Articles | Volume 14, issue 5
https://doi.org/10.5194/amt-14-3923-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-14-3923-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
27 May 2021
Research article |
| 27 May 2021
| 27 May 2021
Testing the altitude attribution and vertical resolution of AirCore measurements with a new spiking method
Thomas Wagenhäuser
CORRESPONDING AUTHOR
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Frankfurt, 60438, Germany
Andreas Engel
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Frankfurt, 60438, Germany
Robert Sitals
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Frankfurt, 60438, Germany
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EGUsphere, https://doi.org/10.5194/egusphere-2024-4034, https://doi.org/10.5194/egusphere-2024-4034, 2025
This preprint is open for discussion and under review for Atmospheric Measurement Techniques (AMT).
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A large balloon was launched in summer 2021 in the Arctic to carry instruments for trace gas measurements up to 32 km, above the reach of aircraft. The main aims were to evaluate different techniques and atmospheric processes. We focus on halogenated greenhouse gases and ozone-depleting substances. For this, air was collected with the AirCore technique and a cryogenic air sampler and measured after the flight. A companion paper reports observations of major greenhouse gases.
Tanja J. Schuck, Johannes Degen, Timo Keber, Katharina Meixner, Thomas Wagenhäuser, Mélanie Ghysels, Georges Durry, Nadir Amarouche, Alessandro Zanchetta, Steven van Heuven, Huilin Chen, Johannes C. Laube, Sophie Baartman, Carina van der Veen, Maria Elena Popa, and Andreas Engel
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A balloon was launched in 2021 in the Arctic to carry instruments for trace gase measurements up to 32 km. One purpose was to compare measurement techniques. We focus on the major greenhouse gases. To measure these, air was sampled with the AirCore technique and with flask sampling and analysed after the flight. In flight, observations were done with an optical method. In a companion paper we report on observations of chlorine and bromine containing trace gases.
Tanja J. Schuck, Johannes Degen, Eric Hintsa, Peter Hoor, Markus Jesswein, Timo Keber, Daniel Kunkel, Fred Moore, Florian Obersteiner, Matt Rigby, Thomas Wagenhäuser, Luke M. Western, Andreas Zahn, and Andreas Engel
Atmos. Chem. Phys., 24, 689–705, https://doi.org/10.5194/acp-24-689-2024, https://doi.org/10.5194/acp-24-689-2024, 2024
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We study the interhemispheric gradient of sulfur hexafluoride (SF6), a strong long-lived greenhouse gas. Its emissions are stronger in the Northern Hemisphere; therefore, mixing ratios in the Southern Hemisphere lag behind. Comparing the observations to a box model, the model predicts air in the Southern Hemisphere to be older. For a better agreement, the emissions used as model input need to be increased (and their spatial pattern changed), and we need to modify north–south transport.
Thomas Wagenhäuser, Markus Jesswein, Timo Keber, Tanja Schuck, and Andreas Engel
Atmos. Chem. Phys., 23, 3887–3903, https://doi.org/10.5194/acp-23-3887-2023, https://doi.org/10.5194/acp-23-3887-2023, 2023
Short summary
Short summary
A common assumption to derive mean age from trace gas observations is that all air enters the stratosphere through the tropical tropopause. Using SF6 as an age tracer, this leads to negative mean age values close to the Northern Hemispheric extra-tropical tropopause. Our improved method also considers extra-tropical input into the stratosphere. More realistic values are derived using this method. Interhemispheric differences in mean age are found when comparing data from two aircraft campaigns.
Markus Jesswein, Rafael P. Fernandez, Lucas Berná, Alfonso Saiz-Lopez, Jens-Uwe Grooß, Ryan Hossaini, Eric C. Apel, Rebecca S. Hornbrook, Elliot L. Atlas, Donald R. Blake, Stephen Montzka, Timo Keber, Tanja Schuck, Thomas Wagenhäuser, and Andreas Engel
Atmos. Chem. Phys., 22, 15049–15070, https://doi.org/10.5194/acp-22-15049-2022, https://doi.org/10.5194/acp-22-15049-2022, 2022
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This study presents the global and seasonal distribution of the two major brominated short-lived substances CH2Br2 and CHBr3 in the upper troposphere and lower stratosphere based on observations from several aircraft campaigns. They show similar seasonality for both hemispheres, except in the respective hemispheric autumn lower stratosphere. A comparison with the TOMCAT and CAM-Chem models shows good agreement in the annual mean but larger differences in the seasonal consideration.
Markus Jesswein, Heiko Bozem, Hans-Christoph Lachnitt, Peter Hoor, Thomas Wagenhäuser, Timo Keber, Tanja Schuck, and Andreas Engel
Atmos. Chem. Phys., 21, 17225–17241, https://doi.org/10.5194/acp-21-17225-2021, https://doi.org/10.5194/acp-21-17225-2021, 2021
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This study presents and compares inorganic chlorine (Cly) derived from observations with the HALO research aircraft in the Antarctic late winter–early fall 2019 and the Arctic winter 2015–2016. Trend-corrected correlations from the Northern Hemisphere show excellent agreement with those from the Southern Hemisphere. After observation allocation inside and outside the vortex based on N2O measurements, results of the two campaigns reveal substantial differences in Cly within the respective vortex.
Johannes C. Laube, Tanja J. Schuck, Huilin Chen, Markus Geldenhuys, Steven van Heuven, Timo Keber, Maria Elena Popa, Elinor Tuffnell, Bärbel Vogel, Thomas Wagenhäuser, Alessandro Zanchetta, and Andreas Engel
EGUsphere, https://doi.org/10.5194/egusphere-2024-4034, https://doi.org/10.5194/egusphere-2024-4034, 2025
This preprint is open for discussion and under review for Atmospheric Measurement Techniques (AMT).
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Short summary
A large balloon was launched in summer 2021 in the Arctic to carry instruments for trace gas measurements up to 32 km, above the reach of aircraft. The main aims were to evaluate different techniques and atmospheric processes. We focus on halogenated greenhouse gases and ozone-depleting substances. For this, air was collected with the AirCore technique and a cryogenic air sampler and measured after the flight. A companion paper reports observations of major greenhouse gases.
Markus Jesswein, Valentin Lauther, Nicolas Emig, Peter Hoor, Timo Keber, Hans-Christoph Lachnitt, Linda Ort, Tanja Schuck, Johannes Strobel, Ronja Van Luijt, C. Michael Volk, Franziska Weyland, and Andreas Engel
EGUsphere, https://doi.org/10.5194/egusphere-2024-3946, https://doi.org/10.5194/egusphere-2024-3946, 2025
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The study investigates transport within the Asian Summer Monsoon, focussing on how CH2Cl2 reaches the subarctic tropopause region. Using data from the PHILEAS campaign in 2023, events with increased mixing ratios were detected. Their origin, the transport paths to the tropopause region and the potential entry into the stratosphere were analysed. The East Asian Summer Monsoon was identified as the main transport pathway, with only a small contribution to the stratosphere in the following days.
Tanja J. Schuck, Johannes Degen, Timo Keber, Katharina Meixner, Thomas Wagenhäuser, Mélanie Ghysels, Georges Durry, Nadir Amarouche, Alessandro Zanchetta, Steven van Heuven, Huilin Chen, Johannes C. Laube, Sophie Baartman, Carina van der Veen, Maria Elena Popa, and Andreas Engel
EGUsphere, https://doi.org/10.5194/egusphere-2024-3279, https://doi.org/10.5194/egusphere-2024-3279, 2024
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A balloon was launched in 2021 in the Arctic to carry instruments for trace gase measurements up to 32 km. One purpose was to compare measurement techniques. We focus on the major greenhouse gases. To measure these, air was sampled with the AirCore technique and with flask sampling and analysed after the flight. In flight, observations were done with an optical method. In a companion paper we report on observations of chlorine and bromine containing trace gases.
Laura N. Saunders, Kaley A. Walker, Gabriele P. Stiller, Thomas von Clarmann, Florian Haenel, Hella Garny, Harald Bönisch, Chris D. Boone, Ariana E. Castillo, Andreas Engel, Johannes C. Laube, Marianna Linz, Felix Ploeger, David A. Plummer, Eric A. Ray, and Patrick E. Sheese
EGUsphere, https://doi.org/10.5194/egusphere-2024-2117, https://doi.org/10.5194/egusphere-2024-2117, 2024
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We present a 17-year stratospheric age of air dataset derived from ACE-FTS satellite measurements of sulfur hexafluoride. This is the longest continuous, global, and vertically resolved age of air time series available to date. In this paper, we show that this dataset agrees well with age of air datasets based on measurements from other instruments. We also present trends in the midlatitude lower stratosphere that indicate changes in the global circulation that are predicted by climate models.
Felicia Kolonjari, Patrick E. Sheese, Kaley A. Walker, Chris D. Boone, David A. Plummer, Andreas Engel, Stephen A. Montzka, David E. Oram, Tanja Schuck, Gabriele P. Stiller, and Geoffrey C. Toon
Atmos. Meas. Tech., 17, 2429–2449, https://doi.org/10.5194/amt-17-2429-2024, https://doi.org/10.5194/amt-17-2429-2024, 2024
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The Canadian Atmospheric Chemistry Experiment Fourier transform spectrometer (ACE-FTS) satellite instrument is currently providing the only vertically resolved chlorodifluoromethane (HCFC-22) measurements from space. This study assesses the most current ACE-FTS HCFC-22 data product in the upper troposphere and lower stratosphere, as well as modelled HCFC-22 from a 39-year run of the Canadian Middle Atmosphere Model (CMAM39) in the same region.
Tanja J. Schuck, Johannes Degen, Eric Hintsa, Peter Hoor, Markus Jesswein, Timo Keber, Daniel Kunkel, Fred Moore, Florian Obersteiner, Matt Rigby, Thomas Wagenhäuser, Luke M. Western, Andreas Zahn, and Andreas Engel
Atmos. Chem. Phys., 24, 689–705, https://doi.org/10.5194/acp-24-689-2024, https://doi.org/10.5194/acp-24-689-2024, 2024
Short summary
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We study the interhemispheric gradient of sulfur hexafluoride (SF6), a strong long-lived greenhouse gas. Its emissions are stronger in the Northern Hemisphere; therefore, mixing ratios in the Southern Hemisphere lag behind. Comparing the observations to a box model, the model predicts air in the Southern Hemisphere to be older. For a better agreement, the emissions used as model input need to be increased (and their spatial pattern changed), and we need to modify north–south transport.
Thomas Wagenhäuser, Markus Jesswein, Timo Keber, Tanja Schuck, and Andreas Engel
Atmos. Chem. Phys., 23, 3887–3903, https://doi.org/10.5194/acp-23-3887-2023, https://doi.org/10.5194/acp-23-3887-2023, 2023
Short summary
Short summary
A common assumption to derive mean age from trace gas observations is that all air enters the stratosphere through the tropical tropopause. Using SF6 as an age tracer, this leads to negative mean age values close to the Northern Hemispheric extra-tropical tropopause. Our improved method also considers extra-tropical input into the stratosphere. More realistic values are derived using this method. Interhemispheric differences in mean age are found when comparing data from two aircraft campaigns.
