Articles | Volume 16, issue 6
https://doi.org/10.5194/amt-16-1551-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-16-1551-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Short-term variability of atmospheric helium revealed through a cryo-enrichment method
Scripps Institution of Oceanography, University of California San Diego, La Jolla, CA 92037, USA
Eric Morgan
Scripps Institution of Oceanography, University of California San Diego, La Jolla, CA 92037, USA
Ralph F. Keeling
Scripps Institution of Oceanography, University of California San Diego, La Jolla, CA 92037, USA
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Benjamin Birner, William Paplawsky, Jeffrey Severinghaus, and Ralph F. Keeling
Atmos. Meas. Tech., 14, 2515–2527, https://doi.org/10.5194/amt-14-2515-2021, https://doi.org/10.5194/amt-14-2515-2021, 2021
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The atmospheric helium-to-nitrogen ratio is a promising indicator for circulation changes in the upper atmosphere and fossil fuel burning by humans. We present a very precise analysis method to determine changes in the helium-to-nitrogen ratio of air samples. The method relies on stabilizing the gas flow to a mass spectrometer and continuous removal of reactive gases. These advances enable new insights and monitoring possibilities for anthropogenic and natural processes.
Benjamin Birner, Martyn P. Chipperfield, Eric J. Morgan, Britton B. Stephens, Marianna Linz, Wuhu Feng, Chris Wilson, Jonathan D. Bent, Steven C. Wofsy, Jeffrey Severinghaus, and Ralph F. Keeling
Atmos. Chem. Phys., 20, 12391–12408, https://doi.org/10.5194/acp-20-12391-2020, https://doi.org/10.5194/acp-20-12391-2020, 2020
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With new high-precision observations from nine aircraft campaigns and 3-D chemical transport modeling, we show that the argon-to-nitrogen ratio (Ar / N2) in the lowermost stratosphere provides a useful constraint on the “age of air” (the time elapsed since entry of an air parcel into the stratosphere). Therefore, Ar / N2 in combination with traditional age-of-air indicators, such as CO2 and N2O, could provide new insights into atmospheric mixing and transport.
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Christian Rödenbeck, Karina E. Adcock, Markus Eritt, Maksym Gachkivskyi, Christoph Gerbig, Samuel Hammer, Armin Jordan, Ralph F. Keeling, Ingeborg Levin, Fabian Maier, Andrew C. Manning, Heiko Moossen, Saqr Munassar, Penelope A. Pickers, Michael Rothe, Yasunori Tohjima, and Sönke Zaehle
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Douglas E. J. Worthy, Michele K. Rauh, Lin Huang, Felix R. Vogel, Alina Chivulescu, Kenneth A. Masarie, Ray L. Langenfelds, Paul B. Krummel, Colin E. Allison, Andrew M. Crotwell, Monica Madronich, Gabrielle Pétron, Ingeborg Levin, Samuel Hammer, Sylvia Michel, Michel Ramonet, Martina Schmidt, Armin Jordan, Heiko Moossen, Michael Rothe, Ralph Keeling, and Eric J. Morgan
Atmos. Meas. Tech., 16, 5909–5935, https://doi.org/10.5194/amt-16-5909-2023, https://doi.org/10.5194/amt-16-5909-2023, 2023
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Network compatibility is important for inferring greenhouse gas fluxes at global or regional scales. This study is the first assessment of the measurement agreement among seven individual programs within the World Meteorological Organization community. It compares co-located flask air measurements at the Alert Observatory in Canada over a 17-year period. The results provide stronger confidence in the uncertainty estimation while using those datasets in various data interpretation applications.
