Articles | Volume 17, issue 15
https://doi.org/10.5194/amt-17-4599-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-17-4599-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
08 Aug 2024
Research article |
| 08 Aug 2024
| 08 Aug 2024
Reliable water vapour isotopic composition measurements at low humidity using frequency-stabilised cavity ring-down spectroscopy
Laboratoire des Sciences du Climat et de l'Environnement, CEA–CNRS–UVSQ–Paris-Saclay–IPSL, Gif-sur-Yvette, France
Amaelle Landais
Laboratoire des Sciences du Climat et de l'Environnement, CEA–CNRS–UVSQ–Paris-Saclay–IPSL, Gif-sur-Yvette, France
Tim Stoltmann
LiPHY, Laboratoire Interdisciplinaire de Physique, Université Grenoble Alpes/CNRS, Grenoble, France
Justin Chaillot
Laboratoire des Sciences du Climat et de l'Environnement, CEA–CNRS–UVSQ–Paris-Saclay–IPSL, Gif-sur-Yvette, France
Mathieu Daëron
Laboratoire des Sciences du Climat et de l'Environnement, CEA–CNRS–UVSQ–Paris-Saclay–IPSL, Gif-sur-Yvette, France
Fréderic Prié
Laboratoire des Sciences du Climat et de l'Environnement, CEA–CNRS–UVSQ–Paris-Saclay–IPSL, Gif-sur-Yvette, France
Baptiste Bordet
LiPHY, Laboratoire Interdisciplinaire de Physique, Université Grenoble Alpes/CNRS, Grenoble, France
Samir Kassi
LiPHY, Laboratoire Interdisciplinaire de Physique, Université Grenoble Alpes/CNRS, Grenoble, France
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Niels Dutrievoz, Cécile Agosta, Cécile Davrinche, Amaëlle Landais, Sébastien Nguyen, Étienne Vignon, Inès Ollivier, Christophe Leroy-Dos Santos, Elise Fourré, Mathieu Casado, Jonathan Wille, Vincent Favier, Bénédicte Minster, and Frédéric Prié
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This preprint is open for discussion and under review for The Cryosphere (TC).
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In December 2018, an atmospheric river event from the Atlantic reached Dome C, East Antarctica, causing a +18 °C warming, tripled water vapour, and a strong isotopic anomaly in water vapour (+ 17 ‰ for δ18O) at the surface. During the peak of the event, we found 70 % of the water vapour came from local snow sublimation, and 30 % from the atmospheric river itself, highlighting both large-scale advection and local interactions at the surface.
Titouan Tcheng, Elise Fourré, Christophe Leroy-Dos-Santos, Frédéric Parrenin, Emmanuel Le Meur, Frédéric Prié, Olivier Jossoud, Roxanne Jacob, Bénédicte Minster, Olivier Magand, Cécile Agosta, Niels Dutrievoz, Vincent Favier, Léa Baubant, Coralie Lassalle-Bernard, Mathieu Casado, Martin Werner, Alexandre Cauquoin, Laurent Arnaud, Bruno Jourdain, Ghislain Picard, Marie Bouchet, and Amaëlle Landais
EGUsphere, https://doi.org/10.5194/egusphere-2025-2863, https://doi.org/10.5194/egusphere-2025-2863, 2025
This preprint is open for discussion and under review for The Cryosphere (TC).
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Studying Antarctic ice cores is crucial to assess past climate changes, as they hold historical climate data. This study examines multiple ice cores from three sites in coastal Adélie Land to see if combining cores improves data interpretability. It does at two sites, but at a third, wind-driven snow layer mixing limited benefits. We show that using multiple ice cores from one location can better uncover climate history, especially in areas with less wind disturbance.
Clémence Paul, Clément Piel, Joana Sauze, Olivier Jossoud, Arnaud Dapoigny, Daniele Romanini, Frédéric Prié, Sébastien Devidal, Roxanne Jacob, Alexandru Milcu, and Amaëlle Landais
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Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-35, https://doi.org/10.5194/essd-2025-35, 2025
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EGUsphere, https://doi.org/10.5194/egusphere-2024-3335, https://doi.org/10.5194/egusphere-2024-3335, 2025
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Our research compares three CFA-CRDS systems from Venice, Paris, and Grenoble for measuring water isotopes in ice cores, crucial for reconstructing past climate. We quantify each system’s mixing and measurement noise effects, which impact the achievable resolution of isotope continuous records. Our findings reveal specific configurations and procedures to enhance measurement accuracy, providing a framework to optimise water isotope analysis.
