Articles | Volume 14, issue 8
https://doi.org/10.5194/amt-14-5501-2021
https://doi.org/10.5194/amt-14-5501-2021
Research article
 | 
12 Aug 2021
Research article |  | 12 Aug 2021

Impact of ozone and inlet design on the quantification of isoprene-derived organic nitrates by thermal dissociation cavity ring-down spectroscopy (TD-CRDS)

Patrick Dewald, Raphael Dörich, Jan Schuladen, Jos Lelieveld, and John N. Crowley

Related authors

Influence of ambient NO and NO2 on the quantification of total peroxy nitrates (∑PNs) and total alkyl nitrates (∑ANs) by thermal dissociation cavity ring-down spectroscopy (TD-CRDS)
Laura Wüst, Patrick Dewald, Gunther N. T. E. Türk, Jos Lelieveld, and John N. Crowley
EGUsphere, https://doi.org/10.5194/egusphere-2024-3694,https://doi.org/10.5194/egusphere-2024-3694, 2024
Short summary
Short lifetimes of organic nitrates in a sub-urban temperate forest indicate efficient assimilation of reactive nitrogen by the biosphere
Simone T. Andersen, Rolf Sander, Patrick Dewald, Laura Wüst, Tobias Seubert, Gunther N. T. E. Türk, Jan Schuladen, Max R. McGillen, Chaoyang Xue, Abdelwahid Mellouki, Alexandre Kukui, Vincent Michoud, Manuela Cirtog, Mathieu Cazaunau, Astrid Bauville, Hichem Bouzidi, Paola Formenti, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Christopher Cantrell, Jos Lelieveld, and John N. Crowley
EGUsphere, https://doi.org/10.5194/egusphere-2024-3437,https://doi.org/10.5194/egusphere-2024-3437, 2024
Short summary
Measurement report: Sources, sinks, and lifetime of NOx in a suburban temperate forest at night
Simone T. Andersen, Max R. McGillen, Chaoyang Xue, Tobias Seubert, Patrick Dewald, Gunther N. T. E. Türk, Jan Schuladen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Abdelwahid Mellouki, Lucy J. Carpenter, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 11603–11618, https://doi.org/10.5194/acp-24-11603-2024,https://doi.org/10.5194/acp-24-11603-2024, 2024
Short summary
NO3 reactivity during a summer period in a temperate forest below and above the canopy
Patrick Dewald, Tobias Seubert, Simone T. Andersen, Gunther N. T. E. Türk, Jan Schuladen, Max R. McGillen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Chaoyang Xue, Abdelwahid Mellouki, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 8983–8997, https://doi.org/10.5194/acp-24-8983-2024,https://doi.org/10.5194/acp-24-8983-2024, 2024
Short summary
Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation
Philip T. M. Carlsson, Luc Vereecken, Anna Novelli, François Bernard, Steven S. Brown, Bellamy Brownwood, Changmin Cho, John N. Crowley, Patrick Dewald, Peter M. Edwards, Nils Friedrich, Juliane L. Fry, Mattias Hallquist, Luisa Hantschke, Thorsten Hohaus, Sungah Kang, Jonathan Liebmann, Alfred W. Mayhew, Thomas Mentel, David Reimer, Franz Rohrer, Justin Shenolikar, Ralf Tillmann, Epameinondas Tsiligiannis, Rongrong Wu, Andreas Wahner, Astrid Kiendler-Scharr, and Hendrik Fuchs
Atmos. Chem. Phys., 23, 3147–3180, https://doi.org/10.5194/acp-23-3147-2023,https://doi.org/10.5194/acp-23-3147-2023, 2023
Short summary

