Articles | Volume 12, issue 2
https://doi.org/10.5194/amt-12-1365-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-12-1365-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
28 Feb 2019
Research article |
| 28 Feb 2019
| 28 Feb 2019
Aerosol light absorption from optical measurements of PTFE membrane filter samples: sensitivity analysis of optical depth measures
Apoorva Pandey
Center for Aerosol Science and Engineering, Department of Energy,
Environmental and Chemical Engineering, Washington University in St. Louis,
St. Louis, MO 63130, USA
Nishit J. Shetty
Center for Aerosol Science and Engineering, Department of Energy,
Environmental and Chemical Engineering, Washington University in St. Louis,
St. Louis, MO 63130, USA
Rajan K. Chakrabarty
CORRESPONDING AUTHOR
Center for Aerosol Science and Engineering, Department of Energy,
Environmental and Chemical Engineering, Washington University in St. Louis,
St. Louis, MO 63130, USA
McDonnell Center for the Space Sciences, Washington University in St.
Louis, St. Louis, MO 63130, USA
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Nishit J. Shetty, Apoorva Pandey, Stephen Baker, Wei Min Hao, and Rajan K. Chakrabarty
Atmos. Chem. Phys., 19, 8817–8830, https://doi.org/10.5194/acp-19-8817-2019, https://doi.org/10.5194/acp-19-8817-2019, 2019
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We investigated biases in particle-phase absorption coefficients for organic aerosol from bulk-phase absorbance measurements of solvent extracts in the visible spectrum. These biases were systematically studied as a function of organic-to-total carbon mass ratios and aerosol single scattering albedo. A linear correlation between SSA and OC / TC ratios was observed. Differences in the absorption Ångström exponents from bulk- and particle-phase measurements were also investigated.
Apoorva Pandey, Sameer Patel, Shamsh Pervez, Suresh Tiwari, Gautam Yadama, Judith C. Chow, John G. Watson, Pratim Biswas, and Rajan K. Chakrabarty
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This study presents real-world aerosol mass emission factors for traditional biomass cookstoves in India to help constrain regional inventory emissions. Aerosol emissions were sampled from an in-use traditional mud stove burning common biomass fuel types in an Indian household. Measured particulate emission factors and their organic carbon content were higher than those from previous laboratory studies. Field emissions showed a distinct profile of temperature-resolved carbon mass fractions.
Rajan K. Chakrabarty, Madhu Gyawali, Reddy L. N. Yatavelli, Apoorva Pandey, Adam C. Watts, Joseph Knue, Lung-Wen A. Chen, Robert R. Pattison, Anna Tsibart, Vera Samburova, and Hans Moosmüller
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Brown carbon aerosols dominate particulate emissions from the burning of Alaskan and Siberian peatlands. They physically occur as amorphous "tar balls" with negligible black carbon mixing. They absorb very strongly in the shorter visible wavelengths, characterized by a mean Ångström coefficient of ≈ 9. These aerosols could result in a net warming of the atmosphere, provided the albedo of the underlying surface is greater than 0.6.
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Atmos. Chem. Phys., 24, 13285–13297, https://doi.org/10.5194/acp-24-13285-2024, https://doi.org/10.5194/acp-24-13285-2024, 2024
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Brown carbon (BrC) aerosols show an order-of-magnitude variation in their light absorption strength. Our understanding of BrC from real-world biomass burning remains limited, complicating the determination of its radiative impact. Our study reports absorption properties of BrC emitted from four major biomass burning sources using field measurements in India. It develops an absorption parameterization for BrC and examines the spatial variability in BrC's absorption strength across India.
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Atmos. Chem. Phys., 22, 14825–14836, https://doi.org/10.5194/acp-22-14825-2022, https://doi.org/10.5194/acp-22-14825-2022, 2022
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Understanding and parameterizing the influences of black carbon (BC) particle morphology and compositional heterogeneity on its light absorption represent a fundamental problem. We develop scaling laws using a single unifying parameter that effectively encompasses large-scale diversity observed in BC light absorption on a per-particle basis. The laws help reconcile the disparities between field observations and model predictions. Our framework is packaged in an open-source Python application.
Joshin Kumar, Theo Paik, Nishit J. Shetty, Patrick Sheridan, Allison C. Aiken, Manvendra K. Dubey, and Rajan K. Chakrabarty
Atmos. Meas. Tech., 15, 4569–4583, https://doi.org/10.5194/amt-15-4569-2022, https://doi.org/10.5194/amt-15-4569-2022, 2022
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Accurate long-term measurement of aerosol light absorption is vital for assessing direct aerosol radiative forcing. Light absorption by aerosols at the US Department of Energy long-term climate monitoring SGP site is measured using the Particle Soot Absorption Photometer (PSAP), which suffers from artifacts and biases difficult to quantify. Machine learning offers a promising path forward to correct for biases in the long-term absorption dataset at the SGP site and similar Class-I areas.
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Atmos. Chem. Phys., 22, 7647–7666, https://doi.org/10.5194/acp-22-7647-2022, https://doi.org/10.5194/acp-22-7647-2022, 2022
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Benjamin Sumlin, Edward Fortner, Andrew Lambe, Nishit J. Shetty, Conner Daube, Pai Liu, Francesca Majluf, Scott Herndon, and Rajan K. Chakrabarty
Atmos. Chem. Phys., 21, 11843–11856, https://doi.org/10.5194/acp-21-11843-2021, https://doi.org/10.5194/acp-21-11843-2021, 2021
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We present a comparison of the changes to light absorption behavior and chemical composition of wildfire smoke particles from day- and nighttime oxidation processes and discuss the results within the context of previous laboratory findings.
