing in size. Much less browning was observed on wet aerosol particles, and no browning was observed with sodium sulfate aerosol. While estimated dry aerosol light absorption caused by background glyoxal (70 ppt) is insignificant compared to that of secondary brown carbon overall, in polluted regions this process could be a source of brown carbon.
Max R. McGillen, William P. L. Carter, Abdelwahid Mellouki, John J. Orlando, Bénédicte Picquet-Varrault, and Timothy J. Wallington
Earth Syst. Sci. Data, 12, 1203–1216, https://doi.org/10.5194/essd-12-1203-2020, https://doi.org/10.5194/essd-12-1203-2020, 2020
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The gas-phase reactions of organic compounds in the atmosphere are a crucial step in the degradation of anthropogenic and biogenic emissions and the formation of secondary pollutants. This work is an attempt to produce a dataset that is as comprehensive as possible regarding the multitude of chemicals that react in the atmosphere. We find that we are able to make substantial improvements upon previous compendia and that this progress will help improve our understanding of atmospheric chemistry.
Andrew T. Lambe, Ezra C. Wood, Jordan E. Krechmer, Francesca Majluf, Leah R. Williams, Philip L. Croteau, Manuela Cirtog, Anaïs Féron, Jean-Eudes Petit, Alexandre Albinet, Jose L. Jimenez, and Zhe Peng
Atmos. Meas. Tech., 13, 2397–2411, https://doi.org/10.5194/amt-13-2397-2020, https://doi.org/10.5194/amt-13-2397-2020, 2020
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We present a new method to continuously generate N2O5 in the gas phase that is injected into a reactor where it decomposes to generate nitrate radicals (NO3). To assess the applicability of the method towards different chemical systems, we present experimental and model characterization of the integrated NO3 exposure and other metrics as a function of operating conditions. We demonstrate the method by characterizing secondary organic aerosol particles generated from the β-pinene + NO3 reaction.
Bénédicte Picquet-Varrault, Ricardo Suarez-Bertoa, Marius Duncianu, Mathieu Cazaunau, Edouard Pangui, Marc David, and Jean-François Doussin
Atmos. Chem. Phys., 20, 487–498, https://doi.org/10.5194/acp-20-487-2020, https://doi.org/10.5194/acp-20-487-2020, 2020
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Multifunctional organic nitrates are important atmospheric species that are known to play a key role in the transport of reactive nitrogen and in aerosol composition. However, very little is known about their atmospheric reactivity. Here we provide an experimental study on the photolysis and reaction of two carbonyl nitrates with OH radicals. Atmospheric implications and the influence of the chemical structure on the reactivity are discussed.
Claudia Di Biagio, Paola Formenti, Yves Balkanski, Lorenzo Caponi, Mathieu Cazaunau, Edouard Pangui, Emilie Journet, Sophie Nowak, Meinrat O. Andreae, Konrad Kandler, Thuraya Saeed, Stuart Piketh, David Seibert, Earle Williams, and Jean-François Doussin
Atmos. Chem. Phys., 19, 15503–15531, https://doi.org/10.5194/acp-19-15503-2019, https://doi.org/10.5194/acp-19-15503-2019, 2019
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This paper presents a new dataset of laboratory measurements of the shortwave (SW) spectral complex refractive index and single-scattering albedo (SSA) for global mineral dust aerosols of varying origin and composition. Our results show that the dust refractive index and SSA vary strongly from source to source, mostly due to particle iron content changes. We recommend that source-dependent values of the SW spectral refractive index and SSA be used in models and remote sensing applications.
Patrick Chazette, Cyrille Flamant, Julien Totems, Marco Gaetani, Gwendoline Smith, Alexandre Baron, Xavier Landsheere, Karine Desboeufs, Jean-François Doussin, and Paola Formenti
Atmos. Chem. Phys., 19, 14979–15005, https://doi.org/10.5194/acp-19-14979-2019, https://doi.org/10.5194/acp-19-14979-2019, 2019
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Evolution of the vertical distribution and optical properties of aerosols in the free troposphere is analysed for the first time over the Namibian coast, a region where uncertainties on aerosol–cloud coupling in climate simulations are significant. The high variability of atmospheric aerosol composition is highlighted using a combination of ground-based, airborne and space-borne lidar. Aerosols are mainly transported from Angola, but part of the highest aerosol layer may come from South America.
