Articles | Volume 12, issue 7
https://doi.org/10.5194/amt-12-3503-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-12-3503-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
02 Jul 2019
Research article |
| 02 Jul 2019
| 02 Jul 2019
Structural changes of CAST soot during a thermal–optical measurement protocol
Theresa Haller
Faculty of Physics, University of Vienna, Vienna, 1090, Austria
Christian Rentenberger
Faculty of Physics, University of Vienna, Vienna, 1090, Austria
Jannik C. Meyer
Faculty of Physics, University of Vienna, Vienna, 1090, Austria
Laura Felgitsch
Institute of Materials Chemistry, TU Wien, Vienna, 1060, Austria
Hinrich Grothe
Institute of Materials Chemistry, TU Wien, Vienna, 1060, Austria
Regina Hitzenberger
CORRESPONDING AUTHOR
Faculty of Physics, University of Vienna, Vienna, 1090, Austria
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Subject: Aerosols | Technique: Laboratory Measurement | Topic: Instruments and Platforms
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Organic aerosol constitutes a significant portion of atmospheric fine particles but is less characterized due to its vast number of constituents. Recently, we developed a system for online measurements of particle-phase highly oxygenated organic molecules (HOMs). In this work, we systematically characterized the system, developed a new unit to enhance its performance, and demonstrated the essential role of thermograms in inferring volatility and quantifying HOMs in organic aerosols.
Xubing Du, Qinhui Xie, Qing Huang, Xuan Li, Junlin Yang, Zhihui Hou, Jingjing Wang, Xue Li, Zhen Zhou, Zhengxu Huang, Wei Gao, and Lei Li
Atmos. Meas. Tech., 17, 1037–1050, https://doi.org/10.5194/amt-17-1037-2024, https://doi.org/10.5194/amt-17-1037-2024, 2024
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Currently, the limitations of single-particle mass spectrometry detection capabilities render it not yet well suited for analyzing complex aerosol components in low-concentration environments. In this study, a new high-performance single-particle aerosol mass spectrometer (HP-SPAMS) is developed to enhance instrument performance regarding the number of detected particles, transmission efficiency, resolution, and sensitivity, which will help in aerosol science.
Zhengning Xu, Jian Gao, Zhuanghao Xu, Michel Attoui, Xiangyu Pei, Mario Amo-González, Kewei Zhang, and Zhibin Wang
Atmos. Meas. Tech., 16, 5995–6006, https://doi.org/10.5194/amt-16-5995-2023, https://doi.org/10.5194/amt-16-5995-2023, 2023
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Planar differential mobility analyzers (DMAs) have higher ion transmission efficiency and sizing resolution compared to cylindrical DMAs and are more suitable for use with mass spectrometers (MSs). Performance of the latest planar DMA (P5) was characterized. Sizing resolution and ion transmission efficiency were 5–16 times and ∼10 times higher than cylindrical DMAs. Sulfuric acid clusters were measured by DMA(P5)-MSs. This technique can be applied for natural products and biomolecule analysis.
Virginia Vernocchi, Elena Abd El, Marco Brunoldi, Silvia Giulia Danelli, Elena Gatta, Tommaso Isolabella, Federico Mazzei, Franco Parodi, Paolo Prati, and Dario Massabò
Atmos. Meas. Tech., 16, 5479–5493, https://doi.org/10.5194/amt-16-5479-2023, https://doi.org/10.5194/amt-16-5479-2023, 2023
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Bioaerosol are airborne particles or droplets that contain living organisms or biological materials, such as bacteria, viruses, fungi, pollen, or other organic matter. The study of the relationship between bioaerosol viability and air quality or meteorological conditions is an open field, and running experiments of the bioareosol viability in an atmospheric simulation chamber gives the possibility to set up well-defined conditions to evaluate the interaction between bioaerosol and pollutants.
Mohit Singh, Stephanie Helen Jones, Alexei Kiselev, Denis Duft, and Thomas Leisner
Atmos. Meas. Tech., 16, 5205–5215, https://doi.org/10.5194/amt-16-5205-2023, https://doi.org/10.5194/amt-16-5205-2023, 2023
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We introduce a novel method for simultaneous measurement of the viscosity and surface tension of metastable liquids. Our approach is based on the phase analysis of excited shape oscillations in levitated droplets. It is applicable to a wide range of atmospheric conditions and can monitor changes in real time. The technique holds great promise for investigating the effect of atmospheric processing on the viscosity and surface tension of solution droplets in equilibrium with water vapour.
Sophie A. Mills, Adam Milsom, Christian Pfrang, A. Rob MacKenzie, and Francis D. Pope
Atmos. Meas. Tech., 16, 4885–4898, https://doi.org/10.5194/amt-16-4885-2023, https://doi.org/10.5194/amt-16-4885-2023, 2023
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Pollen grains are important components of the atmosphere and have the potential to impact upon cloud processes via their ability to help in the formation of rain droplets. This study investigates the hygroscopicity of two different pollen species using an acoustic levitator. Pollen grains are levitated, and their response to changes in relative humidity is investigated. A key advantage of this method is that it is possible study pollen shape under varying environmental conditions.
Alireza Moallemi, Robin L. Modini, Benjamin T. Brem, Barbara Bertozzi, Philippe Giaccari, and Martin Gysel-Beer
Atmos. Meas. Tech., 16, 3653–3678, https://doi.org/10.5194/amt-16-3653-2023, https://doi.org/10.5194/amt-16-3653-2023, 2023
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Polarimetric data, i.e., the angular and polarization dependence of light scattering by aerosols, contain ample information on optical and microphysical properties. Retrieval of these properties is a central approach in aerosol remote sensing. We present a description, calibration, validation, and a first application of a new benchtop polar nephelometer, which provides in situ polarimetric measurements of an aerosol. Such data facilitate agreement between retrieval results and independent data.
Taomou Zong, Zhijun Wu, Junrui Wang, Kai Bi, Wenxu Fang, Yanrong Yang, Xuena Yu, Zhier Bao, Xiangxinyue Meng, Yuheng Zhang, Song Guo, Yang Chen, Chunshan Liu, Yue Zhang, Shao-Meng Li, and Min Hu
Atmos. Meas. Tech., 16, 3679–3692, https://doi.org/10.5194/amt-16-3679-2023, https://doi.org/10.5194/amt-16-3679-2023, 2023
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This study developed and characterized an indoor chamber system (AIR) to simulate atmospheric multiphase chemistry processes. The AIR chamber can accurately control temperature and relative humidity (RH) over a broad range and simulate diurnal variation of ambient atmospheric RH. The aerosol generation unit can generate organic-coating seed particles with different phase states. The AIR chamber demonstrates high-quality performance in simulating secondary aerosol formation.
Marife B. Anunciado, Miranda De Boskey, Laura Haines, Katarina Lindskog, Tracy Dombek, Satoshi Takahama, and Ann M. Dillner
Atmos. Meas. Tech., 16, 3515–3529, https://doi.org/10.5194/amt-16-3515-2023, https://doi.org/10.5194/amt-16-3515-2023, 2023
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Organic sulfur compounds are used to identify sources and atmospheric processing of aerosol. Our paper evaluates the potential of using a non-destructive measurement technique to measure organic sulfur compounds in filter samples by assessing their chemical stability over time. Some were stable, but some evaporated or changed chemically. Future work includes evaluating the stability and potential interference of multiple organic sulfur compounds in laboratory mixtures and ambient aerosol.
