Articles | Volume 18, issue 11
https://doi.org/10.5194/amt-18-2463-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-18-2463-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
11 Jun 2025
Research article |
| 11 Jun 2025
| 11 Jun 2025
The UNAM-MARine Aerosol Tank (UNAM-MARAT): an evaluation of the ice-nucleating abilities of seawater from the Gulf of Mexico and the Mexican Pacific
M. Fernanda Córdoba
Instituto de Ciencias de la Atmósfera y Cambio Climático, Universidad Nacional Autónoma de México, Mexico City, 04510, Mexico
Rachel Chang
Department of Physics and Atmospheric Science, Dalhousie University, Halifax, Nova Scotia, B3H 4R2, Canada
Harry Alvarez-Ospina
Facultad de Ciencias, Universidad Nacional Autónoma de México, Mexico City, 04510, Mexico
Aramis Olivos-Ortiz
Centro Universitario de Investigaciones Oceanológicas, Universidad de Colima, Colima, 28860, Mexico
Graciela B. Raga
Instituto de Ciencias de la Atmósfera y Cambio Climático, Universidad Nacional Autónoma de México, Mexico City, 04510, Mexico
Daniel Rosas-Ramírez
Departamento de Química de Biomacromoléculas, Instituto de Química, Universidad Nacional Autónoma de México, Av. Universidad 3000, Circuito Exterior s/n, Coyoacán, Ciudad Universitaria, Mexico City, 04510, Mexico
Guadalupe Campos
Laboratorio de Alimento Vivo, Procuraduría Estatal de Protección al Medio Ambiente, Aquarium del Puerto de Veracruz, Blvd. Manuel Ávila Camacho s/n, Col. Ricardo Flores Magón, Veracruz, 91900, Mexico
Isabel Márquez
Facultad de Ciencias, Universidad Nacional Autónoma de México, Mexico City, 04510, Mexico
Telma Castro
Instituto de Ciencias de la Atmósfera y Cambio Climático, Universidad Nacional Autónoma de México, Mexico City, 04510, Mexico
Luis A. Ladino
CORRESPONDING AUTHOR
Instituto de Ciencias de la Atmósfera y Cambio Climático, Universidad Nacional Autónoma de México, Mexico City, 04510, Mexico
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Cited articles
Albrecht, B. A.: Aerosols, cloud microphysics, and fractional cloudiness, Science, 245, 1227–1230, https://doi.org/10.1126/science.245.4923.1227, 1989.
Alpert, P. A., Aller, J. Y., and Knopf, D. A.: Ice nucleation from aqueous NaCl droplets with and without marine diatoms, Atmos. Chem. Phys., 11, 5539–5555, https://doi.org/10.5194/acp-11-5539-2011, 2011.
Anderson, D. M., Glibert, P. M., and Burkholder, J. M.: Harmful Algal Blooms and Eutrophication: Nutrient Sources, Composition, and Consequences, Estuaries, 25, 704–726, https://doi.org/10.1007/BF02804901, 2002.
Bates, T. S., Kapustin, V. N., Quinn, P. K., Covert, D. S., Coffman, D. J., Mari, C., Durkee, P. A., De Bruyn, W. J., and Saltzman, E. S.: Processes controlling the distribution of aerosol particles in the lower marine boundary layer during the first aerosol characterization experiment (ACE 1), J. Geophys. Res.-Atmos., 103, 16369–16383, https://doi.org/10.1029/97JD03720, 1998.
Bates, T. S., Quinn, P. K., Frossard, A. A., Russell, L. M., Hakala, J., Petäjä, T., Kulmala, M., Covert, D. S., Cappa, C. D., Li, S. M., Hayden, K. L., Nuaaman, I., McLaren, R., Massoli, P., Canagaratna, M. R., Onasch, T. B., Sueper, D., Worsnop, D. R., and Keene, W. C.: Measurements of ocean derived aerosol off the coast of California, J. Geophys. Res.-Atmos., 117, 1–13, https://doi.org/10.1029/2012JD017588, 2012.
