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AMT | Articles | Volume 12, issue 12
Atmos. Meas. Tech., 12, 6635–6646, 2019
https://doi.org/10.5194/amt-12-6635-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Meas. Tech., 12, 6635–6646, 2019
https://doi.org/10.5194/amt-12-6635-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 17 Dec 2019

Research article | 17 Dec 2019

Multi-scheme chemical ionization inlet (MION) for fast switching of reagent ion chemistry in atmospheric pressure chemical ionization mass spectrometry (CIMS) applications

Matti P. Rissanen et al.

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Cited articles

Agarwal, B., Méndéz, R. G., Lanza, M., Sulzer, P., Märk, T. D., Thomas, N., and Mayhew, C. A.: Sensitivity and Selectivity of Switchable Reagent Ion Soft Chemical Ionization Mass Spectrometry for the Detection of Picric Acid, J. Phys. Chem. A, 118, 8229–8236, 2014. 
Albrecht, S. R., Novelli, A., Hofzumahaus, A., Kang, S., Baker, Y., Mentel, T., Wahner, A., and Fuchs, H.: Measurements of hydroperoxy radicals (HO2) at atmospheric concentrations using bromide chemical ionisation mass spectrometry, Atmos. Meas. Tech., 12, 891–902, https://doi.org/10.5194/amt-12-891-2019, 2019. 
Baeza-Romero, M. T., Blitz, M. A., Goddard, A., and Seakins, P. W.: Time-of-flight mass spectrometry for time-resolved measurements: Some developments and applications, Int J. Chem. Kin., 44, 532–545, 2011. 
Berndt, T., Richters, S., Kaethner, R., Voigtländer, J., Stratmann, F., Sipilä, M., Kulmala, M., and Herrmann, H.: Gas-Phase Ozonolysis of Cycloalkenes: Formation of Highly Oxidized RO2 Radicals and Their Reactions with NO, NO2, SO2, and Other RO2 Radicals, J. Phys. Chem. A, 119, 10336–10348, 2015. 
Bianchi, F., Kurtén, T., Riva, M., Mohr, C., Rissanen, M. P., Roldin, P., Berndt, T., Crounse, J. D., Wennberg, P. O., Mentel, T. F., Wildt, J., Junninen, H., Jokinen, T., Kulmala, M., Worsnop, D. R., Thornton, J. A., Donahue, N., Kjaergaard, H. G., and Ehn, M.: Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol, Chem. Rev., 119, 3472–3509, 2019. 
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Short summary
A novel chemical ionization methodology for rapid gas–phase environmental monitoring is presented. The usefulness of the new inlet design is demonstrated by measuring various aerosol precursor compounds that are present at very low concentrations by using two consecutive ionization schemes. This new inlet enables the detection of a wide range of compounds of interest with a minimum of effort and at a fast repetition rate.
A novel chemical ionization methodology for rapid gas–phase environmental monitoring is...
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