Articles | Volume 7, issue 8
https://doi.org/10.5194/amt-7-2421-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-7-2421-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
08 Aug 2014
Research article |
| 08 Aug 2014
Calibrated high-precision 17O-excess measurements using cavity ring-down spectroscopy with laser-current-tuned cavity resonance
E. J. Steig
Δ*IsoLab, Earth & Space Sciences, and Quaternary Research Center, University of Washington, Seattle, WA 98195, USA
Centre for Ice and Climate, Niels Bohr Institute, University of Copenhagen, 2100 Copenhagen, Denmark
V. Gkinis
Centre for Ice and Climate, Niels Bohr Institute, University of Copenhagen, 2100 Copenhagen, Denmark
Institute of Arctic and Alpine Research, University of Colorado, Boulder, CO 80309, USA
A. J. Schauer
Δ*IsoLab, Earth & Space Sciences, and Quaternary Research Center, University of Washington, Seattle, WA 98195, USA
S. W. Schoenemann
Δ*IsoLab, Earth & Space Sciences, and Quaternary Research Center, University of Washington, Seattle, WA 98195, USA
K. Samek
Δ*IsoLab, Earth & Space Sciences, and Quaternary Research Center, University of Washington, Seattle, WA 98195, USA
J. Hoffnagle
Picarro Inc. Santa Clara, CA 95054, USA
K. J. Dennis
Picarro Inc. Santa Clara, CA 95054, USA
S. M. Tan
Picarro Inc. Santa Clara, CA 95054, USA
Related authors
Mira Berdahl, Gunter R. Leguy, William H. Lipscomb, Bette L. Otto-Bliesner, Esther C. Brady, Robert A. Tomas, Nathan M. Urban, Ian Miller, Harriet Morgan, and Eric J. Steig
Clim. Past, 20, 2349–2371, https://doi.org/10.5194/cp-20-2349-2024, https://doi.org/10.5194/cp-20-2349-2024, 2024
Short summary
Short summary
Studying climate conditions near the Antarctic ice sheet (AIS) during Earth’s past warm periods informs us about how global warming may influence AIS ice loss. Using a global climate model, we investigate climate conditions near the AIS during the Last Interglacial (129 to 116 kyr ago), a period with warmer global temperatures and higher sea level than today. We identify the orbital and freshwater forcings that could cause ice loss and probe the mechanisms that lead to warmer climate conditions.
Gemma K. O'Connor, Paul R. Holland, Eric J. Steig, Pierre Dutrieux, and Gregory J. Hakim
The Cryosphere, 17, 4399–4420, https://doi.org/10.5194/tc-17-4399-2023, https://doi.org/10.5194/tc-17-4399-2023, 2023
Short summary
Short summary
Glaciers in West Antarctica are rapidly melting, but the causes are unknown due to limited observations. A leading hypothesis is that an unusually large wind event in the 1940s initiated the ocean-driven melting. Using proxy reconstructions (e.g., using ice cores) and climate model simulations, we find that wind events similar to the 1940s event are relatively common on millennial timescales, implying that ocean variability or climate trends are also necessary to explain the start of ice loss.
Lindsey Davidge, Eric J. Steig, and Andrew J. Schauer
Atmos. Meas. Tech., 15, 7337–7351, https://doi.org/10.5194/amt-15-7337-2022, https://doi.org/10.5194/amt-15-7337-2022, 2022
Short summary
Short summary
We describe a continuous-flow analysis (CFA) method to measure Δ17O by laser spectroscopy, and we show that centimeter-scale information can be measured reliably in ice cores by this method. We present seasonally resolved Δ17O data from Greenland and demonstrate that the measurement precision is not reduced by the CFA process. Our results encourage the development and use of CFA methods for Δ17O, and they identify calibration strategies as a target for method improvement.
Paul R. Holland, Gemma K. O'Connor, Thomas J. Bracegirdle, Pierre Dutrieux, Kaitlin A. Naughten, Eric J. Steig, David P. Schneider, Adrian Jenkins, and James A. Smith
The Cryosphere, 16, 5085–5105, https://doi.org/10.5194/tc-16-5085-2022, https://doi.org/10.5194/tc-16-5085-2022, 2022
Short summary
Short summary
The Antarctic Ice Sheet is losing ice, causing sea-level rise. However, it is not known whether human-induced climate change has contributed to this ice loss. In this study, we use evidence from climate models and palaeoclimate measurements (e.g. ice cores) to suggest that the ice loss was triggered by natural climate variations but is now sustained by human-forced climate change. This implies that future greenhouse-gas emissions may influence sea-level rise from Antarctica.
Bradley R. Markle and Eric J. Steig
Clim. Past, 18, 1321–1368, https://doi.org/10.5194/cp-18-1321-2022, https://doi.org/10.5194/cp-18-1321-2022, 2022
Short summary
Short summary
The geochemistry preserved in polar ice can provide detailed histories of Earth’s climate over millennia. Here we use the stable isotope ratios of ice from many Antarctic ice cores to reconstruct temperature variability of Antarctica and the midlatitude Southern Hemisphere over tens of thousands of years. We improve upon existing methods to estimate temperature from the geochemical measurements and investigate the patterns of climate change in the past.
Jenna A. Epifanio, Edward J. Brook, Christo Buizert, Jon S. Edwards, Todd A. Sowers, Emma C. Kahle, Jeffrey P. Severinghaus, Eric J. Steig, Dominic A. Winski, Erich C. Osterberg, Tyler J. Fudge, Murat Aydin, Ekaterina Hood, Michael Kalk, Karl J. Kreutz, David G. Ferris, and Joshua A. Kennedy
Clim. Past, 16, 2431–2444, https://doi.org/10.5194/cp-16-2431-2020, https://doi.org/10.5194/cp-16-2431-2020, 2020
Short summary
Short summary
A new ice core drilled at the South Pole provides a 54 000-year paleo-environmental record including the composition of the past atmosphere. This paper describes the gas chronology for the South Pole ice core, based on a high-resolution methane record. The new gas chronology, in combination with the existing ice age scale from Winski et al. (2019), allows a model-independent reconstruction of the delta age record.
Jessica A. Badgeley, Eric J. Steig, Gregory J. Hakim, and Tyler J. Fudge
Clim. Past, 16, 1325–1346, https://doi.org/10.5194/cp-16-1325-2020, https://doi.org/10.5194/cp-16-1325-2020, 2020
Tyler J. Fudge, David A. Lilien, Michelle Koutnik, Howard Conway, C. Max Stevens, Edwin D. Waddington, Eric J. Steig, Andrew J. Schauer, and Nicholas Holschuh
Clim. Past, 16, 819–832, https://doi.org/10.5194/cp-16-819-2020, https://doi.org/10.5194/cp-16-819-2020, 2020
Short summary
Short summary
A 1750 m ice core at the South Pole was recently drilled. The oldest ice is ~55 000 years old. Since ice at the South Pole flows at 10 m per year, the ice in the core originated upstream, where the climate is different. We made measurements of the ice flow, snow accumulation, and temperature upstream. We determined the ice came from ~150 km away near the Titan Dome where the accumulation rate was similar but the temperature was colder. Our measurements improve the interpretation of the ice core.
Dominic A. Winski, Tyler J. Fudge, David G. Ferris, Erich C. Osterberg, John M. Fegyveresi, Jihong Cole-Dai, Zayta Thundercloud, Thomas S. Cox, Karl J. Kreutz, Nikolas Ortman, Christo Buizert, Jenna Epifanio, Edward J. Brook, Ross Beaudette, Jeffrey Severinghaus, Todd Sowers, Eric J. Steig, Emma C. Kahle, Tyler R. Jones, Valerie Morris, Murat Aydin, Melinda R. Nicewonger, Kimberly A. Casey, Richard B. Alley, Edwin D. Waddington, Nels A. Iverson, Nelia W. Dunbar, Ryan C. Bay, Joseph M. Souney, Michael Sigl, and Joseph R. McConnell
Clim. Past, 15, 1793–1808, https://doi.org/10.5194/cp-15-1793-2019, https://doi.org/10.5194/cp-15-1793-2019, 2019
Short summary
Short summary
A deep ice core was recently drilled at the South Pole to understand past variations in the Earth's climate. To understand the information contained within the ice, we present the relationship between the depth and age of the ice in the South Pole Ice Core. We found that the oldest ice in our record is from 54 302 ± 519 years ago. Our results show that, on average, 7.4 cm of snow falls at the South Pole each year.
Robert Tardif, Gregory J. Hakim, Walter A. Perkins, Kaleb A. Horlick, Michael P. Erb, Julien Emile-Geay, David M. Anderson, Eric J. Steig, and David Noone
Clim. Past, 15, 1251–1273, https://doi.org/10.5194/cp-15-1251-2019, https://doi.org/10.5194/cp-15-1251-2019, 2019
Short summary
Short summary
An updated Last Millennium Reanalysis is presented, using an expanded multi-proxy database, and proxy models representing the seasonal characteristics of proxy records, in addition to the dual sensitivity to temperature and moisture of tree-ring-width chronologies. We show enhanced skill in spatial reconstructions of key climate variables in the updated reanalysis, compared to an earlier version, resulting from the combined influences of the enhanced proxy network and improved proxy modeling.
Frazer D. W. Christie, Robert G. Bingham, Noel Gourmelen, Eric J. Steig, Rosie R. Bisset, Hamish D. Pritchard, Kate Snow, and Simon F. B. Tett
The Cryosphere, 12, 2461–2479, https://doi.org/10.5194/tc-12-2461-2018, https://doi.org/10.5194/tc-12-2461-2018, 2018
Short summary
Short summary
With a focus on the hitherto little-studied Marie Byrd Land coastline linking Antarctica's more comprehensively studied Amundsen and Ross Sea Embayments, this paper uses both satellite remote sensing (Landsat, ASTER, ICESat, and CryoSat2) and climate and ocean records (i.e. ERA-Interim, Met Office EN4 data) to examine links between ice recession, inter-decadal atmosphere-ocean forcing and other influences acting upon the Pacific-facing coastline of West Antarctica.
Nancy A. N. Bertler, Howard Conway, Dorthe Dahl-Jensen, Daniel B. Emanuelsson, Mai Winstrup, Paul T. Vallelonga, James E. Lee, Ed J. Brook, Jeffrey P. Severinghaus, Taylor J. Fudge, Elizabeth D. Keller, W. Troy Baisden, Richard C. A. Hindmarsh, Peter D. Neff, Thomas Blunier, Ross Edwards, Paul A. Mayewski, Sepp Kipfstuhl, Christo Buizert, Silvia Canessa, Ruzica Dadic, Helle A. Kjær, Andrei Kurbatov, Dongqi Zhang, Edwin D. Waddington, Giovanni Baccolo, Thomas Beers, Hannah J. Brightley, Lionel Carter, David Clemens-Sewall, Viorela G. Ciobanu, Barbara Delmonte, Lukas Eling, Aja Ellis, Shruthi Ganesh, Nicholas R. Golledge, Skylar Haines, Michael Handley, Robert L. Hawley, Chad M. Hogan, Katelyn M. Johnson, Elena Korotkikh, Daniel P. Lowry, Darcy Mandeno, Robert M. McKay, James A. Menking, Timothy R. Naish, Caroline Noerling, Agathe Ollive, Anaïs Orsi, Bernadette C. Proemse, Alexander R. Pyne, Rebecca L. Pyne, James Renwick, Reed P. Scherer, Stefanie Semper, Marius Simonsen, Sharon B. Sneed, Eric J. Steig, Andrea Tuohy, Abhijith Ulayottil Venugopal, Fernando Valero-Delgado, Janani Venkatesh, Feitang Wang, Shimeng Wang, Dominic A. Winski, V. Holly L. Winton, Arran Whiteford, Cunde Xiao, Jiao Yang, and Xin Zhang
Clim. Past, 14, 193–214, https://doi.org/10.5194/cp-14-193-2018, https://doi.org/10.5194/cp-14-193-2018, 2018
Short summary
Short summary
Temperature and snow accumulation records from the annually dated Roosevelt Island Climate Evolution (RICE) ice core show that for the past 2 700 years, the eastern Ross Sea warmed, while the western Ross Sea showed no trend and West Antarctica cooled. From the 17th century onwards, this dipole relationship changed. Now all three regions show concurrent warming, with snow accumulation declining in West Antarctica and the eastern Ross Sea.
Barbara Stenni, Mark A. J. Curran, Nerilie J. Abram, Anais Orsi, Sentia Goursaud, Valerie Masson-Delmotte, Raphael Neukom, Hugues Goosse, Dmitry Divine, Tas van Ommen, Eric J. Steig, Daniel A. Dixon, Elizabeth R. Thomas, Nancy A. N. Bertler, Elisabeth Isaksson, Alexey Ekaykin, Martin Werner, and Massimo Frezzotti
Clim. Past, 13, 1609–1634, https://doi.org/10.5194/cp-13-1609-2017, https://doi.org/10.5194/cp-13-1609-2017, 2017
Short summary
Short summary
Within PAGES Antarctica2k, we build an enlarged database of ice core water stable isotope records. We produce isotopic composites and temperature reconstructions since 0 CE for seven distinct Antarctic regions. We find a significant cooling trend from 0 to 1900 CE across all regions. Since 1900 CE, significant warming trends are identified for three regions. Only for the Antarctic Peninsula is this most recent century-scale trend unusual in the context of last-2000-year natural variability.
