Articles | Volume 11, issue 6
https://doi.org/10.5194/amt-11-3717-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-11-3717-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
26 Jun 2018
Research article |
| 26 Jun 2018
| 26 Jun 2018
Performance of NO, NO2 low cost sensors and three calibration approaches within a real world application
Alessandro Bigi
CORRESPONDING AUTHOR
“Enzo Ferrari” Department of Engineering, University of Modena and Reggio Emilia, Modena, Italy
Michael Mueller
Empa, Swiss Federal Laboratories for Materials Science and Technology, Duebendorf, Switzerland
Stuart K. Grange
Wolfson Atmospheric Chemistry Laboratory, University of York, York, UK
Grazia Ghermandi
“Enzo Ferrari” Department of Engineering, University of Modena and Reggio Emilia, Modena, Italy
Christoph Hueglin
Empa, Swiss Federal Laboratories for Materials Science and Technology, Duebendorf, Switzerland
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We present an innovative software toolkit to differentiate sources of carbonaceous aerosol in the atmosphere. Our toolkit implements an upgraded mathematical model which allows for determination of fundamental optical properties of the aerosol, its sources, and the mass concentration of different carbonaceous species of particulate matter. We have tested the functionality of the software by re-analysing published data, and we obtained a compatible results with additional information.
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Natalie M. Mahowald, Longlei Li, Julius Vira, Marje Prank, Douglas S. Hamilton, Hitoshi Matsui, Ron L. Miller, Louis Lu, Ezgi Akyuz, Daphne Meidan, Peter Hess, Heikki Lihavainen, Christine Wiedinmyer, Jenny Hand, Maria Grazia Alaimo, Célia Alves, Andres Alastuey, Paulo Artaxo, Africa Barreto, Francisco Barraza, Silvia Becagli, Giulia Calzolai, Shankarararman Chellam, Ying Chen, Patrick Chuang, David D. Cohen, Cristina Colombi, Evangelia Diapouli, Gaetano Dongarra, Konstantinos Eleftheriadis, Corinne Galy-Lacaux, Cassandra Gaston, Dario Gomez, Yenny González Ramos, Hannele Hakola, Roy M. Harrison, Chris Heyes, Barak Herut, Philip Hopke, Christoph Hüglin, Maria Kanakidou, Zsofia Kertesz, Zbiginiw Klimont, Katriina Kyllönen, Fabrice Lambert, Xiaohong Liu, Remi Losno, Franco Lucarelli, Willy Maenhaut, Beatrice Marticorena, Randall V. Martin, Nikolaos Mihalopoulos, Yasser Morera-Gomez, Adina Paytan, Joseph Prospero, Sergio Rodríguez, Patricia Smichowski, Daniela Varrica, Brenna Walsh, Crystal Weagle, and Xi Zhao
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-1, https://doi.org/10.5194/essd-2024-1, 2024
Preprint withdrawn
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Alessandro Bigi, Giorgio Veratti, Elisabeth Andrews, Martine Collaud Coen, Lorenzo Guerrieri, Vera Bernardoni, Dario Massabò, Luca Ferrero, Sergio Teggi, and Grazia Ghermandi
Atmos. Chem. Phys., 23, 14841–14869, https://doi.org/10.5194/acp-23-14841-2023, https://doi.org/10.5194/acp-23-14841-2023, 2023
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Jean-Philippe Putaud, Enrico Pisoni, Alexander Mangold, Christoph Hueglin, Jean Sciare, Michael Pikridas, Chrysanthos Savvides, Jakub Ondracek, Saliou Mbengue, Alfred Wiedensohler, Kay Weinhold, Maik Merkel, Laurent Poulain, Dominik van Pinxteren, Hartmut Herrmann, Andreas Massling, Claus Nordstroem, Andrés Alastuey, Cristina Reche, Noemí Pérez, Sonia Castillo, Mar Sorribas, Jose Antonio Adame, Tuukka Petaja, Katrianne Lehtipalo, Jarkko Niemi, Véronique Riffault, Joel F. de Brito, Augustin Colette, Olivier Favez, Jean-Eudes Petit, Valérie Gros, Maria I. Gini, Stergios Vratolis, Konstantinos Eleftheriadis, Evangelia Diapouli, Hugo Denier van der Gon, Karl Espen Yttri, and Wenche Aas
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Stuart K. Grange, Gaëlle Uzu, Samuël Weber, Jean-Luc Jaffrezo, and Christoph Hueglin
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Horim Kim, Michael Müller, Stephan Henne, and Christoph Hüglin
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Adam Brighty, Véronique Jacob, Gaëlle Uzu, Lucille Borlaza, Sébastien Conil, Christoph Hueglin, Stuart K. Grange, Olivier Favez, Cécile Trébuchon, and Jean-Luc Jaffrezo
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Franz Conen, Annika Einbock, Claudia Mignani, and Christoph Hüglin
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Gang Chen, Yulia Sosedova, Francesco Canonaco, Roman Fröhlich, Anna Tobler, Athanasia Vlachou, Kaspar R. Daellenbach, Carlo Bozzetti, Christoph Hueglin, Peter Graf, Urs Baltensperger, Jay G. Slowik, Imad El Haddad, and André S. H. Prévôt
Atmos. Chem. Phys., 21, 15081–15101, https://doi.org/10.5194/acp-21-15081-2021, https://doi.org/10.5194/acp-21-15081-2021, 2021
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A novel, advanced source apportionment technique was applied to a dataset measured in Magadino. Rolling positive matrix factorisation (PMF) allows for retrieving more realistic, time-dependent, and detailed information on organic aerosol sources. The strength of the rolling PMF mechanism is highlighted by comparing it with results derived from conventional seasonal PMF. Overall, this comprehensive interpretation of aerosol chemical speciation monitor data could be a role model for similar work.
Stuart K. Grange, James D. Lee, Will S. Drysdale, Alastair C. Lewis, Christoph Hueglin, Lukas Emmenegger, and David C. Carslaw
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The changes in mobility across Europe due to the COVID-19 lockdowns had consequences for air quality. We compare what was experienced to estimates of "what would have been" without the lockdowns. Nitrogen dioxide (NO2), an important vehicle-sourced pollutant, decreased by a third. However, ozone (O3) increased in response to lower NO2. Because NO2 is decreasing over time, increases in O3 can be expected in European urban areas and will require management to avoid future negative outcomes.
Martine Collaud Coen, Elisabeth Andrews, Alessandro Bigi, Giovanni Martucci, Gonzague Romanens, Frédéric P. A. Vogt, and Laurent Vuilleumier
Atmos. Meas. Tech., 13, 6945–6964, https://doi.org/10.5194/amt-13-6945-2020, https://doi.org/10.5194/amt-13-6945-2020, 2020
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The Mann–Kendall trend test requires prewhitening in the presence of serially correlated data. The effects of five prewhitening methods and time granularity, autocorrelation, temporal segmentation and length of the time series on the statistical significance and the slope are studies for seven atmospheric datasets. Finally, a new algorithm using three prewhitening methods is proposed in order to optimize the power of the test, the amount of erroneous false positive trends and the slope estimate.
