Articles | Volume 9, issue 6
https://doi.org/10.5194/amt-9-2735-2016
https://doi.org/10.5194/amt-9-2735-2016
Research article
 | 
01 Jul 2016
Research article |  | 01 Jul 2016

A high-resolution time-of-flight chemical ionization mass spectrometer utilizing hydronium ions (H3O+ ToF-CIMS) for measurements of volatile organic compounds in the atmosphere

Bin Yuan, Abigail Koss, Carsten Warneke, Jessica B. Gilman, Brian M. Lerner, Harald Stark, and Joost A. de Gouw

Related authors

Vertical changes in volatile organic compounds (VOCs) and impacts on photochemical ozone formation
Xiao-Bing Li, Bin Yuan, Yibo Huangfu, Suxia Yang, Xin Song, Jipeng Qi, Xianjun He, Sihang Wang, Yubin Chen, Qing Yang, Yongxin Song, Yuwen Peng, Guiqian Tang, Jian Gao, and Min Shao
EGUsphere, https://doi.org/10.5194/egusphere-2024-2755,https://doi.org/10.5194/egusphere-2024-2755, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Formation of Highly Absorptive Secondary Brown Carbon Through Nighttime Multiphase Chemistry of Biomass Burning Emissions
Ye Kuang, Biao Luo, Shan Huang, Junwen Liu, Weiwei Hu, Yuweng Peng, Duohong Chen, Dingli Yue, Wanyun Xu, Bin Yuan, and Min Shao
EGUsphere, https://doi.org/10.5194/egusphere-2024-2654,https://doi.org/10.5194/egusphere-2024-2654, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Measurement report: Vertical and temporal variability in the near-surface ozone production rate and sensitivity in an urban area in the Pearl River Delta region, China
Jun Zhou, Chunsheng Zhang, Aiming Liu, Bin Yuan, Yan Wang, Wenjie Wang, Jie-Ping Zhou, Yixin Hao, Xiao-Bing Li, Xianjun He, Xin Song, Yubin Chen, Suxia Yang, Shuchun Yang, Yanfeng Wu, Bin Jiang, Shan Huang, Junwen Liu, Yuwen Peng, Jipeng Qi, Minhui Deng, Bowen Zhong, Yibo Huangfu, and Min Shao
Atmos. Chem. Phys., 24, 9805–9826, https://doi.org/10.5194/acp-24-9805-2024,https://doi.org/10.5194/acp-24-9805-2024, 2024
Short summary
Estimation of biogenic volatile organic compound (BVOC) emissions in forest ecosystems using drone-based lidar, photogrammetry, and image recognition technologies
Xianzhong Duan, Ming Chang, Guotong Wu, Suping Situ, Shengjie Zhu, Qi Zhang, Yibo Huangfu, Weiwen Wang, Weihua Chen, Bin Yuan, and Xuemei Wang
Atmos. Meas. Tech., 17, 4065–4079, https://doi.org/10.5194/amt-17-4065-2024,https://doi.org/10.5194/amt-17-4065-2024, 2024
Short summary
Emission characteristics of reactive organic gases (ROGs) from industrial volatile chemical products (VCPs) in the Pearl River Delta (PRD), China
Sihang Wang, Bin Yuan, Xianjun He, Ru Cui, Xin Song, Yubin Chen, Caihong Wu, Chaomin Wang, Yibo Huangfu, Xiao-Bing Li, Boguang Wang, and Min Shao
Atmos. Chem. Phys., 24, 7101–7121, https://doi.org/10.5194/acp-24-7101-2024,https://doi.org/10.5194/acp-24-7101-2024, 2024
Short summary

