Articles | Volume 14, issue 9
https://doi.org/10.5194/amt-14-6039-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-14-6039-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
16 Sep 2021
Research article |
| 16 Sep 2021
| 16 Sep 2021
Development of a laser-photofragmentation laser-induced fluorescence instrument for the detection of nitrous acid and hydroxyl radicals in the atmosphere
Brandon Bottorff
Department of Chemistry, Indiana University, Bloomington, IN 47405,
USA
Emily Reidy
Department of Chemistry, Indiana University, Bloomington, IN 47405,
USA
Levi Mielke
O'Neill School of Public and Environmental Affairs, Indiana
University, Bloomington, IN 47405, USA
now at: Department of Chemistry, University of Indianapolis,
Indianapolis, IN 46227, USA
Sebastien Dusanter
O'Neill School of Public and Environmental Affairs, Indiana
University, Bloomington, IN 47405, USA
now at: IMT Lille Douai, Institut Mines-Télécom, Univ. Lille,
Centre for Energy and Environment, 59000 Lille, France
Department of Chemistry, Indiana University, Bloomington, IN 47405,
USA
O'Neill School of Public and Environmental Affairs, Indiana
University, Bloomington, IN 47405, USA
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A multiphasic molecular characterization of oxygenated compounds has been carried out during the ChArMEx field campaign using offline analysis. It leads to the identification of 97 different compounds in the gas and aerosol phases and reveals the important contribution of organic acids to organic aerosol. In addition, comparison between experimental and theoretical partitioning coefficients revealed in most cases a large underestimation by the theory reaching 1 to 7 orders of magnitude.
Michelle M. Lew, Pamela S. Rickly, Brandon P. Bottorff, Emily Reidy, Sofia Sklaveniti, Thierry Léonardis, Nadine Locoge, Sebastien Dusanter, Shuvashish Kundu, Ezra Wood, and Philip S. Stevens
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Sandy Bsaibes, Mohamad Al Ajami, Kenneth Mermet, François Truong, Sébastien Batut, Christophe Hecquet, Sébastien Dusanter, Thierry Léornadis, Stéphane Sauvage, Julien Kammer, Pierre-Marie Flaud, Emilie Perraudin, Eric Villenave, Nadine Locoge, Valérie Gros, and Coralie Schoemaecker
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Shuvashish Kundu, Benjamin L. Deming, Michelle M. Lew, Brandon P. Bottorff, Pamela Rickly, Philip S. Stevens, Sebastien Dusanter, Sofia Sklaveniti, Thierry Leonardis, Nadine Locoge, and Ezra C. Wood
Atmos. Chem. Phys., 19, 9563–9579, https://doi.org/10.5194/acp-19-9563-2019, https://doi.org/10.5194/acp-19-9563-2019, 2019
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Compounds emitted into the atmosphere are chemically transformed, often leading to new compounds which can affect air pollution and climate. Studying the radicals OH, HO2, and RO2 (organic peroxy radicals) is a crucial activity for assessing how well we understand the rates and products of chemical transformations. In this paper we describe the performance of a new instrument, ECHAMP, for measuring peroxy radicals during its first field deployment.
Ali Akherati, Christopher D. Cappa, Michael J. Kleeman, Kenneth S. Docherty, Jose L. Jimenez, Stephen M. Griffith, Sebastien Dusanter, Philip S. Stevens, and Shantanu H. Jathar
Atmos. Chem. Phys., 19, 4561–4594, https://doi.org/10.5194/acp-19-4561-2019, https://doi.org/10.5194/acp-19-4561-2019, 2019
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Vincent Michoud, Stéphane Sauvage, Thierry Léonardis, Isabelle Fronval, Alexandre Kukui, Nadine Locoge, and Sébastien Dusanter
Atmos. Meas. Tech., 11, 5729–5740, https://doi.org/10.5194/amt-11-5729-2018, https://doi.org/10.5194/amt-11-5729-2018, 2018
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This study presents the first measurements of ambient methylglyoxal, an important atmospheric α-dicarbonyl, using proton transfer reaction time-of-flight mass spectrometry. These measurements mostly agree with concomitant measurements from a reference technique: the DNPH derivatization technique and high-performance liquid chromatography with UV detection. In addition, a careful investigation of the differences between the two techniques is carried out to explain the disagreements observed.
Sofia Sklaveniti, Nadine Locoge, Philip S. Stevens, Ezra Wood, Shuvashish Kundu, and Sébastien Dusanter
Atmos. Meas. Tech., 11, 741–761, https://doi.org/10.5194/amt-11-741-2018, https://doi.org/10.5194/amt-11-741-2018, 2018
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Michelle M. Lew, Sebastien Dusanter, and Philip S. Stevens
Atmos. Meas. Tech., 11, 95–109, https://doi.org/10.5194/amt-11-95-2018, https://doi.org/10.5194/amt-11-95-2018, 2018
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This paper describes measurements of the conversion efficiency of several organic peroxy radicals upon reaction with nitric oxide to the hydroperoxy radical, which can interfere with measurements of the latter. This interference could explain some of the discrepancies between measurements and model predictions of the hydroperoxy radical. Previous measurements of the hydroperoxy radical during the Mexico City Metropolitan Area campaign in 2006 are reanalyzed to account for the interference.
Pamela Rickly and Philip S. Stevens
Atmos. Meas. Tech., 11, 1–16, https://doi.org/10.5194/amt-11-1-2018, https://doi.org/10.5194/amt-11-1-2018, 2018
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The hydroxyl radical is the primary atmospheric oxidant in the atmosphere, and measurements of its concentration provide a rigorous test of our understanding of atmospheric chemistry. This paper presents measurements of a potential interference with measurements of OH using laser-induced fluorescence techniques, which may contribute to measurements of OH in forested environments. The results may help to explain discrepancies between measurements and model predictions in these environments.
Hendrik Fuchs, Anna Novelli, Michael Rolletter, Andreas Hofzumahaus, Eva Y. Pfannerstill, Stephan Kessel, Achim Edtbauer, Jonathan Williams, Vincent Michoud, Sebastien Dusanter, Nadine Locoge, Nora Zannoni, Valerie Gros, Francois Truong, Roland Sarda-Esteve, Danny R. Cryer, Charlotte A. Brumby, Lisa K. Whalley, Daniel Stone, Paul W. Seakins, Dwayne E. Heard, Coralie Schoemaecker, Marion Blocquet, Sebastien Coudert, Sebastien Batut, Christa Fittschen, Alexander B. Thames, William H. Brune, Cheryl Ernest, Hartwig Harder, Jennifer B. A. Muller, Thomas Elste, Dagmar Kubistin, Stefanie Andres, Birger Bohn, Thorsten Hohaus, Frank Holland, Xin Li, Franz Rohrer, Astrid Kiendler-Scharr, Ralf Tillmann, Robert Wegener, Zhujun Yu, Qi Zou, and Andreas Wahner
Atmos. Meas. Tech., 10, 4023–4053, https://doi.org/10.5194/amt-10-4023-2017, https://doi.org/10.5194/amt-10-4023-2017, 2017
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Hydroxyl radical reactivity (k(OH)) is closely related to processes that lead to the formation of oxidised, secondary pollutants such as ozone and aerosol. In order to compare the performances of instruments measuring k(OH), experiments were conducted in the simulation chamber SAPHIR. Chemical conditions were chosen either to be representative of the atmosphere or to test potential limitations of instruments. Overall, the results show that instruments are capable of measuring k(OH).
Nora Zannoni, Valerie Gros, Roland Sarda Esteve, Cerise Kalogridis, Vincent Michoud, Sebastien Dusanter, Stephane Sauvage, Nadine Locoge, Aurelie Colomb, and Bernard Bonsang
Atmos. Chem. Phys., 17, 12645–12658, https://doi.org/10.5194/acp-17-12645-2017, https://doi.org/10.5194/acp-17-12645-2017, 2017
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Vincent Michoud, Jean Sciare, Stéphane Sauvage, Sébastien Dusanter, Thierry Léonardis, Valérie Gros, Cerise Kalogridis, Nora Zannoni, Anaïs Féron, Jean-Eudes Petit, Vincent Crenn, Dominique Baisnée, Roland Sarda-Estève, Nicolas Bonnaire, Nicolas Marchand, H. Langley DeWitt, Jorge Pey, Aurélie Colomb, François Gheusi, Sonke Szidat, Iasonas Stavroulas, Agnès Borbon, and Nadine Locoge
Atmos. Chem. Phys., 17, 8837–8865, https://doi.org/10.5194/acp-17-8837-2017, https://doi.org/10.5194/acp-17-8837-2017, 2017
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The ChArMEx SOP2 field campaign took place from 15 July to 5 August 2013 in the western Mediterranean Basin at Ersa, a remote site in Cape Corse. Exhaustive descriptions of the chemical composition of air masses in gas and aerosol phase were performed. An analysis of these measurements was performed using various source-receptor approaches. This led to the identification of several factors linked to primary sources but also to secondary processes of both biogenic and anthropogenic origin.
Benjamin C. Schulze, Henry W. Wallace, James H. Flynn, Barry L. Lefer, Matt H. Erickson, B. Tom Jobson, Sebastien Dusanter, Stephen M. Griffith, Robert F. Hansen, Philip S. Stevens, Timothy VanReken, and Robert J. Griffin
Atmos. Chem. Phys., 17, 1805–1828, https://doi.org/10.5194/acp-17-1805-2017, https://doi.org/10.5194/acp-17-1805-2017, 2017
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The atmospheric chemistry associated with mixing of anthropogenic and natural species was simulated to understand how shade provided by a forest canopy impacts reactions, product distribution, and subsequent phase distribution of the products. This is important to understand, as forested areas downwind of urban areas will be impacted by this phenomenon. It was found that fast transport from below the canopy led to increases in secondary organic aerosol from nitrate radicals above the canopy.
R. F. Hansen, M. Blocquet, C. Schoemaecker, T. Léonardis, N. Locoge, C. Fittschen, B. Hanoune, P. S. Stevens, V. Sinha, and S. Dusanter
Atmos. Meas. Tech., 8, 4243–4264, https://doi.org/10.5194/amt-8-4243-2015, https://doi.org/10.5194/amt-8-4243-2015, 2015
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This paper describes and presents results from a intercomparison, in an environment rich in NOx (i.e., NO+NO2), of two OH reactivity instruments: one based on the comparative reactivity method, and one based on the pump-probe method. Co-located measurements were made of both ambient air and standard mixtures. Ambient OH reactivity values measured by both instruments were found to be in good agreement for ambient NOx mixing ratios as high as 100 ppbv.
N. Zannoni, S. Dusanter, V. Gros, R. Sarda Esteve, V. Michoud, V. Sinha, N. Locoge, and B. Bonsang
Atmos. Meas. Tech., 8, 3851–3865, https://doi.org/10.5194/amt-8-3851-2015, https://doi.org/10.5194/amt-8-3851-2015, 2015
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Our manuscript shows results of an intercomparison exercise conducted on two home-built comparative reactivity method (CRM) instruments operating under the same settings for measuring total OH reactivity. Despite the corrections of the raw data sets for instrumental artifacts having different weights on the two CRMs, we found very consistent results for the final processed data of ambient OH reactivity. Furthermore, we present in detail how to validate the instruments and process the raw data.
V. Michoud, R. F. Hansen, N. Locoge, P. S. Stevens, and S. Dusanter
Atmos. Meas. Tech., 8, 3537–3553, https://doi.org/10.5194/amt-8-3537-2015, https://doi.org/10.5194/amt-8-3537-2015, 2015
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This study presents the results of an exhaustive characterization of a CRM instrument developed at Mines Douai to measure total OH reactivity in the troposphere. To do so, a suite of laboratory experiments was conducted to assess the different corrections that need to be applied during data processing. The results were then compared to simulations from a 0-D box model, including two different chemical mechanisms, leading to reasonable agreement.