Shipeng Kang, Tongzhu Yu, Yixin Yang, Jiguang Wang, Huaqiao Gui, Jianguo Liu, and Da-Ren Chen
Atmos. Meas. Tech., 16, 3245–3255, https://doi.org/10.5194/amt-16-3245-2023, https://doi.org/10.5194/amt-16-3245-2023, 2023
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A new aerosol electrometer, the thermal precipitation aerosol electrometer (TPAE), was designed for particles in sizes less than 300 nm, and its prototype performance was experimentally evaluated. The TPAE combines the thermal precipitator in the disk-to-disk configuration with a microcurrent measurement circuit board (i.e., pre-amplifier) for measuring the current carried by collected particles. Our performance study shows that the TPAE performance is consistent with the reference.
Battist Utinger, Steven John Campbell, Nicolas Bukowiecki, Alexandre Barth, Benjamin Gfeller, Ray Freshwater, Hans-Rudolf Rüegg, and Markus Kalberer
Atmos. Meas. Tech., 16, 2641–2654, https://doi.org/10.5194/amt-16-2641-2023, https://doi.org/10.5194/amt-16-2641-2023, 2023
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Exposure to atmospheric aerosols can lead to adverse health effect, but particle components responsible for this are unknown. Redox-active compounds, some with very short lifetimes, are considered to be a toxic class of compounds in particles. We developed the first online field instrument to quantify short-lived and stable redox-active compounds with a physiological assay based on ascorbic acid and a high time resolution and detection limits to allow measurements at unpolluted locations.
Ella Häkkinen, Jian Zhao, Frans Graeffe, Nicolas Fauré, Jordan E. Krechmer, Douglas Worsnop, Hilkka Timonen, Mikael Ehn, and Juha Kangasluoma
Atmos. Meas. Tech., 16, 1705–1721, https://doi.org/10.5194/amt-16-1705-2023, https://doi.org/10.5194/amt-16-1705-2023, 2023
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Highly oxygenated compounds contribute to the formation and growth of atmospheric organic aerosol and thus impact the global climate. Knowledge of their transformations and fate after condensing into the particle phase has been limited by the lack of suitable detection techniques. Here, we present an online method for measuring highly oxygenated compounds from organic aerosol. We evaluate the performance of the method and demonstrate that the method is applicable to different organic species.
Julia Pikmann, Lasse Moormann, Frank Drewnick, and Stephan Borrmann
Atmos. Meas. Tech., 16, 1323–1341, https://doi.org/10.5194/amt-16-1323-2023, https://doi.org/10.5194/amt-16-1323-2023, 2023
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Aerosols measured in complex environments are usually a mixture of emissions from different sources. To characterize sources individually, we developed a sampling system for particles and organic trace gases which is coupled to real-time data of physical and chemical aerosol properties, gas concentrations, and meteorological variables. Using suitable sampling conditions for individual aerosols which are compared with the real-time data the desired aerosols are sampled separately from each other.
Christopher R. Niedek, Fan Mei, Maria A. Zawadowicz, Zihua Zhu, Beat Schmid, and Qi Zhang
Atmos. Meas. Tech., 16, 955–968, https://doi.org/10.5194/amt-16-955-2023, https://doi.org/10.5194/amt-16-955-2023, 2023
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This novel micronebulization aerosol mass spectrometry (MS) technique requires a low sample volume (10 μL) and can quantify nanogram levels of organic and inorganic particulate matter (PM) components when used with 34SO4. This technique was successfully applied to PM samples collected from uncrewed atmospheric measurement platforms and provided chemical information that agrees well with real-time data from a co-located aerosol chemical speciation monitor and offline data from secondary ion MS.
Martin Rauber, Gary Salazar, Karl Espen Yttri, and Sönke Szidat
Atmos. Meas. Tech., 16, 825–844, https://doi.org/10.5194/amt-16-825-2023, https://doi.org/10.5194/amt-16-825-2023, 2023
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Carbon-containing aerosols from ambient air are analysed for radioactive isotope radiocarbon to determine the contribution from fossil-fuel emissions. Light-absorbing soot-like aerosols are isolated by water extraction and thermal separation. This separation is affected by artefacts, for which we developed a new correction method. The investigation of aerosols from the Arctic shows that our approach works well for such samples, where many artefacts are expected.
Alain Miffre, Danaël Cholleton, Clément Noël, and Patrick Rairoux
Atmos. Meas. Tech., 16, 403–417, https://doi.org/10.5194/amt-16-403-2023, https://doi.org/10.5194/amt-16-403-2023, 2023
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The depolarization ratio of hematite, silica, Arizona and Asian dust is evaluated in a lab with a π-polarimeter operating at lidar 180 ° and at (355, 532) nm wavelengths. The hematite depolarization equals (10±1) % at 355 nm for coarser particles, while that of silica is (33±1) %. This huge difference is explained by accounting for the high imaginary part of the hematite complex refractive index, thus revealing the key role played by light absorption in mineral dust lidar depolarization.
Miriam Chacón-Mateos, Bernd Laquai, Ulrich Vogt, and Cosima Stubenrauch
Atmos. Meas. Tech., 15, 7395–7410, https://doi.org/10.5194/amt-15-7395-2022, https://doi.org/10.5194/amt-15-7395-2022, 2022
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The study evaluates a low-cost dryer to avoid the negative effect of hygroscopic growth and fog droplets in the particulate matter (PM) concentrations of sensors. The results show a reduction in the overestimation of the PM but also an underestimation compared to reference devices. Special care is needed when designing a dryer as high temperatures change the sampled air by evaporating the most volatile particulate species. Low-cost dryers are very promising for different sensor applications.
Svetlana Sofieva, Eija Asmi, Nina S. Atanasova, Aino E. Heikkinen, Emeline Vidal, Jonathan Duplissy, Martin Romantschuk, Rostislav Kouznetsov, Jaakko Kukkonen, Dennis H. Bamford, Antti-Pekka Hyvärinen, and Mikhail Sofiev
Atmos. Meas. Tech., 15, 6201–6219, https://doi.org/10.5194/amt-15-6201-2022, https://doi.org/10.5194/amt-15-6201-2022, 2022
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A new bubble-generating glass chamber design with an extensive set of aerosol production experiments is presented to re-evaluate bubble-bursting-mediated aerosol production as a function of water parameters: bubbling air flow, water salinity, and temperature. Our main findings suggest modest dependence of aerosol production on the water salinity and a strong dependence on temperature below ~ 10 °C.
Kristian J. Kiland, Kevin L. Marroquin, Natalie R. Smith, Shaun Xu, Sergey A. Nizkorodov, and Allan K. Bertram
Atmos. Meas. Tech., 15, 5545–5561, https://doi.org/10.5194/amt-15-5545-2022, https://doi.org/10.5194/amt-15-5545-2022, 2022
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Information on the viscosity of secondary organic aerosols is needed when making air quality, climate, and atmospheric chemistry predictions. Viscosity depends on temperature, so we developed a new method for measuring the temperature-dependent viscosity of small samples. As an application of the method, we measured the viscosity of farnesene secondary organic aerosol at different temperatures.