Related subject area

Subject: Gases | Technique: In Situ Measurement | Topic: Instruments and Platforms
Development of a portable laser-flash photolysis Faraday rotation spectrometer for measuring atmospheric total OH reactivity
Bo Fang, Nana Wei, Weixiong Zhao, Nana Yang, Hao Zhou, Heng Zhang, Jiarong Li, Weijun Zhang, Yanyu Lu, Zhu Zhu, and Yue Liu
Atmos. Meas. Tech., 18, 1243–1256, https://doi.org/10.5194/amt-18-1243-2025,https://doi.org/10.5194/amt-18-1243-2025, 2025
Short summary
Surface distributions and vertical profiles of trace gases (CO, O3, NO, NO2) in the Arctic wintertime boundary layer using low-cost sensors during ALPACA-2022
Brice Barret, Patrice Medina, Natalie Brett, Roman Pohorsky, Kathy S. Law, Slimane Bekki, Gilberto J. Fochesatto, Julia Schmale, Steve R. Arnold, Andrea Baccarini, Maurizio Busetto, Meeta Cesler-Maloney, Barbara D'Anna, Stefano Decesari, Jingqiu Mao, Gianluca Pappaccogli, Joel Savarino, Federico Scoto, and William R. Simpson
Atmos. Meas. Tech., 18, 1163–1184, https://doi.org/10.5194/amt-18-1163-2025,https://doi.org/10.5194/amt-18-1163-2025, 2025
Short summary
Advances in an OH reactivity instrument for airborne field measurements
Hendrik Fuchs, Aaron Stainsby, Florian Berg, René Dubus, Michelle Färber, Andreas Hofzumahaus, Frank Holland, Kelvin H. Bates, Steven S. Brown, Matthew M. Coggon, Glenn S. Diskin, Georgios I. Gkatzelis, Christopher M. Jernigan, Jeff Peischl, Michael A. Robinson, Andrew W. Rollins, Nell B. Schafer, Rebecca H. Schwantes, Chelsea E. Stockwell, Patrick R. Veres, Carsten Warneke, Eleanor M. Waxman, Lu Xu, Kristen Zuraski, Andreas Wahner, and Anna Novelli
Atmos. Meas. Tech., 18, 881–895, https://doi.org/10.5194/amt-18-881-2025,https://doi.org/10.5194/amt-18-881-2025, 2025
Short summary
The ASK-16 motorized glider: an airborne eddy covariance platform to measure turbulence, energy, and matter fluxes
Inge Wiekenkamp, Anna Katharina Lehmann, Alexander Bütow, Jörg Hartmann, Stefan Metzger, Thomas Ruhtz, Christian Wille, Mathias Zöllner, and Torsten Sachs
Atmos. Meas. Tech., 18, 749–772, https://doi.org/10.5194/amt-18-749-2025,https://doi.org/10.5194/amt-18-749-2025, 2025
Short summary
Development of a Peltier-based chilled-mirror hygrometer, SKYDEW, for tropospheric and lower-stratospheric water vapor measurements
Takuji Sugidachi, Masatomo Fujiwara, Kensaku Shimizu, Shin-Ya Ogino, Junko Suzuki, and Ruud J. Dirksen
Atmos. Meas. Tech., 18, 509–531, https://doi.org/10.5194/amt-18-509-2025,https://doi.org/10.5194/amt-18-509-2025, 2025
Short summary

Cited articles

Bach, R. D. and Schlegel, H. B.: Bond Dissociation Energy of Peroxides Revisited, J. Phys. Chem. A, 124, 4742–4751, https://doi.org/10.1021/acs.jpca.0c02859, 2020. 
Barnes, I., Bastian, V., Becker, K. H., and Tong, Z.: Kinetics and products of the reactions of NO3 with monoalkenes, dialkenes, and monoterpenes, J. Phys. Chem., 94, 2413–2419, https://doi.org/10.1021/j100369a041, 1990. 
Bates, K. H. and Jacob, D. J.: A new model mechanism for atmospheric oxidation of isoprene: global effects on oxidants, nitrogen oxides, organic products, and secondary organic aerosol, Atmos. Chem. Phys., 19, 9613–9640, https://doi.org/10.5194/acp-19-9613-2019, 2019. 
Beaver, M. R., Clair, J. M. St., Paulot, F., Spencer, K. M., Crounse, J. D., LaFranchi, B. W., Min, K. E., Pusede, S. E., Wooldridge, P. J., Schade, G. W., Park, C., Cohen, R. C., and Wennberg, P. O.: Importance of biogenic precursors to the budget of organic nitrates: observations of multifunctional organic nitrates by CIMS and TD-LIF during BEARPEX 2009, Atmos. Chem. Phys., 12, 5773–5785, https://doi.org/10.5194/acp-12-5773-2012, 2012. 
Berndt, T. and Boge, O.: Products and Mechanism of the Reaction of NO3 with Selected Acyclic Monoalkenes, J. Atmos. Chem., 21, 275–291, https://doi.org/10.1007/Bf00696759, 1995. 
Download
Short summary
Organic nitrates generated from the reaction between isoprene and the nitrate radical (ISOP-NITs) were detected via their thermal dissociation in heated quartz inlets to nitrogen dioxide monitored by cavity ring-down spectroscopy. The temperature-dependent dissociation profiles of ISOP-NITs in the presence of ozone (O3) are broad in contrast to narrow profiles of common reference compounds. We demonstrate that this broadening is caused by O3-assisted reactions of ISOP-NITs on quartz surfaces.
Share