Nishit J. Shetty, Apoorva Pandey, Stephen Baker, Wei Min Hao, and Rajan K. Chakrabarty
Atmos. Chem. Phys., 19, 8817–8830, https://doi.org/10.5194/acp-19-8817-2019, https://doi.org/10.5194/acp-19-8817-2019, 2019
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We investigated biases in particle-phase absorption coefficients for organic aerosol from bulk-phase absorbance measurements of solvent extracts in the visible spectrum. These biases were systematically studied as a function of organic-to-total carbon mass ratios and aerosol single scattering albedo. A linear correlation between SSA and OC / TC ratios was observed. Differences in the absorption Ångström exponents from bulk- and particle-phase measurements were also investigated.
Shiwen Teng, Chao Liu, Martin Schnaiter, Rajan K. Chakrabarty, and Fengshan Liu
Atmos. Chem. Phys., 19, 2917–2931, https://doi.org/10.5194/acp-19-2917-2019, https://doi.org/10.5194/acp-19-2917-2019, 2019
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Black carbon (BC) possesses complex minor structures besides the overall aggregate geometry, thus altering their optical properties. This study introduces volume variation to quantify and unify different minor structures and develops an empirical relation to account for their effects on BC optical properties. We find the effects of minor structures are mainly contributed by their influence on particle volume/mass, and a relative difference of 5 % is noticed after removing volume differences.
Apoorva Pandey, Sameer Patel, Shamsh Pervez, Suresh Tiwari, Gautam Yadama, Judith C. Chow, John G. Watson, Pratim Biswas, and Rajan K. Chakrabarty
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This study presents real-world aerosol mass emission factors for traditional biomass cookstoves in India to help constrain regional inventory emissions. Aerosol emissions were sampled from an in-use traditional mud stove burning common biomass fuel types in an Indian household. Measured particulate emission factors and their organic carbon content were higher than those from previous laboratory studies. Field emissions showed a distinct profile of temperature-resolved carbon mass fractions.
Luka Drinovec, Asta Gregorič, Peter Zotter, Robert Wolf, Emily Anne Bruns, André S. H. Prévôt, Jean-Eudes Petit, Olivier Favez, Jean Sciare, Ian J. Arnold, Rajan K. Chakrabarty, Hans Moosmüller, Agnes Filep, and Griša Močnik
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Black carbon measurements are usually conducted with absorption filter photometers, which are prone to the filter-loading effect – a saturation of the instrumental response due to the accumulation of the sample in the filter matrix. In this paper, we conducted several field campaigns to investigate the hypothesis that this filter-loading effect depends on the optical properties of particles present in the filter matrix, especially on the coating of black carbon particles.
Rajan K. Chakrabarty, Madhu Gyawali, Reddy L. N. Yatavelli, Apoorva Pandey, Adam C. Watts, Joseph Knue, Lung-Wen A. Chen, Robert R. Pattison, Anna Tsibart, Vera Samburova, and Hans Moosmüller
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Brown carbon aerosols dominate particulate emissions from the burning of Alaskan and Siberian peatlands. They physically occur as amorphous "tar balls" with negligible black carbon mixing. They absorb very strongly in the shorter visible wavelengths, characterized by a mean Ångström coefficient of ≈ 9. These aerosols could result in a net warming of the atmosphere, provided the albedo of the underlying surface is greater than 0.6.
A. Ellis, R. Edwards, M. Saunders, R. K. Chakrabarty, R. Subramanian, A. van Riessen, A. M. Smith, D. Lambrinidis, L. J. Nunes, P. Vallelonga, I. D. Goodwin, A. D. Moy, M. A. J. Curran, and T. D. van Ommen
Atmos. Meas. Tech., 8, 3959–3969, https://doi.org/10.5194/amt-8-3959-2015, https://doi.org/10.5194/amt-8-3959-2015, 2015
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Black carbon is an important environmental pollutant, and the structure and composition of these particles are important to measuring their affect on the climate. Historical records of black carbon emissions are stored in polar ice. This paper details a new method to study black carbon preserved in Antarctic ice cores. By combining filtration to concentrate the particles and electron microscopy to characterize them, this method opens up a new avenue to study the history of our atmosphere.
Related subject area
Subject: Aerosols | Technique: In Situ Measurement | Topic: Validation and Intercomparisons
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The Fifth International Ice Nucleation Workshop 3rd Phase (FIN-03) compared the ambient atmospheric performance of ice nucleating particle (INP) measuring systems and explored general methods for discerning atmospheric INP compositions. Mirroring laboratory results, most measurements agreed within one order of magnitude. Measurements of total aerosol properties and investigations of INP compositions supported a dominant role of soil and plant organic aerosol elements as INPs during the study.
Arash Naseri, Joel C. Corbin, and Jason S. Olfert
Atmos. Meas. Tech., 17, 3719–3738, https://doi.org/10.5194/amt-17-3719-2024, https://doi.org/10.5194/amt-17-3719-2024, 2024
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It is crucial to accurately measure the mixing states of light-absorbing carbon particles from emission sources like wildfires and biomass combustion to decrease climate forcing uncertainties. This study compares methods that measure light-absorbing carbon in the atmosphere. The CPMA-SP2 method offers more accurate results than traditional light-scattering methods, such as the leading-edge-only (LEO) method, thereby enhancing the accuracy of measuring the mixing states of light-absorbing carbon.
Rui Li, Prema Piyusha Panda, Yizhu Chen, Zhenming Zhu, Fu Wang, Yujiao Zhu, He Meng, Yan Ren, Ashwini Kumar, and Mingjin Tang
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We found that for ultrapure water batch leaching, the difference in specific experimental parameters, including agitation methods, filter pore size, and contact time, only led to a small and sometimes insignificant difference in determined aerosol trace element solubility. Furthermore, aerosol trace element solubility determined using four common ultrapure water leaching protocols showed good agreement.