Bigg, E. K.: Ice Nucleus Concentrations in Remote Areas, J. Atmos. Sci., 30, 1153–1157, https://doi.org/10.1175/1520-0469(1973)030<1153:INCIRA>2.0.CO;2, 1973.
Bigg, E. K. and Leck, C.: The composition of fragments of bubbles bursting at the ocean surface, J. Geophys. Res.-Atmos., 113, D11209, https://doi.org/10.1029/2007JD009078, 2008.
Boucher, O., Randall, P. Artaxo, C., Bretherton, G., Feingold, P., Forster, V.-M., Kerminen, Y., Kondo, H., Liao, U., Lohmann, P., Rasch, S. K., Satheesh, S., Sherwood, B. S., and Zhang, X.: Clouds and Aerosols, in: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change, edited by: Stocker, T. F., Qin, D., Plattner, G.-K., Tignor, M., Allen, S. K., Boschung, J., Nauels, A., Xia, Y., Bex, V., and Midgley, P. M., Cambridge, United Kingdom and New York, NY, USA, 571–657 pp., https://doi.org/10.1017/CBO9781107415324.016, 2013.
Burrows, S. M., Hoose, C., Pöschl, U., and Lawrence, M. G.: Ice nuclei in marine air: biogenic particles or dust?, Atmos. Chem. Phys., 13, 245–267, https://doi.org/10.5194/acp-13-245-2013, 2013.
Burrows, S. M., Ogunro, O., Frossard, A. A., Russell, L. M., Rasch, P. J., and Elliott, S. M.: A physically based framework for modeling the organic fractionation of sea spray aerosol from bubble film Langmuir equilibria, Atmos. Chem. Phys., 14, 13601–13629, https://doi.org/10.5194/acp-14-13601-2014, 2014.
Burrows, S. M., McCluskey, C. S., Cornwell, G., Steinke, I., Zhang, K., Zhao, B., Zawadowicz, M., Raman, A., Kulkarni, G., China, S., Zelenyuk, A., and DeMott, P. J.: Ice-Nucleating Particles That Impact Clouds and Climate: Observational and Modeling Research Needs, Rev. Geophys., 60, 1–45, https://doi.org/10.1029/2021RG000745, 2022.
Chakraborty, S., Bhattacharya, S., Feudel, U., and Chattopadhyay, J.: The role of avoidance by zooplankton for survival and dominance of toxic phytoplankton, Ecol. Complex., 11, 144–153, https://doi.org/10.1016/j.ecocom.2012.05.006, 2012.
Chin, W. C., Orellana, M., and Verdugo, P.: Spontaneous assembly of marine dissolved organic matter into polymer gels, Nature, 391, 568–572, https://doi.org/10.1038/35345, 1998.
Chow, J. C. and Watson, J. G.: Elemental Analysis of Airborne Particles, in: Elemetal Analysis of Airborne Particles, Vol. 1, edited by: Creatchman, M., CRC Press, London, 97–137, https://doi.org/10.1201/9781003580706, 1999.
Christiansen, S., Salter, M. E., Gorokhova, E., Nguyen, Q. T., and Bilde, M.: Sea Spray Aerosol Formation: Laboratory Results on the Role of Air Entrainment, Water Temperature, and Phytoplankton Biomass, Environ. Sci. Technol., 53, 13107–13116, https://doi.org/10.1021/acs.est.9b04078, 2019.
Cipriano, R. and Blanchard, C.: Bubble and Aerosol Spectra Produced by a Laboratory “Breaking Wave”, J. Geophys. Res., 86, 8085–8092, 1981.