Marc D. Mallet, Barbara D'Anna, Aurélie Même, Maria Chiara Bove, Federico Cassola, Giandomenico Pace, Karine Desboeufs, Claudia Di Biagio, Jean-Francois Doussin, Michel Maille, Dario Massabò, Jean Sciare, Pascal Zapf, Alcide Giorgio di Sarra, and Paola Formenti
Atmos. Chem. Phys., 19, 11123–11142, https://doi.org/10.5194/acp-19-11123-2019, https://doi.org/10.5194/acp-19-11123-2019, 2019
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We present findings from a summertime field campaign at the remote island of Lampedusa in the central Mediterranean Sea. We show that the aerosol loading is similar to coastal sites around the Mediterranean. We observe higher loadings of sulfate and aged organic aerosol from air masses transported over the central and eastern Mediterranean in comparison to those from the western Mediterranean. These results highlight the rarity of pristine air masses, even in remote marine environments.
Dario Massabò, Silvia Giulia Danelli, Paolo Brotto, Antonio Comite, Camilla Costa, Andrea Di Cesare, Jean François Doussin, Federico Ferraro, Paola Formenti, Elena Gatta, Laura Negretti, Maddalena Oliva, Franco Parodi, Luigi Vezzulli, and Paolo Prati
Atmos. Meas. Tech., 11, 5885–5900, https://doi.org/10.5194/amt-11-5885-2018, https://doi.org/10.5194/amt-11-5885-2018, 2018
Claudia Di Biagio, Paola Formenti, Mathieu Cazaunau, Edouard Pangui, Nicolas Marchand, and Jean-François Doussin
Atmos. Meas. Tech., 10, 2923–2939, https://doi.org/10.5194/amt-10-2923-2017, https://doi.org/10.5194/amt-10-2923-2017, 2017
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Mineral dust is one of the most abundant aerosol species at the global scale and an accurate estimation of its absorption at solar wavelengths is crucial to assess its impact on climate. In this work we provide an estimate of the Aethalometer multiple scattering correction for mineral dust aerosols at 450 and 660 nm. Our results suggest that the use of an optimized correction factor can lead to up to 11 % higher absorption coefficient and to 3 % higher single scattering albedo for mineral dust.
Lorenzo Caponi, Paola Formenti, Dario Massabó, Claudia Di Biagio, Mathieu Cazaunau, Edouard Pangui, Servanne Chevaillier, Gautier Landrot, Meinrat O. Andreae, Konrad Kandler, Stuart Piketh, Thuraya Saeed, Dave Seibert, Earle Williams, Yves Balkanski, Paolo Prati, and Jean-François Doussin
Atmos. Chem. Phys., 17, 7175–7191, https://doi.org/10.5194/acp-17-7175-2017, https://doi.org/10.5194/acp-17-7175-2017, 2017
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This paper presents new laboratory measurements of the shortwave mass absorption efficiency (MAE) used by climate models for mineral dust of different origin and at different sizes. We found that small particles are more efficient, by given mass, in absorbing radiation, particularly at shorter wavelength. Because dust has high concentrations in the atmosphere, light absorption by mineral dust can be competitive to other absorbing atmospheric aerosols such as black and brown carbon.