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Field comparison of dual-spot (AE33) and single-spot (AE31) Aethalometers by full-year collocated measurements suggests that site-specific correction factors are needed to ensure the long-term data continuity for AE31-to-AE33 transition in black carbon monitoring networks; babs agrees well between AE33 and AE31, with slight variations by wavelength (slope: 0.87–1.04; R2: 0.95–0.97). A ~ 20 % difference in secondary brown carbon light absorption was found between AE33 and AE31.
Renmin Yuan, Hongsheng Zhang, Jiajia Hua, Hao Liu, Peizhe Wu, Xingyu Zhu, and Jianning Sun
Atmos. Meas. Tech., 17, 2089–2102, https://doi.org/10.5194/amt-17-2089-2024, https://doi.org/10.5194/amt-17-2089-2024, 2024
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Previously, a new method for atmospheric aerosol flux was proposed, and a large-aperture scintillometer was developed for experimental measurements, but the method was consistently not validated. In this paper, eddy correlation experiments for aerosol vertical transport fluxes were conducted to verify the reliability of the previous large-aperture scintillometer method. The experimental results also show that urban green land is a sink area for aerosol particles.
Vijay Kumar, Dinushani Senarathna, Supraja Gurajala, William Olsen, Shantanu Sur, Sumona Mondal, and Suresh Dhaniyala
Atmos. Meas. Tech., 16, 5415–5427, https://doi.org/10.5194/amt-16-5415-2023, https://doi.org/10.5194/amt-16-5415-2023, 2023
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Low-cost sensors are becoming increasingly important in air quality monitoring due to their affordability and ease of deployment. While low-cost sensors have the potential to democratize air quality monitoring, their use must be accompanied by careful interpretation and validation of the data. Analysis of their long-term data record clearly shows that the reported data from low-cost sensors may not be equally sensitive to all emission sources, which can complicate policy-making.
Ville Leinonen, Miska Olin, Sampsa Martikainen, Panu Karjalainen, and Santtu Mikkonen
Atmos. Meas. Tech., 16, 5075–5089, https://doi.org/10.5194/amt-16-5075-2023, https://doi.org/10.5194/amt-16-5075-2023, 2023
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Emission factor calculation was studied to provide models that do not use traditional CO2-based calculation in exhaust plume analysis. Two types of models, one based on the physical dependency of dilution of the exhaust flow rate and speed and two based on the statistical, measured dependency of dilution of the exhaust flow rate, acceleration, speed, altitude change, and/or wind, were developed. These methods could possibly be extended to also calculate non-exhaust emissions in the future.
Mark Joseph Campmier, Jonathan Gingrich, Saumya Singh, Nisar Baig, Shahzad Gani, Adithi Upadhya, Pratyush Agrawal, Meenakshi Kushwaha, Harsh Raj Mishra, Ajay Pillarisetti, Sreekanth Vakacherla, Ravi Kant Pathak, and Joshua S. Apte
Atmos. Meas. Tech., 16, 4357–4374, https://doi.org/10.5194/amt-16-4357-2023, https://doi.org/10.5194/amt-16-4357-2023, 2023
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We studied a low-cost air pollution sensor called PurpleAir PA-II in three different locations in India (Delhi, Hamirpur, and Bangalore) to characterize its performance. We compared its signal to more expensive reference sensors and found that the PurpleAir sensor was precise but inaccurate without calibration. We created a custom calibration equation for each location, which improved the accuracy of the PurpleAir sensor, and found that calibrations should be adjusted for different seasons.
Mrinmoy Chakraborty, Amanda Giang, and Naomi Zimmerman
Atmos. Meas. Tech., 16, 2333–2352, https://doi.org/10.5194/amt-16-2333-2023, https://doi.org/10.5194/amt-16-2333-2023, 2023
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Black carbon (BC) has important climate and human health impacts. Aethalometers are used to measure BC, but they are hard to deploy in many environments (remote, mobile). We evaluate how well a portable micro-aethalometer (MA300) performs compared to a reference aethalometer at a road-side site in Vancouver, BC, Canada, during regular and wildfire conditions. We find that the MA300 can reproduce overall patterns in concentrations and source characterization but with some underestimation.
William Wandji Nyamsi, Yves-Marie Saint-Drenan, Antti Arola, and Lucien Wald
Atmos. Meas. Tech., 16, 2001–2036, https://doi.org/10.5194/amt-16-2001-2023, https://doi.org/10.5194/amt-16-2001-2023, 2023
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The McClear service provides estimates of surface solar irradiances in cloud-free conditions. By comparing McClear estimates to 1 min measurements performed in Sub-Saharan Africa and the Maldives Archipelago in the Indian Ocean, McClear accurately estimates global irradiance and tends to overestimate direct irrradiance. This work establishes a general overview of the performance of the McClear service.
Misti Levy Zamora, Colby Buehler, Abhirup Datta, Drew R. Gentner, and Kirsten Koehler
Atmos. Meas. Tech., 16, 169–179, https://doi.org/10.5194/amt-16-169-2023, https://doi.org/10.5194/amt-16-169-2023, 2023
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We assessed five pairs of co-located reference and low-cost sensor data sets (PM2.5, O3, NO2, NO, and CO) to make recommendations for best practices regarding the field calibration of low-cost air quality sensors. We found diminishing improvements for calibration periods longer than about 6 weeks for all sensors and that co-location can be minimized if the period is strategically selected and monitored so that the calibration period is representative of the desired measurement setting.
