Articles | Volume 11, issue 9
Atmos. Meas. Tech., 11, 5335–5350, 2018
https://doi.org/10.5194/amt-11-5335-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Atmos. Meas. Tech., 11, 5335–5350, 2018
https://doi.org/10.5194/amt-11-5335-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
25 Sep 2018
Research article
| 25 Sep 2018
Measuring turbulent CO2 fluxes with a closed-path gas analyzer in a marine environment
Martti Honkanen et al.
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Ocean Sci., 17, 1657–1675, https://doi.org/10.5194/os-17-1657-2021, https://doi.org/10.5194/os-17-1657-2021, 2021
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The exchange of carbon dioxide (CO2) between the sea and the atmosphere is regulated by the gradient of CO2 partial pressure (pCO2) between the sea and the air. The daily variation of the seawater pCO2 recorded at the fixed station Utö in the Baltic Sea was found to be mainly biologically driven. Calculation of the annual net exchange of CO2 between the sea and atmosphere based on daily measurements of pCO2 carried out using the same sampling time every day could introduce a bias of up to 12 %.
Matti Räsänen, Mika Aurela, Ville Vakkari, Johan P. Beukes, Juha-Pekka Tuovinen, Pieter G. Van Zyl, Miroslav Josipovic, Stefan J. Siebert, Tuomas Laurila, Markku Kulmala, Lauri Laakso, Janne Rinne, Ram Oren, and Gabriel Katul
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The productivity of semiarid grazed grasslands is linked to the variation in rainfall and transpiration. By combining carbon dioxide and water flux measurements, we show that the annual transpiration is nearly constant during wet years while grasses react quickly to dry spells and drought, which reduce transpiration. The planning of annual grazing strategies could consider the early-season rainfall frequency that was linked to the portion of annual transpiration.
Maiju Linkosalmi, Juha-Pekka Tuovinen, Olli Nevalainen, Mikko Peltoniemi, Cemal M. Taniş, Ali N. Arslan, Juuso Rainne, Annalea Lohila, Tuomas Laurila, and Mika Aurela
Biogeosciences, 19, 4747–4765, https://doi.org/10.5194/bg-19-4747-2022, https://doi.org/10.5194/bg-19-4747-2022, 2022
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Vegetation greenness was monitored with digital cameras in three northern peatlands during five growing seasons. The greenness index derived from the images was highest at the most nutrient-rich site. Greenness indicated the main phases of phenology and correlated with CO2 uptake, though this was mainly related to the common seasonal cycle. The cameras and Sentinel-2 satellite showed consistent results, but more frequent satellite data are needed for reliable detection of phenological phases.
Sari Juutinen, Mika Aurela, Juha-Pekka Tuovinen, Viktor Ivakhov, Maiju Linkosalmi, Aleksi Räsänen, Tarmo Virtanen, Juha Mikola, Johanna Nyman, Emmi Vähä, Marina Loskutova, Alexander Makshtas, and Tuomas Laurila
Biogeosciences, 19, 3151–3167, https://doi.org/10.5194/bg-19-3151-2022, https://doi.org/10.5194/bg-19-3151-2022, 2022
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We measured CO2 and CH4 fluxes in heterogenous Arctic tundra in eastern Siberia. We found that tundra wetlands with sedge and grass vegetation contributed disproportionately to the landscape's ecosystem CO2 uptake and CH4 emissions to the atmosphere. Moreover, we observed high CH4 consumption in dry tundra, particularly in barren areas, offsetting part of the CH4 emissions from the wetlands.
Matti Kämäräinen, Anna Lintunen, Markku Kulmala, Juha-Pekka Tuovinen, Ivan Mammarella, Juha Aalto, Henriikka Vekuri, and Annalea Lohila
Biogeosciences Discuss., https://doi.org/10.5194/bg-2022-108, https://doi.org/10.5194/bg-2022-108, 2022
Revised manuscript under review for BG
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In this work we present an alternative machine learning approach to model the exchange of carbon between the atmosphere and the study site, located in a boreal forest in Southern Finland. The suggested method produces more accurate results than another which has been widely used previously in this context. Accurate estimations of the exchange of carbon are needed for better understanding of the role of forests in regulating atmospheric carbon and climate change.
Lauri Heiskanen, Juha-Pekka Tuovinen, Aleksi Räsänen, Tarmo Virtanen, Sari Juutinen, Henriikka Vekuri, Annalea Lohila, Juha Mikola, and Mika Aurela
Biogeosciences Discuss., https://doi.org/10.5194/bg-2022-69, https://doi.org/10.5194/bg-2022-69, 2022
Revised manuscript accepted for BG
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We measured and modelled the CO2 and CH4 fluxes of the terrestrial and aquatic ecosystems of the subarctic landscape for two years. The landscape was an annual CO2 sink and a CH4 source. The forest had the largest contribution to the landscape-level CO2 sink and the peatland to the CH4 emissions. The lakes released 20 % of the annual net C uptake of the landscape back to the atmosphere. The C fluxes were affected most by the rainy peak growing season of 2017 and the drought event in July 2018.
Olli Nevalainen, Olli Niemitalo, Istem Fer, Antti Juntunen, Tuomas Mattila, Olli Koskela, Joni Kukkamäki, Layla Höckerstedt, Laura Mäkelä, Pieta Jarva, Laura Heimsch, Henriikka Vekuri, Liisa Kulmala, Åsa Stam, Otto Kuusela, Stephanie Gerin, Toni Viskari, Julius Vira, Jari Hyväluoma, Juha-Pekka Tuovinen, Annalea Lohila, Tuomas Laurila, Jussi Heinonsalo, Tuula Aalto, Iivari Kunttu, and Jari Liski
Geosci. Instrum. Method. Data Syst., 11, 93–109, https://doi.org/10.5194/gi-11-93-2022, https://doi.org/10.5194/gi-11-93-2022, 2022
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Better monitoring of soil carbon sequestration is needed to understand the best carbon farming practices in different soils and climate conditions. We, the Field Observatory Network (FiON), have therefore established a methodology for monitoring and forecasting agricultural carbon sequestration by combining offline and near-real-time field measurements, weather data, satellite imagery, and modeling. To disseminate our work, we built a website called the Field Observatory (fieldobservatory.org).
Anna-Maria Virkkala, Susan M. Natali, Brendan M. Rogers, Jennifer D. Watts, Kathleen Savage, Sara June Connon, Marguerite Mauritz, Edward A. G. Schuur, Darcy Peter, Christina Minions, Julia Nojeim, Roisin Commane, Craig A. Emmerton, Mathias Goeckede, Manuel Helbig, David Holl, Hiroki Iwata, Hideki Kobayashi, Pasi Kolari, Efrén López-Blanco, Maija E. Marushchak, Mikhail Mastepanov, Lutz Merbold, Frans-Jan W. Parmentier, Matthias Peichl, Torsten Sachs, Oliver Sonnentag, Masahito Ueyama, Carolina Voigt, Mika Aurela, Julia Boike, Gerardo Celis, Namyi Chae, Torben R. Christensen, M. Syndonia Bret-Harte, Sigrid Dengel, Han Dolman, Colin W. Edgar, Bo Elberling, Eugenie Euskirchen, Achim Grelle, Juha Hatakka, Elyn Humphreys, Järvi Järveoja, Ayumi Kotani, Lars Kutzbach, Tuomas Laurila, Annalea Lohila, Ivan Mammarella, Yojiro Matsuura, Gesa Meyer, Mats B. Nilsson, Steven F. Oberbauer, Sang-Jong Park, Roman Petrov, Anatoly S. Prokushkin, Christopher Schulze, Vincent L. St. Louis, Eeva-Stiina Tuittila, Juha-Pekka Tuovinen, William Quinton, Andrej Varlagin, Donatella Zona, and Viacheslav I. Zyryanov
Earth Syst. Sci. Data, 14, 179–208, https://doi.org/10.5194/essd-14-179-2022, https://doi.org/10.5194/essd-14-179-2022, 2022
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The effects of climate warming on carbon cycling across the Arctic–boreal zone (ABZ) remain poorly understood due to the relatively limited distribution of ABZ flux sites. Fortunately, this flux network is constantly increasing, but new measurements are published in various platforms, making it challenging to understand the ABZ carbon cycle as a whole. Here, we compiled a new database of Arctic–boreal CO2 fluxes to help facilitate large-scale assessments of the ABZ carbon cycle.
Jari Walden, Liisa Pirjola, Tuomas Laurila, Juha Hatakka, Heidi Pettersson, Tuomas Walden, Jukka-Pekka Jalkanen, Harri Nordlund, Toivo Truuts, Miika Meretoja, and Kimmo K. Kahma
Atmos. Chem. Phys., 21, 18175–18194, https://doi.org/10.5194/acp-21-18175-2021, https://doi.org/10.5194/acp-21-18175-2021, 2021
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Ship emissions play an important role in the deposition of gaseous compounds and nanoparticles (Ntot), affecting climate, human health (especially in coastal areas), and eutrophication. Micrometeorological methods showed that ship emissions were mainly responsible for the deposition of Ntot, whereas they only accounted for a minor proportion of CO2 deposition. An uncertainty analysis applied to the fluxes and fuel sulfur content results demonstrated the reliability of the results.
Martti Honkanen, Jens Daniel Müller, Jukka Seppälä, Gregor Rehder, Sami Kielosto, Pasi Ylöstalo, Timo Mäkelä, Juha Hatakka, and Lauri Laakso
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The exchange of carbon dioxide (CO2) between the sea and the atmosphere is regulated by the gradient of CO2 partial pressure (pCO2) between the sea and the air. The daily variation of the seawater pCO2 recorded at the fixed station Utö in the Baltic Sea was found to be mainly biologically driven. Calculation of the annual net exchange of CO2 between the sea and atmosphere based on daily measurements of pCO2 carried out using the same sampling time every day could introduce a bias of up to 12 %.
Laura Heimsch, Annalea Lohila, Juha-Pekka Tuovinen, Henriikka Vekuri, Jussi Heinonsalo, Olli Nevalainen, Mika Korkiakoski, Jari Liski, Tuomas Laurila, and Liisa Kulmala
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CO2 and H2O fluxes were measured at a newly established eddy covariance site in southern Finland for 2 years from 2018 to 2020. This agricultural grassland site focuses on the conversion from intensive towards more sustainable agricultural management. The first summer experienced prolonged dry periods, and notably larger fluxes were observed in the second summer. The field acted as a net carbon sink during both study years.
Thomas Thorp, Stephen R. Arnold, Richard J. Pope, Dominick V. Spracklen, Luke Conibear, Christoph Knote, Mikhail Arshinov, Boris Belan, Eija Asmi, Tuomas Laurila, Andrei I. Skorokhod, Tuomo Nieminen, and Tuukka Petäjä
Atmos. Chem. Phys., 21, 4677–4697, https://doi.org/10.5194/acp-21-4677-2021, https://doi.org/10.5194/acp-21-4677-2021, 2021
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We compare modelled near-surface pollutants with surface and satellite observations to better understand the controls on the regional concentrations of pollution in western Siberia for late spring and summer in 2011. We find two commonly used emission inventories underestimate human emissions when compared to observations. Transport emissions are the main source of pollutants within the region during this period, whilst fire emissions peak during June and are only significant south of 60° N.