Sabin Kasparoglu, Mohammad Maksimul Islam, Nicholas Meskhidze, and Markus D. Petters
Atmos. Meas. Tech., 15, 5007–5018, https://doi.org/10.5194/amt-15-5007-2022, https://doi.org/10.5194/amt-15-5007-2022, 2022
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A modified version of a Handix Scientific printed optical particle spectrometer is introduced. The paper presents characterization experiments, including concentration, size, and time responses. Integration of an external multichannel analyzer card removes counting limitations of the original instrument. It is shown that the high-resolution light-scattering amplitude data can be used to sense particle-phase transitions.
Nikunj Dudani and Satoshi Takahama
Atmos. Meas. Tech., 15, 4693–4707, https://doi.org/10.5194/amt-15-4693-2022, https://doi.org/10.5194/amt-15-4693-2022, 2022
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We designed and fabricated an aerosol collector with high collection efficiency that enables quantitative infrared spectroscopy analysis. By collecting particles on optical windows, typical substrate interferences are eliminated. New methods for fabricating aerosol devices using 3D printing with post-treatment to reduce the time and cost of prototyping are described.
Mao Du, Aristeidis Voliotis, Yunqi Shao, Yu Wang, Thomas J. Bannan, Kelly L. Pereira, Jacqueline F. Hamilton, Carl J. Percival, M. Rami Alfarra, and Gordon McFiggans
Atmos. Meas. Tech., 15, 4385–4406, https://doi.org/10.5194/amt-15-4385-2022, https://doi.org/10.5194/amt-15-4385-2022, 2022
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Atmospheric chemistry plays a key role in the understanding of aerosol formation and air pollution. We designed chamber experiments for the characterization of secondary organic aerosol (SOA) from a biogenic precursor with inorganic seed. Our results highlight the advantages of a combination of online FIGAERO-CIMS and offline LC-Orbitrap MS analytical techniques to characterize the chemical composition of SOA in chamber studies.
Chuan Ping Lee, Mihnea Surdu, David M. Bell, Josef Dommen, Mao Xiao, Xueqin Zhou, Andrea Baccarini, Stamatios Giannoukos, Günther Wehrle, Pascal André Schneider, Andre S. H. Prevot, Jay G. Slowik, Houssni Lamkaddam, Dongyu Wang, Urs Baltensperger, and Imad El Haddad
Atmos. Meas. Tech., 15, 3747–3760, https://doi.org/10.5194/amt-15-3747-2022, https://doi.org/10.5194/amt-15-3747-2022, 2022
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Real-time detection of both the gas and particle phase is needed to elucidate the sources and chemical reaction pathways of organic vapors and particulate matter. The Dual-EESI was developed to measure gas- and particle-phase species to provide new insights into aerosol sources or formation mechanisms. After characterizing the relative gas and particle response factors of EESI via organic aerosol uptake experiments, the Dual-EESI is more sensitive toward gas-phase analyes.
Martin I. Daily, Mark D. Tarn, Thomas F. Whale, and Benjamin J. Murray
Atmos. Meas. Tech., 15, 2635–2665, https://doi.org/10.5194/amt-15-2635-2022, https://doi.org/10.5194/amt-15-2635-2022, 2022
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Mineral dust and particles of biological origin are important types of ice-nucleating particles (INPs) that can trigger ice formation of supercooled cloud droplets. Heat treatments are used to detect the presence of biological INPs in samples collected from the environment as the activity of mineral INPs is assumed unchanged, although not fully assessed. We show that the ice-nucleating ability of some minerals can change after heating and discuss how INP heat tests should be interpreted.
Jiyan Wu, Chi Yang, Chunyan Zhang, Fang Cao, Aiping Wu, and Yanlin Zhang
Atmos. Meas. Tech., 15, 2623–2633, https://doi.org/10.5194/amt-15-2623-2022, https://doi.org/10.5194/amt-15-2623-2022, 2022
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We introduced an online method to simultaneously determine the content of inorganic salt ions and reactive oxygen species (ROS) in PM2.5 hour by hour. We verified the accuracy and precision of the instrument. And we got the daily changes in ROS and the main sources that affect ROS. This breakthrough enables the quantitative assessment of atmospheric particulate matter ROS at the diurnal scale, providing an effective tool to study sources and environmental impacts of ROS.
Virginia Vernocchi, Marco Brunoldi, Silvia G. Danelli, Franco Parodi, Paolo Prati, and Dario Massabò
Atmos. Meas. Tech., 15, 2159–2175, https://doi.org/10.5194/amt-15-2159-2022, https://doi.org/10.5194/amt-15-2159-2022, 2022
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The performance of a mini inverted soot generator was investigated at a simulation chamber facility by studying the soot generated by ethylene and propane combustion, together with the number, size, optical properties, and EC / OC concentrations. Mass absorption coefficients and Ångström absorption exponents are compatible with the literature, with some differences. The characterization of MISG soot particles is fundamental to design and perform experiments in atmospheric simulation chambers.
Magdalena Vallon, Linyu Gao, Feng Jiang, Bianca Krumm, Jens Nadolny, Junwei Song, Thomas Leisner, and Harald Saathoff
Atmos. Meas. Tech., 15, 1795–1810, https://doi.org/10.5194/amt-15-1795-2022, https://doi.org/10.5194/amt-15-1795-2022, 2022
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A LED-based light source has been constructed for the AIDA simulation chamber at the Karlsruhe Institute of Technology. It allows aerosol formation and ageing studies under atmospherically relevant illumination intensities and spectral characteristics at temperatures from –90 °C to 30 °C with the possibility of changing the photon flux and irradiation spectrum at any point. The first results of photolysis experiments with 2,3-pentanedione, iron oxalate and a brown carbon component are shown.
Danaël Cholleton, Émilie Bialic, Antoine Dumas, Pascal Kaluzny, Patrick Rairoux, and Alain Miffre
Atmos. Meas. Tech., 15, 1021–1032, https://doi.org/10.5194/amt-15-1021-2022, https://doi.org/10.5194/amt-15-1021-2022, 2022
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While pollen impacts public health and the Earth’s climate, the identification of each pollen taxon remains challenging. In this context, a laboratory evaluation of the polarimetric light-scattering characteristics of ragweed, ash, birch and pine pollen, when embedded in ambient air, is here performed at two wavelengths. Interestingly, the achieved precision of the retrieved scattering matrix elements allows unequivocal light scattering characteristics of each studied taxon to be identified.
Kanishk Gohil and Akua A. Asa-Awuku
Atmos. Meas. Tech., 15, 1007–1019, https://doi.org/10.5194/amt-15-1007-2022, https://doi.org/10.5194/amt-15-1007-2022, 2022
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This work develops a methodology and software to study and analyze the cloud-droplet-forming ability of aerosols with an aerodynamic aerosol classifier (AAC). This work quantifies the uncertainties in size-resolved measurements and subsequent uncertainties propagated to cloud droplet parameterizations. Lastly, we present the best practices for AAC cloud droplet measurement.