K. R. Baker, A. G. Carlton, T. E. Kleindienst, J. H. Offenberg, M. R. Beaver, D. R. Gentner, A. H. Goldstein, P. L. Hayes, J. L. Jimenez, J. B. Gilman, J. A. de Gouw, M. C. Woody, H. O. T. Pye, J. T. Kelly, M. Lewandowski, M. Jaoui, P. S. Stevens, W. H. Brune, Y.-H. Lin, C. L. Rubitschun, and J. D. Surratt
Atmos. Chem. Phys., 15, 5243–5258, https://doi.org/10.5194/acp-15-5243-2015, https://doi.org/10.5194/acp-15-5243-2015, 2015
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This work details the evaluation of PM2.5 carbon, VOC precursors, and OH estimated by the CMAQ photochemical transport model using routine and special measurements from the 2010 CalNex field study. Here, CMAQ and most recent emissions inventory (2011 NEI) are used to generate model PM2.5 OC estimates that are examined in novel ways including primary vs. secondary formation, fossil vs. contemporary carbon, OH and HO2 evaluation, and the relationship between key VOC precursors and SOC tracers.
C. J. Young, R. A. Washenfelder, P. M. Edwards, D. D. Parrish, J. B. Gilman, W. C. Kuster, L. H. Mielke, H. D. Osthoff, C. Tsai, O. Pikelnaya, J. Stutz, P. R. Veres, J. M. Roberts, S. Griffith, S. Dusanter, P. S. Stevens, J. Flynn, N. Grossberg, B. Lefer, J. S. Holloway, J. Peischl, T. B. Ryerson, E. L. Atlas, D. R. Blake, and S. S. Brown
Atmos. Chem. Phys., 14, 3427–3440, https://doi.org/10.5194/acp-14-3427-2014, https://doi.org/10.5194/acp-14-3427-2014, 2014
R. F. Hansen, S. M. Griffith, S. Dusanter, P. S. Rickly, P. S. Stevens, S. B. Bertman, M. A. Carroll, M. H. Erickson, J. H. Flynn, N. Grossberg, B. T. Jobson, B. L. Lefer, and H. W. Wallace
Atmos. Chem. Phys., 14, 2923–2937, https://doi.org/10.5194/acp-14-2923-2014, https://doi.org/10.5194/acp-14-2923-2014, 2014
S. M. Griffith, R. F. Hansen, S. Dusanter, P. S. Stevens, M. Alaghmand, S. B. Bertman, M. A. Carroll, M. Erickson, M. Galloway, N. Grossberg, J. Hottle, J. Hou, B. T. Jobson, A. Kammrath, F. N. Keutsch, B. L. Lefer, L. H. Mielke, A. O'Brien, P. B. Shepson, M. Thurlow, W. Wallace, N. Zhang, and X. L. Zhou
Atmos. Chem. Phys., 13, 5403–5423, https://doi.org/10.5194/acp-13-5403-2013, https://doi.org/10.5194/acp-13-5403-2013, 2013
Related subject area
Subject: Gases | Technique: In Situ Measurement | Topic: Instruments and Platforms
Deployment and evaluation of an NH4+∕ H3O+ reagent ion switching chemical ionization mass spectrometer for the detection of reduced and oxygenated gas-phase organic compounds
An economical tunable diode laser spectrometer for fast-response measurements of water vapor in the atmospheric boundary layer
Eddy covariance with slow-response greenhouse gas analysers on tall towers: bridging atmospheric and ecosystem greenhouse gas networks
Development of a portable laser-flash photolysis Faraday rotation spectrometer for measuring atmospheric total OH reactivity
An overview of outdoor low-cost gas-phase air quality sensor deployments: current efforts, trends, and limitations
Multiphysical description of atmospheric pressure interface chemical ionisation in MION2 and Eisele type inlets
A portable nitrogen dioxide instrument using cavity-enhanced absorption spectroscopy
Development and deployment of a mid-cost CO2 sensor monitoring network to support atmospheric inverse modeling for quantifying urban CO2 emissions in Paris
UAV-based in situ measurements of CO2 and CH4 fluxes over complex natural ecosystems
Advances in OH reactivity instruments for airborne field measurements
A new aerial approach for quantifying and attributing methane emissions: implementation and validation
Vertical profiles and surface distributions of trace gases (CO, O3, NO, NO2) in the Arctic wintertime boundary layer using low-cost sensors during ALPACA-2022
Drone CO2 measurements during the Tajogaite volcanic eruption
Multi-decadal atmospheric carbon dioxide measurements in Hungary, central Europe
Reliable water vapour isotopic composition measurements at low humidity using frequency-stabilised cavity ring-down spectroscopy
A measurement system for CO2 and CH4 emissions quantification of industrial sites using a new in situ concentration sensor operated on board uncrewed aircraft vehicles
Using metal oxide gas sensors to estimate the emission rates and locations of methane leaks in an industrial site: assessment with controlled methane releases
The ASK-16 Motorized Glider: An Airborne Eddy Covariance Platform to measure Turbulence, Energy and Matter Fluxes
Toward on-demand measurements of greenhouse gas emissions using an uncrewed aircraft AirCore system
Long-term evaluation of commercial air quality sensors: an overview from the QUANT (Quantification of Utility of Atmospheric Network Technologies) study
In-flight characterization of a compact airborne quantum cascade laser absorption spectrometer
Full characterization and calibration of a transfer standard monitor for atmospheric radon measurements
Observing low-altitude features in ozone concentrations in a shoreline environment via uncrewed aerial systems
Development of a Peltier-based chilled-mirror hygrometer for tropospheric and lower stratospheric water vapor measurements
An integrated uncrewed aerial vehicle platform with sensing and sampling systems for the measurement of air pollutant concentrations
Design and evaluation of a low-cost sensor node for near-background methane measurement
Development of a Multichannel Organics In situ enviRonmental Analyzer (MOIRA) for mobile measurements of volatile organic compounds
Evaluation of Aeris mid-infrared absorption (MIRA), Picarro CRDS (cavity ring-down spectroscopy) G2307, and dinitrophenylhydrazine (DNPH)-based sampling for long-term formaldehyde monitoring efforts
Performance characterization of a laminar gas inlet
Validation and field application of a low-cost device to measure CO2 and evapotranspiration (ET) fluxes
Identifying and correcting interferences to PTR-ToF-MS measurements of isoprene and other urban volatile organic compounds
Development of a continuous UAV-mounted air sampler and application to the quantification of CO2 and CH4 emissions from a major coking plant
Uptake behavior of polycyclic aromatic compounds during field calibrations of the XAD-based passive air sampler across seasons and locations
Effect of land–sea air mass transport on spatiotemporal distributions of atmospheric CO2 and CH4 mixing ratios over the southern Yellow Sea
HYPHOP: a tool for high-altitude, long-range monitoring of hydrogen peroxide and higher organic peroxides in the atmosphere
Portable, low-cost samplers for distributed sampling of atmospheric gases
SI-traceable validation of a laser spectrometer for balloon-borne measurements of water vapor in the upper atmosphere
Field evaluation of low-cost electrochemical air quality gas sensors under extreme temperature and relative humidity conditions
A novel, cost-effective analytical method for measuring high-resolution vertical profiles of stratospheric trace gases using a gas chromatograph coupled with an electron capture detector
Ethylene oxide monitor with part-per-trillion precision for in situ measurements
Development of an automated pump-efficiency measuring system for ozonesondes utilizing an airbag-type flowmeter
Short-term variability of atmospheric helium revealed through a cryo-enrichment method
Using tunable infrared laser direct absorption spectroscopy for ambient hydrogen chloride detection: HCl-TILDAS
New methods for the calibration of optical resonators: integrated calibration by means of optical modulation (ICOM) and narrow-band cavity ring-down (NB-CRD)
A modular field system for near-surface, vertical profiling of the atmospheric composition in harsh environments using cavity ring-down spectroscopy
Field comparison of two novel open-path instruments that measure dry deposition and emission of ammonia using flux-gradient and eddy covariance methods
Development of multi-channel whole-air sampling equipment onboard an unmanned aerial vehicle for investigating volatile organic compounds' vertical distribution in the planetary boundary layer
Electrochemical sensors on board a Zeppelin NT: in-flight evaluation of low-cost trace gas measurements
Evaluating the performance of a Picarro G2207-i analyser for high-precision atmospheric O2 measurements
Airborne flux measurements of ammonia over the southern Great Plains using chemical ionization mass spectrometry
Cort L. Zang and Megan D. Willis
Atmos. Meas. Tech., 18, 17–35, https://doi.org/10.5194/amt-18-17-2025, https://doi.org/10.5194/amt-18-17-2025, 2025
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Atmospheric chemistry of the diverse pool of reactive organic carbon (ROC; all organic species excluding methane) controls air quality, both indoors and outdoors, and influences Earth's climate. However, many important ROC compounds in the atmosphere are difficult to measure. We demonstrate measurement of diverse ROC compounds in a single instrument at a forested site. This approach can improve our ability to measure a broad range of atmospheric ROC.
Emily D. Wein, Lars E. Kalnajs, and Darin W. Toohey
Atmos. Meas. Tech., 17, 7097–7107, https://doi.org/10.5194/amt-17-7097-2024, https://doi.org/10.5194/amt-17-7097-2024, 2024
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We describe a low-cost and small research-grade spectrometer for measurements of water vapor in the boundary layer. The instrument uses small Arduino microcontrollers and inexpensive laser diodes to reduce cost while maintaining high performance comparable to more expensive instruments. Performance was assessed with intercomparisons between commercially available instruments outdoors. The design's simplicity, performance, and price point allow it to be accessible to a variety of users.
Pedro Henrique Herig Coimbra, Benjamin Loubet, Olivier Laurent, Laura Bignotti, Mathis Lozano, and Michel Ramonet
Atmos. Meas. Tech., 17, 6625–6645, https://doi.org/10.5194/amt-17-6625-2024, https://doi.org/10.5194/amt-17-6625-2024, 2024
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This study presents direct flux measurements in tall towers using existing slow-response analysers and adding 3D sonic anemometers. This way, we can significantly improve greenhouse gas monitoring with little extra instrumental effort. Slow-response analysers may be used here as the relevant frequency ranges depend on measuring height. Tall towers offer a large footprint, amplifying spatial coverage. The presented concept is a valuable bridge between atmospheric and ecosystem communities.
Bo Fang, Nana Wei, Weixiong Zhao, Nana Yang, Hao Zhou, Heng Zhang, Jiarong Li, Weijun Zhang, Yanyu Lu, Zhu Zhu, and Yue Liu
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-184, https://doi.org/10.5194/amt-2024-184, 2024
Revised manuscript accepted for AMT
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A portable LP-FRS instrument with dimensions of 130 cm × 40 cm × 35 cm was developed. A specific pump-probe MPC was designed to offer a high overlapping factor of 75.4 %. The precision and uncertainty of the LP-FRS instrument for measuring kOH' were 1.0 s-1 (1σ, 300 s) and within 2 s-1, respectively. The developed portable LP-FRS instrument expands the measurement capabilities for atmospheric total OH reactivity and will be employed in more field observations.
Kristen Okorn and Laura T. Iraci
Atmos. Meas. Tech., 17, 6425–6457, https://doi.org/10.5194/amt-17-6425-2024, https://doi.org/10.5194/amt-17-6425-2024, 2024
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We reviewed 60 sensor networks and 17 related efforts (sensor review papers and data accessibility projects) to better understand the landscape of stationary low-cost gas-phase sensor networks deployed in outdoor environments worldwide. Gaps in monitoring efforts include the availability of gas-phase measurements compared to particulate matter (PM) and geographic coverage gaps (the Global South, rural areas). We conclude with a summary of cross-network unification and quality control efforts.
Henning Finkenzeller, Jyri Mikkilä, Cecilia Righi, Paxton Juuti, Mikko Sipilä, Matti Rissanen, Douglas Worsnop, Aleksei Shcherbinin, Nina Sarnela, and Juha Kangasluoma
Atmos. Meas. Tech., 17, 5989–6001, https://doi.org/10.5194/amt-17-5989-2024, https://doi.org/10.5194/amt-17-5989-2024, 2024
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Chemical ionisation mass spectrometry is used in the atmospheric sciences to measure trace gas concentrations. Neutral gases require charging in inlets before the mass-to-charge ratio of the resulting ions can be analysed. This study uses multiphysics modelling to investigate how the MION2 and Eisele type inlets work and shows the effect of tuning parameters and their current limitations. The findings are helpful for inlet users and are expected to aid in developing improved inlets.
