Articles | Volume 6, issue 2
https://doi.org/10.5194/amt-6-301-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-6-301-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
11 Feb 2013
Research article |
| 11 Feb 2013
Evaluation of a cavity ring-down spectrometer for in situ observations of 13CO2
F. R. Vogel
Environment Canada, Climate Research Division, Climate Chemistry Research Section, 4905 Dufferin St., Toronto, Ontario M3H 5T4, Canada
Environment Canada, Climate Research Division, Climate Chemistry Research Section, 4905 Dufferin St., Toronto, Ontario M3H 5T4, Canada
D. Ernst
Environment Canada, Climate Research Division, Climate Chemistry Research Section, 4905 Dufferin St., Toronto, Ontario M3H 5T4, Canada
L. Giroux
Environment Canada, Climate Research Division, Climate Chemistry Research Section, 4905 Dufferin St., Toronto, Ontario M3H 5T4, Canada
S. Racki
Environment Canada, Climate Research Division, Climate Chemistry Research Section, 4905 Dufferin St., Toronto, Ontario M3H 5T4, Canada
D. E. J. Worthy
Environment Canada, Climate Research Division, Climate Chemistry Research Section, 4905 Dufferin St., Toronto, Ontario M3H 5T4, Canada
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We find that the state-of-the-art process-based methane flux models have both lower flux magnitude and reduced inter-model uncertainty compared to a previous model inter-comparison from over a decade ago. Despite these improvements, methane flux estimates from process-based models are still likely too high compared to atmospheric observations. We also find that models with simpler parameterizations often result in better agreement with atmospheric observations in high-latitude North America.
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Measurements of methane with vehicle-based sensors are an effective method to identify and quantify leaks from urban gas distribution systems. We deliberately released methane in different environments, and calibrated the response of different methane analyzers when they transect the plumes in a vehicle. We derived an improved statistical function for consistent emission estimations using different instruments. Repeated transects reduce the uncertainty in emission rate estimates.
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Atmos. Chem. Phys., 24, 10013–10038, https://doi.org/10.5194/acp-24-10013-2024, https://doi.org/10.5194/acp-24-10013-2024, 2024
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Methane (CH4) emissions in Canada for 2007–2017 were estimated using Canada’s surface greenhouse gas measurements. The estimated emissions show no significant trend, but emission uncertainty was reduced as more measurement sites became available. Notably for climate change, we find the wetland CH4 emissions show a positive correlation with surface air temperature in summer. Canada’s measurement network could monitor future CH4 emission changes and compliance with climate change mitigation goals.
Pramod Kumar, Christopher Caldow, Grégoire Broquet, Adil Shah, Olivier Laurent, Camille Yver-Kwok, Sebastien Ars, Sara Defratyka, Susan Warao Gichuki, Luc Lienhardt, Mathis Lozano, Jean-Daniel Paris, Felix Vogel, Caroline Bouchet, Elisa Allegrini, Robert Kelly, Catherine Juery, and Philippe Ciais
Atmos. Meas. Tech., 17, 1229–1250, https://doi.org/10.5194/amt-17-1229-2024, https://doi.org/10.5194/amt-17-1229-2024, 2024
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This study presents a series of mobile measurement campaigns to monitor the CH4 emissions from an active landfill. These measurements are processed using a Gaussian plume model and atmospheric inversion techniques to quantify the landfill CH4 emissions. The methane emission estimates range between ~0.4 and ~7 t CH4 per day, and their variations are analyzed. The robustness of the estimates is assessed depending on the distance of the measurements from the potential sources in the landfill.
Douglas E. J. Worthy, Michele K. Rauh, Lin Huang, Felix R. Vogel, Alina Chivulescu, Kenneth A. Masarie, Ray L. Langenfelds, Paul B. Krummel, Colin E. Allison, Andrew M. Crotwell, Monica Madronich, Gabrielle Pétron, Ingeborg Levin, Samuel Hammer, Sylvia Michel, Michel Ramonet, Martina Schmidt, Armin Jordan, Heiko Moossen, Michael Rothe, Ralph Keeling, and Eric J. Morgan
Atmos. Meas. Tech., 16, 5909–5935, https://doi.org/10.5194/amt-16-5909-2023, https://doi.org/10.5194/amt-16-5909-2023, 2023
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Network compatibility is important for inferring greenhouse gas fluxes at global or regional scales. This study is the first assessment of the measurement agreement among seven individual programs within the World Meteorological Organization community. It compares co-located flask air measurements at the Alert Observatory in Canada over a 17-year period. The results provide stronger confidence in the uncertainty estimation while using those datasets in various data interpretation applications.
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We investigate techniques for calculating emissions from mobile in situ gas concentrations recorded during downwind plume transects. We find that using the enhancement area to estimate emissions is the most consistent method when comparing different setups and instruments. Observations from a multi year urban methane survey and controlled release experiment are analyzed, and emissions rates for combined sewage overflow basins and a large wastewater treatment plant in Toronto are calculated.
Nasrin Mostafavi Pak, Jacob K. Hedelius, Sébastien Roche, Liz Cunningham, Bianca Baier, Colm Sweeney, Coleen Roehl, Joshua Laughner, Geoffrey Toon, Paul Wennberg, Harrison Parker, Colin Arrowsmith, Joseph Mendonca, Pierre Fogal, Tyler Wizenberg, Beatriz Herrera, Kimberly Strong, Kaley A. Walker, Felix Vogel, and Debra Wunch
Atmos. Meas. Tech., 16, 1239–1261, https://doi.org/10.5194/amt-16-1239-2023, https://doi.org/10.5194/amt-16-1239-2023, 2023
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Ground-based remote sensing instruments in the Total Carbon Column Observing Network (TCCON) measure greenhouse gases in the atmosphere. Consistency between TCCON measurements is crucial to accurately infer changes in atmospheric composition. We use portable remote sensing instruments (EM27/SUN) to evaluate biases between TCCON stations in North America. We also improve the retrievals of EM27/SUN instruments and evaluate the previous (GGG2014) and newest (GGG2020) retrieval algorithms.
Carlos Alberti, Frank Hase, Matthias Frey, Darko Dubravica, Thomas Blumenstock, Angelika Dehn, Paolo Castracane, Gregor Surawicz, Roland Harig, Bianca C. Baier, Caroline Bès, Jianrong Bi, Hartmut Boesch, André Butz, Zhaonan Cai, Jia Chen, Sean M. Crowell, Nicholas M. Deutscher, Dragos Ene, Jonathan E. Franklin, Omaira García, David Griffith, Bruno Grouiez, Michel Grutter, Abdelhamid Hamdouni, Sander Houweling, Neil Humpage, Nicole Jacobs, Sujong Jeong, Lilian Joly, Nicholas B. Jones, Denis Jouglet, Rigel Kivi, Ralph Kleinschek, Morgan Lopez, Diogo J. Medeiros, Isamu Morino, Nasrin Mostafavipak, Astrid Müller, Hirofumi Ohyama, Paul I. Palmer, Mahesh Pathakoti, David F. Pollard, Uwe Raffalski, Michel Ramonet, Robbie Ramsay, Mahesh Kumar Sha, Kei Shiomi, William Simpson, Wolfgang Stremme, Youwen Sun, Hiroshi Tanimoto, Yao Té, Gizaw Mengistu Tsidu, Voltaire A. Velazco, Felix Vogel, Masataka Watanabe, Chong Wei, Debra Wunch, Marcia Yamasoe, Lu Zhang, and Johannes Orphal
Atmos. Meas. Tech., 15, 2433–2463, https://doi.org/10.5194/amt-15-2433-2022, https://doi.org/10.5194/amt-15-2433-2022, 2022
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Space-borne greenhouse gas missions require ground-based validation networks capable of providing fiducial reference measurements. Here, considerable refinements of the calibration procedures for the COllaborative Carbon Column Observing Network (COCCON) are presented. Laboratory and solar side-by-side procedures for the characterization of the spectrometers have been refined and extended. Revised calibration factors for XCO2, XCO and XCH4 are provided, incorporating 47 new spectrometers.
Regina Gonzalez Moguel, Felix Vogel, Sébastien Ars, Hinrich Schaefer, Jocelyn C. Turnbull, and Peter M. J. Douglas
Atmos. Chem. Phys., 22, 2121–2133, https://doi.org/10.5194/acp-22-2121-2022, https://doi.org/10.5194/acp-22-2121-2022, 2022
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Evaluating methane (CH4) sources in the Athabasca oil sands region (AOSR) is crucial to effectively mitigate CH4 emissions. We tested the use of carbon isotopes to estimate source contributions from key CH4 sources in the AOSR and found that 56 ± 18 % of CH4 emissions originated from surface mining and processing facilities, 34 ± 18 % from tailings ponds, and 10 ± < 1 % from wetlands, confirming previous findings and showing that this method can be successfully used to partition CH4 sources.
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Atmos. Meas. Tech., 13, 2241–2255, https://doi.org/10.5194/amt-13-2241-2020, https://doi.org/10.5194/amt-13-2241-2020, 2020
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The sustainable support of radon metrology at the environmental level offers new scientific possibilities for the quantification of greenhouse gas (GHG) emissions and the determination of their source terms as well as for the identification of radioactive sources for the assessment of radiation exposure. This study helps to harmonize the techniques commonly used for atmospheric radon and radon progeny activity concentration measurements.
Emmanuel Arzoumanian, Felix R. Vogel, Ana Bastos, Bakhram Gaynullin, Olivier Laurent, Michel Ramonet, and Philippe Ciais
Atmos. Meas. Tech., 12, 2665–2677, https://doi.org/10.5194/amt-12-2665-2019, https://doi.org/10.5194/amt-12-2665-2019, 2019
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We tested commercial lower-cost CO2 sensors in laboratory and field studies to see if they can measure atmospheric CO2 mole fractions with less than 1 ppm bias (with monthly calibration), to allow continuous urban CO2 monitoring.
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Misa Ishizawa, Douglas Chan, Doug Worthy, Elton Chan, Felix Vogel, and Shamil Maksyutov
Atmos. Chem. Phys., 19, 4637–4658, https://doi.org/10.5194/acp-19-4637-2019, https://doi.org/10.5194/acp-19-4637-2019, 2019
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The Canadian Arctic has the potential for enhanced methane (CH4) emissions under global warming. However, the regional CH4 emission (fluxes) estimates range widely. This study analyzes recent Canadian Arctic CH4 observations and estimates the regional emissions. The additional observations yield robust CH4 flux estimates and enable the partitioning of the CH4 sources into wetland and forest fires. The results indicate that years with warmer summer conditions result in more wetland CH4 emissions.
Felix R. Vogel, Matthias Frey, Johannes Staufer, Frank Hase, Grégoire Broquet, Irène Xueref-Remy, Frédéric Chevallier, Philippe Ciais, Mahesh Kumar Sha, Pascale Chelin, Pascal Jeseck, Christof Janssen, Yao Té, Jochen Groß, Thomas Blumenstock, Qiansi Tu, and Johannes Orphal
Atmos. Chem. Phys., 19, 3271–3285, https://doi.org/10.5194/acp-19-3271-2019, https://doi.org/10.5194/acp-19-3271-2019, 2019
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Providing timely information on greenhouse gas emissions to stakeholders at sub-national scale is an emerging challenge and understanding urban CO2 levels is one key aspect. This study uses atmospheric observations of total column CO2 and compares them to numerical simulations to investigate CO2 levels in the Paris metropolitan area due to natural fluxes and anthropogenic emissions. Our measurements reveal the influence of locally added CO2, which our model is also able to predict.
Matthias Frey, Mahesh K. Sha, Frank Hase, Matthäus Kiel, Thomas Blumenstock, Roland Harig, Gregor Surawicz, Nicholas M. Deutscher, Kei Shiomi, Jonathan E. Franklin, Hartmut Bösch, Jia Chen, Michel Grutter, Hirofumi Ohyama, Youwen Sun, André Butz, Gizaw Mengistu Tsidu, Dragos Ene, Debra Wunch, Zhensong Cao, Omaira Garcia, Michel Ramonet, Felix Vogel, and Johannes Orphal
Atmos. Meas. Tech., 12, 1513–1530, https://doi.org/10.5194/amt-12-1513-2019, https://doi.org/10.5194/amt-12-1513-2019, 2019
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In a 3.5-year long study, the long-term performance of a mobile EM27/SUN spectrometer, used for greenhouse gas observations, is checked with respect to a co-located reference spectrometer. We find that the EM27/SUN is stable on timescales of several years, qualifying it for permanent carbon cycle studies.
The performance of an ensemble of 30 EM27/SUN spectrometers was also tested in the framework of the COllaborative Carbon Column Observing Network (COCCON) and found to be very uniform.
Claudia Grossi, Felix R. Vogel, Roger Curcoll, Alba Àgueda, Arturo Vargas, Xavier Rodó, and Josep-Anton Morguí
Atmos. Chem. Phys., 18, 5847–5860, https://doi.org/10.5194/acp-18-5847-2018, https://doi.org/10.5194/acp-18-5847-2018, 2018
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To gain a full picture of the Spanish (and European) GHG balance, understanding of CH4 emissions in different regions is a critical challenge, as is the improvement of bottom-up inventories for all European regions. This study uses, among other elements, GHG, meteorological and 222Rn tracer data from a Spanish region to understand the main causes of temporal variability of GHG mixing ratios. The study can offer new insights into regional emissions by identifying the impacts of changing sources.