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The role of post-depositional processes taking place at the ice sheet's surface on the water stable isotope signal measured in polar ice cores is not fully understood. Using field observations and modelling results, we show that the original precipitation isotopic signal at Dome C, East Antarctica, is modified by post-depositional processes and provide the first quantitative estimation of their mean impact on the isotopic signal observed in the snow.
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Clément Piel, Daniele Romanini, Morgane Farradèche, Justin Chaillot, Clémence Paul, Nicolas Bienville, Thomas Lauwers, Joana Sauze, Kévin Jaulin, Frédéric Prié, and Amaëlle Landais
Atmos. Meas. Tech., 17, 6647–6658, https://doi.org/10.5194/amt-17-6647-2024, https://doi.org/10.5194/amt-17-6647-2024, 2024
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Short summary
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Giuliano Dreossi, Mauro Masiol, Barbara Stenni, Daniele Zannoni, Claudio Scarchilli, Virginia Ciardini, Mathieu Casado, Amaëlle Landais, Martin Werner, Alexandre Cauquoin, Giampietro Casasanta, Massimo Del Guasta, Vittoria Posocco, and Carlo Barbante
The Cryosphere, 18, 3911–3931, https://doi.org/10.5194/tc-18-3911-2024, https://doi.org/10.5194/tc-18-3911-2024, 2024
Short summary
Short summary
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Romilly Harris Stuart, Amaëlle Landais, Laurent Arnaud, Christo Buizert, Emilie Capron, Marie Dumont, Quentin Libois, Robert Mulvaney, Anaïs Orsi, Ghislain Picard, Frédéric Prié, Jeffrey Severinghaus, Barbara Stenni, and Patricia Martinerie
The Cryosphere, 18, 3741–3763, https://doi.org/10.5194/tc-18-3741-2024, https://doi.org/10.5194/tc-18-3741-2024, 2024
Short summary
Short summary
Ice core δO2/N2 records are useful dating tools due to their local insolation pacing. A precise understanding of the physical mechanism driving this relationship, however, remain ambiguous. By compiling data from 15 polar sites, we find a strong dependence of mean δO2/N2 on accumulation rate and temperature in addition to the well-documented insolation dependence. Snowpack modelling is used to investigate which physical properties drive the mechanistic dependence on these local parameters.
Amaelle Landais, Cécile Agosta, Françoise Vimeux, Olivier Magand, Cyrielle Solis, Alexandre Cauquoin, Niels Dutrievoz, Camille Risi, Christophe Leroy-Dos Santos, Elise Fourré, Olivier Cattani, Olivier Jossoud, Bénédicte Minster, Frédéric Prié, Mathieu Casado, Aurélien Dommergue, Yann Bertrand, and Martin Werner
Atmos. Chem. Phys., 24, 4611–4634, https://doi.org/10.5194/acp-24-4611-2024, https://doi.org/10.5194/acp-24-4611-2024, 2024
Short summary
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We have monitored water vapor isotopes since January 2020 on Amsterdam Island in the Indian Ocean. We show 11 periods associated with abrupt negative excursions of water vapor δ18Ο. Six of these events show a decrease in gaseous elemental mercury, suggesting subsidence of air from a higher altitude. Accurately representing the water isotopic signal during these cold fronts is a real challenge for the atmospheric components of Earth system models equipped with water isotopes.
Andrea Spolaor, Federico Scoto, Catherine Larose, Elena Barbaro, Francois Burgay, Mats P. Bjorkman, David Cappelletti, Federico Dallo, Fabrizio de Blasi, Dmitry Divine, Giuliano Dreossi, Jacopo Gabrieli, Elisabeth Isaksson, Jack Kohler, Tonu Martma, Louise S. Schmidt, Thomas V. Schuler, Barbara Stenni, Clara Turetta, Bartłomiej Luks, Mathieu Casado, and Jean-Charles Gallet
The Cryosphere, 18, 307–320, https://doi.org/10.5194/tc-18-307-2024, https://doi.org/10.5194/tc-18-307-2024, 2024
Short summary
Short summary
We evaluate the impact of the increased snowmelt on the preservation of the oxygen isotope (δ18O) signal in firn records recovered from the top of the Holtedahlfonna ice field located in the Svalbard archipelago. Thanks to a multidisciplinary approach we demonstrate a progressive deterioration of the isotope signal in the firn core. We link the degradation of the δ18O signal to the increased occurrence and intensity of melt events associated with the rapid warming occurring in the archipelago.