Paolo Laj, Alessandro Bigi, Clémence Rose, Elisabeth Andrews, Cathrine Lund Myhre, Martine Collaud Coen, Yong Lin, Alfred Wiedensohler, Michael Schulz, John A. Ogren, Markus Fiebig, Jonas Gliß, Augustin Mortier, Marco Pandolfi, Tuukka Petäja, Sang-Woo Kim, Wenche Aas, Jean-Philippe Putaud, Olga Mayol-Bracero, Melita Keywood, Lorenzo Labrador, Pasi Aalto, Erik Ahlberg, Lucas Alados Arboledas, Andrés Alastuey, Marcos Andrade, Begoña Artíñano, Stina Ausmeel, Todor Arsov, Eija Asmi, John Backman, Urs Baltensperger, Susanne Bastian, Olaf Bath, Johan Paul Beukes, Benjamin T. Brem, Nicolas Bukowiecki, Sébastien Conil, Cedric Couret, Derek Day, Wan Dayantolis, Anna Degorska, Konstantinos Eleftheriadis, Prodromos Fetfatzis, Olivier Favez, Harald Flentje, Maria I. Gini, Asta Gregorič, Martin Gysel-Beer, A. Gannet Hallar, Jenny Hand, Andras Hoffer, Christoph Hueglin, Rakesh K. Hooda, Antti Hyvärinen, Ivo Kalapov, Nikos Kalivitis, Anne Kasper-Giebl, Jeong Eun Kim, Giorgos Kouvarakis, Irena Kranjc, Radovan Krejci, Markku Kulmala, Casper Labuschagne, Hae-Jung Lee, Heikki Lihavainen, Neng-Huei Lin, Gunter Löschau, Krista Luoma, Angela Marinoni, Sebastiao Martins Dos Santos, Frank Meinhardt, Maik Merkel, Jean-Marc Metzger, Nikolaos Mihalopoulos, Nhat Anh Nguyen, Jakub Ondracek, Noemi Pérez, Maria Rita Perrone, Jean-Eudes Petit, David Picard, Jean-Marc Pichon, Veronique Pont, Natalia Prats, Anthony Prenni, Fabienne Reisen, Salvatore Romano, Karine Sellegri, Sangeeta Sharma, Gerhard Schauer, Patrick Sheridan, James Patrick Sherman, Maik Schütze, Andreas Schwerin, Ralf Sohmer, Mar Sorribas, Martin Steinbacher, Junying Sun, Gloria Titos, Barbara Toczko, Thomas Tuch, Pierre Tulet, Peter Tunved, Ville Vakkari, Fernando Velarde, Patricio Velasquez, Paolo Villani, Sterios Vratolis, Sheng-Hsiang Wang, Kay Weinhold, Rolf Weller, Margarita Yela, Jesus Yus-Diez, Vladimir Zdimal, Paul Zieger, and Nadezda Zikova
Atmos. Meas. Tech., 13, 4353–4392, https://doi.org/10.5194/amt-13-4353-2020, https://doi.org/10.5194/amt-13-4353-2020, 2020
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The paper establishes the fiducial reference of the GAW aerosol network providing the fully characterized value chain to the provision of four climate-relevant aerosol properties from ground-based sites. Data from almost 90 stations worldwide are reported for a reference year, 2017, providing a unique and very robust view of the variability of these variables worldwide. Current gaps in the GAW network are analysed and requirements for the Global Climate Monitoring System are proposed.
Eirini Boleti, Christoph Hueglin, Stuart K. Grange, André S. H. Prévôt, and Satoshi Takahama
Atmos. Chem. Phys., 20, 9051–9066, https://doi.org/10.5194/acp-20-9051-2020, https://doi.org/10.5194/acp-20-9051-2020, 2020
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Long-term temporal evolution of ozone concentrations between 2000 and 2015 in Europe was estimated using a signal decomposition technique. The seasonal cycles are correlated with local climate conditions and vary according to geographic region, while ozone levels are indicative of distance to emission sources. The site's environment plays a key role in ozone trends, with the most polluted environments showing the least reduction in ozone, while in less polluted areas ozone has decreased.
Martine Collaud Coen, Elisabeth Andrews, Andrés Alastuey, Todor Petkov Arsov, John Backman, Benjamin T. Brem, Nicolas Bukowiecki, Cédric Couret, Konstantinos Eleftheriadis, Harald Flentje, Markus Fiebig, Martin Gysel-Beer, Jenny L. Hand, András Hoffer, Rakesh Hooda, Christoph Hueglin, Warren Joubert, Melita Keywood, Jeong Eun Kim, Sang-Woo Kim, Casper Labuschagne, Neng-Huei Lin, Yong Lin, Cathrine Lund Myhre, Krista Luoma, Hassan Lyamani, Angela Marinoni, Olga L. Mayol-Bracero, Nikos Mihalopoulos, Marco Pandolfi, Natalia Prats, Anthony J. Prenni, Jean-Philippe Putaud, Ludwig Ries, Fabienne Reisen, Karine Sellegri, Sangeeta Sharma, Patrick Sheridan, James Patrick Sherman, Junying Sun, Gloria Titos, Elvis Torres, Thomas Tuch, Rolf Weller, Alfred Wiedensohler, Paul Zieger, and Paolo Laj
Atmos. Chem. Phys., 20, 8867–8908, https://doi.org/10.5194/acp-20-8867-2020, https://doi.org/10.5194/acp-20-8867-2020, 2020
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Long-term trends of aerosol radiative properties (52 stations) prove that aerosol load has significantly decreased over the last 20 years. Scattering trends are negative in Europe (EU) and North America (NA), not ss in Asia, and show a mix of positive and negative trends at polar stations. Absorption has mainly negative trends. The single scattering albedo has positive trends in Asia and eastern EU and negative in western EU and NA, leading to a global positive median trend of 0.02 % per year.
Michael Müller, Peter Graf, Jonas Meyer, Anastasia Pentina, Dominik Brunner, Fernando Perez-Cruz, Christoph Hüglin, and Lukas Emmenegger
Atmos. Meas. Tech., 13, 3815–3834, https://doi.org/10.5194/amt-13-3815-2020, https://doi.org/10.5194/amt-13-3815-2020, 2020
Stuart K. Grange, Hanspeter Lötscher, Andrea Fischer, Lukas Emmenegger, and Christoph Hueglin
Atmos. Meas. Tech., 13, 1867–1885, https://doi.org/10.5194/amt-13-1867-2020, https://doi.org/10.5194/amt-13-1867-2020, 2020
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Black carbon (BC) is an important atmospheric pollutant and can be monitored by instruments called aethalometers. A pragmatic data processing technique called the
aethalometer modelcan be used to apportion aethalometer observations into traffic and woodburning components. We present an exploratory data analysis evaluating the aethalometer model and use the outputs for BC trend analysis across Switzerland. The aethalometer model's robustness and utility for such analyses is discussed.
Pragati Rai, Markus Furger, Jay G. Slowik, Francesco Canonaco, Roman Fröhlich, Christoph Hüglin, María Cruz Minguillón, Krag Petterson, Urs Baltensperger, and André S. H. Prévôt
Atmos. Chem. Phys., 20, 1657–1674, https://doi.org/10.5194/acp-20-1657-2020, https://doi.org/10.5194/acp-20-1657-2020, 2020
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A source apportionment study of hourly resolved elements in PM10 measured at a traffic-influenced site in Härkingen, Switzerland, using positive matrix factorization (PMF) and multilinear engine-2 (ME-2) offered resolution of robust and unambiguous factor profiles and contributions. We show that the rotational control available in ME-2 provides a means for treating extreme events such as fireworks within a PMF analysis.
Marco Pandolfi, Dennis Mooibroek, Philip Hopke, Dominik van Pinxteren, Xavier Querol, Hartmut Herrmann, Andrés Alastuey, Olivier Favez, Christoph Hüglin, Esperanza Perdrix, Véronique Riffault, Stéphane Sauvage, Eric van der Swaluw, Oksana Tarasova, and Augustin Colette
Atmos. Chem. Phys., 20, 409–429, https://doi.org/10.5194/acp-20-409-2020, https://doi.org/10.5194/acp-20-409-2020, 2020
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In the last scientific assessment report from the LRTAP Convention, it is stated that because non-urban sources are often major contributors to urban pollution, many cities will be unable to meet WHO guideline levels for air pollutants through local action alone. Consequently, it is very important to estimate how much the local and non-local sources contribute to urban pollution in order to design global strategies to reduce the levels of pollutants in European cities.
Giulia Stefenelli, Veronika Pospisilova, Felipe D. Lopez-Hilfiker, Kaspar R. Daellenbach, Christoph Hüglin, Yandong Tong, Urs Baltensperger, André S. H. Prévôt, and Jay G. Slowik
Atmos. Chem. Phys., 19, 14825–14848, https://doi.org/10.5194/acp-19-14825-2019, https://doi.org/10.5194/acp-19-14825-2019, 2019
Lu Qi, Mindong Chen, Giulia Stefenelli, Veronika Pospisilova, Yandong Tong, Amelie Bertrand, Christoph Hueglin, Xinlei Ge, Urs Baltensperger, André S. H. Prévôt, and Jay G. Slowik
Atmos. Chem. Phys., 19, 8037–8062, https://doi.org/10.5194/acp-19-8037-2019, https://doi.org/10.5194/acp-19-8037-2019, 2019
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Current understanding of OA sources is limited by the chemical resolution of existing real-time measurement technology. We describe the first wintertime deployment of a novel extractive electrospray ionization time-of-flight mass spectrometer, which provides near-molecular OA measurements with high time resolution. We show that biomass combustion strongly influences winter OA. Via factor analysis, aging-dependent signatures and time contributions of biomass-combustion-derived OA are resolved.
Karl Espen Yttri, David Simpson, Robert Bergström, Gyula Kiss, Sönke Szidat, Darius Ceburnis, Sabine Eckhardt, Christoph Hueglin, Jacob Klenø Nøjgaard, Cinzia Perrino, Ignazio Pisso, Andre Stephan Henry Prevot, Jean-Philippe Putaud, Gerald Spindler, Milan Vana, Yan-Lin Zhang, and Wenche Aas
Atmos. Chem. Phys., 19, 4211–4233, https://doi.org/10.5194/acp-19-4211-2019, https://doi.org/10.5194/acp-19-4211-2019, 2019
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Carbonaceous aerosols from natural sources were abundant regardless of season. Residential wood burning (RWB) emissions were occasionally equally as large as or larger than of fossil-fuel sources, depending on season and region. RWB emissions are poorly constrained; thus emissions inventories need improvement. Harmonizing emission factors between countries is likely the most important step to improve model calculations for biomass burning emissions and European PM2.5 concentrations in general.