Yilong Wang, Grégoire Broquet, Philippe Ciais, Frédéric Chevallier, Felix Vogel, Lin Wu, Yi Yin, Rong Wang, and Shu Tao
Atmos. Chem. Phys., 18, 4229–4250, https://doi.org/10.5194/acp-18-4229-2018, https://doi.org/10.5194/acp-18-4229-2018, 2018
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This paper assesses the potential of atmospheric 14CO2 observations and a global inversion system to solve for fossil fuel CO2 (FFCO2) emissions in Europe. The estimate of monthly emission budgets is largely improved in high emitting regions. The results are sensitive to the observation network and the prior uncertainty. Using a high-resolution transport model and a systematic evaluation of the uncertainty in current emission inventories should improve the potential to retrieve FFCO2 emissions.
Stephanie C. Pugliese, Jennifer G. Murphy, Felix R. Vogel, Michael D. Moran, Junhua Zhang, Qiong Zheng, Craig A. Stroud, Shuzhan Ren, Douglas Worthy, and Gregoire Broquet
Atmos. Chem. Phys., 18, 3387–3401, https://doi.org/10.5194/acp-18-3387-2018, https://doi.org/10.5194/acp-18-3387-2018, 2018
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We developed the Southern Ontario CO2 Emissions (SOCE) inventory, which identifies the spatial and temporal distribution (2.5 km and hourly, respectively) of CO2 emissions from seven source sectors. When the SOCE inventory was used with a chemistry transport model, we found strong agreement between modelled and measured mixing ratios. We were able to quantify that natural gas combustion contributes > 80 % of CO2 emissions at nighttime while on-road emissions contribute > 70 % during the day.
Sabina Assan, Alexia Baudic, Ali Guemri, Philippe Ciais, Valerie Gros, and Felix R. Vogel
Atmos. Meas. Tech., 10, 2077–2091, https://doi.org/10.5194/amt-10-2077-2017, https://doi.org/10.5194/amt-10-2077-2017, 2017
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This study is dedicated to improving measurement methods when using a Cavity Ring Down Spectroscopy instrument to measure methane at sites with elevated ethane concentrations such as Oil and Gas sites. The research was undertaken after measurements of natural gas samples suggested biased δ13CH4 results. Two instruments were extensively tested to characterize the cross sensitivities to ethane and δ13CH4 and propose corrections. Results indicate that it is imperative to account for the biases.
Lamia Ammoura, Irène Xueref-Remy, Felix Vogel, Valérie Gros, Alexia Baudic, Bernard Bonsang, Marc Delmotte, Yao Té, and Frédéric Chevallier
Atmos. Chem. Phys., 16, 15653–15664, https://doi.org/10.5194/acp-16-15653-2016, https://doi.org/10.5194/acp-16-15653-2016, 2016
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We propose a new approach to estimate urban emission ratios that takes advantage of the enhanced local urban signal in the atmosphere at low wind speed. We apply it to estimate monthly ratios between CO2, CO and some VOCs from atmospheric measurement datasets acquired in the centre of Paris between 2010 and 2014. We find that this approach is little sensitive to the regional background level definition. With this new method, we may reveal spatial and seasonal variability in the ratios in Paris.
Elton Chan, Douglas Chan, Misa Ishizawa, Felix Vogel, Jerome Brioude, Andy Delcloo, Yuehua Wu, and Baisuo Jin
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2016-213, https://doi.org/10.5194/gmd-2016-213, 2016
Revised manuscript not accepted
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The main objective of this study is to examine the impacts of errors introduced by different components in our newly developed inversion system on flux estimates with a series of controlled experiments. It is very critical for any inversion system to be fully evaluated prior to applying to real observations. As demonstrated, the results can be very sensitive to the model setup and region. It is not reasonable to expect realistic results can always be obtained using the same approach.
Lin Wu, Grégoire Broquet, Philippe Ciais, Valentin Bellassen, Felix Vogel, Frédéric Chevallier, Irène Xueref-Remy, and Yilong Wang
Atmos. Chem. Phys., 16, 7743–7771, https://doi.org/10.5194/acp-16-7743-2016, https://doi.org/10.5194/acp-16-7743-2016, 2016
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This paper advances atmospheric inversion of city CO2 emissions as follows: (1) illustrate how inversion methodology can be tailored to deal with very large urban networks of sensors measuring CO2 concentrations; (2) demonstrate that atmospheric inversion could be a relevant tool of Monitoring, Reporting and Verification (MRV) of city CO2 emissions; (3) clarify the theoretical potential of inversion for reducing uncertainties in the estimates of citywide total and sectoral CO2 emissions.
E. Chan, D. Chan, M. Ishizawa, F. Vogel, J. Brioude, A. Delcloo, Y. Wu, and B. Jin
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-22715-2015, https://doi.org/10.5194/acpd-15-22715-2015, 2015
Revised manuscript not accepted
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This paper uses synthetic data experiments to investigate the impacts of different error sources associated with prior flux, transport model and optimisation method on the atmospheric greenhouse gas inverse estimates. Results indicate that estimation errors are dominated by the transport model error and can propagate to the flux estimates non-linearly. It is necessary to obtain stable and realistic results in synthetic data experiments before a real observation-based inversion is performed.
R. Kretschmer, C. Gerbig, U. Karstens, G. Biavati, A. Vermeulen, F. Vogel, S. Hammer, and K. U. Totsche
Atmos. Chem. Phys., 14, 7149–7172, https://doi.org/10.5194/acp-14-7149-2014, https://doi.org/10.5194/acp-14-7149-2014, 2014
Hanyu Liu, Felix R. Vogel, Misa Ishizawa, Zhen Zhang, Benjamin Poulter, Doug E. J. Worthy, Leyang Feng, Anna L. Gagné-Landmann, Ao Chen, Ziting Huang, Dylan C. Gaeta, Joe R. Melton, Douglas Chan, Vineet Yadav, Deborah Huntzinger, and Scot M. Miller
EGUsphere, https://doi.org/10.5194/egusphere-2025-2150, https://doi.org/10.5194/egusphere-2025-2150, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
We find that the state-of-the-art process-based methane flux models have both lower flux magnitude and reduced inter-model uncertainty compared to a previous model inter-comparison from over a decade ago. Despite these improvements, methane flux estimates from process-based models are still likely too high compared to atmospheric observations. We also find that models with simpler parameterizations often result in better agreement with atmospheric observations in high-latitude North America.
Sina Voshtani, Dylan B. A. Jones, Debra Wunch, Drew C. Pendergrass, Paul O. Wennberg, David F. Pollard, Isamu Morino, Hirofumi Ohyama, Nicholas M. Deutscher, Frank Hase, Ralf Sussmann, Damien Weidmann, Rigel Kivi, Omaira García, Yao Té, Jack Chen, Kerry Anderson, Robin Stevens, Shobha Kondragunta, Aihua Zhu, Douglas Worthy, Senen Racki, Kathryn McKain, Maria V. Makarova, Nicholas Jones, Emmanuel Mahieu, Andrea Cadena-Caicedo, Paolo Cristofanelli, Casper Labuschagne, Elena Kozlova, Thomas Seitz, Martin Steinbacher, Reza Mahdi, and Isao Murata
EGUsphere, https://doi.org/10.5194/egusphere-2025-858, https://doi.org/10.5194/egusphere-2025-858, 2025
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We assess the complementarity of the greater temporal coverage provided by ground-based remote sensing data with the spatial coverage of satellite observations when these data are used together to quantify CO emissions from extreme wildfires in 2023. Our results reveal that the commonly used biomass burning emission inventories significantly underestimate the fire emissions and emphasize the importance of the ground-based remote sensing data in reducing uncertainties in the estimated emissions.
Judith Tettenborn, Daniel Zavala-Araiza, Daan Stroeken, Hossein Maazallahi, Carina van der Veen, Arjan Hensen, Ilona Velzeboer, Pim van den Bulk, Felix Vogel, Lawson Gillespie, Sebastien Ars, James France, David Lowry, Rebecca Fisher, and Thomas Röckmann
EGUsphere, https://doi.org/10.5194/egusphere-2024-3620, https://doi.org/10.5194/egusphere-2024-3620, 2025
Short summary
Short summary
Measurements of methane with vehicle-based sensors are an effective method to identify and quantify leaks from urban gas distribution systems. We deliberately released methane in different environments, and calibrated the response of different methane analyzers when they transect the plumes in a vehicle. We derived an improved statistical function for consistent emission estimations using different instruments. Repeated transects reduce the uncertainty in emission rate estimates.
Petr Vodička, Kimitaka Kawamura, Bhagawati Kunwar, Lin Huang, Dhananjay K. Deshmukh, Md. Mozammel Haque, Sangeeta Sharma, and Leonard Barrie
EGUsphere, https://doi.org/10.5194/egusphere-2024-3656, https://doi.org/10.5194/egusphere-2024-3656, 2025
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Carbonate carbon (CC) is not negligible in Arctic total suspended particles (TSP). If not considered, CC biases the contribution of elemental and organic carbon. CC content in TSP was strongly reflected in the δ13C values of total carbon (TC). Carbon contribution from CaCO3 supports strong dependence of CC and δ13C on Ca. Finally, two hypothetical CC sources were identified based on the analysis of air mass back trajectories – dust resuspension and marine microorganisms.
Misa Ishizawa, Douglas Chan, Doug Worthy, Elton Chan, Felix Vogel, Joe R. Melton, and Vivek K. Arora
Atmos. Chem. Phys., 24, 10013–10038, https://doi.org/10.5194/acp-24-10013-2024, https://doi.org/10.5194/acp-24-10013-2024, 2024
Short summary
Short summary
Methane (CH4) emissions in Canada for 2007–2017 were estimated using Canada’s surface greenhouse gas measurements. The estimated emissions show no significant trend, but emission uncertainty was reduced as more measurement sites became available. Notably for climate change, we find the wetland CH4 emissions show a positive correlation with surface air temperature in summer. Canada’s measurement network could monitor future CH4 emission changes and compliance with climate change mitigation goals.
Pramod Kumar, Christopher Caldow, Grégoire Broquet, Adil Shah, Olivier Laurent, Camille Yver-Kwok, Sebastien Ars, Sara Defratyka, Susan Warao Gichuki, Luc Lienhardt, Mathis Lozano, Jean-Daniel Paris, Felix Vogel, Caroline Bouchet, Elisa Allegrini, Robert Kelly, Catherine Juery, and Philippe Ciais
Atmos. Meas. Tech., 17, 1229–1250, https://doi.org/10.5194/amt-17-1229-2024, https://doi.org/10.5194/amt-17-1229-2024, 2024
Short summary
Short summary
This study presents a series of mobile measurement campaigns to monitor the CH4 emissions from an active landfill. These measurements are processed using a Gaussian plume model and atmospheric inversion techniques to quantify the landfill CH4 emissions. The methane emission estimates range between ~0.4 and ~7 t CH4 per day, and their variations are analyzed. The robustness of the estimates is assessed depending on the distance of the measurements from the potential sources in the landfill.
Douglas E. J. Worthy, Michele K. Rauh, Lin Huang, Felix R. Vogel, Alina Chivulescu, Kenneth A. Masarie, Ray L. Langenfelds, Paul B. Krummel, Colin E. Allison, Andrew M. Crotwell, Monica Madronich, Gabrielle Pétron, Ingeborg Levin, Samuel Hammer, Sylvia Michel, Michel Ramonet, Martina Schmidt, Armin Jordan, Heiko Moossen, Michael Rothe, Ralph Keeling, and Eric J. Morgan
Atmos. Meas. Tech., 16, 5909–5935, https://doi.org/10.5194/amt-16-5909-2023, https://doi.org/10.5194/amt-16-5909-2023, 2023
Short summary
Short summary
Network compatibility is important for inferring greenhouse gas fluxes at global or regional scales. This study is the first assessment of the measurement agreement among seven individual programs within the World Meteorological Organization community. It compares co-located flask air measurements at the Alert Observatory in Canada over a 17-year period. The results provide stronger confidence in the uncertainty estimation while using those datasets in various data interpretation applications.
Lawson David Gillespie, Sébastien Ars, James Phillip Williams, Louise Klotz, Tianjie Feng, Stephanie Gu, Mishaal Kandapath, Amy Mann, Michael Raczkowski, Mary Kang, Felix Vogel, and Debra Wunch
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2023-193, https://doi.org/10.5194/amt-2023-193, 2023
Preprint withdrawn
Short summary
Short summary
We investigate techniques for calculating emissions from mobile in situ gas concentrations recorded during downwind plume transects. We find that using the enhancement area to estimate emissions is the most consistent method when comparing different setups and instruments. Observations from a multi year urban methane survey and controlled release experiment are analyzed, and emissions rates for combined sewage overflow basins and a large wastewater treatment plant in Toronto are calculated.
Nasrin Mostafavi Pak, Jacob K. Hedelius, Sébastien Roche, Liz Cunningham, Bianca Baier, Colm Sweeney, Coleen Roehl, Joshua Laughner, Geoffrey Toon, Paul Wennberg, Harrison Parker, Colin Arrowsmith, Joseph Mendonca, Pierre Fogal, Tyler Wizenberg, Beatriz Herrera, Kimberly Strong, Kaley A. Walker, Felix Vogel, and Debra Wunch
Atmos. Meas. Tech., 16, 1239–1261, https://doi.org/10.5194/amt-16-1239-2023, https://doi.org/10.5194/amt-16-1239-2023, 2023
Short summary
Short summary
Ground-based remote sensing instruments in the Total Carbon Column Observing Network (TCCON) measure greenhouse gases in the atmosphere. Consistency between TCCON measurements is crucial to accurately infer changes in atmospheric composition. We use portable remote sensing instruments (EM27/SUN) to evaluate biases between TCCON stations in North America. We also improve the retrievals of EM27/SUN instruments and evaluate the previous (GGG2014) and newest (GGG2020) retrieval algorithms.
