Articles | Volume 14, issue 3
https://doi.org/10.5194/amt-14-1783-2021
https://doi.org/10.5194/amt-14-1783-2021
Research article
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04 Mar 2021
Research article | Highlight paper |  | 04 Mar 2021

Comparison of ozone measurement methods in biomass burning smoke: an evaluation under field and laboratory conditions

Russell W. Long, Andrew Whitehill, Andrew Habel, Shawn Urbanski, Hannah Halliday, Maribel Colón, Surender Kaushik, and Matthew S. Landis

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Cited articles

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Baylon, P., Jaffe, D. A., Hall, S. R., Ullmann, K., Alvarado, M. J., and Lefer, B. L.: Impact of Biomass Burning Plumes on Photolysis Rates and Ozone Formation at the Mount Bachelor Observatory, J. Geophys. Res.-Atmos., 123, 2272–2284, 2018. 
Bertschi, I., Yokelson, R. J., Ward, D. E., Babbitt, R. E., Susott, R.A., Goode, J. G., and Hao, W. M.: Trace gas and particle emissions from fires in large diameter and belowground biomass fuels, J. Geophys. Res., 108, 8472, https://doi.org/10.1029/2002JD002100, 2003. 
Boylan, P., Helmig, D., and Park, J.-H.: Characterization and mitigation of water vapor effects in the measurement of ozone by chemiluminescence with nitric oxide, Atmos. Meas. Tech., 7, 1231–1244, https://doi.org/10.5194/amt-7-1231-2014, 2014. 
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This manuscript details field and laboratory-based evaluations of ozone monitoring methods in smoke. UV photometry, the most widely used measurement method for ozone in ambient air, was shown to suffer from a severe positive interference when operated in the presence of smoke, while chemiluminescence-based methods were shown to be free of interferences. The results detailed in this paper will provide monitoring agencies with the tools needed to address smoke-related ozone measurement challenges.
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