Christophe Leroy-Dos Santos, Elise Fourré, Cécile Agosta, Mathieu Casado, Alexandre Cauquoin, Martin Werner, Benedicte Minster, Frédéric Prié, Olivier Jossoud, Leila Petit, and Amaëlle Landais
The Cryosphere, 17, 5241–5254, https://doi.org/10.5194/tc-17-5241-2023, https://doi.org/10.5194/tc-17-5241-2023, 2023
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Short summary
In the face of global warming, understanding the changing water cycle and temperatures in polar regions is crucial. These factors directly impact the balance of ice sheets in the Arctic and Antarctic. By studying the composition of water vapor, we gain insights into climate variations. Our 2-year study at Dumont d’Urville station, Adélie Land, offers valuable data to refine models. Additionally, we demonstrate how modeling aids in interpreting signals from ice core samples in the region.
Marie Bouchet, Amaëlle Landais, Antoine Grisart, Frédéric Parrenin, Frédéric Prié, Roxanne Jacob, Elise Fourré, Emilie Capron, Dominique Raynaud, Vladimir Ya Lipenkov, Marie-France Loutre, Thomas Extier, Anders Svensson, Etienne Legrain, Patricia Martinerie, Markus Leuenberger, Wei Jiang, Florian Ritterbusch, Zheng-Tian Lu, and Guo-Min Yang
Clim. Past, 19, 2257–2286, https://doi.org/10.5194/cp-19-2257-2023, https://doi.org/10.5194/cp-19-2257-2023, 2023
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A new federative chronology for five deep polar ice cores retrieves 800 000 years of past climate variations with improved accuracy. Precise ice core timescales are key to studying the mechanisms linking changes in the Earth’s orbit to the diverse climatic responses (temperature and atmospheric greenhouse gas concentrations). To construct the chronology, new measurements from the oldest continuous ice core as well as glaciological modeling estimates were combined in a statistical model.
Aymeric P. M. Servettaz, Anaïs J. Orsi, Mark A. J. Curran, Andrew D. Moy, Amaelle Landais, Joseph R. McConnell, Trevor J. Popp, Emmanuel Le Meur, Xavier Faïn, and Jérôme Chappellaz
Clim. Past, 19, 1125–1152, https://doi.org/10.5194/cp-19-1125-2023, https://doi.org/10.5194/cp-19-1125-2023, 2023
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The temperature of the past 2000 years is still poorly known in vast parts of the East Antarctic plateau. In this study, we present temperature reconstructions based on water and gas stable isotopes from the Aurora Basin North ice core. Spatial and temporal significance of each proxy differs, and we can identify some cold periods in the snow temperature up to 2°C cooler in the 1000–1400 CE period, which could not be determined with water isotopes only.
Robert Mulvaney, Eric W. Wolff, Mackenzie M. Grieman, Helene H. Hoffmann, Jack D. Humby, Christoph Nehrbass-Ahles, Rachael H. Rhodes, Isobel F. Rowell, Frédéric Parrenin, Loïc Schmidely, Hubertus Fischer, Thomas F. Stocker, Marcus Christl, Raimund Muscheler, Amaelle Landais, and Frédéric Prié
Clim. Past, 19, 851–864, https://doi.org/10.5194/cp-19-851-2023, https://doi.org/10.5194/cp-19-851-2023, 2023
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We present an age scale for a new ice core drilled at Skytrain Ice Rise, an ice rise facing the Ronne Ice Shelf in Antarctica. Various measurements in the ice and air phases are used to match the ice core to other Antarctic cores that have already been dated, and a new age scale is constructed. The 651 m ice core includes ice that is confidently dated to 117 000–126 000 years ago, in the last interglacial. Older ice is found deeper down, but there are flow disturbances in the deeper ice.
Clémence Paul, Clément Piel, Joana Sauze, Nicolas Pasquier, Frédéric Prié, Sébastien Devidal, Roxanne Jacob, Arnaud Dapoigny, Olivier Jossoud, Alexandru Milcu, and Amaëlle Landais
Biogeosciences, 20, 1047–1062, https://doi.org/10.5194/bg-20-1047-2023, https://doi.org/10.5194/bg-20-1047-2023, 2023
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To improve the interpretation of the δ18Oatm and Δ17O of O2 in air bubbles in ice cores, we need to better quantify the oxygen fractionation coefficients associated with biological processes. We performed a simplified analogue of the terrestrial biosphere in a closed chamber. We found a respiration fractionation in agreement with the previous estimates at the microorganism scale, and a terrestrial photosynthetic fractionation was found. This has an impact on the estimation of the Dole effect.