P. Morten Hundt, Michael Müller, Markus Mangold, Béla Tuzson, Philipp Scheidegger, Herbert Looser, Christoph Hüglin, and Lukas Emmenegger
Atmos. Meas. Tech., 11, 2669–2681, https://doi.org/10.5194/amt-11-2669-2018, https://doi.org/10.5194/amt-11-2669-2018, 2018
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NO2 is a pollutant that regularly exceeds its limit values in European cities. We developed a compact, mobile laser spectrometer that measures NO2 concentrations and installed it on a tram in Zurich. Mobile operation resulted in NO2 concentration data with high spatio-temporal resolution. The data were validated against fixed air-quality monitoring sites and provided detailed insights into the spatio-temporal concentration distribution of NO2 in an urban environment.
Stuart K. Grange, David C. Carslaw, Alastair C. Lewis, Eirini Boleti, and Christoph Hueglin
Atmos. Chem. Phys., 18, 6223–6239, https://doi.org/10.5194/acp-18-6223-2018, https://doi.org/10.5194/acp-18-6223-2018, 2018
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Weather (meteorology) has a strong effect on air quality; if not accounted for, there is uncertainty surrounding what drives features in air quality time series. We present a machine learning approach to account for meteorology using PM10 data in Switzerland. With the exception of one site, all Swiss normalised PM10 trends were found to significantly decrease, which validates air quality management efforts. The machine learning models were interpreted to investigate interesting processes.
Athanasia Vlachou, Kaspar R. Daellenbach, Carlo Bozzetti, Benjamin Chazeau, Gary A. Salazar, Soenke Szidat, Jean-Luc Jaffrezo, Christoph Hueglin, Urs Baltensperger, Imad El Haddad, and André S. H. Prévôt
Atmos. Chem. Phys., 18, 6187–6206, https://doi.org/10.5194/acp-18-6187-2018, https://doi.org/10.5194/acp-18-6187-2018, 2018
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Carbonaceous aerosols are related to adverse human health effects, which depend on the aerosol chemical composition and size. Here, we combine aerosol mass spectrometry and radiocarbon measurements of size-resolved samples collected over a long term to identify the origins of primary and secondary carbonaceous aerosols in the fine and coarse modes.
Kaspar R. Daellenbach, Giulia Stefenelli, Carlo Bozzetti, Athanasia Vlachou, Paola Fermo, Raquel Gonzalez, Andrea Piazzalunga, Cristina Colombi, Francesco Canonaco, Christoph Hueglin, Anne Kasper-Giebl, Jean-Luc Jaffrezo, Federico Bianchi, Jay G. Slowik, Urs Baltensperger, Imad El-Haddad, and André S. H. Prévôt
Atmos. Chem. Phys., 17, 13265–13282, https://doi.org/10.5194/acp-17-13265-2017, https://doi.org/10.5194/acp-17-13265-2017, 2017
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We present offline AMS analyses for the organic aerosol (OA) in PM10 at nine sites in central Europe for 2013. Primary OA is separated into traffic, cooking, and wood-burning components. A factor explaining sulfur-containing ions, with an event-driven time series, is also separated. We observe enhanced production of secondary OA (SOA) in summer, following biogenic emissions with temperature. In winter a SOA component is dominant, which correlates with anthropogenic inorganic species.
Michael Mueller, Jonas Meyer, and Christoph Hueglin
Atmos. Meas. Tech., 10, 3783–3799, https://doi.org/10.5194/amt-10-3783-2017, https://doi.org/10.5194/amt-10-3783-2017, 2017
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This study describes the design of a sensor unit featuring NO2 and O3 sensors for applications such as ambient air quality monitoring. The paper presents the sensor calibration, the testing procedure and the long-term deployment of the sensor units in the city of Zurich.
Main conclusions are the necessity of a proper mathematical description of the sensors as well as a concept to monitor sensor performance during operation, e.g. by linking low-cost sensors to traditional infrastructure.
Markus Furger, María Cruz Minguillón, Varun Yadav, Jay G. Slowik, Christoph Hüglin, Roman Fröhlich, Krag Petterson, Urs Baltensperger, and André S. H. Prévôt
Atmos. Meas. Tech., 10, 2061–2076, https://doi.org/10.5194/amt-10-2061-2017, https://doi.org/10.5194/amt-10-2061-2017, 2017
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An Xact 625 Ambient Metals Monitor was tested during a 3-week summer field campaign at a rural, traffic-influenced site in Switzerland. The objective was to characterize the operation of the instrument, evaluate the data quality by intercomparison with other independent measurements, and test its applicability for aerosol source quantification. The results demonstrate significant advantages compared to traditional elemental analysis methods, with some desirable improvements.
Peter Zotter, Hanna Herich, Martin Gysel, Imad El-Haddad, Yanlin Zhang, Griša Močnik, Christoph Hüglin, Urs Baltensperger, Sönke Szidat, and André S. H. Prévôt
Atmos. Chem. Phys., 17, 4229–4249, https://doi.org/10.5194/acp-17-4229-2017, https://doi.org/10.5194/acp-17-4229-2017, 2017
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Most studies use a single Ångström exponent for wood burning (αWB) and traffic (αTR) emissions in the Aethalometer model, used for source apportionment of black carbon, derived from previous work. However, accurate determination of the α values is currently lacking. Comparing radiocarbon measurements (14C) with the Aehtalometer model, good agreement was found, indicating that the Aethalometer model reproduces reasonably well the 14C results using our best estimate of a single αWB and αTR.
Alessandro Bigi and Grazia Ghermandi
Atmos. Chem. Phys., 16, 15777–15788, https://doi.org/10.5194/acp-16-15777-2016, https://doi.org/10.5194/acp-16-15777-2016, 2016
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Po Valley (northern Italy, 42 000 km2, 15 million inhabitants) is a real-scale model to test whether environmental policies may improve one of the worst air qualities in Europe. In this study we show how pollution from fine and coarse atmospheric particles (PM2.5 and PM10–2.5), largely originating from anthropogenic emissions, dropped thanks to the broader use of cleaner and more efficient technologies.
Andrés Alastuey, Xavier Querol, Wenche Aas, Franco Lucarelli, Noemí Pérez, Teresa Moreno, Fabrizia Cavalli, Hans Areskoug, Violeta Balan, Maria Catrambone, Darius Ceburnis, José C. Cerro, Sébastien Conil, Lusine Gevorgyan, Christoph Hueglin, Kornelia Imre, Jean-Luc Jaffrezo, Sarah R. Leeson, Nikolaos Mihalopoulos, Marta Mitosinkova, Colin D. O'Dowd, Jorge Pey, Jean-Philippe Putaud, Véronique Riffault, Anna Ripoll, Jean Sciare, Karine Sellegri, Gerald Spindler, and Karl Espen Yttri
Atmos. Chem. Phys., 16, 6107–6129, https://doi.org/10.5194/acp-16-6107-2016, https://doi.org/10.5194/acp-16-6107-2016, 2016
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Mineral dust content in PM10 was analysed at 20 regional background sites across Europe. Higher dust loadings were observed at most sites in summer, with the most elevated concentrations in the southern- and easternmost countries, due to external and regional sources. Saharan dust outbreaks impacted western and central European in summer and eastern Mediterranean sites in winter. The spatial distribution of some metals reveals the influence of specific anthropogenic sources on a regional scale.