Nga Lee Ng, Steven S. Brown, Alexander T. Archibald, Elliot Atlas, Ronald C. Cohen, John N. Crowley, Douglas A. Day, Neil M. Donahue, Juliane L. Fry, Hendrik Fuchs, Robert J. Griffin, Marcelo I. Guzman, Hartmut Herrmann, Alma Hodzic, Yoshiteru Iinuma, José L. Jimenez, Astrid Kiendler-Scharr, Ben H. Lee, Deborah J. Luecken, Jingqiu Mao, Robert McLaren, Anke Mutzel, Hans D. Osthoff, Bin Ouyang, Benedicte Picquet-Varrault, Ulrich Platt, Havala O. T. Pye, Yinon Rudich, Rebecca H. Schwantes, Manabu Shiraiwa, Jochen Stutz, Joel A. Thornton, Andreas Tilgner, Brent J. Williams, and Rahul A. Zaveri
Atmos. Chem. Phys., 17, 2103–2162, https://doi.org/10.5194/acp-17-2103-2017, https://doi.org/10.5194/acp-17-2103-2017, 2017
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Oxidation of biogenic volatile organic compounds by NO3 is an important interaction between anthropogenic
and natural emissions. This review results from a June 2015 workshop and includes the recent literature
on kinetics, mechanisms, organic aerosol yields, and heterogeneous chemistry; advances in analytical
instrumentation; the current state NO3-BVOC chemistry in atmospheric models; and critical needs for
future research in modeling, field observations, and laboratory studies.
Claudia Di Biagio, Paola Formenti, Yves Balkanski, Lorenzo Caponi, Mathieu Cazaunau, Edouard Pangui, Emilie Journet, Sophie Nowak, Sandrine Caquineau, Meinrat O. Andreae, Konrad Kandler, Thuraya Saeed, Stuart Piketh, David Seibert, Earle Williams, and Jean-François Doussin
Atmos. Chem. Phys., 17, 1901–1929, https://doi.org/10.5194/acp-17-1901-2017, https://doi.org/10.5194/acp-17-1901-2017, 2017
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Modeling the interaction of dust with long-wave (LW) radiation is still a challenge due to the scarcity of information on their refractive index. In this paper, we present a unique dataset of dust refractive indices obtained from in situ measurements in a large smog chamber. Our results show that the dust LW refractive index varies strongly from source to source due to particle composition changes. We recommend taking this variability into account in climate and remote sensing applications.
L. Brégonzio-Rozier, C. Giorio, F. Siekmann, E. Pangui, S. B. Morales, B. Temime-Roussel, A. Gratien, V. Michoud, M. Cazaunau, H. L. DeWitt, A. Tapparo, A. Monod, and J.-F. Doussin
Atmos. Chem. Phys., 16, 1747–1760, https://doi.org/10.5194/acp-16-1747-2016, https://doi.org/10.5194/acp-16-1747-2016, 2016
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The impact of cloud events on isoprene secondary organic aerosol (SOA) formation has been studied from an isoprene/ NOx/light system in an atmospheric simulation chamber. aqSOA formation can be linked to water soluble volatile organic compounds' dissolution in the aqueous phase and to further aqueous phase reactions. Cloud-induced SOA formation is experimentally demonstrated in this study, thus highlighting the importance of aqueous multiphase systems in atmospheric SOA formation estimations.
S. Mailler, L. Menut, A. G. di Sarra, S. Becagli, T. Di Iorio, B. Bessagnet, R. Briant, P. Formenti, J.-F. Doussin, J. L. Gómez-Amo, M. Mallet, G. Rea, G. Siour, D. M. Sferlazzo, R. Traversi, R. Udisti, and S. Turquety
Atmos. Chem. Phys., 16, 1219–1244, https://doi.org/10.5194/acp-16-1219-2016, https://doi.org/10.5194/acp-16-1219-2016, 2016
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We studied the impact of aerosols on tropospheric photolysis rates at Lampedusa during the CharMEx/ADRIMED campaign in June 2013. It is shown by using the CHIMERE chemistry-transport model (CTM) as well as in situ and remote-sensing measurements that taking into account the radiative effect of the tropospheric aerosols improves the ability of the model to reproduce the observed photolysis rates. It is hence important for CTMs to include the radiative effect of aerosols on photochemistry.
