Articles | Volume 12, issue 12
https://doi.org/10.5194/amt-12-6259-2019
https://doi.org/10.5194/amt-12-6259-2019
Research article
 | 
29 Nov 2019
Research article |  | 29 Nov 2019

Caution with spectroscopic NO2 reference cells (cuvettes)

Ulrich Platt and Jonas Kuhn

Related authors

Assessment of laboratory O4 absorption cross-sections at 360 nm using atmospheric long-path DOAS observations
Bianca Lauster, Udo Frieß, Jan-Marcus Nasse, Ulrich Platt, and Thomas Wagner
EGUsphere, https://doi.org/10.5194/egusphere-2024-3881,https://doi.org/10.5194/egusphere-2024-3881, 2025
Short summary
A new accurate retrieval algorithm of bromine monoxide columns inside minor volcanic plumes from Sentinel-5P TROPOMI observations
Simon Warnach, Holger Sihler, Christian Borger, Nicole Bobrowski, Steffen Beirle, Ulrich Platt, and Thomas Wagner
Atmos. Meas. Tech., 16, 5537–5573, https://doi.org/10.5194/amt-16-5537-2023,https://doi.org/10.5194/amt-16-5537-2023, 2023
Short summary
New methods for the calibration of optical resonators: integrated calibration by means of optical modulation (ICOM) and narrow-band cavity ring-down (NB-CRD)
Henning Finkenzeller, Denis Pöhler, Martin Horbanski, Johannes Lampel, and Ulrich Platt
Atmos. Meas. Tech., 16, 1343–1356, https://doi.org/10.5194/amt-16-1343-2023,https://doi.org/10.5194/amt-16-1343-2023, 2023
Short summary
Source mechanisms and transport patterns of tropospheric bromine monoxide: findings from long-term multi-axis differential optical absorption spectroscopy measurements at two Antarctic stations
Udo Frieß, Karin Kreher, Richard Querel, Holger Schmithüsen, Dan Smale, Rolf Weller, and Ulrich Platt
Atmos. Chem. Phys., 23, 3207–3232, https://doi.org/10.5194/acp-23-3207-2023,https://doi.org/10.5194/acp-23-3207-2023, 2023
Short summary
Ozone depletion events in the Arctic spring of 2019: a new modeling approach to bromine emissions
Maximilian Herrmann, Moritz Schöne, Christian Borger, Simon Warnach, Thomas Wagner, Ulrich Platt, and Eva Gutheil
Atmos. Chem. Phys., 22, 13495–13526, https://doi.org/10.5194/acp-22-13495-2022,https://doi.org/10.5194/acp-22-13495-2022, 2022
Short summary

Related subject area

Subject: Gases | Technique: Remote Sensing | Topic: Instruments and Platforms
Maximizing the scientific application of Pandora column observations of HCHO and NO2
Prajjwal Rawat, James H. Crawford, Katherine R. Travis, Laura M. Judd, Mary Angelique G. Demetillo, Lukas C. Valin, James J. Szykman, Andrew Whitehill, Eric Baumann, and Thomas F. Hanisco
Atmos. Meas. Tech., 18, 2899–2917, https://doi.org/10.5194/amt-18-2899-2025,https://doi.org/10.5194/amt-18-2899-2025, 2025
Short summary
Comment on "Design study for an airborne N2O lidar" by Kiemle et al. (2024)
Joel F. Campbell, Bing Lin, and Zhaoyan Liu
EGUsphere, https://doi.org/10.5194/egusphere-2025-1448,https://doi.org/10.5194/egusphere-2025-1448, 2025
Short summary
Expanding Observational Capabilities of A Diode-Laser-Based Lidar Through Shot-To-Shot Modification of Laser Pulse Characteristics
Robert A. Stillwell, Adam Karboski, Matthew Hayman, and Scott M. Spuler
EGUsphere, https://doi.org/10.5194/egusphere-2025-1288,https://doi.org/10.5194/egusphere-2025-1288, 2025
Short summary
Retrieval simulations of a spaceborne differential absorption radar near the 380 GHz water vapor line
Luis F. Millán, Matthew D. Lebsock, and Marcin J. Kurowski
EGUsphere, https://doi.org/10.5194/egusphere-2025-322,https://doi.org/10.5194/egusphere-2025-322, 2025
Short summary
SORAS (Stratospheric Ozone RAdiometer in Seoul), a ground-based 110 GHz microwave radiometer for measuring the stratospheric ozone vertical profile
Soohyun Ka and Jung Jin Oh
Atmos. Meas. Tech., 18, 1283–1299, https://doi.org/10.5194/amt-18-1283-2025,https://doi.org/10.5194/amt-18-1283-2025, 2025
Short summary

Cited articles

Alicke, B., Platt, U., and Stutz, J.: Impact of nitrous acid photolysis on the total hydroxyl radical budget during the Limitation of Oxidant Production/Pianura Padana Produzione di Ozono study in Milan, J. Geophys. Res., 107, 8196, https://doi.org/10.1029/2000JD000075, 2002. 
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I – gas phase reactions of Ox, HOx, NOx and SOx species, Atmos. Chem. Phys., 4, 1461–1738, https://doi.org/10.5194/acp-4-1461-2004, 2004. 
Bahe, F. and Schurath, U.: Measurement of O(1D) Formation by Ozone Photolysis in the Troposphere, Pure Appl. Geophys., 116, 537–544, 1978. 
Bahe, F. C., Marx, W. N., Schurath, U., and Röth, E. P.: Determination of the absolute photolysis rate of ozone by sunlight O3+hνO(1D)+O2(1Δg) at ground level, Atmos. Environ., 13, 1515–1522, 1979. 
Bronstein, I. N., Mühlig, H., Musiol, G., and Semendjajew, K. A.: Taschenbuch der Mathematik (Bronstein), Verlag Europa-Lehrmittel, Nourney, Vollmer GmbH & Co. KG, Haan-Gruiten, Germany, 2013. 
Download
Short summary
Measurements of atmospheric trace gases by absorption spectroscopy are frequently supported by recording the amount of trace gas in absorption cells. These are typically small glass (or quartz) cylinders containing the gas to be studied. Here we show in the example of NO2-absorption cells that the effective amount of gas seen by the instrument can deviate greatly from expected values (by orders of magnitude in severe cases). Some suggestions for improving the situation are discussed.
Share