Articles | Volume 9, issue 3
https://doi.org/10.5194/amt-9-1095-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-9-1095-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
18 Mar 2016
Research article |
| 18 Mar 2016
Global stratospheric measurements of the isotopologues of methane from the Atmospheric Chemistry Experiment Fourier transform spectrometer
Eric M. Buzan
CORRESPONDING AUTHOR
Department of Chemistry and Biochemistry, Old Dominion University, Norfolk, Virginia, USA
Chris A. Beale
Department of Ocean, Earth, and Atmospheric Sciences, Old Dominion University, Norfolk, Virginia, USA
Chris D. Boone
Department of Chemistry, University of Waterloo, Waterloo, Ontario, Canada
Peter F. Bernath
Department of Chemistry and Biochemistry, Old Dominion University, Norfolk, Virginia, USA
Department of Chemistry, University of Waterloo, Waterloo, Ontario, Canada
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Jiansheng Zou, Kaley A. Walker, Patrick E. Sheese, Chris D. Boone, Ryan M. Stauffer, Anne M. Thompson, and David W. Tarasick
Atmos. Meas. Tech., 17, 6983–7005, https://doi.org/10.5194/amt-17-6983-2024, https://doi.org/10.5194/amt-17-6983-2024, 2024
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Ozone measurements from the ACE-FTS satellite instrument have been compared to worldwide balloon-borne ozonesonde profiles using pairs of closely spaced profiles and monthly averaged profiles. ACE-FTS typically measures more ozone in the stratosphere by up to 10 %. The long-term stability of the ACE-FTS ozone data is good, exhibiting small (but non-significant) drifts of less than 3 % per decade in the stratosphere. Lower in the profiles, the calculated drifts are larger (up to 10 % per decade).
Selena Zhang, Susan Solomon, Chris D. Boone, and Ghassan Taha
Atmos. Chem. Phys., 24, 11727–11736, https://doi.org/10.5194/acp-24-11727-2024, https://doi.org/10.5194/acp-24-11727-2024, 2024
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This paper investigates the vertical impacts of the anomalous 2023 Canadian wildfire season using multiple satellite instruments. Our results highlight that despite a record-breaking area burned, only a small amount of smoke managed to enter the stratosphere. This shows that the conditions for deep convection were rarely met in the 2023 wildfire season, suggesting that even a massive area burned is not necessarily an indicator of stratospheric perturbations.
Patrick E. Sheese, Kaley A. Walker, Chris D. Boone, and David A. Plummer
EGUsphere, https://doi.org/10.5194/egusphere-2024-2946, https://doi.org/10.5194/egusphere-2024-2946, 2024
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Observations from ACE-FTS are used to examine global stratospheric water vapour trends for 2004–2021. The satellite measurements are used to quantify trend contributions arising from changes in tropical tropopause temperatures, general circulation patterns, and methane concentrations. While most of the observed trends can be explained by these changes, there remains an unaccounted for and increasing source of water vapour in the lower mid-stratosphere at midlatitudes, which is discussed.
Laura N. Saunders, Kaley A. Walker, Gabriele P. Stiller, Thomas von Clarmann, Florian Haenel, Hella Garny, Harald Bönisch, Chris D. Boone, Ariana E. Castillo, Andreas Engel, Johannes C. Laube, Marianna Linz, Felix Ploeger, David A. Plummer, Eric A. Ray, and Patrick E. Sheese
EGUsphere, https://doi.org/10.5194/egusphere-2024-2117, https://doi.org/10.5194/egusphere-2024-2117, 2024
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We present a 17-year stratospheric age of air dataset derived from ACE-FTS satellite measurements of sulfur hexafluoride. This is the longest continuous, global, and vertically resolved age of air time series available to date. In this paper, we show that this dataset agrees well with age of air datasets based on measurements from other instruments. We also present trends in the midlatitude lower stratosphere that indicate changes in the global circulation that are predicted by climate models.
Felicia Kolonjari, Patrick E. Sheese, Kaley A. Walker, Chris D. Boone, David A. Plummer, Andreas Engel, Stephen A. Montzka, David E. Oram, Tanja Schuck, Gabriele P. Stiller, and Geoffrey C. Toon
Atmos. Meas. Tech., 17, 2429–2449, https://doi.org/10.5194/amt-17-2429-2024, https://doi.org/10.5194/amt-17-2429-2024, 2024
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The Canadian Atmospheric Chemistry Experiment Fourier transform spectrometer (ACE-FTS) satellite instrument is currently providing the only vertically resolved chlorodifluoromethane (HCFC-22) measurements from space. This study assesses the most current ACE-FTS HCFC-22 data product in the upper troposphere and lower stratosphere, as well as modelled HCFC-22 from a 39-year run of the Canadian Middle Atmosphere Model (CMAM39) in the same region.
Patrick E. Sheese, Kaley A. Walker, Chris D. Boone, Adam E. Bourassa, Doug A. Degenstein, Lucien Froidevaux, C. Thomas McElroy, Donal Murtagh, James M. Russell III, and Jiansheng Zou
Atmos. Meas. Tech., 15, 1233–1249, https://doi.org/10.5194/amt-15-1233-2022, https://doi.org/10.5194/amt-15-1233-2022, 2022
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This study analyzes the quality of two versions (v3.6 and v4.1) of ozone concentration measurements from the ACE-FTS (Atmospheric Chemistry Experiment Fourier Transform Spectrometer), by comparing with data from five satellite instruments between 2004 and 2020. It was found that although the v3.6 data exhibit a better agreement than v4.1 with respect to the other instruments, v4.1 exhibits much better stability over time than v3.6. The stability of v4.1 makes it suitable for ozone trend studies.
Patrick E. Sheese, Kaley A. Walker, Chris D. Boone, Doug A. Degenstein, Felicia Kolonjari, David Plummer, Douglas E. Kinnison, Patrick Jöckel, and Thomas von Clarmann
Atmos. Meas. Tech., 14, 1425–1438, https://doi.org/10.5194/amt-14-1425-2021, https://doi.org/10.5194/amt-14-1425-2021, 2021
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Output from climate chemistry models (CMAM, EMAC, and WACCM) is used to estimate the expected geophysical variability of ozone concentrations between coincident satellite instrument measurement times and geolocations. We use the Canadian ACE-FTS and OSIRIS instruments as a case study. Ensemble mean estimates are used to optimize coincidence criteria between the two instruments, allowing for the use of more coincident profiles while providing an estimate of the geophysical variation.
Felicia Kolonjari, David A. Plummer, Kaley A. Walker, Chris D. Boone, James W. Elkins, Michaela I. Hegglin, Gloria L. Manney, Fred L. Moore, Diane Pendlebury, Eric A. Ray, Karen H. Rosenlof, and Gabriele P. Stiller
Atmos. Chem. Phys., 18, 6801–6828, https://doi.org/10.5194/acp-18-6801-2018, https://doi.org/10.5194/acp-18-6801-2018, 2018
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We used satellite observations and model simulations of CFC-11, CFC-12, and N2O to investigate stratospheric transport, which is important for predicting the recovery of the ozone layer and future climate. We found that sampling can impact results and that the model consistently overestimates concentrations of these gases in the lower stratosphere, consistent with a too rapid Brewer–Dobson circulation. An issue with mixing in the tropical lower stratosphere in June–July–August was also found.
Hugh C. Pumphrey, Norbert Glatthor, Peter F. Bernath, Christopher D. Boone, James W. Hannigan, Ivan Ortega, Nathaniel J. Livesey, and William G. Read
Atmos. Chem. Phys., 18, 691–703, https://doi.org/10.5194/acp-18-691-2018, https://doi.org/10.5194/acp-18-691-2018, 2018
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The Microwave Limb Sounder (MLS) is a satellite instrument that has been measuring the amount of various gases in the atmosphere since 2004. In late 2015 and 2016 it observed unusual amounts of hydrogen cyanide (HCN), a gas produced when vegetation is burned. We compare the MLS observations to similar observations from other instruments. The excess HCN is shown to come from fires in Indonesia. There are more fires than usual in 2015–16 due to a drought caused by an El Niño event.
Kevin S. Olsen, Kimberly Strong, Kaley A. Walker, Chris D. Boone, Piera Raspollini, Johannes Plieninger, Whitney Bader, Stephanie Conway, Michel Grutter, James W. Hannigan, Frank Hase, Nicholas Jones, Martine de Mazière, Justus Notholt, Matthias Schneider, Dan Smale, Ralf Sussmann, and Naoko Saitoh
Atmos. Meas. Tech., 10, 3697–3718, https://doi.org/10.5194/amt-10-3697-2017, https://doi.org/10.5194/amt-10-3697-2017, 2017
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The primary instrument on the Greenhouse gases Observing SATellite (GOSAT) is the Thermal And Near infrared Sensor for carbon Observations (TANSO) Fourier transform spectrometer (FTS). TANSO-FTS has a thermal infrared channel to retrieve vertical profiles of CO2 and CH4 volume mixing ratios in the troposphere. We compare the retrieved vertical profiles of CH4 from TANSO-FTS with those from two other spaceborne FTSs and with ground-based FTS observatories to assess their quality.