P. Kupiszewski, E. Weingartner, P. Vochezer, M. Schnaiter, A. Bigi, M. Gysel, B. Rosati, E. Toprak, S. Mertes, and U. Baltensperger
Atmos. Meas. Tech., 8, 3087–3106, https://doi.org/10.5194/amt-8-3087-2015, https://doi.org/10.5194/amt-8-3087-2015, 2015
P. Zotter, V. G. Ciobanu, Y. L. Zhang, I. El-Haddad, M. Macchia, K. R. Daellenbach, G. A. Salazar, R.-J. Huang, L. Wacker, C. Hueglin, A. Piazzalunga, P. Fermo, M. Schwikowski, U. Baltensperger, S. Szidat, and A. S. H. Prévôt
Atmos. Chem. Phys., 14, 13551–13570, https://doi.org/10.5194/acp-14-13551-2014, https://doi.org/10.5194/acp-14-13551-2014, 2014
A. Bigi and G. Ghermandi
Atmos. Chem. Phys., 14, 4895–4907, https://doi.org/10.5194/acp-14-4895-2014, https://doi.org/10.5194/acp-14-4895-2014, 2014
A. Mues, J. Kuenen, C. Hendriks, A. Manders, A. Segers, Y. Scholz, C. Hueglin, P. Builtjes, and M. Schaap
Atmos. Chem. Phys., 14, 939–955, https://doi.org/10.5194/acp-14-939-2014, https://doi.org/10.5194/acp-14-939-2014, 2014
Related subject area
Subject: Gases | Technique: In Situ Measurement | Topic: Instruments and Platforms
Multiphysical description of atmospheric pressure interface chemical ionisation in MION2 and Eisele type inlets
A portable nitrogen dioxide instrument using cavity-enhanced absorption spectroscopy
Development and deployment of a mid-cost CO2 sensor monitoring network to support atmospheric inverse modeling for quantifying urban CO2 emissions in Paris
UAV-based in situ measurements of CO2 and CH4 fluxes over complex natural ecosystems
A new aerial approach for quantifying and attributing methane emissions: implementation and validation
Drone CO2 measurements during the Tajogaite volcanic eruption
Multi-decadal atmospheric carbon dioxide measurements in Hungary, central Europe
Reliable water vapour isotopic composition measurements at low humidity using frequency-stabilised cavity ring-down spectroscopy
A measurement system for CO2 and CH4 emissions quantification of industrial sites using a new in situ concentration sensor operated on board uncrewed aircraft vehicles
Deployment and evaluation of an NH4+/H3O+ reagent-ion switching chemical ionization mass spectrometer for the detection of reduced and oxygenated gas-phase organic compounds
Using metal oxide gas sensors to estimate the emission rates and locations of methane leaks in an industrial site: assessment with controlled methane releases
Toward on-demand measurements of greenhouse gas emissions using an uncrewed aircraft AirCore system
Long-term evaluation of commercial air quality sensors: an overview from the QUANT (Quantification of Utility of Atmospheric Network Technologies) study
In-flight characterization of a compact airborne quantum cascade laser absorption spectrometer
Full characterization and calibration of a transfer standard monitor for atmospheric radon measurements
Observing low-altitude features in ozone concentrations in a shoreline environment via uncrewed aerial systems
Eddy-covariance with slow-response greenhouse gas analyser on tall towers: bridging atmospheric and ecosystem greenhouse gases networks
An integrated uncrewed aerial vehicle platform with sensing and sampling systems for the measurement of air pollutant concentrations
Design and evaluation of a low-cost sensor node for near-background methane measurement
Development of a Multichannel Organics In situ enviRonmental Analyzer (MOIRA) for mobile measurements of volatile organic compounds
An Economical Tunable-Diode Laser Spectrometer for Fast-Response Measurements of Water Vapor in the Atmospheric Boundary Layer
Evaluation of Aeris mid-infrared absorption (MIRA), Picarro CRDS (cavity ring-down spectroscopy) G2307, and dinitrophenylhydrazine (DNPH)-based sampling for long-term formaldehyde monitoring efforts
An overview of outdoor low-cost gas-phase air quality sensor deployments: current efforts, trends, and limitations
Performance characterization of a laminar gas inlet
Validation and field application of a low-cost device to measure CO2 and evapotranspiration (ET) fluxes
Identifying and correcting interferences to PTR-ToF-MS measurements of isoprene and other urban volatile organic compounds
Development of a continuous UAV-mounted air sampler and application to the quantification of CO2 and CH4 emissions from a major coking plant
Uptake behavior of polycyclic aromatic compounds during field calibrations of the XAD-based passive air sampler across seasons and locations
Effect of land–sea air mass transport on spatiotemporal distributions of atmospheric CO2 and CH4 mixing ratios over the southern Yellow Sea
HYPHOP: a tool for high-altitude, long-range monitoring of hydrogen peroxide and higher organic peroxides in the atmosphere
Portable, low-cost samplers for distributed sampling of atmospheric gases
SI-traceable validation of a laser spectrometer for balloon-borne measurements of water vapor in the upper atmosphere
Field evaluation of low-cost electrochemical air quality gas sensors under extreme temperature and relative humidity conditions
A novel, cost-effective analytical method for measuring high-resolution vertical profiles of stratospheric trace gases using a gas chromatograph coupled with an electron capture detector
Ethylene oxide monitor with part-per-trillion precision for in situ measurements
Development of an automated pump-efficiency measuring system for ozonesondes utilizing an airbag-type flowmeter
Short-term variability of atmospheric helium revealed through a cryo-enrichment method
Using tunable infrared laser direct absorption spectroscopy for ambient hydrogen chloride detection: HCl-TILDAS
New methods for the calibration of optical resonators: integrated calibration by means of optical modulation (ICOM) and narrow-band cavity ring-down (NB-CRD)
A modular field system for near-surface, vertical profiling of the atmospheric composition in harsh environments using cavity ring-down spectroscopy
Field comparison of two novel open-path instruments that measure dry deposition and emission of ammonia using flux-gradient and eddy covariance methods
Development of multi-channel whole-air sampling equipment onboard an unmanned aerial vehicle for investigating volatile organic compounds' vertical distribution in the planetary boundary layer
Electrochemical sensors on board a Zeppelin NT: in-flight evaluation of low-cost trace gas measurements
Evaluating the performance of a Picarro G2207-i analyser for high-precision atmospheric O2 measurements
Airborne flux measurements of ammonia over the southern Great Plains using chemical ionization mass spectrometry
Optical receiver characterizations and corrections for ground-based and airborne measurements of spectral actinic flux densities
Development and validation of a new in situ technique to measure total gaseous chlorine in air
True eddy accumulation – Part 1: Solutions to the problem of non-vanishing mean vertical wind velocity
True eddy accumulation – Part 2: Theory and experiment of the short-time eddy accumulation method
Chemical ionization mass spectrometry utilizing ammonium ions (NH4+ CIMS) for measurements of organic compounds in the atmosphere
Henning Finkenzeller, Jyri Mikkilä, Cecilia Righi, Paxton Juuti, Mikko Sipilä, Matti Rissanen, Douglas Worsnop, Aleksei Shcherbinin, Nina Sarnela, and Juha Kangasluoma
Atmos. Meas. Tech., 17, 5989–6001, https://doi.org/10.5194/amt-17-5989-2024, https://doi.org/10.5194/amt-17-5989-2024, 2024
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Chemical ionisation mass spectrometry is used in the atmospheric sciences to measure trace gas concentrations. Neutral gases require charging in inlets before the mass-to-charge ratio of the resulting ions can be analysed. This study uses multiphysics modelling to investigate how the MION2 and Eisele type inlets work and shows the effect of tuning parameters and their current limitations. The findings are helpful for inlet users and are expected to aid in developing improved inlets.
Steven A. Bailey, Reem A. Hannun, Andrew K. Swanson, and Thomas F. Hanisco
Atmos. Meas. Tech., 17, 5903–5910, https://doi.org/10.5194/amt-17-5903-2024, https://doi.org/10.5194/amt-17-5903-2024, 2024
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We have developed a portable, optically based instrument that measures NO2. It consumes less than 6 W of power, so it can easily run off a small battery. This instrument has made both balloon and UAV flights. NO2 measurement results compare favorably with other known NO2 instruments. We find this instrument to be stable with repeatable results compared with calibration sources. Material cost to build a single instrument is around USD 4000. This could be lowered with economies of scale.
Jinghui Lian, Olivier Laurent, Mali Chariot, Luc Lienhardt, Michel Ramonet, Hervé Utard, Thomas Lauvaux, François-Marie Bréon, Grégoire Broquet, Karina Cucchi, Laurent Millair, and Philippe Ciais
Atmos. Meas. Tech., 17, 5821–5839, https://doi.org/10.5194/amt-17-5821-2024, https://doi.org/10.5194/amt-17-5821-2024, 2024
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We have designed and deployed a mid-cost medium-precision CO2 sensor monitoring network in Paris since July 2020. The data are automatically calibrated by a newly implemented data processing system. The accuracies of the mid-cost instruments vary from 1.0 to 2.4 ppm for hourly afternoon measurements. Our model–data analyses highlight prospects for integrating mid-cost instrument data with high-precision measurements to improve fine-scale CO2 emission quantification in urban areas.
Abdullah Bolek, Martin Heimann, and Mathias Göckede
Atmos. Meas. Tech., 17, 5619–5636, https://doi.org/10.5194/amt-17-5619-2024, https://doi.org/10.5194/amt-17-5619-2024, 2024
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This study describes the development of a new UAV platform to measure atmospheric greenhouse gas (GHG) mole fractions, 2D wind speed, air temperature, humidity, and pressure. Understanding GHG flux processes and controls across various ecosystems is essential for estimating the current and future state of climate change. It was shown that using the UAV platform for such measurements is beneficial for improving our understanding of GHG processes over complex landscapes.
