Articles | Volume 6, issue 12
https://doi.org/10.5194/amt-6-3425-2013
https://doi.org/10.5194/amt-6-3425-2013
Research article
 | 
09 Dec 2013
Research article |  | 09 Dec 2013

Reporting the sensitivity of laser-induced fluorescence instruments used for HO2 detection to an interference from RO2 radicals and introducing a novel approach that enables HO2 and certain RO2 types to be selectively measured

L. K. Whalley, M. A. Blitz, M. Desservettaz, P. W. Seakins, and D. E. Heard

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Cited articles

Atkinson, R., Baulch, D. L., Cox, R. A., Hampson, R. F., Kerr, J. A., Rossi, M. J., and Troe, J.: Evaluated kinetic, photochemical and heterogeneous data for atmospheric chemistry .5. IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry, J. Phys. Chem. Ref. Data, 26, 521–1011, 1997.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I – gas phase reactions of Ox, HOx, NOx and SOx species, Atmos. Chem. Phys., 4, 1461–1738, https://doi.org/10.5194/acp-4-1461-2004, 2004.
Bloss, C., Wagner, V., Jenkin, M. E., Volkamer, R., Bloss, W. J., Lee, J. D., Heard, D. E., Wirtz, K., Martin-Reviejo, M., Rea, G., Wenger, J. C., and Pilling, M. J.: Development of a detailed chemical mechanism (MCMv3.1) for the atmospheric oxidation of aromatic hydrocarbons, Atmos. Chem. Phys., 5, 641–664, https://doi.org/10.5194/acp-5-641-2005, 2005.
Bloss, W. J., Camredon, M., Lee, J. D., Heard, D. E., Plane, J. M. C., Saiz-Lopez, A., Bauguitte, S. J.-B., Salmon, R. A., and Jones, A. E.: Coupling of HOx, NOx and halogen chemistry in the antarctic boundary layer, Atmos. Chem. Phys., 10, 10187–10209, https://doi.org/10.5194/acp-10-10187-2010, 2010.
Carslaw, N., Creasey, D. J., Heard, D. E., Lewis, A. C., McQuaid, J. B., Pilling, M. J., Monks, P. S., Bandy, B. J., and Penkett, S. A.: Modeling OH, HO2, and RO2 radicals in the marine boundary layer – 1. Model construction and comparison with field measurements, J. Geophys. Res.-Atmos., 104, 30241–30255, https://doi.org/10.1029/1999jd900783, 1999a.
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