Debora Griffin, Kaley A. Walker, Stephanie Conway, Felicia Kolonjari, Kimberly Strong, Rebecca Batchelor, Chris D. Boone, Lin Dan, James R. Drummond, Pierre F. Fogal, Dejian Fu, Rodica Lindenmaier, Gloria L. Manney, and Dan Weaver
Atmos. Meas. Tech., 10, 3273–3294, https://doi.org/10.5194/amt-10-3273-2017, https://doi.org/10.5194/amt-10-3273-2017, 2017
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Measurements in the high Arctic from two ground-based and one space-borne infrared Fourier transform spectrometer agree well over an 8-year time period (2006–2013). These comparisons show no notable degradation, indicating the consistency of these data sets and suggesting that the space-borne measurements have been stable. Increasing ozone, as well as increases of some other atmospheric gases, has been found over this same time period.
Massimo Valeri, Flavio Barbara, Chris Boone, Simone Ceccherini, Marco Gai, Guido Maucher, Piera Raspollini, Marco Ridolfi, Luca Sgheri, Gerald Wetzel, and Nicola Zoppetti
Atmos. Chem. Phys., 17, 10143–10162, https://doi.org/10.5194/acp-17-10143-2017, https://doi.org/10.5194/acp-17-10143-2017, 2017
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Atmospheric emissions of CCl4 are regulated by the Montreal Protocol due to its role as a strong ozone-depleting substance. The molecule is the subject of recent increased interest as a consequence of the discrepancy between atmospheric observations and reported production and consumption. We use MIPAS/ENVISAT data (2002–2012) to estimate CCl4 trends and lifetime. At 50 hPa we find a decline of about 30–35 % per decade. In the lower stratosphere our lifetime estimate is 47 (39–61) years.
Ellen Eckert, Thomas von Clarmann, Alexandra Laeng, Gabriele P. Stiller, Bernd Funke, Norbert Glatthor, Udo Grabowski, Sylvia Kellmann, Michael Kiefer, Andrea Linden, Arne Babenhauserheide, Gerald Wetzel, Christopher Boone, Andreas Engel, Jeremy J. Harrison, Patrick E. Sheese, Kaley A. Walker, and Peter F. Bernath
Atmos. Meas. Tech., 10, 2727–2743, https://doi.org/10.5194/amt-10-2727-2017, https://doi.org/10.5194/amt-10-2727-2017, 2017
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We retrieved vertical profiles of CCl4 from MIPAS Envisat IMK/IAA data. A detailed description of all characteristics is included in the paper as well as comparisons with historical measurements and comparisons with collocated measurements of instruments covering the same time span as MIPAS Envisat. A particular focus also lies on the usage of a new CCl4 spectroscopic dataset introduced recently, which leads to more realistic CCl4 volume mixing ratios.
Martyn P. Chipperfield, Qing Liang, Matthew Rigby, Ryan Hossaini, Stephen A. Montzka, Sandip Dhomse, Wuhu Feng, Ronald G. Prinn, Ray F. Weiss, Christina M. Harth, Peter K. Salameh, Jens Mühle, Simon O'Doherty, Dickon Young, Peter G. Simmonds, Paul B. Krummel, Paul J. Fraser, L. Paul Steele, James D. Happell, Robert C. Rhew, James Butler, Shari A. Yvon-Lewis, Bradley Hall, David Nance, Fred Moore, Ben R. Miller, James W. Elkins, Jeremy J. Harrison, Chris D. Boone, Elliot L. Atlas, and Emmanuel Mahieu
Atmos. Chem. Phys., 16, 15741–15754, https://doi.org/10.5194/acp-16-15741-2016, https://doi.org/10.5194/acp-16-15741-2016, 2016
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Carbon tetrachloride (CCl4) is a compound which, when released into the atmosphere, can cause depletion of the stratospheric ozone layer. Its emissions are controlled under the Montreal Protocol, and its atmospheric abundance is slowly decreasing. However, this decrease is not as fast as expected based on estimates of its emissions and its atmospheric lifetime. We have used an atmospheric model to look at the uncertainties in the CCl4 lifetime and to examine the impact on its atmospheric decay.
Patrick E. Sheese, Kaley A. Walker, Chris D. Boone, Chris A. McLinden, Peter F. Bernath, Adam E. Bourassa, John P. Burrows, Doug A. Degenstein, Bernd Funke, Didier Fussen, Gloria L. Manney, C. Thomas McElroy, Donal Murtagh, Cora E. Randall, Piera Raspollini, Alexei Rozanov, James M. Russell III, Makoto Suzuki, Masato Shiotani, Joachim Urban, Thomas von Clarmann, and Joseph M. Zawodny
Atmos. Meas. Tech., 9, 5781–5810, https://doi.org/10.5194/amt-9-5781-2016, https://doi.org/10.5194/amt-9-5781-2016, 2016
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This study validates version 3.5 of the ACE-FTS NOy species data sets by comparing diurnally scaled ACE-FTS data to correlative data from 11 other satellite limb sounders. For all five species examined (NO, NO2, HNO3, N2O5, and ClONO2), there is good agreement between ACE-FTS and the other data sets in various regions of the atmosphere. In these validated regions, these NOy data products can be used for further investigation into the composition, dynamics, and climate of the stratosphere.
Richard J. Pope, Nigel A. D. Richards, Martyn P. Chipperfield, David P. Moore, Sarah A. Monks, Stephen R. Arnold, Norbert Glatthor, Michael Kiefer, Tom J. Breider, Jeremy J. Harrison, John J. Remedios, Carsten Warneke, James M. Roberts, Glenn S. Diskin, Lewis G. Huey, Armin Wisthaler, Eric C. Apel, Peter F. Bernath, and Wuhu Feng
Atmos. Chem. Phys., 16, 13541–13559, https://doi.org/10.5194/acp-16-13541-2016, https://doi.org/10.5194/acp-16-13541-2016, 2016
Jeremy J. Harrison, Martyn P. Chipperfield, Christopher D. Boone, Sandip S. Dhomse, Peter F. Bernath, Lucien Froidevaux, John Anderson, and James Russell III
Atmos. Chem. Phys., 16, 10501–10519, https://doi.org/10.5194/acp-16-10501-2016, https://doi.org/10.5194/acp-16-10501-2016, 2016
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HF, the dominant stratospheric fluorine reservoir, results from the atmospheric degradation of anthropogenic species such as CFCs, HCFCs, and HFCs. All are strong greenhouse gases, and CFCs and HCFCs deplete stratospheric ozone.
We report the comparison of HF global distributions and trends measured by the ACE-FTS and HALOE satellite instruments with the output of SLIMCAT, a chemical transport model. The global HF trends reveal a slowing down in the rate of increase of HF since the 1990s.
Gerrit Holl, Kaley A. Walker, Stephanie Conway, Naoko Saitoh, Chris D. Boone, Kimberly Strong, and James R. Drummond
Atmos. Meas. Tech., 9, 1961–1980, https://doi.org/10.5194/amt-9-1961-2016, https://doi.org/10.5194/amt-9-1961-2016, 2016
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Methane is a powerful greenhouse gas, and we need to measure it globally with satellite instruments. We compare measurements from two satellites with measurements from the ground in Eureka, Nunavut, Canada to assess their different strengths and weaknesses. The differences between measurements are discussed and assessed considering the details of each measurement technique and processing. Recommendations are provided for utilization of these data sets for monitoring methane in the high Arctic.
Kevin S. Olsen, Geoffrey C. Toon, Chris D. Boone, and Kimberly Strong
Atmos. Meas. Tech., 9, 1063–1082, https://doi.org/10.5194/amt-9-1063-2016, https://doi.org/10.5194/amt-9-1063-2016, 2016
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A new version of the Atmospheric Chemistry Experiment Fourier transform spectrometer was intended to be sent to Mars to perform a detailed study of the composition of the Martian atmosphere. Of critical importance for such a mission is a method to accurately determine the temperature and pressure of the atmosphere. This paper presents a new algorithm for measuring temperature and pressure from high-resolution infrared spectra of CO2 absorption and applies it to terrestrial spectra.
Christopher E. Sioris, Jason Zou, David A. Plummer, Chris D. Boone, C. Thomas McElroy, Patrick E. Sheese, Omid Moeini, and Peter F. Bernath
Atmos. Chem. Phys., 16, 3265–3278, https://doi.org/10.5194/acp-16-3265-2016, https://doi.org/10.5194/acp-16-3265-2016, 2016
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The AM (annular mode) is the most important internal mode of climatic variability at high latitudes. Upper tropospheric water vapour (UTWV) at high latitudes increases by up to ~ 50 % during the negative phase of the AMs. The response of water vapour to the AMs vanishes above the tropopause. The ultimate goal of the study was to improve UTWV trend uncertainties by explaining shorter-term variability, and this was achieved by accounting for the AM-related response in a multiple linear regression.