Yunqi Shao, Yu Wang, Mao Du, Aristeidis Voliotis, M. Rami Alfarra, Simon P. O'Meara, S. Fiona Turner, and Gordon McFiggans
Atmos. Meas. Tech., 15, 539–559, https://doi.org/10.5194/amt-15-539-2022, https://doi.org/10.5194/amt-15-539-2022, 2022
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A comprehensive description and characterisation of the Manchester Aerosol Chamber (MAC) was conducted. The MAC has good temperature and relative humidity homogeneity, fast mixing times, and comparable losses of gases and particles with other chambers. The MAC's bespoke control system allows improved duty cycles and repeatable experiments. Moreover, the effect of contamination on performance was also investigated. It is highly recommended to regularly track the chamber's performance.
Dina Alfaouri, Monica Passananti, Tommaso Zanca, Lauri Ahonen, Juha Kangasluoma, Jakub Kubečka, Nanna Myllys, and Hanna Vehkamäki
Atmos. Meas. Tech., 15, 11–19, https://doi.org/10.5194/amt-15-11-2022, https://doi.org/10.5194/amt-15-11-2022, 2022
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To study what is happening in the atmosphere, it is important to be able to measure the molecules and clusters present in it. In our work, we studied an artifact that happens inside a mass spectrometer, in particular the fragmentation of clusters. We were able to quantify the fragmentation and retrieve the correct concentration and composition of the clusters using our dual (experimental and theoretical) approach.
Sudheer Salana, Yixiang Wang, Joseph V. Puthussery, and Vishal Verma
Atmos. Meas. Tech., 14, 7579–7593, https://doi.org/10.5194/amt-14-7579-2021, https://doi.org/10.5194/amt-14-7579-2021, 2021
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Oxidative potential (OP) of particulate matter (PM) is an important indicator of PM toxicity. However, no automated instrument has ever been developed to provide a rapid high-throughput analysis of cell-based OP measurements. Here, we developed a semi-automated instrument, the first of its kind, for measuring oxidative potential using rat alveolar cells. We also developed a dataset on the intrinsic cellular OP of several compounds commonly known to be present in ambient PM.
Kevin B. Fischer and Giuseppe A. Petrucci
Atmos. Meas. Tech., 14, 7565–7577, https://doi.org/10.5194/amt-14-7565-2021, https://doi.org/10.5194/amt-14-7565-2021, 2021
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The viscosity of organic particles in atmospheric aerosol is sometimes correlated to bounce factor. It is generally accepted that more viscous particles will be more likely to bounce following acceleration toward and impaction on a surface. We demonstrate that use of multi-stage low-pressure impactors for this purpose may result in measurement artifacts that depend on chemical composition, particle size, and changing relative humidity. A hypothesis for the observed effect is presented.
Najin Kim, Yafang Cheng, Nan Ma, Mira L. Pöhlker, Thomas Klimach, Thomas F. Mentel, Ovid O. Krüger, Ulrich Pöschl, and Hang Su
Atmos. Meas. Tech., 14, 6991–7005, https://doi.org/10.5194/amt-14-6991-2021, https://doi.org/10.5194/amt-14-6991-2021, 2021
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A broad supersaturation scanning CCN (BS2-CCN) system, in which particles are exposed to a range of supersaturation simultaneously, can measure a broad range of CCN activity distribution with a high time resolution. We describe how the BS2-CCN system can be effectively calibrated and which factors can affect the calibration curve. Intercomparison experiments between typical DMA-CCN and BS2-CCN measurements to evaluate the BS2-CCN system showed high correlation and good agreement.
Chenyang Bi, Jordan E. Krechmer, Manjula R. Canagaratna, and Gabriel Isaacman-VanWertz
Atmos. Meas. Tech., 14, 6551–6560, https://doi.org/10.5194/amt-14-6551-2021, https://doi.org/10.5194/amt-14-6551-2021, 2021
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Calibration techniques have been recently developed to log-linearly correlate analyte sensitivity with CIMS operating conditions particularly for compounds without authentic standards. In this work, we examine the previously ignored bias in the log-linear-based calibration method and estimate an average bias of 30 %, with 1 order of magnitude for less sensitive compounds in some circumstances. A step-by-step guide was provided to reduce and even remove the bias.
Chuan Ping Lee, Mihnea Surdu, David M. Bell, Houssni Lamkaddam, Mingyi Wang, Farnoush Ataei, Victoria Hofbauer, Brandon Lopez, Neil M. Donahue, Josef Dommen, Andre S. H. Prevot, Jay G. Slowik, Dongyu Wang, Urs Baltensperger, and Imad El Haddad
Atmos. Meas. Tech., 14, 5913–5923, https://doi.org/10.5194/amt-14-5913-2021, https://doi.org/10.5194/amt-14-5913-2021, 2021
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Extractive electrospray ionization mass spectrometry (EESI-MS) has been deployed for high throughput online detection of particles with minimal fragmentation. Our study elucidates the extraction mechanism between the particles and electrospray (ES) droplets of different properties. The results show that the extraction rate is likely affected by the coagulation rate between the particles and ES droplets. Once coagulated, the particles undergo complete extraction within the ES droplet.
Weimeng Kong, Stavros Amanatidis, Huajun Mai, Changhyuk Kim, Benjamin C. Schulze, Yuanlong Huang, Gregory S. Lewis, Susanne V. Hering, John H. Seinfeld, and Richard C. Flagan
Atmos. Meas. Tech., 14, 5429–5445, https://doi.org/10.5194/amt-14-5429-2021, https://doi.org/10.5194/amt-14-5429-2021, 2021
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We present the design, modeling, and experimental characterization of the nano-scanning electrical mobility spectrometer (nSEMS), a recently developed instrument that probes particle physical properties in the 1.5–25 nm range. The nSEMS has proven to be extremely powerful in examining atmospheric nucleation and the subsequent growth of nanoparticles in the CERN CLOUD experiment, which provides a valuable asset to study atmospheric nanoparticles and to evaluate their impact on climate.
Jack M. Choczynski, Ravleen Kaur Kohli, Craig S. Sheldon, Chelsea L. Price, and James F. Davies
Atmos. Meas. Tech., 14, 5001–5013, https://doi.org/10.5194/amt-14-5001-2021, https://doi.org/10.5194/amt-14-5001-2021, 2021
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Relative humidity (RH) and hygroscopicity play an important role in regulating the physical, chemical, and optical properties of aerosol. In this work, we develop a new method to characterize hygroscopicity using particle levitation. We levitate two droplets with an electrodynamic balance and measure their size with light-scattering methods using one droplet as a probe of the RH. We demonstrate highly accurate and precise measurements of the RH and hygroscopic growth of a range of samples.
Yuhan Yang, Dong Gao, and Rodney J. Weber
Atmos. Meas. Tech., 14, 4707–4719, https://doi.org/10.5194/amt-14-4707-2021, https://doi.org/10.5194/amt-14-4707-2021, 2021
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Iron and copper are commonly found in ambient aerosols and have been linked to adverse health effects. We describe a relatively simple benchtop instrument that can be used to quantify these metals in aqueous solutions and verify the method by comparison with inductively coupled plasma mass spectrometry. The approach is based on forming light-absorbing metal–ligand complexes that can be measured with high sensitivity utilizing a long-path liquid waveguide capillary cell.