Jonathan F. Dooley, Kenneth Minschwaner, Manvendra K. Dubey, Sahar H. El Abbadi, Evan D. Sherwin, Aaron G. Meyer, Emily Follansbee, and James E. Lee
Atmos. Meas. Tech., 17, 5091–5111, https://doi.org/10.5194/amt-17-5091-2024, https://doi.org/10.5194/amt-17-5091-2024, 2024
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Methane is a powerful greenhouse gas originating from both natural and human activities. We describe a new uncrewed aerial system (UAS) designed to measure methane emission rates over a wide range of scales. This system has been used for direct quantification of point sources and distributed emitters over scales of up to 1 km. The system uses simultaneous measurements of methane and ethane to distinguish between different kinds of natural and human-related emission sources.
John Ericksen, Tobias P. Fischer, G. Matthew Fricke, Scott Nowicki, Nemesio M. Pérez, Pedro Hernández Pérez, Eleazar Padrón González, and Melanie E. Moses
Atmos. Meas. Tech., 17, 4725–4736, https://doi.org/10.5194/amt-17-4725-2024, https://doi.org/10.5194/amt-17-4725-2024, 2024
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Volcanic eruptions emit significant quantities of carbon dioxide (CO2) to the atmosphere. We present a new method for directly determining the CO2 emission from a volcanic eruption on the island of La Palma, Spain, using an unpiloted aerial vehicle (UAV). We also collected samples of the emitted CO2 and analyzed their isotopic composition. Together with the emission rate the isotopic data provide valuable information on the state of volcanic activity and the potential evolution of the eruption.
László Haszpra
Atmos. Meas. Tech., 17, 4629–4647, https://doi.org/10.5194/amt-17-4629-2024, https://doi.org/10.5194/amt-17-4629-2024, 2024
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The paper evaluates a 30-year-long atmospheric CO2 data series from a mid-continental central European site, Hegyhátsál (HUN). It presents the site-specific features observed in the long-term evolution of the atmospheric CO2 concentration. Since the measurement data are widely used in atmospheric inverse models and budget calculations all around the world, the paper provides potentially valuable information for model tuning and interpretation of the model results.
Mathieu Casado, Amaelle Landais, Tim Stoltmann, Justin Chaillot, Mathieu Daëron, Fréderic Prié, Baptiste Bordet, and Samir Kassi
Atmos. Meas. Tech., 17, 4599–4612, https://doi.org/10.5194/amt-17-4599-2024, https://doi.org/10.5194/amt-17-4599-2024, 2024
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Measuring water isotopic composition in Antarctica is difficult because of the extremely cold temperature in winter. Here, we designed a new infrared spectrometer able to measure the vapour isotopic composition during more than 95 % of the year in the coldest locations of Antarctica, whereas current commercial instruments are only able to measure during the warm summer months in the interior.
Jean-Louis Bonne, Ludovic Donnat, Grégory Albora, Jérémie Burgalat, Nicolas Chauvin, Delphine Combaz, Julien Cousin, Thomas Decarpenterie, Olivier Duclaux, Nicolas Dumelié, Nicolas Galas, Catherine Juery, Florian Parent, Florent Pineau, Abel Maunoury, Olivier Ventre, Marie-France Bénassy, and Lilian Joly
Atmos. Meas. Tech., 17, 4471–4491, https://doi.org/10.5194/amt-17-4471-2024, https://doi.org/10.5194/amt-17-4471-2024, 2024
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We present a top-down approach to quantify CO2 and CH4 emissions at the scale of an industrial site, based on a mass balance model relying on atmospheric concentrations measurements from a new sensor embarked on board uncrewed aircraft vehicles (UAVs). We present a laboratory characterization of our sensor and a field validation of our quantification method, together with field application to the monitoring of two real-world offshore oil and gas platforms.
Cort L. Zang and Megan D. Willis
EGUsphere, https://doi.org/10.5194/egusphere-2024-1738, https://doi.org/10.5194/egusphere-2024-1738, 2024
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Atmospheric chemistry of the diverse pool of reactive organic carbon (ROC; all organic species excluding methane) controls air quality, both indoor and outdoors, and influences Earth's climate. However, many important ROC compounds in the atmosphere are difficult to measure. We demonstrate measurement of diverse ROC compounds in a single instrument at a forested site. This approach can improve our ability to measure a broad range of atmospheric ROC.
Rodrigo Rivera-Martinez, Pramod Kumar, Olivier Laurent, Gregoire Broquet, Christopher Caldow, Ford Cropley, Diego Santaren, Adil Shah, Cécile Mallet, Michel Ramonet, Leonard Rivier, Catherine Juery, Olivier Duclaux, Caroline Bouchet, Elisa Allegrini, Hervé Utard, and Philippe Ciais
Atmos. Meas. Tech., 17, 4257–4290, https://doi.org/10.5194/amt-17-4257-2024, https://doi.org/10.5194/amt-17-4257-2024, 2024
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We explore the use of metal oxide semiconductors (MOSs) as a low-cost alternative for detecting and measuring CH4 emissions from industrial facilities. MOSs were exposed to several controlled releases to test their accuracy in detecting and quantifying emissions. Two reconstruction models were compared, and emission estimates were computed using a Gaussian dispersion model. Findings show that MOSs can provide accurate emission estimates with a 25 % emission rate error and a 9.5 m location error.
Zihan Zhu, Javier González-Rocha, Yifan Ding, Isis Frausto-Vicencio, Sajjan Heerah, Akula Venkatram, Manvendra Dubey, Don Collins, and Francesca M. Hopkins
Atmos. Meas. Tech., 17, 3883–3895, https://doi.org/10.5194/amt-17-3883-2024, https://doi.org/10.5194/amt-17-3883-2024, 2024
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Increases in agriculture, oil and gas, and waste management activities have contributed to the increase in atmospheric methane levels and resultant climate warming. In this paper, we explore the use of small uncrewed aircraft systems (sUASs) and AirCore technology to detect and quantify methane emissions. Results from field experiments demonstrate that sUASs and AirCore technology can be effective for detecting and quantifying methane emissions in near real time.
Sebastian Diez, Stuart Lacy, Hugh Coe, Josefina Urquiza, Max Priestman, Michael Flynn, Nicholas Marsden, Nicholas A. Martin, Stefan Gillott, Thomas Bannan, and Pete M. Edwards
Atmos. Meas. Tech., 17, 3809–3827, https://doi.org/10.5194/amt-17-3809-2024, https://doi.org/10.5194/amt-17-3809-2024, 2024
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In this paper we present an overview of the QUANT project, which to our knowledge is one of the largest evaluations of commercial sensors to date. The objective was to evaluate the performance of a range of commercial products and also to nourish the different applications in which these technologies can offer relevant information.
Linda Ort, Lenard Lukas Röder, Uwe Parchatka, Rainer Königstedt, Daniel Crowley, Frank Kunz, Ralf Wittkowski, Jos Lelieveld, and Horst Fischer
Atmos. Meas. Tech., 17, 3553–3565, https://doi.org/10.5194/amt-17-3553-2024, https://doi.org/10.5194/amt-17-3553-2024, 2024
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Airborne in situ measurements are of great importance to collect valuable data to improve our knowledge of the atmosphere but also present challenges which demand specific designs. This study presents an IR spectrometer for airborne trace-gas measurements with high data efficiency and a simple, compact design. Its in-flight performance is characterized with the help of a test flight and a comparison with another spectrometer. Moreover, results from its first campaign highlight its benefits.
Roger Curcoll, Claudia Grossi, Stefan Röttger, and Arturo Vargas
Atmos. Meas. Tech., 17, 3047–3065, https://doi.org/10.5194/amt-17-3047-2024, https://doi.org/10.5194/amt-17-3047-2024, 2024
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This paper presents a new user-friendly version of the Atmospheric Radon MONitor (ARMON). The efficiency of the instrument is of 0.0057 s-1, obtained using different techniques at Spanish and German chambers. The total calculated uncertainty of the ARMON for hourly radon concentrations above 5 Bq m-3 is lower than 10 % (k = 1). Results confirm that the ARMON is suitable to measure low-level radon activity concentrations and to be used as a transfer standard to calibrate in situ radon monitors.