Tyler R. Jones, James W. C. White, Eric J. Steig, Bruce H. Vaughn, Valerie Morris, Vasileios Gkinis, Bradley R. Markle, and Spruce W. Schoenemann
Atmos. Meas. Tech., 10, 617–632, https://doi.org/10.5194/amt-10-617-2017, https://doi.org/10.5194/amt-10-617-2017, 2017
Short summary
Short summary
New measurement systems have been developed that continuously melt ice core samples, in contrast to other methods that analyze a single sample at a time. These newer systems are capable of reducing analysis time by many years and improving data set resolution. In this study, we introduce improved methodologies that optimize the speed, accuracy, and precision of a water isotope continuous-flow system. The presented system will be used for Antarctic and Greenland ice core projects.
C. Buizert, K. M. Cuffey, J. P. Severinghaus, D. Baggenstos, T. J. Fudge, E. J. Steig, B. R. Markle, M. Winstrup, R. H. Rhodes, E. J. Brook, T. A. Sowers, G. D. Clow, H. Cheng, R. L. Edwards, M. Sigl, J. R. McConnell, and K. C. Taylor
Clim. Past, 11, 153–173, https://doi.org/10.5194/cp-11-153-2015, https://doi.org/10.5194/cp-11-153-2015, 2015
L. Geng, J. Cole-Dai, B. Alexander, J. Erbland, J. Savarino, A. J. Schauer, E. J. Steig, P. Lin, Q. Fu, and M. C. Zatko
Atmos. Chem. Phys., 14, 13361–13376, https://doi.org/10.5194/acp-14-13361-2014, https://doi.org/10.5194/acp-14-13361-2014, 2014
Short summary
Short summary
Examinations on snowpit and firn core results from Summit, Greenland suggest that there are two mechanisms leading to the observed double nitrate peaks in some years in the industrial era: 1) long-rang transport of nitrate and 2) enhanced local photochemical production of nitrate. Both of these mechanisms are related to pollution transport, as the additional nitrate from either direct transport or enhanced local photochemistry requires enhanced nitrogen sources from anthropogenic emissions.
B. Medley, I. Joughin, B. E. Smith, S. B. Das, E. J. Steig, H. Conway, S. Gogineni, C. Lewis, A. S. Criscitiello, J. R. McConnell, M. R. van den Broeke, J. T. M. Lenaerts, D. H. Bromwich, J. P. Nicolas, and C. Leuschen
The Cryosphere, 8, 1375–1392, https://doi.org/10.5194/tc-8-1375-2014, https://doi.org/10.5194/tc-8-1375-2014, 2014
E. D. Sofen, B. Alexander, E. J. Steig, M. H. Thiemens, S. A. Kunasek, H. M. Amos, A. J. Schauer, M. G. Hastings, J. Bautista, T. L. Jackson, L. E. Vogel, J. R. McConnell, D. R. Pasteris, and E. S. Saltzman
Atmos. Chem. Phys., 14, 5749–5769, https://doi.org/10.5194/acp-14-5749-2014, https://doi.org/10.5194/acp-14-5749-2014, 2014
Rémi Dallmayr, Hannah Meyer, Vasileios Gkinis, Thomas Laepple, Melanie Behrens, Frank Wilhelms, and Maria Hörhold
The Cryosphere, 19, 1067–1083, https://doi.org/10.5194/tc-19-1067-2025, https://doi.org/10.5194/tc-19-1067-2025, 2025
Short summary
Short summary
Recent studies showed that a large number of independent vertical profiles allow for inferring a common local climate signal from the stacked stable water isotope record. Through investigating instrumental limitation and the effect of percolation of such porous samples, this study assesses the continuous flow analysis (CFA) technique in order to analyze the significant number of snow surface profiles within a reasonable time and with high quality.
Chloe A. Brashear, Tyler R. Jones, Valerie Morris, Bruce H. Vaughn, William H. G. Roberts, William B. Skorski, Abigail G. Hughes, Richard Nunn, Sune Olander Rasmussen, Kurt M. Cuffey, Bo M. Vinther, Todd Sowers, Christo Buizert, Vasileios Gkinis, Christian Holme, Mari F. Jensen, Sofia E. Kjellman, Petra M. Langebroek, Florian Mekhaldi, Kevin S. Rozmiarek, Jonathan W. Rheinlænder, Margit H. Simon, Giulia Sinnl, Silje Smith-Johnsen, and James W. C. White
Clim. Past, 21, 529–546, https://doi.org/10.5194/cp-21-529-2025, https://doi.org/10.5194/cp-21-529-2025, 2025
Short summary
Short summary
We use a series of spectral techniques to quantify the strength of high-frequency climate variability in northeastern Greenland to 50 000 ka before present. Importantly, we find that variability consistently decreases hundreds of years prior to Dansgaard–Oeschger warming events. Model simulations suggest a change in North Atlantic sea ice behavior contributed to this pattern, thus providing new information on the conditions which preceded abrupt climate change during the Last Glacial Period.
Fyntan Shaw, Thomas Münch, Vasileios Gkinis, and Thomas Laepple
EGUsphere, https://doi.org/10.5194/egusphere-2024-3650, https://doi.org/10.5194/egusphere-2024-3650, 2024
Short summary
Short summary
Diffusion in combination with measurement noise erase high-frequency water isotope variability in ice cores, linking measurement precision to recoverable resolution. We derive expressions for this relationship, finding a resolution improvement of 1.5 times for a 10-fold measurement noise reduction. Based on the current age-depth model, our method predicts 10,000-year cycles will be recoverable in the 1.5 Myr old ice from the Oldest Ice Core δ18O record if a noise level of 0.01 ‰ is achieved.
Mira Berdahl, Gunter R. Leguy, William H. Lipscomb, Bette L. Otto-Bliesner, Esther C. Brady, Robert A. Tomas, Nathan M. Urban, Ian Miller, Harriet Morgan, and Eric J. Steig
Clim. Past, 20, 2349–2371, https://doi.org/10.5194/cp-20-2349-2024, https://doi.org/10.5194/cp-20-2349-2024, 2024
Short summary
Short summary
Studying climate conditions near the Antarctic ice sheet (AIS) during Earth’s past warm periods informs us about how global warming may influence AIS ice loss. Using a global climate model, we investigate climate conditions near the AIS during the Last Interglacial (129 to 116 kyr ago), a period with warmer global temperatures and higher sea level than today. We identify the orbital and freshwater forcings that could cause ice loss and probe the mechanisms that lead to warmer climate conditions.
Margaret Harlan, Helle Astrid Kjær, Aylin de Campo, Anders Svensson, Thomas Blunier, Vasileios Gkinis, Sarah Jackson, Christopher Plummer, and Tessa Vance
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-335, https://doi.org/10.5194/essd-2024-335, 2024
Preprint under review for ESSD
Short summary
Short summary
This paper provides high-resolution chemistry and impurity measurements from the Mount Brown South ice core in East Antarctica, from 873 to 2009 CE. Measurements include sodium, ammonium, hydrogen peroxide, electrolytic conductivity, and insoluble microparticles. Data are provided on three scales: 1 mm and 3 cm averaged depth resolution and decadally averaged. The paper also describes the continuous flow analysis systems used to collect the data as well as uncertainties and data quality.
Fyntan Shaw, Andrew M. Dolman, Torben Kunz, Vasileios Gkinis, and Thomas Laepple
The Cryosphere, 18, 3685–3698, https://doi.org/10.5194/tc-18-3685-2024, https://doi.org/10.5194/tc-18-3685-2024, 2024
Short summary
Short summary
Fast variability of water isotopes in ice cores is attenuated by diffusion but can be restored if the diffusion length is accurately estimated. Current estimation methods are inadequate for deep ice, mischaracterising millennial-scale climate variability. We address this using variability estimates from shallower ice. The estimated diffusion length of 31 cm for the bottom of the Dome C ice core is 20 cm less than the old method, enabling signal recovery on timescales previously considered lost.
Tessa R. Vance, Nerilie J. Abram, Alison S. Criscitiello, Camilla K. Crockart, Aylin DeCampo, Vincent Favier, Vasileios Gkinis, Margaret Harlan, Sarah L. Jackson, Helle A. Kjær, Chelsea A. Long, Meredith K. Nation, Christopher T. Plummer, Delia Segato, Andrea Spolaor, and Paul T. Vallelonga
Clim. Past, 20, 969–990, https://doi.org/10.5194/cp-20-969-2024, https://doi.org/10.5194/cp-20-969-2024, 2024
Short summary
Short summary
This study presents the chronologies from the new Mount Brown South ice cores from East Antarctica, which were developed by counting annual layers in the ice core data and aligning these to volcanic sulfate signatures. The uncertainty in the dating is quantified, and we discuss initial results from seasonal cycle analysis and mean annual concentrations. The chronologies will underpin the development of new proxy records for East Antarctica spanning the past millennium.
Alexandra M. Zuhr, Sonja Wahl, Hans Christian Steen-Larsen, Maria Hörhold, Hanno Meyer, Vasileios Gkinis, and Thomas Laepple
Earth Syst. Sci. Data, 16, 1861–1874, https://doi.org/10.5194/essd-16-1861-2024, https://doi.org/10.5194/essd-16-1861-2024, 2024
Short summary
Short summary
We present stable water isotope data from the accumulation zone of the Greenland ice sheet. A spatial sampling scheme covering 39 m and three depth layers was carried out between 14 May and 3 August 2018. The data suggest spatial and temporal variability related to meteorological conditions, such as wind-driven snow redistribution and vapour–snow exchange processes. The data can be used to study the formation of the stable water isotopes signal, which is seen as a climate proxy.
Gemma K. O'Connor, Paul R. Holland, Eric J. Steig, Pierre Dutrieux, and Gregory J. Hakim
The Cryosphere, 17, 4399–4420, https://doi.org/10.5194/tc-17-4399-2023, https://doi.org/10.5194/tc-17-4399-2023, 2023
Short summary
Short summary
Glaciers in West Antarctica are rapidly melting, but the causes are unknown due to limited observations. A leading hypothesis is that an unusually large wind event in the 1940s initiated the ocean-driven melting. Using proxy reconstructions (e.g., using ice cores) and climate model simulations, we find that wind events similar to the 1940s event are relatively common on millennial timescales, implying that ocean variability or climate trends are also necessary to explain the start of ice loss.
Lindsey Davidge, Eric J. Steig, and Andrew J. Schauer
Atmos. Meas. Tech., 15, 7337–7351, https://doi.org/10.5194/amt-15-7337-2022, https://doi.org/10.5194/amt-15-7337-2022, 2022
Short summary
Short summary
We describe a continuous-flow analysis (CFA) method to measure Δ17O by laser spectroscopy, and we show that centimeter-scale information can be measured reliably in ice cores by this method. We present seasonally resolved Δ17O data from Greenland and demonstrate that the measurement precision is not reduced by the CFA process. Our results encourage the development and use of CFA methods for Δ17O, and they identify calibration strategies as a target for method improvement.
Paul R. Holland, Gemma K. O'Connor, Thomas J. Bracegirdle, Pierre Dutrieux, Kaitlin A. Naughten, Eric J. Steig, David P. Schneider, Adrian Jenkins, and James A. Smith
The Cryosphere, 16, 5085–5105, https://doi.org/10.5194/tc-16-5085-2022, https://doi.org/10.5194/tc-16-5085-2022, 2022
Short summary
Short summary
The Antarctic Ice Sheet is losing ice, causing sea-level rise. However, it is not known whether human-induced climate change has contributed to this ice loss. In this study, we use evidence from climate models and palaeoclimate measurements (e.g. ice cores) to suggest that the ice loss was triggered by natural climate variations but is now sustained by human-forced climate change. This implies that future greenhouse-gas emissions may influence sea-level rise from Antarctica.
Antoine Grisart, Mathieu Casado, Vasileios Gkinis, Bo Vinther, Philippe Naveau, Mathieu Vrac, Thomas Laepple, Bénédicte Minster, Frederic Prié, Barbara Stenni, Elise Fourré, Hans Christian Steen-Larsen, Jean Jouzel, Martin Werner, Katy Pol, Valérie Masson-Delmotte, Maria Hoerhold, Trevor Popp, and Amaelle Landais
Clim. Past, 18, 2289–2301, https://doi.org/10.5194/cp-18-2289-2022, https://doi.org/10.5194/cp-18-2289-2022, 2022
Short summary
Short summary
This paper presents a compilation of high-resolution (11 cm) water isotopic records, including published and new measurements, for the last 800 000 years from the EPICA Dome C ice core, Antarctica. Using this new combined water isotopes (δ18O and δD) dataset, we study the variability and possible influence of diffusion at the multi-decadal to multi-centennial scale. We observe a stronger variability at the onset of the interglacial interval corresponding to a warm period.
Bradley R. Markle and Eric J. Steig
Clim. Past, 18, 1321–1368, https://doi.org/10.5194/cp-18-1321-2022, https://doi.org/10.5194/cp-18-1321-2022, 2022
Short summary
Short summary
The geochemistry preserved in polar ice can provide detailed histories of Earth’s climate over millennia. Here we use the stable isotope ratios of ice from many Antarctic ice cores to reconstruct temperature variability of Antarctica and the midlatitude Southern Hemisphere over tens of thousands of years. We improve upon existing methods to estimate temperature from the geochemical measurements and investigate the patterns of climate change in the past.