Paul A. Barrett, Steven J. Abel, Hugh Coe, Ian Crawford, Amie Dobracki, James Haywood, Steve Howell, Anthony Jones, Justin Langridge, Greg M. McFarquhar, Graeme J. Nott, Hannah Price, Jens Redemann, Yohei Shinozuka, Kate Szpek, Jonathan W. Taylor, Robert Wood, Huihui Wu, Paquita Zuidema, Stéphane Bauguitte, Ryan Bennett, Keith Bower, Hong Chen, Sabrina Cochrane, Michael Cotterell, Nicholas Davies, David Delene, Connor Flynn, Andrew Freedman, Steffen Freitag, Siddhant Gupta, David Noone, Timothy B. Onasch, James Podolske, Michael R. Poellot, Sebastian Schmidt, Stephen Springston, Arthur J. Sedlacek III, Jamie Trembath, Alan Vance, Maria A. Zawadowicz, and Jianhao Zhang
Atmos. Meas. Tech., 15, 6329–6371, https://doi.org/10.5194/amt-15-6329-2022, https://doi.org/10.5194/amt-15-6329-2022, 2022
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To better understand weather and climate, it is vital to go into the field and collect observations. Often measurements take place in isolation, but here we compared data from two aircraft and one ground-based site. This was done in order to understand how well measurements made on one platform compared to those made on another. Whilst this is easy to do in a controlled laboratory setting, it is more challenging in the real world, and so these comparisons are as valuable as they are rare.
Varaha Ravi Kiran, Madineni Venkat Ratnam, Masatomo Fujiwara, Herman Russchenberg, Frank G. Wienhold, Bomidi Lakshmi Madhavan, Mekalathur Roja Raman, Renju Nandan, Sivan Thankamani Akhil Raj, Alladi Hemanth Kumar, and Saginela Ravindra Babu
Atmos. Meas. Tech., 15, 4709–4734, https://doi.org/10.5194/amt-15-4709-2022, https://doi.org/10.5194/amt-15-4709-2022, 2022
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We proposed and conducted the multi-instrumental BACIS (Balloon-borne Aerosol–Cloud Interaction Studies) field campaigns using balloon-borne in situ measurements and ground-based and space-borne remote sensing instruments. Aerosol-cloud interaction is quantified for liquid clouds by segregating aerosol and cloud information in a balloon profile. Overall, the observational approach proposed here demonstrated its capability for understanding the aerosol–cloud interaction process.
Joshin Kumar, Theo Paik, Nishit J. Shetty, Patrick Sheridan, Allison C. Aiken, Manvendra K. Dubey, and Rajan K. Chakrabarty
Atmos. Meas. Tech., 15, 4569–4583, https://doi.org/10.5194/amt-15-4569-2022, https://doi.org/10.5194/amt-15-4569-2022, 2022
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Accurate long-term measurement of aerosol light absorption is vital for assessing direct aerosol radiative forcing. Light absorption by aerosols at the US Department of Energy long-term climate monitoring SGP site is measured using the Particle Soot Absorption Photometer (PSAP), which suffers from artifacts and biases difficult to quantify. Machine learning offers a promising path forward to correct for biases in the long-term absorption dataset at the SGP site and similar Class-I areas.
Brayden Nilson, Peter L. Jackson, Corinne L. Schiller, and Matthew T. Parsons
Atmos. Meas. Tech., 15, 3315–3328, https://doi.org/10.5194/amt-15-3315-2022, https://doi.org/10.5194/amt-15-3315-2022, 2022
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Correction models were developed using PurpleAir–Federal Equivalent Method (FEM) hourly fine particulate matter (PM2.5) observation colocation sites across North America (NA). These were evaluated in comparison with four existing models at an additional 15 NA colocation sites. This study provides a robust framework for the evaluation of low-cost PM2.5 sensor correction models using the Canadian AQHI+ system and presents an optimized general correction model for North American PA sensors.
Patrick Weber, Andreas Petzold, Oliver F. Bischof, Benedikt Fischer, Marcel Berg, Andrew Freedman, Timothy B. Onasch, and Ulrich Bundke
Atmos. Meas. Tech., 15, 3279–3296, https://doi.org/10.5194/amt-15-3279-2022, https://doi.org/10.5194/amt-15-3279-2022, 2022
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In our laboratory closure study, we measured the full set of aerosol optical properties for different light-absorbing aerosols using a set of instruments.
Our key finding is that the extensive and intensive aerosol optical properties obtained agree with data from reference instruments, except the absorption Ångström exponent of externally mixed aerosols. The reported uncertainty in the single-scattering albedo fulfils the defined goals for Global Climate Observing System applications of 10 %.
Joel C. Corbin, Tobias Schripp, Bruce E. Anderson, Greg J. Smallwood, Patrick LeClercq, Ewan C. Crosbie, Steven Achterberg, Philip D. Whitefield, Richard C. Miake-Lye, Zhenhong Yu, Andrew Freedman, Max Trueblood, David Satterfield, Wenyan Liu, Patrick Oßwald, Claire Robinson, Michael A. Shook, Richard H. Moore, and Prem Lobo
Atmos. Meas. Tech., 15, 3223–3242, https://doi.org/10.5194/amt-15-3223-2022, https://doi.org/10.5194/amt-15-3223-2022, 2022
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The combustion of sustainable aviation fuels in aircraft engines produces particulate matter (PM) emissions with different properties than conventional fuels due to changes in fuel composition. Consequently, the response of various diagnostic instruments to PM emissions may be impacted. We found no significant instrument biases in terms of particle mass, number, and size measurements for conventional and sustainable aviation fuel blends despite large differences in the magnitude of emissions.