Markus Jesswein, Rafael P. Fernandez, Lucas Berná, Alfonso Saiz-Lopez, Jens-Uwe Grooß, Ryan Hossaini, Eric C. Apel, Rebecca S. Hornbrook, Elliot L. Atlas, Donald R. Blake, Stephen Montzka, Timo Keber, Tanja Schuck, Thomas Wagenhäuser, and Andreas Engel
Atmos. Chem. Phys., 22, 15049–15070, https://doi.org/10.5194/acp-22-15049-2022, https://doi.org/10.5194/acp-22-15049-2022, 2022
Short summary
Short summary
This study presents the global and seasonal distribution of the two major brominated short-lived substances CH2Br2 and CHBr3 in the upper troposphere and lower stratosphere based on observations from several aircraft campaigns. They show similar seasonality for both hemispheres, except in the respective hemispheric autumn lower stratosphere. A comparison with the TOMCAT and CAM-Chem models shows good agreement in the annual mean but larger differences in the seasonal consideration.
Luke M. Western, Alison L. Redington, Alistair J. Manning, Cathy M. Trudinger, Lei Hu, Stephan Henne, Xuekun Fang, Lambert J. M. Kuijpers, Christina Theodoridi, David S. Godwin, Jgor Arduini, Bronwyn Dunse, Andreas Engel, Paul J. Fraser, Christina M. Harth, Paul B. Krummel, Michela Maione, Jens Mühle, Simon O'Doherty, Hyeri Park, Sunyoung Park, Stefan Reimann, Peter K. Salameh, Daniel Say, Roland Schmidt, Tanja Schuck, Carolina Siso, Kieran M. Stanley, Isaac Vimont, Martin K. Vollmer, Dickon Young, Ronald G. Prinn, Ray F. Weiss, Stephen A. Montzka, and Matthew Rigby
Atmos. Chem. Phys., 22, 9601–9616, https://doi.org/10.5194/acp-22-9601-2022, https://doi.org/10.5194/acp-22-9601-2022, 2022
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The production of ozone-destroying gases is being phased out. Even though production of one of the main ozone-depleting gases, called HCFC-141b, has been declining for many years, the amount that is being released to the atmosphere has been increasing since 2017. We do not know for sure why this is. A possible explanation is that HCFC-141b that was used to make insulating foams many years ago is only now escaping to the atmosphere, or a large part of its production is not being reported.
Helmut Ziereis, Peter Hoor, Jens-Uwe Grooß, Andreas Zahn, Greta Stratmann, Paul Stock, Michael Lichtenstern, Jens Krause, Vera Bense, Armin Afchine, Christian Rolf, Wolfgang Woiwode, Marleen Braun, Jörn Ungermann, Andreas Marsing, Christiane Voigt, Andreas Engel, Björn-Martin Sinnhuber, and Hermann Oelhaf
Atmos. Chem. Phys., 22, 3631–3654, https://doi.org/10.5194/acp-22-3631-2022, https://doi.org/10.5194/acp-22-3631-2022, 2022
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Airborne observations were conducted in the lowermost Arctic stratosphere during the winter of 2015/2016. The observed distribution of reactive nitrogen shows clear indications of nitrification in mid-winter and denitrification in late winter. This was caused by the formation of polar stratospheric cloud particles, which were observed during several flights. The sedimentation and evaporation of these particles and the descent of air masses cause a redistribution of reactive nitrogen.
Markus Jesswein, Heiko Bozem, Hans-Christoph Lachnitt, Peter Hoor, Thomas Wagenhäuser, Timo Keber, Tanja Schuck, and Andreas Engel
Atmos. Chem. Phys., 21, 17225–17241, https://doi.org/10.5194/acp-21-17225-2021, https://doi.org/10.5194/acp-21-17225-2021, 2021
Short summary
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This study presents and compares inorganic chlorine (Cly) derived from observations with the HALO research aircraft in the Antarctic late winter–early fall 2019 and the Arctic winter 2015–2016. Trend-corrected correlations from the Northern Hemisphere show excellent agreement with those from the Southern Hemisphere. After observation allocation inside and outside the vortex based on N2O measurements, results of the two campaigns reveal substantial differences in Cly within the respective vortex.
Paul D. Hamer, Virginie Marécal, Ryan Hossaini, Michel Pirre, Gisèle Krysztofiak, Franziska Ziska, Andreas Engel, Stephan Sala, Timo Keber, Harald Bönisch, Elliot Atlas, Kirstin Krüger, Martyn Chipperfield, Valery Catoire, Azizan A. Samah, Marcel Dorf, Phang Siew Moi, Hans Schlager, and Klaus Pfeilsticker
Atmos. Chem. Phys., 21, 16955–16984, https://doi.org/10.5194/acp-21-16955-2021, https://doi.org/10.5194/acp-21-16955-2021, 2021
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Bromoform is a stratospheric ozone-depleting gas released by seaweed and plankton transported to the stratosphere via convection in the tropics. We study the chemical interactions of bromoform and its derivatives within convective clouds using a cloud-scale model and observations. Our findings are that soluble bromine gases are efficiently washed out and removed within the convective clouds and that most bromine is transported vertically to the upper troposphere in the form of bromoform.
Meike K. Rotermund, Vera Bense, Martyn P. Chipperfield, Andreas Engel, Jens-Uwe Grooß, Peter Hoor, Tilman Hüneke, Timo Keber, Flora Kluge, Benjamin Schreiner, Tanja Schuck, Bärbel Vogel, Andreas Zahn, and Klaus Pfeilsticker
Atmos. Chem. Phys., 21, 15375–15407, https://doi.org/10.5194/acp-21-15375-2021, https://doi.org/10.5194/acp-21-15375-2021, 2021
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Airborne total bromine (Brtot) and tracer measurements suggest Brtot-rich air masses persistently protruded into the lower stratosphere (LS), creating a high Brtot region over the North Atlantic in fall 2017. The main source is via isentropic transport by the Asian monsoon and to a lesser extent transport across the extratropical tropopause as quantified by a Lagrange model. The transport of Brtot via Central American hurricanes is also observed. Lastly, the impact of Brtot on LS O3 is assessed.
Alistair J. Manning, Alison L. Redington, Daniel Say, Simon O'Doherty, Dickon Young, Peter G. Simmonds, Martin K. Vollmer, Jens Mühle, Jgor Arduini, Gerard Spain, Adam Wisher, Michela Maione, Tanja J. Schuck, Kieran Stanley, Stefan Reimann, Andreas Engel, Paul B. Krummel, Paul J. Fraser, Christina M. Harth, Peter K. Salameh, Ray F. Weiss, Ray Gluckman, Peter N. Brown, John D. Watterson, and Tim Arnold
Atmos. Chem. Phys., 21, 12739–12755, https://doi.org/10.5194/acp-21-12739-2021, https://doi.org/10.5194/acp-21-12739-2021, 2021
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This paper estimates UK emissions of important greenhouse gases (hydrofluorocarbons (HFCs)) using high-quality atmospheric observations and atmospheric modelling. We compare these estimates with those submitted by the UK to the United Nations. We conclude that global concentrations of these gases are still increasing. Our estimates for the UK are 73 % of those reported and that the UK emissions are now falling, demonstrating an impact of UK government policy.
Fides Lefrancois, Markus Jesswein, Markus Thoma, Andreas Engel, Kieran Stanley, and Tanja Schuck
Atmos. Meas. Tech., 14, 4669–4687, https://doi.org/10.5194/amt-14-4669-2021, https://doi.org/10.5194/amt-14-4669-2021, 2021
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Synthetic halocarbons can contribute to stratospheric ozone depletion or to climate change. In many applications they have been replaced over the last years. The presented non-target analysis shows an application approach to quantify those replacements retrospectively, using recorded data of air measurements with gas chromatography coupled to time-of-flight mass spectrometry. We focus on the retrospective analysis of the fourth-generation halocarbons, detected at Taunus Observatory in Germany.
Felix Ploeger, Mohamadou Diallo, Edward Charlesworth, Paul Konopka, Bernard Legras, Johannes C. Laube, Jens-Uwe Grooß, Gebhard Günther, Andreas Engel, and Martin Riese
Atmos. Chem. Phys., 21, 8393–8412, https://doi.org/10.5194/acp-21-8393-2021, https://doi.org/10.5194/acp-21-8393-2021, 2021
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We investigate the global stratospheric circulation (Brewer–Dobson circulation) in the new ECMWF ERA5 reanalysis based on age of air simulations, and we compare it to results from the preceding ERA-Interim reanalysis. Our results show a slower stratospheric circulation and higher age for ERA5. The age of air trend in ERA5 over the 1989–2018 period is negative throughout the stratosphere, related to multi-annual variability and a potential contribution from changes in the reanalysis system.
Marius Hauck, Harald Bönisch, Peter Hoor, Timo Keber, Felix Ploeger, Tanja J. Schuck, and Andreas Engel
Atmos. Chem. Phys., 20, 8763–8785, https://doi.org/10.5194/acp-20-8763-2020, https://doi.org/10.5194/acp-20-8763-2020, 2020
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This study features an extended inversion method that includes transport across the extratropical tropopause to derive age spectra in the lowermost stratosphere from in situ trace gas measurements. The refined method is validated in a model setup and applied to data gained with the HALO research aircraft. Results are congruent with the findings of previous studies so that the method provides a promising toolset for the analysis of stratospheric dynamics based on observations in the future.
Frauke Fritsch, Hella Garny, Andreas Engel, Harald Bönisch, and Roland Eichinger
Atmos. Chem. Phys., 20, 8709–8725, https://doi.org/10.5194/acp-20-8709-2020, https://doi.org/10.5194/acp-20-8709-2020, 2020
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We test two methods to derive age of air as a diagnostic of the Brewer–Dobson circulation from non-linear increasing trace gases such as SF6 using a chemistry-climate model and observations. Both the model and the observations show systematic variation of the age of air trend dependent on the chosen assumptions that are required when deriving age of air from measurements. This provides insight into the differences in age of air trends of observations and models.
Timo Keber, Harald Bönisch, Carl Hartick, Marius Hauck, Fides Lefrancois, Florian Obersteiner, Akima Ringsdorf, Nils Schohl, Tanja Schuck, Ryan Hossaini, Phoebe Graf, Patrick Jöckel, and Andreas Engel
Atmos. Chem. Phys., 20, 4105–4132, https://doi.org/10.5194/acp-20-4105-2020, https://doi.org/10.5194/acp-20-4105-2020, 2020
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In this paper we summarize observations of short-lived halocarbons in the tropopause region. We show that, especially during winter, the levels of short-lived bromine gases at the extratropical tropopause are higher than at the tropical tropopause. We discuss the impact of the distributions on stratospheric bromine levels and compare our observations to two models with four different emission scenarios.