Collins, D. B., Zhao, D. F., Ruppel, M. J., Laskina, O., Grandquist, J. R., Modini, R. L., Stokes, M. D., Russell, L. M., Bertram, T. H., Grassian, V. H., Deane, G. B., and Prather, K. A.: Direct aerosol chemical composition measurements to evaluate the physicochemical differences between controlled sea spray aerosol generation schemes, Atmos. Meas. Tech., 7, 3667–3683, https://doi.org/10.5194/amt-7-3667-2014, 2014.
Córdoba, F., Ramírez-Romero, C., Cabrera, D., Raga, G. B., Miranda, J., Alvarez-Ospina, H., Rosas, D., Figueroa, B., Kim, J. S., Yakobi-Hancock, J., Amador, T., Gutierrez, W., García, M., Bertram, A. K., Baumgardner, D., and Ladino, L. A.: Measurement report: Ice nucleating abilities of biomass burning, African dust, and sea spray aerosol particles over the Yucatán Peninsula, Atmos. Chem. Phys., 21, 4453–4470, https://doi.org/10.5194/acp-21-4453-2021, 2021.
DeMott, P. J., Prenni, A. J., Liu, X., Kreidenweis, S. M., Petters, M. D., Twohy, C. H., Richardson, M. S., Eidhammer, T., and Rogers, D. C.: Predicting global atmospheric ice nuclei distributions and their impacts on climate, P. Natl. Acad. Sci. USA, 107, 11217–11222, https://doi.org/10.1073/pnas.0910818107, 2010.
DeMott, P. J., Hill, T. C. J., McCluskey, C. S., Prather, K. A., Collins, D. B., Sullivan, R. C., Ruppel, M. J., Mason, R. H., Irish, V. E., Lee, T., Hwang, C. Y., Rhee, T. S., Snider, J. R., McMeeking, G. R., Dhaniyala, S., Lewis, E. R., Wentzell, J. J. B., Abbatt, J., Lee, C., Sultana, C. M., Ault, A. P., Axson, J. L., Martinez, M. D., Venero, I., Santos-Figueroa, G., Stokes, M. D., Deane, G. B., Mayol-Bracero, O. L., Grassian, V. H., Bertram, T. H., Bertram, A. K., Moffett, B. F., and Franc, G. D.: Sea spray aerosol as a unique source of ice nucleating particles, P. Natl. Acad. Sci. USA, 113, 5797–5803, https://doi.org/10.1073/pnas.1514034112, 2016.
Facchini, M. C., Rinaldi, M., Decesari, S., Carbone, C., Finessi, E., Mircea, M., Fuzzi, S., Ceburnis, D., Flanagan, R., Nilsson, E. D., de Leeuw, G., Martino, M., Woeltjen, J., and O'Dowd, C. D.: Primary submicron marine aerosol dominated by insoluble organic colloids and aggregates, Geophys. Res. Lett., 35, L17814, https://doi.org/10.1029/2008GL034210, 2008.
Fall, R. and Schnell, R. C.: Association of an ice-nucleating pseudomonad with cultures of the marine dinoflagellate, Heterocapsa niei, J. Mar. Res., 43, 257–265, https://elischolar.library.yale.edu/journal_of_marine_research/1773 (last access: 3 June 2025), 1985.
Fuentes, E., Coe, H., Green, D., de Leeuw, G., and McFiggans, G.: Laboratory-generated primary marine aerosol via bubble-bursting and atomization, Atmos. Meas. Tech., 3, 141–162, https://doi.org/10.5194/amt-3-141-2010, 2010.
Harb, C. and Foroutan, H.: A Systematic Analysis of the Salinity Effect on Air Bubbles Evolution: Laboratory Experiments in a Breaking Wave Analog, J. Geophys. Res.-Oceans, 124, 7355–7374, https://doi.org/10.1029/2019JC015337, 2019.
Hartery, S., MacInnis, J., and Chang, R. Y. W.: Effect of Sodium Dodecyl Benzene Sulfonate on the Production of Cloud Condensation Nuclei from Breaking Waves, ACS Earth Space Chem., 6, 2944–2954, https://doi.org/10.1021/acsearthspacechem.2c00230, 2022.