Jenna A. Epifanio, Edward J. Brook, Christo Buizert, Jon S. Edwards, Todd A. Sowers, Emma C. Kahle, Jeffrey P. Severinghaus, Eric J. Steig, Dominic A. Winski, Erich C. Osterberg, Tyler J. Fudge, Murat Aydin, Ekaterina Hood, Michael Kalk, Karl J. Kreutz, David G. Ferris, and Joshua A. Kennedy
Clim. Past, 16, 2431–2444, https://doi.org/10.5194/cp-16-2431-2020, https://doi.org/10.5194/cp-16-2431-2020, 2020
Short summary
Short summary
A new ice core drilled at the South Pole provides a 54 000-year paleo-environmental record including the composition of the past atmosphere. This paper describes the gas chronology for the South Pole ice core, based on a high-resolution methane record. The new gas chronology, in combination with the existing ice age scale from Winski et al. (2019), allows a model-independent reconstruction of the delta age record.
Seyedhamidreza Mojtabavi, Frank Wilhelms, Eliza Cook, Siwan M. Davies, Giulia Sinnl, Mathias Skov Jensen, Dorthe Dahl-Jensen, Anders Svensson, Bo M. Vinther, Sepp Kipfstuhl, Gwydion Jones, Nanna B. Karlsson, Sergio Henrique Faria, Vasileios Gkinis, Helle Astrid Kjær, Tobias Erhardt, Sarah M. P. Berben, Kerim H. Nisancioglu, Iben Koldtoft, and Sune Olander Rasmussen
Clim. Past, 16, 2359–2380, https://doi.org/10.5194/cp-16-2359-2020, https://doi.org/10.5194/cp-16-2359-2020, 2020
Short summary
Short summary
We present a first chronology for the East Greenland Ice-core Project (EGRIP) over the Holocene and last glacial termination. After field measurements and processing of the ice-core data, the GICC05 timescale is transferred from the NGRIP core to the EGRIP core by means of matching volcanic events and common patterns (381 match points) in the ECM and DEP records. The new timescale is named GICC05-EGRIP-1 and extends back to around 15 kyr b2k.
Anders Svensson, Dorthe Dahl-Jensen, Jørgen Peder Steffensen, Thomas Blunier, Sune O. Rasmussen, Bo M. Vinther, Paul Vallelonga, Emilie Capron, Vasileios Gkinis, Eliza Cook, Helle Astrid Kjær, Raimund Muscheler, Sepp Kipfstuhl, Frank Wilhelms, Thomas F. Stocker, Hubertus Fischer, Florian Adolphi, Tobias Erhardt, Michael Sigl, Amaelle Landais, Frédéric Parrenin, Christo Buizert, Joseph R. McConnell, Mirko Severi, Robert Mulvaney, and Matthias Bigler
Clim. Past, 16, 1565–1580, https://doi.org/10.5194/cp-16-1565-2020, https://doi.org/10.5194/cp-16-1565-2020, 2020
Short summary
Short summary
We identify signatures of large bipolar volcanic eruptions in Greenland and Antarctic ice cores during the last glacial period, which allows for a precise temporal alignment of the ice cores. Thereby the exact timing of unexplained, abrupt climatic changes occurring during the last glacial period can be determined in a global context. The study thus provides a step towards a full understanding of elements of the climate system that may also play an important role in the future.
Abigail G. Hughes, Tyler R. Jones, Bo M. Vinther, Vasileios Gkinis, C. Max Stevens, Valerie Morris, Bruce H. Vaughn, Christian Holme, Bradley R. Markle, and James W. C. White
Clim. Past, 16, 1369–1386, https://doi.org/10.5194/cp-16-1369-2020, https://doi.org/10.5194/cp-16-1369-2020, 2020
Short summary
Short summary
An ice core drilled on the Renland ice cap (RECAP) in east-central Greenland contains a continuous climate record dating through the last glacial period. Here we present the water isotope record for the Holocene, in which high-resolution climate information is retained for the last 8 kyr. We find that the RECAP water isotope record exhibits seasonal and decadal variability which may reflect sea surface conditions and regional climate variability.
Jessica A. Badgeley, Eric J. Steig, Gregory J. Hakim, and Tyler J. Fudge
Clim. Past, 16, 1325–1346, https://doi.org/10.5194/cp-16-1325-2020, https://doi.org/10.5194/cp-16-1325-2020, 2020
Tyler J. Fudge, David A. Lilien, Michelle Koutnik, Howard Conway, C. Max Stevens, Edwin D. Waddington, Eric J. Steig, Andrew J. Schauer, and Nicholas Holschuh
Clim. Past, 16, 819–832, https://doi.org/10.5194/cp-16-819-2020, https://doi.org/10.5194/cp-16-819-2020, 2020
Short summary
Short summary
A 1750 m ice core at the South Pole was recently drilled. The oldest ice is ~55 000 years old. Since ice at the South Pole flows at 10 m per year, the ice in the core originated upstream, where the climate is different. We made measurements of the ice flow, snow accumulation, and temperature upstream. We determined the ice came from ~150 km away near the Titan Dome where the accumulation rate was similar but the temperature was colder. Our measurements improve the interpretation of the ice core.
Dominic A. Winski, Tyler J. Fudge, David G. Ferris, Erich C. Osterberg, John M. Fegyveresi, Jihong Cole-Dai, Zayta Thundercloud, Thomas S. Cox, Karl J. Kreutz, Nikolas Ortman, Christo Buizert, Jenna Epifanio, Edward J. Brook, Ross Beaudette, Jeffrey Severinghaus, Todd Sowers, Eric J. Steig, Emma C. Kahle, Tyler R. Jones, Valerie Morris, Murat Aydin, Melinda R. Nicewonger, Kimberly A. Casey, Richard B. Alley, Edwin D. Waddington, Nels A. Iverson, Nelia W. Dunbar, Ryan C. Bay, Joseph M. Souney, Michael Sigl, and Joseph R. McConnell
Clim. Past, 15, 1793–1808, https://doi.org/10.5194/cp-15-1793-2019, https://doi.org/10.5194/cp-15-1793-2019, 2019
Short summary
Short summary
A deep ice core was recently drilled at the South Pole to understand past variations in the Earth's climate. To understand the information contained within the ice, we present the relationship between the depth and age of the ice in the South Pole Ice Core. We found that the oldest ice in our record is from 54 302 ± 519 years ago. Our results show that, on average, 7.4 cm of snow falls at the South Pole each year.
Robert Tardif, Gregory J. Hakim, Walter A. Perkins, Kaleb A. Horlick, Michael P. Erb, Julien Emile-Geay, David M. Anderson, Eric J. Steig, and David Noone
Clim. Past, 15, 1251–1273, https://doi.org/10.5194/cp-15-1251-2019, https://doi.org/10.5194/cp-15-1251-2019, 2019
Short summary
Short summary
An updated Last Millennium Reanalysis is presented, using an expanded multi-proxy database, and proxy models representing the seasonal characteristics of proxy records, in addition to the dual sensitivity to temperature and moisture of tree-ring-width chronologies. We show enhanced skill in spatial reconstructions of key climate variables in the updated reanalysis, compared to an earlier version, resulting from the combined influences of the enhanced proxy network and improved proxy modeling.
Christian Holme, Vasileios Gkinis, Mika Lanzky, Valerie Morris, Martin Olesen, Abigail Thayer, Bruce H. Vaughn, and Bo M. Vinther
Clim. Past, 15, 893–912, https://doi.org/10.5194/cp-15-893-2019, https://doi.org/10.5194/cp-15-893-2019, 2019
Short summary
Short summary
This study investigates the linear relationship between the water isotopes of three East Greenland ice cores and regional temperatures. By comparing the water isotopes with nearby instrumental temperature records and reanalysis data, this study demonstrates that it can be problematic to reconstruct temperatures through regression of water isotope data from coastal ice cores. We further show that the varying linear relationship could be connected with changes in sea ice near the drill site.
Frazer D. W. Christie, Robert G. Bingham, Noel Gourmelen, Eric J. Steig, Rosie R. Bisset, Hamish D. Pritchard, Kate Snow, and Simon F. B. Tett
The Cryosphere, 12, 2461–2479, https://doi.org/10.5194/tc-12-2461-2018, https://doi.org/10.5194/tc-12-2461-2018, 2018
Short summary
Short summary
With a focus on the hitherto little-studied Marie Byrd Land coastline linking Antarctica's more comprehensively studied Amundsen and Ross Sea Embayments, this paper uses both satellite remote sensing (Landsat, ASTER, ICESat, and CryoSat2) and climate and ocean records (i.e. ERA-Interim, Met Office EN4 data) to examine links between ice recession, inter-decadal atmosphere-ocean forcing and other influences acting upon the Pacific-facing coastline of West Antarctica.
Nancy A. N. Bertler, Howard Conway, Dorthe Dahl-Jensen, Daniel B. Emanuelsson, Mai Winstrup, Paul T. Vallelonga, James E. Lee, Ed J. Brook, Jeffrey P. Severinghaus, Taylor J. Fudge, Elizabeth D. Keller, W. Troy Baisden, Richard C. A. Hindmarsh, Peter D. Neff, Thomas Blunier, Ross Edwards, Paul A. Mayewski, Sepp Kipfstuhl, Christo Buizert, Silvia Canessa, Ruzica Dadic, Helle A. Kjær, Andrei Kurbatov, Dongqi Zhang, Edwin D. Waddington, Giovanni Baccolo, Thomas Beers, Hannah J. Brightley, Lionel Carter, David Clemens-Sewall, Viorela G. Ciobanu, Barbara Delmonte, Lukas Eling, Aja Ellis, Shruthi Ganesh, Nicholas R. Golledge, Skylar Haines, Michael Handley, Robert L. Hawley, Chad M. Hogan, Katelyn M. Johnson, Elena Korotkikh, Daniel P. Lowry, Darcy Mandeno, Robert M. McKay, James A. Menking, Timothy R. Naish, Caroline Noerling, Agathe Ollive, Anaïs Orsi, Bernadette C. Proemse, Alexander R. Pyne, Rebecca L. Pyne, James Renwick, Reed P. Scherer, Stefanie Semper, Marius Simonsen, Sharon B. Sneed, Eric J. Steig, Andrea Tuohy, Abhijith Ulayottil Venugopal, Fernando Valero-Delgado, Janani Venkatesh, Feitang Wang, Shimeng Wang, Dominic A. Winski, V. Holly L. Winton, Arran Whiteford, Cunde Xiao, Jiao Yang, and Xin Zhang
Clim. Past, 14, 193–214, https://doi.org/10.5194/cp-14-193-2018, https://doi.org/10.5194/cp-14-193-2018, 2018
Short summary
Short summary
Temperature and snow accumulation records from the annually dated Roosevelt Island Climate Evolution (RICE) ice core show that for the past 2 700 years, the eastern Ross Sea warmed, while the western Ross Sea showed no trend and West Antarctica cooled. From the 17th century onwards, this dipole relationship changed. Now all three regions show concurrent warming, with snow accumulation declining in West Antarctica and the eastern Ross Sea.
Barbara Stenni, Mark A. J. Curran, Nerilie J. Abram, Anais Orsi, Sentia Goursaud, Valerie Masson-Delmotte, Raphael Neukom, Hugues Goosse, Dmitry Divine, Tas van Ommen, Eric J. Steig, Daniel A. Dixon, Elizabeth R. Thomas, Nancy A. N. Bertler, Elisabeth Isaksson, Alexey Ekaykin, Martin Werner, and Massimo Frezzotti
Clim. Past, 13, 1609–1634, https://doi.org/10.5194/cp-13-1609-2017, https://doi.org/10.5194/cp-13-1609-2017, 2017
Short summary
Short summary
Within PAGES Antarctica2k, we build an enlarged database of ice core water stable isotope records. We produce isotopic composites and temperature reconstructions since 0 CE for seven distinct Antarctic regions. We find a significant cooling trend from 0 to 1900 CE across all regions. Since 1900 CE, significant warming trends are identified for three regions. Only for the Antarctic Peninsula is this most recent century-scale trend unusual in the context of last-2000-year natural variability.
Tyler R. Jones, James W. C. White, Eric J. Steig, Bruce H. Vaughn, Valerie Morris, Vasileios Gkinis, Bradley R. Markle, and Spruce W. Schoenemann
Atmos. Meas. Tech., 10, 617–632, https://doi.org/10.5194/amt-10-617-2017, https://doi.org/10.5194/amt-10-617-2017, 2017
Short summary
Short summary
New measurement systems have been developed that continuously melt ice core samples, in contrast to other methods that analyze a single sample at a time. These newer systems are capable of reducing analysis time by many years and improving data set resolution. In this study, we introduce improved methodologies that optimize the speed, accuracy, and precision of a water isotope continuous-flow system. The presented system will be used for Antarctic and Greenland ice core projects.
Qianjie Chen, Lei Geng, Johan A. Schmidt, Zhouqing Xie, Hui Kang, Jordi Dachs, Jihong Cole-Dai, Andrew J. Schauer, Madeline G. Camp, and Becky Alexander
Atmos. Chem. Phys., 16, 11433–11450, https://doi.org/10.5194/acp-16-11433-2016, https://doi.org/10.5194/acp-16-11433-2016, 2016
Short summary
Short summary
The formation mechanisms of sulfate in the marine boundary layer are not well understood, which could result in large uncertainties in aerosol radiative forcing. We measure the oxygen isotopic composition (Δ17O) of sulfate collected in the MBL and analyze with a global transport model. Our results suggest that 33–50 % of MBL sulfate is formed via oxidation of S(IV) by hypohalous acids HOBr / HOCl in the aqueous phase, and the daily-mean HOBr/HOCl concentrations are on the order of 0.01–0.1 ppt.