Lauri Heiskanen, Juha-Pekka Tuovinen, Aleksi Räsänen, Tarmo Virtanen, Sari Juutinen, Annalea Lohila, Timo Penttilä, Maiju Linkosalmi, Juha Mikola, Tuomas Laurila, and Mika Aurela
Biogeosciences, 18, 873–896, https://doi.org/10.5194/bg-18-873-2021, https://doi.org/10.5194/bg-18-873-2021, 2021
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We studied ecosystem- and plant-community-level carbon (C) exchange between subarctic mire and the atmosphere during 2017–2018. We found strong spatial variation in CO2 and CH4 dynamics between the main plant communities. The earlier onset of growing season in 2018 strengthened the CO2 sink of the ecosystem, but this gain was counterbalanced by a later drought period. Variation in water table level, soil temperature and vegetation explained most of the variation in ecosystem-level C exchange.
Camille Yver-Kwok, Carole Philippon, Peter Bergamaschi, Tobias Biermann, Francescopiero Calzolari, Huilin Chen, Sebastien Conil, Paolo Cristofanelli, Marc Delmotte, Juha Hatakka, Michal Heliasz, Ove Hermansen, Kateřina Komínková, Dagmar Kubistin, Nicolas Kumps, Olivier Laurent, Tuomas Laurila, Irene Lehner, Janne Levula, Matthias Lindauer, Morgan Lopez, Ivan Mammarella, Giovanni Manca, Per Marklund, Jean-Marc Metzger, Meelis Mölder, Stephen M. Platt, Michel Ramonet, Leonard Rivier, Bert Scheeren, Mahesh Kumar Sha, Paul Smith, Martin Steinbacher, Gabriela Vítková, and Simon Wyss
Atmos. Meas. Tech., 14, 89–116, https://doi.org/10.5194/amt-14-89-2021, https://doi.org/10.5194/amt-14-89-2021, 2021
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The Integrated Carbon Observation System (ICOS) is a pan-European research infrastructure which provides harmonized and high-precision scientific data on the carbon cycle and the greenhouse gas (GHG) budget. All stations have to undergo a rigorous assessment before being labeled, i.e., receiving approval to join the network. In this paper, we present the labeling process for the ICOS atmospheric network through the 23 stations that were labeled between November 2017 and November 2019.
Hui Zhang, Eeva-Stiina Tuittila, Aino Korrensalo, Aleksi Räsänen, Tarmo Virtanen, Mika Aurela, Timo Penttilä, Tuomas Laurila, Stephanie Gerin, Viivi Lindholm, and Annalea Lohila
Biogeosciences, 17, 6247–6270, https://doi.org/10.5194/bg-17-6247-2020, https://doi.org/10.5194/bg-17-6247-2020, 2020
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We studied the impact of a stream on peatland microhabitats and CH4 emissions in a northern boreal fen. We found that there were higher water levels, lower peat temperatures, and greater oxygen concentrations close to the stream; these supported the highest biomass production but resulted in the lowest CH4 emissions. Further from the stream, the conditions were drier and CH4 emissions were also low. CH4 emissions were highest at an intermediate distance from the stream.
Joel Kuula, Timo Mäkelä, Minna Aurela, Kimmo Teinilä, Samu Varjonen, Óscar González, and Hilkka Timonen
Atmos. Meas. Tech., 13, 2413–2423, https://doi.org/10.5194/amt-13-2413-2020, https://doi.org/10.5194/amt-13-2413-2020, 2020
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Particle-size-dependent detection ranges of low-cost particulate matter sensors were evaluated in a laboratory experiment. Six different sensor models were evaluated altogether. The results showed that none of the sensor models adhered to the technical specifications provided by the manufacturers, and thus a high risk of sensor misuse is posed. It is paramount that the limitations regarding the particle size discrimination of low-cost sensors are acknowledged properly.
Matti Räsänen, Mika Aurela, Ville Vakkari, Johan P. Beukes, Juha-Pekka Tuovinen, Pieter G. Van Zyl, Miroslav Josipovic, Stefan J. Siebert, Tuomas Laurila, Markku Kulmala, Lauri Laakso, Janne Rinne, Ram Oren, and Gabriel Katul
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2019-651, https://doi.org/10.5194/hess-2019-651, 2020
Revised manuscript not accepted
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The annual ET is approximately equal to precipitation during six measured years for grazed savanna grassland. The computed annual transpiration was highly constrained when rainfall was near or above the long-term mean but was reduced during severe drought year. The developed methodologies can be used in a wide range of arid and semi-arid ecosystems.
Mika Korkiakoski, Juha-Pekka Tuovinen, Timo Penttilä, Sakari Sarkkola, Paavo Ojanen, Kari Minkkinen, Juuso Rainne, Tuomas Laurila, and Annalea Lohila
Biogeosciences, 16, 3703–3723, https://doi.org/10.5194/bg-16-3703-2019, https://doi.org/10.5194/bg-16-3703-2019, 2019
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We measured greenhouse gas and energy fluxes for 2 years after clear-cutting in a peatland forest. We found high carbon dioxide and nitrous oxide emissions. However, in the second year after clear-cutting, the carbon dioxide emissions had already decreased by 33 % from the first year. Also, clear-cutting turned the site from a methane sink into a methane source. We conclude that clear-cutting peatland forests exerts a strong climatic warming effect through accelerated emission of greenhouse gas.
Juha-Pekka Tuovinen, Mika Aurela, Juha Hatakka, Aleksi Räsänen, Tarmo Virtanen, Juha Mikola, Viktor Ivakhov, Vladimir Kondratyev, and Tuomas Laurila
Biogeosciences, 16, 255–274, https://doi.org/10.5194/bg-16-255-2019, https://doi.org/10.5194/bg-16-255-2019, 2019
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We analysed ecosystem-scale measurements of methane exchange between Arctic tundra and the atmosphere, taking into account the large variations in vegetation and soil properties. The measurements are spatial averages, but using meteorological and statistical modelling techniques we could estimate methane emissions for different land cover types and quantify how well the measurements correspond to the spatial variability. This provides a more accurate estimate of the regional methane emission.
Tracey Leah Laban, Pieter Gideon van Zyl, Johan Paul Beukes, Ville Vakkari, Kerneels Jaars, Nadine Borduas-Dedekind, Miroslav Josipovic, Anne Mee Thompson, Markku Kulmala, and Lauri Laakso
Atmos. Chem. Phys., 18, 15491–15514, https://doi.org/10.5194/acp-18-15491-2018, https://doi.org/10.5194/acp-18-15491-2018, 2018
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Surface O3 was measured at four sites in the north-eastern interior of South Africa, which revealed that O3 is a regional problem in continental South Africa, with elevated O3 levels found at rural background and industrial sites. Increased O3 concentrations were associated with high CO levels predominantly related to regional biomass burning, while the O3 production regime was established to be predominantly VOC limited. Increased O3 is associated with strong seasonality of precursor sources.
Ulpu Leijala, Jan-Victor Björkqvist, Milla M. Johansson, Havu Pellikka, Lauri Laakso, and Kimmo K. Kahma
Nat. Hazards Earth Syst. Sci., 18, 2785–2799, https://doi.org/10.5194/nhess-18-2785-2018, https://doi.org/10.5194/nhess-18-2785-2018, 2018
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The coastal flooding risks based on the combined effect of sea level variations and wind-generated waves are estimated for the present, 2050 and 2100. The variability of the wave conditions between the two case study locations in the Helsinki archipelago leads to a difference in the safe building levels of up to 1 m. The rising mean sea level in the Gulf of Finland and the uncertainty of the associated scenarios contribute to the flooding risks notably in 2100.
Tuomo Nieminen, Veli-Matti Kerminen, Tuukka Petäjä, Pasi P. Aalto, Mikhail Arshinov, Eija Asmi, Urs Baltensperger, David C. S. Beddows, Johan Paul Beukes, Don Collins, Aijun Ding, Roy M. Harrison, Bas Henzing, Rakesh Hooda, Min Hu, Urmas Hõrrak, Niku Kivekäs, Kaupo Komsaare, Radovan Krejci, Adam Kristensson, Lauri Laakso, Ari Laaksonen, W. Richard Leaitch, Heikki Lihavainen, Nikolaos Mihalopoulos, Zoltán Németh, Wei Nie, Colin O'Dowd, Imre Salma, Karine Sellegri, Birgitta Svenningsson, Erik Swietlicki, Peter Tunved, Vidmantas Ulevicius, Ville Vakkari, Marko Vana, Alfred Wiedensohler, Zhijun Wu, Annele Virtanen, and Markku Kulmala
Atmos. Chem. Phys., 18, 14737–14756, https://doi.org/10.5194/acp-18-14737-2018, https://doi.org/10.5194/acp-18-14737-2018, 2018
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Atmospheric aerosols have diverse effects on air quality, human health, and global climate. One important source of aerosols is their formation via nucleation and growth in the atmosphere. We have analyzed long-term observations of regional new particle formation events around the globe and provide a comprehensive view on the characteristics of this phenomenon in diverse environments. The results are useful in developing more realistic representation of atmospheric aerosols in global models.
Lauri Laakso, Santtu Mikkonen, Achim Drebs, Anu Karjalainen, Pentti Pirinen, and Pekka Alenius
Ocean Sci., 14, 617–632, https://doi.org/10.5194/os-14-617-2018, https://doi.org/10.5194/os-14-617-2018, 2018
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Meteorological observations at Utö Atmospheric and Marine Research Station, the Baltic Sea, started in 1881 and seawater temperature and salinity observations in 1900. Based on the dataset of more than 100 years of observations, we see an increase in atmospheric temperature after the 1980s, in line with reduced sea ice cover. We also found an increase in seawater temperatures, modulated by changes in salinities. The results indicate that the climate at Utö may have shifted into a new phase.
Kari Minkkinen, Paavo Ojanen, Timo Penttilä, Mika Aurela, Tuomas Laurila, Juha-Pekka Tuovinen, and Annalea Lohila
Biogeosciences, 15, 3603–3624, https://doi.org/10.5194/bg-15-3603-2018, https://doi.org/10.5194/bg-15-3603-2018, 2018
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Drainage often turns peatlands into C sources. We measured C dynamics of a drained forested boreal peatland over 4 years, including one with a drought during growing season. The drained peatland ecosystem was a strong sink of C in all studied years. Also, the peat soil sequestered C. A drought period in one summer significantly decreased C sequestration through decreased gross primary production, but since the drought also decreased ecosystem respiration, the site remained a C sink.
Juha Mikola, Tarmo Virtanen, Maiju Linkosalmi, Emmi Vähä, Johanna Nyman, Olga Postanogova, Aleksi Räsänen, D. Johan Kotze, Tuomas Laurila, Sari Juutinen, Vladimir Kondratyev, and Mika Aurela
Biogeosciences, 15, 2781–2801, https://doi.org/10.5194/bg-15-2781-2018, https://doi.org/10.5194/bg-15-2781-2018, 2018
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To support C exchange measurements, we examined plant and soil attributes in Siberian Arctic tundra. Our results illustrate a typical tundra ecosystem with great spatial variation. Mosses dominate plant biomass and control many soil attributes such as temperature, but variation in moss biomass is difficult to capture by remote sensing. This indicates challenges in spatial extrapolation of some of those plant and soil attributes that are relevant for regional ecosystem and global climate models.