Himadri Sekhar Bhowmik, Ashutosh Shukla, Vipul Lalchandani, Jay Dave, Neeraj Rastogi, Mayank Kumar, Vikram Singh, and Sachchida Nand Tripathi
Atmos. Meas. Tech., 15, 2667–2684, https://doi.org/10.5194/amt-15-2667-2022, https://doi.org/10.5194/amt-15-2667-2022, 2022
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This study presents comparisons between online and offline measurements of both refractory and non-refractory aerosol. This study shows differences between the measurements, related to either the limitations of the instrument (e.g., aerosol mass spectrometer only observing non-refractory aerosol) or known interferences with the technique (e.g., volatilization or reactions). The findings highlight the measurement methods' accuracy and imply the particular type of measurements needed.
Ruoyang Yuan, Prem Lobo, Greg J. Smallwood, Mark P. Johnson, Matthew C. Parker, Daniel Butcher, and Adrian Spencer
Atmos. Meas. Tech., 15, 241–259, https://doi.org/10.5194/amt-15-241-2022, https://doi.org/10.5194/amt-15-241-2022, 2022
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The relationship between the non-volatile particulate matter (nvPM) mass emissions produced by different engine sources and the response of the LII 300 instrument, used for regulatory measurements of nvPM mass emissions in aircraft engine certification tests, was investigated for different sources and operating conditions. Laser fluence optimisation was required for real-time nvPM mass concentration measurements. These results will inform the development of updated calibration protocols.
Yangjunjie Xu-Yang, Rémi Losno, Fabrice Monna, Jean-Louis Rajot, Mohamed Labiadh, Gilles Bergametti, and Béatrice Marticorena
Atmos. Meas. Tech., 14, 7657–7680, https://doi.org/10.5194/amt-14-7657-2021, https://doi.org/10.5194/amt-14-7657-2021, 2021
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Suspended particles in air (aerosols) are sampled with a pump drawing ambient air through a filter. The air inlet must be carefully designed to control the size of sampled particles and to reject the largest ones (> 10 µm). A low-cost sampling head for determination of the finest fraction of aerosol (> 10 µm in diameter) is presented. Compositional data analysis (CoDA) tools are extensively used here to demonstrate similarity between the low-cost sampling head and other existing systems.
Chunshui Lin, Darius Ceburnis, Anna Trubetskaya, Wei Xu, William Smith, Stig Hellebust, John Wenger, Colin O'Dowd, and Jurgita Ovadnevaite
Atmos. Meas. Tech., 14, 6905–6916, https://doi.org/10.5194/amt-14-6905-2021, https://doi.org/10.5194/amt-14-6905-2021, 2021
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Source apportionment of solid-fuel-burning emissions can be complicated by the use of different fuels, stoves, and burning conditions. Here, the organic aerosol mass spectra produced from burning a range of solid fuels in several stoves were compared. This study accounts for the source variability and provides better constraints on the primary factor contributions to the ambient organic aerosol estimations, holding significant implications for public health and policymakers.
Sho Ohata, Tatsuhiro Mori, Yutaka Kondo, Sangeeta Sharma, Antti Hyvärinen, Elisabeth Andrews, Peter Tunved, Eija Asmi, John Backman, Henri Servomaa, Daniel Veber, Konstantinos Eleftheriadis, Stergios Vratolis, Radovan Krejci, Paul Zieger, Makoto Koike, Yugo Kanaya, Atsushi Yoshida, Nobuhiro Moteki, Yongjing Zhao, Yutaka Tobo, Junji Matsushita, and Naga Oshima
Atmos. Meas. Tech., 14, 6723–6748, https://doi.org/10.5194/amt-14-6723-2021, https://doi.org/10.5194/amt-14-6723-2021, 2021
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Reliable values of mass absorption cross sections (MACs) of black carbon (BC) are required to determine mass concentrations of BC at Arctic sites using different types of filter-based absorption photometers. We successfully estimated MAC values for these instruments through comparison with independent measurements of BC by a continuous soot monitoring system called COSMOS. These MAC values are consistent with each other and applicable to study spatial and temporal variation in BC in the Arctic.
Krista Luoma, Aki Virkkula, Pasi Aalto, Katrianne Lehtipalo, Tuukka Petäjä, and Markku Kulmala
Atmos. Meas. Tech., 14, 6419–6441, https://doi.org/10.5194/amt-14-6419-2021, https://doi.org/10.5194/amt-14-6419-2021, 2021
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The study presents a comparison of three absorption photometers that measured ambient aerosol particles at a boreal forest site. The study aims to better understand problems related to filter-based measurements. Results show how different correction algorithms, which are used to produce the data, affect the derived optical properties of aerosol particles.
Jesús Yus-Díez, Vera Bernardoni, Griša Močnik, Andrés Alastuey, Davide Ciniglia, Matic Ivančič, Xavier Querol, Noemí Perez, Cristina Reche, Martin Rigler, Roberta Vecchi, Sara Valentini, and Marco Pandolfi
Atmos. Meas. Tech., 14, 6335–6355, https://doi.org/10.5194/amt-14-6335-2021, https://doi.org/10.5194/amt-14-6335-2021, 2021
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Here we characterize the multiple-scattering factor, C, of the dual-spot Aethalometer AE33 and its cross-sensitivity to scattering and wavelength dependence for three background stations: urban, regional and mountaintop. C was obtained for two sets of filter tapes: M8020 and M8060. The cross-sensitivity to scattering and wavelength dependence of C were determined by inter-comparing with other absorption and scattering measurements including multi-angle off-line absorption measurements.
Hui Li, Boming Liu, Xin Ma, Shikuan Jin, Yingying Ma, Yuefeng Zhao, and Wei Gong
Atmos. Meas. Tech., 14, 5977–5986, https://doi.org/10.5194/amt-14-5977-2021, https://doi.org/10.5194/amt-14-5977-2021, 2021
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Radiosonde (RS) is widely used to detect the vertical structures of the planetary boundary layer (PBL), and numerous methods have been proposed for retrieving PBL height (PBLH) from RS data. However, an algorithm that is suitable under all atmospheric conditions does not exist. This study evaluates the performance of four common PBLH algorithms under different thermodynamic stability conditions based on RS data.