C. W. Rella, J. Hoffnagle, Y. He, and S. Tajima
Atmos. Meas. Tech., 8, 4539–4559, https://doi.org/10.5194/amt-8-4539-2015, https://doi.org/10.5194/amt-8-4539-2015, 2015
Short summary
Short summary
We describe an innovative instrument based on cavity ring-down spectroscopy that analyzes the stable isotopes of methane in the ambient atmosphere. This instrument was used to study atmospheric emissions from oil and gas extraction activities in the Uintah Basin in Utah. These measurements suggest that 85 ± 7% of the total emissions in the basin are from natural gas production. The easy field deployment of this instrument can enable similar regional attribution studies across the world.
A. Svensson, S. Fujita, M. Bigler, M. Braun, R. Dallmayr, V. Gkinis, K. Goto-Azuma, M. Hirabayashi, K. Kawamura, S. Kipfstuhl, H. A. Kjær, T. Popp, M. Simonsen, J. P. Steffensen, P. Vallelonga, and B. M. Vinther
Clim. Past, 11, 1127–1137, https://doi.org/10.5194/cp-11-1127-2015, https://doi.org/10.5194/cp-11-1127-2015, 2015
B. D. Emanuelsson, W. T. Baisden, N. A. N. Bertler, E. D. Keller, and V. Gkinis
Atmos. Meas. Tech., 8, 2869–2883, https://doi.org/10.5194/amt-8-2869-2015, https://doi.org/10.5194/amt-8-2869-2015, 2015
Short summary
Short summary
Here we present an experimental setup for water stable isotopes continuous flow measurements. It is the first continuous flow laser spectroscopy system that is using off-axis integrated cavity output spectroscopy (analyzer manufactured by LGR) in combination with an evaporation unit to continuously analyze sample from an ice core. The isotopic water analyzer setup used during the 2013 RICE ice core processing campaign achieved measurements with high precision and high temporal resolution.
C. Buizert, K. M. Cuffey, J. P. Severinghaus, D. Baggenstos, T. J. Fudge, E. J. Steig, B. R. Markle, M. Winstrup, R. H. Rhodes, E. J. Brook, T. A. Sowers, G. D. Clow, H. Cheng, R. L. Edwards, M. Sigl, J. R. McConnell, and K. C. Taylor
Clim. Past, 11, 153–173, https://doi.org/10.5194/cp-11-153-2015, https://doi.org/10.5194/cp-11-153-2015, 2015
L. Geng, J. Cole-Dai, B. Alexander, J. Erbland, J. Savarino, A. J. Schauer, E. J. Steig, P. Lin, Q. Fu, and M. C. Zatko
Atmos. Chem. Phys., 14, 13361–13376, https://doi.org/10.5194/acp-14-13361-2014, https://doi.org/10.5194/acp-14-13361-2014, 2014
Short summary
Short summary
Examinations on snowpit and firn core results from Summit, Greenland suggest that there are two mechanisms leading to the observed double nitrate peaks in some years in the industrial era: 1) long-rang transport of nitrate and 2) enhanced local photochemical production of nitrate. Both of these mechanisms are related to pollution transport, as the additional nitrate from either direct transport or enhanced local photochemistry requires enhanced nitrogen sources from anthropogenic emissions.
B. Medley, I. Joughin, B. E. Smith, S. B. Das, E. J. Steig, H. Conway, S. Gogineni, C. Lewis, A. S. Criscitiello, J. R. McConnell, M. R. van den Broeke, J. T. M. Lenaerts, D. H. Bromwich, J. P. Nicolas, and C. Leuschen
The Cryosphere, 8, 1375–1392, https://doi.org/10.5194/tc-8-1375-2014, https://doi.org/10.5194/tc-8-1375-2014, 2014
E. D. Sofen, B. Alexander, E. J. Steig, M. H. Thiemens, S. A. Kunasek, H. M. Amos, A. J. Schauer, M. G. Hastings, J. Bautista, T. L. Jackson, L. E. Vogel, J. R. McConnell, D. R. Pasteris, and E. S. Saltzman
Atmos. Chem. Phys., 14, 5749–5769, https://doi.org/10.5194/acp-14-5749-2014, https://doi.org/10.5194/acp-14-5749-2014, 2014
Related subject area
Subject: Gases | Technique: Laboratory Measurement | Topic: Instruments and Platforms
Influence of ambient NO and NO2 on the quantification of total peroxy nitrates (ΣPNs) and total alkyl nitrates (ΣANs) by thermal dissociation cavity ring-down spectroscopy (TD-CRDS)
Identifying key parameters that affect sensitivity of flow tube chemical ionization mass spectrometers
Product ion distributions using H3O+ proton-transfer-reaction time-of-flight mass spectrometry (PTR-ToF-MS): mechanisms, transmission effects, and instrument-to-instrument variability
The Determination of ClNO2 via Thermal Dissociation-Tunable Infrared Laser Direct Absorption Spectroscopy
Simultaneous measurement of greenhouse gases (CH4, CO2 and N2O) using a simplified gas chromatography system
Measuring acetylene with a cavity ring-down spectroscopy gas analyser and its use as a tracer to quantify methane emissions
A new portable sampler of atmospheric methane for radiocarbon measurements
High-precision oxygen isotope (δ18O) measurements of atmospheric dioxygen using optical-feedback cavity-enhanced absorption spectroscopy (OF-CEAS)
Triple oxygen isotope composition of CO2 in the upper troposphere and stratosphere
Water vapor stable isotope memory effects of common tubing materials
Evaluation of a reduced-pressure chemical ion reactor utilizing adduct ionization for the detection of gaseous organic and inorganic species
Ammonium CI-Orbitrap: a tool for characterizing the reactivity of oxygenated organic molecules
A high-accuracy dynamic dilution method for generating reference gas mixtures of carbonyl sulfide at sub-nanomole-per-mole levels for long-term atmospheric observation
Optimizing the iodide-adduct chemical ionization mass spectrometry (CIMS) quantitative method for toluene oxidation intermediates: experimental insights into functional-group differences
Characterization of a new Teflon chamber and on-line analysis of isomeric multifunctional photooxidation products
A versatile water vapor generation module for vapor isotope calibration and liquid isotope measurements
Extraction, purification, and clumped isotope analysis of methane (Δ13CDH3 and Δ12CD2H2) from sources and the atmosphere
Response of protonated, adduct, and fragmented ions in Vocus proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS)
Absorption of volatile organic compounds (VOCs) by polymer tubing: implications for indoor air and use as a simple gas-phase volatility separation technique
A flexible device to produce a gas stream with a precisely controlled water vapour mixing ratio and isotope composition based on microdrop dispensing technology
Revision of an open-split-based dual-inlet system for elemental and isotope ratio mass spectrometers with a focus on clumped-isotope measurements
Characterisation of gaseous iodine species detection using the multi-scheme chemical ionisation inlet 2 with bromide and nitrate chemical ionisation methods
A novel inlet for enriching concentrations of reactive organic gases in low sampling flows
Characterizing the automatic radon flux transfer standard system Autoflux: laboratory calibration and field experiments
Influence of ozone and humidity on PTR-MS and GC-MS VOC measurements with and without a Na2S2O3 ozone scrubber
Laser-induced sublimation extraction for centimeter-resolution multi-species greenhouse gas analysis on ice cores
Ozone reactivity measurement of biogenic volatile organic compound emissions
Comparison of two photolytic calibration methods for nitrous acid
Measurement of enantiomer percentages for five monoterpenes from six conifer species by cartridge-tube-based passive sampling adsorption–thermal desorption (ps-ATD)
Identification, monitoring, and reaction kinetics of reactive trace species using time-resolved mid-infrared quantum cascade laser absorption spectroscopy: development, characterisation, and initial results for the CH2OO Criegee intermediate
Air pollution monitoring: development of ammonia (NH3) dynamic reference gas mixtures at nanomoles per mole levels to improve the lack of traceability of measurements
Formaldehyde and glyoxal measurement deploying a selected ion flow tube mass spectrometer (SIFT-MS)
Fragmentation inside proton-transfer-reaction-based mass spectrometers limits the detection of ROOR and ROOH peroxides
MULTICHARME: a modified Chernin-type multi-pass cell designed for IR and THz long-path absorption measurements in the CHARME atmospheric simulation chamber
Silicone tube humidity generator
A source for the continuous generation of pure and quantifiable HONO mixtures
Photochemical method for removing methane interference for improved gas analysis
A simulation chamber for absorption spectroscopy in planetary atmospheres
An automated system for trace gas flux measurements from plant foliage and other plant compartments
Simultaneous measurement of δ13C, δ18O and δ17O of atmospheric CO2 – performance assessment of a dual-laser absorption spectrometer
Measurement of iodine species and sulfuric acid using bromide chemical ionization mass spectrometers
A method for resolving changes in atmospheric He ∕ N2 as an indicator of fossil fuel extraction and stratospheric circulation
Application of chemical derivatization techniques combined with chemical ionization mass spectrometry to detect stabilized Criegee intermediates and peroxy radicals in the gas phase
Atomic emission detector with gas chromatographic separation and cryogenic pre-concentration (CryoTrap–GC–AED) for atmospheric trace gas measurements
New technique for high-precision, simultaneous measurements of CH4, N2O and CO2 concentrations; isotopic and elemental ratios of N2, O2 and Ar; and total air content in ice cores by wet extraction
High-precision laser spectrometer for multiple greenhouse gas analysis in 1 mL air from ice core samples
A thermal-dissociation–cavity ring-down spectrometer (TD-CRDS) for the detection of organic nitrates in gas and particle phases
Interference from alkenes in chemiluminescent NOx measurements
Calibration of an airborne HOx instrument using the All Pressure Altitude-based Calibrator for HOx Experimentation (APACHE)
Measurement of ammonia, amines and iodine compounds using protonated water cluster chemical ionization mass spectrometry
Laura Wüst, Patrick Dewald, Gunther N. T. E. Türk, Jos Lelieveld, and John N. Crowley
Atmos. Meas. Tech., 18, 1943–1959, https://doi.org/10.5194/amt-18-1943-2025, https://doi.org/10.5194/amt-18-1943-2025, 2025
Short summary
Short summary
Detection of NO2 via cavity ring-down spectroscopy (CRDS) after thermal dissociation (TD) of alkyl and peroxy nitrates can be used to detect total atmospheric organic nitrates originating from the interaction between biogenic emissions of volatile organic compounds and nitrogen oxides of anthropogenic origin. Here we present an improved TD-CRDS technique that avoids systematic bias resulting from secondary chemistry in the heated inlets and that can be deployed in regions with strong biogenic emissions.
Sneha Aggarwal, Priyanka Bansal, Yuwei Wang, Spiro Jorga, Gabrielle Macgregor, Urs Rohner, Thomas Bannan, Matthew Salter, Paul Zieger, Claudia Mohr, and Felipe Lopez-Hilfiker
EGUsphere, https://doi.org/10.5194/egusphere-2025-696, https://doi.org/10.5194/egusphere-2025-696, 2025
Short summary
Short summary
Chemical ionization mass spectrometers used for trace gas analysis can be operated at various conditions, complicating quantitative comparisons. We evaluate sensitivity dependence on relatively few key instrument parameters and show that when these are held constant, consistent performance is achieved. We show that the maximum sensitivity of a given flow tube reactor across various reagent ion chemistries is a constant, which aids in the quantification of compounds lacking analytical standards.
Michael F. Link, Megan S. Claflin, Christina E. Cecelski, Ayomide A. Akande, Delaney Kilgour, Paul A. Heine, Matthew Coggon, Chelsea E. Stockwell, Andrew Jensen, Jie Yu, Han N. Huynh, Jenna C. Ditto, Carsten Warneke, William Dresser, Keighan Gemmell, Spiro Jorga, Rileigh L. Robertson, Joost de Gouw, Timothy Bertram, Jonathan P. D. Abbatt, Nadine Borduas-Dedekind, and Dustin Poppendieck
Atmos. Meas. Tech., 18, 1013–1038, https://doi.org/10.5194/amt-18-1013-2025, https://doi.org/10.5194/amt-18-1013-2025, 2025
Short summary
Short summary
Proton-transfer-reaction mass spectrometry (PTR-MS) is widely used for the measurement of volatile organic compounds (VOCs) both indoors and outdoors. An analytical challenge for PTR-MS measurements is the formation of unintended measurement interferences, product ion distributions (PIDs), that may appear in the data as VOCs of interest. We developed a method for quantifying PID formation and use interlaboratory comparison data to put quantitative constraints on PID formation.
John W. Halfacre, Lewis Marden, Marvin D. Shaw, Lucy J. Carpenter, Emily Matthews, Thomas J. Bannan, Hugh Coe, Scott C. Herndon, Joseph R. Roscioli, Christoph Dyroff, Tara I. Yacovitch, Patrick R. Veres, Michael A. Robinson, Steven S. Brown, and Pete M. Edwards
EGUsphere, https://doi.org/10.5194/egusphere-2025-831, https://doi.org/10.5194/egusphere-2025-831, 2025
Short summary
Short summary
Nitryl chloride (ClNO2) is a reservoir of chlorine atoms and nitrogen oxides, both of which play important roles in atmospheric chemistry. However, all ambient ClNO2 observations so far have been made by a single technique, mass spectrometry, which needs complex calibrations. Here, we present a laser-based method that detects ClNO2 (TD-TILDAS) without the need for complicated calibrations. The results show excellent agreement between these two methods from both laboratory and ambient samples.