Mikko Peltoniemi, Mika Aurela, Kristin Böttcher, Pasi Kolari, John Loehr, Jouni Karhu, Maiju Linkosalmi, Cemal Melih Tanis, Juha-Pekka Tuovinen, and Ali Nadir Arslan
Earth Syst. Sci. Data, 10, 173–184, https://doi.org/10.5194/essd-10-173-2018, https://doi.org/10.5194/essd-10-173-2018, 2018
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Monitoring ecosystems using low-cost time lapse cameras has gained wide interest among researchers worldwide. Quantitative information stored in image pixels can be analysed automatically to track time-dependent phenomena, e.g. seasonal course of leaves in the canopies or snow on ground. As such, cameras can provide valuable ground references to earth observation. Here we document the ecosystem camera network we established to Finland and publish time series of images recorded between 2014–2016.
Thibaud Thonat, Marielle Saunois, Philippe Bousquet, Isabelle Pison, Zeli Tan, Qianlai Zhuang, Patrick M. Crill, Brett F. Thornton, David Bastviken, Ed J. Dlugokencky, Nikita Zimov, Tuomas Laurila, Juha Hatakka, Ove Hermansen, and Doug E. J. Worthy
Atmos. Chem. Phys., 17, 8371–8394, https://doi.org/10.5194/acp-17-8371-2017, https://doi.org/10.5194/acp-17-8371-2017, 2017
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Atmospheric methane simulations in the Arctic have been made for 2012 and compared to continuous observations at six measurement sites. All methane sources significantly affect the measurements at all stations, at least at the synoptic scale, except for biomass burning. An appropriate modelling framework combined with continuous observations of atmospheric methane enables us to gain knowledge on regional methane sources, including those which are usually poorly represented, such as freshwater.
Kgaugelo Euphinia Chiloane, Johan Paul Beukes, Pieter Gideon van Zyl, Petra Maritz, Ville Vakkari, Miroslav Josipovic, Andrew Derick Venter, Kerneels Jaars, Petri Tiitta, Markku Kulmala, Alfred Wiedensohler, Catherine Liousse, Gabisile Vuyisile Mkhatshwa, Avishkar Ramandh, and Lauri Laakso
Atmos. Chem. Phys., 17, 6177–6196, https://doi.org/10.5194/acp-17-6177-2017, https://doi.org/10.5194/acp-17-6177-2017, 2017
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This paper presents atmospheric black carbon (BC) data collected in South Africa (SA). In general, BC level were higher than in the developed world. At one site, five sources were identified, with household combustion as well as savannah and grassland fires the most significant sources during winter and spring, while coal-fired power stations, pyrometallurgical smelters and traffic contributed year round.
Tea Thum, Sönke Zaehle, Philipp Köhler, Tuula Aalto, Mika Aurela, Luis Guanter, Pasi Kolari, Tuomas Laurila, Annalea Lohila, Federico Magnani, Christiaan Van Der Tol, and Tiina Markkanen
Biogeosciences, 14, 1969–1987, https://doi.org/10.5194/bg-14-1969-2017, https://doi.org/10.5194/bg-14-1969-2017, 2017
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Modelling seasonal cycle at the coniferous forests poses a challenge. We implemented a model for sun-induced chlorophyll fluorescence (SIF) to a land surface model JSBACH. It was used to study the seasonality of the carbon cycle in the Fenno-Scandinavian region. Comparison was made to direct CO2 flux measurements and satellite observations of SIF. SIF proved to be a better proxy for photosynthesis than the fraction of absorbed photosynthetically active radiation.
Mika Korkiakoski, Juha-Pekka Tuovinen, Mika Aurela, Markku Koskinen, Kari Minkkinen, Paavo Ojanen, Timo Penttilä, Juuso Rainne, Tuomas Laurila, and Annalea Lohila
Biogeosciences, 14, 1947–1967, https://doi.org/10.5194/bg-14-1947-2017, https://doi.org/10.5194/bg-14-1947-2017, 2017
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We measured methane exchange rates at the forest floor of a nutrient-rich drained peatland in southern Finland. The forest floor acted mainly as a small methane sink, but emission peaks were occasionally observed during spring and rainfall events. The strength of the sink correlated best with groundwater level and soil temperatures at 20 and 30 cm depths. Diurnal variations were also observed but they were caused by changes in ambient wind speed and not by biological processes.
Dominik Schmithüsen, Scott Chambers, Bernd Fischer, Stefan Gilge, Juha Hatakka, Victor Kazan, Rolf Neubert, Jussi Paatero, Michel Ramonet, Clemens Schlosser, Sabine Schmid, Alex Vermeulen, and Ingeborg Levin
Atmos. Meas. Tech., 10, 1299–1312, https://doi.org/10.5194/amt-10-1299-2017, https://doi.org/10.5194/amt-10-1299-2017, 2017
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A European-wide 222radon/222radon progeny comparison study has been conducted at nine measurement stations in order to determine differences between existing 222radon instrumentation and atmospheric data sets, respectively. Mean differences up to 45 % were found between monitors. These differences need to be taken into account if the data shall serve for quantitative regional atmospheric transport model validation.
Andrew D. Venter, Pieter G. van Zyl, Johan P. Beukes, Micky Josipovic, Johan Hendriks, Ville Vakkari, and Lauri Laakso
Atmos. Chem. Phys., 17, 4251–4263, https://doi.org/10.5194/acp-17-4251-2017, https://doi.org/10.5194/acp-17-4251-2017, 2017
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Size-resolved trace metal concentrations were determined at a regional background site impacted by the major pollutant source regions in the interior of South Africa, which include a region holding a large number of pyrometallurgical smelters. ≥70% of trace metal species were in the smaller size fractions, indicating the influence of industrial activities, while the influence of wind-blown dust was reflected in the PM2.5–10 size fraction. Annual average Ni and As exceeded European standards.
Matti Räsänen, Mika Aurela, Ville Vakkari, Johan P. Beukes, Juha-Pekka Tuovinen, Pieter G. Van Zyl, Miroslav Josipovic, Andrew D. Venter, Kerneels Jaars, Stefan J. Siebert, Tuomas Laurila, Janne Rinne, and Lauri Laakso
Biogeosciences, 14, 1039–1054, https://doi.org/10.5194/bg-14-1039-2017, https://doi.org/10.5194/bg-14-1039-2017, 2017
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This study presents measurements of carbon dioxide exchange between the atmosphere and a grazed savanna grassland ecosystem for 3 years. We find that the yearly variation in carbon dioxide balance is largely determined by the changes in the early wet season balance (September to November) and in the mid-growing season balance (December to January).
Kerneels Jaars, Pieter G. van Zyl, Johan P. Beukes, Heidi Hellén, Ville Vakkari, Micky Josipovic, Andrew D. Venter, Matti Räsänen, Leandra Knoetze, Dirk P. Cilliers, Stefan J. Siebert, Markku Kulmala, Janne Rinne, Alex Guenther, Lauri Laakso, and Hannele Hakola
Atmos. Chem. Phys., 16, 15665–15688, https://doi.org/10.5194/acp-16-15665-2016, https://doi.org/10.5194/acp-16-15665-2016, 2016
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Biogenic volatile organic compounds (BVOCs) – important in tropospheric ozone and secondary organic aerosol formation – were measured at a savannah grassland in South Africa. Results presented are the most extensive for this type of landscape. Compared to other parts of the world, monoterpene levels were similar, while very low isoprene levels led to significantly lower total BVOC levels. BVOC levels were an order of magnitude lower compared to anthropogenic VOC levels measured at Welgegund.
Hanna K. Lappalainen, Veli-Matti Kerminen, Tuukka Petäjä, Theo Kurten, Aleksander Baklanov, Anatoly Shvidenko, Jaana Bäck, Timo Vihma, Pavel Alekseychik, Meinrat O. Andreae, Stephen R. Arnold, Mikhail Arshinov, Eija Asmi, Boris Belan, Leonid Bobylev, Sergey Chalov, Yafang Cheng, Natalia Chubarova, Gerrit de Leeuw, Aijun Ding, Sergey Dobrolyubov, Sergei Dubtsov, Egor Dyukarev, Nikolai Elansky, Kostas Eleftheriadis, Igor Esau, Nikolay Filatov, Mikhail Flint, Congbin Fu, Olga Glezer, Aleksander Gliko, Martin Heimann, Albert A. M. Holtslag, Urmas Hõrrak, Juha Janhunen, Sirkku Juhola, Leena Järvi, Heikki Järvinen, Anna Kanukhina, Pavel Konstantinov, Vladimir Kotlyakov, Antti-Jussi Kieloaho, Alexander S. Komarov, Joni Kujansuu, Ilmo Kukkonen, Ella-Maria Duplissy, Ari Laaksonen, Tuomas Laurila, Heikki Lihavainen, Alexander Lisitzin, Alexsander Mahura, Alexander Makshtas, Evgeny Mareev, Stephany Mazon, Dmitry Matishov, Vladimir Melnikov, Eugene Mikhailov, Dmitri Moisseev, Robert Nigmatulin, Steffen M. Noe, Anne Ojala, Mari Pihlatie, Olga Popovicheva, Jukka Pumpanen, Tatjana Regerand, Irina Repina, Aleksei Shcherbinin, Vladimir Shevchenko, Mikko Sipilä, Andrey Skorokhod, Dominick V. Spracklen, Hang Su, Dmitry A. Subetto, Junying Sun, Arkady Y. Terzhevik, Yuri Timofeyev, Yuliya Troitskaya, Veli-Pekka Tynkkynen, Viacheslav I. Kharuk, Nina Zaytseva, Jiahua Zhang, Yrjö Viisanen, Timo Vesala, Pertti Hari, Hans Christen Hansson, Gennady G. Matvienko, Nikolai S. Kasimov, Huadong Guo, Valery Bondur, Sergej Zilitinkevich, and Markku Kulmala
Atmos. Chem. Phys., 16, 14421–14461, https://doi.org/10.5194/acp-16-14421-2016, https://doi.org/10.5194/acp-16-14421-2016, 2016
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After kick off in 2012, the Pan-Eurasian Experiment (PEEX) program has expanded fast and today the multi-disciplinary research community covers ca. 80 institutes and a network of ca. 500 scientists from Europe, Russia, and China. Here we introduce scientific topics relevant in this context. This is one of the first multi-disciplinary overviews crossing scientific boundaries, from atmospheric sciences to socio-economics and social sciences.
Maiju Linkosalmi, Mika Aurela, Juha-Pekka Tuovinen, Mikko Peltoniemi, Cemal M. Tanis, Ali N. Arslan, Pasi Kolari, Kristin Böttcher, Tuula Aalto, Juuso Rainne, Juha Hatakka, and Tuomas Laurila
Geosci. Instrum. Method. Data Syst., 5, 417–426, https://doi.org/10.5194/gi-5-417-2016, https://doi.org/10.5194/gi-5-417-2016, 2016
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Digital photography has become a widely used tool for monitoring the vegetation phenology. The seasonal cycle of the greenness index obtained from photographs correlated well with the CO2 exchange of the plants at our wetland and Scots pine forest sites. While the seasonal changes in the greenness were more obvious for the ecosystem dominated by annual plants, clear seasonal patterns were also observed for the evergreen forest.
Fanni Mylläri, Eija Asmi, Tatu Anttila, Erkka Saukko, Ville Vakkari, Liisa Pirjola, Risto Hillamo, Tuomas Laurila, Anna Häyrinen, Jani Rautiainen, Heikki Lihavainen, Ewan O'Connor, Ville Niemelä, Jorma Keskinen, Miikka Dal Maso, and Topi Rönkkö
Atmos. Chem. Phys., 16, 7485–7496, https://doi.org/10.5194/acp-16-7485-2016, https://doi.org/10.5194/acp-16-7485-2016, 2016
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The primary emissions of a coal-fired power plant were highly affected by the flue-gas cleaning technologies. The primary emission results were used as input values for a Gaussian plume model and the model correlated well with the atmospheric measurements from the flue-gas plume. Concentrations of newly formed particles in the flue gas plume were higher than the primary particle concentration, and thus the source of particle-forming precursors should be characterized in more detail.