Tanja J. Schuck, Ann-Katrin Blank, Elisa Rittmeier, Jonathan Williams, Carl A. M. Brenninkmeijer, Andreas Engel, and Andreas Zahn
Atmos. Meas. Tech., 13, 73–84, https://doi.org/10.5194/amt-13-73-2020, https://doi.org/10.5194/amt-13-73-2020, 2020
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Air sample collection aboard aircraft is a tool to measure atmospheric trace gas mixing ratios at altitude. We present results on the stability of 28 halocarbons during storage of air samples collected in stainless-steel flasks inside an automated air sampling unit which is part of the CARIBIC instrument package. Selected fluorinated compounds grew during the experiments while short-lived compounds were depleted. Individual substances were additionally influenced by high mixing ratios of ozone.
Andreas Marsing, Tina Jurkat-Witschas, Jens-Uwe Grooß, Stefan Kaufmann, Romy Heller, Andreas Engel, Peter Hoor, Jens Krause, and Christiane Voigt
Atmos. Chem. Phys., 19, 10757–10772, https://doi.org/10.5194/acp-19-10757-2019, https://doi.org/10.5194/acp-19-10757-2019, 2019
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We study the partitioning of inorganic chlorine into active (ozone-depleting) and reservoir species in the lowermost stratosphere of the Arctic polar vortex, using novel in situ aircraft measurements in winter 2015/2016. We observe a change in recovery pathways of the reservoirs HCl and ClONO2 with increasing potential temperature. A comparison with the CLaMS model relates the observations to the vortex-wide evolution and confirms unresolved discrepancies in the mid-winter HCl distribution.
Felix Ploeger, Bernard Legras, Edward Charlesworth, Xiaolu Yan, Mohamadou Diallo, Paul Konopka, Thomas Birner, Mengchu Tao, Andreas Engel, and Martin Riese
Atmos. Chem. Phys., 19, 6085–6105, https://doi.org/10.5194/acp-19-6085-2019, https://doi.org/10.5194/acp-19-6085-2019, 2019
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We analyse the change in the circulation of the middle atmosphere based on current generation meteorological reanalysis data sets. We find that long-term changes from 1989 to 2015 are similar for the chosen reanalyses, mainly resembling the forced response in climate model simulations to climate change. For shorter periods circulation changes are less robust, and the representation of decadal variability appears to be a major uncertainty for modelling the circulation of the middle atmosphere.
Marius Hauck, Frauke Fritsch, Hella Garny, and Andreas Engel
Atmos. Chem. Phys., 19, 5269–5291, https://doi.org/10.5194/acp-19-5269-2019, https://doi.org/10.5194/acp-19-5269-2019, 2019
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The paper presents a modified method to invert mixing ratios of chemically active tracers into stratospheric age spectra. It features an imposed seasonal cycle to include transport seasonality into the spectra. An idealized set of tracers from a model is used as proof of concept and results are in good agreement with the model reference, except for the lowermost stratosphere. Applicability is studied with focus on number of tracers and error tolerance, providing a starting point for future work.
Tanja J. Schuck, Fides Lefrancois, Franziska Gallmann, Danrong Wang, Markus Jesswein, Jesica Hoker, Harald Bönisch, and Andreas Engel
Atmos. Chem. Phys., 18, 16553–16569, https://doi.org/10.5194/acp-18-16553-2018, https://doi.org/10.5194/acp-18-16553-2018, 2018
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We present the first results of regular halocarbon measurements at Taunus Observatory, Germany. Halogenated gases contribute to stratospheric ozone depletion and to radiative forcing. Time-of-flight mass spectrometry allows one to assess a large number of compounds; the measurements are expected to provide better constraints for European emission estimates. CFC-11 and CFC-12 show small unexpected differences regarding outlier occurrence and seasonality, indicating ongoing emissions of CFC-11.
Simon Chabrillat, Corinne Vigouroux, Yves Christophe, Andreas Engel, Quentin Errera, Daniele Minganti, Beatriz M. Monge-Sanz, Arjo Segers, and Emmanuel Mahieu
Atmos. Chem. Phys., 18, 14715–14735, https://doi.org/10.5194/acp-18-14715-2018, https://doi.org/10.5194/acp-18-14715-2018, 2018
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Mean age of stratospheric air is computed for the period 1989–2015 with a kinematic transport model which uses surface pressure and wind fields from five reanalyses: ERA-I, MERRA-2, MERRA, CFSR, JRA-55. The spread between the resulting datasets is as large as in climate model intercomparisons; the age trends have large disagreement and depend strongly on the considered period. We highlight the need for similar studies using diabatic transport models which also use temperature and heating rates.
Sören Johansson, Wolfgang Woiwode, Michael Höpfner, Felix Friedl-Vallon, Anne Kleinert, Erik Kretschmer, Thomas Latzko, Johannes Orphal, Peter Preusse, Jörn Ungermann, Michelle L. Santee, Tina Jurkat-Witschas, Andreas Marsing, Christiane Voigt, Andreas Giez, Martina Krämer, Christian Rolf, Andreas Zahn, Andreas Engel, Björn-Martin Sinnhuber, and Hermann Oelhaf
Atmos. Meas. Tech., 11, 4737–4756, https://doi.org/10.5194/amt-11-4737-2018, https://doi.org/10.5194/amt-11-4737-2018, 2018
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We present two-dimensional cross sections of temperature, HNO3, O3, ClONO2, H2O and CFC-12 from measurements of the GLORIA infrared limb imager during the POLSTRACC/GW-LCYCLE/SALSA aircraft campaigns in the Arctic winter 2015/2016. GLORIA sounded the atmosphere between 5 and 14 km with vertical resolutions of 0.4–1 km. Estimated errors are in the range of 1–2 K (temperature) and 10 %–20 % (trace gases). Comparisons to in situ instruments onboard the aircraft and to Aura/MLS are shown.
Jens Krause, Peter Hoor, Andreas Engel, Felix Plöger, Jens-Uwe Grooß, Harald Bönisch, Timo Keber, Björn-Martin Sinnhuber, Wolfgang Woiwode, and Hermann Oelhaf
Atmos. Chem. Phys., 18, 6057–6073, https://doi.org/10.5194/acp-18-6057-2018, https://doi.org/10.5194/acp-18-6057-2018, 2018
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We present tracer measurements of CO and N2O measured during the POLSTRACC aircraft campaign in winter 2015–2016. We found enhanced CO values relative to N2O in the polar lower stratosphere in addition to the ageing of this region during winter. By using model simulations it was possible to link this enhancement to an increased mixing of the tropical tropopause. We thus conclude that the polar lower stratosphere in late winter is strongly influenced by quasi-isentropic mixing from the tropics.
Emma C. Leedham Elvidge, Harald Bönisch, Carl A. M. Brenninkmeijer, Andreas Engel, Paul J. Fraser, Eileen Gallacher, Ray Langenfelds, Jens Mühle, David E. Oram, Eric A. Ray, Anna R. Ridley, Thomas Röckmann, William T. Sturges, Ray F. Weiss, and Johannes C. Laube
Atmos. Chem. Phys., 18, 3369–3385, https://doi.org/10.5194/acp-18-3369-2018, https://doi.org/10.5194/acp-18-3369-2018, 2018
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Chemical species measured in stratospheric air can be used as proxies for stratospheric circulation changes which cannot be measured directly. A range of tracers is important to understand changing stratospheric dynamics. We demonstrate the suitability of PFCs and HFCs as tracers and support recent work that reduces the current stratospheric lifetime of SF6. Updates to policy-relevant parameters (e.g. stratospheric lifetime) linked to this change are provided for O3-depleting substances.
Andreas Engel, Harald Bönisch, Jennifer Ostermöller, Martyn P. Chipperfield, Sandip Dhomse, and Patrick Jöckel
Atmos. Chem. Phys., 18, 601–619, https://doi.org/10.5194/acp-18-601-2018, https://doi.org/10.5194/acp-18-601-2018, 2018
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We present a new method to derive equivalent effective stratospheric chlorine (EESC), which is based on an improved formulation of the propagation of trends of species with chemical loss from the troposphere to the stratosphere. EESC calculated with the new method shows much better agreement with model-derived ESC. Based on this new formulation, we expect the halogen impact on midlatitude stratospheric ozone to return to 1980 values about 10 years later, then using the current formulation.
Ellen Eckert, Thomas von Clarmann, Alexandra Laeng, Gabriele P. Stiller, Bernd Funke, Norbert Glatthor, Udo Grabowski, Sylvia Kellmann, Michael Kiefer, Andrea Linden, Arne Babenhauserheide, Gerald Wetzel, Christopher Boone, Andreas Engel, Jeremy J. Harrison, Patrick E. Sheese, Kaley A. Walker, and Peter F. Bernath
Atmos. Meas. Tech., 10, 2727–2743, https://doi.org/10.5194/amt-10-2727-2017, https://doi.org/10.5194/amt-10-2727-2017, 2017
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We retrieved vertical profiles of CCl4 from MIPAS Envisat IMK/IAA data. A detailed description of all characteristics is included in the paper as well as comparisons with historical measurements and comparisons with collocated measurements of instruments covering the same time span as MIPAS Envisat. A particular focus also lies on the usage of a new CCl4 spectroscopic dataset introduced recently, which leads to more realistic CCl4 volume mixing ratios.
Olivier Membrive, Cyril Crevoisier, Colm Sweeney, François Danis, Albert Hertzog, Andreas Engel, Harald Bönisch, and Laurence Picon
Atmos. Meas. Tech., 10, 2163–2181, https://doi.org/10.5194/amt-10-2163-2017, https://doi.org/10.5194/amt-10-2163-2017, 2017
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A new high-resolution AirCore system is presented. This system flown with stratospheric balloons allows us to sample atmospheric air during the descent. The analysis of trace gases (CO2 and CH4 in this case) in the collected air sample provides information on the vertical distribution along the atmospheric column. The continuous vertical profiles retrieved may contribute to several research topics concerning the observation of greenhouse gases and, more generally, carbon cycle studies.
Andreas Engel, Harald Bönisch, Markus Ullrich, Robert Sitals, Olivier Membrive, Francois Danis, and Cyril Crevoisier
Atmos. Chem. Phys., 17, 6825–6838, https://doi.org/10.5194/acp-17-6825-2017, https://doi.org/10.5194/acp-17-6825-2017, 2017
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AirCore is new technique for sampling stratospheric air. We present new observations of CO2 and CH4 using AirCore and derive stratospheric transport time, called the mean age of air. The purpose of using AirCore is to provide a cost-effective tool for deriving mean age. Mean age may serve as a proxy to investigate changes in stratospheric circulation. We show that there is no statistically significant trend in our 40-year time series of mean age, which is now extended using AirCore.
Mohamadou Diallo, Bernard Legras, Eric Ray, Andreas Engel, and Juan A. Añel
Atmos. Chem. Phys., 17, 3861–3878, https://doi.org/10.5194/acp-17-3861-2017, https://doi.org/10.5194/acp-17-3861-2017, 2017
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We construct a new monthly zonal mean CO2 distribution from the upper troposphere to the stratosphere over the 2000–2010 period. The main features of the CO2 distribution are consistent with expected variability due to the transport of long-lived trace gases by the Brewer–Dobson circulation. The method used to construct this CO2 product is unique and should be useful for model and satellite validation in the upper troposphere and stratosphere.