M. Mallet, F. Dulac, P. Formenti, P. Nabat, J. Sciare, G. Roberts, J. Pelon, G. Ancellet, D. Tanré, F. Parol, C. Denjean, G. Brogniez, A. di Sarra, L. Alados-Arboledas, J. Arndt, F. Auriol, L. Blarel, T. Bourrianne, P. Chazette, S. Chevaillier, M. Claeys, B. D'Anna, Y. Derimian, K. Desboeufs, T. Di Iorio, J.-F. Doussin, P. Durand, A. Féron, E. Freney, C. Gaimoz, P. Goloub, J. L. Gómez-Amo, M. J. Granados-Muñoz, N. Grand, E. Hamonou, I. Jankowiak, M. Jeannot, J.-F. Léon, M. Maillé, S. Mailler, D. Meloni, L. Menut, G. Momboisse, J. Nicolas, T. Podvin, V. Pont, G. Rea, J.-B. Renard, L. Roblou, K. Schepanski, A. Schwarzenboeck, K. Sellegri, M. Sicard, F. Solmon, S. Somot, B Torres, J. Totems, S. Triquet, N. Verdier, C. Verwaerde, F. Waquet, J. Wenger, and P. Zapf
Atmos. Chem. Phys., 16, 455–504, https://doi.org/10.5194/acp-16-455-2016, https://doi.org/10.5194/acp-16-455-2016, 2016
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The aim of this article is to present an experimental campaign over the Mediterranean focused on aerosol-radiation measurements and modeling. Results indicate an important atmospheric loading associated with a moderate absorbing ability of mineral dust. Observations suggest a complex vertical structure and size distributions characterized by large aerosols within dust plumes. The radiative effect is highly variable, with negative forcing over the Mediterranean and positive over northern Africa.
I. Kourtchev, J.-F. Doussin, C. Giorio, B. Mahon, E. M. Wilson, N. Maurin, E. Pangui, D. S. Venables, J. C. Wenger, and M. Kalberer
Atmos. Chem. Phys., 15, 5683–5695, https://doi.org/10.5194/acp-15-5683-2015, https://doi.org/10.5194/acp-15-5683-2015, 2015
C. Denjean, P. Formenti, B. Picquet-Varrault, E. Pangui, P. Zapf, Y. Katrib, C. Giorio, A. Tapparo, A. Monod, B. Temime-Roussel, P. Decorse, C. Mangeney, and J. F. Doussin
Atmos. Chem. Phys., 15, 3339–3358, https://doi.org/10.5194/acp-15-3339-2015, https://doi.org/10.5194/acp-15-3339-2015, 2015
L. Brégonzio-Rozier, F. Siekmann, C. Giorio, E. Pangui, S. B. Morales, B. Temime-Roussel, A. Gratien, V. Michoud, S. Ravier, M. Cazaunau, A. Tapparo, A. Monod, and J.-F. Doussin
Atmos. Chem. Phys., 15, 2953–2968, https://doi.org/10.5194/acp-15-2953-2015, https://doi.org/10.5194/acp-15-2953-2015, 2015
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First- and higher order -generation products formed from the oxidation of isoprene and methacrolein with OH radicals in the presence of NOx have been studied in a simulation chamber. Differences in light source are proposed to partially explain the discrepancies observed between different studies in the literature for both isoprene- and methacrolein-SOA mass yields. According to our results, these SOA yields in the atmosphere could be lower than suggested by most of the current chamber studies.
