Articles | Volume 16, issue 5
https://doi.org/10.5194/amt-16-1179-2023
https://doi.org/10.5194/amt-16-1179-2023
Research article
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07 Mar 2023
Research article | Highlight paper |  | 07 Mar 2023

Influence of ozone and humidity on PTR-MS and GC-MS VOC measurements with and without a Na2S2O3 ozone scrubber

Lisa Ernle, Monika Akima Ringsdorf, and Jonathan Williams

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Cited articles

Apel, E., Hills, A., Lueb, R., Zindel, S., Eisele, S., and Riemer, D.: A fast-GC/MS system to measure C2 to C4 carbonyls and methanol aboard aircraft, J. Geophys. Res.-Atmos., 108, 8794, https://doi.org/10.1029/2002JD003199, 2003. a, b, c, d, e, f, g, h
Bourtsoukidis, E., Helleis, F., Tomsche, L., Fischer, H., Hofmann, R., Lelieveld, J., and Williams, J.: An aircraft gas chromatograph–mass spectrometer System for Organic Fast Identification Analysis (SOFIA): design, performance and a case study of Asian monsoon pollution outflow, Atmos. Meas. Tech., 10, 5089–5105, https://doi.org/10.5194/amt-10-5089-2017, 2017. a, b, c
Buhr, K., van Ruth, S., and Delahunty, C.: Analysis of volatile flavour compounds by Proton Transfer Reaction-Mass Spectrometry: fragmentation patterns and discrimination between isobaric and isomeric compounds, Int. J. Mass Spectrom., 221, 1–7, 2002. a, b
Colomb, A., Williams, J., Crowley, J., Gros, V., Hofmann, R., Salisbury, G., Klüpfel, T., Kormann, R., Stickler, A., Forster, C., and Lelieveld, J.: Airborne measurements of trace organic species in the upper troposphere over Europe: the impact of deep convection, Environ. Chem., 3, 244–259, 2006. a
Crutzen, P. J. and Lelieveld, J.: Human impacts on atmospheric chemistry, Annu. Rev. Earth Pl. Sc., 29, 17–45, 2001. a
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Executive editor
I agree with the handling editor that this paper covers a very good study that would be a very useful for the community, especially for measurements of reactive gases.
Short summary
Atmospheric ozone can induce artefacts in volatile organic compound measurements. Laboratory tests were made using GC-MS and PTR-MS aircraft systems under tropospheric and stratospheric conditions of humidity and ozone, with and without sodium thiosulfate filter scrubbers. Ozone in dry air produces some carbonyls and degrades alkenes. The scrubber lifetime depends on ozone concentration, flow rate and humidity. For the troposphere with scrubber, no significant artefacts were found over 14 d.
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