Antoine Berchet, Philippe Bousquet, Isabelle Pison, Robin Locatelli, Frédéric Chevallier, Jean-Daniel Paris, Ed J. Dlugokencky, Tuomas Laurila, Juha Hatakka, Yrjo Viisanen, Doug E. J. Worthy, Euan Nisbet, Rebecca Fisher, James France, David Lowry, Viktor Ivakhov, and Ove Hermansen
Atmos. Chem. Phys., 16, 4147–4157, https://doi.org/10.5194/acp-16-4147-2016, https://doi.org/10.5194/acp-16-4147-2016, 2016
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We propose insights based on atmospheric observations around the Arctic circle to evaluate estimates of methane emissions to the atmosphere from the East Siberian Arctic Shelf. Based on a comprehensive statistical analysis of the observations and of high-resolution transport simulations, annual methane emissions from ESAS are estimated to range from 0.0 to 4.5 TgCH4 yr−1, with a maximum in summer and very low emissions in winter.
J.-V. Björkqvist, H. Pettersson, L. Laakso, K. K. Kahma, H. Jokinen, and P. Kosloff
Geosci. Instrum. Method. Data Syst., 5, 17–25, https://doi.org/10.5194/gi-5-17-2016, https://doi.org/10.5194/gi-5-17-2016, 2016
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We identified a previously unknown artefact in the Datawell DWR-G4 wave buoy, which measures the GPS signal to resolve surface water waves. The artefact interferes with the part of the measurements containing information about the longer waves and must be removed to obtain accurate readings. We presented a correction method and found it to be accurate based on a comparison to measurements from a larger wave buoy that measures the movements of the device without using the GPS signal.
E. Asmi, V. Kondratyev, D. Brus, T. Laurila, H. Lihavainen, J. Backman, V. Vakkari, M. Aurela, J. Hatakka, Y. Viisanen, T. Uttal, V. Ivakhov, and A. Makshtas
Atmos. Chem. Phys., 16, 1271–1287, https://doi.org/10.5194/acp-16-1271-2016, https://doi.org/10.5194/acp-16-1271-2016, 2016
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Aerosol number size distributions were measured in Arctic Russia continuously during 4 years. The particles' seasonal characteristics and sources were identified based on these data. In early spring, elevated concentrations were detected during episodes of Arctic haze and during days of secondary particle formation. In summer, Siberian forests biogenic emissions had a significant impact on particle number and mass. These are the first such results obtained from the region.
F. Kuik, A. Lauer, J. P. Beukes, P. G. Van Zyl, M. Josipovic, V. Vakkari, L. Laakso, and G. T. Feig
Atmos. Chem. Phys., 15, 8809–8830, https://doi.org/10.5194/acp-15-8809-2015, https://doi.org/10.5194/acp-15-8809-2015, 2015
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The numerical model WRF-Chem is used to estimate the contribution of anthropogenic emissions to BC, aerosol optical depth and atmospheric heating rates over southern Africa. An evaluation of the model with observational data including long-term BC measurements shows that the basic meteorology is reproduced reasonably well but simulated near-surface BC concentrations are underestimated by up to 50%. It is found that up to 100% of the BC in highly industrialized regions is of anthropogenic origin.
E. Giannakaki, A. Pfüller, K. Korhonen, T. Mielonen, L. Laakso, V. Vakkari, H. Baars, R. Engelmann, J. P. Beukes, P. G. Van Zyl, M. Josipovic, P. Tiitta, K. Chiloane, S. Piketh, H. Lihavainen, K. E. J. Lehtinen, and M. Komppula
Atmos. Chem. Phys., 15, 5429–5442, https://doi.org/10.5194/acp-15-5429-2015, https://doi.org/10.5194/acp-15-5429-2015, 2015
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In this study we summarize 1 year of Raman lidar observations over South Africa. The analyses of lidar measurements presented here could assist in bridging existing gaps in the knowledge of vertical distribution of aerosols above South Africa, since limited long-term data of this type are available for this region. For the first time, we have been able to cover the full seasonal cycle on geometrical characteristics and optical properties of free tropospheric aerosol layers in the region.
A.-M. Sundström, A. Nikandrova, K. Atlaskina, T. Nieminen, V. Vakkari, L. Laakso, J. P. Beukes, A. Arola, P. G. van Zyl, M. Josipovic, A. D. Venter, K. Jaars, J. J. Pienaar, S. Piketh, A. Wiedensohler, E. K. Chiloane, G. de Leeuw, and M. Kulmala
Atmos. Chem. Phys., 15, 4983–4996, https://doi.org/10.5194/acp-15-4983-2015, https://doi.org/10.5194/acp-15-4983-2015, 2015
J. Backman, A. Virkkula, V. Vakkari, J. P. Beukes, P. G. Van Zyl, M. Josipovic, S. Piketh, P. Tiitta, K. Chiloane, T. Petäjä, M. Kulmala, and L. Laakso
Atmos. Meas. Tech., 7, 4285–4298, https://doi.org/10.5194/amt-7-4285-2014, https://doi.org/10.5194/amt-7-4285-2014, 2014
K. Jaars, J. P. Beukes, P. G. van Zyl, A. D. Venter, M. Josipovic, J. J. Pienaar, V. Vakkari, H. Aaltonen, H. Laakso, M. Kulmala, P. Tiitta, A. Guenther, H. Hellén, L. Laakso, and H. Hakola
Atmos. Chem. Phys., 14, 7075–7089, https://doi.org/10.5194/acp-14-7075-2014, https://doi.org/10.5194/acp-14-7075-2014, 2014
O. Peltola, A. Hensen, C. Helfter, L. Belelli Marchesini, F. C. Bosveld, W. C. M. van den Bulk, J. A. Elbers, S. Haapanala, J. Holst, T. Laurila, A. Lindroth, E. Nemitz, T. Röckmann, A. T. Vermeulen, and I. Mammarella
Biogeosciences, 11, 3163–3186, https://doi.org/10.5194/bg-11-3163-2014, https://doi.org/10.5194/bg-11-3163-2014, 2014
A. Hirsikko, E. J. O'Connor, M. Komppula, K. Korhonen, A. Pfüller, E. Giannakaki, C. R. Wood, M. Bauer-Pfundstein, A. Poikonen, T. Karppinen, H. Lonka, M. Kurri, J. Heinonen, D. Moisseev, E. Asmi, V. Aaltonen, A. Nordbo, E. Rodriguez, H. Lihavainen, A. Laaksonen, K. E. J. Lehtinen, T. Laurila, T. Petäjä, M. Kulmala, and Y. Viisanen
Atmos. Meas. Tech., 7, 1351–1375, https://doi.org/10.5194/amt-7-1351-2014, https://doi.org/10.5194/amt-7-1351-2014, 2014
K. Korhonen, E. Giannakaki, T. Mielonen, A. Pfüller, L. Laakso, V. Vakkari, H. Baars, R. Engelmann, J. P. Beukes, P. G. Van Zyl, A. Ramandh, L. Ntsangwane, M. Josipovic, P. Tiitta, G. Fourie, I. Ngwana, K. Chiloane, and M. Komppula
Atmos. Chem. Phys., 14, 4263–4278, https://doi.org/10.5194/acp-14-4263-2014, https://doi.org/10.5194/acp-14-4263-2014, 2014
P. Tiitta, V. Vakkari, P. Croteau, J. P. Beukes, P. G. van Zyl, M. Josipovic, A. D. Venter, K. Jaars, J. J. Pienaar, N. L. Ng, M. R. Canagaratna, J. T. Jayne, V.-M. Kerminen, H. Kokkola, M. Kulmala, A. Laaksonen, D. R. Worsnop, and L. Laakso
Atmos. Chem. Phys., 14, 1909–1927, https://doi.org/10.5194/acp-14-1909-2014, https://doi.org/10.5194/acp-14-1909-2014, 2014
M. Koskinen, K. Minkkinen, P. Ojanen, M. Kämäräinen, T. Laurila, and A. Lohila
Biogeosciences, 11, 347–363, https://doi.org/10.5194/bg-11-347-2014, https://doi.org/10.5194/bg-11-347-2014, 2014
A. I. Partanen, A. Laakso, A. Schmidt, H. Kokkola, T. Kuokkanen, J.-P. Pietikäinen, V.-M. Kerminen, K. E. J. Lehtinen, L. Laakso, and H. Korhonen
Atmos. Chem. Phys., 13, 12059–12071, https://doi.org/10.5194/acp-13-12059-2013, https://doi.org/10.5194/acp-13-12059-2013, 2013
A. Berchet, I. Pison, F. Chevallier, P. Bousquet, S. Conil, M. Geever, T. Laurila, J. Lavrič, M. Lopez, J. Moncrieff, J. Necki, M. Ramonet, M. Schmidt, M. Steinbacher, and J. Tarniewicz
Atmos. Chem. Phys., 13, 7115–7132, https://doi.org/10.5194/acp-13-7115-2013, https://doi.org/10.5194/acp-13-7115-2013, 2013
A. Hirsikko, V. Vakkari, P. Tiitta, J. Hatakka, V.-M. Kerminen, A.-M. Sundström, J. P. Beukes, H. E. Manninen, M. Kulmala, and L. Laakso
Atmos. Chem. Phys., 13, 5523–5532, https://doi.org/10.5194/acp-13-5523-2013, https://doi.org/10.5194/acp-13-5523-2013, 2013
V. Vakkari, J. P. Beukes, H. Laakso, D. Mabaso, J. J. Pienaar, M. Kulmala, and L. Laakso
Atmos. Chem. Phys., 13, 1751–1770, https://doi.org/10.5194/acp-13-1751-2013, https://doi.org/10.5194/acp-13-1751-2013, 2013
L. Riuttanen, M. Dal Maso, G. de Leeuw, I. Riipinen, L. Sogacheva, V. Vakkari, L. Laakso, and M. Kulmala
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-4289-2013, https://doi.org/10.5194/acpd-13-4289-2013, 2013
Revised manuscript has not been submitted
J. Leppä, S. Gagné, L. Laakso, H. E. Manninen, K. E. J. Lehtinen, M. Kulmala, and V.-M. Kerminen
Atmos. Chem. Phys., 13, 463–486, https://doi.org/10.5194/acp-13-463-2013, https://doi.org/10.5194/acp-13-463-2013, 2013
A.-P. Hyvärinen, V. Vakkari, L. Laakso, R. K. Hooda, V. P. Sharma, T. S. Panwar, J. P. Beukes, P. G. van Zyl, M. Josipovic, R. M. Garland, M. O. Andreae, U. Pöschl, and A. Petzold
Atmos. Meas. Tech., 6, 81–90, https://doi.org/10.5194/amt-6-81-2013, https://doi.org/10.5194/amt-6-81-2013, 2013
V.-M. Kerminen, M. Paramonov, T. Anttila, I. Riipinen, C. Fountoukis, H. Korhonen, E. Asmi, L. Laakso, H. Lihavainen, E. Swietlicki, B. Svenningsson, A. Asmi, S. N. Pandis, M. Kulmala, and T. Petäjä
Atmos. Chem. Phys., 12, 12037–12059, https://doi.org/10.5194/acp-12-12037-2012, https://doi.org/10.5194/acp-12-12037-2012, 2012
Related subject area
Subject: Gases | Technique: In Situ Measurement | Topic: Instruments and Platforms
Airborne flux measurements of ammonia over the southern Great Plains using chemical ionization mass spectrometry
Optical receiver characterizations and corrections for ground-based and airborne measurements of spectral actinic flux densities
Development and validation of a new in situ technique to measure total gaseous chlorine in air
True eddy accumulation – Part 1: Solutions to the problem of non-vanishing mean vertical wind velocity
True eddy accumulation – Part 2: Theory and experiment of the short-time eddy accumulation method
Chemical ionization mass spectrometry utilizing ammonium ions (NH4+ CIMS) for measurements of organic compounds in the atmosphere
Direct measurement of N2O5 heterogeneous uptake coefficients on ambient aerosols via an aerosol flow tube system: design, characterization and performance
Online measurements of cycloalkanes based on NO+ chemical ionization in proton transfer reaction time-of-flight mass spectrometry (PTR-ToF-MS)
Intercomparison of in situ measurements of ambient NH3: instrument performance and application under field conditions
A lightweight broadband cavity-enhanced spectrometer for NO2 measurement on uncrewed aerial vehicles
On the development of a new prototype PTR-ToF-MS instrument and its application to the detection of atmospheric amines
Development of multi-channel whole-air sampling equipment onboard unmanned aerial vehicle for investigating VOCs vertical distribution in the planetary boundary layer