Antoine Grisart, Mathieu Casado, Vasileios Gkinis, Bo Vinther, Philippe Naveau, Mathieu Vrac, Thomas Laepple, Bénédicte Minster, Frederic Prié, Barbara Stenni, Elise Fourré, Hans Christian Steen-Larsen, Jean Jouzel, Martin Werner, Katy Pol, Valérie Masson-Delmotte, Maria Hoerhold, Trevor Popp, and Amaelle Landais
Clim. Past, 18, 2289–2301, https://doi.org/10.5194/cp-18-2289-2022, https://doi.org/10.5194/cp-18-2289-2022, 2022
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This paper presents a compilation of high-resolution (11 cm) water isotopic records, including published and new measurements, for the last 800 000 years from the EPICA Dome C ice core, Antarctica. Using this new combined water isotopes (δ18O and δD) dataset, we study the variability and possible influence of diffusion at the multi-decadal to multi-centennial scale. We observe a stronger variability at the onset of the interglacial interval corresponding to a warm period.
Clément Outrequin, Anne Alexandre, Christine Vallet-Coulomb, Clément Piel, Sébastien Devidal, Amaelle Landais, Martine Couapel, Jean-Charles Mazur, Christophe Peugeot, Monique Pierre, Frédéric Prié, Jacques Roy, Corinne Sonzogni, and Claudia Voigt
Clim. Past, 17, 1881–1902, https://doi.org/10.5194/cp-17-1881-2021, https://doi.org/10.5194/cp-17-1881-2021, 2021
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Continental atmospheric humidity is a key climate parameter poorly captured by global climate models. Model–data comparison approaches that are applicable beyond the instrumental period are essential to progress on this issue but face a lack of quantitative relative humidity proxies. Here, we calibrate the triple oxygen isotope composition of phytoliths as a new quantitative proxy of continental relative humidity suitable for past climate reconstructions.
Christophe Leroy-Dos Santos, Mathieu Casado, Frédéric Prié, Olivier Jossoud, Erik Kerstel, Morgane Farradèche, Samir Kassi, Elise Fourré, and Amaëlle Landais
Atmos. Meas. Tech., 14, 2907–2918, https://doi.org/10.5194/amt-14-2907-2021, https://doi.org/10.5194/amt-14-2907-2021, 2021
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We developed an instrument that can generate water vapor at low humidity at a very stable level. This instrument was conceived to calibrate water vapor isotopic records obtained in very dry places such as central Antarctica. Here, we provide details on the instrument as well as results obtained for correcting water isotopic records for diurnal variability during a long field season at the Concordia station in East Antarctica.
Jinhwa Shin, Christoph Nehrbass-Ahles, Roberto Grilli, Jai Chowdhry Beeman, Frédéric Parrenin, Grégory Teste, Amaelle Landais, Loïc Schmidely, Lucas Silva, Jochen Schmitt, Bernhard Bereiter, Thomas F. Stocker, Hubertus Fischer, and Jérôme Chappellaz
Clim. Past, 16, 2203–2219, https://doi.org/10.5194/cp-16-2203-2020, https://doi.org/10.5194/cp-16-2203-2020, 2020
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We reconstruct atmospheric CO2 from the EPICA Dome C ice core during Marine Isotope Stage 6 (185–135 ka) to understand carbon mechanisms under the different boundary conditions of the climate system. The amplitude of CO2 is highly determined by the Northern Hemisphere stadial duration. Carbon dioxide maxima show different lags with respect to the corresponding abrupt CH4 jumps, the latter reflecting rapid warming in the Northern Hemisphere.
Cited articles
Akers, P. D., Kopec, B. G., Mattingly, K. S., Klein, E. S., Causey, D., and Welker, J. M.: Baffin Bay sea ice extent and synoptic moisture transport drive water vapor isotope (δ18O, δ2H, and deuterium excess) variability in coastal northwest Greenland, Atmos. Chem. Phys., 20, 13929–13955, https://doi.org/10.5194/acp-20-13929-2020, 2020.
Bagheri Dastgerdi, S., Behrens, M., Bonne, J.-L., Hörhold, M., Lohmann, G., Schlosser, E., and Werner, M.: Continuous monitoring of surface water vapour isotopic compositions at Neumayer Station III, East Antarctica, The Cryosphere, 15, 4745–4767, https://doi.org/10.5194/tc-15-4745-2021, 2021.