Josie K. Radtke, Benjamin N. Kies, Whitney A. Mottishaw, Sydney M. Zeuli, Aidan T. H. Voon, Kelly L. Koerber, Grant W. Petty, Michael P. Vermeuel, Timothy H. Bertram, Ankur R. Desai, Joseph P. Hupy, R. Bradley Pierce, Timothy J. Wagner, and Patricia A. Cleary
Atmos. Meas. Tech., 17, 2833–2847, https://doi.org/10.5194/amt-17-2833-2024, https://doi.org/10.5194/amt-17-2833-2024, 2024
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The use of uncrewed aircraft systems (UASs) to conduct a vertical profiling of ozone and meteorological variables was evaluated using comparisons between tower or ground observations and UAS-based measurements. Changes to the UAS profiler showed an improvement in performance. The profiler was used to see the impact of Chicago pollution plumes on a shoreline area near Lake Michigan.
Pedro Henrique Herig Coimbra, Benjamin Loubet, Olivier Laurent, Laura Bignotti, Mathis Lozano, and Michel Ramonet
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-71, https://doi.org/10.5194/amt-2024-71, 2024
Revised manuscript accepted for AMT
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This study explores using infrastructure built to assess atmospheric gas concentration with high precision to measure local emissions and sequestration. This only requires, relatively inexpensive, 3D wind measurements. The study uses the Saclay tower near Paris, in a mixed urban, forest and agricultural area. Results identified strong heating plant emissions and carbon uptake by the forest. Collaboration between scientific communities is further encouraged, so to better monitor greenhouse gases.
Chen-Wei Liang and Chang-Hung Shen
Atmos. Meas. Tech., 17, 2671–2686, https://doi.org/10.5194/amt-17-2671-2024, https://doi.org/10.5194/amt-17-2671-2024, 2024
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In the present study, a UAV platform with sensing and sampling systems was developed for 3D air pollutant concentration measurements. The sensing system of this platform contains multiple microsensors and IoT technologies for obtaining the real-time 3D distributions of critical air pollutants. The sampling system contains gas sampling sets and a 1 L Tedlar bag instead of a canister for the 3D measurement of VOC concentrations in accordance with the TO-15 method of the US EPA.
Daniel Furuta, Bruce Wilson, Albert A. Presto, and Jiayu Li
Atmos. Meas. Tech., 17, 2103–2121, https://doi.org/10.5194/amt-17-2103-2024, https://doi.org/10.5194/amt-17-2103-2024, 2024
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Methane is an important driver of climate change and is challenging to inexpensively sense in low atmospheric concentrations. We developed a low-cost sensor to monitor methane and tested it in indoor and outdoor settings. Our device shows promise for monitoring low levels of methane. We characterize its limitations and suggest future research directions for further development.
Audrey J. Dang, Nathan M. Kreisberg, Tyler L. Cargill, Jhao-Hong Chen, Sydney Hornitschek, Remy Hutheesing, Jay R. Turner, and Brent J. Williams
Atmos. Meas. Tech., 17, 2067–2087, https://doi.org/10.5194/amt-17-2067-2024, https://doi.org/10.5194/amt-17-2067-2024, 2024
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The Multichannel Organics In situ enviRonmental Analyzer (MOIRA) is a new instrument for measuring speciated volatile organic compounds (VOCs) in the air and has been developed for mapping concentrations from a hybrid car. MOIRA is characterized in the lab and pilot field studies of indoor air in a single-family residence and outdoor air during a mobile deployment. Future applications include indoor, outdoor, and lab measurements to grasp the impact of VOCs on air quality, health, and climate.
Emily Wein, Lars Kalnajs, and Darin Toohey
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-34, https://doi.org/10.5194/amt-2024-34, 2024
Revised manuscript accepted for AMT
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We describe a low cost and small research grade spectrometer for measurements of water vapor in the boundary layer. The instrument uses small Arduino microcontrollers and inexpensive laser diodes to reduce cost while maintaining high performance comparable to more expensive instruments. Performance was assessed with intercomparisons between commercially available instruments outdoors. The design's simplicity, performance and price point allow it to be accessible to a variety of users.
Asher P. Mouat, Zelda A. Siegel, and Jennifer Kaiser
Atmos. Meas. Tech., 17, 1979–1994, https://doi.org/10.5194/amt-17-1979-2024, https://doi.org/10.5194/amt-17-1979-2024, 2024
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Three fast-measurement formaldehyde monitors were deployed at two field sites in Atlanta, GA, over 1 year. Four different zeroing methods were tested to develop an optimal field setup as well as procedures for instrument calibration. Observations agreed well after calibration but were much higher compared to the TO-11A monitoring method, which is the golden standard. Historical HCHO concentrations were compared with measurements in this work, showing a 22 % reduction in midday HCHO since 1999.
Kristen Okorn and Laura T. Iraci
EGUsphere, https://doi.org/10.5194/egusphere-2024-1004, https://doi.org/10.5194/egusphere-2024-1004, 2024
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We reviewed 60 sensor networks and 15 related efforts (sensor review papers and data accessibility projects) to better understand the landscape of stationary low-cost gas-phase sensor networks deployed in outdoor environments worldwide. Gaps in monitoring efforts include the availability of gas-phase measurements compared to particulate matter (PM), and geographic coverage gaps (the global south, rural areas). We conclude with a summary of cross-network unification and quality control efforts.
Da Yang, Margarita Reza, Roy Mauldin, Rainer Volkamer, and Suresh Dhaniyala
Atmos. Meas. Tech., 17, 1463–1474, https://doi.org/10.5194/amt-17-1463-2024, https://doi.org/10.5194/amt-17-1463-2024, 2024
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This paper evaluates the performance of an aircraft gas inlet. Here, we use computational fluid dynamics (CFD) and experiments to demonstrate the role of turbulence in determining sampling performance of a gas inlet and identify ideal conditions for inlet operation to minimize gas loss. Experiments conducted in a high-speed wind tunnel under near-aircraft speeds validated numerical results. We believe that the results obtained from this work will greatly inform future gas inlet studies.
Reena Macagga, Michael Asante, Geoffroy Sossa, Danica Antonijević, Maren Dubbert, and Mathias Hoffmann
Atmos. Meas. Tech., 17, 1317–1332, https://doi.org/10.5194/amt-17-1317-2024, https://doi.org/10.5194/amt-17-1317-2024, 2024
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Using only low-cost microcontrollers and sensors, we constructed a measurement device to accurately and precisely obtain atmospheric carbon dioxide and water fluxes. The device was tested against known concentration increases and high-cost, commercial sensors during a laboratory and field experiment. We additionally tested the device over a longer period in a field study in Ghana during which the net ecosystem carbon balance and water use efficiency of maize cultivation were studied.
Matthew M. Coggon, Chelsea E. Stockwell, Megan S. Claflin, Eva Y. Pfannerstill, Lu Xu, Jessica B. Gilman, Julia Marcantonio, Cong Cao, Kelvin Bates, Georgios I. Gkatzelis, Aaron Lamplugh, Erin F. Katz, Caleb Arata, Eric C. Apel, Rebecca S. Hornbrook, Felix Piel, Francesca Majluf, Donald R. Blake, Armin Wisthaler, Manjula Canagaratna, Brian M. Lerner, Allen H. Goldstein, John E. Mak, and Carsten Warneke
Atmos. Meas. Tech., 17, 801–825, https://doi.org/10.5194/amt-17-801-2024, https://doi.org/10.5194/amt-17-801-2024, 2024
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Mass spectrometry is a tool commonly used to measure air pollutants. This study evaluates measurement artifacts produced in the proton-transfer-reaction mass spectrometer. We provide methods to correct these biases and better measure compounds that degrade air quality.
Tianran Han, Conghui Xie, Yayong Liu, Yanrong Yang, Yuheng Zhang, Yufei Huang, Xiangyu Gao, Xiaohua Zhang, Fangmin Bao, and Shao-Meng Li
Atmos. Meas. Tech., 17, 677–691, https://doi.org/10.5194/amt-17-677-2024, https://doi.org/10.5194/amt-17-677-2024, 2024
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This study reported an integrated UAV measurement platform for GHG monitoring and its application for emission quantification from a coking plant. The key element of this system is a newly designed air sampler, consisting of a 150 m long tube with remote-controlled time stamping. When comparing the top-down results to those derived from the bottom-up inventory method, the present findings indicate that the use of IPCC emission factors for emission calculations can lead to overestimation.
Yuening Li, Faqiang Zhan, Yushan Su, Ying Duan Lei, Chubashini Shunthirasingham, Zilin Zhou, Jonathan P. D. Abbatt, Hayley Hung, and Frank Wania
Atmos. Meas. Tech., 17, 715–729, https://doi.org/10.5194/amt-17-715-2024, https://doi.org/10.5194/amt-17-715-2024, 2024
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A simple device for sampling gases from the atmosphere without the help of pumps was calibrated for an important group of hazardous air pollutants called polycyclic aromatic compounds (PACs). While the sampler appeared to perform well when used for relatively short periods of up to several months, some PACs were lost from the sampler during longer deployments. Sampling rates that can be used to quantitatively interpret the quantities of PACs taken up in the device have been derived.