Christopher E. Sioris, Jason Zou, C. Thomas McElroy, Chris D. Boone, Patrick E. Sheese, and Peter F. Bernath
Atmos. Chem. Phys., 16, 2207–2219, https://doi.org/10.5194/acp-16-2207-2016, https://doi.org/10.5194/acp-16-2207-2016, 2016
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This paper shows that volcanic eruptions occurring at higher latitudes in windy environments can lead to significant perturbations to upper tropospheric (UT) humidity mostly due to entrainment of lower tropospheric moisture by wind-blown plumes.
This research was performed for the purpose of determining long-term trends in high-latitude UT water vapour. The steps involve building a monthly climatology and using it to deseasonalize the time series. Large observed anomalies are then studied.
L. Froidevaux, J. Anderson, H.-J. Wang, R. A. Fuller, M. J. Schwartz, M. L. Santee, N. J. Livesey, H. C. Pumphrey, P. F. Bernath, J. M. Russell III, and M. P. McCormick
Atmos. Chem. Phys., 15, 10471–10507, https://doi.org/10.5194/acp-15-10471-2015, https://doi.org/10.5194/acp-15-10471-2015, 2015
V. Proschek, G. Kirchengast, S. Schweitzer, J. S. A. Brooke, P. F. Bernath, C. B. Thomas, J.-G. Wang, K. A. Tereszchuk, G. González Abad, R. J. Hargreaves, C. A. Beale, J. J. Harrison, P. A. Martin, V. L. Kasyutich, C. Gerbig, O. Kolle, and A. Loescher
Atmos. Meas. Tech., 8, 3315–3336, https://doi.org/10.5194/amt-8-3315-2015, https://doi.org/10.5194/amt-8-3315-2015, 2015
M. Höpfner, C. D. Boone, B. Funke, N. Glatthor, U. Grabowski, A. Günther, S. Kellmann, M. Kiefer, A. Linden, S. Lossow, H. C. Pumphrey, W. G. Read, A. Roiger, G. Stiller, H. Schlager, T. von Clarmann, and K. Wissmüller
Atmos. Chem. Phys., 15, 7017–7037, https://doi.org/10.5194/acp-15-7017-2015, https://doi.org/10.5194/acp-15-7017-2015, 2015
G. E. Nedoluha, D. E. Siskind, A. Lambert, and C. Boone
Atmos. Chem. Phys., 15, 4215–4224, https://doi.org/10.5194/acp-15-4215-2015, https://doi.org/10.5194/acp-15-4215-2015, 2015
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While global stratospheric O3 has begun to recover, there are localized regions where O3 has decreased since 1991. O3 in the mid-stratosphere is very sensitive to nitrogen chemistry, with increased NOy resulting in decreased O3. We show how the observed O3 changes in the tropical mid-stratosphere can be caused by long-term variations in dynamics. These variations result in a decrease in N2O, an increase in NOy, and a resulting decrease in O3.
P. E. Sheese, C. D. Boone, and K. A. Walker
Atmos. Meas. Tech., 8, 741–750, https://doi.org/10.5194/amt-8-741-2015, https://doi.org/10.5194/amt-8-741-2015, 2015
W. Bader, T. Stavrakou, J.-F. Muller, S. Reimann, C. D. Boone, J. J. Harrison, O. Flock, B. Bovy, B. Franco, B. Lejeune, C. Servais, and E. Mahieu
Atmos. Meas. Tech., 7, 3861–3872, https://doi.org/10.5194/amt-7-3861-2014, https://doi.org/10.5194/amt-7-3861-2014, 2014
J. J. Harrison, M. P. Chipperfield, A. Dudhia, S. Cai, S. Dhomse, C. D. Boone, and P. F. Bernath
Atmos. Chem. Phys., 14, 11915–11933, https://doi.org/10.5194/acp-14-11915-2014, https://doi.org/10.5194/acp-14-11915-2014, 2014
M. García-Comas, B. Funke, A. Gardini, M. López-Puertas, A. Jurado-Navarro, T. von Clarmann, G. Stiller, M. Kiefer, C. D. Boone, T. Leblanc, B. T. Marshall, M. J. Schwartz, and P. E. Sheese
Atmos. Meas. Tech., 7, 3633–3651, https://doi.org/10.5194/amt-7-3633-2014, https://doi.org/10.5194/amt-7-3633-2014, 2014
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We present the new vM21 MIPAS temperatures from 20 to 102km for all of its 2005-2012 MA, UA and NLC measurements. The main upgrades are the update of ESA L1b spectra, spectroscopic database and O and CO2 climatologies, and improvement in Tk-gradient and offset regularizations and apodization accuracy. The vM21 Tk's correct the main systematic errors of previous versions and lead to remarkable improvement in their comparisons with ACE-FTS, MLS, OSIRIS, SABER and SOFIE and the MLO and TMF lidars.
K. M. Saad, D. Wunch, G. C. Toon, P. Bernath, C. Boone, B. Connor, N. M. Deutscher, D. W. T. Griffith, R. Kivi, J. Notholt, C. Roehl, M. Schneider, V. Sherlock, and P. O. Wennberg
Atmos. Meas. Tech., 7, 2907–2918, https://doi.org/10.5194/amt-7-2907-2014, https://doi.org/10.5194/amt-7-2907-2014, 2014
C. E. Sioris, C. D. Boone, R. Nassar, K. J. Sutton, I. E. Gordon, K. A. Walker, and P. F. Bernath
Atmos. Meas. Tech., 7, 2243–2262, https://doi.org/10.5194/amt-7-2243-2014, https://doi.org/10.5194/amt-7-2243-2014, 2014
E. Mahieu, R. Zander, G. C. Toon, M. K. Vollmer, S. Reimann, J. Mühle, W. Bader, B. Bovy, B. Lejeune, C. Servais, P. Demoulin, G. Roland, P. F. Bernath, C. D. Boone, K. A. Walker, and P. Duchatelet
Atmos. Meas. Tech., 7, 333–344, https://doi.org/10.5194/amt-7-333-2014, https://doi.org/10.5194/amt-7-333-2014, 2014
A. T. Brown, M. P. Chipperfield, N. A. D. Richards, C. Boone, and P. F. Bernath
Atmos. Chem. Phys., 14, 267–282, https://doi.org/10.5194/acp-14-267-2014, https://doi.org/10.5194/acp-14-267-2014, 2014
T. Sugita, Y. Kasai, Y. Terao, S. Hayashida, G. L. Manney, W. H. Daffer, H. Sagawa, M. Suzuki, M. Shiotani, K. A. Walker, C. D. Boone, and P. F. Bernath
Atmos. Meas. Tech., 6, 3099–3113, https://doi.org/10.5194/amt-6-3099-2013, https://doi.org/10.5194/amt-6-3099-2013, 2013
D. Griffin, K. A. Walker, J. E. Franklin, M. Parrington, C. Whaley, J. Hopper, J. R. Drummond, P. I. Palmer, K. Strong, T. J. Duck, I. Abboud, P. F. Bernath, C. Clerbaux, P.-F. Coheur, K. R. Curry, L. Dan, E. Hyer, J. Kliever, G. Lesins, M. Maurice, A. Saha, K. Tereszchuk, and D. Weaver
Atmos. Chem. Phys., 13, 10227–10241, https://doi.org/10.5194/acp-13-10227-2013, https://doi.org/10.5194/acp-13-10227-2013, 2013
Y. Kasai, H. Sagawa, D. Kreyling, E. Dupuy, P. Baron, J. Mendrok, K. Suzuki, T. O. Sato, T. Nishibori, S. Mizobuchi, K. Kikuchi, T. Manabe, H. Ozeki, T. Sugita, M. Fujiwara, Y. Irimajiri, K. A. Walker, P. F. Bernath, C. Boone, G. Stiller, T. von Clarmann, J. Orphal, J. Urban, D. Murtagh, E. J. Llewellyn, D. Degenstein, A. E. Bourassa, N. D. Lloyd, L. Froidevaux, M. Birk, G. Wagner, F. Schreier, J. Xu, P. Vogt, T. Trautmann, and M. Yasui
Atmos. Meas. Tech., 6, 2311–2338, https://doi.org/10.5194/amt-6-2311-2013, https://doi.org/10.5194/amt-6-2311-2013, 2013
A. T. Brown, M. P. Chipperfield, S. Dhomse, C. Boone, and P. F. Bernath
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-23491-2013, https://doi.org/10.5194/acpd-13-23491-2013, 2013
Revised manuscript has not been submitted
R. L. Gattinger, E. Kyrölä, C. D. Boone, W. F. J. Evans, K. A. Walker, I. C. McDade, P. F. Bernath, and E. J. Llewellyn
Atmos. Chem. Phys., 13, 7813–7824, https://doi.org/10.5194/acp-13-7813-2013, https://doi.org/10.5194/acp-13-7813-2013, 2013
J. J. Harrison and P. F. Bernath
Atmos. Chem. Phys., 13, 7405–7413, https://doi.org/10.5194/acp-13-7405-2013, https://doi.org/10.5194/acp-13-7405-2013, 2013
A. T. Brown, C. M. Volk, M. R. Schoeberl, C. D. Boone, and P. F. Bernath
Atmos. Chem. Phys., 13, 6921–6950, https://doi.org/10.5194/acp-13-6921-2013, https://doi.org/10.5194/acp-13-6921-2013, 2013
K. A. Tereszchuk, D. P. Moore, J. J. Harrison, C. D. Boone, M. Park, J. J. Remedios, W. J. Randel, and P. F. Bernath
Atmos. Chem. Phys., 13, 5601–5613, https://doi.org/10.5194/acp-13-5601-2013, https://doi.org/10.5194/acp-13-5601-2013, 2013
K. A. Tereszchuk, G. González Abad, C. Clerbaux, J. Hadji-Lazaro, D. Hurtmans, P.-F. Coheur, and P. F. Bernath
Atmos. Chem. Phys., 13, 4529–4541, https://doi.org/10.5194/acp-13-4529-2013, https://doi.org/10.5194/acp-13-4529-2013, 2013
Related subject area
Subject: Gases | Technique: Remote Sensing | Topic: Validation and Intercomparisons