Michał Bucha, Dominika Lewicka-Szczebak, and Piotr Wójtowicz
Atmos. Meas. Tech., 18, 897–908, https://doi.org/10.5194/amt-18-897-2025, https://doi.org/10.5194/amt-18-897-2025, 2025
Short summary
Short summary
We present a method for the determination of greenhouse gases (CH4, CO2, N2O) using a chromatographic system with a barrier ion discharge detector (BID) and a Carboxen 1010 capillary column. The system omits the need for an electron capture detector (ECD) containing radiogenic components for N2O analysis and a flame ionisation detector (FID) with a methaniser for CO2 samples. This simplification reduces analytical costs, facilitates instrument maintenance and improves measurement robustness.
Adil Shah, Olivier Laurent, Pramod Kumar, Grégoire Broquet, Loïc Loigerot, Timothé Depelchin, Mathis Lozano, Camille Yver Kwok, Carole Philippon, Clément Romand, Elisa Allegrini, Matthieu Trombetti, and Philippe Ciais
EGUsphere, https://doi.org/10.5194/egusphere-2024-4089, https://doi.org/10.5194/egusphere-2024-4089, 2025
Short summary
Short summary
Acetylene mole fraction measurements from the Picarro G2203 were characterised. Abnormal sensor behaviour was observed in wet conditions. A dry linear calibration was derived, although this was invalid below 1.2 ppb due to unstable measurements. The instrument was used to measure acetylene as a methane tracer at a landfill site. Fluxes were derived from fourteen downwind transects using both raw and calibrated acetylene mole fraction, with raw measurements resulting in 8 % flux underestimation.
Giulia Zazzeri, Lukas Wacker, Negar Haghipour, Philip Gautschi, Thomas Laemmel, Sönke Szidat, and Heather Graven
Atmos. Meas. Tech., 18, 319–325, https://doi.org/10.5194/amt-18-319-2025, https://doi.org/10.5194/amt-18-319-2025, 2025
Short summary
Short summary
Radiocarbon (14C) is an optimal tracer of methane (CH4) emissions, as 14C measurements enable distinguishing between fossil methane and biogenic methane. However, these measurements are particularly challenging, mainly due to technical difficulties in the sampling procedure. We made the sample extraction much simpler and time efficient, providing a new technology that can be used by any research group, with the goal of expanding 14C measurements for an improved understanding of methane sources.
Clément Piel, Daniele Romanini, Morgane Farradèche, Justin Chaillot, Clémence Paul, Nicolas Bienville, Thomas Lauwers, Joana Sauze, Kévin Jaulin, Frédéric Prié, and Amaëlle Landais
Atmos. Meas. Tech., 17, 6647–6658, https://doi.org/10.5194/amt-17-6647-2024, https://doi.org/10.5194/amt-17-6647-2024, 2024
Short summary
Short summary
This paper introduces a new optical gas analyzer based on an optical-feedback cavity-enhanced absorption spectroscopy (OF-CEAS) technique enabling high-temporal-resolution and high-precision measurements of oxygen isotopes (δ18O) and dioxygen (O2) concentration of atmospheric O2 (respectively 0.06 ‰ and 0.002 % over 10 min integration). The results underscore the good agreement with isotope ratio mass spectrometry measurements and the ability of the instrument to monitor biological processes.
Getachew Agmuas Adnew, Gerbrand Koren, Neha Mehendale, Sergey Gromov, Maarten Krol, and Thomas Röckmann
EGUsphere, https://doi.org/10.5194/egusphere-2024-3231, https://doi.org/10.5194/egusphere-2024-3231, 2024
Short summary
Short summary
This study presents high-precision measurements of ∆′17O(CO2). Key findings include the extension of the N2O-∆′17O correlation to the upper troposphere and the identification of significant differences in the N2O-∆′17O slope in StratoClim samples. Additionally, the ∆′17O measurements are used to estimate global stratospheric production and surface removal of ∆′17O, providing an independent estimate of global vegetation CO2 exchange.
Alexandra L. Meyer and Lisa R. Welp
Atmos. Meas. Tech., 17, 6193–6212, https://doi.org/10.5194/amt-17-6193-2024, https://doi.org/10.5194/amt-17-6193-2024, 2024
Short summary
Short summary
Water molecules stick to air intake tubing wall surfaces, smoothing measurements of fast isotopic variability in the atmosphere. We tested this stickiness and saw small differences in isotopic signal speed between materials, tubing inner dimensions, and isotopic switch direction, although no consistent temperature effects. Researchers can confidently compare measurements across observation systems using different commonly used tubing materials and plan for optimal inlet designs of new systems.
Matthieu Riva, Veronika Pospisilova, Carla Frege, Sebastien Perrier, Priyanka Bansal, Spiro Jorga, Patrick Sturm, Joel A. Thornton, Urs Rohner, and Felipe Lopez-Hilfiker
Atmos. Meas. Tech., 17, 5887–5901, https://doi.org/10.5194/amt-17-5887-2024, https://doi.org/10.5194/amt-17-5887-2024, 2024
Short summary
Short summary
We present a newly designed reduced-pressure chemical ionization reactor for detection of gas-phase organic and inorganic species. The system operates through the combined use of vacuum ultraviolet ionization and photosensitizers to generate numerous adduct ionization schemes. As a result, it offers the ability to simultaneously measure a wide variety of organic and inorganic species in terms of compound volatility and functionality, while being largely independent of changes in sample humidity.
Dandan Li, Dongyu Wang, Lucia Caudillo, Wiebke Scholz, Mingyi Wang, Sophie Tomaz, Guillaume Marie, Mihnea Surdu, Elias Eccli, Xianda Gong, Loic Gonzalez-Carracedo, Manuel Granzin, Joschka Pfeifer, Birte Rörup, Benjamin Schulze, Pekka Rantala, Sébastien Perrier, Armin Hansel, Joachim Curtius, Jasper Kirkby, Neil M. Donahue, Christian George, Imad El-Haddad, and Matthieu Riva
Atmos. Meas. Tech., 17, 5413–5428, https://doi.org/10.5194/amt-17-5413-2024, https://doi.org/10.5194/amt-17-5413-2024, 2024
Short summary
Short summary
Due to the analytical challenges of measuring organic vapors, it remains challenging to identify and quantify organic molecules present in the atmosphere. Here, we explore the performance of the Orbitrap chemical ionization mass spectrometer (CI-Orbitrap) using ammonium ion chemistry. This study shows that ammonium-ion-based chemistry associated with the high mass resolution of the Orbitrap mass analyzer can measure almost all inclusive compounds.
Hideki Nara, Takuya Saito, Taku Umezawa, and Yasunori Tohjima
Atmos. Meas. Tech., 17, 5187–5200, https://doi.org/10.5194/amt-17-5187-2024, https://doi.org/10.5194/amt-17-5187-2024, 2024
Short summary
Short summary
We have developed a high-accuracy dynamic dilution system for generating reference gas mixtures containing carbonyl sulfide (COS). Although COS at ambient levels generally has poor storage stability, our approach involves the dilution of a gas mixture containing micromole-per-mole levels of COS, the stability of which was validated for more than 1 decade. The developed system has excellent dilution performance and will facilitate accurate instrumental calibration for atmospheric COS observation.
Mengdi Song, Shuyu He, Xin Li, Ying Liu, Shengrong Lou, Sihua Lu, Limin Zeng, and Yuanhang Zhang
Atmos. Meas. Tech., 17, 5113–5127, https://doi.org/10.5194/amt-17-5113-2024, https://doi.org/10.5194/amt-17-5113-2024, 2024
Short summary
Short summary
We introduce detailed and improved quantitation and semi-quantitation methods of iodide-adduct time-of-flight chemical ionization mass spectrometry (I-CIMS) to measure toluene oxidation intermediates. We assess the experimental sensitivity of various functional group species and their binding energy with iodide ions in I-CIMS. A novel classification approach was introduced to significantly enhance the accuracy of semi-quantitative methods (improving R2 values from 0.52 to beyond 0.88).
Finja Löher, Esther Borrás, Amalia Muñoz, and Anke Christine Nölscher
Atmos. Meas. Tech., 17, 4553–4579, https://doi.org/10.5194/amt-17-4553-2024, https://doi.org/10.5194/amt-17-4553-2024, 2024
Short summary
Short summary
We constructed and characterized a new indoor Teflon atmospheric simulation chamber. We evaluated wall losses, photolysis rates, and secondary reactions of multifunctional photooxidation products in the chamber. To measure these products on-line, we combined chromatographic and mass spectrometric analyses to obtain both isomeric information and a high temporal resolution. For method validation, we studied the formation yields of the main ring-retaining products of toluene.
Hans Christian Steen-Larsen and Daniele Zannoni
Atmos. Meas. Tech., 17, 4391–4409, https://doi.org/10.5194/amt-17-4391-2024, https://doi.org/10.5194/amt-17-4391-2024, 2024
Short summary
Short summary
The water vapor generation module is completely scalable, allowing autonomous calibrations to use N standards and providing integration times only restricted by sample availability. We document improved reproducibility in 17O-excess liquid measurements. This module makes spectroscopy measurements comparable to mass spectrometry. We document that the vapor generation module can be used to analyze instrument performance and for vapor isotope calibration during field campaign measurements.
Malavika Sivan, Thomas Röckmann, Carina van der Veen, and Maria Elena Popa
Atmos. Meas. Tech., 17, 2687–2705, https://doi.org/10.5194/amt-17-2687-2024, https://doi.org/10.5194/amt-17-2687-2024, 2024
Short summary
Short summary
We have set up a measurement system for methane-clumped isotopologues. We have built an extraction and purification system to extract pure methane for these measurements, for samples of various origins, including atmospheric air, for which we need to process about 1000 L of air for one measurement. We report here the technical setup for extraction and measurements, as well as the calibration, and we give an overview of the samples measured so far.
Fangbing Li, Dan Dan Huang, Linhui Tian, Bin Yuan, Wen Tan, Liang Zhu, Penglin Ye, Douglas Worsnop, Ka In Hoi, Kai Meng Mok, and Yong Jie Li
Atmos. Meas. Tech., 17, 2415–2427, https://doi.org/10.5194/amt-17-2415-2024, https://doi.org/10.5194/amt-17-2415-2024, 2024
Short summary
Short summary
The responses of protonated, adduct, and fragmented ions of 21 volatile organic compounds (VOCs) were investigated with varying instrument settings and relative humidity (RH) in a Vocus proton-transfer-reaction mass spectrometer (PTR-MS). The protonated ions of most VOCs studied show < 15 % variation in sensitivity, except for some long-chain aldehydes. The relationship between sensitivity and PTR rate constant is complicated by the influences from ion transmission and protonated ion fraction.
Melissa A. Morris, Demetrios Pagonis, Douglas A. Day, Joost A. de Gouw, Paul J. Ziemann, and Jose L. Jimenez
Atmos. Meas. Tech., 17, 1545–1559, https://doi.org/10.5194/amt-17-1545-2024, https://doi.org/10.5194/amt-17-1545-2024, 2024
Short summary
Short summary
Polymer absorption of volatile organic compounds (VOCs) is important to characterize for atmospheric sampling setups (as interactions cause sampling delays) and indoor air quality. Here we test different polymer materials and quantify their absorptive capacities through modeling. We found the main polymers in carpets to be highly absorptive, acting as large reservoirs for indoor pollution. We also demonstrated how polymer tubes can be used as a low-cost gas separation technique.
Harald Sodemann, Alena Dekhtyareva, Alvaro Fernandez, Andrew Seidl, and Jenny Maccali
Atmos. Meas. Tech., 16, 5181–5203, https://doi.org/10.5194/amt-16-5181-2023, https://doi.org/10.5194/amt-16-5181-2023, 2023
Short summary
Short summary
We describe a device that allows one to produce a continuous stream of water vapour with a specified level of humidity. As a main innovation, we can mix waters with different water isotope composition. Through a series of tests we show that the performance characteristics of the device are in line with specifications. We present two laboratory applications where the device proves useful, first in characterizing instruments, and second for the analysis of water contained in stalagmites.
Stephan Räss, Peter Nyfeler, Paul Wheeler, Will Price, and Markus Christian Leuenberger
Atmos. Meas. Tech., 16, 4489–4505, https://doi.org/10.5194/amt-16-4489-2023, https://doi.org/10.5194/amt-16-4489-2023, 2023
Short summary
Short summary
Due to technological advances clumped-isotope studies have gained importance in recent years. Typically, these studies are performed with high-resolution isotope ratio mass spectrometers (IRMSs) along with a changeover-valve-based dual-inlet system (DIS). We are taking a different approach, namely performing clumped-isotope measurements with a compact low-resolution IRMS with an open-split-based DIS. Currently, we are working with pure-oxygen gas for which we are providing a proof of concept.