Stavros Amanatidis, Yuanlong Huang, Buddhi Pushpawela, Benjamin C. Schulze, Christopher M. Kenseth, Ryan X. Ward, John H. Seinfeld, Susanne V. Hering, and Richard C. Flagan
Atmos. Meas. Tech., 14, 4507–4516, https://doi.org/10.5194/amt-14-4507-2021, https://doi.org/10.5194/amt-14-4507-2021, 2021
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We assess the performance of a highly portable mobility analyzer, the Spider DMA, in measuring ambient aerosol particle size distributions, with specific attention to its moderate sizing resolution (R=3). Long-term field testing showed excellent correlation with a conventional mobility analyzer (R=10) over the 17–500 nm range, suggesting that moderate resolution may be sufficient to obtain key properties of ambient size distributions, enabling smaller instruments and better counting statistics.
Cited articles
Adachi, K. and Buseck, P. R.: Changes of ns-soot mixing states and shapes in
an urban area during CalNex, J. Geophys. Res., 9, 3723–3730, https://doi.org/10.1002/jgrd.50321, 2013.
Adachi, K., Chung, S. H., and Buseck, P. R.: Shapes of soot aerosol particles
and implications for their effects on climate, J. Geophys. Res., D15,
6469, https://doi.org/10.1029/2009JD012868, 2010.
Anderson, J. O., Thundiyil, J. G., and Stolbach, A.: Clearing the air. A
review of the effects of particulate matter air pollution on human health, J.
Med. Toxicol., 2, 166–175, https://doi.org/10.1007/s13181-011-0203-1, 2012.
Andreae, M. O. and Gelencsér, A.: Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols, Atmos. Chem. Phys., 6, 3131–3148, https://doi.org/10.5194/acp-6-3131-2006, 2006.
Arnott, W. P., Moosmüller, H., Fred Rogers, C., Jin, T., and Bruch, R.:
Photoacoustic spectrometer for measuring light absorption by aerosol.
Instrument description, Atmos. Environ., 17, 2845–2852, https://doi.org/10.1016/S1352-2310(98)00361-6, 1999.
Aryal, R., Terman, P., and Voss, K. J.: Comparison of Two Filter-Based
Reflectance Methods to Measure the Light Absorption by Atmospheric Aerosols,
J. Atmos. Ocean. Tech., 4, 923–929, https://doi.org/10.1175/JTECH-D-13-00131.1,
2014.
Birch, M. E. and Cary, R. A.: Elemental Carbon-Based Method for Monitoring
Occupational Exposures to Particulate Diesel Exhaust, Aerosol Sci.
Technol., 3, 221–241, https://doi.org/10.1080/02786829608965393, 1996.
Bladt, H., Ivleva, N. P., and Niessner, R.: Internally mixed multicomponent
soot. Impact of different salts on soot structure and thermo-chemical
properties, J. Aerosol Sci., 70, 26–35, https://doi.org/10.1016/j.jaerosci.2013.11.007, 2014.
Bohren, C. F. and Huffman, D. R.: Absorption and Scattering of Light by Small Particles, Wiley, New York, 1998.
Bond, T. C.: Spectral dependence of visible light absorption by carbonaceous
particles emitted from coal combustion, Geophys. Res. Lett., 21, 4075–4078,
https://doi.org/10.1029/2001GL013652, 2001.
Bond, T. C. and Bergstrom, R. W.: Light Absorption by Carbonaceous
Particles. An Investigative Review, Aerosol Sci. Technol., 1,
27–67, https://doi.org/10.1080/02786820500421521, 2006.
Bondy, A. L., Bonanno, D., Moffet, R. C., Wang, B., Laskin, A., and Ault, A. P.: The diverse chemical mixing state of aerosol particles in the southeastern United States, Atmos. Chem. Phys., 18, 12595–12612, https://doi.org/10.5194/acp-18-12595-2018, 2018.
Brown, R. J. C., Beccaceci, S., Butterfield, D. M., Quincey, P. G., Harris,
P. M., Maggos, T., Panteliadis, P., John, A., Jedynska, A., Kuhlbusch, T. A.
J., Putaud, J.-P., and Karanasiou, A.: Standardisation of a European
measurement method for organic carbon and elemental carbon in ambient air.
Results of the field trial campaign and the determination of a measurement
uncertainty and working range, Environ. Sci.-Pro. Imp., 10,
1249–1259, https://doi.org/10.1039/C7EM00261K, 2017.
Buseck, P. R., Adachi, K., Gelencsér, A., Tompa, É., and Pósfai,
M.: Ns-Soot. A Material-Based Term for Strongly Light-Absorbing Carbonaceous
Particles, Aerosol Sci. Technol., 7, 777–788, https://doi.org/10.1080/02786826.2014.919374, 2014.
Cappa, C. D., Onasch, T. B., Massoli, P.,
Worsnop, D. R., Bates, T. S., Cross, E. S., Davidovits, P., Hakala, J.,
Hayden, K. L., Jobson, B. T., Kolesar, K. R., Lack, D. A., Lerner, B. M.,
Li, S.-M., Mellon, D., Nuaaman, I., Olfert, J. S., Petäjä, T.,
Quinn, P. K., Song, C., Subramanian, R., Williams, E. J., and Zaveri, R. A.:
Radiative absorption enhancements due to the mixing state of atmospheric
black carbon, Science, 6098, 1078–1081, https://doi.org/10.1126/science.1223447, 2012.
Cavalli, F., Viana, M., Yttri, K. E., Genberg, J., and Putaud, J.-P.: Toward a standardised thermal-optical protocol for measuring atmospheric organic and elemental carbon: the EUSAAR protocol, Atmos. Meas. Tech., 3, 79–89, https://doi.org/10.5194/amt-3-79-2010, 2010.
Cheng, Y., Duan, F.-K., He, K.-B., Du, Z.-Y., Zheng, M., and Ma, Y.-L.:
Intercomparison of thermal-optical method with different temperature
protocols. Implications from source samples and solvent extraction,
Atmos. Environ., 453–462, https://doi.org/10.1016/j.atmosenv.2012.07.066,
2012.
Chhowalla, M., Robertson, J., Chen, C. W., Silva, S. R. P., Davis, C. A.,
Amaratunga, G. A. J., and Milne, W. I.: Influence of ion energy and substrate
temperature on the optical and electronic properties of tetrahedral
amorphous carbon (ta-C) films, J. Appl. Phys., 1, 139–145,
https://doi.org/10.1063/1.364000, 1997.
China, S., Mazzoleni, C., Gorkowski, K., Aiken, A. C., and Dubey, M. K.:
Morphology and mixing state of individual freshly emitted wildfire
carbonaceous particles, Nat. Commun., 4, 2122, https://doi.org/10.1038/ncomms3122, 2013.
Chow, J. C., Watson, J. G., Chen, L.-W. A., Arnott, W. P., Moosmüller,
H., and Fung, K.: Equivalence of Elemental Carbon by Thermal/Optical
Reflectance and Transmittance with Different Temperature Protocols, Environ.