Steven A. Bailey, Reem A. Hannun, Andrew K. Swanson, and Thomas F. Hanisco
Atmos. Meas. Tech., 17, 5903–5910, https://doi.org/10.5194/amt-17-5903-2024, https://doi.org/10.5194/amt-17-5903-2024, 2024
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We have developed a portable, optically based instrument that measures NO2. It consumes less than 6 W of power, so it can easily run off a small battery. This instrument has made both balloon and UAV flights. NO2 measurement results compare favorably with other known NO2 instruments. We find this instrument to be stable with repeatable results compared with calibration sources. Material cost to build a single instrument is around USD 4000. This could be lowered with economies of scale.
Jinghui Lian, Olivier Laurent, Mali Chariot, Luc Lienhardt, Michel Ramonet, Hervé Utard, Thomas Lauvaux, François-Marie Bréon, Grégoire Broquet, Karina Cucchi, Laurent Millair, and Philippe Ciais
Atmos. Meas. Tech., 17, 5821–5839, https://doi.org/10.5194/amt-17-5821-2024, https://doi.org/10.5194/amt-17-5821-2024, 2024
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We have designed and deployed a mid-cost medium-precision CO2 sensor monitoring network in Paris since July 2020. The data are automatically calibrated by a newly implemented data processing system. The accuracies of the mid-cost instruments vary from 1.0 to 2.4 ppm for hourly afternoon measurements. Our model–data analyses highlight prospects for integrating mid-cost instrument data with high-precision measurements to improve fine-scale CO2 emission quantification in urban areas.
Abdullah Bolek, Martin Heimann, and Mathias Göckede
Atmos. Meas. Tech., 17, 5619–5636, https://doi.org/10.5194/amt-17-5619-2024, https://doi.org/10.5194/amt-17-5619-2024, 2024
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This study describes the development of a new UAV platform to measure atmospheric greenhouse gas (GHG) mole fractions, 2D wind speed, air temperature, humidity, and pressure. Understanding GHG flux processes and controls across various ecosystems is essential for estimating the current and future state of climate change. It was shown that using the UAV platform for such measurements is beneficial for improving our understanding of GHG processes over complex landscapes.
Hendrik Fuchs, Aaron Stainsby, Florian Berg, René Dubus, Michelle Färber, Andreas Hofzumahaus, Frank Holland, Kelvin H. Bates, Steven S. Brown, Matthew M. Coggon, Glenn S. Diskin, Georgios I. Gkatzelis, Christopher M. Jernigan, Jeff Peischl, Michael A. Robinson, Andrew W. Rollins, Nell B. Schafer, Rebecca H. Schwantes, Chelsea E. Stockwell, Patrick R. Veres, Carsten Warneke, Eleanor M. Waxman, Lu Xu, Kristen Zuraski, Andreas Wahner, and Anna Novelli
EGUsphere, https://doi.org/10.5194/egusphere-2024-2752, https://doi.org/10.5194/egusphere-2024-2752, 2024
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Significant improvements have been made to the instruments used to measure OH reactivity, which is equivalent to the sum of air pollutant concentrations. Accurate and precise measurements with a high time resolution have been achieved, allowing use on aircraft, as demonstrated during flights in the USA.
Jonathan F. Dooley, Kenneth Minschwaner, Manvendra K. Dubey, Sahar H. El Abbadi, Evan D. Sherwin, Aaron G. Meyer, Emily Follansbee, and James E. Lee
Atmos. Meas. Tech., 17, 5091–5111, https://doi.org/10.5194/amt-17-5091-2024, https://doi.org/10.5194/amt-17-5091-2024, 2024
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Methane is a powerful greenhouse gas originating from both natural and human activities. We describe a new uncrewed aerial system (UAS) designed to measure methane emission rates over a wide range of scales. This system has been used for direct quantification of point sources and distributed emitters over scales of up to 1 km. The system uses simultaneous measurements of methane and ethane to distinguish between different kinds of natural and human-related emission sources.
Brice Barret, Patrice Medina, Natalie Brett, Roman Pohorsky, Kathy Law, Slimane Bekki, Gilberto J. Fochesatto, Julia Schmale, Steve Arnold, Andrea Baccarini, Mauricio Busetto, Meeta Cesler-Maloney, Barbara D'Anna, Stefano Decesari, Jingqiu Mao, Gianluca Pappaccogli, Joel Savarino, Federico Scoto, and William R. Simpson
EGUsphere, https://doi.org/10.5194/egusphere-2024-2421, https://doi.org/10.5194/egusphere-2024-2421, 2024
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The Fairbanks area experiences severe pollution episodes in winter because of enhanced emissions of pollutants trapped near the surface by strong temperature inversions. Low-cost sensors were deployed onboard a car and a tethered balloon to measure the concentrations of gaseous pollutants (CO, O3, NOx) in Fairbanks during the winter of 2022. Data calibration with reference measurements and machine learning methods enabled to document pollution at the surface and power plant plumes aloft.
John Ericksen, Tobias P. Fischer, G. Matthew Fricke, Scott Nowicki, Nemesio M. Pérez, Pedro Hernández Pérez, Eleazar Padrón González, and Melanie E. Moses
Atmos. Meas. Tech., 17, 4725–4736, https://doi.org/10.5194/amt-17-4725-2024, https://doi.org/10.5194/amt-17-4725-2024, 2024
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Volcanic eruptions emit significant quantities of carbon dioxide (CO2) to the atmosphere. We present a new method for directly determining the CO2 emission from a volcanic eruption on the island of La Palma, Spain, using an unpiloted aerial vehicle (UAV). We also collected samples of the emitted CO2 and analyzed their isotopic composition. Together with the emission rate the isotopic data provide valuable information on the state of volcanic activity and the potential evolution of the eruption.
László Haszpra
Atmos. Meas. Tech., 17, 4629–4647, https://doi.org/10.5194/amt-17-4629-2024, https://doi.org/10.5194/amt-17-4629-2024, 2024
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The paper evaluates a 30-year-long atmospheric CO2 data series from a mid-continental central European site, Hegyhátsál (HUN). It presents the site-specific features observed in the long-term evolution of the atmospheric CO2 concentration. Since the measurement data are widely used in atmospheric inverse models and budget calculations all around the world, the paper provides potentially valuable information for model tuning and interpretation of the model results.
Mathieu Casado, Amaelle Landais, Tim Stoltmann, Justin Chaillot, Mathieu Daëron, Fréderic Prié, Baptiste Bordet, and Samir Kassi
Atmos. Meas. Tech., 17, 4599–4612, https://doi.org/10.5194/amt-17-4599-2024, https://doi.org/10.5194/amt-17-4599-2024, 2024
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Measuring water isotopic composition in Antarctica is difficult because of the extremely cold temperature in winter. Here, we designed a new infrared spectrometer able to measure the vapour isotopic composition during more than 95 % of the year in the coldest locations of Antarctica, whereas current commercial instruments are only able to measure during the warm summer months in the interior.
Jean-Louis Bonne, Ludovic Donnat, Grégory Albora, Jérémie Burgalat, Nicolas Chauvin, Delphine Combaz, Julien Cousin, Thomas Decarpenterie, Olivier Duclaux, Nicolas Dumelié, Nicolas Galas, Catherine Juery, Florian Parent, Florent Pineau, Abel Maunoury, Olivier Ventre, Marie-France Bénassy, and Lilian Joly
Atmos. Meas. Tech., 17, 4471–4491, https://doi.org/10.5194/amt-17-4471-2024, https://doi.org/10.5194/amt-17-4471-2024, 2024
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We present a top-down approach to quantify CO2 and CH4 emissions at the scale of an industrial site, based on a mass balance model relying on atmospheric concentrations measurements from a new sensor embarked on board uncrewed aircraft vehicles (UAVs). We present a laboratory characterization of our sensor and a field validation of our quantification method, together with field application to the monitoring of two real-world offshore oil and gas platforms.
Rodrigo Rivera-Martinez, Pramod Kumar, Olivier Laurent, Gregoire Broquet, Christopher Caldow, Ford Cropley, Diego Santaren, Adil Shah, Cécile Mallet, Michel Ramonet, Leonard Rivier, Catherine Juery, Olivier Duclaux, Caroline Bouchet, Elisa Allegrini, Hervé Utard, and Philippe Ciais
Atmos. Meas. Tech., 17, 4257–4290, https://doi.org/10.5194/amt-17-4257-2024, https://doi.org/10.5194/amt-17-4257-2024, 2024
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We explore the use of metal oxide semiconductors (MOSs) as a low-cost alternative for detecting and measuring CH4 emissions from industrial facilities. MOSs were exposed to several controlled releases to test their accuracy in detecting and quantifying emissions. Two reconstruction models were compared, and emission estimates were computed using a Gaussian dispersion model. Findings show that MOSs can provide accurate emission estimates with a 25 % emission rate error and a 9.5 m location error.
Inge Wiekenkamp, Anna Katharina Lehmann, Alexander Bütow, Jörg Hartmann, Stefan Metzger, Thomas Ruhtz, Christian Wille, Mathias Zöllner, and Torsten Sachs
EGUsphere, https://doi.org/10.5194/egusphere-2024-1586, https://doi.org/10.5194/egusphere-2024-1586, 2024
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Airborne eddy covariance platforms are crucial, as they measure the three-dimension wind, and turbulent transport of matter and energy between the surface and the atmosphere at larger scales. In this study we introduce the new ASK-16 eddy covariance platform that is able to accurately measure turbulent fluxes and wind vectors. Data from this platform can help to build bridges between local tower measurements and regional remote sensing fluxes or inversion products.
Zihan Zhu, Javier González-Rocha, Yifan Ding, Isis Frausto-Vicencio, Sajjan Heerah, Akula Venkatram, Manvendra Dubey, Don Collins, and Francesca M. Hopkins
Atmos. Meas. Tech., 17, 3883–3895, https://doi.org/10.5194/amt-17-3883-2024, https://doi.org/10.5194/amt-17-3883-2024, 2024
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Increases in agriculture, oil and gas, and waste management activities have contributed to the increase in atmospheric methane levels and resultant climate warming. In this paper, we explore the use of small uncrewed aircraft systems (sUASs) and AirCore technology to detect and quantify methane emissions. Results from field experiments demonstrate that sUASs and AirCore technology can be effective for detecting and quantifying methane emissions in near real time.
Sebastian Diez, Stuart Lacy, Hugh Coe, Josefina Urquiza, Max Priestman, Michael Flynn, Nicholas Marsden, Nicholas A. Martin, Stefan Gillott, Thomas Bannan, and Pete M. Edwards
Atmos. Meas. Tech., 17, 3809–3827, https://doi.org/10.5194/amt-17-3809-2024, https://doi.org/10.5194/amt-17-3809-2024, 2024
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In this paper we present an overview of the QUANT project, which to our knowledge is one of the largest evaluations of commercial sensors to date. The objective was to evaluate the performance of a range of commercial products and also to nourish the different applications in which these technologies can offer relevant information.
Linda Ort, Lenard Lukas Röder, Uwe Parchatka, Rainer Königstedt, Daniel Crowley, Frank Kunz, Ralf Wittkowski, Jos Lelieveld, and Horst Fischer
Atmos. Meas. Tech., 17, 3553–3565, https://doi.org/10.5194/amt-17-3553-2024, https://doi.org/10.5194/amt-17-3553-2024, 2024
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Airborne in situ measurements are of great importance to collect valuable data to improve our knowledge of the atmosphere but also present challenges which demand specific designs. This study presents an IR spectrometer for airborne trace-gas measurements with high data efficiency and a simple, compact design. Its in-flight performance is characterized with the help of a test flight and a comparison with another spectrometer. Moreover, results from its first campaign highlight its benefits.