Jiaxin Li, Kunpeng Zang, Yi Lin, Yuanyuan Chen, Shuo Liu, Shanshan Qiu, Kai Jiang, Xuemei Qing, Haoyu Xiong, Haixiang Hong, Shuangxi Fang, Honghui Xu, and Yujun Jiang
Atmos. Meas. Tech., 16, 4757–4768, https://doi.org/10.5194/amt-16-4757-2023, https://doi.org/10.5194/amt-16-4757-2023, 2023
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Based on observed data of CO2 and CH4 and meteorological parameters over the Yellow Sea in November 2012 and June 2013, a data process and quality control method was optimized and established to filter the data influenced by multiple factors. Spatial and seasonal variations in CO2 and CH4 mixing ratios were mainly controlled by the East Asian Monsoon, while the influence of air–sea exchange was slight.
Zaneta Hamryszczak, Antonia Hartmann, Dirk Dienhart, Sascha Hafermann, Bettina Brendel, Rainer Königstedt, Uwe Parchatka, Jos Lelieveld, and Horst Fischer
Atmos. Meas. Tech., 16, 4741–4756, https://doi.org/10.5194/amt-16-4741-2023, https://doi.org/10.5194/amt-16-4741-2023, 2023
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Hydroperoxide measurements improve the understanding of atmospheric oxidation processes. We introduce an instrumental setup for airborne measurements. The aim of the work is the characterization of the measurement method with emphasis on interferences impacting instrumental uncertainty. Technical and physical challenges do not critically impact the instrumental performance. The instrument resolves dynamic processes, such as convective transport, as shown based on the CAFE-Brazil campaign.
James F. Hurley, Alejandra Caceres, Deborah F. McGlynn, Mary E. Tovillo, Suzanne Pinar, Roger Schürch, Ksenia Onufrieva, and Gabriel Isaacman-VanWertz
Atmos. Meas. Tech., 16, 4681–4692, https://doi.org/10.5194/amt-16-4681-2023, https://doi.org/10.5194/amt-16-4681-2023, 2023
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Volatile organic compounds (VOCs) have a wide range of sources and impacts on environments and human health that make them spatially, temporally, and chemically varied. Current methods lack the ability to collect samples in ways that provide spatial and chemical resolution without complex, costly instrumentation. We describe and validate a low-cost, portable VOC sampler and demonstrate its utility in collecting distributed coordinated samples.
Simone Brunamonti, Manuel Graf, Tobias Bühlmann, Céline Pascale, Ivan Ilak, Lukas Emmenegger, and Béla Tuzson
Atmos. Meas. Tech., 16, 4391–4407, https://doi.org/10.5194/amt-16-4391-2023, https://doi.org/10.5194/amt-16-4391-2023, 2023
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The abundance of water vapor (H2O) in the upper atmosphere has a significant impact on the rate of global warming. We developed a new lightweight spectrometer (ALBATROSS) for H2O measurements aboard meteorological balloons. Here, we assess the accuracy and precision of ALBATROSS using metrology-grade reference gases. The results demonstrate the exceptional potential of mid-infrared laser absorption spectroscopy as a new reference method for in situ measurements of H2O in the upper atmosphere.
Roubina Papaconstantinou, Marios Demosthenous, Spyros Bezantakos, Neoclis Hadjigeorgiou, Marinos Costi, Melina Stylianou, Elli Symeou, Chrysanthos Savvides, and George Biskos
Atmos. Meas. Tech., 16, 3313–3329, https://doi.org/10.5194/amt-16-3313-2023, https://doi.org/10.5194/amt-16-3313-2023, 2023
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In this paper, we investigate the performance of low-cost electrochemical gas sensors. We carried out yearlong measurements at a traffic air quality monitoring station, where the low-cost sensors were collocated with reference instruments and exposed to highly variable environmental conditions with extremely high temperatures and low relative humidity (RH). Sensors provide measurements that exhibit increasing errors and decreasing correlations as temperature increases and RH decreases.
Jianghanyang Li, Bianca C. Baier, Fred Moore, Tim Newberger, Sonja Wolter, Jack Higgs, Geoff Dutton, Eric Hintsa, Bradley Hall, and Colm Sweeney
Atmos. Meas. Tech., 16, 2851–2863, https://doi.org/10.5194/amt-16-2851-2023, https://doi.org/10.5194/amt-16-2851-2023, 2023
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Monitoring a suite of trace gases in the stratosphere will help us better understand the stratospheric circulation and its impact on the earth's radiation balance. However, such measurements are rare and usually expensive. We developed an instrument that can measure stratospheric trace gases using a low-cost sampling platform (AirCore). The results showed expected agreement with aircraft measurements, demonstrating this technique provides a low-cost and robust way to observe the stratosphere.
Tara I. Yacovitch, Christoph Dyroff, Joseph R. Roscioli, Conner Daube, J. Barry McManus, and Scott C. Herndon
Atmos. Meas. Tech., 16, 1915–1921, https://doi.org/10.5194/amt-16-1915-2023, https://doi.org/10.5194/amt-16-1915-2023, 2023
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Ethylene oxide is a toxic, carcinogenic compound used in the medical and bulk sterilization industry. Here we describe a precise and fast laser-based ethylene oxide monitor. We report months-long concentrations at a Massachusetts site, and we show how they suggest a potential emission source 35 km away. This source, and another, is confirmed by driving the instrument downwind of the sites, where concentrations were tens to tens of thousands of times greater than background levels.
Tatsumi Nakano and Takashi Morofuji
Atmos. Meas. Tech., 16, 1583–1595, https://doi.org/10.5194/amt-16-1583-2023, https://doi.org/10.5194/amt-16-1583-2023, 2023
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We have developed a system that can automatically measure the pump efficiency of the ECC-type ozonesonde. Operational measurement for 13 years by this system revealed that the efficiency fluctuates in each and slightly increases over time. Those can affect the estimation of total ozone amount by up to 4 %. This result indicates that it is necessary to understand the tendency of the pump correction factor of each ozonesonde in order to detect the actual atmospheric change with high accuracy.
Benjamin Birner, Eric Morgan, and Ralph F. Keeling
Atmos. Meas. Tech., 16, 1551–1561, https://doi.org/10.5194/amt-16-1551-2023, https://doi.org/10.5194/amt-16-1551-2023, 2023
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Atmospheric variations of helium (He) and CO2 are strongly linked due to the co-release of both gases from natural-gas burning. This implies that atmospheric He measurements may be a potentially powerful tool for verifying reported anthropogenic natural-gas usage. Here, we present the development and initial results of a novel measurement system of atmospheric He that paves the way for establishing a global monitoring network in the future.
John W. Halfacre, Jordan Stewart, Scott C. Herndon, Joseph R. Roscioli, Christoph Dyroff, Tara I. Yacovitch, Michael Flynn, Stephen J. Andrews, Steven S. Brown, Patrick R. Veres, and Pete M. Edwards
Atmos. Meas. Tech., 16, 1407–1429, https://doi.org/10.5194/amt-16-1407-2023, https://doi.org/10.5194/amt-16-1407-2023, 2023
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This study details a new sampling method for the optical detection of hydrogen chloride (HCl). HCl is an important atmospheric reservoir for chlorine atoms, which can affect nitrogen oxide cycling and the lifetimes of volatile organic compounds and ozone. However, HCl has a high affinity for interacting with surfaces, thereby preventing fast, quantitative measurements. The sampling technique in this study minimizes these surface interactions and provides a high-quality measurement of HCl.
Henning Finkenzeller, Denis Pöhler, Martin Horbanski, Johannes Lampel, and Ulrich Platt
Atmos. Meas. Tech., 16, 1343–1356, https://doi.org/10.5194/amt-16-1343-2023, https://doi.org/10.5194/amt-16-1343-2023, 2023
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Optical resonators enhance the light path in compact instruments, thereby improving their sensitivity. Determining the established path length in the instrument is a prerequisite for the accurate determination of trace gas concentrations but can be a significant complication in the use of such resonators. Here we show two calibration techniques which are relatively simple and free of consumables but still provide accurate calibrations. This facilitates the use of optical resonators.
Andrew W. Seidl, Harald Sodemann, and Hans Christian Steen-Larsen
Atmos. Meas. Tech., 16, 769–790, https://doi.org/10.5194/amt-16-769-2023, https://doi.org/10.5194/amt-16-769-2023, 2023
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It is challenging to make field measurements of stable water isotopes in the Arctic. To this end, we present a modular stable-water-isotope analyzer profiling system. The system operated for a 2-week field campaign on Svalbard during the Arctic winter. We evaluate the system’s performance and analyze any potential impact that the field conditions might have had on the isotopic measurements and the system's ability to resolve isotope gradients in the lowermost layer of the atmosphere.