Sci. Technol., 16, 4414–4422, https://doi.org/10.1021/es034936u, 2004.
Commodo, M., de Falco, G., Larciprete, R., D'Anna, A., and Minutolo, P.: On
the hydrophilic/hydrophobic character of carbonaceous nanoparticles formed
in laminar premixed flames, Exp. Therm. Fl. Sci., 73, 56–63,
https://doi.org/10.1016/j.expthermflusci.2015.09.005, 2016.
Cuesta, A., Dhamelincourt, P., Laureyns, J., Martínez-Alonso, A., and
Tascón, J. M. D.: Raman microprobe studies on carbon materials, Carbon, 8,
1523–1532, https://doi.org/10.1016/0008-6223(94)90148-1, 1994.
Deboudt, K., Flament, P., Choël, M., Gloter, A., Sobanska, S., and
Colliex, C.: Mixing state of aerosols and direct observation of carbonaceous
and marine coatings on African dust by individual particle analysis, J. Geophys. Res., D24, 833, https://doi.org/10.1029/2010JD013921, 2010.
Després, V., Huffman, J. A., Burrows, S. M., Hoose, C., Safatov, A.,
Buryak, G., Fröhlich-Nowoisky, J., Elbert, W., Andreae, M., Pöschl,
U., and Jaenicke, R.: Primary biological aerosol particles in the atmosphere.
A review, Tellus B, 1, 15598, https://doi.org/10.3402/tellusb.v64i0.15598, 2012.
Dippel, B., Jander, H., and Heintzenberg, J.: NIR FT Raman spectroscopic
study of flame soot, Phys. Chem. Chem. Phys., 20, 4707–4712, https://doi.org/10.1039/a904529e, 1999.
EEA: Air Quality in Europe – 2017 Report, EAA report, Copenhagen, 2017.
Ess, M. N., Ferry, D., Kireeva, E. D., Niessner, R., Ouf, F.-X., and Ivleva,
N. P.: In situ Raman microspectroscopic analysis of soot samples with
different organic carbon content. Structural changes during heating, Carbon, 105,
572–585, https://doi.org/10.1016/j.carbon.2016.04.056, 2016.
Fan, X., Wei, S., Zhu, M., Song, J., and Peng, P.: Comprehensive characterization of humic-like substances in smoke PM2.5 emitted from the combustion of biomass materials and fossil fuels, Atmos. Chem. Phys., 16, 13321–13340, https://doi.org/10.5194/acp-16-13321-2016, 2016.
Ferrari, A. C. and Robertson, J.: Interpretation of Raman spectra of
disordered and amorphous carbon, Phys. Rev. B, 20, 14095–14107, https://doi.org/10.1103/PhysRevB.61.14095, 2000.
Fultz, B. and Howe, J. M.: Transmission electron microscopy and
diffractometry of materials, Physics and astronomy online
library, Springer, Berlin, 2001.
Gammer, C., Mangler, C., Rentenberger, C., and Karnthaler, H. P.:
Quantitative local profile analysis of nanomaterials by electron
diffraction, Scripta Materialia, 3, 312–315, https://doi.org/10.1016/j.scriptamat.2010.04.019, 2010.
Graber, E. R. and Rudich, Y.: Atmospheric HULIS: How humic-like are they? A comprehensive and critical review, Atmos. Chem. Phys., 6, 729–753, https://doi.org/10.5194/acp-6-729-2006, 2006.
Highwood, E. J. and Kinnersley, R. P.: When smoke gets in our eyes. The
multiple impacts of atmospheric black carbon on climate, air quality and
health, Environ. Int., 4, 560–566, https://doi.org/10.1016/j.envint.2005.12.003, 2006.
Hitzenberger, R. and Tohno, S.: Comparison of black carbon (BC) aerosols in
two urban areas – concentrations and size distributions, Atmos.
Environ., 12, 2153–2167, https://doi.org/10.1016/S1352-2310(00)00480-5, 2001.
Hitzenberger, R., Petzold, A., Bauer, H., Ctyroky, P., Pouresmaeil, P.,
Laskus, L., and Puxbaum, H.: Intercomparison of Thermal and Optical
Measurement Methods for Elemental Carbon and Black Carbon at an Urban
Location, Environ. Sci. Technol., 20, 6377–6383, https://doi.org/10.1021/es051228v,
2006.
Hoffer, A., Gelencsér, A., Blazsó, M., Guyon, P., Artaxo, P., and Andreae, M. O.: Diel and seasonal variations in the chemical composition of biomass burning aerosol, Atmos. Chem. Phys., 6, 3505–3515, https://doi.org/10.5194/acp-6-3505-2006, 2006.
Ichikawa, Y. and Naito, S.: Chemical Compositions of Primary PM2.5 Derived
from Biomass Burning Emissions, Ajae, 11, 79–95, https://doi.org/10.5572/ajae.2017.11.2.079, 2017.
IPCC: Clouds and
Aerosols. Climate Change 2013: The Physical Science Basis. Contribution of
Working Group I to the Fifth Assessment Report of the Intergovernmental
Panel on Climate Change, edited by: Stocker, T. F., Qin, D., Plattner, G.-K., Tignor, M., Allen,
S. K., Boschung, J., Nauels, A., Xia, Y., Bex, V., and Midgley, P. M.,
Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA,
2013.
Ivleva, N. P., McKeon, U., Niessner, R., and Pöschl, U.: Raman
Microspectroscopic Analysis of Size-Resolved Atmospheric Aerosol Particle
Samples Collected with an ELPI. Soot, Humic-Like Substances, and Inorganic
Compounds, Aerosol Sci. Technol., 7, 655–671, https://doi.org/10.1080/02786820701376391, 2007a.
Ivleva, N. P., Messerer, A., Yang, X., Niessner, R., and Pöschl, U.:
Raman Microspectroscopic Analysis of Changes in the Chemical Structure and
Reactivity of Soot in a Diesel Exhaust Aftertreatment Model System, Environ.
Sci. Technol., 10, 3702–3707, https://doi.org/10.1021/es0612448, 2007b.
Jankowski, N., Schmidl, C., Marr, I. L., Bauer, H., and Puxbaum, H.:
Comparison of methods for the quantification of carbonate carbon in
atmospheric PM10 aerosol samples, Atmos. Environ., 34, 8055–8064,
https://doi.org/10.1016/j.atmosenv.2008.06.012, 2008.
Jawhari, T., Roid, A., and Casado, J.: Raman spectroscopic characterization
of some commercially available carbon black materials, Carbon, 11,
1561–1565, https://doi.org/10.1016/0008-6223(95)00117-V, 1995.
Kim, J., Bauer, H., Dobovičnik, T., Hitzenberger, R., Lottin, D., Ferry,
D., and Petzold, A.: Assessing Optical Properties and Refractive Index of
Combustion Aerosol Particles Through Combined Experimental and Modeling
Studies, Aerosol Sci. Technol., 5, 340–350, https://doi.org/10.1080/02786826.2015.1020996, 2015.