Roger Curcoll, Claudia Grossi, Stefan Röttger, and Arturo Vargas
Atmos. Meas. Tech., 17, 3047–3065, https://doi.org/10.5194/amt-17-3047-2024, https://doi.org/10.5194/amt-17-3047-2024, 2024
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This paper presents a new user-friendly version of the Atmospheric Radon MONitor (ARMON). The efficiency of the instrument is of 0.0057 s-1, obtained using different techniques at Spanish and German chambers. The total calculated uncertainty of the ARMON for hourly radon concentrations above 5 Bq m-3 is lower than 10 % (k = 1). Results confirm that the ARMON is suitable to measure low-level radon activity concentrations and to be used as a transfer standard to calibrate in situ radon monitors.
Josie K. Radtke, Benjamin N. Kies, Whitney A. Mottishaw, Sydney M. Zeuli, Aidan T. H. Voon, Kelly L. Koerber, Grant W. Petty, Michael P. Vermeuel, Timothy H. Bertram, Ankur R. Desai, Joseph P. Hupy, R. Bradley Pierce, Timothy J. Wagner, and Patricia A. Cleary
Atmos. Meas. Tech., 17, 2833–2847, https://doi.org/10.5194/amt-17-2833-2024, https://doi.org/10.5194/amt-17-2833-2024, 2024
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The use of uncrewed aircraft systems (UASs) to conduct a vertical profiling of ozone and meteorological variables was evaluated using comparisons between tower or ground observations and UAS-based measurements. Changes to the UAS profiler showed an improvement in performance. The profiler was used to see the impact of Chicago pollution plumes on a shoreline area near Lake Michigan.
Takuji Sugidachi, Masatomo Fujiwara, Kensaku Shimizu, Shin-Ya Ogino, Junko Suzuki, and Ruud J. Dirksen
EGUsphere, https://doi.org/10.5194/egusphere-2024-635, https://doi.org/10.5194/egusphere-2024-635, 2024
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A Peltier-based chilled-mirror hygrometer, SKYDEW, has been developed to measure tropospheric and stratospheric water vapor. Continuous accurate measurements of water vapor are essential for climate monitoring. More than 40 soundings with SKYDEW have been conducted since 2011 to evaluate the performance. The result of soundings at tropical and mid-latitudes demonstrated that SKYDEW is able to measure up to an altitude of 20–25 km for daytime soundings and above 25 km for nighttime soundings.
Chen-Wei Liang and Chang-Hung Shen
Atmos. Meas. Tech., 17, 2671–2686, https://doi.org/10.5194/amt-17-2671-2024, https://doi.org/10.5194/amt-17-2671-2024, 2024
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In the present study, a UAV platform with sensing and sampling systems was developed for 3D air pollutant concentration measurements. The sensing system of this platform contains multiple microsensors and IoT technologies for obtaining the real-time 3D distributions of critical air pollutants. The sampling system contains gas sampling sets and a 1 L Tedlar bag instead of a canister for the 3D measurement of VOC concentrations in accordance with the TO-15 method of the US EPA.
Daniel Furuta, Bruce Wilson, Albert A. Presto, and Jiayu Li
Atmos. Meas. Tech., 17, 2103–2121, https://doi.org/10.5194/amt-17-2103-2024, https://doi.org/10.5194/amt-17-2103-2024, 2024
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Methane is an important driver of climate change and is challenging to inexpensively sense in low atmospheric concentrations. We developed a low-cost sensor to monitor methane and tested it in indoor and outdoor settings. Our device shows promise for monitoring low levels of methane. We characterize its limitations and suggest future research directions for further development.
Audrey J. Dang, Nathan M. Kreisberg, Tyler L. Cargill, Jhao-Hong Chen, Sydney Hornitschek, Remy Hutheesing, Jay R. Turner, and Brent J. Williams
Atmos. Meas. Tech., 17, 2067–2087, https://doi.org/10.5194/amt-17-2067-2024, https://doi.org/10.5194/amt-17-2067-2024, 2024
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The Multichannel Organics In situ enviRonmental Analyzer (MOIRA) is a new instrument for measuring speciated volatile organic compounds (VOCs) in the air and has been developed for mapping concentrations from a hybrid car. MOIRA is characterized in the lab and pilot field studies of indoor air in a single-family residence and outdoor air during a mobile deployment. Future applications include indoor, outdoor, and lab measurements to grasp the impact of VOCs on air quality, health, and climate.
Asher P. Mouat, Zelda A. Siegel, and Jennifer Kaiser
Atmos. Meas. Tech., 17, 1979–1994, https://doi.org/10.5194/amt-17-1979-2024, https://doi.org/10.5194/amt-17-1979-2024, 2024
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Three fast-measurement formaldehyde monitors were deployed at two field sites in Atlanta, GA, over 1 year. Four different zeroing methods were tested to develop an optimal field setup as well as procedures for instrument calibration. Observations agreed well after calibration but were much higher compared to the TO-11A monitoring method, which is the golden standard. Historical HCHO concentrations were compared with measurements in this work, showing a 22 % reduction in midday HCHO since 1999.
Da Yang, Margarita Reza, Roy Mauldin, Rainer Volkamer, and Suresh Dhaniyala
Atmos. Meas. Tech., 17, 1463–1474, https://doi.org/10.5194/amt-17-1463-2024, https://doi.org/10.5194/amt-17-1463-2024, 2024
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This paper evaluates the performance of an aircraft gas inlet. Here, we use computational fluid dynamics (CFD) and experiments to demonstrate the role of turbulence in determining sampling performance of a gas inlet and identify ideal conditions for inlet operation to minimize gas loss. Experiments conducted in a high-speed wind tunnel under near-aircraft speeds validated numerical results. We believe that the results obtained from this work will greatly inform future gas inlet studies.
Reena Macagga, Michael Asante, Geoffroy Sossa, Danica Antonijević, Maren Dubbert, and Mathias Hoffmann
Atmos. Meas. Tech., 17, 1317–1332, https://doi.org/10.5194/amt-17-1317-2024, https://doi.org/10.5194/amt-17-1317-2024, 2024
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Using only low-cost microcontrollers and sensors, we constructed a measurement device to accurately and precisely obtain atmospheric carbon dioxide and water fluxes. The device was tested against known concentration increases and high-cost, commercial sensors during a laboratory and field experiment. We additionally tested the device over a longer period in a field study in Ghana during which the net ecosystem carbon balance and water use efficiency of maize cultivation were studied.
Matthew M. Coggon, Chelsea E. Stockwell, Megan S. Claflin, Eva Y. Pfannerstill, Lu Xu, Jessica B. Gilman, Julia Marcantonio, Cong Cao, Kelvin Bates, Georgios I. Gkatzelis, Aaron Lamplugh, Erin F. Katz, Caleb Arata, Eric C. Apel, Rebecca S. Hornbrook, Felix Piel, Francesca Majluf, Donald R. Blake, Armin Wisthaler, Manjula Canagaratna, Brian M. Lerner, Allen H. Goldstein, John E. Mak, and Carsten Warneke
Atmos. Meas. Tech., 17, 801–825, https://doi.org/10.5194/amt-17-801-2024, https://doi.org/10.5194/amt-17-801-2024, 2024
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Mass spectrometry is a tool commonly used to measure air pollutants. This study evaluates measurement artifacts produced in the proton-transfer-reaction mass spectrometer. We provide methods to correct these biases and better measure compounds that degrade air quality.
Tianran Han, Conghui Xie, Yayong Liu, Yanrong Yang, Yuheng Zhang, Yufei Huang, Xiangyu Gao, Xiaohua Zhang, Fangmin Bao, and Shao-Meng Li
Atmos. Meas. Tech., 17, 677–691, https://doi.org/10.5194/amt-17-677-2024, https://doi.org/10.5194/amt-17-677-2024, 2024
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This study reported an integrated UAV measurement platform for GHG monitoring and its application for emission quantification from a coking plant. The key element of this system is a newly designed air sampler, consisting of a 150 m long tube with remote-controlled time stamping. When comparing the top-down results to those derived from the bottom-up inventory method, the present findings indicate that the use of IPCC emission factors for emission calculations can lead to overestimation.
Yuening Li, Faqiang Zhan, Yushan Su, Ying Duan Lei, Chubashini Shunthirasingham, Zilin Zhou, Jonathan P. D. Abbatt, Hayley Hung, and Frank Wania
Atmos. Meas. Tech., 17, 715–729, https://doi.org/10.5194/amt-17-715-2024, https://doi.org/10.5194/amt-17-715-2024, 2024
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A simple device for sampling gases from the atmosphere without the help of pumps was calibrated for an important group of hazardous air pollutants called polycyclic aromatic compounds (PACs). While the sampler appeared to perform well when used for relatively short periods of up to several months, some PACs were lost from the sampler during longer deployments. Sampling rates that can be used to quantitatively interpret the quantities of PACs taken up in the device have been derived.
Jiaxin Li, Kunpeng Zang, Yi Lin, Yuanyuan Chen, Shuo Liu, Shanshan Qiu, Kai Jiang, Xuemei Qing, Haoyu Xiong, Haixiang Hong, Shuangxi Fang, Honghui Xu, and Yujun Jiang
Atmos. Meas. Tech., 16, 4757–4768, https://doi.org/10.5194/amt-16-4757-2023, https://doi.org/10.5194/amt-16-4757-2023, 2023
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Based on observed data of CO2 and CH4 and meteorological parameters over the Yellow Sea in November 2012 and June 2013, a data process and quality control method was optimized and established to filter the data influenced by multiple factors. Spatial and seasonal variations in CO2 and CH4 mixing ratios were mainly controlled by the East Asian Monsoon, while the influence of air–sea exchange was slight.
Zaneta Hamryszczak, Antonia Hartmann, Dirk Dienhart, Sascha Hafermann, Bettina Brendel, Rainer Königstedt, Uwe Parchatka, Jos Lelieveld, and Horst Fischer
Atmos. Meas. Tech., 16, 4741–4756, https://doi.org/10.5194/amt-16-4741-2023, https://doi.org/10.5194/amt-16-4741-2023, 2023
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Hydroperoxide measurements improve the understanding of atmospheric oxidation processes. We introduce an instrumental setup for airborne measurements. The aim of the work is the characterization of the measurement method with emphasis on interferences impacting instrumental uncertainty. Technical and physical challenges do not critically impact the instrumental performance. The instrument resolves dynamic processes, such as convective transport, as shown based on the CAFE-Brazil campaign.
James F. Hurley, Alejandra Caceres, Deborah F. McGlynn, Mary E. Tovillo, Suzanne Pinar, Roger Schürch, Ksenia Onufrieva, and Gabriel Isaacman-VanWertz
Atmos. Meas. Tech., 16, 4681–4692, https://doi.org/10.5194/amt-16-4681-2023, https://doi.org/10.5194/amt-16-4681-2023, 2023
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Volatile organic compounds (VOCs) have a wide range of sources and impacts on environments and human health that make them spatially, temporally, and chemically varied. Current methods lack the ability to collect samples in ways that provide spatial and chemical resolution without complex, costly instrumentation. We describe and validate a low-cost, portable VOC sampler and demonstrate its utility in collecting distributed coordinated samples.
Simone Brunamonti, Manuel Graf, Tobias Bühlmann, Céline Pascale, Ivan Ilak, Lukas Emmenegger, and Béla Tuzson
Atmos. Meas. Tech., 16, 4391–4407, https://doi.org/10.5194/amt-16-4391-2023, https://doi.org/10.5194/amt-16-4391-2023, 2023
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The abundance of water vapor (H2O) in the upper atmosphere has a significant impact on the rate of global warming. We developed a new lightweight spectrometer (ALBATROSS) for H2O measurements aboard meteorological balloons. Here, we assess the accuracy and precision of ALBATROSS using metrology-grade reference gases. The results demonstrate the exceptional potential of mid-infrared laser absorption spectroscopy as a new reference method for in situ measurements of H2O in the upper atmosphere.