Cynthia H. Whaley, Rashed Mahmood, Knut von Salzen, Barbara Winter, Sabine Eckhardt, Stephen Arnold, Stephen Beagley, Silvia Becagli, Rong-You Chien, Jesper Christensen, Sujay Manish Damani, Xinyi Dong, Konstantinos Eleftheriadis, Nikolaos Evangeliou, Gregory Faluvegi, Mark Flanner, Joshua S. Fu, Michael Gauss, Fabio Giardi, Wanmin Gong, Jens Liengaard Hjorth, Lin Huang, Ulas Im, Yugo Kanaya, Srinath Krishnan, Zbigniew Klimont, Thomas Kühn, Joakim Langner, Kathy S. Law, Louis Marelle, Andreas Massling, Dirk Olivié, Tatsuo Onishi, Naga Oshima, Yiran Peng, David A. Plummer, Olga Popovicheva, Luca Pozzoli, Jean-Christophe Raut, Maria Sand, Laura N. Saunders, Julia Schmale, Sangeeta Sharma, Ragnhild Bieltvedt Skeie, Henrik Skov, Fumikazu Taketani, Manu A. Thomas, Rita Traversi, Kostas Tsigaridis, Svetlana Tsyro, Steven Turnock, Vito Vitale, Kaley A. Walker, Minqi Wang, Duncan Watson-Parris, and Tahya Weiss-Gibbons
Atmos. Chem. Phys., 22, 5775–5828, https://doi.org/10.5194/acp-22-5775-2022, https://doi.org/10.5194/acp-22-5775-2022, 2022
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Air pollutants, like ozone and soot, play a role in both global warming and air quality. Atmospheric models are often used to provide information to policy makers about current and future conditions under different emissions scenarios. In order to have confidence in those simulations, in this study we compare simulated air pollution from 18 state-of-the-art atmospheric models to measured air pollution in order to assess how well the models perform.
Carlos Alberti, Frank Hase, Matthias Frey, Darko Dubravica, Thomas Blumenstock, Angelika Dehn, Paolo Castracane, Gregor Surawicz, Roland Harig, Bianca C. Baier, Caroline Bès, Jianrong Bi, Hartmut Boesch, André Butz, Zhaonan Cai, Jia Chen, Sean M. Crowell, Nicholas M. Deutscher, Dragos Ene, Jonathan E. Franklin, Omaira García, David Griffith, Bruno Grouiez, Michel Grutter, Abdelhamid Hamdouni, Sander Houweling, Neil Humpage, Nicole Jacobs, Sujong Jeong, Lilian Joly, Nicholas B. Jones, Denis Jouglet, Rigel Kivi, Ralph Kleinschek, Morgan Lopez, Diogo J. Medeiros, Isamu Morino, Nasrin Mostafavipak, Astrid Müller, Hirofumi Ohyama, Paul I. Palmer, Mahesh Pathakoti, David F. Pollard, Uwe Raffalski, Michel Ramonet, Robbie Ramsay, Mahesh Kumar Sha, Kei Shiomi, William Simpson, Wolfgang Stremme, Youwen Sun, Hiroshi Tanimoto, Yao Té, Gizaw Mengistu Tsidu, Voltaire A. Velazco, Felix Vogel, Masataka Watanabe, Chong Wei, Debra Wunch, Marcia Yamasoe, Lu Zhang, and Johannes Orphal
Atmos. Meas. Tech., 15, 2433–2463, https://doi.org/10.5194/amt-15-2433-2022, https://doi.org/10.5194/amt-15-2433-2022, 2022
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Space-borne greenhouse gas missions require ground-based validation networks capable of providing fiducial reference measurements. Here, considerable refinements of the calibration procedures for the COllaborative Carbon Column Observing Network (COCCON) are presented. Laboratory and solar side-by-side procedures for the characterization of the spectrometers have been refined and extended. Revised calibration factors for XCO2, XCO and XCH4 are provided, incorporating 47 new spectrometers.
Regina Gonzalez Moguel, Felix Vogel, Sébastien Ars, Hinrich Schaefer, Jocelyn C. Turnbull, and Peter M. J. Douglas
Atmos. Chem. Phys., 22, 2121–2133, https://doi.org/10.5194/acp-22-2121-2022, https://doi.org/10.5194/acp-22-2121-2022, 2022
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Evaluating methane (CH4) sources in the Athabasca oil sands region (AOSR) is crucial to effectively mitigate CH4 emissions. We tested the use of carbon isotopes to estimate source contributions from key CH4 sources in the AOSR and found that 56 ± 18 % of CH4 emissions originated from surface mining and processing facilities, 34 ± 18 % from tailings ponds, and 10 ± < 1 % from wetlands, confirming previous findings and showing that this method can be successfully used to partition CH4 sources.
Jessica L. McCarty, Juha Aalto, Ville-Veikko Paunu, Steve R. Arnold, Sabine Eckhardt, Zbigniew Klimont, Justin J. Fain, Nikolaos Evangeliou, Ari Venäläinen, Nadezhda M. Tchebakova, Elena I. Parfenova, Kaarle Kupiainen, Amber J. Soja, Lin Huang, and Simon Wilson
Biogeosciences, 18, 5053–5083, https://doi.org/10.5194/bg-18-5053-2021, https://doi.org/10.5194/bg-18-5053-2021, 2021
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Fires, including extreme fire seasons, and fire emissions are more common in the Arctic. A review and synthesis of current scientific literature find climate change and human activity in the north are fuelling an emerging Arctic fire regime, causing more black carbon and methane emissions within the Arctic. Uncertainties persist in characterizing future fire landscapes, and thus emissions, as well as policy-relevant challenges in understanding, monitoring, and managing Arctic fire regimes.
Lin Huang, Wendy Zhang, Guaciara M. Santos, Blanca T. Rodríguez, Sandra R. Holden, Vincent Vetro, and Claudia I. Czimczik
Atmos. Meas. Tech., 14, 3481–3500, https://doi.org/10.5194/amt-14-3481-2021, https://doi.org/10.5194/amt-14-3481-2021, 2021
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Radiocarbon (14C)-based source apportionment of aerosol carbon fractions requires the physical separation of OC from EC and minimizing of the incorporation of extraneous carbon. Using pure and mixed reference materials ranging in age from modern to fossil, we show that the ECT9 protocol effectively isolates OC and EC. This work expands existing opportunities for characterizing and monitoring sources of carbonaceous aerosols, including µg C-sized samples from the Arctic.
Tuukka Petäjä, Ella-Maria Duplissy, Ksenia Tabakova, Julia Schmale, Barbara Altstädter, Gerard Ancellet, Mikhail Arshinov, Yurii Balin, Urs Baltensperger, Jens Bange, Alison Beamish, Boris Belan, Antoine Berchet, Rossana Bossi, Warren R. L. Cairns, Ralf Ebinghaus, Imad El Haddad, Beatriz Ferreira-Araujo, Anna Franck, Lin Huang, Antti Hyvärinen, Angelika Humbert, Athina-Cerise Kalogridis, Pavel Konstantinov, Astrid Lampert, Matthew MacLeod, Olivier Magand, Alexander Mahura, Louis Marelle, Vladimir Masloboev, Dmitri Moisseev, Vaios Moschos, Niklas Neckel, Tatsuo Onishi, Stefan Osterwalder, Aino Ovaska, Pauli Paasonen, Mikhail Panchenko, Fidel Pankratov, Jakob B. Pernov, Andreas Platis, Olga Popovicheva, Jean-Christophe Raut, Aurélie Riandet, Torsten Sachs, Rosamaria Salvatori, Roberto Salzano, Ludwig Schröder, Martin Schön, Vladimir Shevchenko, Henrik Skov, Jeroen E. Sonke, Andrea Spolaor, Vasileios K. Stathopoulos, Mikko Strahlendorff, Jennie L. Thomas, Vito Vitale, Sterios Vratolis, Carlo Barbante, Sabine Chabrillat, Aurélien Dommergue, Konstantinos Eleftheriadis, Jyri Heilimo, Kathy S. Law, Andreas Massling, Steffen M. Noe, Jean-Daniel Paris, André S. H. Prévôt, Ilona Riipinen, Birgit Wehner, Zhiyong Xie, and Hanna K. Lappalainen
Atmos. Chem. Phys., 20, 8551–8592, https://doi.org/10.5194/acp-20-8551-2020, https://doi.org/10.5194/acp-20-8551-2020, 2020
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The role of polar regions is increasing in terms of megatrends such as globalization, new transport routes, demography, and the use of natural resources with consequent effects on regional and transported pollutant concentrations. Here we summarize initial results from our integrative project exploring the Arctic environment and pollution to deliver data products, metrics, and indicators for stakeholders.
Claudia Grossi, Scott D. Chambers, Olivier Llido, Felix R. Vogel, Victor Kazan, Alessandro Capuana, Sylvester Werczynski, Roger Curcoll, Marc Delmotte, Arturo Vargas, Josep-Anton Morguí, Ingeborg Levin, and Michel Ramonet
Atmos. Meas. Tech., 13, 2241–2255, https://doi.org/10.5194/amt-13-2241-2020, https://doi.org/10.5194/amt-13-2241-2020, 2020
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The sustainable support of radon metrology at the environmental level offers new scientific possibilities for the quantification of greenhouse gas (GHG) emissions and the determination of their source terms as well as for the identification of radioactive sources for the assessment of radiation exposure. This study helps to harmonize the techniques commonly used for atmospheric radon and radon progeny activity concentration measurements.
Tak W. Chan, Lin Huang, Kulbir Banwait, Wendy Zhang, Darrell Ernst, Xiaoliang Wang, John G. Watson, Judith C. Chow, Mark Green, Claudia I. Czimczik, Guaciara M. Santos, Sangeeta Sharma, and Keith Jones
Atmos. Meas. Tech., 12, 4543–4560, https://doi.org/10.5194/amt-12-4543-2019, https://doi.org/10.5194/amt-12-4543-2019, 2019
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This study compared 10 years of carbonaceous aerosol measurements collected at Egbert by three North American long-term monitoring networks. The study evaluated how differences in sample collection and analysis affected the concentrations of total carbon (TC), organic carbon (OC), and elemental carbon (EC). Various carbonaceous fractions measured by the three networks were consistent and comparable over the period. Elevated OC and EC were observed when ambient temperature exceeded 10 °C.
Emmanuel Arzoumanian, Felix R. Vogel, Ana Bastos, Bakhram Gaynullin, Olivier Laurent, Michel Ramonet, and Philippe Ciais
Atmos. Meas. Tech., 12, 2665–2677, https://doi.org/10.5194/amt-12-2665-2019, https://doi.org/10.5194/amt-12-2665-2019, 2019
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We tested commercial lower-cost CO2 sensors in laboratory and field studies to see if they can measure atmospheric CO2 mole fractions with less than 1 ppm bias (with monthly calibration), to allow continuous urban CO2 monitoring.
We find that the sensors' CO2 readings are influenced by temperature, atmospheric pressure and water vapour content, but this can be corrected for by adding sensors (T, p, RH) and carefully calibrating each sensor against a high-precision instrument.
Marina Saccon, Anna Kornilova, Lin Huang, and Jochen Rudolph
Atmos. Chem. Phys., 19, 5495–5509, https://doi.org/10.5194/acp-19-5495-2019, https://doi.org/10.5194/acp-19-5495-2019, 2019
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As compound are emitted into the atmosphere, they can undergo chemical reactions to produce secondary products. This paper investigates the relations of compounds' unique chemical characteristics to the processes that formed them from emissions in the atmosphere. A model is applied to help with this investigation. The complexity of the atmosphere, including mixing of air masses and variability in precursor reactivity, is taken into consideration, and results are presented.
Heike Wex, Lin Huang, Wendy Zhang, Hayley Hung, Rita Traversi, Silvia Becagli, Rebecca J. Sheesley, Claire E. Moffett, Tate E. Barrett, Rossana Bossi, Henrik Skov, Anja Hünerbein, Jasmin Lubitz, Mareike Löffler, Olivia Linke, Markus Hartmann, Paul Herenz, and Frank Stratmann
Atmos. Chem. Phys., 19, 5293–5311, https://doi.org/10.5194/acp-19-5293-2019, https://doi.org/10.5194/acp-19-5293-2019, 2019
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We found an annual cycle for ice-nucleating particles in the Arctic. These particles are important for Arctic clouds, as they can change the lifetime of clouds. We suggest that higher concentrations of these particles in summertime originate from the Arctic biosphere (both marine and terrestrial). With a warming Arctic, these concentrations may increase further, influencing aerosol–cloud interactions and therewith the observed strong warming of the Arctic.
Misa Ishizawa, Douglas Chan, Doug Worthy, Elton Chan, Felix Vogel, and Shamil Maksyutov
Atmos. Chem. Phys., 19, 4637–4658, https://doi.org/10.5194/acp-19-4637-2019, https://doi.org/10.5194/acp-19-4637-2019, 2019
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The Canadian Arctic has the potential for enhanced methane (CH4) emissions under global warming. However, the regional CH4 emission (fluxes) estimates range widely. This study analyzes recent Canadian Arctic CH4 observations and estimates the regional emissions. The additional observations yield robust CH4 flux estimates and enable the partitioning of the CH4 sources into wetland and forest fires. The results indicate that years with warmer summer conditions result in more wetland CH4 emissions.