Validation of the version 4.5 MAESTRO ozone and NO2 measurements
Benchmarking data-driven inversion methods for the estimation of local CO2 emissions from synthetic satellite images of XCO2 and NO2
Validation of 12 years (2008–2019) of IASI-A CO with IAGOS aircraft observations
Diurnal variations of NO2 tropospheric vertical column density over the Seoul metropolitan area from the Geostationary Environment Monitoring Spectrometer (GEMS): seasonal differences and the influence of the a priori NO2 profile
Validation of ACE-FTS version 5.2 ozone data with ozonesonde measurements
Intercomparison of long-term ground-based measurements of total, tropospheric, and stratospheric ozone at Lauder, New Zealand
First evaluation of the GEMS glyoxal products against TROPOMI and ground-based measurements
Validation of GEMS tropospheric NO2 columns and their diurnal variation with ground-based DOAS measurements
Using open-path dual-comb spectroscopy to monitor methane emissions from simulated grazing cattle
Atmospheric horizontal gradients measured with eight co-located GNSS stations and a microwave radiometer
Greenhouse gas column observations from a portable spectrometer in Uganda
Independent validation of IASI/MetOp-A LMD and RAL CH4 products using CAMS model, in situ profiles, and ground-based FTIR measurements
Joint spectral retrievals of ozone with Suomi NPP CrIS augmented by S5P/TROPOMI
An evaluation of atmospheric absorption models at millimetre and sub-millimetre wavelengths using airborne observations
Applicability of the inverse dispersion method to measure emissions from animal housings
5 years of Sentinel-5P TROPOMI operational ozone profiling and geophysical validation using ozonesonde and lidar ground-based networks
Using a portable FTIR spectrometer to evaluate the consistency of Total Carbon Column Observing Network (TCCON) measurements on a global scale: the Collaborative Carbon Column Observing Network (COCCON) travel standard
Comparison of the H2O, HDO and δD stratospheric climatologies between the MIPAS-ESA V8, MIPAS-IMK V5 and ACE-FTS V4.1/4.2 satellite datasets
TROPESS-CrIS CO single-pixel vertical profiles: intercomparisons with MOPITT and model simulations for 2020 western US wildfires
TOLNet validation of satellite ozone profiles in the troposphere: impact of retrieval wavelengths
An uncertainty methodology for solar occultation flux measurements: ammonia emissions from livestock production
Validation of Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) chlorodifluoromethane (HCFC-22) in the upper troposphere and lower stratosphere
First validation of high-resolution satellite-derived methane emissions from an active gas leak in the UK
Ship- and aircraft-based XCH4 over oceans as a new tool for satellite validation
Single-blind test of nine methane-sensing satellite systems from three continents
Water vapor measurements inside clouds and storms using a differential absorption radar
Evaluation of the first year of Pandora NO2 measurements over Beijing and application to satellite validation
Validation of MUSES NH3 observations from AIRS and CrIS against aircraft measurements from DISCOVER-AQ and a surface network in the Magic Valley
Performance and sensitivity of column-wise and pixel-wise methane retrievals for imaging spectrometers
Methane point source quantification using MethaneAIR: a new airborne imaging spectrometer
Evaluation of total ozone measurements from Geostationary Environmental Monitoring Spectrometer (GEMS)
To new heights by flying low: comparison of aircraft vertical NO2 profiles to model simulations and implications for TROPOMI NO2 retrievals
Local comparisons of tropospheric ozone: vertical soundings at two neighbouring stations in southern Bavaria
Ground-based Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) observations of NO2 and H2CO at Kinshasa and comparisons with TROPOMI observations
Total column ozone trends from the NASA Merged Ozone time series 1979 to 2021 showing latitude-dependent ozone recovery dates (1994 to 1998)
The SPARC water vapour assessment II: biases and drifts of water vapour satellite data records with respect to frost point hygrometer records
Vicarious calibration of the Tropospheric Monitoring Instrument (TROPOMI) short-wave infrared (SWIR) module over the Railroad Valley Playa
First-time comparison between NO2 vertical columns from Geostationary Environmental Monitoring Spectrometer (GEMS) and Pandora measurements
A blended TROPOMI+GOSAT satellite data product for atmospheric methane using machine learning to correct retrieval biases
Evaluating the consistency between OCO-2 and OCO-3 XCO2 estimates derived from the NASA ACOS version 10 retrieval algorithm
OLCI-A/B tandem phase: evaluation of FLuorescence EXplorer (FLEX)-like radiances and estimation of systematic differences between OLCI-A and OLCI-FLEX
Multi-parameter dynamical diagnostics for upper tropospheric and lower stratospheric studies
An approach to track instrument calibration and produce consistent products with the version-8 total column ozone algorithm (V8TOZ)
Satellite remote-sensing capability to assess tropospheric-column ratios of formaldehyde and nitrogen dioxide: case study during the Long Island Sound Tropospheric Ozone Study 2018 (LISTOS 2018) field campaign
Validation of Sentinel-5P TROPOMI tropospheric NO2 products by comparison with NO2 measurements from airborne imaging DOAS, ground-based stationary DOAS, and mobile car DOAS measurements during the S5P-VAL-DE-Ruhr campaign
Evaluation of open- and closed-path sampling systems for the determination of emission rates of NH3 and CH4 with inverse dispersion modeling
Performance of AIRS ozone retrieval over the central Himalayas: use of ozonesonde and other satellite datasets
Solar occultation measurement of mesospheric ozone by SAGE III/ISS: impact of variations along the line of sight caused by photochemistry
Understanding the potential of Sentinel-2 for monitoring methane point emissions
TROPOMI/S5P Total Column Water Vapor validation against AERONET ground-based measurements
Paul S. Jeffery, James R. Drummond, C. Thomas McElroy, Kaley A. Walker, and Jiansheng Zou
Atmos. Meas. Tech., 18, 569–602, https://doi.org/10.5194/amt-18-569-2025, https://doi.org/10.5194/amt-18-569-2025, 2025
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The MAESTRO instrument has been monitoring ozone and NO2 since February 2004. A new version of these data products has recently been released; however, these new products must be validated against other datasets to ensure their validity. This study presents such an assessment, using measurements from 11 satellite instruments to characterize the new MAESTRO products. In the stratosphere, good agreement is found for ozone and acceptable agreement is found for NO2 with these other datasets.
Diego Santaren, Janne Hakkarainen, Gerrit Kuhlmann, Erik Koene, Frédéric Chevallier, Iolanda Ialongo, Hannakaisa Lindqvist, Janne Nurmela, Johanna Tamminen, Laia Amorós, Dominik Brunner, and Grégoire Broquet
Atmos. Meas. Tech., 18, 211–239, https://doi.org/10.5194/amt-18-211-2025, https://doi.org/10.5194/amt-18-211-2025, 2025
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This study evaluates data-driven inversion methods for estimating CO2 emissions from local sources, such as power plants and cities, using meteorological data and XCO2 and NO2 satellite images rather than atmospheric transport modeling. We assess and compare the performance of five different methods using simulations of 1 year of satellite images, taken from the upcoming Copernicus CO2 Monitoring Mission, covering 15 power plants and the city of Berlin, Germany.
