Articles | Volume 13, issue 12
https://doi.org/10.5194/amt-13-6703-2020
https://doi.org/10.5194/amt-13-6703-2020
Research article
 | 
15 Dec 2020
Research article |  | 15 Dec 2020

New technique for high-precision, simultaneous measurements of CH4, N2O and CO2 concentrations; isotopic and elemental ratios of N2, O2 and Ar; and total air content in ice cores by wet extraction

Ikumi Oyabu, Kenji Kawamura, Kyotaro Kitamura, Remi Dallmayr, Akihiro Kitamura, Chikako Sawada, Jeffrey P. Severinghaus, Ross Beaudette, Anaïs Orsi, Satoshi Sugawara, Shigeyuki Ishidoya, Dorthe Dahl-Jensen, Kumiko Goto-Azuma, Shuji Aoki, and Takakiyo Nakazawa

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Cited articles

Ahn, J., Brook, E. J., and Howell, K.: A high-precision method for measurement of paleoatmospheric CO2 in small polar ice samples, J. Glaciol., 55, 499–506, https://doi.org/10.3189/002214309788816731, 2009. 
Ahn, J., Brook, E. J., Mitchell, L., Rosen, J., McConnell, J. R., Taylor, K., Etheridge, D., and Rubino, M.: Atmospheric CO2 over the last 1000 years: A high-resolution record from the West Antarctic Ice Sheet (WAIS) Divide ice core, Global Biogeochem. Cy., 26, https://doi.org/10.1029/2011GB004247, 2012. 
Anklin, M., Barnola, J. M., Schwander, J., Stauffer, B., and Raynaud, D.: Processes Affecting the CO2 Concentrations Measured in Greenland Ice, Tellus B, 47, 461–470, https://doi.org/10.1034/j.1600-0889.47.issue4.6.x, 1995. 
Aoki, N., Ishidoya, S., Matsumoto, N., Watanabe, T., Shimosaka, T., and Murayama, S.: Preparation of primary standard mixtures for atmospheric oxygen measurements with less than 1 µmol mol−1 uncertainty for oxygen molar fractions, Atmos. Meas. Tech., 12, 2631–2646, https://doi.org/10.5194/amt-12-2631-2019, 2019. 
Aoki, S., Nakazawa, T., Murayama, S., and Kawaguchi, S.: Measurements of atmospheric methane at the Japanese Antarctic Station, Syowa, Tellus, 44, 273–281, https://doi.org/10.3402/tellusb.v44i4.15455, 1992. 
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Short summary
Air in polar ice cores provides information on past atmosphere and climate. We present a new method for simultaneously measuring eight gases (CH4, N2O and CO2 concentrations; isotopic ratios of N2 and O2; elemental ratios between N2, O2 and Ar; and total air content) from single ice-core samples with high precision.
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