Felix R. Vogel, Matthias Frey, Johannes Staufer, Frank Hase, Grégoire Broquet, Irène Xueref-Remy, Frédéric Chevallier, Philippe Ciais, Mahesh Kumar Sha, Pascale Chelin, Pascal Jeseck, Christof Janssen, Yao Té, Jochen Groß, Thomas Blumenstock, Qiansi Tu, and Johannes Orphal
Atmos. Chem. Phys., 19, 3271–3285, https://doi.org/10.5194/acp-19-3271-2019, https://doi.org/10.5194/acp-19-3271-2019, 2019
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Providing timely information on greenhouse gas emissions to stakeholders at sub-national scale is an emerging challenge and understanding urban CO2 levels is one key aspect. This study uses atmospheric observations of total column CO2 and compares them to numerical simulations to investigate CO2 levels in the Paris metropolitan area due to natural fluxes and anthropogenic emissions. Our measurements reveal the influence of locally added CO2, which our model is also able to predict.
Matthias Frey, Mahesh K. Sha, Frank Hase, Matthäus Kiel, Thomas Blumenstock, Roland Harig, Gregor Surawicz, Nicholas M. Deutscher, Kei Shiomi, Jonathan E. Franklin, Hartmut Bösch, Jia Chen, Michel Grutter, Hirofumi Ohyama, Youwen Sun, André Butz, Gizaw Mengistu Tsidu, Dragos Ene, Debra Wunch, Zhensong Cao, Omaira Garcia, Michel Ramonet, Felix Vogel, and Johannes Orphal
Atmos. Meas. Tech., 12, 1513–1530, https://doi.org/10.5194/amt-12-1513-2019, https://doi.org/10.5194/amt-12-1513-2019, 2019
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In a 3.5-year long study, the long-term performance of a mobile EM27/SUN spectrometer, used for greenhouse gas observations, is checked with respect to a co-located reference spectrometer. We find that the EM27/SUN is stable on timescales of several years, qualifying it for permanent carbon cycle studies.
The performance of an ensemble of 30 EM27/SUN spectrometers was also tested in the framework of the COllaborative Carbon Column Observing Network (COCCON) and found to be very uniform.
Betty Croft, Randall V. Martin, W. Richard Leaitch, Julia Burkart, Rachel Y.-W. Chang, Douglas B. Collins, Patrick L. Hayes, Anna L. Hodshire, Lin Huang, John K. Kodros, Alexander Moravek, Emma L. Mungall, Jennifer G. Murphy, Sangeeta Sharma, Samantha Tremblay, Gregory R. Wentworth, Megan D. Willis, Jonathan P. D. Abbatt, and Jeffrey R. Pierce
Atmos. Chem. Phys., 19, 2787–2812, https://doi.org/10.5194/acp-19-2787-2019, https://doi.org/10.5194/acp-19-2787-2019, 2019
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Summertime Arctic atmospheric aerosols are strongly controlled by processes related to natural regional sources. We use a chemical transport model with size-resolved aerosol microphysics to interpret measurements made during summertime 2016 in the Canadian Arctic Archipelago. Our results explore the processes that control summertime aerosol size distributions and support a climate-relevant role for Arctic marine secondary organic aerosol formed from precursor vapors with Arctic marine sources.
Jonathan P. D. Abbatt, W. Richard Leaitch, Amir A. Aliabadi, Allan K. Bertram, Jean-Pierre Blanchet, Aude Boivin-Rioux, Heiko Bozem, Julia Burkart, Rachel Y. W. Chang, Joannie Charette, Jai P. Chaubey, Robert J. Christensen, Ana Cirisan, Douglas B. Collins, Betty Croft, Joelle Dionne, Greg J. Evans, Christopher G. Fletcher, Martí Galí, Roya Ghahreman, Eric Girard, Wanmin Gong, Michel Gosselin, Margaux Gourdal, Sarah J. Hanna, Hakase Hayashida, Andreas B. Herber, Sareh Hesaraki, Peter Hoor, Lin Huang, Rachel Hussherr, Victoria E. Irish, Setigui A. Keita, John K. Kodros, Franziska Köllner, Felicia Kolonjari, Daniel Kunkel, Luis A. Ladino, Kathy Law, Maurice Levasseur, Quentin Libois, John Liggio, Martine Lizotte, Katrina M. Macdonald, Rashed Mahmood, Randall V. Martin, Ryan H. Mason, Lisa A. Miller, Alexander Moravek, Eric Mortenson, Emma L. Mungall, Jennifer G. Murphy, Maryam Namazi, Ann-Lise Norman, Norman T. O'Neill, Jeffrey R. Pierce, Lynn M. Russell, Johannes Schneider, Hannes Schulz, Sangeeta Sharma, Meng Si, Ralf M. Staebler, Nadja S. Steiner, Jennie L. Thomas, Knut von Salzen, Jeremy J. B. Wentzell, Megan D. Willis, Gregory R. Wentworth, Jun-Wei Xu, and Jacqueline D. Yakobi-Hancock
Atmos. Chem. Phys., 19, 2527–2560, https://doi.org/10.5194/acp-19-2527-2019, https://doi.org/10.5194/acp-19-2527-2019, 2019
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The Arctic is experiencing considerable environmental change with climate warming, illustrated by the dramatic decrease in sea-ice extent. It is important to understand both the natural and perturbed Arctic systems to gain a better understanding of how they will change in the future. This paper summarizes new insights into the relationships between Arctic aerosol particles and climate, as learned over the past five or so years by a large Canadian research consortium, NETCARE.
Wanmin Gong, Stephen R. Beagley, Sophie Cousineau, Mourad Sassi, Rodrigo Munoz-Alpizar, Sylvain Ménard, Jacinthe Racine, Junhua Zhang, Jack Chen, Heather Morrison, Sangeeta Sharma, Lin Huang, Pascal Bellavance, Jim Ly, Paul Izdebski, Lynn Lyons, and Richard Holt
Atmos. Chem. Phys., 18, 16653–16687, https://doi.org/10.5194/acp-18-16653-2018, https://doi.org/10.5194/acp-18-16653-2018, 2018
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The navigability of the Arctic Ocean is increasing with the warming in recent years. Using model simulations at a much finer resolution than previous pan-Arctic studies, the impact of marine shipping emissions on air pollution in the Canadian Arctic is assessed for present (2010) and projected levels in 2030. The study found that shipping emissions have a local-to-regional impact in the Arctic at the current level; the impact will increase significantly in a projected business-as-usual scenario.
Claudia Grossi, Felix R. Vogel, Roger Curcoll, Alba Àgueda, Arturo Vargas, Xavier Rodó, and Josep-Anton Morguí
Atmos. Chem. Phys., 18, 5847–5860, https://doi.org/10.5194/acp-18-5847-2018, https://doi.org/10.5194/acp-18-5847-2018, 2018
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To gain a full picture of the Spanish (and European) GHG balance, understanding of CH4 emissions in different regions is a critical challenge, as is the improvement of bottom-up inventories for all European regions. This study uses, among other elements, GHG, meteorological and 222Rn tracer data from a Spanish region to understand the main causes of temporal variability of GHG mixing ratios. The study can offer new insights into regional emissions by identifying the impacts of changing sources.
Yilong Wang, Grégoire Broquet, Philippe Ciais, Frédéric Chevallier, Felix Vogel, Lin Wu, Yi Yin, Rong Wang, and Shu Tao
Atmos. Chem. Phys., 18, 4229–4250, https://doi.org/10.5194/acp-18-4229-2018, https://doi.org/10.5194/acp-18-4229-2018, 2018
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This paper assesses the potential of atmospheric 14CO2 observations and a global inversion system to solve for fossil fuel CO2 (FFCO2) emissions in Europe. The estimate of monthly emission budgets is largely improved in high emitting regions. The results are sensitive to the observation network and the prior uncertainty. Using a high-resolution transport model and a systematic evaluation of the uncertainty in current emission inventories should improve the potential to retrieve FFCO2 emissions.
Katrina M. Macdonald, Sangeeta Sharma, Desiree Toom, Alina Chivulescu, Andrew Platt, Mike Elsasser, Lin Huang, Richard Leaitch, Nathan Chellman, Joseph R. McConnell, Heiko Bozem, Daniel Kunkel, Ying Duan Lei, Cheol-Heon Jeong, Jonathan P. D. Abbatt, and Greg J. Evans
Atmos. Chem. Phys., 18, 3485–3503, https://doi.org/10.5194/acp-18-3485-2018, https://doi.org/10.5194/acp-18-3485-2018, 2018
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The sources of key contaminants in Arctic snow may be an important factor in understanding the rapid climate changes observed in the Arctic. Fresh snow samples collected frequently through the winter season were analyzed for major constituents. Temporally refined source apportionment via positive matrix factorization in conjunction with FLEXPART suggested potential source characteristics and locations. The identity of these sources and their relative contribution to key analytes is discussed.
Stephanie C. Pugliese, Jennifer G. Murphy, Felix R. Vogel, Michael D. Moran, Junhua Zhang, Qiong Zheng, Craig A. Stroud, Shuzhan Ren, Douglas Worthy, and Gregoire Broquet
Atmos. Chem. Phys., 18, 3387–3401, https://doi.org/10.5194/acp-18-3387-2018, https://doi.org/10.5194/acp-18-3387-2018, 2018
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We developed the Southern Ontario CO2 Emissions (SOCE) inventory, which identifies the spatial and temporal distribution (2.5 km and hourly, respectively) of CO2 emissions from seven source sectors. When the SOCE inventory was used with a chemistry transport model, we found strong agreement between modelled and measured mixing ratios. We were able to quantify that natural gas combustion contributes > 80 % of CO2 emissions at nighttime while on-road emissions contribute > 70 % during the day.
W. Richard Leaitch, Lynn M. Russell, Jun Liu, Felicia Kolonjari, Desiree Toom, Lin Huang, Sangeeta Sharma, Alina Chivulescu, Dan Veber, and Wendy Zhang
Atmos. Chem. Phys., 18, 3269–3287, https://doi.org/10.5194/acp-18-3269-2018, https://doi.org/10.5194/acp-18-3269-2018, 2018
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Over 2 years of atmospheric aerosol organic functional group and microphysics measurements at the world's northernmost land observatory offer a unique high-latitude dataset. Lower organic mass (OM) concentrations and higher OM fractions accompany smaller particles during summer, with opposite results during winter to spring. Seasonally, the OM oxidation level is highest in winter, associated with primary marine alcohol groups. In summer, secondary processes dominate the marine influence on OM.
Sangeeta Sharma, W. Richard Leaitch, Lin Huang, Daniel Veber, Felicia Kolonjari, Wendy Zhang, Sarah J. Hanna, Allan K. Bertram, and John A. Ogren
Atmos. Chem. Phys., 17, 15225–15243, https://doi.org/10.5194/acp-17-15225-2017, https://doi.org/10.5194/acp-17-15225-2017, 2017
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A new and unique data set on BC properties at the highest latitude observatory in the world, at Alert, Canada, evaluates three techniques for estimating black carbon (BC) and gives seasonal best estimates of the BC mass concentrations and BC mass absorption coefficients (MAC) for 2.5 years of data. As a short-lived climate forcer, better estimates of the properties of BC are necessary to ensure accurate modelling of aerosol climate forcing of the Arctic atmosphere for mitigation purposes.
Jun-Wei Xu, Randall V. Martin, Andrew Morrow, Sangeeta Sharma, Lin Huang, W. Richard Leaitch, Julia Burkart, Hannes Schulz, Marco Zanatta, Megan D. Willis, Daven K. Henze, Colin J. Lee, Andreas B. Herber, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 17, 11971–11989, https://doi.org/10.5194/acp-17-11971-2017, https://doi.org/10.5194/acp-17-11971-2017, 2017
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We interpret a series of recent airborne and ground-based measurements with the GEOS-Chem model and its adjoint to attribute the sources of Arctic BC. Anthropogenic emissions in eastern and southern Asia make the largest contribution to Arctic BC. Gas flaring emissions from oilfields in western Siberia and from the Tarim oilfield in western China could have striking impacts on Arctic BC loadings.
Sabina Assan, Alexia Baudic, Ali Guemri, Philippe Ciais, Valerie Gros, and Felix R. Vogel
Atmos. Meas. Tech., 10, 2077–2091, https://doi.org/10.5194/amt-10-2077-2017, https://doi.org/10.5194/amt-10-2077-2017, 2017
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This study is dedicated to improving measurement methods when using a Cavity Ring Down Spectroscopy instrument to measure methane at sites with elevated ethane concentrations such as Oil and Gas sites. The research was undertaken after measurements of natural gas samples suggested biased δ13CH4 results. Two instruments were extensively tested to characterize the cross sensitivities to ethane and δ13CH4 and propose corrections. Results indicate that it is imperative to account for the biases.
Katrina M. Macdonald, Sangeeta Sharma, Desiree Toom, Alina Chivulescu, Sarah Hanna, Allan K. Bertram, Andrew Platt, Mike Elsasser, Lin Huang, David Tarasick, Nathan Chellman, Joseph R. McConnell, Heiko Bozem, Daniel Kunkel, Ying Duan Lei, Greg J. Evans, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 17, 5775–5788, https://doi.org/10.5194/acp-17-5775-2017, https://doi.org/10.5194/acp-17-5775-2017, 2017
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Rapid climate changes within the Arctic have highlighted existing uncertainties in the transport of contaminants to Arctic snow. Fresh snow samples collected frequently through the winter season were analyzed for major constituents creating a unique record of Arctic snow. Comparison with simultaneous atmospheric measurements provides insight into the driving processes in the transfer of contaminants from air to snow. The relative importance of deposition mechanisms over the season is proposed.