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Nobuyuki Aoki, Shigeyuki Ishidoya, Yasunori Tohjima, Shinji Morimoto, Ralph F. Keeling, Adam Cox, Shuichiro Takebayashi, and Shohei Murayama
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Yenny Gonzalez, Róisín Commane, Ethan Manninen, Bruce C. Daube, Luke D. Schiferl, J. Barry McManus, Kathryn McKain, Eric J. Hintsa, James W. Elkins, Stephen A. Montzka, Colm Sweeney, Fred Moore, Jose L. Jimenez, Pedro Campuzano Jost, Thomas B. Ryerson, Ilann Bourgeois, Jeff Peischl, Chelsea R. Thompson, Eric Ray, Paul O. Wennberg, John Crounse, Michelle Kim, Hannah M. Allen, Paul A. Newman, Britton B. Stephens, Eric C. Apel, Rebecca S. Hornbrook, Benjamin A. Nault, Eric Morgan, and Steven C. Wofsy
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Britton B. Stephens, Eric J. Morgan, Jonathan D. Bent, Ralph F. Keeling, Andrew S. Watt, Stephen R. Shertz, and Bruce C. Daube
Atmos. Meas. Tech., 14, 2543–2574, https://doi.org/10.5194/amt-14-2543-2021, https://doi.org/10.5194/amt-14-2543-2021, 2021
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Benjamin Birner, William Paplawsky, Jeffrey Severinghaus, and Ralph F. Keeling
Atmos. Meas. Tech., 14, 2515–2527, https://doi.org/10.5194/amt-14-2515-2021, https://doi.org/10.5194/amt-14-2515-2021, 2021
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The atmospheric helium-to-nitrogen ratio is a promising indicator for circulation changes in the upper atmosphere and fossil fuel burning by humans. We present a very precise analysis method to determine changes in the helium-to-nitrogen ratio of air samples. The method relies on stabilizing the gas flow to a mass spectrometer and continuous removal of reactive gases. These advances enable new insights and monitoring possibilities for anthropogenic and natural processes.
Yuming Jin, Ralph F. Keeling, Eric J. Morgan, Eric Ray, Nicholas C. Parazoo, and Britton B. Stephens
Atmos. Chem. Phys., 21, 217–238, https://doi.org/10.5194/acp-21-217-2021, https://doi.org/10.5194/acp-21-217-2021, 2021
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We propose a new atmospheric coordinate (Mθe) based on equivalent potential temperature (θe) but with mass as the unit. This coordinate is useful in studying the spatial and temporal distribution of long-lived chemical tracers (CO2, CH4, O2 / N2, etc.) from sparse data, like airborne observation. Using this coordinate and sparse airborne observation (HIPPO and ATom), we resolve the Northern Hemisphere mass-weighted average CO2 seasonal cycle with high accuracy.
Benjamin Birner, Martyn P. Chipperfield, Eric J. Morgan, Britton B. Stephens, Marianna Linz, Wuhu Feng, Chris Wilson, Jonathan D. Bent, Steven C. Wofsy, Jeffrey Severinghaus, and Ralph F. Keeling
Atmos. Chem. Phys., 20, 12391–12408, https://doi.org/10.5194/acp-20-12391-2020, https://doi.org/10.5194/acp-20-12391-2020, 2020
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With new high-precision observations from nine aircraft campaigns and 3-D chemical transport modeling, we show that the argon-to-nitrogen ratio (Ar / N2) in the lowermost stratosphere provides a useful constraint on the “age of air” (the time elapsed since entry of an air parcel into the stratosphere). Therefore, Ar / N2 in combination with traditional age-of-air indicators, such as CO2 and N2O, could provide new insights into atmospheric mixing and transport.
Cited articles
Birner, B., Chipperfield, M. P., Morgan, E. J., Stephens, B. B., Linz, M., Feng, W., Wilson, C., Bent, J. D., Wofsy, S. C., Severinghaus, J., and Keeling, R. F.:
Gravitational separation of and age of air in the lowermost stratosphere in airborne observations and a chemical transport model, Atmos. Chem. Phys., 20, 12391–12408, https://doi.org/10.5194/acp-20-12391-2020, 2020.
Birner, B., Paplawsky, W., Severinghaus, J., and Keeling, R. F.:
A method for resolving changes in atmospheric as an indicator of fossil fuel extraction and stratospheric circulation, Atmos. Meas. Tech., 14, 2515–2527, https://doi.org/10.5194/amt-14-2515-2021, 2021.
Birner, B., Severinghaus, J., Paplawsky, B., and Keeling, R. F.:
Increasing atmospheric helium due to fossil fuel exploitation, Nat. Geosci., 15, 346–348, https://doi.org/10.1038/s41561-022-00932-3, 2022a.
Birner, B., Morgan, E., and Keeling, R.: Data from: Short-term variability of atmospheric helium revealed through a cryo-enrichment method, UC San Diego Library Digital Collections [data set], https://doi.org/10.6075/J0J966JF, 2022b.
Blaine, T. W., Keeling, R. F., and Paplawsky, W. J.:
An improved inlet for precisely measuring the atmospheric ratio, Atmos. Chem. Phys., 6, 1181–1184, https://doi.org/10.5194/acp-6-1181-2006, 2006.
Boucher, C., Marty, B., Zimmermann, L., and Langenfelds, R.:
Atmospheric helium isotopic ratio from 1910 to 2016 recorded in stainless steel containers, Geochem. Perspect. Lett., 6, 23–27, https://doi.org/10.7185/geochemlet.1804, 2018a.