Hill, T. C. J., DeMott, P. J., Tobo, Y., Fröhlich-Nowoisky, J., Moffett, B. F., Franc, G. D., and Kreidenweis, S. M.: Sources of organic ice nucleating particles in soils, Atmos. Chem. Phys., 16, 7195–7211, https://doi.org/10.5194/acp-16-7195-2016, 2016.
Holden, M. A., Campbell, J. M., Meldrum, F. C., Murray, B. J., and Christenson, H. K.: Active sites for ice nucleation differ depending on nucleation mode, P. Natl. Acad. Sci. USA, 118, 1–9, https://doi.org/10.1073/pnas.2022859118, 2021.
Jacobson, M. Z.: Global direct radiative forcing due to multicomponent anthropogenic and natural aerosols, J. Geophys. Res.-Atmos., 106, 1551–1568, https://doi.org/10.1029/2000jd900514, 2001.
Jelley, J. V.: Sea waves: their nature, behaviour, and practical importance, Endeavour, 13, 148–156, https://doi.org/10.1016/S0160-9327(89)80002-X, 1989.
Kennedy, F., Martin, A., Bowman, J. P., Wilson, R., and McMinn, A.: Dark metabolism: a molecular insight into how the Antarctic sea-ice diatom Fragilariopsis cylindrus survives long-term darkness, New Phytol., 223, 675–691, https://doi.org/10.1111/nph.15843, 2019.
Knopf, D. A., Alpert, P. A., Wang, B., and Aller, J. Y.: Stimulation of ice nucleation by marine diatoms, Nat. Geosci., 4, 88–90, https://doi.org/10.1038/ngeo1037, 2011.
Kuuppo, P., Autio, R., Kuosa, H., Setälä, O., and Tanskanen, S.: Nitrogen, silicate and zooplankton control of the planktonic food-web in spring, Estuar. Coast. Shelf S., 46, 65–75, https://doi.org/10.1006/ecss.1997.0258, 1998.
Ladino, L. A., Raga, G. B., Alvarez-Ospina, H., Andino-Enríquez, M. A., Rosas, I., Martínez, L., Salinas, E., Miranda, J., Ramírez-Díaz, Z., Figueroa, B., Chou, C., Bertram, A. K., Quintana, E. T., Maldonado, L. A., García-Reynoso, A., Si, M., and Irish, V. E.: Ice-nucleating particles in a coastal tropical site, Atmos. Chem. Phys., 19, 6147–6165, https://doi.org/10.5194/acp-19-6147-2019, 2019.
Ladino, L., Juaréz-Pérez, J., Ramírez-Díaz, Z., Miller, L. A., Herrera, J., Raga, G. B., Simpson, K. G., Cruz, G., Pereira, D. L., and Córdoba, F.: The UNAM-droplet freezing assay: An evaluation of the ice nucleating capacity of the sea-surface microlayer and surface mixed layer in tropical and subpolar waters, Atmosfera, 35, 127–141, https://doi.org/10.20937/ATM.52938, 2022.
Lamarre, E. and Melville, W. K.: Air entrainment and dissipation in breaking waves, Nature, 351, 469–472, https://doi.org/10.1038/351469a0, 1991.
Lewis, E. R. and Schwartz, S. E.: Sea Salt Aerosol Production: Mechanisms, Methods, Measurements and Models – A critical Review, American Geophysical Union, Washington, DC, ISBN 978-0-87590-417-7, 2004.
Mason, R. H., Si, M., Li, J., Chou, C., Dickie, R., Toom-Sauntry, D., Pöhlker, C., Yakobi-Hancock, J. D., Ladino, L. A., Jones, K., Leaitch, W. R., Schiller, C. L., Abbatt, J. P. D., Huffman, J. A., and Bertram, A. K.: Ice nucleating particles at a coastal marine boundary layer site: correlations with aerosol type and meteorological conditions, Atmos. Chem. Phys., 15, 12547–12566, https://doi.org/10.5194/acp-15-12547-2015, 2015.