Andrew D. Teakles, Rita So, Bruce Ainslie, Robert Nissen, Corinne Schiller, Roxanne Vingarzan, Ian McKendry, Anne Marie Macdonald, Daniel A. Jaffe, Allan K. Bertram, Kevin B. Strawbridge, W. Richard Leaitch, Sarah Hanna, Desiree Toom, Jonathan Baik, and Lin Huang
Atmos. Chem. Phys., 17, 2593–2611, https://doi.org/10.5194/acp-17-2593-2017, https://doi.org/10.5194/acp-17-2593-2017, 2017
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We present a case study of an intense wildfire smoke plume from Siberia that affected the air quality across the Pacific Northwest on 6–10 July 2012. The transport, entrainment, and chemical composition of the plume are examined to characterize the event. Ambient O3 and PM2.5 from surface monitoring is contrast to modelled baseline air quality estimates to show the overall contribution of the plume to exceedances in O3 and PM2.5 air quality standards and objectives that occurred.
Lamia Ammoura, Irène Xueref-Remy, Felix Vogel, Valérie Gros, Alexia Baudic, Bernard Bonsang, Marc Delmotte, Yao Té, and Frédéric Chevallier
Atmos. Chem. Phys., 16, 15653–15664, https://doi.org/10.5194/acp-16-15653-2016, https://doi.org/10.5194/acp-16-15653-2016, 2016
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We propose a new approach to estimate urban emission ratios that takes advantage of the enhanced local urban signal in the atmosphere at low wind speed. We apply it to estimate monthly ratios between CO2, CO and some VOCs from atmospheric measurement datasets acquired in the centre of Paris between 2010 and 2014. We find that this approach is little sensitive to the regional background level definition. With this new method, we may reveal spatial and seasonal variability in the ratios in Paris.
Elton Chan, Douglas Chan, Misa Ishizawa, Felix Vogel, Jerome Brioude, Andy Delcloo, Yuehua Wu, and Baisuo Jin
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2016-213, https://doi.org/10.5194/gmd-2016-213, 2016
Revised manuscript not accepted
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The main objective of this study is to examine the impacts of errors introduced by different components in our newly developed inversion system on flux estimates with a series of controlled experiments. It is very critical for any inversion system to be fully evaluated prior to applying to real observations. As demonstrated, the results can be very sensitive to the model setup and region. It is not reasonable to expect realistic results can always be obtained using the same approach.
Anna Kornilova, Lin Huang, Marina Saccon, and Jochen Rudolph
Atmos. Chem. Phys., 16, 11755–11772, https://doi.org/10.5194/acp-16-11755-2016, https://doi.org/10.5194/acp-16-11755-2016, 2016
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The photochemical oxidation of organic compounds in the atmosphere results in the formation of important secondary pollutants such as ozone and fine particles. The extent of oxidation the organic compounds have been subjected too since there emissions is essential is key for understanding the formation of secondary pollutants. This paper demonstrates that measurements of the carbon isotope ratios allow determining the extent of photochemical processing for individual compounds.
Lin Wu, Grégoire Broquet, Philippe Ciais, Valentin Bellassen, Felix Vogel, Frédéric Chevallier, Irène Xueref-Remy, and Yilong Wang
Atmos. Chem. Phys., 16, 7743–7771, https://doi.org/10.5194/acp-16-7743-2016, https://doi.org/10.5194/acp-16-7743-2016, 2016
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This paper advances atmospheric inversion of city CO2 emissions as follows: (1) illustrate how inversion methodology can be tailored to deal with very large urban networks of sensors measuring CO2 concentrations; (2) demonstrate that atmospheric inversion could be a relevant tool of Monitoring, Reporting and Verification (MRV) of city CO2 emissions; (3) clarify the theoretical potential of inversion for reducing uncertainties in the estimates of citywide total and sectoral CO2 emissions.
Antoine Berchet, Philippe Bousquet, Isabelle Pison, Robin Locatelli, Frédéric Chevallier, Jean-Daniel Paris, Ed J. Dlugokencky, Tuomas Laurila, Juha Hatakka, Yrjo Viisanen, Doug E. J. Worthy, Euan Nisbet, Rebecca Fisher, James France, David Lowry, Viktor Ivakhov, and Ove Hermansen
Atmos. Chem. Phys., 16, 4147–4157, https://doi.org/10.5194/acp-16-4147-2016, https://doi.org/10.5194/acp-16-4147-2016, 2016
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We propose insights based on atmospheric observations around the Arctic circle to evaluate estimates of methane emissions to the atmosphere from the East Siberian Arctic Shelf. Based on a comprehensive statistical analysis of the observations and of high-resolution transport simulations, annual methane emissions from ESAS are estimated to range from 0.0 to 4.5 TgCH4 yr−1, with a maximum in summer and very low emissions in winter.
Scot M. Miller, Roisin Commane, Joe R. Melton, Arlyn E. Andrews, Joshua Benmergui, Edward J. Dlugokencky, Greet Janssens-Maenhout, Anna M. Michalak, Colm Sweeney, and Doug E. J. Worthy
Biogeosciences, 13, 1329–1339, https://doi.org/10.5194/bg-13-1329-2016, https://doi.org/10.5194/bg-13-1329-2016, 2016
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We use atmospheric data from the US and Canada to examine seven wetland methane flux estimates. Relative to existing estimates, we find a methane source that is smaller in magnitude with a broader seasonal cycle. Furthermore, we estimate the largest fluxes over the Hudson Bay Lowlands, a spatial distribution that differs from commonly used remote sensing estimates of wetland location.
M. Saccon, A. Kornilova, L. Huang, S. Moukhtar, and J. Rudolph
Atmos. Chem. Phys., 15, 10825–10838, https://doi.org/10.5194/acp-15-10825-2015, https://doi.org/10.5194/acp-15-10825-2015, 2015
E. Chan, D. Chan, M. Ishizawa, F. Vogel, J. Brioude, A. Delcloo, Y. Wu, and B. Jin
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-22715-2015, https://doi.org/10.5194/acpd-15-22715-2015, 2015
Revised manuscript not accepted
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This paper uses synthetic data experiments to investigate the impacts of different error sources associated with prior flux, transport model and optimisation method on the atmospheric greenhouse gas inverse estimates. Results indicate that estimation errors are dominated by the transport model error and can propagate to the flux estimates non-linearly. It is necessary to obtain stable and realistic results in synthetic data experiments before a real observation-based inversion is performed.
S. Eckhardt, B. Quennehen, D. J. L. Olivié, T. K. Berntsen, R. Cherian, J. H. Christensen, W. Collins, S. Crepinsek, N. Daskalakis, M. Flanner, A. Herber, C. Heyes, Ø. Hodnebrog, L. Huang, M. Kanakidou, Z. Klimont, J. Langner, K. S. Law, M. T. Lund, R. Mahmood, A. Massling, S. Myriokefalitakis, I. E. Nielsen, J. K. Nøjgaard, J. Quaas, P. K. Quinn, J.-C. Raut, S. T. Rumbold, M. Schulz, S. Sharma, R. B. Skeie, H. Skov, T. Uttal, K. von Salzen, and A. Stohl
Atmos. Chem. Phys., 15, 9413–9433, https://doi.org/10.5194/acp-15-9413-2015, https://doi.org/10.5194/acp-15-9413-2015, 2015
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The concentrations of sulfate, black carbon and other aerosols in the Arctic are characterized by high values in late winter and spring (so-called Arctic Haze) and low values in summer. Models have long been struggling to capture this seasonality. In this study, we evaluate sulfate and BC concentrations from different updated models and emissions against a comprehensive pan-Arctic measurement data set. We find that the models improved but still struggle to get the maximum concentrations.
A. Kornilova, S. Moukhtar, M. Saccon, L. Huang, W. Zhang, and J. Rudolph
Atmos. Meas. Tech., 8, 2301–2313, https://doi.org/10.5194/amt-8-2301-2015, https://doi.org/10.5194/amt-8-2301-2015, 2015
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A technique for compound specific analysis of stable carbon isotope ratios and concentration of ambient volatile organic compounds (VOC) is presented. It is based on selective VOC sampling onto adsorbent filled cartridges. Examples of measurements conducted demonstrate that the ability to make accurate measurements in air with low VOC mixing ratios is important to avoid bias from an overrepresentation of samples that are strongly impacted by recent emissions.
R. Zhao, A. K. Y. Lee, L. Huang, X. Li, F. Yang, and J. P. D. Abbatt
Atmos. Chem. Phys., 15, 6087–6100, https://doi.org/10.5194/acp-15-6087-2015, https://doi.org/10.5194/acp-15-6087-2015, 2015
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Aqueous-phase photochemical decay of light absorbing organic compounds, or atmospheric brown carbon (BrC), is investigated in this study. The absorptive change of laboratory surrogates of BrC, as well as biofuel combustion samples, were monitored during photolysis and OH oxidation experiments. The major finding is the rapid change in the absorptivity of BrC during such photochemical processing. This change should be taken into account to evaluate the importance of BrC in the atmosphere.
L. Bruhwiler, E. Dlugokencky, K. Masarie, M. Ishizawa, A. Andrews, J. Miller, C. Sweeney, P. Tans, and D. Worthy
Atmos. Chem. Phys., 14, 8269–8293, https://doi.org/10.5194/acp-14-8269-2014, https://doi.org/10.5194/acp-14-8269-2014, 2014
E. Sepúlveda, M. Schneider, F. Hase, S. Barthlott, D. Dubravica, O. E. García, A. Gomez-Pelaez, Y. González, J. C. Guerra, M. Gisi, R. Kohlhepp, S. Dohe, T. Blumenstock, K. Strong, D. Weaver, M. Palm, A. Sadeghi, N. M. Deutscher, T. Warneke, J. Notholt, N. Jones, D. W. T. Griffith, D. Smale, G. W. Brailsford, J. Robinson, F. Meinhardt, M. Steinbacher, T. Aalto, and D. Worthy
Atmos. Meas. Tech., 7, 2337–2360, https://doi.org/10.5194/amt-7-2337-2014, https://doi.org/10.5194/amt-7-2337-2014, 2014
R. Kretschmer, C. Gerbig, U. Karstens, G. Biavati, A. Vermeulen, F. Vogel, S. Hammer, and K. U. Totsche
Atmos. Chem. Phys., 14, 7149–7172, https://doi.org/10.5194/acp-14-7149-2014, https://doi.org/10.5194/acp-14-7149-2014, 2014
B. D. Hall, A. Engel, J. Mühle, J. W. Elkins, F. Artuso, E. Atlas, M. Aydin, D. Blake, E.-G. Brunke, S. Chiavarini, P. J. Fraser, J. Happell, P. B. Krummel, I. Levin, M. Loewenstein, M. Maione, S. A. Montzka, S. O'Doherty, S. Reimann, G. Rhoderick, E. S. Saltzman, H. E. Scheel, L. P. Steele, M. K. Vollmer, R. F. Weiss, D. Worthy, and Y. Yokouchi
Atmos. Meas. Tech., 7, 469–490, https://doi.org/10.5194/amt-7-469-2014, https://doi.org/10.5194/amt-7-469-2014, 2014
M. Saccon, R. Busca, C. Facca, L. Huang, S. Irei, A. Kornilova, D. Lane, and J. Rudolph
Atmos. Meas. Tech., 6, 2965–2974, https://doi.org/10.5194/amt-6-2965-2013, https://doi.org/10.5194/amt-6-2965-2013, 2013
S. Basu, S. Guerlet, A. Butz, S. Houweling, O. Hasekamp, I. Aben, P. Krummel, P. Steele, R. Langenfelds, M. Torn, S. Biraud, B. Stephens, A. Andrews, and D. Worthy
Atmos. Chem. Phys., 13, 8695–8717, https://doi.org/10.5194/acp-13-8695-2013, https://doi.org/10.5194/acp-13-8695-2013, 2013
Related subject area
Subject: Gases | Technique: In Situ Measurement | Topic: Instruments and Platforms
A modular approach to volatile organic compound samplers for tethered balloon and drone platforms
Performance validation and calibration conditions for novel dynamic baseline tracking air sensors in long-term field monitoring
Observation of greenhouse gas vertical profiles in the boundary layer of the Mount Qomolangma region using a multirotor UAV
Description and Validation of a Carbon Monoxide and Nitrous Oxide Instrument for High-Altitude Airborne Science (COMA)
Development of a portable laser-flash photolysis Faraday rotation spectrometer for measuring atmospheric total OH reactivity
Surface distributions and vertical profiles of trace gases (CO, O3, NO, NO2) in the Arctic wintertime boundary layer using low-cost sensors during ALPACA-2022
Advances in an OH reactivity instrument for airborne field measurements
The ASK-16 motorized glider: an airborne eddy covariance platform to measure turbulence, energy, and matter fluxes
Development of a Peltier-based chilled-mirror hygrometer, SKYDEW, for tropospheric and lower-stratospheric water vapor measurements
Vertical distribution of halogenated trace gases in the summer Arctic stratosphere determined by two independent in situ methods
Deployment and evaluation of an NH4+∕ H3O+ reagent ion switching chemical ionization mass spectrometer for the detection of reduced and oxygenated gas-phase organic compounds
An economical tunable diode laser spectrometer for fast-response measurements of water vapor in the atmospheric boundary layer
Eddy covariance with slow-response greenhouse gas analysers on tall towers: bridging atmospheric and ecosystem greenhouse gas networks
An overview of outdoor low-cost gas-phase air quality sensor deployments: current efforts, trends, and limitations
Multiphysical description of atmospheric pressure interface chemical ionisation in MION2 and Eisele type inlets
Development of a Forced Advection Sampling Technique (FAST) for Quantification of Methane Emissions from Orphaned Wells
A portable nitrogen dioxide instrument using cavity-enhanced absorption spectroscopy
Development and deployment of a mid-cost CO2 sensor monitoring network to support atmospheric inverse modeling for quantifying urban CO2 emissions in Paris
UAV-based in situ measurements of CO2 and CH4 fluxes over complex natural ecosystems
A new aerial approach for quantifying and attributing methane emissions: implementation and validation
Drone CO2 measurements during the Tajogaite volcanic eruption
Multi-decadal atmospheric carbon dioxide measurements in Hungary, central Europe