New methods for the calibration of optical resonators: Integrated Calibration by means of Optical Modulation (ICOM) and Narrow Band Cavity ring-down (NB-CRD)
Low-complexity methods to mitigate the impact of environmental variables on low-cost UAS-based atmospheric carbon dioxide measurements
Comparison of airborne measurements of NO, NO2, HONO, NOy, and CO during FIREX-AQ
Development of a broadband cavity-enhanced absorption spectrometer for simultaneous measurements of ambient NO3, NO2, and H2O
Improvements of a low-cost CO2 commercial nondispersive near-infrared (NDIR) sensor for unmanned aerial vehicle (UAV) atmospheric mapping applications
Development and testing of a novel sulfur dioxide sonde
Temperature-dependent sensitivity of iodide chemical ionization mass spectrometers
A quadcopter unmanned aerial system (UAS)-based methodology for measuring biomass burning emission factors
Evaluating the performance of a Picarro G2207-i analyser for high-precision atmospheric O2 measurements
A modular field system enabling cavity ring-down spectroscopy of in-situ vapor observations in harsh environments: The ISE-CUBE system
Electrochemical sensors onboard a Zeppelin NT: In-flight evaluation of low-cost trace gas measurements
Air quality observations onboard commercial and targeted Zeppelin flights in Germany – a platform for high-resolution trace-gas and aerosol measurements within the planetary boundary layer
Measuring dry deposition of ammonia using flux-gradient and eddy covariance methods with two novel open-path instruments
Performance of open-path lasers and Fourier transform infrared spectroscopic systems in agriculture emissions research
Metrology for low-cost CO2 sensors applications: the case of a steady-state through-flow (SS-TF) chamber for CO2 fluxes observations
A relaxed eddy accumulation (REA) LOPAP system for flux measurements of nitrous acid (HONO)
Fill dynamics and sample mixing in the AirCore
IRIS analyser assessment reveals sub-hourly variability of isotope ratios in carbon dioxide at Baring Head, New Zealand's atmospheric observatory in the Southern Ocean
A versatile vacuum ultraviolet ion source for reduced pressure bipolar chemical ionization mass spectrometry
Design and characterization of a semi-open dynamic chamber for measuring biogenic volatile organic compound (BVOC) emissions from plants
First eddy covariance flux measurements of semi-volatile organic compounds with the PTR3-TOF-MS
An unmanned aerial vehicle sampling platform for atmospheric water vapor isotopes in polar environments
Novel approach to observing system simulation experiments improves information gain of surface–atmosphere field measurements
UAS Chromatograph for Atmospheric Trace Species (UCATS) – a versatile instrument for trace gas measurements on airborne platforms
Modification of a conventional photolytic converter for improving aircraft measurements of NO2 via chemiluminescence
Bromine speciation in volcanic plumes: new in situ derivatization LC-MS method for the determination of gaseous hydrogen bromide by gas diffusion denuder sampling
Application of a mobile laboratory using a selected-ion flow-tube mass spectrometer (SIFT-MS) for characterisation of volatile organic compounds and atmospheric trace gases
Development of a laser-photofragmentation laser-induced fluorescence instrument for the detection of nitrous acid and hydroxyl radicals in the atmosphere
Calibration and assessment of electrochemical low-cost sensors in remote alpine harsh environments
Intercomparison of IBBCEAS, NitroMAC and FTIR analyses for HONO, NO2 and CH2O measurements during the reaction of NO2 with H2O vapour in the simulation chamber CESAM
Impact of ozone and inlet design on the quantification of isoprene-derived organic nitrates by thermal dissociation cavity ring-down spectroscopy (TD-CRDS)
The Berkeley Environmental Air-quality and CO2 Network: field calibrations of sensor temperature dependence and assessment of network scale CO2 accuracy
Iodide CIMS and m∕z 62: the detection of HNO3 as NO3− in the presence of PAN, peroxyacetic acid and ozone
Airborne Mid-Infrared Cavity enhanced Absorption spectrometer (AMICA)
Ethane measurement by Picarro CRDS G2201-i in laboratory and field conditions: potential and limitations
On-line solid phase microextraction derivatization for the sensitive determination of multi-oxygenated volatile compounds in air
Thermal dissociation cavity-enhanced absorption spectrometer for measuring NO2, RO2NO2, and RONO2 in the atmosphere
Internal consistency of the IAGOS ozone and carbon monoxide measurements for the last 25 years
Siegfried Schobesberger, Emma L. D'Ambro, Lejish Vettikkat, Ben H. Lee, Qiaoyun Peng, David M. Bell, John E. Shilling, Manish Shrivastava, Mikhail Pekour, Jerome Fast, and Joel A. Thornton
Atmos. Meas. Tech., 16, 247–271, https://doi.org/10.5194/amt-16-247-2023, https://doi.org/10.5194/amt-16-247-2023, 2023
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We present a new, highly sensitive technique for measuring atmospheric ammonia, an important trace gas that is emitted mainly by agriculture. We deployed the instrument on an aircraft during research flights over rural Oklahoma. Due to its fast response, we could analyze correlations with turbulent winds and calculate ammonia emissions from nearby areas at 1 to 2 km resolution. We observed high spatial variability and point sources that are not resolved in the US National Emissions Inventory.
Birger Bohn and Insa Lohse
Atmos. Meas. Tech., 16, 209–233, https://doi.org/10.5194/amt-16-209-2023, https://doi.org/10.5194/amt-16-209-2023, 2023
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Optical receivers for solar spectral actinic radiation are designed for angle-independent sensitivities within a hemisphere. Remaining imperfections can be compensated for by receiver-specific corrections based on laboratory characterizations and radiative transfer calculations of spectral radiance distributions. The corrections cover a wide range of realistic atmospheric conditions and were applied to ground-based and airborne measurements in a wavelength range 280–660 nm.
Teles C. Furlani, RenXi Ye, Jordan Stewart, Leigh R. Crilley, Peter M. Edwards, Tara F. Kahan, and Cora J. Young
Atmos. Meas. Tech., 16, 181–193, https://doi.org/10.5194/amt-16-181-2023, https://doi.org/10.5194/amt-16-181-2023, 2023
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This study describes a new technique to measure total gaseous chlorine, which is the sum of gas-phase chlorine-containing chemicals. The method converts any chlorine-containing molecule to hydrogen chloride that can be detected in real time using a cavity ring-down spectrometer. The new method was validated through laboratory experiments, as well as by making measurements of ambient outdoor air and indoor air during cleaning with a chlorine-based cleaner.
Anas Emad and Lukas Siebicke
Atmos. Meas. Tech., 16, 29–40, https://doi.org/10.5194/amt-16-29-2023, https://doi.org/10.5194/amt-16-29-2023, 2023
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The true eddy accumulation (TEA) method enables measuring atmospheric exchange with slow-response gas analyzers. TEA is formulated assuming ideal conditions with a zero mean vertical wind velocity during the averaging interval. This core assumption is rarely valid under field conditions. Here, we extend the TEA equation to accommodate nonideal conditions. The new equation allows constraining the systematic error term in the measured fluxes and the possibility to minimize or remove it.
Anas Emad and Lukas Siebicke
Atmos. Meas. Tech., 16, 41–55, https://doi.org/10.5194/amt-16-41-2023, https://doi.org/10.5194/amt-16-41-2023, 2023
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A new micrometeorological method to measure atmospheric exchange is proposed, and a prototype sampler is evaluated. The new method, called short-time eddy accumulation, is a variant of the eddy accumulation method, which is suited for use with slow gas analyzers. The new method enables adaptive time-varying accumulation intervals, which brings many advantages to flux measurements such as an improved dynamic range and the ability to run eddy accumulation in a continuous flow-through mode.
Lu Xu, Matthew M. Coggon, Chelsea E. Stockwell, Jessica B. Gilman, Michael A. Robinson, Martin Breitenlechner, Aaron Lamplugh, John D. Crounse, Paul O. Wennberg, J. Andrew Neuman, Gordon A. Novak, Patrick R. Veres, Steven S. Brown, and Carsten Warneke
Atmos. Meas. Tech., 15, 7353–7373, https://doi.org/10.5194/amt-15-7353-2022, https://doi.org/10.5194/amt-15-7353-2022, 2022
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We describe the development and operation of a chemical ionization mass spectrometer using an ammonium–water cluster (NH4+·H2O) as a reagent ion. NH4+·H2O is a highly versatile reagent ion for measurements of a wide range of oxygenated organic compounds. The major product ion is the cluster with NH4+ produced via ligand-switching reactions. The instrumental sensitivities of analytes depend on the binding energy of the analyte–NH4+ cluster; sensitivities can be estimated using voltage scanning.
Xiaorui Chen, Haichao Wang, Tianyu Zhai, Chunmeng Li, and Keding Lu
Atmos. Meas. Tech., 15, 7019–7037, https://doi.org/10.5194/amt-15-7019-2022, https://doi.org/10.5194/amt-15-7019-2022, 2022
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N2O5 is an important reservoir of atmospheric nitrogen, on whose interface reaction ambient particles can largely influence the fate of nitrogen oxides and air quality. In this study, we develop an approach to enable the reactions of N2O5 on ambient particles directly in a tube reactor, deriving the reaction rates with high accuracy by means of a chemistry model. Its successful application helps complement the data scarcity and to fill the knowledge gap between laboratory and field results.
Yubin Chen, Bin Yuan, Chaomin Wang, Sihang Wang, Xianjun He, Caihong Wu, Xin Song, Yibo Huangfu, Xiao-Bing Li, Yijia Liao, and Min Shao
Atmos. Meas. Tech., 15, 6935–6947, https://doi.org/10.5194/amt-15-6935-2022, https://doi.org/10.5194/amt-15-6935-2022, 2022
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In this study, we demonstrate that selective online measurements of cycloalkanes can be achieved using proton transfer reaction time-of-flight mass spectrometry with NO+ chemical ionization (NO+ PTR-ToF-MS), with fast response and low detection limits. Applications of this method in both urban air and emission sources will be shown.