Mayer, K. J., Wang, X., Santander, M. V., Mitts, B. A., Sauer, J. S., Sultana, C. M., Cappa, C. D., and Prather, K. A.: Secondary Marine Aerosol Plays a Dominant Role over Primary Sea Spray Aerosol in Cloud Formation, ACS Cent. Sci., 6, 2259–2266, https://doi.org/10.1021/acscentsci.0c00793, 2020.
McCluskey, C. S., Hill, T. C. J., Malfatti, F., Sultana, C. M., Lee, C., Santander, M. V., Beall, C. M., Moore, K. A., Cornwell, G. C., Collins, D. B., Prather, K. A., Jayarathne, T., Stone, E. A., Azam, F., Kreidenweis, S. M., and DeMott, P. J.: A dynamic link between ice nucleating particles released in nascent sea spray aerosol and oceanic biological activity during two mesocosm experiments, J. Atmos. Sci., 74, 151–166, https://doi.org/10.1175/JAS-D-16-0087.1, 2017.
McCluskey, C. S., Ovadnevaite, J., Rinaldi, M., Atkinson, J., Belosi, F., Ceburnis, D., Marullo, S., Hill, T. C. J., Lohmann, U., Kanji, Z. A., O'Dowd, C., Kreidenweis, S. M., and DeMott, P. J.: Marine and Terrestrial Organic Ice-Nucleating Particles in Pristine Marine to Continentally Influenced Northeast Atlantic Air Masses, J. Geophys. Res.-Atmos., 123, 6196–6212, https://doi.org/10.1029/2017JD028033, 2018.
Melchum, A., Córdoba, F., Salinas, E., Martínez, L., Campos, G., Rosas, I., Garcia, E., Olivos, A., Raga, G. B., Pizano, B., Silva, M. M., and Ladino, L. A.: Maritime and continental microorganisms collected in Mexico: An investigation of their ice-nucleating abilities, Atmos. Res., 293, 106893, https://doi.org/10.1016/j.atmosres.2023.106893, 2023.
Prather, K. A., Bertram, T. H., Grassian, V. H., Deane, G. B., Stokes, M. D., DeMott, P. J., Aluwihare, L. I., Palenik, B. P., Azam, F., Seinfeld, J. H., Moffet, R. C., Molina, M. J., Cappa, C. D., Geiger, F. M., Roberts, G. C., Russell, L. M., Ault, A. P., Baltrusaitis, J., Collins, D. B., Corrigan, C. E., Cuadra-Rodriguez, L. A., Ebben, C. J., Forestieri, S. D., Guasco, T. L., Hersey, S. P., Kim, M. J., Lambert, W. F., Modini, R. L., Mui, W., Pedler, B. E., Ruppel, M. J., Ryder, O. S., Schoepp, N. G., Sullivan, R. C., and Zhao, D.: Bringing the ocean into the laboratory to probe the chemical complexity of sea spray aerosol, P. Natl. Acad. Sci. USA, 110, 7550–7555, https://doi.org/10.1073/pnas.1300262110, 2013.
Quinn, P., Collins, D., Grassian, V., Prather, K., and Bates, T.: Chemistry and Related Properties of Freshly Emitted Sea Spray Aerosol, Chem. Rev., 115, 4383–4399, https://doi.org/10.1021/cr500713g, 2015.
Resch, F. and Afeti, G.: Submicron Film Drop Production by Bubbles in Sea Water, J. Geophys. Res., 97, 3679–3683, https://doi.org/10.1029/91JC02961, 1992.
Rosinski, J., Haagenson, P. L., Nagamoto, C. T., and Parungo, F.: Nature of ice-forming nuclei in marine air masses, J. Aerosol Sci., 18, 291–309, https://doi.org/10.1016/0021-8502(87)90024-3, 1987.