C. Denjean, P. Formenti, B. Picquet-Varrault, M. Camredon, E. Pangui, P. Zapf, Y. Katrib, C. Giorio, A. Tapparo, B. Temime-Roussel, A. Monod, B. Aumont, and J. F. Doussin
Atmos. Chem. Phys., 15, 883–897, https://doi.org/10.5194/acp-15-883-2015, https://doi.org/10.5194/acp-15-883-2015, 2015
W. Ait-Helal, A. Borbon, S. Sauvage, J. A. de Gouw, A. Colomb, V. Gros, F. Freutel, M. Crippa, C. Afif, U. Baltensperger, M. Beekmann, J.-F. Doussin, R. Durand-Jolibois, I. Fronval, N. Grand, T. Leonardis, M. Lopez, V. Michoud, K. Miet, S. Perrier, A. S. H. Prévôt, J. Schneider, G. Siour, P. Zapf, and N. Locoge
Atmos. Chem. Phys., 14, 10439–10464, https://doi.org/10.5194/acp-14-10439-2014, https://doi.org/10.5194/acp-14-10439-2014, 2014
C. Denjean, P. Formenti, B. Picquet-Varrault, Y. Katrib, E. Pangui, P. Zapf, and J. F. Doussin
Atmos. Meas. Tech., 7, 183–197, https://doi.org/10.5194/amt-7-183-2014, https://doi.org/10.5194/amt-7-183-2014, 2014
J.-F. Doussin and A. Monod
Atmos. Chem. Phys., 13, 11625–11641, https://doi.org/10.5194/acp-13-11625-2013, https://doi.org/10.5194/acp-13-11625-2013, 2013
Q. J. Zhang, M. Beekmann, F. Drewnick, F. Freutel, J. Schneider, M. Crippa, A. S. H. Prevot, U. Baltensperger, L. Poulain, A. Wiedensohler, J. Sciare, V. Gros, A. Borbon, A. Colomb, V. Michoud, J.-F. Doussin, H. A. C. Denier van der Gon, M. Haeffelin, J.-C. Dupont, G. Siour, H. Petetin, B. Bessagnet, S. N. Pandis, A. Hodzic, O. Sanchez, C. Honoré, and O. Perrussel
Atmos. Chem. Phys., 13, 5767–5790, https://doi.org/10.5194/acp-13-5767-2013, https://doi.org/10.5194/acp-13-5767-2013, 2013
Related subject area
Subject: Gases | Technique: Laboratory Measurement | Topic: Data Processing and Information Retrieval
An Algorithm for Automatic Fitting and Formula Assignment in Atmospheric Mass Spectra
Atmospheric H2 observations from the NOAA Cooperative Global Air Sampling Network
Application of fuzzy c-means clustering for analysis of chemical ionization mass spectra: insights into the gas phase chemistry of NO3-initiated oxidation of isoprene
Wall loss of semi-volatile organic compounds in a Teflon bag chamber for the temperature range of 262–298 K: mechanistic insight on temperature dependence
Obtaining accurate non-methane hydrocarbon data for ambient air in urban areas: comparison of non-methane hydrocarbon data between indirect and direct methods
Reconstruction of high-frequency methane atmospheric concentration peaks from measurements using metal oxide low-cost sensors
Cavity ring-down spectroscopy of water vapor in the deep-blue region
Development and application of a supervised pattern recognition algorithm for identification of fuel-specific emissions profiles
Orbitool: a software tool for analyzing online Orbitrap mass spectrometry data
Dynamic infrared gas analysis from longleaf pine fuel beds burned in a wind tunnel: observation of phenol in pyrolysis and combustion phases
High-precision measurements of nitrous oxide and methane in air with cavity ring-down spectroscopy at 7.6 µm
Mapping and quantifying isomer sets of hydrocarbons ( ≥ C12) in diesel exhaust, lubricating oil and diesel fuel samples using GC × GC-ToF-MS
Uncertainty budgets of major ozone absorption cross sections used in UV remote sensing applications
New and improved infrared absorption cross sections for chlorodifluoromethane (HCFC-22)
High spectral resolution ozone absorption cross-sections – Part 1: Measurements, data analysis and comparison with previous measurements around 293 K
High spectral resolution ozone absorption cross-sections – Part 2: Temperature dependence
Maintaining consistent traceability in high-precision isotope measurements of CO2: a way to verify atmospheric trends of δ13C and δ18O
On the interference of Kr during carbon isotope analysis of methane using continuous-flow combustion–isotope ratio mass spectrometry
OH clock determination by proton transfer reaction mass spectrometry at an environmental chamber
Water isotopic ratios from a continuously melted ice core sample
Valter Mickwitz, Otso Peräkylä, Frans Graeffe, Douglas Worsnop, and Mikael Ehn
EGUsphere, https://doi.org/10.5194/egusphere-2024-3047, https://doi.org/10.5194/egusphere-2024-3047, 2024
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This work presents and evaluates an algorithm that automatically conducts the steps of fitting peaks and identifying formulas, necessary but time consuming steps for most applications of mass spectrometry within atmospheric science. The aim of the algorithm is to save researchers working on these tasks significant amounts of time, and allow them to proceed with their analysis. The work demonstrates that this algorithm can achieve the goal of speeding up analysis, and provide accurate formulas.