Boucher, C., Lan, T., Mabry, J., Bekaert, D. V., Burnard, P. G., and Marty, B.:
Spatial analysis of the atmospheric helium isotopic composition: Geochemical and environmental implications, Geochim. Cosmochim. Ac., 237, 120–130, https://doi.org/10.1016/j.gca.2018.06.010, 2018b.
Glückauf, E.:
A simple analysis of the helium content of air, T. Faraday Soc., 44, 436–439, 1944.
Graven, H. D., Guilderson, T. P., and Keeling, R. F.:
Observations of radiocarbon in CO2 at La Jolla, California, USA 1992-2007: Analysis of the long-term trend, J. Geophys. Res.-Atmos., 117, 1–14, https://doi.org/10.1029/2011JD016533, 2012.
Gurney, K. R., Liang, J., Patarasuk, R., Song, Y., Huang, J., and Roest, G.:
The Vulcan Version 3.0 High-Resolution Fossil Fuel CO2 Emissions for the United States, J. Geophys. Res.-Atmos., 125, 1–27, https://doi.org/10.1029/2020JD032974, 2020.
Holton, J. R., Haynes, P. H., Mcintyre, M. E., Douglass, A. R., and Rood, B.:
Stratosphere-Troposphere exchange, Rev. Geophys., 33, 403–439, 1995.
Ishidoya, S., Sugawara, S., Morimoto, S., Aoki, S., and Nakazawa, T.:
Gravitational separation of major atmospheric components of nitrogen and oxygen in the stratosphere, Geophys. Res. Lett., 35, 1–5, https://doi.org/10.1029/2007GL030456, 2008.
Ishidoya, S., Sugawara, S., Morimoto, S., Aoki, S., Nakazawa, T., Honda, H., and Murayama, S.:
Gravitational separation in the stratosphere – a new indicator of atmospheric circulation, Atmos. Chem. Phys., 13, 8787–8796, https://doi.org/10.5194/acp-13-8787-2013, 2013.
Jordan, A. and Steinberg, B.:
Calibration of atmospheric hydrogen measurements, Atmos. Meas. Tech., 4, 509–521, https://doi.org/10.5194/amt-4-509-2011, 2011.
Keeling, R. and Shertz, S.:
Atmospheric oxygen and implications for the global carbon cycle, Nature, 358, 723–727, https://doi.org/10.1038/358723a0, 1992.
Keeling, R. F., Manning, A. C., McEvoy, E. M., and Shertz, S. R.:
Methods for measuring changes in atmospheric O2 concentration and their application in southern hemisphere air, J. Geophys. Res., 103, 3381–3397, https://doi.org/10.1029/97JD02537, 1998.
Keeling, R. F., Blaine, T., Paplawsky, B., Katz, L., Atwood, C., and Brockwell, T.:
Measurement of changes in atmospheric ratio using a rapid-switching, single-capillary mass spectrometer system, Tellus, 56B, 322–338, https://doi.org/10.1111/j.1600-0889.2004.00117.x, 2004.
Lupton, J. and Evans, L.:
The atmospheric helium isotope ratio: Is it changing?, Geophys. Res. Lett., 31, 1–4, https://doi.org/10.1029/2004GL020041, 2004.
Lupton, J. and Evans, L.:
Changes in the atmospheric helium isotope ratio over the past 40 years, Geophys. Res. Lett., 40, 6271–6275, https://doi.org/10.1002/2013GL057681, 2013.
Manning, A. C., Keeling, R. F., and Severinghaus, P.:
Precise atmospheric oxygen measurements with a paramagnetic oxygen analyzer several repeated measurements interval various aspects of the global The analyzer was used to measure atmospheric period strongly changes sources to define, Global Biogeochem. Cy., 13, 1107–1115, 1999.
Montzka, S. A., Dutton, G. S., Yu, P., Ray, E., Portmann, R. W., Daniel, J. S., Kuijpers, L., Hall, B. D., Mondeel, D., Siso, C., Nance, J. D., Rigby, M., Manning, A. J., Hu, L., Moore, F., Miller, B. R., and Elkins, J. W.:
An unexpected and persistent increase in global emissions of ozone-depleting CFC-11, Nature, 557, 413–417, https://doi.org/10.1038/s41586-018-0106-2, 2018.