Rosinski, J., Haagenson, P. L., Nagamoto, C. T., Quintana, B., Parungo, F., and Hoyt, S. D.: Ice-forming nuclei in air masses over the Gulf of Mexico, J. Aerosol Sci., 19, 539–551, https://doi.org/10.1016/0021-8502(88)90206-6, 1988.
Russell, L. M., Hawkins, L. N., Frossard, A. A., Quinn, P. K., and Bates, T. S.: Carbohydrate-like composition of submicron atmospheric particles and their production from ocean bubble bursting, P. Natl. Acad. Sci. USA, 107, 6652–6657, https://doi.org/10.1073/pnas.0908905107, 2010.
Schnell, R. C.: Ice Nuclei in Seawater, Fog Water and Marine Air off the Coast of Nova Scotia: Summer 1975, J. Atmos. Sci., 34, 1299–1305, 1977.
Schnell, R. C. and Vali, G.: Freezing nuclei in marine waters, Tellus A, 27, 321–323, https://doi.org/10.3402/tellusa.v27i3.9911, 1975.
Sellegri, K., O'Dowd, C. D., Yoon, Y. J., Jennings, S. G., and de Leeuw, G.: Surfactants and submicron sea spray generation, J. Geophys. Res., 111, D22215, https://doi.org/10.1029/2005JD006658, 2006.
Si, M., Irish, V. E., Mason, R. H., Vergara-Temprado, J., Hanna, S. J., Ladino, L. A., Yakobi-Hancock, J. D., Schiller, C. L., Wentzell, J. J. B., Abbatt, J. P. D., Carslaw, K. S., Murray, B. J., and Bertram, A. K.: Ice-nucleating ability of aerosol particles and possible sources at three coastal marine sites, Atmos. Chem. Phys., 18, 15669–15685, https://doi.org/10.5194/acp-18-15669-2018, 2018.
Stokes, M. D., Deane, G. B., Prather, K., Bertram, T. H., Ruppel, M. J., Ryder, O. S., Brady, J. M., and Zhao, D.: A Marine Aerosol Reference Tank system as a breaking wave analogue for the production of foam and sea-spray aerosols, Atmos. Meas. Tech., 6, 1085–1094, https://doi.org/10.5194/amt-6-1085-2013, 2013.
Thornton, D. C. O., Brooks, S. D., Wilbourn, E. K., Mirrielees, J., Alsante, A. N., Gold-Bouchot, G., Whitesell, A., and McFadden, K.: Production of ice-nucleating particles (INPs) by fast-growing phytoplankton, Atmos. Chem. Phys., 23, 12707–12729, https://doi.org/10.5194/acp-23-12707-2023, 2023.
Trueblood, J. V., Wang, X., Or, V. W., Alves, M. R., Santander, M. V., Prather, K. A., and Grassian, V. H.: The Old and the New: Aging of Sea Spray Aerosol and Formation of Secondary Marine Aerosol through OH Oxidation Reactions, ACS Earth Space Chem., 3, 2307–2314, https://doi.org/10.1021/acsearthspacechem.9b00087, 2019.
Verdugo, P., Alldredge, A. L., Azam, F., Kirchman, D. L., Passow, U., and Santschi, P. H.: The oceanic gel phase: A bridge in the DOM-POM continuum, Mar. Chem., 92, 67–85, https://doi.org/10.1016/j.marchem.2004.06.017, 2004.
Vergara-Temprado, J., Murray, B. J., Wilson, T. W., O'Sullivan, D., Browse, J., Pringle, K. J., Ardon-Dryer, K., Bertram, A. K., Burrows, S. M., Ceburnis, D., DeMott, P. J., Mason, R. H., O'Dowd, C. D., Rinaldi, M., and Carslaw, K. S.: Contribution of feldspar and marine organic aerosols to global ice nucleating particle concentrations, Atmos. Chem. Phys., 17, 3637–3658, https://doi.org/10.5194/acp-17-3637-2017, 2017.