Gabrielle Pétron, Andrew M. Crotwell, John Mund, Molly Crotwell, Thomas Mefford, Kirk Thoning, Bradley Hall, Duane Kitzis, Monica Madronich, Eric Moglia, Donald Neff, Sonja Wolter, Armin Jordan, Paul Krummel, Ray Langenfelds, and John Patterson
Atmos. Meas. Tech., 17, 4803–4823, https://doi.org/10.5194/amt-17-4803-2024, https://doi.org/10.5194/amt-17-4803-2024, 2024
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Hydrogen (H2) is a gas in trace amounts in the Earth’s atmosphere with indirect impacts on climate and air quality. Renewed interest in H2 as a low- or zero-carbon source of energy may lead to increased production, uses, and supply chain emissions. NOAA measurements of weekly air samples collected between 2009 and 2021 at over 50 sites in mostly remote locations are now available, and they complement other datasets to study the H2 global budget.
Rongrong Wu, Sören R. Zorn, Sungah Kang, Astrid Kiendler-Scharr, Andreas Wahner, and Thomas F. Mentel
Atmos. Meas. Tech., 17, 1811–1835, https://doi.org/10.5194/amt-17-1811-2024, https://doi.org/10.5194/amt-17-1811-2024, 2024
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Recent advances in high-resolution time-of-flight chemical ionization mass spectrometry (CIMS) enable the detection of highly oxygenated organic molecules, which efficiently contribute to secondary organic aerosol. Here we present an application of fuzzy c-means (FCM) clustering to deconvolve CIMS data. FCM not only reduces the complexity of mass spectrometric data but also the chemical and kinetic information retrieved by clustering gives insights into the chemical processes involved.
Longkun He, Wenli Liu, Yatai Li, Jixuan Wang, Mikinori Kuwata, and Yingjun Liu
Atmos. Meas. Tech., 17, 755–764, https://doi.org/10.5194/amt-17-755-2024, https://doi.org/10.5194/amt-17-755-2024, 2024
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We experimentally investigated vapor wall loss of n-alkanes in a Teflon chamber across a wide temperature range. Increased wall loss was observed at lower temperatures. Further analysis suggests that lower temperatures enhance partitioning of n-alkanes to the surface layer of a Teflon wall but slow their diffusion into the inner layer. The results are important for quantitative analysis of chamber experiments conducted at low temperatures, simulating wintertime or upper-tropospheric conditions.
Song Gao, Yong Yang, Xiao Tong, Linyuan Zhang, Yusen Duan, Guigang Tang, Qiang Wang, Changqing Lin, Qingyan Fu, Lipeng Liu, and Lingning Meng
Atmos. Meas. Tech., 16, 5709–5723, https://doi.org/10.5194/amt-16-5709-2023, https://doi.org/10.5194/amt-16-5709-2023, 2023
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We optimized and conducted an experimental program for the real-time monitoring of non-methane hydrocarbon instruments using the direct method. Changing the enrichment and specially designed columns further improved the test effect. The results correct the measurement errors that have prevailed for many years and can lay a foundation for the evaluation of volatile organic compounds in the regional ambient air and provide direction for the measurement of low-concentration ambient air pollutants.
Rodrigo Andres Rivera Martinez, Diego Santaren, Olivier Laurent, Gregoire Broquet, Ford Cropley, Cécile Mallet, Michel Ramonet, Adil Shah, Leonard Rivier, Caroline Bouchet, Catherine Juery, Olivier Duclaux, and Philippe Ciais
Atmos. Meas. Tech., 16, 2209–2235, https://doi.org/10.5194/amt-16-2209-2023, https://doi.org/10.5194/amt-16-2209-2023, 2023
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A network of low-cost sensors is a good alternative to improve the detection of fugitive CH4 emissions. We present the results of four tests conducted with two types of Figaro sensors that were assembled on four chambers in a laboratory experiment: a comparison of five models to reconstruct the CH4 signal, a strategy to reduce the training set size, a detection of age effects in the sensors and a test of the capability to transfer a model between chambers for the same type of sensor.