Roubina Papaconstantinou, Marios Demosthenous, Spyros Bezantakos, Neoclis Hadjigeorgiou, Marinos Costi, Melina Stylianou, Elli Symeou, Chrysanthos Savvides, and George Biskos
Atmos. Meas. Tech., 16, 3313–3329, https://doi.org/10.5194/amt-16-3313-2023, https://doi.org/10.5194/amt-16-3313-2023, 2023
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In this paper, we investigate the performance of low-cost electrochemical gas sensors. We carried out yearlong measurements at a traffic air quality monitoring station, where the low-cost sensors were collocated with reference instruments and exposed to highly variable environmental conditions with extremely high temperatures and low relative humidity (RH). Sensors provide measurements that exhibit increasing errors and decreasing correlations as temperature increases and RH decreases.
Jianghanyang Li, Bianca C. Baier, Fred Moore, Tim Newberger, Sonja Wolter, Jack Higgs, Geoff Dutton, Eric Hintsa, Bradley Hall, and Colm Sweeney
Atmos. Meas. Tech., 16, 2851–2863, https://doi.org/10.5194/amt-16-2851-2023, https://doi.org/10.5194/amt-16-2851-2023, 2023
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Monitoring a suite of trace gases in the stratosphere will help us better understand the stratospheric circulation and its impact on the earth's radiation balance. However, such measurements are rare and usually expensive. We developed an instrument that can measure stratospheric trace gases using a low-cost sampling platform (AirCore). The results showed expected agreement with aircraft measurements, demonstrating this technique provides a low-cost and robust way to observe the stratosphere.
Tara I. Yacovitch, Christoph Dyroff, Joseph R. Roscioli, Conner Daube, J. Barry McManus, and Scott C. Herndon
Atmos. Meas. Tech., 16, 1915–1921, https://doi.org/10.5194/amt-16-1915-2023, https://doi.org/10.5194/amt-16-1915-2023, 2023
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Ethylene oxide is a toxic, carcinogenic compound used in the medical and bulk sterilization industry. Here we describe a precise and fast laser-based ethylene oxide monitor. We report months-long concentrations at a Massachusetts site, and we show how they suggest a potential emission source 35 km away. This source, and another, is confirmed by driving the instrument downwind of the sites, where concentrations were tens to tens of thousands of times greater than background levels.
Tatsumi Nakano and Takashi Morofuji
Atmos. Meas. Tech., 16, 1583–1595, https://doi.org/10.5194/amt-16-1583-2023, https://doi.org/10.5194/amt-16-1583-2023, 2023
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We have developed a system that can automatically measure the pump efficiency of the ECC-type ozonesonde. Operational measurement for 13 years by this system revealed that the efficiency fluctuates in each and slightly increases over time. Those can affect the estimation of total ozone amount by up to 4 %. This result indicates that it is necessary to understand the tendency of the pump correction factor of each ozonesonde in order to detect the actual atmospheric change with high accuracy.
Benjamin Birner, Eric Morgan, and Ralph F. Keeling
Atmos. Meas. Tech., 16, 1551–1561, https://doi.org/10.5194/amt-16-1551-2023, https://doi.org/10.5194/amt-16-1551-2023, 2023
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Atmospheric variations of helium (He) and CO2 are strongly linked due to the co-release of both gases from natural-gas burning. This implies that atmospheric He measurements may be a potentially powerful tool for verifying reported anthropogenic natural-gas usage. Here, we present the development and initial results of a novel measurement system of atmospheric He that paves the way for establishing a global monitoring network in the future.
John W. Halfacre, Jordan Stewart, Scott C. Herndon, Joseph R. Roscioli, Christoph Dyroff, Tara I. Yacovitch, Michael Flynn, Stephen J. Andrews, Steven S. Brown, Patrick R. Veres, and Pete M. Edwards
Atmos. Meas. Tech., 16, 1407–1429, https://doi.org/10.5194/amt-16-1407-2023, https://doi.org/10.5194/amt-16-1407-2023, 2023
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This study details a new sampling method for the optical detection of hydrogen chloride (HCl). HCl is an important atmospheric reservoir for chlorine atoms, which can affect nitrogen oxide cycling and the lifetimes of volatile organic compounds and ozone. However, HCl has a high affinity for interacting with surfaces, thereby preventing fast, quantitative measurements. The sampling technique in this study minimizes these surface interactions and provides a high-quality measurement of HCl.
Henning Finkenzeller, Denis Pöhler, Martin Horbanski, Johannes Lampel, and Ulrich Platt
Atmos. Meas. Tech., 16, 1343–1356, https://doi.org/10.5194/amt-16-1343-2023, https://doi.org/10.5194/amt-16-1343-2023, 2023
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Optical resonators enhance the light path in compact instruments, thereby improving their sensitivity. Determining the established path length in the instrument is a prerequisite for the accurate determination of trace gas concentrations but can be a significant complication in the use of such resonators. Here we show two calibration techniques which are relatively simple and free of consumables but still provide accurate calibrations. This facilitates the use of optical resonators.
Andrew W. Seidl, Harald Sodemann, and Hans Christian Steen-Larsen
Atmos. Meas. Tech., 16, 769–790, https://doi.org/10.5194/amt-16-769-2023, https://doi.org/10.5194/amt-16-769-2023, 2023
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It is challenging to make field measurements of stable water isotopes in the Arctic. To this end, we present a modular stable-water-isotope analyzer profiling system. The system operated for a 2-week field campaign on Svalbard during the Arctic winter. We evaluate the system’s performance and analyze any potential impact that the field conditions might have had on the isotopic measurements and the system's ability to resolve isotope gradients in the lowermost layer of the atmosphere.
Daan Swart, Jun Zhang, Shelley van der Graaf, Susanna Rutledge-Jonker, Arjan Hensen, Stijn Berkhout, Pascal Wintjen, René van der Hoff, Marty Haaima, Arnoud Frumau, Pim van den Bulk, Ruben Schulte, Margreet van Zanten, and Thomas van Goethem
Atmos. Meas. Tech., 16, 529–546, https://doi.org/10.5194/amt-16-529-2023, https://doi.org/10.5194/amt-16-529-2023, 2023
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During a 5-week comparison campaign, we tested two set-ups to measure half hourly ammonia fluxes. The eddy covariance and flux gradient systems showed very similar results when the upwind terrain was both homogeneous and free of obstacles. We discuss the technical performance and practical limitations of both systems. Measurements from these instruments can facilitate the study of processes behind ammonia deposition, an important contributor to eutrophication and acidificationin natural areas.
Suding Yang, Xin Li, Limin Zeng, Xuena Yu, Ying Liu, Sihua Lu, Xiaofeng Huang, Dongmei Zhang, Haibin Xu, Shuchen Lin, Hefan Liu, Miao Feng, Danlin Song, Qinwen Tan, Jinhui Cui, Lifan Wang, Ying Chen, Wenjie Wang, Haijiong Sun, Mengdi Song, Liuwei Kong, Yi Liu, Linhui Wei, Xianwu Zhu, and Yuanhang Zhang
Atmos. Meas. Tech., 16, 501–512, https://doi.org/10.5194/amt-16-501-2023, https://doi.org/10.5194/amt-16-501-2023, 2023
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Vertical observation of volatile organic compounds (VOCs) is essential to study the spatial distribution and evolution patterns of VOCs in the planetary boundary layer (PBL). This paper describes multi-channel whole-air sampling equipment onboard an unmanned aerial vehicle (UAV) for near-continuous VOC vertical observation. Vertical profiles of VOCs and trace gases during the evolution of the PBL in south-western China have been successfully obtained by deploying the newly developed UAV system.
Tobias Schuldt, Georgios I. Gkatzelis, Christian Wesolek, Franz Rohrer, Benjamin Winter, Thomas A. J. Kuhlbusch, Astrid Kiendler-Scharr, and Ralf Tillmann
Atmos. Meas. Tech., 16, 373–386, https://doi.org/10.5194/amt-16-373-2023, https://doi.org/10.5194/amt-16-373-2023, 2023
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We report in situ measurements of air pollutant concentrations within the planetary boundary layer on board a Zeppelin NT in Germany. We highlight the in-flight evaluation of electrochemical sensors that were installed inside a hatch box located on the bottom of the Zeppelin. Results from this work emphasize the potential of these sensors for other in situ airborne applications, e.g., on board unmanned aerial vehicles (UAVs).
Leigh S. Fleming, Andrew C. Manning, Penelope A. Pickers, Grant L. Forster, and Alex J. Etchells
Atmos. Meas. Tech., 16, 387–401, https://doi.org/10.5194/amt-16-387-2023, https://doi.org/10.5194/amt-16-387-2023, 2023
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Measurements of atmospheric O2 can help constrain the carbon cycle processes and quantify fossil fuel CO2 emissions; however, measurement of atmospheric O2 is very challenging, and existing analysers are complex systems to build and maintain. We have tested a new O2 analyser (Picarro Inc. G2207-i) in the laboratory and at Weybourne Atmospheric Observatory. We have found that the G2207-i does not perform as well as an existing O2 analyser from Sable Systems Inc.
Siegfried Schobesberger, Emma L. D'Ambro, Lejish Vettikkat, Ben H. Lee, Qiaoyun Peng, David M. Bell, John E. Shilling, Manish Shrivastava, Mikhail Pekour, Jerome Fast, and Joel A. Thornton
Atmos. Meas. Tech., 16, 247–271, https://doi.org/10.5194/amt-16-247-2023, https://doi.org/10.5194/amt-16-247-2023, 2023
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We present a new, highly sensitive technique for measuring atmospheric ammonia, an important trace gas that is emitted mainly by agriculture. We deployed the instrument on an aircraft during research flights over rural Oklahoma. Due to its fast response, we could analyze correlations with turbulent winds and calculate ammonia emissions from nearby areas at 1 to 2 km resolution. We observed high spatial variability and point sources that are not resolved in the US National Emissions Inventory.
Cited articles
Acker, K., Möller, D., Wieprecht, W., Meixner, F. X., Bohn, B., Gilge,
S., Plass-Dülmer, C., and Berresheim, H.: Strong daytime production of
OH from HNO2 at a rural mountain site, Geophys. Res. Lett., 33, L02809, https://doi.org/10.1029/2005GL024643, 2006.
Afif, C., Jambert, C., Michoud, V., Colomb, A., Eyglunent, G., Borbon, A.,
Daële, V., Doussin, J.-F., and Perros, P.: NitroMAC: An instrument for
the measurement of HONO and intercomparison with a long-path absorption
photometer, J. Environ. Sci., 40, 105–113,
https://doi.org/10.1016/j.jes.2015.10.024, 2016.
Bartolomei, V., Gomez Alvarez, E., Wittmer, J., Tlili, S., Strekowski, R.,
Temime-Roussel, B., Quivet, E., Wortham, H., Zetzsch, C., Kleffmann, J., and
Gligorovski, S.: Combustion Processes as a Source of High Levels of Indoor
Hydroxyl Radicals through the Photolysis of Nitrous Acid, Environ. Sci.
Technol., 49, 6599–6607, https://doi.org/10.1021/acs.est.5b01905, 2015.
Beckett, W. S., Russi, M. B., Haber, A. D., Rivkin, R. M., Sullivan, J. R.,
Tameroglu, Z., Mohsenin, V., and Leaderer, B. P.: Effect of nitrous acid on
lung function in asthmatics: a chamber study, Environ. Health. Persp.,
103, 372–375, https://doi.org/10.1289/ehp.95103372, 1995.
Bejan, I., Abd El Aal, Y., Barnes, I., Benter, T., Bohn, B., Wiesen, P., and
Kleffmann, J.: The photolysis of ortho-nitrophenols: a new gas phase source
of HONO, Phys. Chem. Chem. Phys., 8, 2028–2035, https://doi.org/10.1039/B516590C, 2006.
Brauer, M., Ryan, P. B., Suh, H. H., Koutrakis, P., Spengler, J. D., Leslie,
N. P., and Billick, I. H.: Measurements of nitrous acid inside two research
houses, Environ. Sci. Technol., 24, 1521–1527, https://doi.org/10.1021/es00080a011, 1990.
Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Cappa, C.,
Crounse, J. D., Dibble, T. S., Huie, R. E., Kolb, C. E., Kurylo, M. J.,
Orkin, V. L., Percival, C. J., Wilmouth, D. M., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 19, JPL Publication 19-5, Jet Propulsion Laboratory, Pasadena, 2019.
Cantrell, C. A., Zimmer, A., and Tyndall, G. S.: Absorption cross sections
for water vapor from 183 to 193 nm, Geophys. Res. Lett., 24, 2195–2198, https://doi.org/10.1029/97GL02100, 1997.
Collins, D. B., Hems, R. F., Zhou, S., Wang, C., Grignon, E., Alavy, M.,
Siegel, J. A., and Abbatt, J. P. D.: Evidence for Gas–Surface Equilibrium
Control of Indoor Nitrous Acid, Environ. Sci. Technol., 52, 12419–12427, https://doi.org/10.1021/acs.est.8b04512, 2018.
Crilley, L. R., Kramer, L. J., Ouyang, B., Duan, J., Zhang, W., Tong, S., Ge, M., Tang, K., Qin, M., Xie, P., Shaw, M. D., Lewis, A. C., Mehra, A., Bannan, T. J., Worrall, S. D., Priestley, M., Bacak, A., Coe, H., Allan, J., Percival, C. J., Popoola, O. A. M., Jones, R. L., and Bloss, W. J.: Intercomparison of nitrous acid (HONO) measurement techniques in a megacity (Beijing), Atmos. Meas. Tech., 12, 6449–6463, https://doi.org/10.5194/amt-12-6449-2019, 2019.
Dibb, J. E., Gregory Huey, L., Slusher, D. L., and Tanner, D. J.: Soluble
reactive nitrogen oxides at South Pole during ISCAT 2000, Atmos. Environ.,
38, 5399–5409, https://doi.org/10.1016/j.atmosenv.2003.01.001, 2004.
Duan, J., Qin, M., Ouyang, B., Fang, W., Li, X., Lu, K., Tang, K., Liang, S., Meng, F., Hu, Z., Xie, P., Liu, W., and Häsler, R.: Development of an incoherent broadband cavity-enhanced absorption spectrometer for in situ measurements of HONO and NO2, Atmos. Meas. Tech., 11, 4531–4543, https://doi.org/10.5194/amt-11-4531-2018, 2018.
Dusanter, S., Vimal, D., and Stevens, P. S.: Technical note: Measuring tropospheric OH and HO2 by laser-induced fluorescence at low pressure. A comparison of calibration techniques, Atmos. Chem. Phys., 8, 321–340, https://doi.org/10.5194/acp-8-321-2008, 2008.
Dusanter, S., Vimal, D., Stevens, P. S., Volkamer, R., and Molina, L. T.: Measurements of OH and HO2 concentrations during the MCMA-2006 field campaign – Part 1: Deployment of the Indiana University laser-induced fluorescence instrument, Atmos. Chem. Phys., 9, 1665–1685, https://doi.org/10.5194/acp-9-1665-2009, 2009a.
Dusanter, S., Vimal, D., Stevens, P. S., Volkamer, R., Molina, L. T., Baker, A., Meinardi, S., Blake, D., Sheehy, P., Merten, A., Zhang, R., Zheng, J., Fortner, E. C., Junkermann, W., Dubey, M., Rahn, T., Eichinger, B., Lewandowski, P., Prueger, J., and Holder, H.: Measurements of OH and HO2 concentrations during the MCMA-2006 field campaign – Part 2: Model comparison and radical budget, Atmos. Chem. Phys., 9, 6655–6675, https://doi.org/10.5194/acp-9-6655-2009, 2009b.
Dyson, J. E., Boustead, G. A., Fleming, L. T., Blitz, M., Stone, D., Arnold, S. R., Whalley, L. K., and Heard, D. E.: Production of HONO from NO2 uptake on illuminated TiO2 aerosol particles and following the illumination of mixed TiO2/ammonium nitrate particles, Atmos. Chem. Phys., 21, 5755–5775, https://doi.org/10.5194/acp-21-5755-2021, 2021.
Farmer, D. K., Vance, M. E., Abbatt, J. P. D., Abeleira, A., Alves, M. R.,
Arata, C., Boedicker, E., Bourne, S., Cardoso-Saldaña, F., Corsi, R.,
DeCarlo, P. F., Goldstein, A. H., Grassian, V. H., Hildebrandt Ruiz, L.,
Jimenez, J. L., Kahan, T. F., Katz, E. F., Mattila, J. M., Nazaroff, W. W.,
Novoselac, A., O'Brien, R. E., Or, V. W., Patel, S., Sankhyan, S., Stevens,
P. S., Tian, Y., Wade, M., Wang, C., Zhou, S., and Zhou, Y.: Overview of
HOMEChem: House Observations of Microbial and Environmental Chemistry,
Environ. Sci., 21, 1280–1300, https://doi.org/10.1039/C9EM00228F, 2019.
Febo, A., Perrino, C., Gherardi, M., and Sparapani, R.: Evaluation of a
High-Purity and High-Stability Continuous Generation System for Nitrous
Acid, Environ. Sci. Technol., 29, 2390–2395, https://doi.org/10.1021/es00009a035, 1995.
Fittschen, C., Al Ajami, M., Batut, S., Ferracci, V., Archer-Nicholls, S., Archibald, A. T., and Schoemaecker, C.: ROOOH: a missing piece of the puzzle for OH measurements in low-NO environments?, Atmos. Chem. Phys., 19, 349–362, https://doi.org/10.5194/acp-19-349-2019, 2019.
George, C., Strekowski, R. S., Kleffmann, J., Stemmler, K., and Ammann, M.:
Photoenhanced uptake of gaseous NO2 on solid organic compounds: a
photochemical source of HONO?, Faraday Discuss., 130, 195–210, https://doi.org/10.1039/B417888M, 2005.
Gingerysty, N. J. and Osthoff, H. D.: A compact, high-purity source of HONO validated by Fourier transform infrared and thermal-dissociation cavity ring-down spectroscopy, Atmos. Meas. Tech., 13, 4159–4167, https://doi.org/10.5194/amt-13-4159-2020, 2020.
Gómez Alvarez, E., Amedro, D., Afif, C., Gligorovski, S., Schoemaecker,
C., Fittschen, C., Doussin, J.-F., and Wortham, H.: Unexpectedly high indoor
hydroxyl radical concentrations associated with nitrous acid, P. Natl.
Acad. Sci. USA, 110, 13294, https://doi.org/10.1073/pnas.1308310110, 2013.
Griffith, S. M., Hansen, R. F., Dusanter, S., Michoud, V., Gilman, J. B.,
Kuster, W. C., Veres, P. R., Graus, M., de Gouw, J. A., Roberts, J., Young,
C., Washenfelder, R., Brown, S. S., Thalman, R., Waxman, E., Volkamer, R.,
Tsai, C., Stutz, J., Flynn, J. H., Grossberg, N., Lefer, B., Alvarez, S. L.,
Rappenglueck, B., Mielke, L. H., Osthoff, H. D., and Stevens, P. S.:
Measurements of hydroxyl and hydroperoxy radicals during CalNex-LA: Model
comparisons and radical budgets, J. Geophys. Res.-Atmos., 121, 4211–4232, https://doi.org/10.1002/2015JD024358, 2016.
Heard, D. E. and Pilling, M. J.: Measurement of OH and HO2 in the
Troposphere, Chem. Rev., 103, 5163–5198, https://doi.org/10.1021/cr020522s, 2003.
Heland, J., Kleffmann, J., Kurtenbach, R., and Wiesen, P.: A New Instrument
To Measure Gaseous Nitrous Acid (HONO) in the Atmosphere, Environ. Sci.
Technol., 35, 3207–3212, https://doi.org/10.1021/es000303t, 2001.
Hofzumahaus, A., Brauers, T., Aschmutat, U., Brandenburger, U., Dorn, H. P.,
Hausmann, M., Heßling, M., Holland, F., Plass-Dülmer, C., Sedlacek,
M., Weber, M., and Ehhalt, D. H.: Reply [to “Comment on `The measurement of
tropospheric OH radicals by laser-induced fluorescence spectroscopy during
the POPCORN field campaign' by Hofzumahaus et al. and `Intercomparison of
tropospheric OH radical measurements by multiple folded long-path laser
absorption and laser induced fluorescence' by Brauers et al.”], Geophys.
Res. Lett., 24, 3039–3040, https://doi.org/10.1029/97GL02947, 1997.
Huang, G., Zhou, X., Deng, G., Qiao, H., and Civerolo, K.: Measurements of
atmospheric nitrous acid and nitric acid, Atmos. Environ., 36, 2225–2235, https://doi.org/10.1016/S1352-2310(02)00170-X, 2002.
Jarvis, D. L., Leaderer, B. P., Chinn, S., and Burney, P. G.: Indoor nitrous
acid and respiratory symptoms and lung function in adults, Thorax, 60, 474, https://doi.org/10.1136/thx.2004.032177, 2005.
Jenkin, M. E., Saunders, S. M., and Pilling, M. J.: The tropospheric
degradation of volatile organic compounds: a protocol for mechanism
development, Atmos. Environ., 31, 81–104,
https://doi.org/10.1016/S1352-2310(96)00105-7, 1997.
Jordan, N. and Osthoff, H. D.: Quantification of nitrous acid (HONO) and nitrogen dioxide (NO2) in ambient air by broadband cavity-enhanced absorption spectroscopy (IBBCEAS) between 361 and 388 nm, Atmos. Meas. Tech., 13, 273–285, https://doi.org/10.5194/amt-13-273-2020, 2020.
Kirchstetter, T. W., Harley, R. A., and Littlejohn, D.: Measurement of
Nitrous Acid in Motor Vehicle Exhaust, Environ. Sci. Technol., 30,
2843–2849, https://doi.org/10.1021/es960135y, 1996.
Kleffmann, J., Becker, K. H., and Wiesen, P.: Heterogeneous NO2 conversion
processes on acid surfaces: possible atmospheric implications, Atmos.
Environ., 32, 2721–2729, https://doi.org/10.1016/S1352-2310(98)00065-X, 1998.
Kleffmann, J., Gavriloaiei, T., Hofzumahaus, A., Holland, F., Koppmann, R.,
Rupp, L., Schlosser, E., Siese, M., and Wahner, A.: Daytime formation of
nitrous acid: A major source of OH radicals in a forest, Geophys. Res.
Lett.,32, L05818, https://doi.org/10.1029/2005GL022524, 2005.
Kowal, S. F., Allen, S. R., and Kahan, T. F.: Wavelength-Resolved Photon
Fluxes of Indoor Light Sources: Implications for HOx Production, Environ.
Sci. Technol., 51, 10423–10430, https://doi.org/10.1021/acs.est.7b02015, 2017.
Kurtenbach, R., Becker, K. H., Gomes, J. A. G., Kleffmann, J., Lörzer,
J. C., Spittler, M., Wiesen, P., Ackermann, R., Geyer, A., and Platt, U.:
Investigations of emissions and heterogeneous formation of HONO in a road
traffic tunnel, Atmos. Environ., 35, 3385–3394, https://doi.org/10.1016/S1352-2310(01)00138-8, 2001.
Lanzendorf, E. J., Hanisco, T. F., Donahue, N. M., and Wennberg, P. O.:
Comment on: “The measurement of tropospheric OH radicals by laser-induced
fluorescence spectroscopy during the POPCORN Field Campaign” by Hofzumahaus
et al. and “Intercomparison of tropospheric OH radical measurements by
multiple folded long-path laser absorption and laser induced fluorescence”
by Brauers et al, Geophys. Res. Lett., 24, 3037–3038, https://doi.org/10.1029/97GL02899,
1997.