Jennifer Ostermöller, Harald Bönisch, Patrick Jöckel, and Andreas Engel
Atmos. Chem. Phys., 17, 3785–3797, https://doi.org/10.5194/acp-17-3785-2017, https://doi.org/10.5194/acp-17-3785-2017, 2017
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We analysed the temporal evolution of fractional release factors (FRFs) from EMAC model simulations for several halocarbons and nitrous oxide. The current formulation of FRFs yields values that depend on the tropospheric trend of the species. This is a problematic issue for the application of FRF in the calculation of steady-state quantities (e.g. ODP). Including a loss term in the calculation, we develop a new formulation of FRF and find that the time dependence can almost be compensated.
Florian Obersteiner, Harald Bönisch, Timo Keber, Simon O'Doherty, and Andreas Engel
Atmos. Meas. Tech., 9, 5265–5279, https://doi.org/10.5194/amt-9-5265-2016, https://doi.org/10.5194/amt-9-5265-2016, 2016
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The analysis of trace gases in ambient air requires a preconcentration technique, in many cases to make the species of interest detectable and quantifiable. In this paper, such a preconcentration set-up is presented. Target species are trapped on adsorptive material cooled by a Stirling cooler which allows for a very low adsorption temperature but only requires electrical power. A simple and lightweight mechanical design guarantees very good suitability for remote-site field operation.
Stefan Müller, Peter Hoor, Heiko Bozem, Ellen Gute, Bärbel Vogel, Andreas Zahn, Harald Bönisch, Timo Keber, Martina Krämer, Christian Rolf, Martin Riese, Hans Schlager, and Andreas Engel
Atmos. Chem. Phys., 16, 10573–10589, https://doi.org/10.5194/acp-16-10573-2016, https://doi.org/10.5194/acp-16-10573-2016, 2016
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In situ airborne measurements performed during TACTS/ESMVal 2012 were analysed to investigate the chemical compostion of the upper troposphere and lower stratosphere. N2O, CO and O3 data show an increase in tropospherically affected air masses within the extratropical stratosphere from August to September 2012, which originate from the Asian monsoon region. Thus, the Asian monsoon anticyclone significantly affected the chemical composition of the extratropical stratosphere during summer 2012.
E. Eckert, A. Laeng, S. Lossow, S. Kellmann, G. Stiller, T. von Clarmann, N. Glatthor, M. Höpfner, M. Kiefer, H. Oelhaf, J. Orphal, B. Funke, U. Grabowski, F. Haenel, A. Linden, G. Wetzel, W. Woiwode, P. F. Bernath, C. Boone, G. S. Dutton, J. W. Elkins, A. Engel, J. C. Gille, F. Kolonjari, T. Sugita, G. C. Toon, and K. A. Walker
Atmos. Meas. Tech., 9, 3355–3389, https://doi.org/10.5194/amt-9-3355-2016, https://doi.org/10.5194/amt-9-3355-2016, 2016
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We investigate the accuracy, precision and long-term stability of the MIPAS Envisat IMK/IAA CFC-11 (CCl3F) and CFC-12 (CCl2F2) products.
For comparisons we use several data products from satellite, airplane and balloon-borne instruments as well as ground-based data.
MIPAS Envisat CFC-11 has a slight high bias at the lower end of the profile.
CFC-12 agrees well with other data products.
The temporal stability is good up to ~ 30 km, but still leaves room for improvement.
R. Hossaini, P. K. Patra, A. A. Leeson, G. Krysztofiak, N. L. Abraham, S. J. Andrews, A. T. Archibald, J. Aschmann, E. L. Atlas, D. A. Belikov, H. Bönisch, L. J. Carpenter, S. Dhomse, M. Dorf, A. Engel, W. Feng, S. Fuhlbrügge, P. T. Griffiths, N. R. P. Harris, R. Hommel, T. Keber, K. Krüger, S. T. Lennartz, S. Maksyutov, H. Mantle, G. P. Mills, B. Miller, S. A. Montzka, F. Moore, M. A. Navarro, D. E. Oram, K. Pfeilsticker, J. A. Pyle, B. Quack, A. D. Robinson, E. Saikawa, A. Saiz-Lopez, S. Sala, B.-M. Sinnhuber, S. Taguchi, S. Tegtmeier, R. T. Lidster, C. Wilson, and F. Ziska
Atmos. Chem. Phys., 16, 9163–9187, https://doi.org/10.5194/acp-16-9163-2016, https://doi.org/10.5194/acp-16-9163-2016, 2016
M. Chirkov, G. P. Stiller, A. Laeng, S. Kellmann, T. von Clarmann, C. D. Boone, J. W. Elkins, A. Engel, N. Glatthor, U. Grabowski, C. M. Harth, M. Kiefer, F. Kolonjari, P. B. Krummel, A. Linden, C. R. Lunder, B. R. Miller, S. A. Montzka, J. Mühle, S. O'Doherty, J. Orphal, R. G. Prinn, G. Toon, M. K. Vollmer, K. A. Walker, R. F. Weiss, A. Wiegele, and D. Young
Atmos. Chem. Phys., 16, 3345–3368, https://doi.org/10.5194/acp-16-3345-2016, https://doi.org/10.5194/acp-16-3345-2016, 2016
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HCFC-22 global distributions from MIPAS measurements for 2005 to 2012 are presented. Tropospheric trends are in good agreement with ground-based observations. A layer of enhanced HCFC-22 in the upper tropospheric tropics and northern subtropics is identified to come from Asian sources uplifted in the Asian monsoon. Stratospheric distributions provide show seasonal, semi-annual, and QBO-related variations. Hemispheric asymmetries of trends hint towards a change in the stratospheric circulation.
Andreas Engel, Harald Bönisch, Tim Schwarzenberger, Hans-Peter Haase, Katja Grunow, Jana Abalichin, and Stephan Sala
Atmos. Meas. Tech., 9, 1051–1062, https://doi.org/10.5194/amt-9-1051-2016, https://doi.org/10.5194/amt-9-1051-2016, 2016
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We present a validation of MIPAS-ENVISAT vertical profiles (ESA operational retrieval version 6.0) of N2O, CH4, CFC-12, and CFC-11. The geophysical validation is performed using data from a balloon-borne cryogenic whole air sampler and trajectory matching. We show that the validation results are different for the period prior to 2005 compared to the post 2005 period. N2O, CH4, and CFC-12 show partly good agreement while CFC-11 data from this retrieval cannot be used for scientific studies.
F. Obersteiner, H. Bönisch, and A. Engel
Atmos. Meas. Tech., 9, 179–194, https://doi.org/10.5194/amt-9-179-2016, https://doi.org/10.5194/amt-9-179-2016, 2016
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We present the characterization and application of a new gas chromatography time-of-flight mass spectrometry instrument, with focus on quantitative analysis of halocarbons in air samples. The applicability of the TOFMS technique, e.g. to form the basis of a "digital air archieve", is supported by the findings of this work: very high sensitivity, high measurement precision, a large dynamical range and an open data format which allows in-depth analysis of the data.
A. Laeng, J. Plieninger, T. von Clarmann, U. Grabowski, G. Stiller, E. Eckert, N. Glatthor, F. Haenel, S. Kellmann, M. Kiefer, A. Linden, S. Lossow, L. Deaver, A. Engel, M. Hervig, I. Levin, M. McHugh, S. Noël, G. Toon, and K. Walker
Atmos. Meas. Tech., 8, 5251–5261, https://doi.org/10.5194/amt-8-5251-2015, https://doi.org/10.5194/amt-8-5251-2015, 2015
J. Hoker, F. Obersteiner, H. Bönisch, and A. Engel
Atmos. Meas. Tech., 8, 2195–2206, https://doi.org/10.5194/amt-8-2195-2015, https://doi.org/10.5194/amt-8-2195-2015, 2015
M. Kaufmann, J. Blank, T. Guggenmoser, J. Ungermann, A. Engel, M. Ern, F. Friedl-Vallon, D. Gerber, J. U. Grooß, G. Guenther, M. Höpfner, A. Kleinert, E. Kretschmer, Th. Latzko, G. Maucher, T. Neubert, H. Nordmeyer, H. Oelhaf, F. Olschewski, J. Orphal, P. Preusse, H. Schlager, H. Schneider, D. Schuettemeyer, F. Stroh, O. Suminska-Ebersoldt, B. Vogel, C. M. Volk, W. Woiwode, and M. Riese
Atmos. Meas. Tech., 8, 81–95, https://doi.org/10.5194/amt-8-81-2015, https://doi.org/10.5194/amt-8-81-2015, 2015
A. Tilgner, L. Schöne, P. Bräuer, D. van Pinxteren, E. Hoffmann, G. Spindler, S. A. Styler, S. Mertes, W. Birmili, R. Otto, M. Merkel, K. Weinhold, A. Wiedensohler, H. Deneke, R. Schrödner, R. Wolke, J. Schneider, W. Haunold, A. Engel, A. Wéber, and H. Herrmann
Atmos. Chem. Phys., 14, 9105–9128, https://doi.org/10.5194/acp-14-9105-2014, https://doi.org/10.5194/acp-14-9105-2014, 2014
S. Sala, H. Bönisch, T. Keber, D. E. Oram, G. Mills, and A. Engel
Atmos. Chem. Phys., 14, 6903–6923, https://doi.org/10.5194/acp-14-6903-2014, https://doi.org/10.5194/acp-14-6903-2014, 2014
S. Tegtmeier, K. Krüger, B. Quack, E. Atlas, D. R. Blake, H. Boenisch, A. Engel, H. Hepach, R. Hossaini, M. A. Navarro, S. Raimund, S. Sala, Q. Shi, and F. Ziska
Atmos. Chem. Phys., 13, 11869–11886, https://doi.org/10.5194/acp-13-11869-2013, https://doi.org/10.5194/acp-13-11869-2013, 2013
R. Hossaini, H. Mantle, M. P. Chipperfield, S. A. Montzka, P. Hamer, F. Ziska, B. Quack, K. Krüger, S. Tegtmeier, E. Atlas, S. Sala, A. Engel, H. Bönisch, T. Keber, D. Oram, G. Mills, C. Ordóñez, A. Saiz-Lopez, N. Warwick, Q. Liang, W. Feng, F. Moore, B. R. Miller, V. Marécal, N. A. D. Richards, M. Dorf, and K. Pfeilsticker
Atmos. Chem. Phys., 13, 11819–11838, https://doi.org/10.5194/acp-13-11819-2013, https://doi.org/10.5194/acp-13-11819-2013, 2013
P. D. Hamer, V. Marécal, R. Hossaini, M. Pirre, N. Warwick, M. Chipperfield, A. A. Samah, N. Harris, A. Robinson, B. Quack, A. Engel, K. Krüger, E. Atlas, K. Subramaniam, D. Oram, Emma C. Leedham Elvidge, G. Mills, K. Pfeilsticker, S. Sala, T. Keber, H. Bönisch, L. K. Peng, M. S. M. Nadzir, P. T. Lim, A. Mujahid, A. Anton, H. Schlager, V. Catoire, G. Krysztofiak, S. Fühlbrügge, M. Dorf, and W. T. Sturges
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-20611-2013, https://doi.org/10.5194/acpd-13-20611-2013, 2013
Revised manuscript not accepted
J. C. Laube, A. Keil, H. Bönisch, A. Engel, T. Röckmann, C. M. Volk, and W. T. Sturges
Atmos. Chem. Phys., 13, 2779–2791, https://doi.org/10.5194/acp-13-2779-2013, https://doi.org/10.5194/acp-13-2779-2013, 2013
Related subject area
Subject: Gases | Technique: In Situ Measurement | Topic: Instruments and Platforms
The ASK-16 motorized glider: an airborne eddy covariance platform to measure turbulence, energy, and matter fluxes
Development of a Peltier-based chilled-mirror hygrometer, SKYDEW, for tropospheric and lower-stratospheric water vapor measurements
Deployment and evaluation of an NH4+∕ H3O+ reagent ion switching chemical ionization mass spectrometer for the detection of reduced and oxygenated gas-phase organic compounds
An economical tunable diode laser spectrometer for fast-response measurements of water vapor in the atmospheric boundary layer
Observation of GHG vertical profile in the boundary layer of the Mount Qomolangma region using a multirotor UAV
Eddy covariance with slow-response greenhouse gas analysers on tall towers: bridging atmospheric and ecosystem greenhouse gas networks