Qing-Ying Yang, Eamon K. Conway, Hui Liang, Iouli E. Gordon, Yan Tan, and Shui-Ming Hu
Atmos. Meas. Tech., 15, 4463–4472, https://doi.org/10.5194/amt-15-4463-2022, https://doi.org/10.5194/amt-15-4463-2022, 2022
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Water vapor absorption in the near-UV region is essential to describe the energy budget of Earth; however, there is little spectroscopic information available. And accurate near-UV water absorption is also required in both ground-based observations and satellite missions for trace gas species. Here, we provide the high-resolution spectra of water vapor around 415 nm measured with cavity ring-down spectroscopy. These absorption lines have never been experimentally verified before.
Christos Stamatis and Kelley Claire Barsanti
Atmos. Meas. Tech., 15, 2591–2606, https://doi.org/10.5194/amt-15-2591-2022, https://doi.org/10.5194/amt-15-2591-2022, 2022
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Building on the identification of hundreds of gas-phase chemicals in smoke samples from laboratory and field studies, an algorithm was developed that successfully identified chemical patterns that were consistent among types of trees and unique between types of trees that are common fuels in western coniferous forests. The algorithm is a promising approach for selecting chemical speciation profiles for air quality modeling using a highly reduced suite of measured compounds.
Runlong Cai, Yihao Li, Yohann Clément, Dandan Li, Clément Dubois, Marlène Fabre, Laurence Besson, Sebastien Perrier, Christian George, Mikael Ehn, Cheng Huang, Ping Yi, Yingge Ma, and Matthieu Riva
Atmos. Meas. Tech., 14, 2377–2387, https://doi.org/10.5194/amt-14-2377-2021, https://doi.org/10.5194/amt-14-2377-2021, 2021
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Orbitool is an open-source software tool, mainly coded in Python, with a graphical user interface (GUI), specifically developed to facilitate the analysis of online Orbitrap mass spectrometric data. It is notably optimized for long-term atmospheric measurements and laboratory studies.
Catherine A. Banach, Ashley M. Bradley, Russell G. Tonkyn, Olivia N. Williams, Joey Chong, David R. Weise, Tanya L. Myers, and Timothy J. Johnson
Atmos. Meas. Tech., 14, 2359–2376, https://doi.org/10.5194/amt-14-2359-2021, https://doi.org/10.5194/amt-14-2359-2021, 2021
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We have developed a novel method to identify and characterize the gases emitted in biomass burning fires in a time-resolved fashion. Using time-resolved infrared spectroscopy combined with time-resolved thermal imaging in a wind tunnel, we were able to capture the gas-phase dynamics of the burning of plants native to the southeastern United States.
Jing Tang, Bincheng Li, and Jing Wang
Atmos. Meas. Tech., 12, 2851–2861, https://doi.org/10.5194/amt-12-2851-2019, https://doi.org/10.5194/amt-12-2851-2019, 2019
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A high-sensitivity CH4 and N2O sensor based on mid-IR (7.6 µm) cavity ring-down spectroscopy was developed. The effect of temperature fluctuation on measurement sensitivity was analyzed and corrected, and detection limits of 5 pptv for CH4 and 9 pptv for N2O were experimentally achieved. Separate and continuous measurements of CH4 and N2O concentrations of indoor and outdoor air at different locations showed the spatial and temporal concentration variations of CH4 and N2O in air.