Brice Barret, Pierre Loicq, Eric Le Flochmoën, Yasmine Bennouna, Juliette Hadji-Lazaro, Daniel Hurtmans, and Bastien Sauvage
Atmos. Meas. Tech., 18, 129–149, https://doi.org/10.5194/amt-18-129-2025, https://doi.org/10.5194/amt-18-129-2025, 2025
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Profiles of carbon monoxide (CO) retrieved from the Infrared Atmospheric Sounding Interferometer (IASI) with the SOftware for a Fast Retrieval of IASI Data (SOFRID) and Fast Optimal Retrievals on Layers for IASI (FORLI) are validated with 8500 observations at 33 airports from the In-service Aircraft for a Global Observing System (IAGOS) for 2008–2019. IASI retrievals underestimate CO, with stronger bias in the middle to upper troposphere for SOFRID and in the lower troposphere for FORLI.
Seunghwan Seo, Si-Wan Kim, Kyoung-Min Kim, Andreas Richter, Kezia Lange, John P. Burrows, Junsung Park, Hyunkee Hong, Hanlim Lee, Ukkyo Jeong, Jung-Hun Woo, and Jhoon Kim
Atmos. Meas. Tech., 18, 115–128, https://doi.org/10.5194/amt-18-115-2025, https://doi.org/10.5194/amt-18-115-2025, 2025
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Over the Seoul metropolitan area, tropospheric NO2 vertical column densities from the Geostationary Environment Monitoring Spectrometer show distinct seasonal features. Also, varying a priori data have substantial impacts on the observed NO2 columns. The a priori data from different chemical transport models resulted in differences of up to −18.3 %. Notably, diurnal patterns of observed NO2 columns are similar for all datasets, although their a priori data exhibit contrasting diurnal patterns.
Jiansheng Zou, Kaley A. Walker, Patrick E. Sheese, Chris D. Boone, Ryan M. Stauffer, Anne M. Thompson, and David W. Tarasick
Atmos. Meas. Tech., 17, 6983–7005, https://doi.org/10.5194/amt-17-6983-2024, https://doi.org/10.5194/amt-17-6983-2024, 2024
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Ozone measurements from the ACE-FTS satellite instrument have been compared to worldwide balloon-borne ozonesonde profiles using pairs of closely spaced profiles and monthly averaged profiles. ACE-FTS typically measures more ozone in the stratosphere by up to 10 %. The long-term stability of the ACE-FTS ozone data is good, exhibiting small (but non-significant) drifts of less than 3 % per decade in the stratosphere. Lower in the profiles, the calculated drifts are larger (up to 10 % per decade).
Robin Björklund, Corinne Vigouroux, Peter Effertz, Omaira E. García, Alex Geddes, James Hannigan, Koji Miyagawa, Michael Kotkamp, Bavo Langerock, Gerald Nedoluha, Ivan Ortega, Irina Petropavlovskikh, Deniz Poyraz, Richard Querel, John Robinson, Hisako Shiona, Dan Smale, Penny Smale, Roeland Van Malderen, and Martine De Mazière
Atmos. Meas. Tech., 17, 6819–6849, https://doi.org/10.5194/amt-17-6819-2024, https://doi.org/10.5194/amt-17-6819-2024, 2024
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Different ground-based ozone measurements from the last 2 decades at Lauder are compared to each other. We want to know why different trends have been observed in the stratosphere. Also, the quality and relevance of tropospheric datasets need to be evaluated. While remaining drifts are still present, our study explains roughly half of the differences in observed trends in previous studies and shows the necessity for continuous review and improvement of the measurements.
Eunjo S. Ha, Rokjin J. Park, Hyeong-Ahn Kwon, Gitaek T. Lee, Sieun D. Lee, Seunga Shin, Dong-Won Lee, Hyunkee Hong, Christophe Lerot, Isabelle De Smedt, Thomas Danckaert, Francois Hendrick, and Hitoshi Irie
Atmos. Meas. Tech., 17, 6369–6384, https://doi.org/10.5194/amt-17-6369-2024, https://doi.org/10.5194/amt-17-6369-2024, 2024
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In this study, we evaluated the GEMS glyoxal products by comparing them with TROPOMI and MAX-DOAS measurements. GEMS and TROPOMI VCDs present similar spatial distributions. Monthly variations in GEMS VCDs and TROPOMI and MAX-DOAS VCDs differ in northeastern Asia, which we attributed to a polluted reference spectrum and high NO2 concentrations. GEMS glyoxal products with unparalleled temporal resolution would enrich our understanding of VOC emissions and diurnal variation.
Kezia Lange, Andreas Richter, Tim Bösch, Bianca Zilker, Miriam Latsch, Lisa K. Behrens, Chisom M. Okafor, Hartmut Bösch, John P. Burrows, Alexis Merlaud, Gaia Pinardi, Caroline Fayt, Martina M. Friedrich, Ermioni Dimitropoulou, Michel Van Roozendael, Steffen Ziegler, Simona Ripperger-Lukosiunaite, Leon Kuhn, Bianca Lauster, Thomas Wagner, Hyunkee Hong, Donghee Kim, Lim-Seok Chang, Kangho Bae, Chang-Keun Song, Jong-Uk Park, and Hanlim Lee
Atmos. Meas. Tech., 17, 6315–6344, https://doi.org/10.5194/amt-17-6315-2024, https://doi.org/10.5194/amt-17-6315-2024, 2024
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Instruments for air quality observations on geostationary satellites provide multiple observations per day and allow for the analysis of the diurnal variation of important air pollutants such as nitrogen dioxide (NO2) over large areas. The South Korean instrument GEMS, launched in February 2020, is the first instrument in geostationary orbit and covers a large part of Asia. Our investigations show the observed diurnal evolution of NO2 at different measurement sites.
Chinthaka Weerasekara, Lindsay C. Morris, Nathan A. Malarich, Fabrizio R. Giorgetta, Daniel I. Herman, Kevin C. Cossel, Nathan R. Newbury, Clenton E. Owensby, Stephen M. Welch, Cosmin Blaga, Brett D. DePaola, Ian Coddington, Brian R. Washburn, and Eduardo A. Santos
Atmos. Meas. Tech., 17, 6107–6117, https://doi.org/10.5194/amt-17-6107-2024, https://doi.org/10.5194/amt-17-6107-2024, 2024
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Most methane emissions during the life cycle of beef cattle occur during the grazing phase. Measuring methane in grazing systems is difficult due to the high mobility and low density of animals. This work investigates if dual-comb spectroscopy can measure methane emissions from small cattle herds. An enhancement of 10 nmol mol-1 methane above the atmospheric background was measured, equivalent to 20 head located 60 m away. The calculated methane flux was within 5 % of the actual release rate.
Ning Tong and Gunnar Elgered
EGUsphere, https://doi.org/10.5194/egusphere-2024-2716, https://doi.org/10.5194/egusphere-2024-2716, 2024
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The gradients estimated from multi-GNSS data were compared to WVR data. A better agreement is obtained when using WVR data with a smaller value of liquid water content. A weak constraint in GNSS data processing may be desirable for applications with a higher tolerance for formal errors but a greater focus on tracking the variability of water vapour. The averaged GNSS gradients can significantly reduce the random noise which can be used to obtain a more reliable variability of the water vapour.
Neil Humpage, Hartmut Boesch, William Okello, Jia Chen, Florian Dietrich, Mark F. Lunt, Liang Feng, Paul I. Palmer, and Frank Hase
Atmos. Meas. Tech., 17, 5679–5707, https://doi.org/10.5194/amt-17-5679-2024, https://doi.org/10.5194/amt-17-5679-2024, 2024
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We used a Bruker EM27/SUN spectrometer within an automated weatherproof enclosure to measure greenhouse gas column concentrations over a 3-month period in Jinja, Uganda. The portability of the EM27/SUN allows us to evaluate satellite and model data in locations not covered by traditional validation networks. This is of particular value in tropical Africa, where extensive terrestrial ecosystems are a significant store of carbon and play a key role in the atmospheric budgets of CO2 and CH4.
Bart Dils, Minqiang Zhou, Claude Camy-Peyret, Martine De Mazière, Yannick Kangah, Bavo Langerock, Pascal Prunet, Carmine Serio, Richard Siddans, and Brian Kerridge
Atmos. Meas. Tech., 17, 5491–5524, https://doi.org/10.5194/amt-17-5491-2024, https://doi.org/10.5194/amt-17-5491-2024, 2024
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The paper discusses two very distinct methane products from the IASI instrument aboard the MetOp-A satellite. One (referred to as LMD NLISv8.3) uses a machine-learning approach, while the other (RALv2.0) uses a more conventional optimal estimation approach. We used a variety of model and independent reference measurement data to assess both products' overall quality, their differences, and specific aspects of each product that would benefit from further analysis by the product development teams.