Marsailidh M. Twigg, Augustinus J. C. Berkhout, Nicholas Cowan, Sabine Crunaire, Enrico Dammers, Volker Ebert, Vincent Gaudion, Marty Haaima, Christoph Häni, Lewis John, Matthew R. Jones, Bjorn Kamps, John Kentisbeer, Thomas Kupper, Sarah R. Leeson, Daiana Leuenberger, Nils O. B. Lüttschwager, Ulla Makkonen, Nicholas A. Martin, David Missler, Duncan Mounsor, Albrecht Neftel, Chad Nelson, Eiko Nemitz, Rutger Oudwater, Celine Pascale, Jean-Eudes Petit, Andrea Pogany, Nathalie Redon, Jörg Sintermann, Amy Stephens, Mark A. Sutton, Yuk S. Tang, Rens Zijlmans, Christine F. Braban, and Bernhard Niederhauser
Atmos. Meas. Tech., 15, 6755–6787, https://doi.org/10.5194/amt-15-6755-2022, https://doi.org/10.5194/amt-15-6755-2022, 2022
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Ammonia (NH3) gas in the atmosphere impacts the environment, human health, and, indirectly, climate. Historic NH3 monitoring was labour intensive, and the instruments were complicated. Over the last decade, there has been a rapid technology development, including “plug-and-play” instruments. This study is an extensive field comparison of the currently available technologies and provides evidence that for routine monitoring, standard operating protocols are required for datasets to be comparable.
Caroline C. Womack, Steven S. Brown, Steven J. Ciciora, Ru-Shan Gao, Richard J. McLaughlin, Michael A. Robinson, Yinon Rudich, and Rebecca A. Washenfelder
Atmos. Meas. Tech., 15, 6643–6652, https://doi.org/10.5194/amt-15-6643-2022, https://doi.org/10.5194/amt-15-6643-2022, 2022
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We present a new miniature instrument to measure nitrogen dioxide (NO2) using cavity-enhanced spectroscopy. NO2 contributes to the formation of pollutants such as ozone and particulate matter, and its concentration can vary widely near sources. We developed this lightweight (3.05 kg) low-power (<35 W) instrument to measure NO2 on uncrewed aircraft vehicles (UAVs) and demonstrate that it has the accuracy and precision needed for atmospheric field measurements.
Alexander Håland, Tomáš Mikoviny, Elisabeth Emilie Syse, and Armin Wisthaler
Atmos. Meas. Tech., 15, 6297–6307, https://doi.org/10.5194/amt-15-6297-2022, https://doi.org/10.5194/amt-15-6297-2022, 2022
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PTR-MS is widely used in atmospheric sciences for the detection of non-methane organic trace gases. The two most widely used types of PTR-MS instruments differ in their ion source and drift tube design. We herein present a new prototype PTR-MS instrument that hybridizes these designs and combines a conventional hollow cathode glow discharge ion source with a focusing ion–molecule reactor. We also show how this new instrument performs in detecting atmospheric amines.
Suding Yang, Xin Li, Limin Zeng, Xuena Yu, Ying Liu, Sihua Lu, Xiaofeng Huang, Dongmei Zhang, Haibin Xu, Shuchen Lin, Jinhui Cui, Lifan Wang, Ying Chen, Wenjie Wang, Mengdi Song, Liuwei Kong, Yi Liu, Linhui Wei, Xianwu Zhu, and Yuanhang Zhang
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2022-277, https://doi.org/10.5194/amt-2022-277, 2022
Revised manuscript accepted for AMT
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Vertical observation of volatile organic compounds (VOCs) is essential to study the spatial distribution and evolution patterns of VOCs in the planetary boundary layer (PBL). This paper describes multi-channel whole-air sampling equipment onboard the unmanned aerial vehicle (UAV) for near-continuous VOC vertical observation. Vertical profiles of VOCs and trace gases during the evolution of PBL in southwest China have been successfully obtained by deploying the newly developed UAV system.
Henning Finkenzeller, Denis Pöhler, Martin Horbanski, Johannes Lampel, and Ulrich Platt
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2022-274, https://doi.org/10.5194/amt-2022-274, 2022
Revised manuscript accepted for AMT
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Optical resonators enhance the light path in compact instruments, thereby improving the sensitivity. Determining the established path length in the instrument is a prerequisite for the accurate determination of trace gas concentrations but can be a significant complication in the use of such resonators. Here we show two calibration techniques which are relatively simple and free of consumables, but still provide accurate calibrations. This facilitates the use of optical resonators.
Gustavo Britto Hupsel de Azevedo, Bill Doyle, Christopher A. Fiebrich, and David Schvartzman
Atmos. Meas. Tech., 15, 5599–5618, https://doi.org/10.5194/amt-15-5599-2022, https://doi.org/10.5194/amt-15-5599-2022, 2022
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Strong changes in pressure, temperature, and humidity occur when small scientific aircraft ascend through the atmosphere to measure carbon dioxide. These strong changes can produce errors in the carbon dioxide measurements. To avoid these errors, we present a low-cost and simple correction method. This low-complexity method allows more researchers to study atmospheric carbon dioxide, reducing entry barriers in this field.
Ilann Bourgeois, Jeff Peischl, J. Andrew Neuman, Steven S. Brown, Hannah M. Allen, Pedro Campuzano-Jost, Matthew M. Coggon, Joshua P. DiGangi, Glenn S. Diskin, Jessica B. Gilman, Georgios I. Gkatzelis, Hongyu Guo, Hannah A. Halliday, Thomas F. Hanisco, Christopher D. Holmes, L. Gregory Huey, Jose L. Jimenez, Aaron D. Lamplugh, Young Ro Lee, Jakob Lindaas, Richard H. Moore, Benjamin A. Nault, John B. Nowak, Demetrios Pagonis, Pamela S. Rickly, Michael A. Robinson, Andrew W. Rollins, Vanessa Selimovic, Jason M. St. Clair, David Tanner, Krystal T. Vasquez, Patrick R. Veres, Carsten Warneke, Paul O. Wennberg, Rebecca A. Washenfelder, Elizabeth B. Wiggins, Caroline C. Womack, Lu Xu, Kyle J. Zarzana, and Thomas B. Ryerson
Atmos. Meas. Tech., 15, 4901–4930, https://doi.org/10.5194/amt-15-4901-2022, https://doi.org/10.5194/amt-15-4901-2022, 2022
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Understanding fire emission impacts on the atmosphere is key to effective air quality management and requires accurate measurements. We present a comparison of airborne measurements of key atmospheric species in ambient air and in fire smoke. We show that most instruments performed within instrument uncertainties. In some cases, further work is needed to fully characterize instrument performance. Comparing independent measurements using different techniques is important to assess their accuracy.
Woohui Nam, Changmin Cho, Begie Perdigones, Tae Siek Rhee, and Kyung-Eun Min
Atmos. Meas. Tech., 15, 4473–4487, https://doi.org/10.5194/amt-15-4473-2022, https://doi.org/10.5194/amt-15-4473-2022, 2022
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We describe our vibration-resistant instrument for measuring ambient NO3, NO2, and H2O based on cavity-enhanced absorption spectroscopy. By simultaneous retrieval of H2O with the other species using a measured H2O absorption spectrum, direct quantifications among all species are possible without any pre-treatment for H2O. Our instrument achieves the effective light path to ~101.5 km, which allows the sensitive measurements of NO3 and NO2 as 1.41 pptv and 6.92 ppbv (1σ) in 1 s.
Yunsong Liu, Jean-Daniel Paris, Mihalis Vrekoussis, Panayiota Antoniou, Christos Constantinides, Maximilien Desservettaz, Christos Keleshis, Olivier Laurent, Andreas Leonidou, Carole Philippon, Panagiotis Vouterakos, Pierre-Yves Quéhé, Philippe Bousquet, and Jean Sciare
Atmos. Meas. Tech., 15, 4431–4442, https://doi.org/10.5194/amt-15-4431-2022, https://doi.org/10.5194/amt-15-4431-2022, 2022
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This paper details laboratory-based and field developments of a cost-effective and compacted UAV CO2 sensor system to address the challenge of measuring CO2 with sufficient precision and acquisition frequency. We assess its performance extensively through laboratory and field tests and provide a case study in an urban area (Nicosia, Cyprus). We therefore expect that this portable system will be widely used for measuring CO2 emission and distribution in natural or urban environments.
Subin Yoon, Alexander Kotsakis, Sergio L. Alvarez, Mark G. Spychala, Elizabeth Klovenski, Paul Walter, Gary Morris, Ernesto Corrales, Alfredo Alan, Jorge A. Diaz, and James H. Flynn
Atmos. Meas. Tech., 15, 4373–4384, https://doi.org/10.5194/amt-15-4373-2022, https://doi.org/10.5194/amt-15-4373-2022, 2022
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SO2 is adverse to human health and the environment. A single SO2 sonde was developed to provide direct SO2 measurement with a greater vertical extent, a lower limit of detection, and less uncertainty relative to the previous dual-sonde method. The single sonde was tested in the field near volcanoes and anthropogenic sources where the sonde measured SO2 ranging from 0.5 to 940 ppb. This lighter-weight payload can be a great candidate to attach to small drones and unmanned aerial vehicles.
Michael A. Robinson, J. Andrew Neuman, L. Gregory Huey, James M. Roberts, Steven S. Brown, and Patrick R. Veres
Atmos. Meas. Tech., 15, 4295–4305, https://doi.org/10.5194/amt-15-4295-2022, https://doi.org/10.5194/amt-15-4295-2022, 2022
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Iodide chemical ionization mass spectrometry (CIMS) is commonly used in atmospheric chemistry laboratory studies and field campaigns. Deployment of the NOAA iodide CIMS instrument in the summer of 2021 indicated a significant and overlooked temperature dependence of the instrument sensitivity. This work explores which analytes are influenced by this phenomena. Additionally, we recommend controls to reduce this effect for future field deployments.
Roland Vernooij, Patrik Winiger, Martin Wooster, Tercia Strydom, Laurent Poulain, Ulrike Dusek, Mark Grosvenor, Gareth J. Roberts, Nick Schutgens, and Guido R. van der Werf
Atmos. Meas. Tech., 15, 4271–4294, https://doi.org/10.5194/amt-15-4271-2022, https://doi.org/10.5194/amt-15-4271-2022, 2022
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Landscape fires are a substantial emitter of greenhouse gases and aerosols. Previous studies have indicated savanna emission factors to be highly variable. Improving fire emission estimates, and understanding future climate- and human-induced changes in fire regimes, requires in situ measurements. We present a drone-based method that enables the collection of a large amount of high-quality emission factor measurements that do not have the biases of aircraft or surface measurements.
Leigh S. Fleming, Andrew C. Manning, Penelope A. Pickers, Grant L. Forster, and Alex J. Etchells
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2022-207, https://doi.org/10.5194/amt-2022-207, 2022
Revised manuscript accepted for AMT
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Measurements of atmospheric O2 can help constrain the carbon cycle processes and quantify fossil fuel CO2 emissions; however, atmospheric O2 measurement is very challenging, and existing analysers are complex systems to build and maintain. We have tested a new O2 analyser (Picarro Inc. G2207-i) in the laboratory and at Weybourne Atmospheric Observatory. We have found that the G2207-i does not perform as well as an existing O2 analyser from Sable Systems Inc..