Development of a portable laser-flash photolysis Faraday rotation spectrometer for measuring atmospheric total OH reactivity
An overview of outdoor low-cost gas-phase air quality sensor deployments: current efforts, trends, and limitations
Multiphysical description of atmospheric pressure interface chemical ionisation in MION2 and Eisele type inlets
A portable nitrogen dioxide instrument using cavity-enhanced absorption spectroscopy
Development and deployment of a mid-cost CO2 sensor monitoring network to support atmospheric inverse modeling for quantifying urban CO2 emissions in Paris
UAV-based in situ measurements of CO2 and CH4 fluxes over complex natural ecosystems
Advances in OH reactivity instruments for airborne field measurements
A new aerial approach for quantifying and attributing methane emissions: implementation and validation
Vertical profiles and surface distributions of trace gases (CO, O3, NO, NO2) in the Arctic wintertime boundary layer using low-cost sensors during ALPACA-2022
Drone CO2 measurements during the Tajogaite volcanic eruption
Impact and Optimization of Calibration Conditions for Air Quality Sensors in the Long-term Field Monitoring
Multi-decadal atmospheric carbon dioxide measurements in Hungary, central Europe
Reliable water vapour isotopic composition measurements at low humidity using frequency-stabilised cavity ring-down spectroscopy
A measurement system for CO2 and CH4 emissions quantification of industrial sites using a new in situ concentration sensor operated on board uncrewed aircraft vehicles
Using metal oxide gas sensors to estimate the emission rates and locations of methane leaks in an industrial site: assessment with controlled methane releases
Toward on-demand measurements of greenhouse gas emissions using an uncrewed aircraft AirCore system
A modular approach to volatile organic compound samplers for tethered balloon and drone platforms
Long-term evaluation of commercial air quality sensors: an overview from the QUANT (Quantification of Utility of Atmospheric Network Technologies) study
In-flight characterization of a compact airborne quantum cascade laser absorption spectrometer
Full characterization and calibration of a transfer standard monitor for atmospheric radon measurements
Observing low-altitude features in ozone concentrations in a shoreline environment via uncrewed aerial systems
An integrated uncrewed aerial vehicle platform with sensing and sampling systems for the measurement of air pollutant concentrations
Design and evaluation of a low-cost sensor node for near-background methane measurement
Development of a Multichannel Organics In situ enviRonmental Analyzer (MOIRA) for mobile measurements of volatile organic compounds
Evaluation of Aeris mid-infrared absorption (MIRA), Picarro CRDS (cavity ring-down spectroscopy) G2307, and dinitrophenylhydrazine (DNPH)-based sampling for long-term formaldehyde monitoring efforts
Performance characterization of a laminar gas inlet
Validation and field application of a low-cost device to measure CO2 and evapotranspiration (ET) fluxes
Identifying and correcting interferences to PTR-ToF-MS measurements of isoprene and other urban volatile organic compounds
Development of a continuous UAV-mounted air sampler and application to the quantification of CO2 and CH4 emissions from a major coking plant
Uptake behavior of polycyclic aromatic compounds during field calibrations of the XAD-based passive air sampler across seasons and locations
Effect of land–sea air mass transport on spatiotemporal distributions of atmospheric CO2 and CH4 mixing ratios over the southern Yellow Sea
HYPHOP: a tool for high-altitude, long-range monitoring of hydrogen peroxide and higher organic peroxides in the atmosphere
Portable, low-cost samplers for distributed sampling of atmospheric gases
SI-traceable validation of a laser spectrometer for balloon-borne measurements of water vapor in the upper atmosphere
Field evaluation of low-cost electrochemical air quality gas sensors under extreme temperature and relative humidity conditions
A novel, cost-effective analytical method for measuring high-resolution vertical profiles of stratospheric trace gases using a gas chromatograph coupled with an electron capture detector
Ethylene oxide monitor with part-per-trillion precision for in situ measurements
Development of an automated pump-efficiency measuring system for ozonesondes utilizing an airbag-type flowmeter
Short-term variability of atmospheric helium revealed through a cryo-enrichment method
Using tunable infrared laser direct absorption spectroscopy for ambient hydrogen chloride detection: HCl-TILDAS
New methods for the calibration of optical resonators: integrated calibration by means of optical modulation (ICOM) and narrow-band cavity ring-down (NB-CRD)
A modular field system for near-surface, vertical profiling of the atmospheric composition in harsh environments using cavity ring-down spectroscopy
Field comparison of two novel open-path instruments that measure dry deposition and emission of ammonia using flux-gradient and eddy covariance methods
Development of multi-channel whole-air sampling equipment onboard an unmanned aerial vehicle for investigating volatile organic compounds' vertical distribution in the planetary boundary layer
Inge Wiekenkamp, Anna Katharina Lehmann, Alexander Bütow, Jörg Hartmann, Stefan Metzger, Thomas Ruhtz, Christian Wille, Mathias Zöllner, and Torsten Sachs
Atmos. Meas. Tech., 18, 749–772, https://doi.org/10.5194/amt-18-749-2025, https://doi.org/10.5194/amt-18-749-2025, 2025
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Airborne eddy covariance platforms are crucial to measure three-dimensional wind and turbulent matter and energy transport between the surface and the atmosphere at larger scales. In this study, we introduce a new airborne eddy covariance platform (Schleicher ASK-16) and demonstrate that this platform is able to accurately measure turbulent fluxes and wind vectors. Data from this platform can help to build bridges between local tower measurements and remote-sensing-based products.
Takuji Sugidachi, Masatomo Fujiwara, Kensaku Shimizu, Shin-Ya Ogino, Junko Suzuki, and Ruud J. Dirksen
Atmos. Meas. Tech., 18, 509–531, https://doi.org/10.5194/amt-18-509-2025, https://doi.org/10.5194/amt-18-509-2025, 2025
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A Peltier-based chilled-mirror hygrometer, SKYDEW, has been developed to measure tropospheric and stratospheric water vapor. Continuous accurate measurements of water vapor are essential for climate monitoring. More than 40 soundings with SKYDEW have been conducted since 2011 to evaluate the performance. The result of soundings at tropical and midlatitudes demonstrated that SKYDEW is able to measure up to an altitude of 20–25 km for daytime soundings and above 25 km for nighttime soundings.
Cort L. Zang and Megan D. Willis
Atmos. Meas. Tech., 18, 17–35, https://doi.org/10.5194/amt-18-17-2025, https://doi.org/10.5194/amt-18-17-2025, 2025
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Atmospheric chemistry of the diverse pool of reactive organic carbon (ROC; all organic species excluding methane) controls air quality, both indoors and outdoors, and influences Earth's climate. However, many important ROC compounds in the atmosphere are difficult to measure. We demonstrate measurement of diverse ROC compounds in a single instrument at a forested site. This approach can improve our ability to measure a broad range of atmospheric ROC.
Emily D. Wein, Lars E. Kalnajs, and Darin W. Toohey
Atmos. Meas. Tech., 17, 7097–7107, https://doi.org/10.5194/amt-17-7097-2024, https://doi.org/10.5194/amt-17-7097-2024, 2024
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We describe a low-cost and small research-grade spectrometer for measurements of water vapor in the boundary layer. The instrument uses small Arduino microcontrollers and inexpensive laser diodes to reduce cost while maintaining high performance comparable to more expensive instruments. Performance was assessed with intercomparisons between commercially available instruments outdoors. The design's simplicity, performance, and price point allow it to be accessible to a variety of users.
Ying Zhou, Congcong Qiao, Minqiang Zhou, Yilong Wang, Xiangjun Tian, Yinghong Wang, and Minzheng Duan
EGUsphere, https://doi.org/10.5194/egusphere-2024-3478, https://doi.org/10.5194/egusphere-2024-3478, 2024
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We developed an automated low-cost multi-altitude atmospheric sampling device for various flight platforms. During a 5-day field campaign in the Everest region, we performed 15 flights using the device mounted on a hexacopter UAV platform. 139 samples were analyzed using an Angilent GC 7890A. Vertical profiles of four greenhouse gases (CO2, CH4, N2O, and SF6) were analyzed and discussed.
Pedro Henrique Herig Coimbra, Benjamin Loubet, Olivier Laurent, Laura Bignotti, Mathis Lozano, and Michel Ramonet
Atmos. Meas. Tech., 17, 6625–6645, https://doi.org/10.5194/amt-17-6625-2024, https://doi.org/10.5194/amt-17-6625-2024, 2024
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This study presents direct flux measurements in tall towers using existing slow-response analysers and adding 3D sonic anemometers. This way, we can significantly improve greenhouse gas monitoring with little extra instrumental effort. Slow-response analysers may be used here as the relevant frequency ranges depend on measuring height. Tall towers offer a large footprint, amplifying spatial coverage. The presented concept is a valuable bridge between atmospheric and ecosystem communities.
Bo Fang, Nana Wei, Weixiong Zhao, Nana Yang, Hao Zhou, Heng Zhang, Jiarong Li, Weijun Zhang, Yanyu Lu, Zhu Zhu, and Yue Liu
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-184, https://doi.org/10.5194/amt-2024-184, 2024
Revised manuscript accepted for AMT
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A portable LP-FRS instrument with dimensions of 130 cm × 40 cm × 35 cm was developed. A specific pump-probe MPC was designed to offer a high overlapping factor of 75.4 %. The precision and uncertainty of the LP-FRS instrument for measuring kOH' were 1.0 s-1 (1σ, 300 s) and within 2 s-1, respectively. The developed portable LP-FRS instrument expands the measurement capabilities for atmospheric total OH reactivity and will be employed in more field observations.