Xu-Cheng He, Jiali Shen, Siddharth Iyer, Paxton Juuti, Jiangyi Zhang, Mrisha Koirala, Mikko M. Kytökari, Douglas R. Worsnop, Matti Rissanen, Markku Kulmala, Norbert M. Maier, Jyri Mikkilä, Mikko Sipilä, and Juha Kangasluoma
Atmos. Meas. Tech., 16, 4461–4487, https://doi.org/10.5194/amt-16-4461-2023, https://doi.org/10.5194/amt-16-4461-2023, 2023
Short summary
Short summary
In this study, the upgraded multi-scheme chemical ionisation inlet 2 is presented. Sulfuric acid, hypoiodous acid, iodine, sulfur dioxide, and hydroperoxyl radicals are calibrated, and the improved ion optics allow us to detect sulfuric acid and iodine-containing molecules at as low as a few parts per quadrillion by volume. Additionally, we confirm the reliable detection of iodic acid using both the nitrate and bromide chemical ionisation methods under atmospherically relevant conditions.
Namrata Shanmukh Panji and Gabriel Isaacman-VanWertz
Atmos. Meas. Tech., 16, 4319–4330, https://doi.org/10.5194/amt-16-4319-2023, https://doi.org/10.5194/amt-16-4319-2023, 2023
Short summary
Short summary
Measuring volatile organic compounds (VOCs) in the atmosphere is crucial for understanding air quality and environmental impact. Since these compounds are present in low concentrations, preconcentration of samples is often necessary for accurate detection. To address this issue, we have developed a novel inlet that uses selective permeation to concentrate organic gases in small sample flows. This device offers a promising approach for accurately detecting low levels of VOCs in the atmosphere.
Claudia Grossi, Daniel Rabago, Scott Chambers, Carlos Sáinz, Roger Curcoll, Peter P. S. Otáhal, Eliška Fialová, Luis Quindos, and Arturo Vargas
Atmos. Meas. Tech., 16, 2655–2672, https://doi.org/10.5194/amt-16-2655-2023, https://doi.org/10.5194/amt-16-2655-2023, 2023
Short summary
Short summary
The automatic and low-maintenance radon flux system Autoflux, completed with environmental soil and atmosphere sensors, has been theoretically and experimentally characterized and calibrated under laboratory conditions to be used as transfer standard for in situ measurements. It will offer for the first time long-term measurements to validate radon flux maps used by the climate and the radiation protection communities for assessing the radon gas emissions in the atmosphere.
Lisa Ernle, Monika Akima Ringsdorf, and Jonathan Williams
Atmos. Meas. Tech., 16, 1179–1194, https://doi.org/10.5194/amt-16-1179-2023, https://doi.org/10.5194/amt-16-1179-2023, 2023
Short summary
Short summary
Atmospheric ozone can induce artefacts in volatile organic compound measurements. Laboratory tests were made using GC-MS and PTR-MS aircraft systems under tropospheric and stratospheric conditions of humidity and ozone, with and without sodium thiosulfate filter scrubbers. Ozone in dry air produces some carbonyls and degrades alkenes. The scrubber lifetime depends on ozone concentration, flow rate and humidity. For the troposphere with scrubber, no significant artefacts were found over 14 d.
Lars Mächler, Daniel Baggenstos, Florian Krauss, Jochen Schmitt, Bernhard Bereiter, Remo Walther, Christoph Reinhard, Béla Tuzson, Lukas Emmenegger, and Hubertus Fischer
Atmos. Meas. Tech., 16, 355–372, https://doi.org/10.5194/amt-16-355-2023, https://doi.org/10.5194/amt-16-355-2023, 2023
Short summary
Short summary
We present a new method to extract the gases from ice cores and measure their greenhouse gas composition. The ice is sublimated continuously with a near-infrared laser, releasing the gases, which are then analyzed on a laser absorption spectrometer. The main advantage over previous efforts is a low effective resolution of 1–2 cm. This capability is crucial for the analysis of highly thinned ice, as expected from ongoing drilling efforts to extend ice core history further back in time.
Detlev Helmig, Alex Guenther, Jacques Hueber, Ryan Daly, Wei Wang, Jeong-Hoo Park, Anssi Liikanen, and Arnaud P. Praplan
Atmos. Meas. Tech., 15, 5439–5454, https://doi.org/10.5194/amt-15-5439-2022, https://doi.org/10.5194/amt-15-5439-2022, 2022
Short summary
Short summary
This research demonstrates a new method for determination of the chemical reactivity of volatile organic compounds that are emitted from the leaves and needles of trees. These measurements allow elucidating if and how much of these emissions and their associated reactivity are captured and quantified by currently applicable chemical analysis methods.
Andrew J. Lindsay and Ezra C. Wood
Atmos. Meas. Tech., 15, 5455–5464, https://doi.org/10.5194/amt-15-5455-2022, https://doi.org/10.5194/amt-15-5455-2022, 2022
Short summary
Short summary
Nitrous acid (HONO) is an important source of the main atmospheric oxidant – the hydroxyl radical (OH). Advances in nitrous acid measurement techniques and calibration methods therefore improve our understanding of atmospheric oxidation processes. In this paper, we present two calibration methods based on photo-dissociating water vapor. These calibration methods are useful alternatives to conventional calibrations that involve a reacting hydrogen chloride vapor with sodium nitrite.
Ying Wang, Wentai Luo, Todd N. Rosenstiel, and James F. Pankow
Atmos. Meas. Tech., 15, 4651–4661, https://doi.org/10.5194/amt-15-4651-2022, https://doi.org/10.5194/amt-15-4651-2022, 2022
Short summary
Short summary
A rapid, sensitive, and precise analytical method was developed for measuring the fractional amounts of the (−) and (+) forms of chiral enantiomeric forms of monoterpenes in air containing biogenic plant emissions. The method uses passive air sampling onto adsorption–thermal desorption (ATD) gas sampling cartridge tubes; this is followed by automatable thermal desorption onto a chiral gas chromatography (GC) column, followed by detection with mass spectrometry (MS).
Zara S. Mir, Matthew Jamieson, Nicholas R. Greenall, Paul W. Seakins, Mark A. Blitz, and Daniel Stone
Atmos. Meas. Tech., 15, 2875–2887, https://doi.org/10.5194/amt-15-2875-2022, https://doi.org/10.5194/amt-15-2875-2022, 2022
Short summary
Short summary
In this work we describe the development and characterisation of an experiment using laser flash photolysis coupled with time-resolved mid-infrared (mid-IR) quantum cascade laser (QCL) absorption spectroscopy, with initial results reported for measurements of the infrared spectrum, kinetics, and product yields for the reaction of the CH2OO Criegee intermediate with SO2. This work has significance for the identification and measurement of reactive trace species in complex systems.
Tatiana Macé, Maitane Iturrate-Garcia, Céline Pascale, Bernhard Niederhauser, Sophie Vaslin-Reimann, and Christophe Sutour
Atmos. Meas. Tech., 15, 2703–2718, https://doi.org/10.5194/amt-15-2703-2022, https://doi.org/10.5194/amt-15-2703-2022, 2022
Short summary
Short summary
LNE developed, with the company 2M PROCESS, a gas reference generator to dynamically generate NH3 reference gas mixtures in the air at very low fractions between 1 and 400 nmol/mol. The procedure defined by LNE for calibrating NH3 analyzers used for monitoring air quality guarantees relative expanded uncertainties lower than 2 % for this measurement range. The results of a comparison organized between METAS and LNE allowed the validation of LNE's reference generator and calibration procedure.
Antonia G. Zogka, Manolis N. Romanias, and Frederic Thevenet
Atmos. Meas. Tech., 15, 2001–2019, https://doi.org/10.5194/amt-15-2001-2022, https://doi.org/10.5194/amt-15-2001-2022, 2022
Short summary
Short summary
We emphasize the application of SIFT-MS to detect two important atmospheric pollutants, i.e., formaldehyde (FM) and glyoxal (GL). FM and GL are secondary products formed by volatile organic compound oxidation in indoor and outdoor environments and play a key role in air quality and climate. We show that SIFT-MS is able to monitor these species selectively and in real time, overcoming the limitations of other, classical analytical techniques used to monitor these species in the atmosphere.
Haiyan Li, Thomas Golin Almeida, Yuanyuan Luo, Jian Zhao, Brett B. Palm, Christopher D. Daub, Wei Huang, Claudia Mohr, Jordan E. Krechmer, Theo Kurtén, and Mikael Ehn
Atmos. Meas. Tech., 15, 1811–1827, https://doi.org/10.5194/amt-15-1811-2022, https://doi.org/10.5194/amt-15-1811-2022, 2022
Short summary
Short summary
This work evaluated the potential for PTR-based mass spectrometers to detect ROOR and ROOH peroxides both experimentally and through computations. Laboratory experiments using a Vocus PTR observed only noisy signals of potential dimers during α-pinene ozonolysis and a few small signals of dimeric compounds during cyclohexene ozonolysis. Quantum chemical calculations for model ROOR and ROOH systems showed that most of these peroxides should fragment partially following protonation.
Jean Decker, Éric Fertein, Jonas Bruckhuisen, Nicolas Houzel, Pierre Kulinski, Bo Fang, Weixiong Zhao, Francis Hindle, Guillaume Dhont, Robin Bocquet, Gaël Mouret, Cécile Coeur, and Arnaud Cuisset
Atmos. Meas. Tech., 15, 1201–1215, https://doi.org/10.5194/amt-15-1201-2022, https://doi.org/10.5194/amt-15-1201-2022, 2022
Short summary
Short summary
We present a multiple pass system developed for the CHamber for Atmospheric Reactivity and Metrology of the Environment. This multi-pass cell allows monitoring of atmospheric species at trace levels by high-resolution spectroscopy with long interaction path lengths in the IR and for the first time in the terahertz range. Interesting prospects are highlighted in this frequency domain, such as a high degree of selectivity or the possibility to monitor in real-time atmospheric processes.
Robert F. Berg, Nicola Chiodo, and Eric Georgin
Atmos. Meas. Tech., 15, 819–832, https://doi.org/10.5194/amt-15-819-2022, https://doi.org/10.5194/amt-15-819-2022, 2022
Short summary
Short summary
We made a humidity generator that adds water vapor to a flowing gas. Its range of humidity is useful for calibrating balloon-borne probes to the Earth's stratosphere. The generator’s novel feature is a saturator that comprises 5 m of silicone tubing immersed in water. The length was enough to ensure that the saturator’s output was independent of the dimensions and permeability of the tube. This simple, low-cost design provides an accuracy that is acceptable for many applications.
Guillermo Villena and Jörg Kleffmann
Atmos. Meas. Tech., 15, 627–637, https://doi.org/10.5194/amt-15-627-2022, https://doi.org/10.5194/amt-15-627-2022, 2022
Short summary
Short summary
A continuous source for the generation of pure HONO mixtures was developed and characterized, which is based on the Henry's law solubility of HONO in acidic aqueous solutions. The source shows a fast time response and an excellent long-term stability and can be easily adjusted to HONO mixing ratios in the range 0.05–500 ppb. A general equation based on Henry's law is developed, whereby the HONO concentration of the source can be absolutely calculated with an accuracy of better than 10 %.
Merve Polat, Jesper Baldtzer Liisberg, Morten Krogsbøll, Thomas Blunier, and Matthew S. Johnson
Atmos. Meas. Tech., 14, 8041–8067, https://doi.org/10.5194/amt-14-8041-2021, https://doi.org/10.5194/amt-14-8041-2021, 2021
Short summary
Short summary
We have designed a process for removing methane from a gas stream so that nitrous oxide can be measured without interference. These are both key long-lived greenhouse gases frequently studied in relation to ice cores, plants, water treatment and so on. However, many researchers are not aware of the problem of methane interference, and in addition there have not been good methods available for solving the problem. Here we present and evaluate such a method.
Marcel Snels, Stefania Stefani, Angelo Boccaccini, David Biondi, and Giuseppe Piccioni
Atmos. Meas. Tech., 14, 7187–7197, https://doi.org/10.5194/amt-14-7187-2021, https://doi.org/10.5194/amt-14-7187-2021, 2021
Short summary
Short summary
A novel simulation chamber, PASSxS (Planetary Atmosphere Simulation System for Spectroscopy), has been developed for absorption measurements with a Fourier transform spectrometer (FTS) and possibly a cavity ring-down (CRD) spectrometer, with a sample temperature ranging from 100 K up to 550 K, while the pressure of the gas can be varied up to 60 bar. These temperature and pressure ranges cover a significant part of the planetary atmospheres in the solar system and possibly extrasolar planets.
Lukas Kohl, Markku Koskinen, Tatu Polvinen, Salla Tenhovirta, Kaisa Rissanen, Marjo Patama, Alessandro Zanetti, and Mari Pihlatie
Atmos. Meas. Tech., 14, 4445–4460, https://doi.org/10.5194/amt-14-4445-2021, https://doi.org/10.5194/amt-14-4445-2021, 2021
Short summary
Short summary
We present ShoTGa-FluMS, a measurement system designed for continuous and automated measurements of trace gas and volatile organic compound (VOC) fluxes from plant shoots. ShoTGa-FluMS uses transparent shoot enclosures equipped with cooling elements, automatically replaces fixated CO2, and removes transpired water from the enclosure, thus solving multiple technical problems that have so far prevented automated plant shoot trace gas flux measurements.
Pharahilda M. Steur, Hubertus A. Scheeren, Dave D. Nelson, J. Barry McManus, and Harro A. J. Meijer
Atmos. Meas. Tech., 14, 4279–4304, https://doi.org/10.5194/amt-14-4279-2021, https://doi.org/10.5194/amt-14-4279-2021, 2021
Short summary
Short summary
For understanding the sources and sinks of atmospheric CO2, measurement of stable isotopes has proven to be highly valuable. We present a new method using laser absorption spectroscopy to simultaneously conduct measurements of three CO2 isotopes, directly on dry-air samples. This new method reduces sample preparation time significantly, compared to the conventional method in which measurements are conducted on pure CO2, and avoids measurement biases introduced by CO2 extraction.