Eija Asmi, John Backman, Henri Servomaa, Aki Virkkula, Maria I. Gini, Konstantinos Eleftheriadis, Thomas Müller, Sho Ohata, Yutaka Kondo, and Antti Hyvärinen
Atmos. Meas. Tech., 14, 5397–5413, https://doi.org/10.5194/amt-14-5397-2021, https://doi.org/10.5194/amt-14-5397-2021, 2021
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Absorbing aerosols are warming the planet and accurate measurements of their concentrations in pristine environments are needed. We applied eight different absorbing-aerosol measurement methods in a field campaign at the Arctic Pallas station. The filter-based techniques were found to be the most sensitive to detect the minuscule amounts of black carbon present, showing a 40 % agreement between them. Our results help to reduce uncertainties in absorbing aerosol measurements.
Karoline K. Barkjohn, Brett Gantt, and Andrea L. Clements
Atmos. Meas. Tech., 14, 4617–4637, https://doi.org/10.5194/amt-14-4617-2021, https://doi.org/10.5194/amt-14-4617-2021, 2021
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Although widely used, air sensor measurements are often biased. In this work we develop a correction with a relative humidity term that reduces the bias and improves consistency between different United States regions. This correction equation, along with proposed data cleaning criteria, has been applied to PurpleAir PM2.5 measurements across the US on the AirNow Fire and Smoke Map and has the potential to be successfully used in other air quality and public health applications.
Richard H. Moore, Elizabeth B. Wiggins, Adam T. Ahern, Stephen Zimmerman, Lauren Montgomery, Pedro Campuzano Jost, Claire E. Robinson, Luke D. Ziemba, Edward L. Winstead, Bruce E. Anderson, Charles A. Brock, Matthew D. Brown, Gao Chen, Ewan C. Crosbie, Hongyu Guo, Jose L. Jimenez, Carolyn E. Jordan, Ming Lyu, Benjamin A. Nault, Nicholas E. Rothfuss, Kevin J. Sanchez, Melinda Schueneman, Taylor J. Shingler, Michael A. Shook, Kenneth L. Thornhill, Nicholas L. Wagner, and Jian Wang
Atmos. Meas. Tech., 14, 4517–4542, https://doi.org/10.5194/amt-14-4517-2021, https://doi.org/10.5194/amt-14-4517-2021, 2021
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Atmospheric particles are everywhere and exist in a range of sizes, from a few nanometers to hundreds of microns. Because particle size determines the behavior of chemical and physical processes, accurately measuring particle sizes is an important and integral part of atmospheric field measurements! Here, we discuss the performance of two commonly used particle sizers and how changes in particle composition and optical properties may result in sizing uncertainties, which we quantify.
Alexandra J. Boris, Satoshi Takahama, Andrew T. Weakley, Bruno M. Debus, Stephanie L. Shaw, Eric S. Edgerton, Taekyu Joo, Nga L. Ng, and Ann M. Dillner
Atmos. Meas. Tech., 14, 4355–4374, https://doi.org/10.5194/amt-14-4355-2021, https://doi.org/10.5194/amt-14-4355-2021, 2021
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Infrared spectrometry can be applied in routine monitoring of atmospheric particles to give comprehensive characterization of the organic material by bond rather than species. Using this technique, the concentrations of particle organic material were found to decrease 2011–2016 in the southeastern US, driven by a decline in highly aged material, concurrent with declining anthropogenic emissions. However, an increase was observed in the fraction of more moderately aged organic matter.
Hongyu Guo, Pedro Campuzano-Jost, Benjamin A. Nault, Douglas A. Day, Jason C. Schroder, Dongwook Kim, Jack E. Dibb, Maximilian Dollner, Bernadett Weinzierl, and Jose L. Jimenez
Atmos. Meas. Tech., 14, 3631–3655, https://doi.org/10.5194/amt-14-3631-2021, https://doi.org/10.5194/amt-14-3631-2021, 2021
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We utilize a set of high-quality datasets collected during the NASA Atmospheric Tomography Mission to investigate the impact of differences in observable particle sizes across aerosol instruments in aerosol measurement comparisons. Very good agreement was found between chemically and physically derived submicron aerosol volume. Results support a lack of significant unknown biases in the response of an Aerodyne aerosol mass spectrometer (AMS) when sampling remote aerosols across the globe.
Xiaolu Zhang, Krystyna Trzepla, Warren White, Sean Raffuse, and Nicole Pauly Hyslop
Atmos. Meas. Tech., 14, 3217–3231, https://doi.org/10.5194/amt-14-3217-2021, https://doi.org/10.5194/amt-14-3217-2021, 2021
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Three models of carbon analyzer were used in the past decade to measure carbonaceous particles from samples collected within the Chemical Speciation Network. This study compares results from these analyzer models to investigate the impact on long-term data from instrument differences. Good agreement was found among the three models for total carbon, organic carbon, and elemental carbon, while the reasons for and implications of some notable differences in their subtractions are investigated.
Hengnan Guo, Zefeng Zhang, Lin Jiang, Junlin An, Bin Zhu, Hanqing Kang, and Jing Wang
Atmos. Meas. Tech., 14, 2441–2450, https://doi.org/10.5194/amt-14-2441-2021, https://doi.org/10.5194/amt-14-2441-2021, 2021
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Visibility is an indicator of atmospheric transparency and is widely used in many research fields. Although efforts have been made to improve the performance of visibility meters, a significant error exists in measured visibility data. This is because current methods of visibility measurement include a false assumption, which leads to the long-term neglect of an important source of visibility errors. Without major adjustments to current methods, it is not possible to obtain reliable data.