Kristen Okorn and Laura T. Iraci
Atmos. Meas. Tech., 17, 6425–6457, https://doi.org/10.5194/amt-17-6425-2024, https://doi.org/10.5194/amt-17-6425-2024, 2024
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We reviewed 60 sensor networks and 17 related efforts (sensor review papers and data accessibility projects) to better understand the landscape of stationary low-cost gas-phase sensor networks deployed in outdoor environments worldwide. Gaps in monitoring efforts include the availability of gas-phase measurements compared to particulate matter (PM) and geographic coverage gaps (the Global South, rural areas). We conclude with a summary of cross-network unification and quality control efforts.
Henning Finkenzeller, Jyri Mikkilä, Cecilia Righi, Paxton Juuti, Mikko Sipilä, Matti Rissanen, Douglas Worsnop, Aleksei Shcherbinin, Nina Sarnela, and Juha Kangasluoma
Atmos. Meas. Tech., 17, 5989–6001, https://doi.org/10.5194/amt-17-5989-2024, https://doi.org/10.5194/amt-17-5989-2024, 2024
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Chemical ionisation mass spectrometry is used in the atmospheric sciences to measure trace gas concentrations. Neutral gases require charging in inlets before the mass-to-charge ratio of the resulting ions can be analysed. This study uses multiphysics modelling to investigate how the MION2 and Eisele type inlets work and shows the effect of tuning parameters and their current limitations. The findings are helpful for inlet users and are expected to aid in developing improved inlets.
Steven A. Bailey, Reem A. Hannun, Andrew K. Swanson, and Thomas F. Hanisco
Atmos. Meas. Tech., 17, 5903–5910, https://doi.org/10.5194/amt-17-5903-2024, https://doi.org/10.5194/amt-17-5903-2024, 2024
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We have developed a portable, optically based instrument that measures NO2. It consumes less than 6 W of power, so it can easily run off a small battery. This instrument has made both balloon and UAV flights. NO2 measurement results compare favorably with other known NO2 instruments. We find this instrument to be stable with repeatable results compared with calibration sources. Material cost to build a single instrument is around USD 4000. This could be lowered with economies of scale.
Jinghui Lian, Olivier Laurent, Mali Chariot, Luc Lienhardt, Michel Ramonet, Hervé Utard, Thomas Lauvaux, François-Marie Bréon, Grégoire Broquet, Karina Cucchi, Laurent Millair, and Philippe Ciais
Atmos. Meas. Tech., 17, 5821–5839, https://doi.org/10.5194/amt-17-5821-2024, https://doi.org/10.5194/amt-17-5821-2024, 2024
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We have designed and deployed a mid-cost medium-precision CO2 sensor monitoring network in Paris since July 2020. The data are automatically calibrated by a newly implemented data processing system. The accuracies of the mid-cost instruments vary from 1.0 to 2.4 ppm for hourly afternoon measurements. Our model–data analyses highlight prospects for integrating mid-cost instrument data with high-precision measurements to improve fine-scale CO2 emission quantification in urban areas.
Abdullah Bolek, Martin Heimann, and Mathias Göckede
Atmos. Meas. Tech., 17, 5619–5636, https://doi.org/10.5194/amt-17-5619-2024, https://doi.org/10.5194/amt-17-5619-2024, 2024
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This study describes the development of a new UAV platform to measure atmospheric greenhouse gas (GHG) mole fractions, 2D wind speed, air temperature, humidity, and pressure. Understanding GHG flux processes and controls across various ecosystems is essential for estimating the current and future state of climate change. It was shown that using the UAV platform for such measurements is beneficial for improving our understanding of GHG processes over complex landscapes.
Hendrik Fuchs, Aaron Stainsby, Florian Berg, René Dubus, Michelle Färber, Andreas Hofzumahaus, Frank Holland, Kelvin H. Bates, Steven S. Brown, Matthew M. Coggon, Glenn S. Diskin, Georgios I. Gkatzelis, Christopher M. Jernigan, Jeff Peischl, Michael A. Robinson, Andrew W. Rollins, Nell B. Schafer, Rebecca H. Schwantes, Chelsea E. Stockwell, Patrick R. Veres, Carsten Warneke, Eleanor M. Waxman, Lu Xu, Kristen Zuraski, Andreas Wahner, and Anna Novelli
EGUsphere, https://doi.org/10.5194/egusphere-2024-2752, https://doi.org/10.5194/egusphere-2024-2752, 2024
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Significant improvements have been made to the instruments used to measure OH reactivity, which is equivalent to the sum of air pollutant concentrations. Accurate and precise measurements with a high time resolution have been achieved, allowing use on aircraft, as demonstrated during flights in the USA.
Jonathan F. Dooley, Kenneth Minschwaner, Manvendra K. Dubey, Sahar H. El Abbadi, Evan D. Sherwin, Aaron G. Meyer, Emily Follansbee, and James E. Lee
Atmos. Meas. Tech., 17, 5091–5111, https://doi.org/10.5194/amt-17-5091-2024, https://doi.org/10.5194/amt-17-5091-2024, 2024
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Methane is a powerful greenhouse gas originating from both natural and human activities. We describe a new uncrewed aerial system (UAS) designed to measure methane emission rates over a wide range of scales. This system has been used for direct quantification of point sources and distributed emitters over scales of up to 1 km. The system uses simultaneous measurements of methane and ethane to distinguish between different kinds of natural and human-related emission sources.
Brice Barret, Patrice Medina, Natalie Brett, Roman Pohorsky, Kathy Law, Slimane Bekki, Gilberto J. Fochesatto, Julia Schmale, Steve Arnold, Andrea Baccarini, Mauricio Busetto, Meeta Cesler-Maloney, Barbara D'Anna, Stefano Decesari, Jingqiu Mao, Gianluca Pappaccogli, Joel Savarino, Federico Scoto, and William R. Simpson
EGUsphere, https://doi.org/10.5194/egusphere-2024-2421, https://doi.org/10.5194/egusphere-2024-2421, 2024
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The Fairbanks area experiences severe pollution episodes in winter because of enhanced emissions of pollutants trapped near the surface by strong temperature inversions. Low-cost sensors were deployed onboard a car and a tethered balloon to measure the concentrations of gaseous pollutants (CO, O3, NOx) in Fairbanks during the winter of 2022. Data calibration with reference measurements and machine learning methods enabled to document pollution at the surface and power plant plumes aloft.
John Ericksen, Tobias P. Fischer, G. Matthew Fricke, Scott Nowicki, Nemesio M. Pérez, Pedro Hernández Pérez, Eleazar Padrón González, and Melanie E. Moses
Atmos. Meas. Tech., 17, 4725–4736, https://doi.org/10.5194/amt-17-4725-2024, https://doi.org/10.5194/amt-17-4725-2024, 2024
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Volcanic eruptions emit significant quantities of carbon dioxide (CO2) to the atmosphere. We present a new method for directly determining the CO2 emission from a volcanic eruption on the island of La Palma, Spain, using an unpiloted aerial vehicle (UAV). We also collected samples of the emitted CO2 and analyzed their isotopic composition. Together with the emission rate the isotopic data provide valuable information on the state of volcanic activity and the potential evolution of the eruption.
Han Mei, Peng Wei, Meisam Ahmadi Ghadikolaei, Nirmal Kumar Gali, Ya Wang, and Zhi Ning
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-130, https://doi.org/10.5194/amt-2024-130, 2024
Revised manuscript accepted for AMT
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Long-term field testing across diverse climatic environments is conducted to identify the optimized calibration conditions for NO2, NO, CO, and O3 electrochemical sensors. The results uncovered three factors that influence calibration performance: calibration period, concentration range, and time averaging. We developed a comprehensive framework for the best sensor calibration practices, which serves as a valuable reference for calibrating various sensor types used in air quality monitoring.
László Haszpra
Atmos. Meas. Tech., 17, 4629–4647, https://doi.org/10.5194/amt-17-4629-2024, https://doi.org/10.5194/amt-17-4629-2024, 2024
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The paper evaluates a 30-year-long atmospheric CO2 data series from a mid-continental central European site, Hegyhátsál (HUN). It presents the site-specific features observed in the long-term evolution of the atmospheric CO2 concentration. Since the measurement data are widely used in atmospheric inverse models and budget calculations all around the world, the paper provides potentially valuable information for model tuning and interpretation of the model results.
Mathieu Casado, Amaelle Landais, Tim Stoltmann, Justin Chaillot, Mathieu Daëron, Fréderic Prié, Baptiste Bordet, and Samir Kassi
Atmos. Meas. Tech., 17, 4599–4612, https://doi.org/10.5194/amt-17-4599-2024, https://doi.org/10.5194/amt-17-4599-2024, 2024
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Measuring water isotopic composition in Antarctica is difficult because of the extremely cold temperature in winter. Here, we designed a new infrared spectrometer able to measure the vapour isotopic composition during more than 95 % of the year in the coldest locations of Antarctica, whereas current commercial instruments are only able to measure during the warm summer months in the interior.
Jean-Louis Bonne, Ludovic Donnat, Grégory Albora, Jérémie Burgalat, Nicolas Chauvin, Delphine Combaz, Julien Cousin, Thomas Decarpenterie, Olivier Duclaux, Nicolas Dumelié, Nicolas Galas, Catherine Juery, Florian Parent, Florent Pineau, Abel Maunoury, Olivier Ventre, Marie-France Bénassy, and Lilian Joly
Atmos. Meas. Tech., 17, 4471–4491, https://doi.org/10.5194/amt-17-4471-2024, https://doi.org/10.5194/amt-17-4471-2024, 2024
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We present a top-down approach to quantify CO2 and CH4 emissions at the scale of an industrial site, based on a mass balance model relying on atmospheric concentrations measurements from a new sensor embarked on board uncrewed aircraft vehicles (UAVs). We present a laboratory characterization of our sensor and a field validation of our quantification method, together with field application to the monitoring of two real-world offshore oil and gas platforms.
Rodrigo Rivera-Martinez, Pramod Kumar, Olivier Laurent, Gregoire Broquet, Christopher Caldow, Ford Cropley, Diego Santaren, Adil Shah, Cécile Mallet, Michel Ramonet, Leonard Rivier, Catherine Juery, Olivier Duclaux, Caroline Bouchet, Elisa Allegrini, Hervé Utard, and Philippe Ciais
Atmos. Meas. Tech., 17, 4257–4290, https://doi.org/10.5194/amt-17-4257-2024, https://doi.org/10.5194/amt-17-4257-2024, 2024
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We explore the use of metal oxide semiconductors (MOSs) as a low-cost alternative for detecting and measuring CH4 emissions from industrial facilities. MOSs were exposed to several controlled releases to test their accuracy in detecting and quantifying emissions. Two reconstruction models were compared, and emission estimates were computed using a Gaussian dispersion model. Findings show that MOSs can provide accurate emission estimates with a 25 % emission rate error and a 9.5 m location error.