Mingyi Wang, Xu-Cheng He, Henning Finkenzeller, Siddharth Iyer, Dexian Chen, Jiali Shen, Mario Simon, Victoria Hofbauer, Jasper Kirkby, Joachim Curtius, Norbert Maier, Theo Kurtén, Douglas R. Worsnop, Markku Kulmala, Matti Rissanen, Rainer Volkamer, Yee Jun Tham, Neil M. Donahue, and Mikko Sipilä
Atmos. Meas. Tech., 14, 4187–4202, https://doi.org/10.5194/amt-14-4187-2021, https://doi.org/10.5194/amt-14-4187-2021, 2021
Short summary
Short summary
Atmospheric iodine species are often short-lived with low abundance and have thus been challenging to measure. We show that the bromide chemical ionization mass spectrometry, compatible with both the atmospheric pressure and reduced pressure interfaces, can simultaneously detect various gas-phase iodine species. Combining calibration experiments and quantum chemical calculations, we quantify detection sensitivities to HOI, HIO3, I2, and H2SO4, giving detection limits down to < 106 molec. cm-3.
Benjamin Birner, William Paplawsky, Jeffrey Severinghaus, and Ralph F. Keeling
Atmos. Meas. Tech., 14, 2515–2527, https://doi.org/10.5194/amt-14-2515-2021, https://doi.org/10.5194/amt-14-2515-2021, 2021
Short summary
Short summary
The atmospheric helium-to-nitrogen ratio is a promising indicator for circulation changes in the upper atmosphere and fossil fuel burning by humans. We present a very precise analysis method to determine changes in the helium-to-nitrogen ratio of air samples. The method relies on stabilizing the gas flow to a mass spectrometer and continuous removal of reactive gases. These advances enable new insights and monitoring possibilities for anthropogenic and natural processes.
Alexander Zaytsev, Martin Breitenlechner, Anna Novelli, Hendrik Fuchs, Daniel A. Knopf, Jesse H. Kroll, and Frank N. Keutsch
Atmos. Meas. Tech., 14, 2501–2513, https://doi.org/10.5194/amt-14-2501-2021, https://doi.org/10.5194/amt-14-2501-2021, 2021
Short summary
Short summary
We have developed an online method for speciated measurements of organic peroxy radicals and stabilized Criegee intermediates using chemical derivatization combined with chemical ionization mass spectrometry. Chemical derivatization prevents secondary radical reactions and eliminates potential interferences. Comparison between our measurements and results from numeric modeling shows that the method can be used for the quantification of a wide range of atmospheric radicals and intermediates.
Einar Karu, Mengze Li, Lisa Ernle, Carl A. M. Brenninkmeijer, Jos Lelieveld, and Jonathan Williams
Atmos. Meas. Tech., 14, 1817–1831, https://doi.org/10.5194/amt-14-1817-2021, https://doi.org/10.5194/amt-14-1817-2021, 2021
Short summary
Short summary
A gas measurement device was developed to measure trace gases (ppt level) in the air based on an atomic emission detector. It combines a cryogenic pre-concentrator (CryoTrap), a gas chromatograph (GC), and a new high-resolution atomic emission detector (AED). The CryoTrap–GC–AED instrumental setup, limits of detection, and elemental performance are presented and discussed. Two measurement case studies are reported: one in a Finnish boreal forest and the other based on an aircraft campaign.
Ikumi Oyabu, Kenji Kawamura, Kyotaro Kitamura, Remi Dallmayr, Akihiro Kitamura, Chikako Sawada, Jeffrey P. Severinghaus, Ross Beaudette, Anaïs Orsi, Satoshi Sugawara, Shigeyuki Ishidoya, Dorthe Dahl-Jensen, Kumiko Goto-Azuma, Shuji Aoki, and Takakiyo Nakazawa
Atmos. Meas. Tech., 13, 6703–6731, https://doi.org/10.5194/amt-13-6703-2020, https://doi.org/10.5194/amt-13-6703-2020, 2020
Short summary
Short summary
Air in polar ice cores provides information on past atmosphere and climate. We present a new method for simultaneously measuring eight gases (CH4, N2O and CO2 concentrations; isotopic ratios of N2 and O2; elemental ratios between N2, O2 and Ar; and total air content) from single ice-core samples with high precision.
Bernhard Bereiter, Béla Tuzson, Philipp Scheidegger, André Kupferschmid, Herbert Looser, Lars Mächler, Daniel Baggenstos, Jochen Schmitt, Hubertus Fischer, and Lukas Emmenegger
Atmos. Meas. Tech., 13, 6391–6406, https://doi.org/10.5194/amt-13-6391-2020, https://doi.org/10.5194/amt-13-6391-2020, 2020
Short summary
Short summary
The record of past greenhouse gas composition from ice cores is crucial for our understanding of global climate change. Deciphering this archive requires highly accurate and spatially resolved analysis of the very small amount of gas that is trapped in the ice. This is achieved with a mid-IR laser absorption spectrometer that provides simultaneous, high-precision measurements of CH4, N2O, CO2, and δ13C(CO2) and which will be coupled to a quantitative sublimation extraction method.
Natalie I. Keehan, Bellamy Brownwood, Andrey Marsavin, Douglas A. Day, and Juliane L. Fry
Atmos. Meas. Tech., 13, 6255–6269, https://doi.org/10.5194/amt-13-6255-2020, https://doi.org/10.5194/amt-13-6255-2020, 2020
Short summary
Short summary
This paper describes a new instrument (a thermal-dissociation–cavity ring-down spectrometer, TD-CRDS) for the measurement of key atmospheric gaseous and particle-phase molecules containing the nitrate functional group. Several operational considerations affecting the measurements are described, as well as several characterization experiments comparing the TD-CRDS measurements to analogous measurements from other instruments. Examples are given using a TD-CRDS for ambient and laboratory studies.
Mohammed S. Alam, Leigh R. Crilley, James D. Lee, Louisa J. Kramer, Christian Pfrang, Mónica Vázquez-Moreno, Milagros Ródenas, Amalia Muñoz, and William J. Bloss
Atmos. Meas. Tech., 13, 5977–5991, https://doi.org/10.5194/amt-13-5977-2020, https://doi.org/10.5194/amt-13-5977-2020, 2020
Short summary
Short summary
We report on the interference arising in measurements of nitrogen oxides (NOx) from the presence of a range of alkenes in sampled air when using the most widespread air quality monitoring technique for chemiluminescence detection. Interferences of up to 11 % are reported, depending upon the alkene present and conditions used. Such interferences may be of substantial importance for the interpretation of ambient NOx data, particularly for high volatile organic compound and low NOx environments.
Daniel Marno, Cheryl Ernest, Korbinian Hens, Umar Javed, Thomas Klimach, Monica Martinez, Markus Rudolf, Jos Lelieveld, and Hartwig Harder
Atmos. Meas. Tech., 13, 2711–2731, https://doi.org/10.5194/amt-13-2711-2020, https://doi.org/10.5194/amt-13-2711-2020, 2020
Short summary
Short summary
In this study, a calibration device for OH and HO2 instruments is characterized at pressures of 275 to 1000 mbar, allowing instrument pressure sensitivity to be quantified to an accuracy of 22 % (1σ). Computational fluid dynamic simulations supporting the understanding of interactions between generated HOx and the instrument inlet led to enhanced determination of factors affecting instrument sensitivity.
Joschka Pfeifer, Mario Simon, Martin Heinritzi, Felix Piel, Lena Weitz, Dongyu Wang, Manuel Granzin, Tatjana Müller, Steffen Bräkling, Jasper Kirkby, Joachim Curtius, and Andreas Kürten
Atmos. Meas. Tech., 13, 2501–2522, https://doi.org/10.5194/amt-13-2501-2020, https://doi.org/10.5194/amt-13-2501-2020, 2020
Short summary
Short summary
Ammonia is an important atmospheric trace gas that affects secondary aerosol formation and, together with sulfuric acid, the formation of new particles. A measurement technique is presented that uses high-resolution mass spectrometry and protonated water clusters for the ultrasensitive detection of ammonia at single-digit parts per trillion by volume levels. The instrument is further capable of measuring amines and a suite of iodine compounds at sub-parts per trillion by volume levels.
Cited articles
Abe, O.: Isotope fractionation of molecular oxygen during adsorption/desorption by molecular sieve zeolite, Rapid Commun. Mass Spec., 22, 2510–2514, 2008.
Aemisegger, F., Sturm, P., Graf, P., Sodemann, H., Pfahl, S., Knohl, A., and Wernli, H.: Measuring variations of δ18O and δ2H in atmospheric water vapour using two commercial laser-based spectrometers: an instrument characterisation study, Atmos. Meas. Tech., 5, 1491–1511, https://doi.org/10.5194/amt-5-1491-2012, 2012.
Audi, G., Wapstra, A. H., and Thibault, C.: The 2003 atomic mass evaluation. II: Tables, graphs and references, Nucl. Phys. A, 729, 337–676, 2003.
Baker, L., Franchi, I. A., Maynard, J., Wright, I. P., and Pillinger, C. T.: A technique for the determination of \chem^{18O/^16O} and \chem^{17O/^16O} isotopic ratios in water from small liquid and solid samples, Anal. Chem., 74, 1665–1673, 2002.
Barkan, E. and Luz, B.: High precision measurements of \chem^{18O/^16O} and \chem^{17O/^16O} ratios in H2O, Rapid Commun. Mass Sp., 19, 3737–3742, 2005.
Barkan, E. and Luz, B.: Diffusivity fractionations of $H216O/H217O$ and $H216O/H218O$ in air and their implications for isotope hydrology, Rapid Commun. Mass Spec., 21, 2999–3005, 2007.
Begley, I. S. and Scrimgeour, C. M.: High-precision $\delta ^2$H and δ18O measurement for water and volatile organic compounds by continuous-flow pyrolysis isotope ratio mass spectrometry, Anal. Chem., 69, 1530–1535, 1997.
Berman, E. S. F., Levin, N., Landais, A., Li, S., and Thomas Owano, T.: Measurement of δ18O, δ17O, and 17O-excess in water by off-axis integrated cavity output spectroscopy and isotope ratio mass spectrometry, Anal. Chem., 85, 10392–10398, 2013.
Bigeleisen, J., Perlman, M. L., and Prosser, H. C.: Conversion Of hydrogenic materials to hydrogen for isotopic analysis, Anal. Chem., 24, 1356–1357, 1952.
Blossey, P. N., Kuang, Z., and Romps, D. M.: Isotopic composition of water in the tropical tropopause layer in cloud-resolving simulations of an idealized tropical circulation, J. Geophys. Res.-Atmos., 115, D24309, https://doi.org/10.1029/2010JD014554, 2010.
Brand, W. A., Geilmann, H., Crosson, E. R., and Rella, C. W.: Cavity ring-down spectroscopy versus high-temperature conversion isotope ratio mass spectrometry; a case study on $\delta ^2$H and δ18O of pure water samples and alcohol/water mixtures, Rapid Commun. Mass Spec., 23, 1879–1884, 2009.
Cohn, M. and Urey, H.: Oxygen exchange reactions of organic compounds and water, J. Am. Chem. Soc., 60, 679–687, 1938.
Coplen, T.: Normalization of oxygen and hydrogen isotope data, Chem. Geol., 72, 293–297, 1988.
Craig, H. H.: Isotopic standards for carbon and oxygen and correction factors for mass-spectrometric analysis of carbon dioxide, Geochim. Cosmochim. Acta, 12, 133–149, 1957.
Crosson, E. R.: A cavity ring-down analyzer for measuring atmospheric levels of methane, carbon dioxide, and water vapor, Appl. Phys. B, 92, 403–408, 2008.
Crosson, E., Fidric, B., Paldus, B., and Tan, S.: Wavelength control for cavity ringdown spectrometer, Patent US7106763 B2, Picarro, Inc., 2006.
Dansgaard, W.: Stable isotopes in precipitation, Tellus, 16, 436–468, 1964.
Dansgaard, W., Clausen, H., Gundestrup, N., Hammer, C., Johnsen, S., Kristinsdottir, P., and Reeh, N.: A new Greenland deep ice core, Science, 218, 1273–1277, 1982.
Epstein, S. and Mayeda, T.: Variations of 18O content of waters from natural sources, Geochim. Cosmochim. Acta, 4, 213–224, 1953.
Galatry, L.: Simultaneous effect of Doppler and foreign gas broadening on spectral lines, Phys. Rev., 122, 1218–1223, 1961.
Gehre, M., Hoefling, R., Kowski, P., and Strauch, G.: Sample preparation device for quantitative hydrogen isotope analysis using chromium metal, Anal. Chem., 68, 4414–4417, 1996.
Gehre, M., Geilmann, H., Richter, J., Werner, R. A., and Brand, W. A.: Continuous flow 2H/1H and 18O/16O analysis of water samples with dual inlet precision, Rapid Commun. Mass Spec., 18, 2650–2660, 2004.
Gianfrani, L., Gagliardi, G., van Burgel, M., and Kerstel, E. R. T.: Isotope analysis of water by means of near-infrared dual-wavelength diode laser spectroscopy, Opt. Express, 11, 1566–1576, 2003.