Rosaria E. Pileci, Robin L. Modini, Michele Bertò, Jinfeng Yuan, Joel C. Corbin, Angela Marinoni, Bas Henzing, Marcel M. Moerman, Jean P. Putaud, Gerald Spindler, Birgit Wehner, Thomas Müller, Thomas Tuch, Arianna Trentini, Marco Zanatta, Urs Baltensperger, and Martin Gysel-Beer
Atmos. Meas. Tech., 14, 1379–1403, https://doi.org/10.5194/amt-14-1379-2021, https://doi.org/10.5194/amt-14-1379-2021, 2021
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Black carbon (BC), which is an important constituent of atmospheric aerosols, remains difficult to quantify due to various limitations of available methods. This study provides an extensive comparison of co-located field measurements, applying two methods based on different principles. It was shown that both methods indeed quantify the same aerosol property – BC mass concentration. The level of agreement that can be expected was quantified, and some reasons for discrepancy were identified.
Ondřej Tichý, Miroslav Hýža, Nikolaos Evangeliou, and Václav Šmídl
Atmos. Meas. Tech., 14, 803–818, https://doi.org/10.5194/amt-14-803-2021, https://doi.org/10.5194/amt-14-803-2021, 2021
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We present an investigation of the usability of newly developed real-time concentration monitoring systems, which are based on the gamma-ray counting of aerosol filters. These high-resolution data were used for inverse modeling of the 106Ru release in 2017. Our inverse modeling results agree with previously published estimates and provide better temporal resolution of the estimates.
Martine Collaud Coen, Elisabeth Andrews, Alessandro Bigi, Giovanni Martucci, Gonzague Romanens, Frédéric P. A. Vogt, and Laurent Vuilleumier
Atmos. Meas. Tech., 13, 6945–6964, https://doi.org/10.5194/amt-13-6945-2020, https://doi.org/10.5194/amt-13-6945-2020, 2020
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The Mann–Kendall trend test requires prewhitening in the presence of serially correlated data. The effects of five prewhitening methods and time granularity, autocorrelation, temporal segmentation and length of the time series on the statistical significance and the slope are studies for seven atmospheric datasets. Finally, a new algorithm using three prewhitening methods is proposed in order to optimize the power of the test, the amount of erroneous false positive trends and the slope estimate.
Charlotte M. Beall, Dolan Lucero, Thomas C. Hill, Paul J. DeMott, M. Dale Stokes, and Kimberly A. Prather
Atmos. Meas. Tech., 13, 6473–6486, https://doi.org/10.5194/amt-13-6473-2020, https://doi.org/10.5194/amt-13-6473-2020, 2020
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Ice-nucleating particles (INPs) can influence multiple climate-relevant cloud properties. Previous studies report INP observations from precipitation samples that were stored prior to analysis, yet storage protocols vary widely, and little is known about how storage impacts INPs. This study finds that storing samples at −20 °C best preserves INP concentrations and that significant losses of small INPs occur across all storage protocols.
Benjamin A. Nault, Pedro Campuzano-Jost, Douglas A. Day, Hongyu Guo, Duseong S. Jo, Anne V. Handschy, Demetrios Pagonis, Jason C. Schroder, Melinda K. Schueneman, Michael J. Cubison, Jack E. Dibb, Alma Hodzic, Weiwei Hu, Brett B. Palm, and Jose L. Jimenez
Atmos. Meas. Tech., 13, 6193–6213, https://doi.org/10.5194/amt-13-6193-2020, https://doi.org/10.5194/amt-13-6193-2020, 2020
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Collecting particulate matter, or aerosols, onto filters to be analyzed offline is a widely used method to investigate the mass concentration and chemical composition of the aerosol, especially the inorganic portion. Here, we show that acidic aerosol (sulfuric acid) collected onto filters and then exposed to high ammonia mixing ratios (from human emissions) will lead to biases in the ammonium collected onto filters, and the uptake of ammonia is rapid (< 10 s), which impacts the filter data.
Laurent Poulain, Gerald Spindler, Achim Grüner, Thomas Tuch, Bastian Stieger, Dominik van Pinxteren, Jean-Eudes Petit, Olivier Favez, Hartmut Herrmann, and Alfred Wiedensohler
Atmos. Meas. Tech., 13, 4973–4994, https://doi.org/10.5194/amt-13-4973-2020, https://doi.org/10.5194/amt-13-4973-2020, 2020
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The stability and the comparability between ACSM and collocated filter sampling and MPSS measurements was investigated in order to examine the instruments robustness for year-long measurements. Specific attention was paid to the influence of the upper size cutoff diameter to better understand how it might affect the data validation. Recommendations are provided for better on-site quality assurance and quality control of the ACSM, which would be useful for either long-term or intensive campaigns.
Martin Rigler, Luka Drinovec, Gašper Lavrič, Athanasia Vlachou, André S. H. Prévôt, Jean Luc Jaffrezo, Iasonas Stavroulas, Jean Sciare, Judita Burger, Irena Kranjc, Janja Turšič, Anthony D. A. Hansen, and Griša Močnik
Atmos. Meas. Tech., 13, 4333–4351, https://doi.org/10.5194/amt-13-4333-2020, https://doi.org/10.5194/amt-13-4333-2020, 2020
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Carbonaceous aerosols are a large fraction of fine particulate matter. They are extremely diverse, and they directly impact air quality, visibility, cloud formation and public health. In this paper we present a new instrument and new method to measure carbon content in particulate matter in real time and at a high time resolution. The new method was validated in a 1-month winter field campaign in Ljubljana, Slovenia.