Reliable water vapour isotopic composition measurements at low humidity using frequency-stabilised cavity ring-down spectroscopy
On Path Length, Beam Divergence, and Retroreflector Array Size in Open-Path FTIR Spectroscopy
A measurement system for CO2 and CH4 emissions quantification of industrial sites using a new in situ concentration sensor operated on board uncrewed aircraft vehicles
Using metal oxide gas sensors to estimate the emission rates and locations of methane leaks in an industrial site: assessment with controlled methane releases
Toward on-demand measurements of greenhouse gas emissions using an uncrewed aircraft AirCore system
An easy-to-use water vapor sampling approach for stable isotope analysis using affordable membrane valve multi-foil bags
Long-term evaluation of commercial air quality sensors: an overview from the QUANT (Quantification of Utility of Atmospheric Network Technologies) study
In-flight characterization of a compact airborne quantum cascade laser absorption spectrometer
Full characterization and calibration of a transfer standard monitor for atmospheric radon measurements
Observing low-altitude features in ozone concentrations in a shoreline environment via uncrewed aerial systems
An integrated uncrewed aerial vehicle platform with sensing and sampling systems for the measurement of air pollutant concentrations
Design and evaluation of a low-cost sensor node for near-background methane measurement
Development of a Multichannel Organics In situ enviRonmental Analyzer (MOIRA) for mobile measurements of volatile organic compounds
Evaluation of Aeris mid-infrared absorption (MIRA), Picarro CRDS (cavity ring-down spectroscopy) G2307, and dinitrophenylhydrazine (DNPH)-based sampling for long-term formaldehyde monitoring efforts
Performance characterization of a laminar gas inlet
Validation and field application of a low-cost device to measure CO2 and evapotranspiration (ET) fluxes
Identifying and correcting interferences to PTR-ToF-MS measurements of isoprene and other urban volatile organic compounds
Development of a continuous UAV-mounted air sampler and application to the quantification of CO2 and CH4 emissions from a major coking plant
Uptake behavior of polycyclic aromatic compounds during field calibrations of the XAD-based passive air sampler across seasons and locations
Effect of land–sea air mass transport on spatiotemporal distributions of atmospheric CO2 and CH4 mixing ratios over the southern Yellow Sea
HYPHOP: a tool for high-altitude, long-range monitoring of hydrogen peroxide and higher organic peroxides in the atmosphere
Portable, low-cost samplers for distributed sampling of atmospheric gases
SI-traceable validation of a laser spectrometer for balloon-borne measurements of water vapor in the upper atmosphere
Field evaluation of low-cost electrochemical air quality gas sensors under extreme temperature and relative humidity conditions
A novel, cost-effective analytical method for measuring high-resolution vertical profiles of stratospheric trace gases using a gas chromatograph coupled with an electron capture detector
Ethylene oxide monitor with part-per-trillion precision for in situ measurements
Development of an automated pump-efficiency measuring system for ozonesondes utilizing an airbag-type flowmeter
Short-term variability of atmospheric helium revealed through a cryo-enrichment method
Meghan Guagenti, Darielle Dexheimer, Alexandra Ulinksi, Paul Walter, James H. Flynn III, and Sascha Usenko
Atmos. Meas. Tech., 18, 2125–2136, https://doi.org/10.5194/amt-18-2125-2025, https://doi.org/10.5194/amt-18-2125-2025, 2025
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A robust, automatic volatile organic compound (VOC) collection system was developed for vertical VOC sampling associated with the 2022 DOE ARM-program-led TRACER in Houston, Texas. This modular sampler has been developed to measure vertical profiles of VOCs to improve near-surface characterization. This article helps fill the current lack of commercially available options for aerial VOC sampling and serves to support and encourage researchers to build and develop custom samplers.
Han Mei, Peng Wei, Meisam Ahmadi Ghadikolaei, Nirmal Kumar Gali, Ya Wang, and Zhi Ning
Atmos. Meas. Tech., 18, 1771–1785, https://doi.org/10.5194/amt-18-1771-2025, https://doi.org/10.5194/amt-18-1771-2025, 2025
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Long-term field testing across diverse climatic environments is conducted to identify the optimized calibration conditions for NO2, NO, CO and O3 electrochemical sensors. The results uncovered three factors that influence calibration performance: calibration period, concentration range and time averaging. We developed a comprehensive framework for the best sensor calibration practices, which serves as a valuable reference for calibrating various sensor types used in air quality monitoring.
Ying Zhou, Congcong Qiao, Minqiang Zhou, Yilong Wang, Xiangjun Tian, Yinghong Wang, and Minzheng Duan
Atmos. Meas. Tech., 18, 1609–1619, https://doi.org/10.5194/amt-18-1609-2025, https://doi.org/10.5194/amt-18-1609-2025, 2025
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We developed an automated, flexible atmospheric sampling device for various platforms. During a 5 d field campaign in the Mount Qomolangma region, we performed 15 flights using the device mounted on a hexacopter unoccupied aerial vehicle (UAV). A total of 139 samples were analyzed using an Agilent 7890A gas chromatograph. Vertical profiles of four greenhouse gases (carbon dioxide (CO2), methane (CH4), nitrous oxide (N2O), and sulfur hexafluoride (SF6)) were analyzed and discussed.
Emma L. Yates, Levi M. Golston, James R. Podolske, Laura T. Iraci, Kristen E. Okorn, Caroline Dang, Roy R. Johnson, James Eilers, Richard Kolyer, Ian Astley, and J. Brian Leen
EGUsphere, https://doi.org/10.5194/egusphere-2025-1081, https://doi.org/10.5194/egusphere-2025-1081, 2025
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In this work, we describe the development of the Carbon monOxide Measurement from Ames (COMA) instrument for measurement of carbon monoxide (CO) and nitrous oxide (N2O) aboard NASA's WB-57 high altitude research aircraft. We detail the modifications and testing conducted as well as details of COMA's performance during research flights for NASA’s Asian summer monsoon Chemical & CLImate Project (ACCLIP) 2022 campaign.
Bo Fang, Nana Wei, Weixiong Zhao, Nana Yang, Hao Zhou, Heng Zhang, Jiarong Li, Weijun Zhang, Yanyu Lu, Zhu Zhu, and Yue Liu
Atmos. Meas. Tech., 18, 1243–1256, https://doi.org/10.5194/amt-18-1243-2025, https://doi.org/10.5194/amt-18-1243-2025, 2025
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A portable laser-flash photolysis Faraday rotation spectrometer for measuring atmospheric total hydroxyl (OH) reactivity was developed, with optical box dimensions of 130 cm × 40 cm × 35 cm. It features a pump–probe multi-pass cell with a high overlapping factor of 75.4 %. The instrument’s precision and uncertainty are 1.0 s-1 (1σ, 300 s) and within 2 s-1, respectively. This portable, cost-effective instrument expands current measurement capabilities and is convenient for field applications.
Brice Barret, Patrice Medina, Natalie Brett, Roman Pohorsky, Kathy S. Law, Slimane Bekki, Gilberto J. Fochesatto, Julia Schmale, Steve R. Arnold, Andrea Baccarini, Maurizio Busetto, Meeta Cesler-Maloney, Barbara D'Anna, Stefano Decesari, Jingqiu Mao, Gianluca Pappaccogli, Joel Savarino, Federico Scoto, and William R. Simpson
Atmos. Meas. Tech., 18, 1163–1184, https://doi.org/10.5194/amt-18-1163-2025, https://doi.org/10.5194/amt-18-1163-2025, 2025
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The Fairbanks area experiences severe pollution episodes in winter because of enhanced emissions of pollutants trapped near the surface by strong temperature inversions. Low-cost sensors were deployed on board a car and a tethered balloon to measure the concentrations of gaseous pollutants (CO, O3, and NOx) in Fairbanks during winter 2022. Data calibration with reference measurements and machine learning methods enabled us to document pollution at the surface and power plant plumes aloft.
Hendrik Fuchs, Aaron Stainsby, Florian Berg, René Dubus, Michelle Färber, Andreas Hofzumahaus, Frank Holland, Kelvin H. Bates, Steven S. Brown, Matthew M. Coggon, Glenn S. Diskin, Georgios I. Gkatzelis, Christopher M. Jernigan, Jeff Peischl, Michael A. Robinson, Andrew W. Rollins, Nell B. Schafer, Rebecca H. Schwantes, Chelsea E. Stockwell, Patrick R. Veres, Carsten Warneke, Eleanor M. Waxman, Lu Xu, Kristen Zuraski, Andreas Wahner, and Anna Novelli
Atmos. Meas. Tech., 18, 881–895, https://doi.org/10.5194/amt-18-881-2025, https://doi.org/10.5194/amt-18-881-2025, 2025
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Significant improvements have been made to the instruments used to measure OH reactivity, which is equivalent to the sum of air pollutant concentrations. Accurate and precise measurements with a high time resolution have been achieved, allowing use on aircraft, as demonstrated during flights in the USA.
Inge Wiekenkamp, Anna Katharina Lehmann, Alexander Bütow, Jörg Hartmann, Stefan Metzger, Thomas Ruhtz, Christian Wille, Mathias Zöllner, and Torsten Sachs
Atmos. Meas. Tech., 18, 749–772, https://doi.org/10.5194/amt-18-749-2025, https://doi.org/10.5194/amt-18-749-2025, 2025
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Airborne eddy covariance platforms are crucial to measure three-dimensional wind and turbulent matter and energy transport between the surface and the atmosphere at larger scales. In this study, we introduce a new airborne eddy covariance platform (Schleicher ASK-16) and demonstrate that this platform is able to accurately measure turbulent fluxes and wind vectors. Data from this platform can help to build bridges between local tower measurements and remote-sensing-based products.
Takuji Sugidachi, Masatomo Fujiwara, Kensaku Shimizu, Shin-Ya Ogino, Junko Suzuki, and Ruud J. Dirksen
Atmos. Meas. Tech., 18, 509–531, https://doi.org/10.5194/amt-18-509-2025, https://doi.org/10.5194/amt-18-509-2025, 2025
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A Peltier-based chilled-mirror hygrometer, SKYDEW, has been developed to measure tropospheric and stratospheric water vapor. Continuous accurate measurements of water vapor are essential for climate monitoring. More than 40 soundings with SKYDEW have been conducted since 2011 to evaluate the performance. The result of soundings at tropical and midlatitudes demonstrated that SKYDEW is able to measure up to an altitude of 20–25 km for daytime soundings and above 25 km for nighttime soundings.
Johannes C. Laube, Tanja J. Schuck, Huilin Chen, Markus Geldenhuys, Steven van Heuven, Timo Keber, Maria Elena Popa, Elinor Tuffnell, Bärbel Vogel, Thomas Wagenhäuser, Alessandro Zanchetta, and Andreas Engel
EGUsphere, https://doi.org/10.5194/egusphere-2024-4034, https://doi.org/10.5194/egusphere-2024-4034, 2025
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A large balloon was launched in summer 2021 in the Arctic to carry instruments for trace gas measurements up to 32 km, above the reach of aircraft. The main aims were to evaluate different techniques and atmospheric processes. We focus on halogenated greenhouse gases and ozone-depleting substances. For this, air was collected with the AirCore technique and a cryogenic air sampler and measured after the flight. A companion paper reports observations of major greenhouse gases.
Cort L. Zang and Megan D. Willis
Atmos. Meas. Tech., 18, 17–35, https://doi.org/10.5194/amt-18-17-2025, https://doi.org/10.5194/amt-18-17-2025, 2025
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Atmospheric chemistry of the diverse pool of reactive organic carbon (ROC; all organic species excluding methane) controls air quality, both indoors and outdoors, and influences Earth's climate. However, many important ROC compounds in the atmosphere are difficult to measure. We demonstrate measurement of diverse ROC compounds in a single instrument at a forested site. This approach can improve our ability to measure a broad range of atmospheric ROC.
Emily D. Wein, Lars E. Kalnajs, and Darin W. Toohey
Atmos. Meas. Tech., 17, 7097–7107, https://doi.org/10.5194/amt-17-7097-2024, https://doi.org/10.5194/amt-17-7097-2024, 2024
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We describe a low-cost and small research-grade spectrometer for measurements of water vapor in the boundary layer. The instrument uses small Arduino microcontrollers and inexpensive laser diodes to reduce cost while maintaining high performance comparable to more expensive instruments. Performance was assessed with intercomparisons between commercially available instruments outdoors. The design's simplicity, performance, and price point allow it to be accessible to a variety of users.
Pedro Henrique Herig Coimbra, Benjamin Loubet, Olivier Laurent, Laura Bignotti, Mathis Lozano, and Michel Ramonet
Atmos. Meas. Tech., 17, 6625–6645, https://doi.org/10.5194/amt-17-6625-2024, https://doi.org/10.5194/amt-17-6625-2024, 2024
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This study presents direct flux measurements in tall towers using existing slow-response analysers and adding 3D sonic anemometers. This way, we can significantly improve greenhouse gas monitoring with little extra instrumental effort. Slow-response analysers may be used here as the relevant frequency ranges depend on measuring height. Tall towers offer a large footprint, amplifying spatial coverage. The presented concept is a valuable bridge between atmospheric and ecosystem communities.