Daan Swart, Jun Zhang, Shelley van der Graaf, Susanna Rutledge-Jonker, Arjan Hensen, Stijn Berkhout, Pascal Wintjen, René van der Hoff, Marty Haaima, Arnoud Frumau, Pim van den Bulk, Ruben Schulte, Margreet van Zanten, and Thomas van Goethem
Atmos. Meas. Tech., 16, 529–546, https://doi.org/10.5194/amt-16-529-2023, https://doi.org/10.5194/amt-16-529-2023, 2023
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During a 5-week comparison campaign, we tested two set-ups to measure half hourly ammonia fluxes. The eddy covariance and flux gradient systems showed very similar results when the upwind terrain was both homogeneous and free of obstacles. We discuss the technical performance and practical limitations of both systems. Measurements from these instruments can facilitate the study of processes behind ammonia deposition, an important contributor to eutrophication and acidificationin natural areas.
Suding Yang, Xin Li, Limin Zeng, Xuena Yu, Ying Liu, Sihua Lu, Xiaofeng Huang, Dongmei Zhang, Haibin Xu, Shuchen Lin, Hefan Liu, Miao Feng, Danlin Song, Qinwen Tan, Jinhui Cui, Lifan Wang, Ying Chen, Wenjie Wang, Haijiong Sun, Mengdi Song, Liuwei Kong, Yi Liu, Linhui Wei, Xianwu Zhu, and Yuanhang Zhang
Atmos. Meas. Tech., 16, 501–512, https://doi.org/10.5194/amt-16-501-2023, https://doi.org/10.5194/amt-16-501-2023, 2023
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Vertical observation of volatile organic compounds (VOCs) is essential to study the spatial distribution and evolution patterns of VOCs in the planetary boundary layer (PBL). This paper describes multi-channel whole-air sampling equipment onboard an unmanned aerial vehicle (UAV) for near-continuous VOC vertical observation. Vertical profiles of VOCs and trace gases during the evolution of the PBL in south-western China have been successfully obtained by deploying the newly developed UAV system.
Tobias Schuldt, Georgios I. Gkatzelis, Christian Wesolek, Franz Rohrer, Benjamin Winter, Thomas A. J. Kuhlbusch, Astrid Kiendler-Scharr, and Ralf Tillmann
Atmos. Meas. Tech., 16, 373–386, https://doi.org/10.5194/amt-16-373-2023, https://doi.org/10.5194/amt-16-373-2023, 2023
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We report in situ measurements of air pollutant concentrations within the planetary boundary layer on board a Zeppelin NT in Germany. We highlight the in-flight evaluation of electrochemical sensors that were installed inside a hatch box located on the bottom of the Zeppelin. Results from this work emphasize the potential of these sensors for other in situ airborne applications, e.g., on board unmanned aerial vehicles (UAVs).
Leigh S. Fleming, Andrew C. Manning, Penelope A. Pickers, Grant L. Forster, and Alex J. Etchells
Atmos. Meas. Tech., 16, 387–401, https://doi.org/10.5194/amt-16-387-2023, https://doi.org/10.5194/amt-16-387-2023, 2023
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Measurements of atmospheric O2 can help constrain the carbon cycle processes and quantify fossil fuel CO2 emissions; however, measurement of atmospheric O2 is very challenging, and existing analysers are complex systems to build and maintain. We have tested a new O2 analyser (Picarro Inc. G2207-i) in the laboratory and at Weybourne Atmospheric Observatory. We have found that the G2207-i does not perform as well as an existing O2 analyser from Sable Systems Inc.
Siegfried Schobesberger, Emma L. D'Ambro, Lejish Vettikkat, Ben H. Lee, Qiaoyun Peng, David M. Bell, John E. Shilling, Manish Shrivastava, Mikhail Pekour, Jerome Fast, and Joel A. Thornton
Atmos. Meas. Tech., 16, 247–271, https://doi.org/10.5194/amt-16-247-2023, https://doi.org/10.5194/amt-16-247-2023, 2023
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We present a new, highly sensitive technique for measuring atmospheric ammonia, an important trace gas that is emitted mainly by agriculture. We deployed the instrument on an aircraft during research flights over rural Oklahoma. Due to its fast response, we could analyze correlations with turbulent winds and calculate ammonia emissions from nearby areas at 1 to 2 km resolution. We observed high spatial variability and point sources that are not resolved in the US National Emissions Inventory.
Birger Bohn and Insa Lohse
Atmos. Meas. Tech., 16, 209–233, https://doi.org/10.5194/amt-16-209-2023, https://doi.org/10.5194/amt-16-209-2023, 2023
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Optical receivers for solar spectral actinic radiation are designed for angle-independent sensitivities within a hemisphere. Remaining imperfections can be compensated for by receiver-specific corrections based on laboratory characterizations and radiative transfer calculations of spectral radiance distributions. The corrections cover a wide range of realistic atmospheric conditions and were applied to ground-based and airborne measurements in a wavelength range 280–660 nm.
Teles C. Furlani, RenXi Ye, Jordan Stewart, Leigh R. Crilley, Peter M. Edwards, Tara F. Kahan, and Cora J. Young
Atmos. Meas. Tech., 16, 181–193, https://doi.org/10.5194/amt-16-181-2023, https://doi.org/10.5194/amt-16-181-2023, 2023
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This study describes a new technique to measure total gaseous chlorine, which is the sum of gas-phase chlorine-containing chemicals. The method converts any chlorine-containing molecule to hydrogen chloride that can be detected in real time using a cavity ring-down spectrometer. The new method was validated through laboratory experiments, as well as by making measurements of ambient outdoor air and indoor air during cleaning with a chlorine-based cleaner.
Anas Emad and Lukas Siebicke
Atmos. Meas. Tech., 16, 29–40, https://doi.org/10.5194/amt-16-29-2023, https://doi.org/10.5194/amt-16-29-2023, 2023
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The true eddy accumulation (TEA) method enables measuring atmospheric exchange with slow-response gas analyzers. TEA is formulated assuming ideal conditions with a zero mean vertical wind velocity during the averaging interval. This core assumption is rarely valid under field conditions. Here, we extend the TEA equation to accommodate nonideal conditions. The new equation allows constraining the systematic error term in the measured fluxes and the possibility to minimize or remove it.
Anas Emad and Lukas Siebicke
Atmos. Meas. Tech., 16, 41–55, https://doi.org/10.5194/amt-16-41-2023, https://doi.org/10.5194/amt-16-41-2023, 2023
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A new micrometeorological method to measure atmospheric exchange is proposed, and a prototype sampler is evaluated. The new method, called short-time eddy accumulation, is a variant of the eddy accumulation method, which is suited for use with slow gas analyzers. The new method enables adaptive time-varying accumulation intervals, which brings many advantages to flux measurements such as an improved dynamic range and the ability to run eddy accumulation in a continuous flow-through mode.
Lu Xu, Matthew M. Coggon, Chelsea E. Stockwell, Jessica B. Gilman, Michael A. Robinson, Martin Breitenlechner, Aaron Lamplugh, John D. Crounse, Paul O. Wennberg, J. Andrew Neuman, Gordon A. Novak, Patrick R. Veres, Steven S. Brown, and Carsten Warneke
Atmos. Meas. Tech., 15, 7353–7373, https://doi.org/10.5194/amt-15-7353-2022, https://doi.org/10.5194/amt-15-7353-2022, 2022
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We describe the development and operation of a chemical ionization mass spectrometer using an ammonium–water cluster (NH4+·H2O) as a reagent ion. NH4+·H2O is a highly versatile reagent ion for measurements of a wide range of oxygenated organic compounds. The major product ion is the cluster with NH4+ produced via ligand-switching reactions. The instrumental sensitivities of analytes depend on the binding energy of the analyte–NH4+ cluster; sensitivities can be estimated using voltage scanning.
Cited articles
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Alphasense Ltd: Environmental changes: temperature, pressure, humidity, Tech. Rep. AAN 110, Great Notley, UK, available at: http://www.alphasense.com/WEB1213/wp-content/uploads/2013/07/AAN_110.pdf, last access: 20 June 2018, 2017.
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Short summary
Low cost sensors for monitoring atmospheric pollution are growing in popularity worldwide. Nonetheless, the expectations from these devices were seldom met, thus urging for more research. This study focuses on sensor performance within the realistic framework of an initial calibration next to a reference instrument and the subsequent distant deployment. Within this framework, we assessed the uncertainty of these sensors and their suitability to map intra-urban gradients of NO/NO2.
Low cost sensors for monitoring atmospheric pollution are growing in popularity worldwide....