Rosa Delia García-Cabrera, Emilio Cuevas-Agulló, África Barreto, Victoria Eugenia Cachorro, Mario Pó, Ramón Ramos, and Kees Hoogendijk
Atmos. Meas. Tech., 13, 2601–2621, https://doi.org/10.5194/amt-13-2601-2020, https://doi.org/10.5194/amt-13-2601-2020, 2020
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Spectral direct UV–visible normal solar irradiance, measured with an EKO MS-711 grating spectroradiometer at the Izaña Atmospheric Observatory (Spain), has been used to determine aerosol optical depth (AOD) at several wavelengths, and has been compared to synchronous AOD measurements from a reference AERONET (Aerosol RObotic NETwork) Cimel sun photometer.
Yan Zheng, Xi Cheng, Keren Liao, Yaowei Li, Yong Jie Li, Ru-Jin Huang, Weiwei Hu, Ying Liu, Tong Zhu, Shiyi Chen, Limin Zeng, Douglas R. Worsnop, and Qi Chen
Atmos. Meas. Tech., 13, 2457–2472, https://doi.org/10.5194/amt-13-2457-2020, https://doi.org/10.5194/amt-13-2457-2020, 2020
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This paper provides important information to help researchers to understand the mass quantification and source apportionment by Aerodyne aerosol mass spectrometers.
Minxing Si, Ying Xiong, Shan Du, and Ke Du
Atmos. Meas. Tech., 13, 1693–1707, https://doi.org/10.5194/amt-13-1693-2020, https://doi.org/10.5194/amt-13-1693-2020, 2020
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The study evaluated the performance of a low-cost PM sensor in ambient conditions and calibrated its readings using simple linear regression (SLR), multiple linear regression (MLR), and two more powerful machine-learning algorithms with random search techniques for the best model architectures. The two machine-learning algorithms are XGBoost and a feedforward neural network (NN).
Zhe Jiang, Minzheng Duan, Huizheng Che, Wenxing Zhang, Teruyuki Nakajima, Makiko Hashimoto, Bin Chen, and Akihiro Yamazaki
Atmos. Meas. Tech., 13, 1195–1212, https://doi.org/10.5194/amt-13-1195-2020, https://doi.org/10.5194/amt-13-1195-2020, 2020
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This study analyzed the aerosol optical properties derived by SKYRAD.pack versions 5.0 and 4.2 using the radiometer measurements over Qionghai and Yucheng in China, which are two new sites of SKYNET. The seasonal variability of the aerosol properties over the two sites were investigated based on SKYRAD.pack V5.0. The validation results provide valuable references for continued improvement of the retrieval algorithms of SKYNET and other aerosol observational networks.
Ernest Nyaku, Robert Loughman, Pawan K. Bhartia, Terry Deshler, Zhong Chen, and Peter R. Colarco
Atmos. Meas. Tech., 13, 1071–1087, https://doi.org/10.5194/amt-13-1071-2020, https://doi.org/10.5194/amt-13-1071-2020, 2020
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This paper shows the importance of the nature of the aerosol phase function used in the retrieval of the stratospheric aerosol extinction from limb scattering measurements. The aerosol phase function is derived from the parameters using either a unimodal lognormal or gamma aerosol size distribution. These two distributions were fitted to the same aerosol concentration measurements at two altitudes, and depending on the nature of the measurements, each distribution shows its strengths.
Fan Mei, Jian Wang, Jennifer M. Comstock, Ralf Weigel, Martina Krämer, Christoph Mahnke, John E. Shilling, Johannes Schneider, Christiane Schulz, Charles N. Long, Manfred Wendisch, Luiz A. T. Machado, Beat Schmid, Trismono Krisna, Mikhail Pekour, John Hubbe, Andreas Giez, Bernadett Weinzierl, Martin Zoeger, Mira L. Pöhlker, Hans Schlager, Micael A. Cecchini, Meinrat O. Andreae, Scot T. Martin, Suzane S. de Sá, Jiwen Fan, Jason Tomlinson, Stephen Springston, Ulrich Pöschl, Paulo Artaxo, Christopher Pöhlker, Thomas Klimach, Andreas Minikin, Armin Afchine, and Stephan Borrmann
Atmos. Meas. Tech., 13, 661–684, https://doi.org/10.5194/amt-13-661-2020, https://doi.org/10.5194/amt-13-661-2020, 2020
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In 2014, the US DOE G1 aircraft and the German HALO aircraft overflew the Amazon basin to study how aerosols influence cloud cycles under a clean condition and around a tropical megacity. This paper describes how to meaningfully compare similar measurements from two research aircraft and identify the potential measurement issue. We also discuss the uncertainty range for each measurement for further usage in model evaluation and satellite data validation.
Andebo Waza, Kilian Schneiders, Jan May, Sergio Rodríguez, Bernd Epple, and Konrad Kandler
Atmos. Meas. Tech., 12, 6647–6665, https://doi.org/10.5194/amt-12-6647-2019, https://doi.org/10.5194/amt-12-6647-2019, 2019
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Deposition or other passive measurement techniques are used to sample mineral dust from the atmosphere. However, there exist a multitude of different collection instruments with different, usually not well-characterized sampling efficiencies, so the resulting data might be considerably biased with respect to their size representatively. In the paper, we report on collection properties of different deposition and other passive samplers based on single-particle measurements.
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Short summary
This study quantitatively establishes simple-to-use correction factors for accurately estimating particle-phase light absorption properties from bulk-phase attenuation measurements of Teflon filter samples. Using contact-free optical instrumentation with a two-stream radiative transfer model, we developed a wavelength-independent empirical correction formulation by comparing filter attenuation of aerosol-laden Teflon filter samples with in situ light absorption for a range of real-world fuels.
This study quantitatively establishes simple-to-use correction factors for accurately estimating...