Edward Malina, Kevin W. Bowman, Valentin Kantchev, Le Kuai, Thomas P. Kurosu, Kazuyuki Miyazaki, Vijay Natraj, Gregory B. Osterman, Fabiano Oyafuso, and Matthew D. Thill
Atmos. Meas. Tech., 17, 5341–5371, https://doi.org/10.5194/amt-17-5341-2024, https://doi.org/10.5194/amt-17-5341-2024, 2024
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Characterizing the distribution of ozone in the atmosphere is a challenging problem, with current Earth observation satellites using either thermal infrared (TIR) or ultraviolet (UV) instruments, sensitive to different portions of the atmosphere, making it difficult to gain a full picture. In this work, we combine measurements from the TIR and UV instruments Suomi NPP CrIS and Sentinel-5P/TROPOMI to improve sensitivity through the whole atmosphere and improve knowledge of ozone distribution.
Stuart Fox, Vinia Mattioli, Emma Turner, Alan Vance, Domenico Cimini, and Donatello Gallucci
Atmos. Meas. Tech., 17, 4957–4978, https://doi.org/10.5194/amt-17-4957-2024, https://doi.org/10.5194/amt-17-4957-2024, 2024
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Airborne observations are used to evaluate two models for absorption and emission by atmospheric gases, including water vapour and oxygen, at microwave and sub-millimetre wavelengths. These models are needed for the Ice Cloud Imager (ICI) on the next generation of European polar-orbiting weather satellites, which measures at frequencies up to 664 GHz. Both models can provide a good match to measurements from airborne radiometers and are sufficiently accurate for use with ICI.
Marcel Bühler, Christoph Häni, Albrecht Neftel, Patrice Bühler, Christof Ammann, and Thomas Kupper
Atmos. Meas. Tech., 17, 4649–4658, https://doi.org/10.5194/amt-17-4649-2024, https://doi.org/10.5194/amt-17-4649-2024, 2024
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Methane was released from an artificial source inside a barn to test the applicability of the inverse dispersion method (IDM). Multiple open-path concentration devices and ultrasonic anemometers were used at the site. It is concluded that, for the present study case, the effect of a building and a tree in the main wind axis led to a systematic underestimation of the IDM-derived emission rate probably due to deviations in the wind field and turbulent dispersion from the ideal assumptions.
Arno Keppens, Serena Di Pede, Daan Hubert, Jean-Christopher Lambert, Pepijn Veefkind, Maarten Sneep, Johan De Haan, Mark ter Linden, Thierry Leblanc, Steven Compernolle, Tijl Verhoelst, José Granville, Oindrila Nath, Ann Mari Fjæraa, Ian Boyd, Sander Niemeijer, Roeland Van Malderen, Herman G. J. Smit, Valentin Duflot, Sophie Godin-Beekmann, Bryan J. Johnson, Wolfgang Steinbrecht, David W. Tarasick, Debra E. Kollonige, Ryan M. Stauffer, Anne M. Thompson, Angelika Dehn, and Claus Zehner
Atmos. Meas. Tech., 17, 3969–3993, https://doi.org/10.5194/amt-17-3969-2024, https://doi.org/10.5194/amt-17-3969-2024, 2024
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The Sentinel-5P satellite operated by the European Space Agency has carried the TROPOspheric Monitoring Instrument (TROPOMI) around the Earth since October 2017. This mission also produces atmospheric ozone profile data which are described in detail for May 2018 to April 2023. Independent validation using ground-based reference measurements demonstrates that the operational ozone profile product mostly fully and at least partially complies with all mission requirements.
Benedikt Herkommer, Carlos Alberti, Paolo Castracane, Jia Chen, Angelika Dehn, Florian Dietrich, Nicholas M. Deutscher, Matthias Max Frey, Jochen Groß, Lawson Gillespie, Frank Hase, Isamu Morino, Nasrin Mostafavi Pak, Brittany Walker, and Debra Wunch
Atmos. Meas. Tech., 17, 3467–3494, https://doi.org/10.5194/amt-17-3467-2024, https://doi.org/10.5194/amt-17-3467-2024, 2024
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The Total Carbon Column Observing Network is a network of ground-based Fourier transform infrared (FTIR) spectrometers used mainly for satellite validation. To ensure the highest-quality validation data, the network needs to be highly consistent. This is a major challenge, which so far is solved by site comparisons with airborne in situ measurements. In this work, we describe the use of a portable FTIR spectrometer as a travel standard for evaluating the consistency of TCCON sites.
Karen De Los Ríos, Paulina Ordoñez, Gabriele P. Stiller, Piera Raspollini, Marco Gai, Kaley A. Walker, Cristina Peña-Ortiz, and Luis Acosta
Atmos. Meas. Tech., 17, 3401–3418, https://doi.org/10.5194/amt-17-3401-2024, https://doi.org/10.5194/amt-17-3401-2024, 2024
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This study examines newer versions of H2O and HDO retrievals from Envisat/MIPAS and SCISAT/ACE-FTS. Results reveal a better agreement in stratospheric H2O profiles than in HDO profiles. The H2O tape recorder signal is consistent across databases, but δD tape recorder composites show differences that impact the interpretation of water vapour transport. These findings enhance the need for intercomparisons to refine our insights.
Ming Luo, Helen M. Worden, Robert D. Field, Kostas Tsigaridis, and Gregory S. Elsaesser
Atmos. Meas. Tech., 17, 2611–2624, https://doi.org/10.5194/amt-17-2611-2024, https://doi.org/10.5194/amt-17-2611-2024, 2024
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The TROPESS CrIS single-pixel CO profile retrievals are compared to the MOPITT CO products in steps of adjusting them to the common a priori assumptions. The two data sets are found to agree within 5 %. We also demonstrated and analyzed the proper steps in evaluating GISS ModelE CO simulations using satellite CO retrieval products for the western US wildfire events in September 2020.
Matthew S. Johnson, Alexei Rozanov, Mark Weber, Nora Mettig, John Sullivan, Michael J. Newchurch, Shi Kuang, Thierry Leblanc, Fernando Chouza, Timothy A. Berkoff, Guillaume Gronoff, Kevin B. Strawbridge, Raul J. Alvarez, Andrew O. Langford, Christoph J. Senff, Guillaume Kirgis, Brandi McCarty, and Larry Twigg
Atmos. Meas. Tech., 17, 2559–2582, https://doi.org/10.5194/amt-17-2559-2024, https://doi.org/10.5194/amt-17-2559-2024, 2024
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Monitoring tropospheric ozone (O3), a harmful pollutant negatively impacting human health, is primarily done using ground-based measurements and ozonesondes. However, these observation types lack the coverage to fully understand tropospheric O3. Satellites can retrieve tropospheric ozone with near-daily global coverage; however, they are known to have biases and errors. This study uses ground-based lidars to validate multiple satellites' ability to observe tropospheric O3.
Johan Mellqvist, Nathalia T. Vechi, Charlotte Scheutz, Marc Durif, Francois Gautier, John Johansson, Jerker Samuelsson, Brian Offerle, and Samuel Brohede
Atmos. Meas. Tech., 17, 2465–2479, https://doi.org/10.5194/amt-17-2465-2024, https://doi.org/10.5194/amt-17-2465-2024, 2024
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The solar occultation flux method retrieves ammonia gas columns from the solar spectrum. Emissions are obtained by multiplying the integrated plume concentration by the wind speed profile. The methodology for uncertainty estimation was established considering an error budget with systematic and random components, resulting in an expanded uncertainty in the range of 20 % to 30 %. The method was validated in a controlled release, and its application was demonstrated in different farms.
Felicia Kolonjari, Patrick E. Sheese, Kaley A. Walker, Chris D. Boone, David A. Plummer, Andreas Engel, Stephen A. Montzka, David E. Oram, Tanja Schuck, Gabriele P. Stiller, and Geoffrey C. Toon
Atmos. Meas. Tech., 17, 2429–2449, https://doi.org/10.5194/amt-17-2429-2024, https://doi.org/10.5194/amt-17-2429-2024, 2024
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The Canadian Atmospheric Chemistry Experiment Fourier transform spectrometer (ACE-FTS) satellite instrument is currently providing the only vertically resolved chlorodifluoromethane (HCFC-22) measurements from space. This study assesses the most current ACE-FTS HCFC-22 data product in the upper troposphere and lower stratosphere, as well as modelled HCFC-22 from a 39-year run of the Canadian Middle Atmosphere Model (CMAM39) in the same region.
Emily Dowd, Alistair J. Manning, Bryn Orth-Lashley, Marianne Girard, James France, Rebecca E. Fisher, Dave Lowry, Mathias Lanoisellé, Joseph R. Pitt, Kieran M. Stanley, Simon O'Doherty, Dickon Young, Glen Thistlethwaite, Martyn P. Chipperfield, Emanuel Gloor, and Chris Wilson
Atmos. Meas. Tech., 17, 1599–1615, https://doi.org/10.5194/amt-17-1599-2024, https://doi.org/10.5194/amt-17-1599-2024, 2024
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We provide the first validation of the satellite-derived emission estimates using surface-based mobile greenhouse gas surveys of an active gas leak detected near Cheltenham, UK. GHGSat’s emission estimates broadly agree with the surface-based mobile survey and steps were taken to fix the leak, highlighting the importance of satellite data in identifying emissions and helping to reduce our human impact on climate change.