Lao, M., Crilley, L. R., Salehpoor, L., Furlani, T. C., Bourgeois, I., Neuman, J. A., Rollins, A. W., Veres, P. R., Washenfelder, R. A., Womack, C. C., Young, C. J., and VandenBoer, T. C.: A portable, robust, stable, and tunable calibration source for gas-phase nitrous acid (HONO), Atmos. Meas. Tech., 13, 5873–5890, https://doi.org/10.5194/amt-13-5873-2020, 2020.
Lawler, M. J., Sander, R., Carpenter, L. J., Lee, J. D., von Glasow, R., Sommariva, R., and Saltzman, E. S.: HOCl and Cl2 observations in marine air, Atmos. Chem. Phys., 11, 7617–7628, https://doi.org/10.5194/acp-11-7617-2011, 2011.
Leaderer, B. P., Naeher, L., Jankun, T., Balenger, K., Holford, T. R., Toth,
C., Sullivan, J., Wolfson, J. M., and Koutrakis, P.: Indoor, outdoor, and
regional summer and winter concentrations of PM10, PM2.5, SO
Lee, J. D., Whalley, L. K., Heard, D. E., Stone, D., Dunmore, R. E., Hamilton, J. F., Young, D. E., Allan, J. D., Laufs, S., and Kleffmann, J.: Detailed budget analysis of HONO in central London reveals a missing daytime source, Atmos. Chem. Phys., 16, 2747–2764, https://doi.org/10.5194/acp-16-2747-2016, 2016.
Lee, K., Xue, J., Geyh Alison, S., Ozkaynak, H., Leaderer Brian, P.,
Weschler Charles, J., and Spengler John, D.: Nitrous acid, nitrogen dioxide,
and ozone concentrations in residential environments, Environ. Health.
Persp., 110, 145–150, https://doi.org/10.1289/ehp.02110145, 2002.
Legrand, M., Preunkert, S., Frey, M., Bartels-Rausch, Th., Kukui, A., King, M. D., Savarino, J., Kerbrat, M., and Jourdain, B.: Large mixing ratios of atmospheric nitrous acid (HONO) at Concordia (East Antarctic Plateau) in summer: a strong source from surface snow?, Atmos. Chem. Phys., 14, 9963–9976, https://doi.org/10.5194/acp-14-9963-2014, 2014.
Lew, M. M., Rickly, P. S., Bottorff, B. P., Reidy, E., Sklaveniti, S., Léonardis, T., Locoge, N., Dusanter, S., Kundu, S., Wood, E., and Stevens, P. S.: OH and HO2 radical chemistry in a midlatitude forest: measurements and model comparisons, Atmos. Chem. Phys., 20, 9209–9230, https://doi.org/10.5194/acp-20-9209-2020, 2020.
Li, Y. Q., Schwab, J. J., and Demerjian, K. L.: Fast time response
measurements of gaseous nitrous acid using a tunable diode laser absorption
spectrometer: HONO emission source from vehicle exhausts, Geophys. Res.
Lett., 35, L04803, https://doi.org/10.1029/2007GL031218, 2008.
Liao, W., Hecobian, A., Mastromarino, J., and Tan, D.: Development of a
photo-fragmentation/laser-induced fluorescence measurement of atmospheric
nitrous acid, Atmos. Environ., 40, 17–26, https://doi.org/10.1016/j.atmosenv.2005.07.001,
2006a.
Liao, W., Case, A. T., Mastromarino, J., Tan, D., and Dibb, J. E.:
Observations of HONO by laser-induced fluorescence at the South Pole during
ANTCI 2003, Geophys. Res. Lett., 33, L09810, https://doi.org/10.1029/2005GL025470, 2006b.
Liao, J., Huey, L. G., Tanner, D. J., Flocke, F. M., Orlando, J. J., Neuman,
J. A., Nowak, J. B., Weinheimer, A. J., Hall, S. R., Smith, J. N., Fried,
A., Staebler, R. M., Wang, Y., Koo, J.-H., Cantrell, C. A., Weibring, P.,
Walega, J., Knapp, D. J., Shepson, P. B., and Stephens, C. R.: Observations of
inorganic bromine (HOBr, BrO, and Br2) speciation at Barrow, Alaska, in
spring 2009, J. Geophys. Res., 117, D00R16, https://doi.org/10.1029/2011JD016641, 2012.
Liu, J., Li, S., Zeng, J., Mekic, M., Yu, Z., Zhou, W., Loisel, G.,
Gandolfo, A., Song, W., Wang, X., Zhou, Z., Herrmann, H., Li, X., and
Gligorovski, S.: Assessing indoor gas phase oxidation capacity through
real-time measurements of HONO and NOx in Guangzhou, China, Environ. Sci., 21, 1393–1402, https://doi.org/10.1039/C9EM00194H, 2019.
Logue, J. M., Klepeis, N. E., Lobscheid, A. B., and Singer, B. C.: Pollutant
Exposures from Natural Gas Cooking Burners: A Simulation-Based Assessment
for Southern California, Environ. Health Persp., 122, 43–50, 2014.
Mao, J., Ren, X., Zhang, L., Van Duin, D. M., Cohen, R. C., Park, J.-H., Goldstein, A. H., Paulot, F., Beaver, M. R., Crounse, J. D., Wennberg, P. O., DiGangi, J. P., Henry, S. B., Keutsch, F. N., Park, C., Schade, G. W., Wolfe, G. M., Thornton, J. A., and Brune, W. H.: Insights into hydroxyl measurements and atmospheric oxidation in a California forest, Atmos. Chem. Phys., 12, 8009–8020, https://doi.org/10.5194/acp-12-8009-2012, 2012.
Meusel, H., Kuhn, U., Reiffs, A., Mallik, C., Harder, H., Martinez, M., Schuladen, J., Bohn, B., Parchatka, U., Crowley, J. N., Fischer, H., Tomsche, L., Novelli, A., Hoffmann, T., Janssen, R. H. H., Hartogensis, O., Pikridas, M., Vrekoussis, M., Bourtsoukidis, E., Weber, B., Lelieveld, J., Williams, J., Pöschl, U., Cheng, Y., and Su, H.: Daytime formation of nitrous acid at a coastal remote site in Cyprus indicating a common ground source of atmospheric HONO and NO, Atmos. Chem. Phys., 16, 14475–14493, https://doi.org/10.5194/acp-16-14475-2016, 2016.
Meusel, H., Tamm, A., Kuhn, U., Wu, D., Leifke, A. L., Fiedler, S., Ruckteschler, N., Yordanova, P., Lang-Yona, N., Pöhlker, M., Lelieveld, J., Hoffmann, T., Pöschl, U., Su, H., Weber, B., and Cheng, Y.: Emission of nitrous acid from soil and biological soil crusts represents an important source of HONO in the remote atmosphere in Cyprus, Atmos. Chem. Phys., 18, 799–813, https://doi.org/10.5194/acp-18-799-2018, 2018.
Mushinski, R. M., Phillips, R. P., Payne, Z. C., Abney, R. B., Jo, I., Fei,
S., Pusede, S. E., White, J. R., Rusch, D. B., and Raff, J. D.: Microbial
mechanisms and ecosystem flux estimation for aerobic NOy emissions from
deciduous forest soils, P. Natl. Acad. Sci. USA, 116, 2138, https://doi.org/10.1073/pnas.1814632116, 2019.
Nakashima, Y. and Sadanaga, Y.: Validation of in situ Measurements of
Atmospheric Nitrous Acid Using Incoherent Broadband Cavity-enhanced
Absorption Spectroscopy, Anal. Sci., 33, 519–524, https://doi.org/10.2116/analsci.33.519, 2017.
Neftel, A., Blatter, A., Hesterberg, R., and Staffelbach, T.: Measurements
of concentration gradients of HNO2 and HNO3 over a semi-natural ecosystem,
Atmos. Environ., 30, 3017–3025, https://doi.org/10.1016/1352-2310(96)00011-8, 1996.
Novelli, A., Hens, K., Tatum Ernest, C., Kubistin, D., Regelin, E., Elste, T., Plass-Dülmer, C., Martinez, M., Lelieveld, J., and Harder, H.: Characterisation of an inlet pre-injector laser-induced fluorescence instrument for the measurement of atmospheric hydroxyl radicals, Atmos. Meas. Tech., 7, 3413–3430, https://doi.org/10.5194/amt-7-3413-2014, 2014.
Oswald, R., Behrendt, T., Ermel, M., Wu, D., Su, H., Cheng, Y., Breuninger,
C., Moravek, A., Mougin, E., Delon, C., Loubet, B., Pommerening-Röser,
A., Sörgel, M., Pöschl, U., Hoffmann, T., Andreae, M. O., Meixner,
F. X., and Trebs, I.: HONO Emissions from Soil Bacteria as a Major Source of
Atmospheric Reactive Nitrogen, Science, 341, 1233, https://doi.org/10.1126/science.1242266,
2013.
Oswald, R., Ermel, M., Hens, K., Novelli, A., Ouwersloot, H. G., Paasonen, P., Petäjä, T., Sipilä, M., Keronen, P., Bäck, J., Königstedt, R., Hosaynali Beygi, Z., Fischer, H., Bohn, B., Kubistin, D., Harder, H., Martinez, M., Williams, J., Hoffmann, T., Trebs, I., and Sörgel, M.: A comparison of HONO budgets for two measurement heights at a field station within the boreal forest in Finland, Atmos. Chem. Phys., 15, 799–813, https://doi.org/10.5194/acp-15-799-2015, 2015.
Pérez, I. M., Wooldridge, P. J., and Cohen, R. C.: Laboratory evaluation
of a novel thermal dissociation chemiluminescence method for in situ
detection of nitrous acid, Atmos. Environ., 41, 3993–4001,
https://doi.org/10.1016/j.atmosenv.2007.01.060, 2007.
Perner, D. and Platt, U.: Detection of nitrous acid in the atmosphere by
differential optical absorption, Geophys. Res. Lett., 6, 917–920, https://doi.org/10.1029/GL006i012p00917, 1979.
Pinto, J. P., Dibb, J., Lee, B. H., Rappenglück, B., Wood, E. C., Levy,
M., Zhang, R. Y., Lefer, B., Ren, X. R., Stutz, J., Tsai, C., Ackermann, L.,
Golovko, J., Herndon, S. C., Oakes, M., Meng, Q. Y., Munger, J. W.,
Zahniser, M., and Zheng, J.: Intercomparison of field measurements of
nitrous acid (HONO) during the SHARP campaign, J. Geophys. Res.-Atmos.,
119, 5583–5601, https://doi.org/10.1002/2013JD020287, 2014.
Ramazan, K. A., Syomin, D., and Finlayson-Pitts, B. J.: The photochemical
production of HONO during the heterogeneous hydrolysis of NO2, Phys. Chem.
Chem. Phys., 6, 3836–3843, https://doi.org/10.1039/B402195A, 2004.
Ren, X., van Duin, D., Cazorla, M., Chen, S., Mao, J., Zhang, L., Brune, W.
H., Flynn, J. H., Grossberg, N., Lefer, B. L., Rappenglück, B., Wong, K.
W., Tsai, C., Stutz, J., Dibb, J. E., Thomas Jobson, B., Luke, W. T., and
Kelley, P.: Atmospheric oxidation chemistry and ozone production: Results
from SHARP 2009 in Houston, Texas, J. Geophys. Res.-Atmos., 118, 5770–5780, https://doi.org/10.1002/jgrd.50342, 2013.
Rickly, P. and Stevens, P. S.: Measurements of a potential interference with laser-induced fluorescence measurements of ambient OH from the ozonolysis of biogenic alkenes, Atmos. Meas. Tech., 11, 1–16, https://doi.org/10.5194/amt-11-1-2018, 2018.
Roberts, J. M., Veres, P., Warneke, C., Neuman, J. A., Washenfelder, R. A., Brown, S. S., Baasandorj, M., Burkholder, J. B., Burling, I. R., Johnson, T. J., Yokelson, R. J., and de Gouw, J.: Measurement of HONO, HNCO, and other inorganic acids by negative-ion proton-transfer chemical-ionization mass spectrometry (NI-PT-CIMS): application to biomass burning emissions, Atmos. Meas. Tech., 3, 981–990, https://doi.org/10.5194/amt-3-981-2010, 2010.