Related subject area

Subject: Gases | Technique: In Situ Measurement | Topic: Instruments and Platforms
Eddy covariance with slow-response greenhouse gas analysers on tall towers: bridging atmospheric and ecosystem greenhouse gas networks
Pedro Henrique Herig Coimbra, Benjamin Loubet, Olivier Laurent, Laura Bignotti, Mathis Lozano, and Michel Ramonet
Atmos. Meas. Tech., 17, 6625–6645, https://doi.org/10.5194/amt-17-6625-2024,https://doi.org/10.5194/amt-17-6625-2024, 2024
Short summary
An overview of outdoor low-cost gas-phase air quality sensor deployments: current efforts, trends, and limitations
Kristen Okorn and Laura T. Iraci
Atmos. Meas. Tech., 17, 6425–6457, https://doi.org/10.5194/amt-17-6425-2024,https://doi.org/10.5194/amt-17-6425-2024, 2024
Short summary
Multiphysical description of atmospheric pressure interface chemical ionisation in MION2 and Eisele type inlets
Henning Finkenzeller, Jyri Mikkilä, Cecilia Righi, Paxton Juuti, Mikko Sipilä, Matti Rissanen, Douglas Worsnop, Aleksei Shcherbinin, Nina Sarnela, and Juha Kangasluoma
Atmos. Meas. Tech., 17, 5989–6001, https://doi.org/10.5194/amt-17-5989-2024,https://doi.org/10.5194/amt-17-5989-2024, 2024
Short summary
A portable nitrogen dioxide instrument using cavity-enhanced absorption spectroscopy
Steven A. Bailey, Reem A. Hannun, Andrew K. Swanson, and Thomas F. Hanisco
Atmos. Meas. Tech., 17, 5903–5910, https://doi.org/10.5194/amt-17-5903-2024,https://doi.org/10.5194/amt-17-5903-2024, 2024
Short summary
Development and deployment of a mid-cost CO2 sensor monitoring network to support atmospheric inverse modeling for quantifying urban CO2 emissions in Paris
Jinghui Lian, Olivier Laurent, Mali Chariot, Luc Lienhardt, Michel Ramonet, Hervé Utard, Thomas Lauvaux, François-Marie Bréon, Grégoire Broquet, Karina Cucchi, Laurent Millair, and Philippe Ciais
Atmos. Meas. Tech., 17, 5821–5839, https://doi.org/10.5194/amt-17-5821-2024,https://doi.org/10.5194/amt-17-5821-2024, 2024
Short summary

Cited articles

Atkinson, R.: Atmospheric chemistry of VOCs and NOx, Atmospheric Environment, 34, 2063–2101, 2000.
Baasandorj, M., Millet, D. B., Hu, L., Mitroo, D., and Williams, B. J.: Measuring acetic and formic acid by proton-transfer-reaction mass spectrometry: sensitivity, humidity dependence, and quantifying interferences, Atmos. Meas. Tech., 8, 1303–1321, https://doi.org/10.5194/amt-8-1303-2015, 2015.
Bertram, T. H., Kimmel, J. R., Crisp, T. A., Ryder, O. S., Yatavelli, R. L. N., Thornton, J. A., Cubison, M. J., Gonin, M., and Worsnop, D. R.: A field-deployable, chemical ionization time-of-flight mass spectrometer, Atmos. Meas. Tech., 4, 1471–1479, https://doi.org/10.5194/amt-4-1471-2011, 2011.
Blake, R. S., Whyte, C., Hughes, C. O., Ellis, A. M., and Monks, P. S.: Demonstration of proton-transfer reaction time-of-flight mass spectrometry for real-time analysis of trace volatile organic compounds, Anal. Chem., 76, 3841–3845, https://doi.org/10.1021/ac0498260, 2004.
Blake, R. S., Monks, P. S., and Ellis, A. M.: Proton-Transfer Reaction Mass Spectrometry, Chem. Rev., 109, 861–896, https://doi.org/10.1021/Cr800364q, 2009.
Download
Short summary
We present the development of a hydronium (H3O+) time of flight chemical ionization mass spectrometer (H3O+ ToF-CIMS). We characterize the humidity dependence of the reagent ions and VOC signals in details. The low mass cutoff issue of RF-only quadrupole leads to unusual humidity dependence of reagent ions. The new H3O+ ToF-CIMS was successfully deployed on the NOAA WP-3D research aircraft for the SONGNEX campaign in 2015 and some initial results from the SONGNEX campaign are presented.