Mühle, J., Ganesan, A. L., Miller, B. R., Salameh, P. K., Harth, C. M., Greally, B. R., Rigby, M., Porter, L. W., Steele, L. P., Trudinger, C. M., Krummel, P. B., O'Doherty, S., Fraser, P. J., Simmonds, P. G., Prinn, R. G., and Weiss, R. F.:
Perfluorocarbons in the global atmosphere: tetrafluoromethane, hexafluoroethane, and octafluoropropane, Atmos. Chem. Phys., 10, 5145–5164, https://doi.org/10.5194/acp-10-5145-2010, 2010.
Nevison, C. D., Dlugokencky, E., Dutton, G., Elkins, J. W., Fraser, P., Hall, B., Krummel, P. B., Langenfelds, R. L., O'Doherty, S., Prinn, R. G., Steele, L. P., and Weiss, R. F.:
Exploring causes of interannual variability in the seasonal cycles of tropospheric nitrous oxide, Atmos. Chem. Phys., 11, 3713–3730, https://doi.org/10.5194/acp-11-3713-2011, 2011.
Oliver, B. M., Bradley, J. G., and Farrar IV, H.:
Helium concentration in the Earth's lower atmosphere, Geochim. Cosmochim. Ac., 48, 1759–1767, https://doi.org/10.1016/0016-7037(84)90030-9, 1984.
Patra, P. K., Takigawa, M., Dutton, G. S., Uhse, K., Ishijima, K., Lintner, B. R., Miyazaki, K., and Elkins, J. W.:
Transport mechanisms for synoptic, seasonal and interannual SF6 variations and “age” of air in troposphere, Atmos. Chem. Phys., 9, 1209–1225, https://doi.org/10.5194/acp-9-1209-2009, 2009.
Patterson, J. D., Aydin, M., Crotwell, A. M., Pétron, G., Severinghaus, J. P., Krummel, P. B., Langenfelds, R. L., and Saltzman, E. S.:
H2 in Antarctic firn air: Atmospheric reconstructions and implications for anthropogenic emissions, P. Natl. Acad. Sci. USA, 118, 1–8, https://doi.org/10.1073/pnas.2103335118, 2021.
Pierson-Wickmann, A. C., Marty, B., and Ploquin, A.:
Helium trapped in historical slags: A search for temporal variation of the He isotopic composition of air, Earth Planet. Sc. Lett., 194, 165–175, https://doi.org/10.1016/S0012-821X(01)00554-4, 2001.
Ray, E. A., Portmann, R. W., Yu, P., Daniel, J., Montzka, S. A., Dutton, G. S., Hall, B. D., Moore, F. L., and Rosenlof, K. H.:
The influence of the stratospheric Quasi-Biennial Oscillation on trace gas levels at the Earth's surface, Nat. Geosci., 13, 22–27, https://doi.org/10.1038/s41561-019-0507-3, 2020.
Riley, W. J., Randerson, J. T., Foster, P. N., and Lueker, T. J.:
Influence of terrestrial ecosystems and topography on coastal CO2 measurements: A case study at Trinidad Head, California, J. Geophys. Res., 110, 1–15, https://doi.org/10.1029/2004jg000007, 2005.
Salby, M. L. and Callaghan, P. F.:
Influence of the Brewer-Dobson circulation on stratosphere-troposphere exchange, J. Geophys. Res.-Atmos., 111, 1–9, https://doi.org/10.1029/2006JD007051, 2006.
Sano, Y., Wakita, H., Makide, Y., and Tominaga, T.:
A ten-year decrease in the atmospheric helium isotope ratio possibly caused by human activity, Geophys. Res. Lett., 16, 1371–1374, https://doi.org/10.1029/GL016i012p01371, 1989.
Sano, Y., Furukawa, Y., and Takahata, N.:
Atmospheric helium isotope ratio: Possible temporal and spatial variations, Geochim. Cosmochim. Ac., 74, 4893–4901, https://doi.org/10.1016/j.gca.2010.06.003, 2010.
Škerlak, B., Sprenger, M., and Wernli, H.:
A global climatology of stratosphere–troposphere exchange using the ERA-Interim data set from 1979 to 2011, Atmos. Chem. Phys., 14, 913–937, https://doi.org/10.5194/acp-14-913-2014, 2014.
Short summary
Atmospheric variations of helium (He) and CO2 are strongly linked due to the co-release of both gases from natural-gas burning. This implies that atmospheric He measurements may be a potentially powerful tool for verifying reported anthropogenic natural-gas usage. Here, we present the development and initial results of a novel measurement system of atmospheric He that paves the way for establishing a global monitoring network in the future.
Atmospheric variations of helium (He) and CO2 are strongly linked due to the co-release of both...