Kristen Okorn and Laura T. Iraci
Atmos. Meas. Tech., 17, 6425–6457, https://doi.org/10.5194/amt-17-6425-2024, https://doi.org/10.5194/amt-17-6425-2024, 2024
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We reviewed 60 sensor networks and 17 related efforts (sensor review papers and data accessibility projects) to better understand the landscape of stationary low-cost gas-phase sensor networks deployed in outdoor environments worldwide. Gaps in monitoring efforts include the availability of gas-phase measurements compared to particulate matter (PM) and geographic coverage gaps (the Global South, rural areas). We conclude with a summary of cross-network unification and quality control efforts.
Henning Finkenzeller, Jyri Mikkilä, Cecilia Righi, Paxton Juuti, Mikko Sipilä, Matti Rissanen, Douglas Worsnop, Aleksei Shcherbinin, Nina Sarnela, and Juha Kangasluoma
Atmos. Meas. Tech., 17, 5989–6001, https://doi.org/10.5194/amt-17-5989-2024, https://doi.org/10.5194/amt-17-5989-2024, 2024
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Chemical ionisation mass spectrometry is used in the atmospheric sciences to measure trace gas concentrations. Neutral gases require charging in inlets before the mass-to-charge ratio of the resulting ions can be analysed. This study uses multiphysics modelling to investigate how the MION2 and Eisele type inlets work and shows the effect of tuning parameters and their current limitations. The findings are helpful for inlet users and are expected to aid in developing improved inlets.
Mohit L. Dubey, Andre Santos, Andrew B. Moyes, Ken Reichl, James E. Lee, Manvendra K. Dubey, Corentin LeYhuelic, Evan Variano, Emily Follansbee, Fotini K. Chow, and Sébastien C. Biraud
EGUsphere, https://doi.org/10.5194/egusphere-2024-3040, https://doi.org/10.5194/egusphere-2024-3040, 2024
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Orphaned wells, meaning wells lacking responsible owners, pose a significant and poorly understood environmental challenge. We propose, develop, and test a novel method for estimating emissions from orphaned wells using a Forced Advection Sampling Technique (FAST) that can overcome many of the limitations in current methods (cost, accuracy, safety). Our results suggest that the FAST method can provide a low-cost alternative to existing methods over a range of leak rates.
Steven A. Bailey, Reem A. Hannun, Andrew K. Swanson, and Thomas F. Hanisco
Atmos. Meas. Tech., 17, 5903–5910, https://doi.org/10.5194/amt-17-5903-2024, https://doi.org/10.5194/amt-17-5903-2024, 2024
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We have developed a portable, optically based instrument that measures NO2. It consumes less than 6 W of power, so it can easily run off a small battery. This instrument has made both balloon and UAV flights. NO2 measurement results compare favorably with other known NO2 instruments. We find this instrument to be stable with repeatable results compared with calibration sources. Material cost to build a single instrument is around USD 4000. This could be lowered with economies of scale.
Jinghui Lian, Olivier Laurent, Mali Chariot, Luc Lienhardt, Michel Ramonet, Hervé Utard, Thomas Lauvaux, François-Marie Bréon, Grégoire Broquet, Karina Cucchi, Laurent Millair, and Philippe Ciais
Atmos. Meas. Tech., 17, 5821–5839, https://doi.org/10.5194/amt-17-5821-2024, https://doi.org/10.5194/amt-17-5821-2024, 2024
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We have designed and deployed a mid-cost medium-precision CO2 sensor monitoring network in Paris since July 2020. The data are automatically calibrated by a newly implemented data processing system. The accuracies of the mid-cost instruments vary from 1.0 to 2.4 ppm for hourly afternoon measurements. Our model–data analyses highlight prospects for integrating mid-cost instrument data with high-precision measurements to improve fine-scale CO2 emission quantification in urban areas.
Abdullah Bolek, Martin Heimann, and Mathias Göckede
Atmos. Meas. Tech., 17, 5619–5636, https://doi.org/10.5194/amt-17-5619-2024, https://doi.org/10.5194/amt-17-5619-2024, 2024
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This study describes the development of a new UAV platform to measure atmospheric greenhouse gas (GHG) mole fractions, 2D wind speed, air temperature, humidity, and pressure. Understanding GHG flux processes and controls across various ecosystems is essential for estimating the current and future state of climate change. It was shown that using the UAV platform for such measurements is beneficial for improving our understanding of GHG processes over complex landscapes.
Jonathan F. Dooley, Kenneth Minschwaner, Manvendra K. Dubey, Sahar H. El Abbadi, Evan D. Sherwin, Aaron G. Meyer, Emily Follansbee, and James E. Lee
Atmos. Meas. Tech., 17, 5091–5111, https://doi.org/10.5194/amt-17-5091-2024, https://doi.org/10.5194/amt-17-5091-2024, 2024
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Methane is a powerful greenhouse gas originating from both natural and human activities. We describe a new uncrewed aerial system (UAS) designed to measure methane emission rates over a wide range of scales. This system has been used for direct quantification of point sources and distributed emitters over scales of up to 1 km. The system uses simultaneous measurements of methane and ethane to distinguish between different kinds of natural and human-related emission sources.
John Ericksen, Tobias P. Fischer, G. Matthew Fricke, Scott Nowicki, Nemesio M. Pérez, Pedro Hernández Pérez, Eleazar Padrón González, and Melanie E. Moses
Atmos. Meas. Tech., 17, 4725–4736, https://doi.org/10.5194/amt-17-4725-2024, https://doi.org/10.5194/amt-17-4725-2024, 2024
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Volcanic eruptions emit significant quantities of carbon dioxide (CO2) to the atmosphere. We present a new method for directly determining the CO2 emission from a volcanic eruption on the island of La Palma, Spain, using an unpiloted aerial vehicle (UAV). We also collected samples of the emitted CO2 and analyzed their isotopic composition. Together with the emission rate the isotopic data provide valuable information on the state of volcanic activity and the potential evolution of the eruption.
László Haszpra
Atmos. Meas. Tech., 17, 4629–4647, https://doi.org/10.5194/amt-17-4629-2024, https://doi.org/10.5194/amt-17-4629-2024, 2024
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The paper evaluates a 30-year-long atmospheric CO2 data series from a mid-continental central European site, Hegyhátsál (HUN). It presents the site-specific features observed in the long-term evolution of the atmospheric CO2 concentration. Since the measurement data are widely used in atmospheric inverse models and budget calculations all around the world, the paper provides potentially valuable information for model tuning and interpretation of the model results.
Mathieu Casado, Amaelle Landais, Tim Stoltmann, Justin Chaillot, Mathieu Daëron, Fréderic Prié, Baptiste Bordet, and Samir Kassi
Atmos. Meas. Tech., 17, 4599–4612, https://doi.org/10.5194/amt-17-4599-2024, https://doi.org/10.5194/amt-17-4599-2024, 2024
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Measuring water isotopic composition in Antarctica is difficult because of the extremely cold temperature in winter. Here, we designed a new infrared spectrometer able to measure the vapour isotopic composition during more than 95 % of the year in the coldest locations of Antarctica, whereas current commercial instruments are only able to measure during the warm summer months in the interior.
Cameron E. N. Power and Aldona Wiacek
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-97, https://doi.org/10.5194/amt-2024-97, 2024
Revised manuscript accepted for AMT
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The choice of path length and retroreflector array size in open-path FTIR spectroscopy must be made with care. Longer paths increase target gas absorption (lowering detection limits) and larger retroreflector arrays improve the SNR of spectra by increasing the return signal (improving retrieved concentration precision), but there are limitations to both. An optimum array size and path combination exists in each specific observational environment and application, as explored in this work.
Jean-Louis Bonne, Ludovic Donnat, Grégory Albora, Jérémie Burgalat, Nicolas Chauvin, Delphine Combaz, Julien Cousin, Thomas Decarpenterie, Olivier Duclaux, Nicolas Dumelié, Nicolas Galas, Catherine Juery, Florian Parent, Florent Pineau, Abel Maunoury, Olivier Ventre, Marie-France Bénassy, and Lilian Joly
Atmos. Meas. Tech., 17, 4471–4491, https://doi.org/10.5194/amt-17-4471-2024, https://doi.org/10.5194/amt-17-4471-2024, 2024
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We present a top-down approach to quantify CO2 and CH4 emissions at the scale of an industrial site, based on a mass balance model relying on atmospheric concentrations measurements from a new sensor embarked on board uncrewed aircraft vehicles (UAVs). We present a laboratory characterization of our sensor and a field validation of our quantification method, together with field application to the monitoring of two real-world offshore oil and gas platforms.
Rodrigo Rivera-Martinez, Pramod Kumar, Olivier Laurent, Gregoire Broquet, Christopher Caldow, Ford Cropley, Diego Santaren, Adil Shah, Cécile Mallet, Michel Ramonet, Leonard Rivier, Catherine Juery, Olivier Duclaux, Caroline Bouchet, Elisa Allegrini, Hervé Utard, and Philippe Ciais
Atmos. Meas. Tech., 17, 4257–4290, https://doi.org/10.5194/amt-17-4257-2024, https://doi.org/10.5194/amt-17-4257-2024, 2024
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We explore the use of metal oxide semiconductors (MOSs) as a low-cost alternative for detecting and measuring CH4 emissions from industrial facilities. MOSs were exposed to several controlled releases to test their accuracy in detecting and quantifying emissions. Two reconstruction models were compared, and emission estimates were computed using a Gaussian dispersion model. Findings show that MOSs can provide accurate emission estimates with a 25 % emission rate error and a 9.5 m location error.
Zihan Zhu, Javier González-Rocha, Yifan Ding, Isis Frausto-Vicencio, Sajjan Heerah, Akula Venkatram, Manvendra Dubey, Don Collins, and Francesca M. Hopkins
Atmos. Meas. Tech., 17, 3883–3895, https://doi.org/10.5194/amt-17-3883-2024, https://doi.org/10.5194/amt-17-3883-2024, 2024
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Increases in agriculture, oil and gas, and waste management activities have contributed to the increase in atmospheric methane levels and resultant climate warming. In this paper, we explore the use of small uncrewed aircraft systems (sUASs) and AirCore technology to detect and quantify methane emissions. Results from field experiments demonstrate that sUASs and AirCore technology can be effective for detecting and quantifying methane emissions in near real time.
Adrian Dahlmann, John D. Marshall, David Dubbert, Mathias Hoffmann, and Maren Dubbert
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-43, https://doi.org/10.5194/amt-2024-43, 2024
Revised manuscript accepted for AMT
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Water-stable isotopes are commonly used in hydrological and ecological research. Until now, measurements were obtained either destructive or directly in the field. Here, we present a novel, affordable, and easy-to-use approach to measure the stable isotope signatures of soil water. Our gas bag approach demonstrates a high accuracy and extends the usability by allowing water vapor samples to be collected and stored in the field without the need for an instrument or a permanent power supply.
Sebastian Diez, Stuart Lacy, Hugh Coe, Josefina Urquiza, Max Priestman, Michael Flynn, Nicholas Marsden, Nicholas A. Martin, Stefan Gillott, Thomas Bannan, and Pete M. Edwards
Atmos. Meas. Tech., 17, 3809–3827, https://doi.org/10.5194/amt-17-3809-2024, https://doi.org/10.5194/amt-17-3809-2024, 2024
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In this paper we present an overview of the QUANT project, which to our knowledge is one of the largest evaluations of commercial sensors to date. The objective was to evaluate the performance of a range of commercial products and also to nourish the different applications in which these technologies can offer relevant information.
Linda Ort, Lenard Lukas Röder, Uwe Parchatka, Rainer Königstedt, Daniel Crowley, Frank Kunz, Ralf Wittkowski, Jos Lelieveld, and Horst Fischer
Atmos. Meas. Tech., 17, 3553–3565, https://doi.org/10.5194/amt-17-3553-2024, https://doi.org/10.5194/amt-17-3553-2024, 2024
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Airborne in situ measurements are of great importance to collect valuable data to improve our knowledge of the atmosphere but also present challenges which demand specific designs. This study presents an IR spectrometer for airborne trace-gas measurements with high data efficiency and a simple, compact design. Its in-flight performance is characterized with the help of a test flight and a comparison with another spectrometer. Moreover, results from its first campaign highlight its benefits.
Roger Curcoll, Claudia Grossi, Stefan Röttger, and Arturo Vargas
Atmos. Meas. Tech., 17, 3047–3065, https://doi.org/10.5194/amt-17-3047-2024, https://doi.org/10.5194/amt-17-3047-2024, 2024
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This paper presents a new user-friendly version of the Atmospheric Radon MONitor (ARMON). The efficiency of the instrument is of 0.0057 s-1, obtained using different techniques at Spanish and German chambers. The total calculated uncertainty of the ARMON for hourly radon concentrations above 5 Bq m-3 is lower than 10 % (k = 1). Results confirm that the ARMON is suitable to measure low-level radon activity concentrations and to be used as a transfer standard to calibrate in situ radon monitors.