Berkelhammer, M., Noone, D. C., Steen-Larsen, H. C., Bailey, A., Cox, C. J., O'Neill, M. S., Schneider, D., Steffen, K., and White, J. W. C.: Surface-atmosphere decoupling limits accumulation at Summit, Greenland, Sci. Adv., 2, e1501704, https://doi.org/10.1126/sciadv.1501704, 2016.
Bonne, J.-L., Masson-Delmotte, V., Cattani, O., Delmotte, M., Risi, C., Sodemann, H., and Steen-Larsen, H. C.: The isotopic composition of water vapour and precipitation in Ivittuut, southern Greenland, Atmos. Chem. Phys., 14, 4419–4439, https://doi.org/10.5194/acp-14-4419-2014, 2014.
Bonne, J.-L., Behrens, M., Meyer, H., Kipfstuhl, S., Rabe, B., Schönicke, L., Steen-Larsen, H. C., and Werner, M.: Resolving the controls of water vapour isotopes in the Atlantic sector, Nat. Commun., 10, 1–10, 2019.
Bréant, C., Dos Santos, C. L., Agosta, C., Casado, M., Fourré, E., Goursaud, S., Masson-Delmotte, V., Favier, V., Cattani, O., and Prié, F.: Coastal water vapor isotopic composition driven by katabatic wind variability in summer at Dumont d'Urville, coastal East Antarctica, Earth Planet. Sc. Lett., 514, 37–47, 2019.
Burkart, J. and Kassi, S.: Absorption line metrology by optical feedback frequency-stabilized cavity ring-down spectroscopy, Appl. Phys. B, 119, 97–109, https://doi.org/10.1007/s00340-014-5999-3, 2015.
Burkart, J., Romanini, D., and Kassi, S.: Optical feedback stabilized laser tuned by single-sideband modulation, Opt. Lett., 38, 2062–2064, 2013.
Burkart, J., Romanini, D., and Kassi, S.: Optical feedback frequency stabilized cavity ring-down spectroscopy, Opt. Lett., 39, 4695–4698, https://doi.org/10.1364/OL.39.004695, 2014.
Burkart, J., Sala, T., Romanini, D., Marangoni, M., Campargue, A., and Kassi, S.: Communication: Saturated CO2 absorption near 1.6 µm for kilohertz-accuracy transition frequencies, J. Chem. Phys., 142, 191103, https://doi.org/10.1063/1.4921557, 2015.
Casado, M.: Water stable isotopic composition on the East Antarctic Plateau: measurements at low temperature of the vapour composition, utilisation as an atmospheric tracer and implication for paleoclimate studies, PhD Thesis, Paris Saclay, https://theses.hal.science/tel-01409702 (last access: 6 August 2024), 2016.
Casado, M.: Antarctic Stable Isotopes, in: Reference Module in Earth Systems and Environmental Sciences, online Reference Collection, Elsevier, ISBN 9780124095489, 2018.
Casado, M.: MathieuIso/Glaciotools: Glaciotools (Version v1), Zenodo [code], https://doi.org/10.5281/zenodo.13235227, 2024.
Casado, M., Landais, A., Masson-Delmotte, V., Genthon, C., Kerstel, E., Kassi, S., Arnaud, L., Picard, G., Prie, F., Cattani, O., Steen-Larsen, H.-C., Vignon, E., and Cermak, P.: Continuous measurements of isotopic composition of water vapour on the East Antarctic Plateau, Atmos. Chem. Phys., 16, 8521–8538, https://doi.org/10.5194/acp-16-8521-2016, 2016.
Casado, M., Landais, A., Picard, G., Münch, T., Laepple, T., Stenni, B., Dreossi, G., Ekaykin, A., Arnaud, L., Genthon, C., Touzeau, A., Masson-Delmotte, V., and Jouzel, J.: Archival processes of the water stable isotope signal in East Antarctic ice cores, The Cryosphere, 12, 1745–1766, https://doi.org/10.5194/tc-12-1745-2018, 2018.
Casado, M., Münch, T., and Laepple, T.: Climatic information archived in ice cores: impact of intermittency and diffusion on the recorded isotopic signal in Antarctica, Clim. Past, 16, 1581–1598, https://doi.org/10.5194/cp-16-1581-2020, 2020.
Casado, M., Landais, A., Picard, G., Arnaud, L., Dreossi, G., Stenni, B., and Prié, F.: Water isotopic signature of surface snow metamorphism in Antarctica, Geophys. Res. Lett., 48, e2021GL093382, https://doi.org/10.1029/2021GL093382, 2021.