Andrew Walter Seidl, Harald Sodemann, and Hans Christian Steen-Larsen
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2022-208, https://doi.org/10.5194/amt-2022-208, 2022
Revised manuscript accepted for AMT
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It is challenging to make field measurements of stable water isotopes in the Arctic. To this end, we present a modular stable water isotope analyzer deployment system, the ISE-CUBEs. The system operated for a two week field campaign during the Arctic winter. We evaluate the system’s performance and analyze any potential impact that the field conditions might have had on the isotopic measurements.
Tobias Schuldt, Georgios I. Gkatzelis, Christian Wesolek, Franz Rohrer, Benjamin Winter, Thomas A. J. Kuhlbusch, Astrid Kiendler-Scharr, and Ralf Tillmann
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2022-186, https://doi.org/10.5194/amt-2022-186, 2022
Revised manuscript accepted for AMT
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We report in-situ measurements of air pollutant concentrations within the planetary boundary layer on board a Zeppelin NT in Germany. We highlight the in-flight evaluation of electrochemical sensors that were installed inside a hatch box located on the bottom of the Zeppelin. Results from this work emphasize the potential of these sensors for other in situ airborne applications, e.g., onboard unmanned aerial vehicles (UAVs).
Ralf Tillmann, Georgios I. Gkatzelis, Franz Rohrer, Benjamin Winter, Christian Wesolek, Tobias Schuldt, Anne C. Lange, Philipp Franke, Elmar Friese, Michael Decker, Robert Wegener, Morten Hundt, Oleg Aseev, and Astrid Kiendler-Scharr
Atmos. Meas. Tech., 15, 3827–3842, https://doi.org/10.5194/amt-15-3827-2022, https://doi.org/10.5194/amt-15-3827-2022, 2022
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We report in situ measurements of air pollutant concentrations within the planetary boundary layer on board a Zeppelin in Germany. The low costs of commercial flights provide an affordable and efficient method to improve our understanding of changes in emissions in space and time. The experimental setup expands the capabilities of this platform and provides insights into primary and secondary pollution observations and planetary boundary layer dynamics which determine air quality significantly.
Daan Swart, Jun Zhang, Shelley van der Graaf, Susanna Rutledge-Jonker, Arjan Hensen, Stijn Berkhout, Pascal Wintjen, René van der Hoff, Marty Haaima, Arnoud Frumau, Pim van den Bulk, Ruben Schulte, and Thomas van Goethem
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2022-171, https://doi.org/10.5194/amt-2022-171, 2022
Revised manuscript accepted for AMT
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During a five-week comparison campaign, we tested two setups that aim to measure half-hourly ammonia fluxes. The eddy covariance and flux gradient systems showed very similar results when the upwind terrain was both homogeneous and free of obstacles. We discuss the technical performance and practical limitations of both systems. Measurements from these instruments can facilitate the study of processes behind ammonia deposition, an important contributor to eutrophication in natural areas.
Mei Bai, Zoe Loh, David W. T. Griffith, Debra Turner, Richard Eckard, Robert Edis, Owen T. Denmead, Glenn W. Bryant, Clare Paton-Walsh, Matthew Tonini, Sean M. McGinn, and Deli Chen
Atmos. Meas. Tech., 15, 3593–3610, https://doi.org/10.5194/amt-15-3593-2022, https://doi.org/10.5194/amt-15-3593-2022, 2022
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The open-path laser (OPL) and open-path Fourier transform infrared (OP-FTIR) are used in agricultural research, but their error in emissions research has not been the focus of studies. We conducted trace gas release trials and herd and paddock emission studies to compare their applicability and performance. The OP-FTIR has better stability in stable conditions than OPL. The CH4 OPL accurately detects the low background level of CH4, but the NH3 OPL only detects background values >10 ppbv.
Roger Curcoll, Josep-Anton Morguí, Armand Kamnang, Lídia Cañas, Arturo Vargas, and Claudia Grossi
Atmos. Meas. Tech., 15, 2807–2818, https://doi.org/10.5194/amt-15-2807-2022, https://doi.org/10.5194/amt-15-2807-2022, 2022
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Low-cost air enquirer kits, including CO2 and environmental parameter sensors, have been designed, built, and tested in a new steady-state through-flow chamber for simultaneous measurements of CO2 fluxes in soil and CO2 concentrations in air. A CO2 calibration and multiparametric fitting reduced the total uncertainty of CO2 concentration by 90 %. This system allows continuous measurement of CO2 fluxes and CO2 ambient air, with low cost (EUR 1200), low energy demand (<5 W), and low maintenance.
Lisa von der Heyden, Walter Wißdorf, Ralf Kurtenbach, and Jörg Kleffmann
Atmos. Meas. Tech., 15, 1983–2000, https://doi.org/10.5194/amt-15-1983-2022, https://doi.org/10.5194/amt-15-1983-2022, 2022
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A relaxed eddy accumulation (REA) system based on the LOPAP technique for the quantification of vertical fluxes of nitrous acid (HONO) was developed and tested in a field campaign. Typical diurnal variations of the HONO fluxes were observed with low, partly negative fluxes during night-time and higher positive fluxes around noon. The highest correlation of the HONO flux was observed with the product of the NO2 photolysis frequency and the NO2 concentration.
Pieter Tans
Atmos. Meas. Tech., 15, 1903–1916, https://doi.org/10.5194/amt-15-1903-2022, https://doi.org/10.5194/amt-15-1903-2022, 2022
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The AirCore collects a continuous air sample in a long tube that can be read later when the captured air is slowly pushed through an analyzer. Much of the variation of gas composition encountered during collection is preserved, like having up to ~ 100 separate air samples. This is illustrated through examples of actual flights, and the analysis algorithm is described. The AirCore provides access to air as high as the mid stratosphere, enabling validation for satellite air composition soundings.
Peter Sperlich, Gordon W. Brailsford, Rowena C. Moss, John McGregor, Ross J. Martin, Sylvia Nichol, Sara Mikaloff-Fletcher, Beata Bukosa, Magda Mandic, C. Ian Schipper, Paul Krummel, and Alan D. Griffiths
Atmos. Meas. Tech., 15, 1631–1656, https://doi.org/10.5194/amt-15-1631-2022, https://doi.org/10.5194/amt-15-1631-2022, 2022
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We tested an in situ analyser for carbon and oxygen isotopes in atmospheric CO2 at Baring Head, New Zealand’s observatory for Southern Ocean baseline air. The analyser was able to resolve regional signals of the terrestrial carbon cycle, although the analysis of small events was limited by analytical uncertainty. Further improvement of the instrument performance would be desirable for the robust analysis of distant signals and to resolve the small variability in Southern Ocean baseline air.
Martin Breitenlechner, Gordon A. Novak, J. Andrew Neuman, Andrew W. Rollins, and Patrick R. Veres
Atmos. Meas. Tech., 15, 1159–1169, https://doi.org/10.5194/amt-15-1159-2022, https://doi.org/10.5194/amt-15-1159-2022, 2022
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We coupled a new ion source to a commercially available state-of-the-art trace gas analyzer. The instrument is particularly well suited for conducting high-altitude observations, addressing the challenges of low ambient pressures and a complex sample matrix. The new instrument and ion source provides significant advantages to more traditional modes of operation, without sacrificing the sensitivity and flexibility of this technique.
Jianqiang Zeng, Yanli Zhang, Huina Zhang, Wei Song, Zhenfeng Wu, and Xinming Wang
Atmos. Meas. Tech., 15, 79–93, https://doi.org/10.5194/amt-15-79-2022, https://doi.org/10.5194/amt-15-79-2022, 2022
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The emission of biogenic volatile organic compounds (BVOCs) from plant leaves is an essential part of biosphere–atmosphere interactions. Here we demonstrate how a dynamic chamber for measuring branch-scale BVOC emissions could be characterized both in the lab for adsorptive losses and in the field for ambient–enclosure environmental differences. The results also imply emission factors for terpenes might be underestimated if measured using dynamic chambers without certified transfer efficiencies.
Lukas Fischer, Martin Breitenlechner, Eva Canaval, Wiebke Scholz, Marcus Striednig, Martin Graus, Thomas G. Karl, Tuukka Petäjä, Markku Kulmala, and Armin Hansel
Atmos. Meas. Tech., 14, 8019–8039, https://doi.org/10.5194/amt-14-8019-2021, https://doi.org/10.5194/amt-14-8019-2021, 2021
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Ecosystems emit biogenic volatile organic compounds (BVOCs), which are then oxidized in the atmosphere, contributing to ozone and secondary aerosol formation. While flux measurements of BVOCs are state of the art, flux measurements of the less volatile oxidation products are difficult to achieve due to inlet losses. Here we present first flux measurements, utilizing a novel PTR3 instrument in combination with a specially designed wall-less inlet we put on top of the Hyytiälä tower in Finland.
Kevin S. Rozmiarek, Bruce H. Vaughn, Tyler R. Jones, Valerie Morris, William B. Skorski, Abigail G. Hughes, Jack Elston, Sonja Wahl, Anne-Katrine Faber, and Hans Christian Steen-Larsen
Atmos. Meas. Tech., 14, 7045–7067, https://doi.org/10.5194/amt-14-7045-2021, https://doi.org/10.5194/amt-14-7045-2021, 2021
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We have designed an unmanned aerial vehicle (UAV) sampling platform for operation in extreme polar environments that is capable of sampling atmospheric water vapor for subsequent measurement of water isotopes. During flight, we measure location, temperature, humidity, and pressure to determine the height of the planetary boundary layer (PBL) using algorithms, allowing for strategic decision-making by the pilot to collect samples in glass flasks contained in the nose cone of the UAV.
Stefan Metzger, David Durden, Sreenath Paleri, Matthias Sühring, Brian J. Butterworth, Christopher Florian, Matthias Mauder, David M. Plummer, Luise Wanner, Ke Xu, and Ankur R. Desai
Atmos. Meas. Tech., 14, 6929–6954, https://doi.org/10.5194/amt-14-6929-2021, https://doi.org/10.5194/amt-14-6929-2021, 2021
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The key points are the following. (i) Integrative observing system design can multiply the information gain of surface–atmosphere field measurements. (ii) Catalyzing numerical simulations and first-principles machine learning open up observing system simulation experiments to novel applications. (iii) Use cases include natural climate solutions, emission inventory validation, urban air quality, and industry leak detection.
Eric J. Hintsa, Fred L. Moore, Dale F. Hurst, Geoff S. Dutton, Bradley D. Hall, J. David Nance, Ben R. Miller, Stephen A. Montzka, Laura P. Wolton, Audra McClure-Begley, James W. Elkins, Emrys G. Hall, Allen F. Jordan, Andrew W. Rollins, Troy D. Thornberry, Laurel A. Watts, Chelsea R. Thompson, Jeff Peischl, Ilann Bourgeois, Thomas B. Ryerson, Bruce C. Daube, Yenny Gonzalez Ramos, Roisin Commane, Gregory W. Santoni, Jasna V. Pittman, Steven C. Wofsy, Eric Kort, Glenn S. Diskin, and T. Paul Bui
Atmos. Meas. Tech., 14, 6795–6819, https://doi.org/10.5194/amt-14-6795-2021, https://doi.org/10.5194/amt-14-6795-2021, 2021
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We built UCATS to study atmospheric chemistry and transport. It has measured trace gases including CFCs, N2O, SF6, CH4, CO, and H2 with gas chromatography, as well as ozone and water vapor. UCATS has been part of missions to study the tropical tropopause; transport of air into the stratosphere; greenhouse gases, transport, and chemistry in the troposphere; and ozone chemistry, on both piloted and unmanned aircraft. Its design, capabilities, and some results are shown and described here.
