Articles | Volume 10, issue 3
https://doi.org/10.5194/amt-10-1061-2017
https://doi.org/10.5194/amt-10-1061-2017
Research article
 | 
16 Mar 2017
Research article |  | 16 Mar 2017

Quantitation of 11 alkylamines in atmospheric samples: separating structural isomers by ion chromatography

Bryan K. Place, Aleya T. Quilty, Robert A. Di Lorenzo, Susan E. Ziegler, and Trevor C. VandenBoer

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Cited articles

Akyüz, M.: Simultaneous determination of aliphatic and aromatic amines in indoor and outdoor air samples by gas chromatography-mass spectrometry, Talanta, 71, 486–492, https://doi.org/10.1016/j.talanta.2006.10.028, 2007.
Angelino, S., Suess, D. T., and Prather, K. A.: Formation of aerosol particles from reactions of secondary and tertiary alkylamines: Characterization by aerosol time-of-flight mass spectrometry, Environ. Sci. Technol., 35, 3130–3138, https://doi.org/10.1021/es0015444, 2001.
Ault, A. P., Moffet, R. C., Baltrusaitis, J., Collins, D. B., Ruppel, M. J., Cuadra-Rodriguez, L. A., Zhao, D., Guasco, T. L., Ebben, C. J., Geiger, F. M., Bertram, T. H., Prather, K. A., and Grassian, V. H.: Size-dependent changes in sea spray aerosol composition and properties with different seawater conditions, Environ. Sci. Technol., 47, 5603–5612, https://doi.org/10.1021/es400416g, 2013.
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Short summary
Amines are important drivers in particle formation and growth, which has implications for Earth’s climate. We developed a novel ion chromatographic method for separating and quantifying the 11 most abundant atmospheric alkyl amines, including three sets of structural isomers and two diamines. The detection limits are in the picogram per injection range. We quantified these analytes in two Canadian biomass burning aerosol samples with ammonium ratios of 1 : 2 up to 1000 : 1.
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