Knauer, M., Schuster, M. E., Su, D., Schlögl, R., Niessner, R., and
Ivleva, N. P.: Soot Structure and Reactivity Analysis by Raman
Microspectroscopy, Temperature-Programmed Oxidation, and High-Resolution
Transmission Electron Microscopy, J. Phys. Chem. A, 50, 13871–13880, https://doi.org/10.1021/jp905639d, 2009.
Kubelka, P. and Munk, F.: Ein Beitrag zur Optik der Farbanstriche,
Zeitschrift für Technische Physik, 12, 593–601, 1931.
Mamakos, A., Khalek, I., Giannelli, R., and Spears, M.: Characterization of
Combustion Aerosol Produced by a Mini-CAST and Treated in a Catalytic
Stripper, Aerosol Sci. Technol., 8, 927–936, https://doi.org/10.1080/02786826.2013.802762, 2013.
Mayol-Bracero, O. L.: Water-soluble organic compounds in biomass burning
aerosols over Amazonia 2. Apportionment of the chemical composition and
importance of the polyacidic fraction, J. Geophys. Res., D20, 995, https://doi.org/10.1029/2001JD000522, 2002.
McNeill, V. F.: Atmospheric Aerosols. Clouds, Chemistry, and Climate, Annu.
Rev. Chem. Biomol. Eng., 1, 427–444, https://doi.org/10.1146/annurev-chembioeng-060816-101538, 2017.
Mesquita, S. R., van Drooge, B. L., Dall'Osto, M., Grimalt, J. O., Barata,
C., Vieira, N., Guimarães, L., and Piña, B.: Toxic potential of
organic constituents of submicron particulate matter (PM1) in an urban road
site (Barcelona), Environ. Sci. Pollut. Res., 18, 15406–15415, https://doi.org/10.1007/s11356-017-9201-4, 2017.
Moore, R. H., Ziemba, L. D., Dutcher, D., Beyersdorf, A. J., Chan, K.,
Crumeyrolle, S., Raymond, T. M., Thornhill, K. L., Winstead, E. L., and
Anderson, B. E.: Mapping the Operation of the Miniature Combustion Aerosol
Standard (Mini-CAST) Soot Generator, Aerosol Sci. Technol., 5,
467–479, https://doi.org/10.1080/02786826.2014.890694, 2014.
Moosmüller, H., Arnott, W. P., Rogers, C. F., Chow, J. C., Frazier, C.
A., Sherman, L. E., and Dietrich, D. L.: Photoacoustic and filter
measurements related to aerosol light absorption during the Northern Front
Range Air Quality Study (Colorado 1996/1997), J. Geophys. Res., D21,
28149–28157, https://doi.org/10.1029/98JD02618, 1998.
Müller, K., Spindler, G., Maenhaut, W., Hitzenberger, R., Wieprecht, W.,
Baltensperger, U., and ten Brink, H.: INTERCOMP2000, a campaign to assess the
comparability of methods in use in Europe for measuring aerosol composition,
Atmos. Environ., 38, 6459–6466, https://doi.org/10.1016/j.atmosenv.2004.08.031, 2004.
Okada, K. and Hitzenberger, R. M.: Mixing properties of individual
submicrometer aerosol particles in Vienna, Atmos. Environ., 32,
5617–5628, https://doi.org/10.1016/S1352-2310(01)00126-1, 2001.
Panteliadis, P., Hafkenscheid, T., Cary, B., Diapouli, E., Fischer, A., Favez, O., Quincey, P., Viana, M., Hitzenberger, R., Vecchi, R., Saraga, D., Sciare, J., Jaffrezo, J. L., John, A., Schwarz, J., Giannoni, M., Novak, J., Karanasiou, A., Fermo, P., and Maenhaut, W.: ECOC comparison exercise with identical thermal protocols after temperature offset correction – instrument diagnostics by in-depth evaluation of operational parameters, Atmos. Meas. Tech., 8, 779–792, https://doi.org/10.5194/amt-8-779-2015, 2015.
Park, S. S. and Yu, J.: Chemical and light absorption properties of
humic-like substances from biomass burning emissions under controlled
combustion experiments, Atmos. Environ., 136, 114–122, https://doi.org/10.1016/j.atmosenv.2016.04.022, 2016.
Park, S., Son, S.-C., and Lee, S.: Characterization, sources, and light
absorption of fine organic aerosols during summer and winter at an urban
site, Atmos. Res., 213, 370–380, https://doi.org/10.1016/j.atmosres.2018.06.017, 2018.
Partanen, A.-I., Landry, J.-S., and Matthews, H. D.: Climate and health
implications of future aerosol emission scenarios, Environ. Res. Lett., 13, 024028,
https://doi.org/10.1088/1748-9326/aaa511, 2018.
Petzold, A., Ogren, J. A., Fiebig, M., Laj, P., Li, S.-M., Baltensperger, U., Holzer-Popp, T., Kinne, S., Pappalardo, G., Sugimoto, N., Wehrli, C., Wiedensohler, A., and Zhang, X.-Y.: Recommendations for reporting “black carbon” measurements, Atmos. Chem. Phys., 13, 8365–8379, https://doi.org/10.5194/acp-13-8365-2013, 2013.
Pöschl, U.: Atmospheric Aerosols. Composition, Transformation, Climate
and Health Effects, Angew. Chem. Int. Ed., 46, 7520–7540, https://doi.org/10.1002/anie.200501122, 2005.
Pratt, K. A. and Prather, K. A.: Aircraft measurements of vertical profiles
of aerosol mixing states, J. Geophys. Res., D11, 3131, https://doi.org/10.1029/2009JD013150, 2010.
Reisinger, P., Wonaschütz, A., Hitzenberger, R., Petzold, A., Bauer, H.,
Jankowski, N., Puxbaum, H., Chi, X., and Maenhaut, W.: Intercomparison of
Measurement Techniques for Black or Elemental Carbon Under Urban Background
Conditions in Wintertime. Influence of Biomass Combustion, Environ. Sci.
Technol., 3, 884–889, https://doi.org/10.1021/es0715041, 2008.
Robertson, J. and O'Reilly, E. P.: Electronic and atomic structure of amorphous carbon, Phys. Rev. B, 6, 2946–2957, https://doi.org/10.1103/PhysRevB.35.2946, 1987.
Rohr, A. and McDonald, J.: Health effects of carbon-containing particulate
matter. Focus on sources and recent research program results, Crit.
Rev. Toxicol., 2, 97–137, https://doi.org/10.3109/10408444.2015.1107024, 2015.
Rosen, H. and Novakov, T.: Identification of primary particulate carbon and
sulfate species by Raman spectroscopy, Atmos. Environ., 12,
923–927, https://doi.org/10.1016/0004-6981(78)90031-8, 1978.
Sadezky, A., Muckenhuber, H., Grothe, H., Niessner, R., and Pöschl, U.:
Raman microspectroscopy of soot and related carbonaceous materials. Spectral
analysis and structural information, Carbon, 8, 1731–1742, https://doi.org/10.1016/j.carbon.2005.02.018, 2005.
Schmid, J., Grob, B., Niessner, R., and Ivleva, N. P.: Multiwavelength Raman
Microspectroscopy for Rapid Prediction of Soot Oxidation Reactivity, Anal.
Chem., 4, 1173–1179, https://doi.org/10.1021/ac102939w, 2011.