Casado, M., Stoltmann, T., Landais, A., Jobert, N., Daëron, M., Prié, F., and Kassi, S.: High stability in near-infrared spectroscopy: part 1, adapting clock techniques to optical feedback, Appl. Phys. B, 128, 1–7, 2022.
Čermák, P., Karlovets, E. V, Mondelain, D., Kassi, S., Perevalov, V. I., and Campargue, A.: High sensitivity CRDS of CO2 in the 1.74 µm transparency window. A validation test for the spectroscopic databases, J. Quant. Spectrosc. Ra., 207, 95–103, 2018.
Chaillot, J., Dasari, S., Fleurbaey, H., Daeron, M., Savarino, J., and Kassi, S.: High-precision laser spectroscopy of H2S for simultaneous probing of multiple-sulfur isotopes, Environ. Sci. Adv., 2, 78–86, https://doi.org/10.1039/D2VA00104G, 2023.
Craig, H. and Gordon, L. I.: Deuterium and oxygen-18 variations in the ocean and the marine atmosphere, in: Stable Isotopes in Oceanographic Studies and Palaiotemperatures, edited by: Tongiorgi, E., Lab. Geol. Nucl. Pisa, Italy, 1–122, 1965.
Dansgaard, W.: Stable isotopes in precipitation, Tellus, 16, 436–468, https://doi.org/10.1111/j.2153-3490.1964.tb00181.x, 1964.
Ekaykin, A. A., Lipenkov, V. Y., Barkov, N. I., Petit, J. R., and Masson-Delmotte, V.: Spatial and temporal variability in isotope composition of recent snow in the vicinity of Vostok station, Antarctica: implications for ice-core record interpretation, Ann. Glaciol., 35, 181–186, https://doi.org/10.3189/172756402781816726, 2002.
Ellehoj, M. D., Steen-Larsen, H. C., Johnsen, S. J., and Madsen, M. B.: Ice-vapor equilibrium fractionation factor of hydrogen and oxygen isotopes: Experimental investigations and implications for stable water isotope studies, Rapid Commun. Mass Sp., 27, 2149–2158, https://doi.org/10.1002/rcm.6668, 2013.
EPICA: Eight glacial cycles from an Antarctic ice core, Nature, 429, 623–628, https://doi.org/10.1038/nature02599, 2004.
Galewsky, J., Steen-Larsen, H. C., Field, R. D., Worden, J., Risi, C., and Schneider, M.: Stable isotopes in atmospheric water vapor and applications to the hydrologic cycle, Rev. Geophys., 54, 809–865, 2016.
Genthon, C., Piard, L., Vignon, E., Madeleine, J.-B., Casado, M., and Gallée, H.: Atmospheric moisture supersaturation in the near-surface atmosphere at Dome C, Antarctic Plateau, Atmos. Chem. Phys., 17, 691–704, https://doi.org/10.5194/acp-17-691-2017, 2017.
Genthon, C., Veron, D., Vignon, E., Six, D., Dufresne, J.-L., Madeleine, J.-B., Sultan, E., and Forget, F.: 10 years of temperature and wind observation on a 45 m tower at Dome C, East Antarctic plateau, Earth Syst. Sci. Data, 13, 5731–5746, https://doi.org/10.5194/essd-13-5731-2021, 2021.
Genthon, C., Veron, D. E., Vignon, E., Madeleine, J.-B., and Piard, L.: Water vapor in cold and clean atmosphere: a 3-year data set in the boundary layer of Dome C, East Antarctic Plateau, Earth Syst. Sci. Data, 14, 1571–1580, https://doi.org/10.5194/essd-14-1571-2022, 2022.
Gotti, R., Sala, T., Prevedelli, M., Kassi, S., Marangoni, M., and Romanini, D.: Feed-forward comb-assisted coherence transfer to a widely tunable DFB diode laser, J. Chem. Phys., 149, 154201, https://doi.org/10.1063/1.5046387, 2018.
Izutsu, M., Shikama, S., and Sueta, T.: Integrated optical SSB modulator/frequency shifter, IEEE J. Quantum Elect., 17, 2225–2227, 1981.
Jobert, N., Casado, M., and Kassi, S.: High stability in near-infrared spectroscopy: part 2, optomechanical analysis of an optical contacted V-shaped cavity, Appl. Phys. B, 128, 56, https://doi.org/10.1007/s00340-022-07779-x, 2022.
Jouzel, J. and Masson-Delmotte, V.: Paleoclimates: what do we learn from deep ice cores?, WIREs Clim. Change, 1, 654–669, https://doi.org/10.1002/wcc.72, 2010.