Zihan Zhu, Javier González-Rocha, Yifan Ding, Isis Frausto-Vicencio, Sajjan Heerah, Akula Venkatram, Manvendra Dubey, Don Collins, and Francesca M. Hopkins
Atmos. Meas. Tech., 17, 3883–3895, https://doi.org/10.5194/amt-17-3883-2024, https://doi.org/10.5194/amt-17-3883-2024, 2024
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Increases in agriculture, oil and gas, and waste management activities have contributed to the increase in atmospheric methane levels and resultant climate warming. In this paper, we explore the use of small uncrewed aircraft systems (sUASs) and AirCore technology to detect and quantify methane emissions. Results from field experiments demonstrate that sUASs and AirCore technology can be effective for detecting and quantifying methane emissions in near real time.
Meghan Guagenti, Darielle Dexheimer, Alexandra Ulinksi, Paul Walter, James H. Flynn III, and Sascha Usenko
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-96, https://doi.org/10.5194/amt-2024-96, 2024
Revised manuscript accepted for AMT
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A robust, automatic VOC collection system was developed for vertical volatile organic compounds (VOCs) sampling associated with the 2022 DOE ARM program-led TRACER in Houston, TX. This modular sampler has been developed to measure vertical profiles of VOCs to improve near-surface characterization. This article helps fill the current lack of commercially available options for aerial VOC sampling and serves to support and encourage researchers to build and develop custom samplers.
Sebastian Diez, Stuart Lacy, Hugh Coe, Josefina Urquiza, Max Priestman, Michael Flynn, Nicholas Marsden, Nicholas A. Martin, Stefan Gillott, Thomas Bannan, and Pete M. Edwards
Atmos. Meas. Tech., 17, 3809–3827, https://doi.org/10.5194/amt-17-3809-2024, https://doi.org/10.5194/amt-17-3809-2024, 2024
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In this paper we present an overview of the QUANT project, which to our knowledge is one of the largest evaluations of commercial sensors to date. The objective was to evaluate the performance of a range of commercial products and also to nourish the different applications in which these technologies can offer relevant information.
Linda Ort, Lenard Lukas Röder, Uwe Parchatka, Rainer Königstedt, Daniel Crowley, Frank Kunz, Ralf Wittkowski, Jos Lelieveld, and Horst Fischer
Atmos. Meas. Tech., 17, 3553–3565, https://doi.org/10.5194/amt-17-3553-2024, https://doi.org/10.5194/amt-17-3553-2024, 2024
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Airborne in situ measurements are of great importance to collect valuable data to improve our knowledge of the atmosphere but also present challenges which demand specific designs. This study presents an IR spectrometer for airborne trace-gas measurements with high data efficiency and a simple, compact design. Its in-flight performance is characterized with the help of a test flight and a comparison with another spectrometer. Moreover, results from its first campaign highlight its benefits.
Roger Curcoll, Claudia Grossi, Stefan Röttger, and Arturo Vargas
Atmos. Meas. Tech., 17, 3047–3065, https://doi.org/10.5194/amt-17-3047-2024, https://doi.org/10.5194/amt-17-3047-2024, 2024
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This paper presents a new user-friendly version of the Atmospheric Radon MONitor (ARMON). The efficiency of the instrument is of 0.0057 s-1, obtained using different techniques at Spanish and German chambers. The total calculated uncertainty of the ARMON for hourly radon concentrations above 5 Bq m-3 is lower than 10 % (k = 1). Results confirm that the ARMON is suitable to measure low-level radon activity concentrations and to be used as a transfer standard to calibrate in situ radon monitors.
Josie K. Radtke, Benjamin N. Kies, Whitney A. Mottishaw, Sydney M. Zeuli, Aidan T. H. Voon, Kelly L. Koerber, Grant W. Petty, Michael P. Vermeuel, Timothy H. Bertram, Ankur R. Desai, Joseph P. Hupy, R. Bradley Pierce, Timothy J. Wagner, and Patricia A. Cleary
Atmos. Meas. Tech., 17, 2833–2847, https://doi.org/10.5194/amt-17-2833-2024, https://doi.org/10.5194/amt-17-2833-2024, 2024
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The use of uncrewed aircraft systems (UASs) to conduct a vertical profiling of ozone and meteorological variables was evaluated using comparisons between tower or ground observations and UAS-based measurements. Changes to the UAS profiler showed an improvement in performance. The profiler was used to see the impact of Chicago pollution plumes on a shoreline area near Lake Michigan.
Chen-Wei Liang and Chang-Hung Shen
Atmos. Meas. Tech., 17, 2671–2686, https://doi.org/10.5194/amt-17-2671-2024, https://doi.org/10.5194/amt-17-2671-2024, 2024
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In the present study, a UAV platform with sensing and sampling systems was developed for 3D air pollutant concentration measurements. The sensing system of this platform contains multiple microsensors and IoT technologies for obtaining the real-time 3D distributions of critical air pollutants. The sampling system contains gas sampling sets and a 1 L Tedlar bag instead of a canister for the 3D measurement of VOC concentrations in accordance with the TO-15 method of the US EPA.
Daniel Furuta, Bruce Wilson, Albert A. Presto, and Jiayu Li
Atmos. Meas. Tech., 17, 2103–2121, https://doi.org/10.5194/amt-17-2103-2024, https://doi.org/10.5194/amt-17-2103-2024, 2024
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Methane is an important driver of climate change and is challenging to inexpensively sense in low atmospheric concentrations. We developed a low-cost sensor to monitor methane and tested it in indoor and outdoor settings. Our device shows promise for monitoring low levels of methane. We characterize its limitations and suggest future research directions for further development.
Audrey J. Dang, Nathan M. Kreisberg, Tyler L. Cargill, Jhao-Hong Chen, Sydney Hornitschek, Remy Hutheesing, Jay R. Turner, and Brent J. Williams
Atmos. Meas. Tech., 17, 2067–2087, https://doi.org/10.5194/amt-17-2067-2024, https://doi.org/10.5194/amt-17-2067-2024, 2024
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The Multichannel Organics In situ enviRonmental Analyzer (MOIRA) is a new instrument for measuring speciated volatile organic compounds (VOCs) in the air and has been developed for mapping concentrations from a hybrid car. MOIRA is characterized in the lab and pilot field studies of indoor air in a single-family residence and outdoor air during a mobile deployment. Future applications include indoor, outdoor, and lab measurements to grasp the impact of VOCs on air quality, health, and climate.
Asher P. Mouat, Zelda A. Siegel, and Jennifer Kaiser
Atmos. Meas. Tech., 17, 1979–1994, https://doi.org/10.5194/amt-17-1979-2024, https://doi.org/10.5194/amt-17-1979-2024, 2024
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Three fast-measurement formaldehyde monitors were deployed at two field sites in Atlanta, GA, over 1 year. Four different zeroing methods were tested to develop an optimal field setup as well as procedures for instrument calibration. Observations agreed well after calibration but were much higher compared to the TO-11A monitoring method, which is the golden standard. Historical HCHO concentrations were compared with measurements in this work, showing a 22 % reduction in midday HCHO since 1999.
Da Yang, Margarita Reza, Roy Mauldin, Rainer Volkamer, and Suresh Dhaniyala
Atmos. Meas. Tech., 17, 1463–1474, https://doi.org/10.5194/amt-17-1463-2024, https://doi.org/10.5194/amt-17-1463-2024, 2024
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This paper evaluates the performance of an aircraft gas inlet. Here, we use computational fluid dynamics (CFD) and experiments to demonstrate the role of turbulence in determining sampling performance of a gas inlet and identify ideal conditions for inlet operation to minimize gas loss. Experiments conducted in a high-speed wind tunnel under near-aircraft speeds validated numerical results. We believe that the results obtained from this work will greatly inform future gas inlet studies.
Reena Macagga, Michael Asante, Geoffroy Sossa, Danica Antonijević, Maren Dubbert, and Mathias Hoffmann
Atmos. Meas. Tech., 17, 1317–1332, https://doi.org/10.5194/amt-17-1317-2024, https://doi.org/10.5194/amt-17-1317-2024, 2024
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Using only low-cost microcontrollers and sensors, we constructed a measurement device to accurately and precisely obtain atmospheric carbon dioxide and water fluxes. The device was tested against known concentration increases and high-cost, commercial sensors during a laboratory and field experiment. We additionally tested the device over a longer period in a field study in Ghana during which the net ecosystem carbon balance and water use efficiency of maize cultivation were studied.
Matthew M. Coggon, Chelsea E. Stockwell, Megan S. Claflin, Eva Y. Pfannerstill, Lu Xu, Jessica B. Gilman, Julia Marcantonio, Cong Cao, Kelvin Bates, Georgios I. Gkatzelis, Aaron Lamplugh, Erin F. Katz, Caleb Arata, Eric C. Apel, Rebecca S. Hornbrook, Felix Piel, Francesca Majluf, Donald R. Blake, Armin Wisthaler, Manjula Canagaratna, Brian M. Lerner, Allen H. Goldstein, John E. Mak, and Carsten Warneke
Atmos. Meas. Tech., 17, 801–825, https://doi.org/10.5194/amt-17-801-2024, https://doi.org/10.5194/amt-17-801-2024, 2024
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Mass spectrometry is a tool commonly used to measure air pollutants. This study evaluates measurement artifacts produced in the proton-transfer-reaction mass spectrometer. We provide methods to correct these biases and better measure compounds that degrade air quality.
Tianran Han, Conghui Xie, Yayong Liu, Yanrong Yang, Yuheng Zhang, Yufei Huang, Xiangyu Gao, Xiaohua Zhang, Fangmin Bao, and Shao-Meng Li
Atmos. Meas. Tech., 17, 677–691, https://doi.org/10.5194/amt-17-677-2024, https://doi.org/10.5194/amt-17-677-2024, 2024
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This study reported an integrated UAV measurement platform for GHG monitoring and its application for emission quantification from a coking plant. The key element of this system is a newly designed air sampler, consisting of a 150 m long tube with remote-controlled time stamping. When comparing the top-down results to those derived from the bottom-up inventory method, the present findings indicate that the use of IPCC emission factors for emission calculations can lead to overestimation.
Yuening Li, Faqiang Zhan, Yushan Su, Ying Duan Lei, Chubashini Shunthirasingham, Zilin Zhou, Jonathan P. D. Abbatt, Hayley Hung, and Frank Wania
Atmos. Meas. Tech., 17, 715–729, https://doi.org/10.5194/amt-17-715-2024, https://doi.org/10.5194/amt-17-715-2024, 2024
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A simple device for sampling gases from the atmosphere without the help of pumps was calibrated for an important group of hazardous air pollutants called polycyclic aromatic compounds (PACs). While the sampler appeared to perform well when used for relatively short periods of up to several months, some PACs were lost from the sampler during longer deployments. Sampling rates that can be used to quantitatively interpret the quantities of PACs taken up in the device have been derived.