Ródenas, M., Muñoz, A., Alacreu, F., Brauers, T., Dorn, H.-P.,
Kleffmann, J., and Bloss, W.: Assessment of HONO Measurements: The FIONA
Campaign at EUPHORE, Disposal of Dangerous Chemicals in Urban Areas and Mega
Cities, Dordrecht, 45–58, 2013.
Rohrer, F. and Berresheim, H.: Strong correlation between levels of
tropospheric hydroxyl radicals and solar ultraviolet radiation, Nature, 442,
p. 184, https://doi.org/10.1038/nature04924, 2006.
Salthammer, T., Mentese, S., and Marutzky, R.: Formaldehyde in the Indoor
Environment, Chem. Rev., 110, 2536–2572, 2010.
Stemmler, K., Ammann, M., Donders, C., Kleffmann, J., and George, C.:
Photosensitized reduction of nitrogen dioxide on humic acid as a source of
nitrous acid, Nature, 440, p. 195, https://doi.org/10.1038/nature04603, 2006.
Stutz, J., Kim, E. S., Platt, U., Bruno, P., Perrino, C., and Febo, A.:
UV-visible absorption cross sections of nitrous acid, J. Geophys. Res.-Atmos., 105, 14585–14592, https://doi.org/10.1029/2000JD900003, 2000.
Stutz, J., Alicke, B., Ackermann, R., Geyer, A., Wang, S., White, A. B.,
Williams, E. J., Spicer, C. W., and Fast, J. D.: Relative humidity
dependence of HONO chemistry in urban areas, J. Geophys. Res.-Atmos., 109, D03307, https://doi.org/10.1029/2003JD004135, 2004.
Stutz, J., Oh, H.-J., Whitlow, S. I., Anderson, C., Dibb, J. E., Flynn, J.
H., Rappenglück, B., and Lefer, B.: Simultaneous DOAS and mist-chamber
IC measurements of HONO in Houston, TX, Atmos. Environ., 44, 4090–4098, https://doi.org/10.1016/j.atmosenv.2009.02.003, 2010.
Su, H., Cheng, Y., Oswald, R., Behrendt, T., Trebs, I., Meixner, F. X.,
Andreae, M. O., Cheng, P., Zhang, Y., and Pöschl, U.: Soil Nitrite as a
Source of Atmospheric HONO and OH Radicals, Science, 333, 1616, https://doi.org/10.1126/science.1207687, 2011.
Tang, K., Qin, M., Fang, W., Duan, J., Meng, F., Ye, K., Zhang, H., Xie, P., He, Y., Xu, W., Liu, J., and Liu, W.: Simultaneous detection of atmospheric HONO and NO2 utilising an IBBCEAS system based on an iterative algorithm, Atmos. Meas. Tech., 13, 6487–6499, https://doi.org/10.5194/amt-13-6487-2020, 2020.
Tang, Y., An, J., Wang, F., Li, Y., Qu, Y., Chen, Y., and Lin, J.: Impacts of an unknown daytime HONO source on the mixing ratio and budget of HONO, and hydroxyl, hydroperoxyl, and organic peroxy radicals, in the coastal regions of China, Atmos. Chem. Phys., 15, 9381–9398, https://doi.org/10.5194/acp-15-9381-2015, 2015.
Tham, Y. J., He, X.-C., Li, Q., Cuevas, C. A., Shen, J., Kalliokoski, J.,
Yan, C., Iyer, S., Lehmusjarvi, T., Jang, S., Thakur, R. C., Beck, L.,
Kemppainen, D., Olin, M., Sarnela, N., Mikkila, J., Hakala, J., Marbouti,
M., Yao, L., Li, H., Huang, W., Wang, Y., Wimmer, D., Zha, Q., Virkanen, J.,
Spain, T. G., O'Doherty, S., Jokinen, T., Bianchi, F., Petaja, T., Worsnop,
D. R., Mauldin, R. L., Ovadnevaite, J., Ceburnis, D., Maier, N. M., Kulmala,
M., O'Dowd, C., Dal Maso, M., Saiz-Lopez, A., and Sipila, M.: Direct field
evidence of autocatalytic iodine release from atmospheric aerosol, P.
Natl. Acad. Sci. USA, 118, e2009951118, https://doi.org/10.1073/pnas.2009951118, 2021.
Tsai, C., Spolaor, M., Colosimo, S. F., Pikelnaya, O., Cheung, R., Williams, E., Gilman, J. B., Lerner, B. M., Zamora, R. J., Warneke, C., Roberts, J. M., Ahmadov, R., de Gouw, J., Bates, T., Quinn, P. K., and Stutz, J.: Nitrous acid formation in a snow-free wintertime polluted rural area, Atmos. Chem. Phys., 18, 1977–1996, https://doi.org/10.5194/acp-18-1977-2018, 2018.
van Strien, R. T., Gent, J. F., Belanger, K., Triche, E., Bracken, M. B.,
and Leaderer, B. P.: Exposure to NO2 and Nitrous Acid and Respiratory
Symptoms in the First Year of Life, Epidemiology, 15, 471–478, 2004.
Vecera, Z., and Dasgupta, P. K.: Indoor Nitrous Acid Levels. Production of
Nitrous Acid from Open-Flame Sources, Int. J. Environ. Anal. Chem., 56,
311–316, https://doi.org/10.1080/03067319408034109, 1994.
Veres, P. R., Roberts, J. M., Wild, R. J., Edwards, P. M., Brown, S. S., Bates, T. S., Quinn, P. K., Johnson, J. E., Zamora, R. J., and de Gouw, J.: Peroxynitric acid (HO2NO2) measurements during the UBWOS 2013 and 2014 studies using iodide ion chemical ionization mass spectrometry, Atmos. Chem. Phys., 15, 8101–8114, https://doi.org/10.5194/acp-15-8101-2015, 2015.
Villena, G., Wiesen, P., Cantrell, C. A., Flocke, F., Fried, A., Hall, S.
R., Hornbrook, R. S., Knapp, D., Kosciuch, E., Mauldin Iii, R. L., McGrath,
J. A., Montzka, D., Richter, D., Ullmann, K., Walega, J., Weibring, P.,
Weinheimer, A., Staebler, R. M., Liao, J., Huey, L. G., and Kleffmann, J.:
Nitrous acid (HONO) during polar spring in Barrow, Alaska: A net source of
OH radicals?, J. Geophys. Res.-Atmos., 116, D00R07, https://doi.org/10.1029/2011JD016643, 2011.
Volkamer, R., Sheehy, P., Molina, L. T., and Molina, M. J.: Oxidative capacity of the Mexico City atmosphere – Part 1: A radical source perspective, Atmos. Chem. Phys., 10, 6969–6991, https://doi.org/10.5194/acp-10-6969-2010, 2010.
Wang, C., Bottorff, B., Reidy, E., Rosales, C. M. F., Collins, D. B.,
Novoselac, A., Farmer, D. K., Vance, M. E., Stevens, P. S., and Abbatt, J.
P. D.: Cooking, Bleach Cleaning, and Air Conditioning Strongly Impact Levels
of HONO in a House, Environ. Sci. Technol., 54, 13488–13497, https://doi.org/10.1021/acs.est.0c05356, 2020a.
Wang, C., Collins, D. B., Arata, C., Goldstein, A. H., Mattila, J. M.,
Farmer, D. K., Ampollini, L., DeCarlo, P. F., Novoselac, A., Vance, M. E.,
Nazaroff, W. W., and Abbatt, J. P. D.: Surface reservoirs dominate dynamic
gas-surface partitioning of many indoor air constituents, Sci. Adv., 6,
eaay8973, https://doi.org/10.1126/sciadv.aay8973, 2020b.
Weber, B., Wu, D., Tamm, A., Ruckteschler, N., Rodríguez-Caballero, E.,
Steinkamp, J., Meusel, H., Elbert, W., Behrendt, T., Sörgel, M., Cheng,
Y., Crutzen, P. J., Su, H., and Pöschl, U.: Biological soil crusts
accelerate the nitrogen cycle through large NO and HONO emissions in
drylands, P. Natl. Acad. Sci. USA, 112, 15384, https://doi.org/10.1073/pnas.1515818112, 2015.
Wennberg, P. O., Cohen, R. C., Hazen, N. L., Lapson, L. B., Allen, N. T.,
Hanisco, T. F., Oliver, J. F., Lanham, N. W., Demusz, J. N., and Anderson,
J. G.: Aircraft-borne, laser-induced fluorescence instrument for the in situ
detection of hydroxyl and hydroperoxyl radicals, Rev. Sci. Instrum., 65,
1858–1876, https://doi.org/10.1063/1.1144835, 1994.
Xu, Z., Wang, T., Wu, J., Xue, L., Chan, J., Zha, Q., Zhou, S., Louie, P. K.
K., and Luk, C. W. Y.: Nitrous acid (HONO) in a polluted subtropical
atmosphere: Seasonal variability, direct vehicle emissions and heterogeneous
production at ground surface, Atmos. Environ., 106, 100–109, https://doi.org/10.1016/j.atmosenv.2015.01.061, 2015.
Xue, C., Zhang, C., Ye, C., Liu, P., Catoire, V., Krysztofiak, G., Chen, H.,
Ren, Y., Zhao, X., Wang, J., Zhang, F., Zhang, C., Zhang, J., An, J., Wang,
T., Chen, J., Kleffmann, J., Mellouki, A., and Mu, Y.: HONO Budget and Its
Role in Nitrate Formation in the Rural North China Plain, Environ. Sci.
Technol., 54, 11048–11057, https://doi.org/10.1021/acs.est.0c01832, 2020.
Young, C. J., Washenfelder, R. A., Roberts, J. M., Mielke, L. H., Osthoff,
H. D., Tsai, C., Pikelnaya, O., Stutz, J., Veres, P. R., Cochran, A. K.,
VandenBoer, T. C., Flynn, J., Grossberg, N., Haman, C. L., Lefer, B., Stark,
H., Graus, M., de Gouw, J., Gilman, J. B., Kuster, W. C., and Brown, S. S.:
Vertically Resolved Measurements of Nighttime Radical Reservoirs in Los
Angeles and Their Contribution to the Urban Radical Budget, Environ. Sci.
Technol., 46, 10965–10973, https://doi.org/10.1021/es302206a, 2012.
Zhou, S., Young, C. J., VandenBoer, T. C., Kowal, S. F., and Kahan, T. F.:
Time-Resolved Measurements of Nitric Oxide, Nitrogen Dioxide, and Nitrous
Acid in an Occupied New York Home, Environ. Sci. Technol., 52, 8355–8364, https://doi.org/10.1021/acs.est.8b01792, 2018.
Zhou, X., Qiao, H., Deng, G., and Civerolo, K.: A Method for the Measurement
of Atmospheric HONO Based on DNPH Derivatization and HPLC Analysis, Environ.
Sci. Technol., 33, 3672–3679, https://doi.org/10.1021/es981304c, 1999.
Zhou, X., Zhang, N., TerAvest, M., Tang, D., Hou, J., Bertman, S.,
Alaghmand, M., Shepson, P. B., Carroll, M. A., Griffith, S., Dusanter, S.,
and Stevens, P. S.: Nitric acid photolysis on forest canopy surface as a
source for tropospheric nitrous acid, Nat. Geosci., 4, 440–443, https://doi.org/10.1038/ngeo1164, 2011.
Short summary
Nitrous acid (HONO) is an important source of hydroxyl (OH) radicals, the primary oxidant in the atmosphere. Accurate measurements of HONO are thus important to understand the oxidative capacity of the atmosphere. A new instrument capable of measuring atmospheric nitrous acid (HONO) with high sensitivity is presented, utilizing laser photofragmentation of ambient HONO and subsequent detection of the OH radical fragment.
Nitrous acid (HONO) is an important source of hydroxyl (OH) radicals, the primary oxidant in the...