Mohammed S. Alam, Soheil Zeraati-Rezaei, Zhirong Liang, Christopher Stark, Hongming Xu, A. Rob MacKenzie, and Roy M. Harrison
Atmos. Meas. Tech., 11, 3047–3058, https://doi.org/10.5194/amt-11-3047-2018, https://doi.org/10.5194/amt-11-3047-2018, 2018
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Diesel fuel, lubricating oil and diesel exhaust emissions all contain a very complex mixture of chemical compounds with diverse molecular structures. The GC × GC-ToF-MS analytical method is a very powerful way of separating and identifying those compounds. This paper describes the allocation of compounds into groups with similar molecular structures and chemical properties, which facilitates the intercomparison of very complex mixtures such as are found in diesel fuel, oil and emissions.
Mark Weber, Victor Gorshelev, and Anna Serdyuchenko
Atmos. Meas. Tech., 9, 4459–4470, https://doi.org/10.5194/amt-9-4459-2016, https://doi.org/10.5194/amt-9-4459-2016, 2016
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Ozone absorption cross sections measured in the laboratory using spectroscopic means can be a major source of uncertainty in atmospheric ozone retrievals. In this paper we assess the overall uncertainty in three published UV ozone cross-section datasets that are most popular in the remote sensing community. The overall uncertainties were estimated using Monte Carlo simulations. They are important for traceability of atmospheric ozone measuring instruments to common metrological standards.
Jeremy J. Harrison
Atmos. Meas. Tech., 9, 2593–2601, https://doi.org/10.5194/amt-9-2593-2016, https://doi.org/10.5194/amt-9-2593-2016, 2016
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Using infrared sounders on satellite platforms to monitor concentrations of atmospheric HCFC-22, a stratospheric-ozone-depleting molecule which is still increasing in the atmosphere, crucially requires accurate laboratory spectroscopic data. This manuscript describes a new high-resolution infrared absorption cross-section data set for remote-sensing purposes; this improves upon the one currently available in the HITRAN and GEISA databases.
V. Gorshelev, A. Serdyuchenko, M. Weber, W. Chehade, and J. P. Burrows
Atmos. Meas. Tech., 7, 609–624, https://doi.org/10.5194/amt-7-609-2014, https://doi.org/10.5194/amt-7-609-2014, 2014
A. Serdyuchenko, V. Gorshelev, M. Weber, W. Chehade, and J. P. Burrows
Atmos. Meas. Tech., 7, 625–636, https://doi.org/10.5194/amt-7-625-2014, https://doi.org/10.5194/amt-7-625-2014, 2014
L. Huang, A. Chivulescu, D. Ernst, W. Zhang, A.-L. Norman, and Y.-S. Lee
Atmos. Meas. Tech., 6, 1685–1705, https://doi.org/10.5194/amt-6-1685-2013, https://doi.org/10.5194/amt-6-1685-2013, 2013
J. Schmitt, B. Seth, M. Bock, C. van der Veen, L. Möller, C. J. Sapart, M. Prokopiou, T. Sowers, T. Röckmann, and H. Fischer
Atmos. Meas. Tech., 6, 1425–1445, https://doi.org/10.5194/amt-6-1425-2013, https://doi.org/10.5194/amt-6-1425-2013, 2013
P. Barmet, J. Dommen, P. F. DeCarlo, T. Tritscher, A. P. Praplan, S. M. Platt, A. S. H. Prévôt, N. M. Donahue, and U. Baltensperger
Atmos. Meas. Tech., 5, 647–656, https://doi.org/10.5194/amt-5-647-2012, https://doi.org/10.5194/amt-5-647-2012, 2012
V. Gkinis, T. J. Popp, T. Blunier, M. Bigler, S. Schüpbach, E. Kettner, and S. J. Johnsen
Atmos. Meas. Tech., 4, 2531–2542, https://doi.org/10.5194/amt-4-2531-2011, https://doi.org/10.5194/amt-4-2531-2011, 2011
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Short summary
A commercial PTR-ToF-MS has been optimized in order to allow the measurement of individual organic nitrates in the atmosphere. This has been accomplished by shifting the distribution between different ionizing analytes. The proposed approach has been proved to be appropriate for the online detection of individual alkyl nitrates and functionalized nitrates.
A commercial PTR-ToF-MS has been optimized in order to allow the measurement of individual...