Clara M. Nussbaumer, Uwe Parchatka, Ivan Tadic, Birger Bohn, Daniel Marno, Monica Martinez, Roland Rohloff, Hartwig Harder, Flora Kluge, Klaus Pfeilsticker, Florian Obersteiner, Martin Zöger, Raphael Doerich, John N. Crowley, Jos Lelieveld, and Horst Fischer
Atmos. Meas. Tech., 14, 6759–6776, https://doi.org/10.5194/amt-14-6759-2021, https://doi.org/10.5194/amt-14-6759-2021, 2021
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NO2 plays a central role in atmospheric photochemical processes and requires accurate measurements. This research presents NO2 data obtained via chemiluminescence using a photolytic converter from airborne studies around Cabo Verde and laboratory investigations. We show the limits and error-proneness of a conventional blue light converter in aircraft measurements affected by humidity and NO levels and suggest the use of an alternative quartz converter for more reliable results.
Alexandra Gutmann, Nicole Bobrowski, Marcello Liotta, and Thorsten Hoffmann
Atmos. Meas. Tech., 14, 6395–6406, https://doi.org/10.5194/amt-14-6395-2021, https://doi.org/10.5194/amt-14-6395-2021, 2021
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Motivated by a special interest in bromine chemistry in volcanic plumes, the study presented here describes a new method for the quantitative collection of gaseous hydrogen bromide in gas diffusion denuders. The hydrogen bromide reacted during sampling with appropriate epoxides applied to the denuder walls. The denuder sampling assembly was successfully deployed in the volcanic plume of Masaya volcano, Nicaragua.
Rebecca L. Wagner, Naomi J. Farren, Jack Davison, Stuart Young, James R. Hopkins, Alastair C. Lewis, David C. Carslaw, and Marvin D. Shaw
Atmos. Meas. Tech., 14, 6083–6100, https://doi.org/10.5194/amt-14-6083-2021, https://doi.org/10.5194/amt-14-6083-2021, 2021
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We describe the use of a selected-ion flow-tube mass spectrometer (SIFT-MS) in a mobile laboratory to provide on-road, high spatial and temporal measurements of CO2, CH4, multiple volatile organic compounds (VOCs) and other trace gases. Results are presented that highlight the potential of this platform for developing characterisation methods of different emissions sources in complex urban areas.
Brandon Bottorff, Emily Reidy, Levi Mielke, Sebastien Dusanter, and Philip S. Stevens
Atmos. Meas. Tech., 14, 6039–6056, https://doi.org/10.5194/amt-14-6039-2021, https://doi.org/10.5194/amt-14-6039-2021, 2021
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Nitrous acid (HONO) is an important source of hydroxyl (OH) radicals, the primary oxidant in the atmosphere. Accurate measurements of HONO are thus important to understand the oxidative capacity of the atmosphere. A new instrument capable of measuring atmospheric nitrous acid (HONO) with high sensitivity is presented, utilizing laser photofragmentation of ambient HONO and subsequent detection of the OH radical fragment.
Federico Dallo, Daniele Zannoni, Jacopo Gabrieli, Paolo Cristofanelli, Francescopiero Calzolari, Fabrizio de Blasi, Andrea Spolaor, Dario Battistel, Rachele Lodi, Warren Raymond Lee Cairns, Ann Mari Fjæraa, Paolo Bonasoni, and Carlo Barbante
Atmos. Meas. Tech., 14, 6005–6021, https://doi.org/10.5194/amt-14-6005-2021, https://doi.org/10.5194/amt-14-6005-2021, 2021
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Our work showed how the adoption of low-cost technology could be useful in environmental research and monitoring. We focused our work on tropospheric ozone, but we also showed how to make a general purpose low-cost sensing system which may be adapted and optimised to be used in many other case studies. Given the importance of providing quality data, we put a lot of effort in the sensor's calibration, and we believe that our results show how to exploit the potential of the low-cost technology.
Hongming Yi, Mathieu Cazaunau, Aline Gratien, Vincent Michoud, Edouard Pangui, Jean-Francois Doussin, and Weidong Chen
Atmos. Meas. Tech., 14, 5701–5715, https://doi.org/10.5194/amt-14-5701-2021, https://doi.org/10.5194/amt-14-5701-2021, 2021
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HONO and NO2 play a crucial role in the atmospheric oxidation capacity that affects the regional air quality and global climate. Accurate measurements of HONO are challenging due to the drawback of existing detection methods. Calibration-free high-sensitivity direct, simultaneous measurements of NO2, HONO and CH2O with UV-IBBCEAS provide accurate and fast quantitative analysis of their concentration variation within their lifetime by intercomparison with NOx, FTIR and NitroMAC sensors.
Patrick Dewald, Raphael Dörich, Jan Schuladen, Jos Lelieveld, and John N. Crowley
Atmos. Meas. Tech., 14, 5501–5519, https://doi.org/10.5194/amt-14-5501-2021, https://doi.org/10.5194/amt-14-5501-2021, 2021
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Organic nitrates generated from the reaction between isoprene and the nitrate radical (ISOP-NITs) were detected via their thermal dissociation in heated quartz inlets to nitrogen dioxide monitored by cavity ring-down spectroscopy. The temperature-dependent dissociation profiles of ISOP-NITs in the presence of ozone (O3) are broad in contrast to narrow profiles of common reference compounds. We demonstrate that this broadening is caused by O3-assisted reactions of ISOP-NITs on quartz surfaces.
Erin R. Delaria, Jinsol Kim, Helen L. Fitzmaurice, Catherine Newman, Paul J. Wooldridge, Kevin Worthington, and Ronald C. Cohen
Atmos. Meas. Tech., 14, 5487–5500, https://doi.org/10.5194/amt-14-5487-2021, https://doi.org/10.5194/amt-14-5487-2021, 2021
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The use of a dense network of low-cost CO2 sensors is an attractive option for measuring CO2 emissions in cities. However, these low-cost sensors are also subject to uncertainties. Here, we describe a novel method of field calibration for correcting temperature-related errors in the CO2 sensors deployed in the BEACO2N network. We show that with this temperature correction, we can achieve a sufficiently low network error to allow for the evaluation of CO2 emissions at a neighborhood scale.
Raphael Dörich, Philipp Eger, Jos Lelieveld, and John N. Crowley
Atmos. Meas. Tech., 14, 5319–5332, https://doi.org/10.5194/amt-14-5319-2021, https://doi.org/10.5194/amt-14-5319-2021, 2021
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We demonstrate in laboratory experiments that the formation of IOx anions (formed in reactions of I− with O3) or acetate anions (formed e.g. by the reaction of I− with peracetic acid) results in unexpected sensitivity of an iodide chemical ionisation mass spectrometer (I-CIMS) to HNO3 at a mass-to-charge ratio of 62. This helps explain observations of apparent high daytime levels of N2O5. Airborne measurements using I-CIMS confirm these conclusions.
Corinna Kloss, Vicheith Tan, J. Brian Leen, Garrett L. Madsen, Aaron Gardner, Xu Du, Thomas Kulessa, Johannes Schillings, Herbert Schneider, Stefanie Schrade, Chenxi Qiu, and Marc von Hobe
Atmos. Meas. Tech., 14, 5271–5297, https://doi.org/10.5194/amt-14-5271-2021, https://doi.org/10.5194/amt-14-5271-2021, 2021
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We describe the innovative analyzer
AMICAfor airborne trace gas measurements by infrared spectroscopy. Its design makes it robust and allows for sensitive measurements. AMICA has been used on two different aircraft for measuring gases including carbonyl sulfide, carbon monoxide and ozone. With fairly simple adaptions, AMICA can measure many stable trace gases that absorb light in the infrared.
Sara M. Defratyka, Jean-Daniel Paris, Camille Yver-Kwok, Daniel Loeb, James France, Jon Helmore, Nigel Yarrow, Valérie Gros, and Philippe Bousquet
Atmos. Meas. Tech., 14, 5049–5069, https://doi.org/10.5194/amt-14-5049-2021, https://doi.org/10.5194/amt-14-5049-2021, 2021
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We consider the possibility of using the CRDS Picarro G2201-i instrument, originally designed for isotopic CH4 and CO2, for measurements of ethane : methane in near-source conditions. The work involved laboratory tests, a controlled release experiment and mobile measurements. We show the potential of determining ethane : methane with 50 ppb ethane uncertainty. The instrument can correctly estimate the ratio in CH4 enhancements of 1 ppm and more, as can be found at strongly emitting sites.
Esther Borrás, Luis A. Tortajada-Genaro, Milagro Ródenas, Teresa Vera, Thomas Speak, Paul Seakins, Marvin D. Shaw, Alastair C. Lewis, and Amalia Muñoz
Atmos. Meas. Tech., 14, 4989–4999, https://doi.org/10.5194/amt-14-4989-2021, https://doi.org/10.5194/amt-14-4989-2021, 2021
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This work presents promising results in the characterization of specific atmospheric pollutants (oxygenated VOCs) present at very low but highly relevant concentrations.
We carried out this research at EUPHORE facilities within the framework of the EUROCHAMP project. A new analytical method, with high robustness and precision, also clean in the use of solvents, low cost, and easily adaptable for use in mobile laboratories for air quality monitoring, is presented.
Chunmeng Li, Haichao Wang, Xiaorui Chen, Tianyu Zhai, Shiyi Chen, Xin Li, Limin Zeng, and Keding Lu
Atmos. Meas. Tech., 14, 4033–4051, https://doi.org/10.5194/amt-14-4033-2021, https://doi.org/10.5194/amt-14-4033-2021, 2021
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We present a feasible instrument for the measurement of NO2, total peroxy nitrates (PNs, RO2NO2), and total alkyl nitrates (ANs, RONO2) in the atmosphere. The instrument samples sequentially from three channels at different temperature settings and then measures spectra using one cavity-enhanced absorption spectrometer. The concentrations are determined by spectral fitting and corrected using the lookup table method conveniently. The instrument will promote the study of PNs and ANs.
Romain Blot, Philippe Nedelec, Damien Boulanger, Pawel Wolff, Bastien Sauvage, Jean-Marc Cousin, Gilles Athier, Andreas Zahn, Florian Obersteiner, Dieter Scharffe, Hervé Petetin, Yasmine Bennouna, Hannah Clark, and Valérie Thouret
Atmos. Meas. Tech., 14, 3935–3951, https://doi.org/10.5194/amt-14-3935-2021, https://doi.org/10.5194/amt-14-3935-2021, 2021
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A lack of information about temporal changes in measurement uncertainties is an area of concern for long-term trend studies of the key compounds which have a direct or indirect impact on climate change. The IAGOS program has measured O3 and CO within the troposphere and lower stratosphere for more than 25 years. In this study, we demonstrated that the IAGOS database can be treated as one continuous program and is therefore appropriate for studies of long-term trends.
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Short summary
The exchange rate of carbon dioxide (CO2) between the atmosphere and the sea is typically small compared to the fluxes observed in the terrestrial ecosystems, causing technical challenges for the measurements of the CO2 sea–air fluxes. In this paper, we examine CO2 sea–air flux measurements carried out on a fixed station on an island. The problems generated by water vapor interference and unmet theoretical assumptions of the eddy covariance method are addressed.
The exchange rate of carbon dioxide (CO2) between the atmosphere and the sea is typically small...