Gkinis, V., Popp, T. J., Johnsen, S. J., and Blunier, T.: A continuous stream flash evaporator for the calibration of an IR cavity ring-down spectrometer for the isotopic analysis of water, Isotop. Environ. Health Stud., 46, 463–475, 2010.
Gkinis, V., Popp, T. J., Blunier, T., Bigler, M., Schüpbach, S., Kettner, E., and Johnsen, S. J.: Water isotopic ratios from a continuously melted ice core sample, Atmos. Meas. Tech., 4, 2531–2542, https://doi.org/10.5194/amt-4-2531-2011, 2011.
Gonfiantini, R.: Standards for stable isotope measurements in natural compounds, Nature, 271, 534–536, 1978.
Gonfiantini, R., Stichler, W., and Rozanski, K.: Standards and Intercomparison Materials Distributed by the International Atomic Energy Agency for Stable Isotope Measurements, Vol. 825 of IAEA-TECDOC, 13–29, International Atomic Energy Agency, Vienna, 1995.
Gupta, P., Noone, D., Galewsky, J., Sweeney, C., and Vaughn, B. H.: Demonstration of high-precision continuous measurements of water vapor isotopologues in laboratory and remote field deployments using wavelength-scanned cavity ring-down spectroscopy (WS-CRDS) technology, Rapid Commun. Mass Spec., 23, 2534–2542, 2009.
Hsiao, G. Hoffnagle, J. Gkinis, V., Steig, E. J., Vaughn, B., Schoenemann, S. and Schauer, A: \chem^{17O_excess} measurements of water without fluorination using optical spectroscopy, Geophysical Research Abstracts, 14, EGU2012-6565, 2012.
Hodges, J. T. and Lisak, D.: Frequency-stabilized cavity ring-down spectrometer for high-sensitivity measurements of water vapor concentration, Appl. Phys. B., 85, 375–382, 2007.
Johnsen, S. J., Dansgaard, W., and White, J. W. C.: The origin of Arctic precipitation under present and glacial conditions, Tellus B, 41, 452–468, 1989.
Johnsen, S. J., Clausen, H. B., Dansgaard, W., Gundestrup, N. S., Hammer, C. U., and Tauber, H.: The Eem stable-isotope record along the GRIP ice core and its interpretation, Quaternary Res., 43, 117–124, 1995.
Jouzel, J., Masson-Delmotte, V., Cattani, O., Dreyfus, G., Falourd, S., Hoffmann, G., Minster, B., Nouet, J., Barnola, J. M., Chappellaz, J., Fischer, H., Gallet, J. C., Johnsen, S., Leuenberger, M., Loulergue, L., Luethi, D., Oerter, H., Parrenin, F., Raisbeck, G., Raynaud, D., Schilt, A., Schwander, J., Selmo, E., Souchez, R., Spahni, R., Stauffer, B., Steffensen, J. P., Stenni, B., Stocker, T. F., Tison, J. L., Werner, M., and Wolff, E. W.: Orbital and millennial Antarctic climate variability over the past 800 000 years, Science, 317, 793–796, 2007.
Kaiser, J.: Reformulated 17O correction of mass spectrometric stable isotope measurements in carbon dioxide and a critical appraisal of historic "absolute" carbon and oxygen isotope ratios, Geochim. Cosmochim. Acta, 72, 1312–1334, 2008.
Kerstel, E. R. T.: Isotope ratio infrared spectrometry, Vol. 1 of Handbook of Stable Isotope Analytical Techniques, 759–787, Elsevier B. V., Amsterdam, 2004.
Kerstel, E. R. T., van Trigt, R., Dam, N., Reuss, J., and Meijer, H. A. J.: Simultaneous determination of the 2H/$^1$H, 17O/16O and 18O/16O isotope abundance ratios in water by means of laser spectrometry, Anal. Chem., 71, 5297–5303, 1999.
Kerstel, E. R. T., Gagliardi, G., Gianfrani, L., Meijer, H. A. J., van Trigt, R., and Ramaker, R.: Determination of the 2H/$^1$H, 17O/16O, and 18O/16O isotope ratios in water by means of tunable diode laser spectroscopy at 1.39 μm, Spectrochim. Ac. A, 58, 2389–2396, 2002.
Kerstel, E. R. T., Iannone, R. Q., Chenevier, M., Kassi, S., Jost, H. J., and Romanini, D.: A water isotope (2H, 17O, 18O) spectrometer based on optical feedback cavity-enhanced absorption for in situ airborne applications, Appl. Phys. B, 85, 397–406, 2006.
Kurita, N., Newman, B. D., Araguas-Araguas, L. J., and Aggarwal, P.: Evaluation of continuous water vapor δD and δ18O measurements by off-axis integrated cavity output spectroscopy, Atmos. Meas. Tech., 5, 2069–2080, https://doi.org/10.5194/amt-5-2069-2012, 2012.
Kusakabe, M. and Matsuhisa, Y.: Oxygen three-isotope ratios of silicate reference materials determined by direct comparison with VSMOW-oxygen, Geochem. J., 42, 309–317, 2008.
Landais, A., Barkan, E., and Luz, B.: Record of delta O-18 and O-17-excess in ice from Vostok Antarctica during the last 150 000 years, Geophys. Res. Lett., 35, L02709, https://doi.org/10.1029/2007GL032096 2008.
Lin, Y., Clayton, R. N., and Groening, M.: Calibration of δ17O and δ18O of international measurement standards – VSMOW, VSMOW2, SLAP, and SLAP2, Rapid Comm. Mass Spec., 24, 773–776, 2010.
Luz, B. and Barkan, E.: Variations of 17O/16O and 18O/16O in meteoric waters, Geochim. Cosmochim. Acta, 74, 6276–6286, 2010.
Masson-Delmotte, V., Jouzel, J., Landais, A., Stievenard, M., Johnsen, S. J., White, J. W. C., Werner, M., Sveinbjornsdottir, A., and Fuhrer, K.: GRIP deuterium excess reveals rapid and orbital-scale changes in Greenland moisture origin, Science, 309, 118–121, 2005.
Matsuhisa, Y., Goldsmith, J. R., and Clayton, R. N.: Mechanisms of hydrothermal crystallization of quartz at 250 °C and 15 kbar, Geochim. Cosmochim. Acta, 42, 173–182, 1978.
McKinney, C. R., McCreal, J. M., Epstein, S., Allen, H. A., and Urey, H. C.: Improvements in mass spectrometers for the measurement of small differences in isotope abundance ratios, Rev. Sci. Instrum., 21, 724–730, 1950.
Meijer, H. A. J. and Li, W. J.: The use of electrolysis for accurate δ17O and δ18O isotope measurements in water, Isotop. Environ. Health Stud., 34, 349–369, 1998.
Merlivat, L. and Jouzel, J.: Global Climatic Interpretation of the Deuterium-Oxygen 18 Relationship for Precipitation, J. Geophys. Res., 84, 5029–5033, 1979.
Miller, M. F.: Isotopic fractionation and the quantification of 17O anomalies in the oxygen three-isotope system: an appraisal and geochemical significance, Geochim. Cosmochim. Acta, 66, 1881–1889, 2002.
Mook, W.: Environmental Isotopes in the Hydrological Cycle: Principles and Applications, Vol. I, IAEA, Unesco and IAEA, 2000.
Morville, J., Kassi, S., Chenevier, M., and Romanini, D.: Fast, low-noise, mode-by-mode, cavity-enhanced absorption spectroscopy by diode-laser self-locking, Appl. Phys. B, 80, 1027–1038., 2005.
Noone, D., Galewsky, J., Sharp, Z. D., Worden, J., Barnes, J., Baer, D., Bailey, A., Brown, D. P., Christensen, L., Crosson, E., Dong, F., Hurley, J. V., Johnson, L. R., Strong, M., Toohey, D., Van Pelt, A., and Wright, J. S.: Properties of air mass mixing and humidity in the subtropics from measurements of the D/H isotope ratio of water vapor at the Mauna Loa Observatory, J. Geophys. Res., 116, D22113, https://doi.org/10.1029/2011JD015773, 2011.
Petit, J. R., White, J. W. C., Young, N. W., Jouzel, J., and Korotkevich, Y. S.: Deuterium excess in recent Antarctic snow, J. Geophys. Res., 96, 5113–5122, 1991.
Risi, C., Landais, A., Bony, S., Jouzel, J., Masson-Delmotte, V., and Vimeux, F.: Understanding the 17O excess glacial-interglacial variations in Vostok precipitation, J. Geophys. Res., 115, D10112, https://doi.org/10.1029/2008JD011535, 2010.
Rothman, L. S., Rinsland, C. P., Goldman, A., Massie, S. T., Edwards, D. P., Flaud, J.-M., Perrin, A., Camy-Peyret, C., Dana, V., Mandin, J.-Y., Schroeder, J., McCann, A., Gamache, R. R., Wattson, R. B., Yoshino, K., Chance, K. V., Jucks, K. W., Brown, L. R., Nemtchinov, V., and Varanasi, P.: The HITRAN spectroscopic database and HAWKS (HITRAN Atmospheric Workstation): 1996 edition, J. Quant. Spectrosc. Ra., 60, 665–710, 1996.
Sayres, D. S., Moyer, E. J., Hanisco, T. F., St Clair, J. M., Keutsch, F. N., O'Brien, A., Allen, N. T., Lapson, L., Demusz, J. N., Rivero, M., Martin, T., Greenberg, M., Tuozzolo, C., Engel, G. S., Kroll, J. H., Paul, J. B., and Anderson, J. G.: A new cavity based absorption instrument for detection of water isotopologues in the upper troposphere and lower stratosphere, Rev. Sci. Instrum., 80, 044102, https://doi.org/10.1063/1.3117349, 2009.
Schmidt, M., Maseyk, K., Lett, C., Biron, P., Richard, P., Bariac, T., and Seibt, U.: Concentration effects on laser-based δ18O and δ2H measurements and implications for the calibration of vapour measurements with liquid standards, Rapid Comm. Mass Spec., 24, 3553–3561, 2010.
Schoenemann, S. W., Schauer, A. J., and Steig, E. J.: Measurement of SLAP and GISP δ17O and proposed VSMOW-SLAP normalization for 17O_excess, Rapid Commun. Mass Spec., 27, 582–590, 2013.
Schoenemann, S. W., Steig, E. J., Ding, Q., Markle, B. R., and Schauer, A. J.: Triple water-isotopologue record from WAIS Divide Antarctica: controls on glacial-interglacial changes in \chem^{17O_excess} of precipitation, J. Geophys. Res., 119, https://doi.org/10.1002/2014JD021770, in press, 2014.
Steig, E.J., Gkinis, V, Schauer A.J., Hoffnagle, J., Tan, S., and Schoenemann, S.: Cavity ring-down spectroscopy for the high-precision analysis of the triple oxygen isotope composition of water and water vapor, Mineral. Magazine, 77, 2257, 2013.
Tan, S. M.: Wavelength measurement method based on combination of two signals in quadrature, Patent US7420686 B2, Picarro, Inc., 2008.
Urey, H. C.: The thermodynamic poperties of isotopic substances, J. Chem. Soc., 562–581, 1947.
Van Trigt, R., Meijer, H. A. J., Sveinbjornsdottir, A. E., Johnson, S. J., and Kerstel, E. R. T.: Measuring stable isotopes of hydrogen and oxygen in ice by means of laser spectrometry: the Bølling transition in the Dye-3 (south Greenland) ice core, Ann. Glaciol., 35, 125–130, 2002.
Varghese, P. L. and Hanson, R. K.: Collisional narrowing effects on spectral lines shapes measured at high resolution, Appl. Opt., 23, 2376–2385, 1984.
Vaughn, B. H., White, J. W. C., Delmotte, M., Trolier, M., Cattani, O., and Stievenard, M.: An automated system for hydrogen isotope analysis of water, Chem. Geol., 152, 309–319, 1998.
Vimeux, F., Masson, V., Jouzel, J., Petit, J. R., Steig, E. J., Stievenard, M., Vaikmae, R., and White J. W. C.: Holocene hydrological cycle changes in the Southern Hemisphere documented in East Antarctic deuterium excess records, Clim. Dynam., 17, 503–513, 2001.
Wassenaar, L. I., Ahmad, M., Aggarwal, P., van Duren, M., Poltenstein, L., Araguas, L., and Kurttas, T.: Worldwide proficiency test for routine analysis of δ2H and δ18O in water by isotope-ratio mass spectrometry and laser absorption spectroscopy, Rapid Commun. Mass Spec., 26, 1641–1648, 2012.
Werle, P.: Accuracy and precision of laser spectrometers for trace gas sensing in the presence of optical fringes and atmospheric turbulence, Appl. Phys. B, 102, 313–329, 2011.
Wu, T., Chen, W. D., Kerstel, E., Fertein, E., Gao, X. M., Koeth, J., Rossner, K., and Bruckner, D.: Kalman filtering real-time measurements of H2O isotopologue ratios by laser absorption spectroscopy at 2.73 \mum, Opt. Lett., 35, 634–636, 2010.
York, D.: Least squares fitting of a straight line with correlated errors, Earth Planet. Sci. Lett., 5, 320–324, 1969.
Young, E. D., Galy, A., and Nagahara, H.: Kinetic and equilibrium mass-dependent isotope fractionation laws in nature and their geochemical and cosmochemical significance, Geochim. Cosmochim. Acta, 66, 1095–1104, 2002.