Schmidl, C., Bauer, H., Dattler, A., Hitzenberger, R., Weissenboeck, G.,
Marr, I. L., and Puxbaum, H.: Chemical characterisation of particle emissions
from burning leaves, Atmos. Environ., 40, 9070–9079, https://doi.org/10.1016/j.atmosenv.2008.09.010, 2008.
Schwarz, J. P., Gao, R. S., Fahey, D. W., Thomson, D. S., Watts, L. A.,
Wilson, J. C., Reeves, J. M., Darbeheshti, M., Baumgardner, D. G., Kok, G.
L., Chung, S. H., Schulz, M., Hendricks, J., Lauer, A., Kärcher, B.,
Slowik, J. G., Rosenlof, K. H., Thompson, T. L., Langford, A. O.,
Loewenstein, M., and Aikin, K. C.: Single-particle measurements of
midlatitude black carbon and light-scattering aerosols from the boundary
layer to the lower stratosphere, J. Geophys. Res., D16, 2845, https://doi.org/10.1029/2006JD007076, 2006.
Sedlacek, A. J., Onasch, T. B., Nichman, L., Lewis, E. R., Davidovits, P.,
Freedman, A., and Williams, L.: Formation of refractory black carbon by
SP2-induced charring of organic aerosol, Aerosol Sci. Technol., 12,
1345–1350, https://doi.org/10.1080/02786826.2018.1531107, 2018.
Stadelmann, P.: Java Electron Microscopy Software JEMS, available at:
https://cime.epfl.ch/ (last access: 7 June 2019), 2004.
Stephens, M., Turner, N., and Sandberg, J.: Particle identification by
laser-induced incandescence in a solid-state laser cavity, Appl. Optics, 19,
3726, https://doi.org/10.1364/AO.42.003726, 2003.
Sun, H., Biedermann, L., and Bond, T. C.: Color of brown carbon. A model for
ultraviolet and visible light absorption by organic carbon aerosol, Geophys.
Res. Lett., 17, 3131, https://doi.org/10.1029/2007GL029797, 2007.
Sun, J., Zhi, G., Hitzenberger, R., Chen, Y., Tian, C., Zhang, Y., Feng, Y., Cheng, M., Zhang, Y., Cai, J., Chen, F., Qiu, Y., Jiang, Z., Li, J., Zhang, G., and Mo, Y.: Emission factors and light absorption properties of brown carbon from household coal combustion in China, Atmos. Chem. Phys., 17, 4769–4780, https://doi.org/10.5194/acp-17-4769-2017, 2017.
Sze, S. K., Siddique, N., Sloan, J. J., and Escribano, R.: Raman
spectroscopic characterization of carbonaceous aerosols, Atmos.
Environ., 3, 561–568, https://doi.org/10.1016/S1352-2310(00)00325-3, 2001.
Tuinstra, F. and Koenig, J. L.: Raman Spectrum of Graphite, J.
Chem. Phys., 3, 1126–1130, https://doi.org/10.1063/1.1674108, 1970.
Venkatachari, P., Zhou, L., Hopke, P. K., Schwab, J. J., Demerjian, K. L.,
Weimer, S., Hogrefe, O., Felton, D., and Rattigan, O.: An Intercomparison of
Measurement Methods for Carbonaceous Aerosol in the Ambient Air in New York
City, Aerosol Sci. Technol., 40, 788–795, https://doi.org/10.1080/02786820500380289, 2006.
Wang, Y., Chung, A., and Paulson, S. E.: The effect of metal salts on quantification of elemental and organic carbon in diesel exhaust particles using thermal-optical evolved gas analysis, Atmos. Chem. Phys., 10, 11447–11457, https://doi.org/10.5194/acp-10-11447-2010, 2010.
Watson, J. G., Chow, J. C., and Chen, L. W. A.: Summary of Organic and
Elemental Carbon/Black Carbon Analysis Methods and Intercomparisons,
Aerosol Air Qual. Res., 5, 65–102, 2005.
Wonaschütz, A., Hitzenberger, R., Bauer, H., Pouresmaeil, P., Klatzer,
B., Caseiro, A., and Puxbaum, H.: Application of the Integrating Sphere
Method to Separate the Contributions of Brown and Black Carbon in
Atmospheric Aerosols, Environ. Sci. Technol., 43, 1141–1146, https://doi.org/10.1021/es8008503, 2009.
Ye, Q., Gu, P., Li, H. Z., Robinson, E. S., Lipsky, E., Kaltsonoudis, C., Lee, A. K. Y., Apte, J. S., Robinson, A. L., Sullivan, R. C., Presto, A. A., and Donahue, N. M.: Spatial Variability of Sources and Mixing State of Atmospheric Particles in a Metropolitan Area, Environ. Sci. Technol., 12, 6807–6815, https://doi.org/10.1021/acs.est.8b01011, 2018.
Yttri, K. E., Aas, W., Bjerke, A., Cape, J. N., Cavalli, F., Ceburnis, D., Dye, C., Emblico, L., Facchini, M. C., Forster, C., Hanssen, J. E., Hansson, H. C., Jennings, S. G., Maenhaut, W., Putaud, J. P., and Tørseth, K.: Elemental and organic carbon in PM10: a one year measurement campaign within the European Monitoring and Evaluation Programme EMEP, Atmos. Chem. Phys., 7, 5711–5725, https://doi.org/10.5194/acp-7-5711-2007, 2007.
Yu, J. Z., Xu, J., and Yang, H.: Charring Characteristics of Atmospheric
Organic Particulate Matter in Thermal Analysis, Environ. Sci. Technol., 36,
754–761, https://doi.org/10.1021/es015540q, 2002.
Zhang, G., Bi, X., He, J., Chen, D., Lo Chan, Y., Xie, G., Wang, X., Sheng, G., Fu, J., and Zhou, Z.: Variation of secondary coatings associated with elemental carbon by single particle analysis, Atmos. Environ., 92, 162–170, https://doi.org/10.1016/j.atmosenv.2014.04.018, 2014.
Zhu, Y., Huang, L., Li, J., Ying, Q., Zhang, H., Liu, X., Liao, H., Li, N.,
Liu, Z., Mao, Y., Fang, H., and Hu, J.: Sources of particulate matter in
China. Insights from source apportionment studies published in 1987–2017,
Environ. Int., 115, 343–357, https://doi.org/10.1016/j.envint.2018.03.037,
2018.
Zickler, G. A., Smarsly, B., Gierlinger, N., Peterlik, H., and Paris, O.: A
reconsideration of the relationship between the crystallite size La of
carbons determined by X-ray diffraction and Raman spectroscopy, Carbon, 44,
3239–3246, https://doi.org/10.1016/j.carbon.2006.06.029, 2006.
Short summary
In thermal–optical measurement techniques – widely used techniques to separate organic and elemental carbon – a filter sample is heated stepwise first in He and then in He+O2. Pyrolysis of organic material occurring during heating in He influences the results but is not fully understood. In this study, structural changes of carbonaceous material during a thermal–optical heating procedure are analyzed with Raman spectroscopy, TEM, UV–VIS and the integrating-sphere method.
In thermal–optical measurement techniques – widely used techniques to separate organic and...
