Articles | Volume 18, issue 5
https://doi.org/10.5194/amt-18-1243-2025
https://doi.org/10.5194/amt-18-1243-2025
Research article
 | 
11 Mar 2025
Research article |  | 11 Mar 2025

Development of a portable laser-flash photolysis Faraday rotation spectrometer for measuring atmospheric total OH reactivity

Bo Fang, Nana Wei, Weixiong Zhao, Nana Yang, Hao Zhou, Heng Zhang, Jiarong Li, Weijun Zhang, Yanyu Lu, Zhu Zhu, and Yue Liu

Related authors

MULTICHARME: a modified Chernin-type multi-pass cell designed for IR and THz long-path absorption measurements in the CHARME atmospheric simulation chamber
Jean Decker, Éric Fertein, Jonas Bruckhuisen, Nicolas Houzel, Pierre Kulinski, Bo Fang, Weixiong Zhao, Francis Hindle, Guillaume Dhont, Robin Bocquet, Gaël Mouret, Cécile Coeur, and Arnaud Cuisset
Atmos. Meas. Tech., 15, 1201–1215, https://doi.org/10.5194/amt-15-1201-2022,https://doi.org/10.5194/amt-15-1201-2022, 2022
Short summary

Cited articles

Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I – gas phase reactions of Ox, HOx, NOx and SOx species, Atmos. Chem. Phys., 4, 1461–1738, https://doi.org/10.5194/acp-4-1461-2004, 2004. 
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., Troe, J., and IUPAC Subcommittee: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species, Atmos. Chem. Phys., 6, 3625–4055, https://doi.org/10.5194/acp-6-3625-2006, 2006. 
Brecha, R. J., Pedrotti, L. M., and Krause, D.: Magnetic rotation spectroscopy of molecular oxygen with a diode laser, J. Opt. Soc. Am. B, 14, 1921–1930, https://doi.org/10.1063/1.1149176, 1997. 
Cheng, F., Zhao, W., Fang, B., Zhang, Y., Yang, N., Zhou, H., and Zhang, W.: High band-width mid-infrared frequency-modulated Faraday rotation spectrometer for time resolved measurement of the OH radical, Opt. Express, 31, 25058–25069, https://doi.org/10.1364/OE.493270, 2023. 
Di Carlo, P., Brune, W. H., Martinez, M., Harder, H., Lesher, R., Ren, X., Thornberry, T., Carroll, M. A., Young, V., Shepson, P. B., Riemer, D., Apel, E., and Campbell, C.: Missing OH reactivity in a forest: evidence for unknown reactive biogenic VOCs, Science, 304, 722–725, https://doi.org/10.1126/science.1094392, 2004. 
Download
Short summary
A portable laser-flash photolysis Faraday rotation spectrometer for measuring atmospheric total hydroxyl (OH) reactivity was developed, with optical box dimensions of 130 cm × 40 cm × 35 cm. It features a pump–probe multi-pass cell with a high overlapping factor of 75.4 %. The instrument’s precision and uncertainty are 1.0 s-1 (1σ, 300 s) and within 2 s-1, respectively. This portable, cost-effective instrument expands current measurement capabilities and is convenient for field applications.
Share