Jiaxin Li, Kunpeng Zang, Yi Lin, Yuanyuan Chen, Shuo Liu, Shanshan Qiu, Kai Jiang, Xuemei Qing, Haoyu Xiong, Haixiang Hong, Shuangxi Fang, Honghui Xu, and Yujun Jiang
Atmos. Meas. Tech., 16, 4757–4768, https://doi.org/10.5194/amt-16-4757-2023, https://doi.org/10.5194/amt-16-4757-2023, 2023
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Based on observed data of CO2 and CH4 and meteorological parameters over the Yellow Sea in November 2012 and June 2013, a data process and quality control method was optimized and established to filter the data influenced by multiple factors. Spatial and seasonal variations in CO2 and CH4 mixing ratios were mainly controlled by the East Asian Monsoon, while the influence of air–sea exchange was slight.
Zaneta Hamryszczak, Antonia Hartmann, Dirk Dienhart, Sascha Hafermann, Bettina Brendel, Rainer Königstedt, Uwe Parchatka, Jos Lelieveld, and Horst Fischer
Atmos. Meas. Tech., 16, 4741–4756, https://doi.org/10.5194/amt-16-4741-2023, https://doi.org/10.5194/amt-16-4741-2023, 2023
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Hydroperoxide measurements improve the understanding of atmospheric oxidation processes. We introduce an instrumental setup for airborne measurements. The aim of the work is the characterization of the measurement method with emphasis on interferences impacting instrumental uncertainty. Technical and physical challenges do not critically impact the instrumental performance. The instrument resolves dynamic processes, such as convective transport, as shown based on the CAFE-Brazil campaign.
James F. Hurley, Alejandra Caceres, Deborah F. McGlynn, Mary E. Tovillo, Suzanne Pinar, Roger Schürch, Ksenia Onufrieva, and Gabriel Isaacman-VanWertz
Atmos. Meas. Tech., 16, 4681–4692, https://doi.org/10.5194/amt-16-4681-2023, https://doi.org/10.5194/amt-16-4681-2023, 2023
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Volatile organic compounds (VOCs) have a wide range of sources and impacts on environments and human health that make them spatially, temporally, and chemically varied. Current methods lack the ability to collect samples in ways that provide spatial and chemical resolution without complex, costly instrumentation. We describe and validate a low-cost, portable VOC sampler and demonstrate its utility in collecting distributed coordinated samples.
Simone Brunamonti, Manuel Graf, Tobias Bühlmann, Céline Pascale, Ivan Ilak, Lukas Emmenegger, and Béla Tuzson
Atmos. Meas. Tech., 16, 4391–4407, https://doi.org/10.5194/amt-16-4391-2023, https://doi.org/10.5194/amt-16-4391-2023, 2023
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The abundance of water vapor (H2O) in the upper atmosphere has a significant impact on the rate of global warming. We developed a new lightweight spectrometer (ALBATROSS) for H2O measurements aboard meteorological balloons. Here, we assess the accuracy and precision of ALBATROSS using metrology-grade reference gases. The results demonstrate the exceptional potential of mid-infrared laser absorption spectroscopy as a new reference method for in situ measurements of H2O in the upper atmosphere.
Roubina Papaconstantinou, Marios Demosthenous, Spyros Bezantakos, Neoclis Hadjigeorgiou, Marinos Costi, Melina Stylianou, Elli Symeou, Chrysanthos Savvides, and George Biskos
Atmos. Meas. Tech., 16, 3313–3329, https://doi.org/10.5194/amt-16-3313-2023, https://doi.org/10.5194/amt-16-3313-2023, 2023
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In this paper, we investigate the performance of low-cost electrochemical gas sensors. We carried out yearlong measurements at a traffic air quality monitoring station, where the low-cost sensors were collocated with reference instruments and exposed to highly variable environmental conditions with extremely high temperatures and low relative humidity (RH). Sensors provide measurements that exhibit increasing errors and decreasing correlations as temperature increases and RH decreases.
Jianghanyang Li, Bianca C. Baier, Fred Moore, Tim Newberger, Sonja Wolter, Jack Higgs, Geoff Dutton, Eric Hintsa, Bradley Hall, and Colm Sweeney
Atmos. Meas. Tech., 16, 2851–2863, https://doi.org/10.5194/amt-16-2851-2023, https://doi.org/10.5194/amt-16-2851-2023, 2023
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Monitoring a suite of trace gases in the stratosphere will help us better understand the stratospheric circulation and its impact on the earth's radiation balance. However, such measurements are rare and usually expensive. We developed an instrument that can measure stratospheric trace gases using a low-cost sampling platform (AirCore). The results showed expected agreement with aircraft measurements, demonstrating this technique provides a low-cost and robust way to observe the stratosphere.
Tara I. Yacovitch, Christoph Dyroff, Joseph R. Roscioli, Conner Daube, J. Barry McManus, and Scott C. Herndon
Atmos. Meas. Tech., 16, 1915–1921, https://doi.org/10.5194/amt-16-1915-2023, https://doi.org/10.5194/amt-16-1915-2023, 2023
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Ethylene oxide is a toxic, carcinogenic compound used in the medical and bulk sterilization industry. Here we describe a precise and fast laser-based ethylene oxide monitor. We report months-long concentrations at a Massachusetts site, and we show how they suggest a potential emission source 35 km away. This source, and another, is confirmed by driving the instrument downwind of the sites, where concentrations were tens to tens of thousands of times greater than background levels.
Tatsumi Nakano and Takashi Morofuji
Atmos. Meas. Tech., 16, 1583–1595, https://doi.org/10.5194/amt-16-1583-2023, https://doi.org/10.5194/amt-16-1583-2023, 2023
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We have developed a system that can automatically measure the pump efficiency of the ECC-type ozonesonde. Operational measurement for 13 years by this system revealed that the efficiency fluctuates in each and slightly increases over time. Those can affect the estimation of total ozone amount by up to 4 %. This result indicates that it is necessary to understand the tendency of the pump correction factor of each ozonesonde in order to detect the actual atmospheric change with high accuracy.
Benjamin Birner, Eric Morgan, and Ralph F. Keeling
Atmos. Meas. Tech., 16, 1551–1561, https://doi.org/10.5194/amt-16-1551-2023, https://doi.org/10.5194/amt-16-1551-2023, 2023
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Atmospheric variations of helium (He) and CO2 are strongly linked due to the co-release of both gases from natural-gas burning. This implies that atmospheric He measurements may be a potentially powerful tool for verifying reported anthropogenic natural-gas usage. Here, we present the development and initial results of a novel measurement system of atmospheric He that paves the way for establishing a global monitoring network in the future.
John W. Halfacre, Jordan Stewart, Scott C. Herndon, Joseph R. Roscioli, Christoph Dyroff, Tara I. Yacovitch, Michael Flynn, Stephen J. Andrews, Steven S. Brown, Patrick R. Veres, and Pete M. Edwards
Atmos. Meas. Tech., 16, 1407–1429, https://doi.org/10.5194/amt-16-1407-2023, https://doi.org/10.5194/amt-16-1407-2023, 2023
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This study details a new sampling method for the optical detection of hydrogen chloride (HCl). HCl is an important atmospheric reservoir for chlorine atoms, which can affect nitrogen oxide cycling and the lifetimes of volatile organic compounds and ozone. However, HCl has a high affinity for interacting with surfaces, thereby preventing fast, quantitative measurements. The sampling technique in this study minimizes these surface interactions and provides a high-quality measurement of HCl.
Henning Finkenzeller, Denis Pöhler, Martin Horbanski, Johannes Lampel, and Ulrich Platt
Atmos. Meas. Tech., 16, 1343–1356, https://doi.org/10.5194/amt-16-1343-2023, https://doi.org/10.5194/amt-16-1343-2023, 2023
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Optical resonators enhance the light path in compact instruments, thereby improving their sensitivity. Determining the established path length in the instrument is a prerequisite for the accurate determination of trace gas concentrations but can be a significant complication in the use of such resonators. Here we show two calibration techniques which are relatively simple and free of consumables but still provide accurate calibrations. This facilitates the use of optical resonators.
Andrew W. Seidl, Harald Sodemann, and Hans Christian Steen-Larsen
Atmos. Meas. Tech., 16, 769–790, https://doi.org/10.5194/amt-16-769-2023, https://doi.org/10.5194/amt-16-769-2023, 2023
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It is challenging to make field measurements of stable water isotopes in the Arctic. To this end, we present a modular stable-water-isotope analyzer profiling system. The system operated for a 2-week field campaign on Svalbard during the Arctic winter. We evaluate the system’s performance and analyze any potential impact that the field conditions might have had on the isotopic measurements and the system's ability to resolve isotope gradients in the lowermost layer of the atmosphere.
Daan Swart, Jun Zhang, Shelley van der Graaf, Susanna Rutledge-Jonker, Arjan Hensen, Stijn Berkhout, Pascal Wintjen, René van der Hoff, Marty Haaima, Arnoud Frumau, Pim van den Bulk, Ruben Schulte, Margreet van Zanten, and Thomas van Goethem
Atmos. Meas. Tech., 16, 529–546, https://doi.org/10.5194/amt-16-529-2023, https://doi.org/10.5194/amt-16-529-2023, 2023
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During a 5-week comparison campaign, we tested two set-ups to measure half hourly ammonia fluxes. The eddy covariance and flux gradient systems showed very similar results when the upwind terrain was both homogeneous and free of obstacles. We discuss the technical performance and practical limitations of both systems. Measurements from these instruments can facilitate the study of processes behind ammonia deposition, an important contributor to eutrophication and acidificationin natural areas.
Suding Yang, Xin Li, Limin Zeng, Xuena Yu, Ying Liu, Sihua Lu, Xiaofeng Huang, Dongmei Zhang, Haibin Xu, Shuchen Lin, Hefan Liu, Miao Feng, Danlin Song, Qinwen Tan, Jinhui Cui, Lifan Wang, Ying Chen, Wenjie Wang, Haijiong Sun, Mengdi Song, Liuwei Kong, Yi Liu, Linhui Wei, Xianwu Zhu, and Yuanhang Zhang
Atmos. Meas. Tech., 16, 501–512, https://doi.org/10.5194/amt-16-501-2023, https://doi.org/10.5194/amt-16-501-2023, 2023
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Vertical observation of volatile organic compounds (VOCs) is essential to study the spatial distribution and evolution patterns of VOCs in the planetary boundary layer (PBL). This paper describes multi-channel whole-air sampling equipment onboard an unmanned aerial vehicle (UAV) for near-continuous VOC vertical observation. Vertical profiles of VOCs and trace gases during the evolution of the PBL in south-western China have been successfully obtained by deploying the newly developed UAV system.
Cited articles
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Short summary
AirCore samplers are increasingly deployed to weather balloons to collect continuous atmospheric samples. We introduce a technique that can be used in situ to evaluate different data processing methods that are required to derive vertical trace gas profiles from AirCore measurements after sample recovery. Results from two test flights with a specific AirCore configuration provide evidence for systematic deviations in altitude attribution for the upper levels, which can be empirically corrected.
AirCore samplers are increasingly deployed to weather balloons to collect continuous atmospheric...