Kassi, S., Stoltmann, T., Casado, M., Daëron, M., and Campargue, A.: Lamb dip CRDS of highly saturated transitions of water near 1.4 µm, J. Chem. Phys., 148, 54201, https://doi.org/10.1063/1.5010957, 2018.
Kurita, N., Hirasawa, N., Koga, S., Matsushita, J., and Fujiyoshi, Y.: Identification of Air Masses Responsible for Warm Events on the East Antarctic Coast, SOLA, 12, 307–313, https://doi.org/10.2151/sola.2016-060, 2016.
Laepple, T., Münch, T., Casado, M., Hoerhold, M., Landais, A., and Kipfstuhl, S.: On the similarity and apparent cycles of isotopic variations in East Antarctic snow pits, The Cryosphere, 12, 169–187, https://doi.org/10.5194/tc-12-169-2018, 2018.
Lamb, K. D., Clouser, B. W., Bolot, M., Sarkozy, L., Ebert, V., Saathoff, H., Möhler, O., and Moyer, E. J.: Laboratory measurements of
Landsberg, J., Romanini, D., and Kerstel, E.: Very high finesse optical-feedback cavity-enhanced absorption spectrometer for low concentration water vapor isotope analyses, Opt. Lett., 39, 1795–1798, https://doi.org/10.1364/OL.39.001795, 2014.
Laurent, P., Clairon, A., and Breant, C.: Frequency noise analysis of optically self-locked diode lasers, Quantum Electron. IEEE J., 25, 1131–1142, 1989.
Leroy-Dos Santos, C., Masson-Delmotte, V., Casado, M., Fourré, E., Steen-Larsen, H. C., Maturilli, M., Orsi, A., Berchet, A., Cattani, O., and Minster, B.: A 4.5 year-long record of Svalbard water vapor isotopic composition documents winter air mass origin, J. Geophys. Res.-Atmos., 125, e2020JD032681, https://doi.org/10.1029/2020JD032681, 2020.
Leroy-Dos Santos, C., Casado, M., Prié, F., Jossoud, O., Kerstel, E., Farradèche, M., Kassi, S., Fourré, E., and Landais, A.: A dedicated robust instrument for water vapor generation at low humidity for use with a laser water isotope analyzer in cold and dry polar regions, Atmos. Meas. Tech., 14, 2907–2918, https://doi.org/10.5194/amt-14-2907-2021, 2021.
Long, D. A., Bielska, K., Lisak, D., Havey, D. K., Okumura, M., Miller, C. E., and Hodges, J. T.: The air-broadened, near-infrared CO2 line shape in the spectrally isolated regime: Evidence of simultaneous Dicke narrowing and speed dependence, J. Chem. Phys., 135, 064308, https://doi.org/10.1063/1.3624527, 2011.
Lorius, C., Merlivat, L., and Hagemann, R.: Variation in the mean deuterium content of precipitations in Antarctica, J. Geophys. Res., 74, 7027–7031, https://doi.org/10.1029/JC074i028p07027, 1969.
Majoube, M.: FRACTIONATION IN O-18 BETWEEN ICE AND WATER VAPOR, J. Chim. Phys. P. C. B., 68, 625–636, 1971.
Merlivat, L. and Nief, G.: Fractionnement isotopique lors des changements d'état solide-vapeur et liquide-vapeur de l'eau à des températures inférieures à 0 °C, Tellus, 19, 122–127, https://doi.org/10.1111/j.2153-3490.1967.tb01465.x, 1967.
Morville, J., Kassi, S., Chenevier, M., and Romanini, D.: Fast, low-noise, mode-by-mode, cavity-enhanced absorption spectroscopy by diode-laser self-locking, Appl. Phys. B, 80, 1027–1038, https://doi.org/10.1007/s00340-005-1828-z, 2005.
North Greenland Ice Core Project members: High-resolution record of Northern Hemisphere climate extending into the last interglacial period, Nature, 431, 147–151, https://doi.org/10.1038/nature02805, 2004.
Risi, C., Bony, S., and Vimeux, F.: Influence of convective processes on the isotopic composition (δ18O and δD) of precipitation and water vapor in the tropics: 2. Physical interpretation of the amount effect, J. Geophys. Res.-Atmos., 113, D19306, https://doi.org/10.1029/2008JD009943, 2008.