Wang, X., Sultana, C. M., Trueblood, J., Hill, T. C. J., Malfatti, F., Lee, C., Laskina, O., Moore, K. A., Beall, C. M., McCluskey, C. S., Cornwell, G. C., Zhou, Y., Cox, J. L., Pendergraft, M. A., Santander, M. V., Bertram, T. H., Cappa, C. D., Azam, F., DeMott, P. J., Grassian, V. H., and Prather, K. A.: Microbial control of sea spray aerosol composition: A tale of two blooms, ACS Cent. Sci., 1, 124–131, https://doi.org/10.1021/acscentsci.5b00148, 2015.
Wang, X., Deane, G. B., Moore, K. A., Ryder, O. S., Stokes, M. D., Beall, C. M., Collins, D. B., Santander, M. V., Burrows, S. M., Sultana, C. M., and Prather, K. A.: The role of jet and film drops in controlling the mixing state of submicron sea spray aerosol particles, P. Natl. Acad. Sci. USA, 114, 6978–6983, https://doi.org/10.1073/pnas.1702420114, 2017.
Wilson, T. W., Ladino, L. A., Alpert, P. A., Breckels, M. N., Brooks, I. M., Browse, J., Burrows, S. M., Carslaw, K. S., Huffman, J. A., Judd, C., Kilthau, W. P., Mason, R. H., McFiggans, G., Miller, L. A., Najera, J. J., Polishchuk, E., Rae, S., Schiller, C. L., Si, M., Temprado, J. V., Whale, T. F., Wong, J. P. S., Wurl, O., Yakobi-Hancock, J. D., Abbatt, J. P. D., Aller, J. Y., Bertram, A. K., Knopf, D. A., and Murray, B. J.: A marine biogenic source of atmospheric ice-nucleating particles, Nature, 525, 234–238, https://doi.org/10.1038/nature14986, 2015.
Wolf, M. J., Goodell, M., Dong, E., Dove, L. A., Zhang, C., Franco, L. J., Shen, C., Rutkowski, E. G., Narducci, D. N., Mullen, S., Babbin, A. R., and Cziczo, D. J.: A link between the ice nucleation activity and the biogeochemistry of seawater, Atmos. Chem. Phys., 20, 15341–15356, https://doi.org/10.5194/acp-20-15341-2020, 2020.
Wu, J. T. and Chou, T. L.: Silicate as the limiting nutrient for phytoplankton in a subtropical eutrophic estuary of Taiwan, Estuar. Coast. Shelf S., 58, 155–162, https://doi.org/10.1016/S0272-7714(03)00070-2, 2003.
Wurl, O., Werner, E., Landing, W. M., and Zappa, C. J.: Sea surface microlayer in a changing ocean – A perspective, Elementa: Science of the Anthropocene, 5, 31, https://doi.org/10.1525/elementa.228, 2017.
Yakobi-Hancock, J. D., Ladino, L. A., and Abbatt, J. P. D.: Review of Recent Developments and Shortcomings in the Characterization of Potential Atmospheric Ice Nuclei: Focus on the Tropics, Rev. Ciencias, 17, 15–34, https://doi.org/10.25100/rc.v17i3.476, 2014.
Short summary
The present study shows the development of the UNAM-MARine Aerosol Tank (UNAM-MARAT), a device that simulates wave breaking to generate marine aerosol particles. The portable and automatic tank is able to generate particle concentrations as high as 2000 cm-3, covering a wide range of sizes, similar to those found in the ambient marine boundary layer. The sea spray aerosol generated from three natural seawater samples was found to act as ice-nucleating particles (INPs) via immersion freezing.
The present study shows the development of the UNAM-MARine Aerosol Tank (UNAM-MARAT), a device...