Astrid Müller, Hiroshi Tanimoto, Takafumi Sugita, Prabir K. Patra, Shin-ichiro Nakaoka, Toshinobu Machida, Isamu Morino, André Butz, and Kei Shiomi
Atmos. Meas. Tech., 17, 1297–1316, https://doi.org/10.5194/amt-17-1297-2024, https://doi.org/10.5194/amt-17-1297-2024, 2024
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Satellite CH4 observations with high accuracy are needed to understand changes in atmospheric CH4 concentrations. But over oceans, reference data are limited. We combine various ship and aircraft observations with the help of atmospheric chemistry models to derive observation-based column-averaged mixing ratios of CH4 (obs. XCH4). We discuss three different approaches and demonstrate the applicability of the new reference dataset for carbon cycle studies and satellite evaluation.
Evan D. Sherwin, Sahar H. El Abbadi, Philippine M. Burdeau, Zhan Zhang, Zhenlin Chen, Jeffrey S. Rutherford, Yuanlei Chen, and Adam R. Brandt
Atmos. Meas. Tech., 17, 765–782, https://doi.org/10.5194/amt-17-765-2024, https://doi.org/10.5194/amt-17-765-2024, 2024
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Countries and companies increasingly rely on a growing fleet of satellites to find large emissions of climate-warming methane, particularly from oil and natural gas systems across the globe. We independently assessed the performance of nine such systems by releasing controlled, undisclosed amounts of methane as satellites passed overhead. The tested systems produced reliable detection and quantification results, including the smallest-ever emission detected from space in such a test.
Luis F. Millán, Matthew D. Lebsock, Ken B. Cooper, Jose V. Siles, Robert Dengler, Raquel Rodriguez Monje, Amin Nehrir, Rory A. Barton-Grimley, James E. Collins, Claire E. Robinson, Kenneth L. Thornhill, and Holger Vömel
Atmos. Meas. Tech., 17, 539–559, https://doi.org/10.5194/amt-17-539-2024, https://doi.org/10.5194/amt-17-539-2024, 2024
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In this study, we describe and validate a new technique in which three radar tones are used to estimate the water vapor inside clouds and precipitation. This instrument flew on board NASA's P-3 aircraft during the Investigation of Microphysics and Precipitation for Atlantic Coast-Threatening Snowstorms (IMPACTS) campaign and the Synergies Of Active optical and Active microwave Remote Sensing Experiment (SOA2RSE) campaign.
Ouyang Liu, Zhengqiang Li, Yangyan Lin, Cheng Fan, Ying Zhang, Kaitao Li, Peng Zhang, Yuanyuan Wei, Tianzeng Chen, Jiantao Dong, and Gerrit de Leeuw
Atmos. Meas. Tech., 17, 377–395, https://doi.org/10.5194/amt-17-377-2024, https://doi.org/10.5194/amt-17-377-2024, 2024
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Nitrogen dioxide (NO2) is a trace gas which is important for atmospheric chemistry and may affect human health. To understand processes leading to harmful concentrations, it is important to monitor NO2 concentrations near the surface and higher up. To this end, a Pandora instrument has been installed in Beijing. An overview of the first year of data shows the large variability on diurnal to seasonal timescales and how this is affected by wind speed and direction and chemistry.
Karen E. Cady-Pereira, Xuehui Guo, Rui Wang, April B. Leytem, Chase Calkins, Elizabeth Berry, Kang Sun, Markus Müller, Armin Wisthaler, Vivienne H. Payne, Mark W. Shephard, Mark A. Zondlo, and Valentin Kantchev
Atmos. Meas. Tech., 17, 15–36, https://doi.org/10.5194/amt-17-15-2024, https://doi.org/10.5194/amt-17-15-2024, 2024
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Ammonia is a significant precursor of PM2.5 particles and thus contributes to poor air quality in many regions. Furthermore, ammonia concentrations are rising due to the increase of large-scale, intensive agricultural activities. Here we evaluate satellite measurements of ammonia against aircraft and surface network data, and show that there are differences in magnitude, but the satellite data are spatially and temporally well correlated with the in situ data.
Alana K. Ayasse, Daniel Cusworth, Kelly O'Neill, Justin Fisk, Andrew K. Thorpe, and Riley Duren
Atmos. Meas. Tech., 16, 6065–6074, https://doi.org/10.5194/amt-16-6065-2023, https://doi.org/10.5194/amt-16-6065-2023, 2023
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Methane is a powerful greenhouse gas, and a significant portion of methane comes from large individual plumes. Recently, airplane-mounted infrared technologies have proven very good at detecting and quantifying these plumes. In order to extract the methane signal from the infrared image, there are two widely used approaches. In this study, we assess the performance of both approaches using controlled-release experiments. We also examine the minimum detection limit of the infrared technology.
Apisada Chulakadabba, Maryann Sargent, Thomas Lauvaux, Joshua S. Benmergui, Jonathan E. Franklin, Christopher Chan Miller, Jonas S. Wilzewski, Sébastien Roche, Eamon Conway, Amir H. Souri, Kang Sun, Bingkun Luo, Jacob Hawthrone, Jenna Samra, Bruce C. Daube, Xiong Liu, Kelly Chance, Yang Li, Ritesh Gautam, Mark Omara, Jeff S. Rutherford, Evan D. Sherwin, Adam Brandt, and Steven C. Wofsy
Atmos. Meas. Tech., 16, 5771–5785, https://doi.org/10.5194/amt-16-5771-2023, https://doi.org/10.5194/amt-16-5771-2023, 2023
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We show that MethaneAIR, a precursor to the MethaneSAT satellite, demonstrates accurate point source quantification during controlled release experiments and regional observations in 2021 and 2022. Results from our two independent quantification methods suggest the accuracy of our sensor and algorithms is better than 25 % for sources emitting 200 kg h−1 or more. Insights from these measurements help establish the capabilities of MethaneSAT and MethaneAIR.
Kanghyun Baek, Jae Hwan Kim, Juseon Bak, David P. Haffner, Mina Kang, and Hyunkee Hong
Atmos. Meas. Tech., 16, 5461–5478, https://doi.org/10.5194/amt-16-5461-2023, https://doi.org/10.5194/amt-16-5461-2023, 2023
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The GEMS mission was the first mission of the geostationary satellite constellation for hourly atmospheric composition monitoring. The GEMS ozone measurements were cross-compared to those of Pandora, OMPS, and TROPOMI satellite sensors and excellent agreement was found. GEMS has proven to be a powerful new instrument for monitoring and assessing the diurnal variation in atmospheric ozone. This experience can be used to advance research with future geostationary environmental satellite missions.
Tobias Christoph Valentin Werner Riess, Klaas Folkert Boersma, Ward Van Roy, Jos de Laat, Enrico Dammers, and Jasper van Vliet
Atmos. Meas. Tech., 16, 5287–5304, https://doi.org/10.5194/amt-16-5287-2023, https://doi.org/10.5194/amt-16-5287-2023, 2023
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Satellite retrievals of trace gases require prior knowledge of the vertical distribution of the pollutant, which is usually obtained from models. Using aircraft-measured vertical NO2 profiles over the North Sea in summer 2021, we evaluate the Transport Model 5 profiles used in the TROPOMI NO2 retrieval. We conclude that driven by the low horizontal resolution and the overestimated vertical mixing, resulting NO2 columns are 20 % too low. This has important implications for emission estimates.
Thomas Trickl, Martin Adelwart, Dina Khordakova, Ludwig Ries, Christian Rolf, Michael Sprenger, Wolfgang Steinbrecht, and Hannes Vogelmann
Atmos. Meas. Tech., 16, 5145–5165, https://doi.org/10.5194/amt-16-5145-2023, https://doi.org/10.5194/amt-16-5145-2023, 2023
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Tropospheric ozone have been measured for more than a century. Highly quantitative ozone measurements have been made at monitoring stations. However, deficits have been reported for vertical sounding systems. Here, we report a thorough intercomparison effort between a differential-absorption lidar system and two types of balloon-borne ozone sondes, also using ozone sensors at nearby mountain sites as references. The sondes agree very well with the lidar after offset corrections.