Josie K. Radtke, Benjamin N. Kies, Whitney A. Mottishaw, Sydney M. Zeuli, Aidan T. H. Voon, Kelly L. Koerber, Grant W. Petty, Michael P. Vermeuel, Timothy H. Bertram, Ankur R. Desai, Joseph P. Hupy, R. Bradley Pierce, Timothy J. Wagner, and Patricia A. Cleary
Atmos. Meas. Tech., 17, 2833–2847, https://doi.org/10.5194/amt-17-2833-2024, https://doi.org/10.5194/amt-17-2833-2024, 2024
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The use of uncrewed aircraft systems (UASs) to conduct a vertical profiling of ozone and meteorological variables was evaluated using comparisons between tower or ground observations and UAS-based measurements. Changes to the UAS profiler showed an improvement in performance. The profiler was used to see the impact of Chicago pollution plumes on a shoreline area near Lake Michigan.
Chen-Wei Liang and Chang-Hung Shen
Atmos. Meas. Tech., 17, 2671–2686, https://doi.org/10.5194/amt-17-2671-2024, https://doi.org/10.5194/amt-17-2671-2024, 2024
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In the present study, a UAV platform with sensing and sampling systems was developed for 3D air pollutant concentration measurements. The sensing system of this platform contains multiple microsensors and IoT technologies for obtaining the real-time 3D distributions of critical air pollutants. The sampling system contains gas sampling sets and a 1 L Tedlar bag instead of a canister for the 3D measurement of VOC concentrations in accordance with the TO-15 method of the US EPA.
Daniel Furuta, Bruce Wilson, Albert A. Presto, and Jiayu Li
Atmos. Meas. Tech., 17, 2103–2121, https://doi.org/10.5194/amt-17-2103-2024, https://doi.org/10.5194/amt-17-2103-2024, 2024
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Methane is an important driver of climate change and is challenging to inexpensively sense in low atmospheric concentrations. We developed a low-cost sensor to monitor methane and tested it in indoor and outdoor settings. Our device shows promise for monitoring low levels of methane. We characterize its limitations and suggest future research directions for further development.
Audrey J. Dang, Nathan M. Kreisberg, Tyler L. Cargill, Jhao-Hong Chen, Sydney Hornitschek, Remy Hutheesing, Jay R. Turner, and Brent J. Williams
Atmos. Meas. Tech., 17, 2067–2087, https://doi.org/10.5194/amt-17-2067-2024, https://doi.org/10.5194/amt-17-2067-2024, 2024
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The Multichannel Organics In situ enviRonmental Analyzer (MOIRA) is a new instrument for measuring speciated volatile organic compounds (VOCs) in the air and has been developed for mapping concentrations from a hybrid car. MOIRA is characterized in the lab and pilot field studies of indoor air in a single-family residence and outdoor air during a mobile deployment. Future applications include indoor, outdoor, and lab measurements to grasp the impact of VOCs on air quality, health, and climate.
Asher P. Mouat, Zelda A. Siegel, and Jennifer Kaiser
Atmos. Meas. Tech., 17, 1979–1994, https://doi.org/10.5194/amt-17-1979-2024, https://doi.org/10.5194/amt-17-1979-2024, 2024
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Three fast-measurement formaldehyde monitors were deployed at two field sites in Atlanta, GA, over 1 year. Four different zeroing methods were tested to develop an optimal field setup as well as procedures for instrument calibration. Observations agreed well after calibration but were much higher compared to the TO-11A monitoring method, which is the golden standard. Historical HCHO concentrations were compared with measurements in this work, showing a 22 % reduction in midday HCHO since 1999.
Da Yang, Margarita Reza, Roy Mauldin, Rainer Volkamer, and Suresh Dhaniyala
Atmos. Meas. Tech., 17, 1463–1474, https://doi.org/10.5194/amt-17-1463-2024, https://doi.org/10.5194/amt-17-1463-2024, 2024
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This paper evaluates the performance of an aircraft gas inlet. Here, we use computational fluid dynamics (CFD) and experiments to demonstrate the role of turbulence in determining sampling performance of a gas inlet and identify ideal conditions for inlet operation to minimize gas loss. Experiments conducted in a high-speed wind tunnel under near-aircraft speeds validated numerical results. We believe that the results obtained from this work will greatly inform future gas inlet studies.
Reena Macagga, Michael Asante, Geoffroy Sossa, Danica Antonijević, Maren Dubbert, and Mathias Hoffmann
Atmos. Meas. Tech., 17, 1317–1332, https://doi.org/10.5194/amt-17-1317-2024, https://doi.org/10.5194/amt-17-1317-2024, 2024
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Using only low-cost microcontrollers and sensors, we constructed a measurement device to accurately and precisely obtain atmospheric carbon dioxide and water fluxes. The device was tested against known concentration increases and high-cost, commercial sensors during a laboratory and field experiment. We additionally tested the device over a longer period in a field study in Ghana during which the net ecosystem carbon balance and water use efficiency of maize cultivation were studied.
Matthew M. Coggon, Chelsea E. Stockwell, Megan S. Claflin, Eva Y. Pfannerstill, Lu Xu, Jessica B. Gilman, Julia Marcantonio, Cong Cao, Kelvin Bates, Georgios I. Gkatzelis, Aaron Lamplugh, Erin F. Katz, Caleb Arata, Eric C. Apel, Rebecca S. Hornbrook, Felix Piel, Francesca Majluf, Donald R. Blake, Armin Wisthaler, Manjula Canagaratna, Brian M. Lerner, Allen H. Goldstein, John E. Mak, and Carsten Warneke
Atmos. Meas. Tech., 17, 801–825, https://doi.org/10.5194/amt-17-801-2024, https://doi.org/10.5194/amt-17-801-2024, 2024
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Mass spectrometry is a tool commonly used to measure air pollutants. This study evaluates measurement artifacts produced in the proton-transfer-reaction mass spectrometer. We provide methods to correct these biases and better measure compounds that degrade air quality.
Tianran Han, Conghui Xie, Yayong Liu, Yanrong Yang, Yuheng Zhang, Yufei Huang, Xiangyu Gao, Xiaohua Zhang, Fangmin Bao, and Shao-Meng Li
Atmos. Meas. Tech., 17, 677–691, https://doi.org/10.5194/amt-17-677-2024, https://doi.org/10.5194/amt-17-677-2024, 2024
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This study reported an integrated UAV measurement platform for GHG monitoring and its application for emission quantification from a coking plant. The key element of this system is a newly designed air sampler, consisting of a 150 m long tube with remote-controlled time stamping. When comparing the top-down results to those derived from the bottom-up inventory method, the present findings indicate that the use of IPCC emission factors for emission calculations can lead to overestimation.
Yuening Li, Faqiang Zhan, Yushan Su, Ying Duan Lei, Chubashini Shunthirasingham, Zilin Zhou, Jonathan P. D. Abbatt, Hayley Hung, and Frank Wania
Atmos. Meas. Tech., 17, 715–729, https://doi.org/10.5194/amt-17-715-2024, https://doi.org/10.5194/amt-17-715-2024, 2024
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A simple device for sampling gases from the atmosphere without the help of pumps was calibrated for an important group of hazardous air pollutants called polycyclic aromatic compounds (PACs). While the sampler appeared to perform well when used for relatively short periods of up to several months, some PACs were lost from the sampler during longer deployments. Sampling rates that can be used to quantitatively interpret the quantities of PACs taken up in the device have been derived.
Jiaxin Li, Kunpeng Zang, Yi Lin, Yuanyuan Chen, Shuo Liu, Shanshan Qiu, Kai Jiang, Xuemei Qing, Haoyu Xiong, Haixiang Hong, Shuangxi Fang, Honghui Xu, and Yujun Jiang
Atmos. Meas. Tech., 16, 4757–4768, https://doi.org/10.5194/amt-16-4757-2023, https://doi.org/10.5194/amt-16-4757-2023, 2023
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Based on observed data of CO2 and CH4 and meteorological parameters over the Yellow Sea in November 2012 and June 2013, a data process and quality control method was optimized and established to filter the data influenced by multiple factors. Spatial and seasonal variations in CO2 and CH4 mixing ratios were mainly controlled by the East Asian Monsoon, while the influence of air–sea exchange was slight.
Zaneta Hamryszczak, Antonia Hartmann, Dirk Dienhart, Sascha Hafermann, Bettina Brendel, Rainer Königstedt, Uwe Parchatka, Jos Lelieveld, and Horst Fischer
Atmos. Meas. Tech., 16, 4741–4756, https://doi.org/10.5194/amt-16-4741-2023, https://doi.org/10.5194/amt-16-4741-2023, 2023
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Hydroperoxide measurements improve the understanding of atmospheric oxidation processes. We introduce an instrumental setup for airborne measurements. The aim of the work is the characterization of the measurement method with emphasis on interferences impacting instrumental uncertainty. Technical and physical challenges do not critically impact the instrumental performance. The instrument resolves dynamic processes, such as convective transport, as shown based on the CAFE-Brazil campaign.
James F. Hurley, Alejandra Caceres, Deborah F. McGlynn, Mary E. Tovillo, Suzanne Pinar, Roger Schürch, Ksenia Onufrieva, and Gabriel Isaacman-VanWertz
Atmos. Meas. Tech., 16, 4681–4692, https://doi.org/10.5194/amt-16-4681-2023, https://doi.org/10.5194/amt-16-4681-2023, 2023
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Volatile organic compounds (VOCs) have a wide range of sources and impacts on environments and human health that make them spatially, temporally, and chemically varied. Current methods lack the ability to collect samples in ways that provide spatial and chemical resolution without complex, costly instrumentation. We describe and validate a low-cost, portable VOC sampler and demonstrate its utility in collecting distributed coordinated samples.
Simone Brunamonti, Manuel Graf, Tobias Bühlmann, Céline Pascale, Ivan Ilak, Lukas Emmenegger, and Béla Tuzson
Atmos. Meas. Tech., 16, 4391–4407, https://doi.org/10.5194/amt-16-4391-2023, https://doi.org/10.5194/amt-16-4391-2023, 2023
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The abundance of water vapor (H2O) in the upper atmosphere has a significant impact on the rate of global warming. We developed a new lightweight spectrometer (ALBATROSS) for H2O measurements aboard meteorological balloons. Here, we assess the accuracy and precision of ALBATROSS using metrology-grade reference gases. The results demonstrate the exceptional potential of mid-infrared laser absorption spectroscopy as a new reference method for in situ measurements of H2O in the upper atmosphere.
Roubina Papaconstantinou, Marios Demosthenous, Spyros Bezantakos, Neoclis Hadjigeorgiou, Marinos Costi, Melina Stylianou, Elli Symeou, Chrysanthos Savvides, and George Biskos
Atmos. Meas. Tech., 16, 3313–3329, https://doi.org/10.5194/amt-16-3313-2023, https://doi.org/10.5194/amt-16-3313-2023, 2023
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In this paper, we investigate the performance of low-cost electrochemical gas sensors. We carried out yearlong measurements at a traffic air quality monitoring station, where the low-cost sensors were collocated with reference instruments and exposed to highly variable environmental conditions with extremely high temperatures and low relative humidity (RH). Sensors provide measurements that exhibit increasing errors and decreasing correlations as temperature increases and RH decreases.
Jianghanyang Li, Bianca C. Baier, Fred Moore, Tim Newberger, Sonja Wolter, Jack Higgs, Geoff Dutton, Eric Hintsa, Bradley Hall, and Colm Sweeney
Atmos. Meas. Tech., 16, 2851–2863, https://doi.org/10.5194/amt-16-2851-2023, https://doi.org/10.5194/amt-16-2851-2023, 2023
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Monitoring a suite of trace gases in the stratosphere will help us better understand the stratospheric circulation and its impact on the earth's radiation balance. However, such measurements are rare and usually expensive. We developed an instrument that can measure stratospheric trace gases using a low-cost sampling platform (AirCore). The results showed expected agreement with aircraft measurements, demonstrating this technique provides a low-cost and robust way to observe the stratosphere.
Tara I. Yacovitch, Christoph Dyroff, Joseph R. Roscioli, Conner Daube, J. Barry McManus, and Scott C. Herndon
Atmos. Meas. Tech., 16, 1915–1921, https://doi.org/10.5194/amt-16-1915-2023, https://doi.org/10.5194/amt-16-1915-2023, 2023
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Ethylene oxide is a toxic, carcinogenic compound used in the medical and bulk sterilization industry. Here we describe a precise and fast laser-based ethylene oxide monitor. We report months-long concentrations at a Massachusetts site, and we show how they suggest a potential emission source 35 km away. This source, and another, is confirmed by driving the instrument downwind of the sites, where concentrations were tens to tens of thousands of times greater than background levels.
Tatsumi Nakano and Takashi Morofuji
Atmos. Meas. Tech., 16, 1583–1595, https://doi.org/10.5194/amt-16-1583-2023, https://doi.org/10.5194/amt-16-1583-2023, 2023
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We have developed a system that can automatically measure the pump efficiency of the ECC-type ozonesonde. Operational measurement for 13 years by this system revealed that the efficiency fluctuates in each and slightly increases over time. Those can affect the estimation of total ozone amount by up to 4 %. This result indicates that it is necessary to understand the tendency of the pump correction factor of each ozonesonde in order to detect the actual atmospheric change with high accuracy.
Benjamin Birner, Eric Morgan, and Ralph F. Keeling
Atmos. Meas. Tech., 16, 1551–1561, https://doi.org/10.5194/amt-16-1551-2023, https://doi.org/10.5194/amt-16-1551-2023, 2023
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Atmospheric variations of helium (He) and CO2 are strongly linked due to the co-release of both gases from natural-gas burning. This implies that atmospheric He measurements may be a potentially powerful tool for verifying reported anthropogenic natural-gas usage. Here, we present the development and initial results of a novel measurement system of atmospheric He that paves the way for establishing a global monitoring network in the future.
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