Ritter, F., Steen-Larsen, H. C., Werner, M., Masson-Delmotte, V., Orsi, A., Behrens, M., Birnbaum, G., Freitag, J., Risi, C., and Kipfstuhl, S.: Isotopic exchange on the diurnal scale between near-surface snow and lower atmospheric water vapor at Kohnen station, East Antarctica, The Cryosphere, 10, 1647–1663, https://doi.org/10.5194/tc-10-1647-2016, 2016.
Romanini, D., Kachanov, A. A., Sadeghi, N., and Stoeckel, F.: CW cavity ring down spectroscopy, Chem. Phys. Lett., 264, 316–322, https://doi.org/10.1016/S0009-2614(96)01351-6, 1997.
Steen-Larsen, H. C., Johnsen, S. J., Masson-Delmotte, V., Stenni, B., Risi, C., Sodemann, H., Balslev-Clausen, D., Blunier, T., Dahl-Jensen, D., Ellehøj, M. D., Falourd, S., Grindsted, A., Gkinis, V., Jouzel, J., Popp, T., Sheldon, S., Simonsen, S. B., Sjolte, J., Steffensen, J. P., Sperlich, P., Sveinbjörnsdóttir, A. E., Vinther, B. M., and White, J. W. C.: Continuous monitoring of summer surface water vapor isotopic composition above the Greenland Ice Sheet, Atmos. Chem. Phys., 13, 4815–4828, https://doi.org/10.5194/acp-13-4815-2013, 2013.
Steen-Larsen, H. C., Masson-Delmotte, V., Hirabayashi, M., Winkler, R., Satow, K., Prié, F., Bayou, N., Brun, E., Cuffey, K. M., Dahl-Jensen, D., Dumont, M., Guillevic, M., Kipfstuhl, S., Landais, A., Popp, T., Risi, C., Steffen, K., Stenni, B., and Sveinbjörnsdottír, A. E.: What controls the isotopic composition of Greenland surface snow?, Clim. Past, 10, 377–392, https://doi.org/10.5194/cp-10-377-2014, 2014.
Steig, E. J., Gkinis, V., Schauer, A. J., Schoenemann, S. W., Samek, K., Hoffnagle, J., Dennis, K. J., and Tan, S. M.: Calibrated high-precision 17O-excess measurements using cavity ring-down spectroscopy with laser-current-tuned cavity resonance, Atmos. Meas. Tech., 7, 2421–2435, https://doi.org/10.5194/amt-7-2421-2014, 2014.
Stoltmann, T., Casado, M., Daëron, M., Landais, A., and Kassi, S.: Direct, Precise Measurements of Isotopologue Abundance Ratios in CO2 Using Molecular Absorption Spectroscopy: Application to Δ17O, Anal. Chem., 89, 10129–10132, 2017.
Thurnherr, I., Kozachek, A., Graf, P., Weng, Y., Bolshiyanov, D., Landwehr, S., Pfahl, S., Schmale, J., Sodemann, H., Steen-Larsen, H. C., Toffoli, A., Wernli, H., and Aemisegger, F.: Meridional and vertical variations of the water vapour isotopic composition in the marine boundary layer over the Atlantic and Southern Ocean, Atmos. Chem. Phys., 20, 5811–5835, https://doi.org/10.5194/acp-20-5811-2020, 2020.
Wei, Z., Lee, X., Aemisegger, F., Benetti, M., Berkelhammer, M., Casado, M., Caylor, K., Christner, E., Dyroff, C., and García, O.: A global database of water vapor isotopes measured with high temporal resolution infrared laser spectroscopy, Sci. Data, 6, 1–15, 2019.
Weng, Y., Touzeau, A., and Sodemann, H.: Correcting the impact of the isotope composition on the mixing ratio dependency of water vapour isotope measurements with cavity ring-down spectrometers, Atmos. Meas. Tech., 13, 3167–3190, https://doi.org/10.5194/amt-13-3167-2020, 2020.
Werner, M., Langebroek, P. M., Carlsen, T., Herold, M., and Lohmann, G.: Stable water isotopes in the ECHAM5 general circulation model: Toward high-resolution isotope modeling on a global scale, J. Geophys. Res.-Atmos., 116, D15109, https://doi.org/10.1029/2011JD015681, 2011.
Short summary
Measuring water isotopic composition in Antarctica is difficult because of the extremely cold temperature in winter. Here, we designed a new infrared spectrometer able to measure the vapour isotopic composition during more than 95 % of the year in the coldest locations of Antarctica, whereas current commercial instruments are only able to measure during the warm summer months in the interior.
Measuring water isotopic composition in Antarctica is difficult because of the extremely cold...