Rodriguez Yombo Phaka, Alexis Merlaud, Gaia Pinardi, Martina M. Friedrich, Michel Van Roozendael, Jean-François Müller, Trissevgeni Stavrakou, Isabelle De Smedt, François Hendrick, Ermioni Dimitropoulou, Richard Bopili Mbotia Lepiba, Edmond Phuku Phuati, Buenimio Lomami Djibi, Lars Jacobs, Caroline Fayt, Jean-Pierre Mbungu Tsumbu, and Emmanuel Mahieu
Atmos. Meas. Tech., 16, 5029–5050, https://doi.org/10.5194/amt-16-5029-2023, https://doi.org/10.5194/amt-16-5029-2023, 2023
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We present air quality measurements in Kinshasa, Democratic Republic of the Congo, performed with a newly developed instrument which was installed on a roof of the University of Kinshasa in November 2019. The instrument records spectra of the scattered sunlight, from which we derive the abundances of nitrogen dioxide and formaldehyde, two important pollutants. We compare our ground-based measurements with those of the TROPOspheric Monitoring Instrument (TROPOMI).
Jay Herman, Jerald Ziemke, and Richard McPeters
Atmos. Meas. Tech., 16, 4693–4707, https://doi.org/10.5194/amt-16-4693-2023, https://doi.org/10.5194/amt-16-4693-2023, 2023
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Fourier series multivariate linear regression trends (% per decade) in ozone were estimated from the Merged Ozone Data Set (MOD) from 1979 to 2021 in two different regimes, from 1979 to TA (the date when ozone stopped decreasing) and TA to 2021. The derived TA is a latitude-dependent date, ranging from 1994 to 1998. TA(θ) is a marker for photochemistry dynamics models attempting to represent ozone change over the past 42 years.
Michael Kiefer, Dale F. Hurst, Gabriele P. Stiller, Stefan Lossow, Holger Vömel, John Anderson, Faiza Azam, Jean-Loup Bertaux, Laurent Blanot, Klaus Bramstedt, John P. Burrows, Robert Damadeo, Bianca Maria Dinelli, Patrick Eriksson, Maya García-Comas, John C. Gille, Mark Hervig, Yasuko Kasai, Farahnaz Khosrawi, Donal Murtagh, Gerald E. Nedoluha, Stefan Noël, Piera Raspollini, William G. Read, Karen H. Rosenlof, Alexei Rozanov, Christopher E. Sioris, Takafumi Sugita, Thomas von Clarmann, Kaley A. Walker, and Katja Weigel
Atmos. Meas. Tech., 16, 4589–4642, https://doi.org/10.5194/amt-16-4589-2023, https://doi.org/10.5194/amt-16-4589-2023, 2023
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We quantify biases and drifts (and their uncertainties) between the stratospheric water vapor measurement records of 15 satellite-based instruments (SATs, with 31 different retrievals) and balloon-borne frost point hygrometers (FPs) launched at 27 globally distributed stations. These comparisons of measurements during the period 2000–2016 are made using robust, consistent statistical methods. With some exceptions, the biases and drifts determined for most SAT–FP pairs are < 10 % and < 1 % yr−1.
Tim A. van Kempen, Tim J. Rotmans, Richard M. van Hees, Carol Bruegge, Dejian Fu, Ruud Hoogeveen, Thomas J. Pongetti, Robert Rosenberg, and Ilse Aben
Atmos. Meas. Tech., 16, 4507–4527, https://doi.org/10.5194/amt-16-4507-2023, https://doi.org/10.5194/amt-16-4507-2023, 2023
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Validation of satellite measurements is essential for providing reliable and consistent products. In this paper, a validation method for TROPOMI-SWIR (Tropospheric Measurement Instrument in the short-wavelength infrared) is explored. TROPOMI-SWIR has been shown to be exceptionally stable, a necessity to explore the methodology. Railroad Valley, Nevada, is a prime location to perform the necessary measurements to validate the satellite measurements of TROPOMI-SWIR.
Serin Kim, Daewon Kim, Hyunkee Hong, Lim-Seok Chang, Hanlim Lee, Deok-Rae Kim, Donghee Kim, Jeong-Ah Yu, Dongwon Lee, Ukkyo Jeong, Chang-Kuen Song, Sang-Woo Kim, Sang Seo Park, Jhoon Kim, Thomas F. Hanisco, Junsung Park, Wonei Choi, and Kwangyul Lee
Atmos. Meas. Tech., 16, 3959–3972, https://doi.org/10.5194/amt-16-3959-2023, https://doi.org/10.5194/amt-16-3959-2023, 2023
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A first evaluation of the Geostationary Environmental Monitoring Spectrometer (GEMS) NO2 was carried out via comparison with the NO2 data obtained from the ground-based Pandora direct-sun measurements at four sites in Seosan, Republic of Korea. Comparisons between GEMS NO2 and Pandora NO2 were performed according to GEMS cloud fraction. GEMS NO2 showed good agreement with that of Pandora NO2 under less cloudy conditions.
Nicholas Balasus, Daniel J. Jacob, Alba Lorente, Joannes D. Maasakkers, Robert J. Parker, Hartmut Boesch, Zichong Chen, Makoto M. Kelp, Hannah Nesser, and Daniel J. Varon
Atmos. Meas. Tech., 16, 3787–3807, https://doi.org/10.5194/amt-16-3787-2023, https://doi.org/10.5194/amt-16-3787-2023, 2023
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We use machine learning to remove biases in TROPOMI satellite observations of atmospheric methane, with GOSAT observations serving as a reference. We find that the TROPOMI biases relative to GOSAT are related to the presence of aerosols and clouds, the surface brightness, and the specific detector that makes the observation aboard TROPOMI. The resulting blended TROPOMI+GOSAT product is more reliable for quantifying methane emissions.
Thomas E. Taylor, Christopher W. O'Dell, David Baker, Carol Bruegge, Albert Chang, Lars Chapsky, Abhishek Chatterjee, Cecilia Cheng, Frédéric Chevallier, David Crisp, Lan Dang, Brian Drouin, Annmarie Eldering, Liang Feng, Brendan Fisher, Dejian Fu, Michael Gunson, Vance Haemmerle, Graziela R. Keller, Matthäus Kiel, Le Kuai, Thomas Kurosu, Alyn Lambert, Joshua Laughner, Richard Lee, Junjie Liu, Lucas Mandrake, Yuliya Marchetti, Gregory McGarragh, Aronne Merrelli, Robert R. Nelson, Greg Osterman, Fabiano Oyafuso, Paul I. Palmer, Vivienne H. Payne, Robert Rosenberg, Peter Somkuti, Gary Spiers, Cathy To, Brad Weir, Paul O. Wennberg, Shanshan Yu, and Jia Zong
Atmos. Meas. Tech., 16, 3173–3209, https://doi.org/10.5194/amt-16-3173-2023, https://doi.org/10.5194/amt-16-3173-2023, 2023
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NASA's Orbiting Carbon Observatory 2 and 3 (OCO-2 and OCO-3, respectively) provide complementary spatiotemporal coverage from a sun-synchronous and precession orbit, respectively. Estimates of total column carbon dioxide (XCO2) derived from the two sensors using the same retrieval algorithm show broad consistency over a 2.5-year overlapping time record. This suggests that data from the two satellites may be used together for scientific analysis.
Lena Katharina Jänicke, Rene Preusker, Marco Celesti, Marin Tudoroiu, Jürgen Fischer, Dirk Schüttemeyer, and Matthias Drusch
Atmos. Meas. Tech., 16, 3101–3121, https://doi.org/10.5194/amt-16-3101-2023, https://doi.org/10.5194/amt-16-3101-2023, 2023
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To compare two top-of-atmosphere radiances measured by instruments with different spectral characteristics, a transfer function has been developed. It is applied to a tandem data set of Sentinel-3A and B, for which OLCI-B mimicked the ESA’s eighth Earth Explorer FLEX. We found that OLCI-A measured radiances about 2 % brighter than OLCI-FLEX. Only at larger wavelengths were OLCI-A measurements about 5 % darker. The method is thus successful, being sensitive to calibration and processing issues.
Luis F. Millán, Gloria L. Manney, Harald Boenisch, Michaela I. Hegglin, Peter Hoor, Daniel Kunkel, Thierry Leblanc, Irina Petropavlovskikh, Kaley Walker, Krzysztof Wargan, and Andreas Zahn
Atmos. Meas. Tech., 16, 2957–2988, https://doi.org/10.5194/amt-16-2957-2023, https://doi.org/10.5194/amt-16-2957-2023, 2023
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The determination of atmospheric composition trends in the upper troposphere and lower stratosphere (UTLS) is still highly uncertain. We present the creation of dynamical diagnostics to map several ozone datasets (ozonesondes, lidars, aircraft, and satellite measurements) in geophysically based coordinate systems. The diagnostics can also be used to analyze other greenhouse gases relevant to surface climate and UTLS chemistry.
Zhihua Zhang, Jianguo Niu, Lawrence E. Flynn, Eric Beach, and Trevor Beck
Atmos. Meas. Tech., 16, 2919–2941, https://doi.org/10.5194/amt-16-2919-2023, https://doi.org/10.5194/amt-16-2919-2023, 2023
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This study mainly focused on addressing stability and improvement when using a broadband approach, establishing soft-calibration adjustments for both OMPS S-NPP and N20, analyzing error biases based on multi-sensor bias correction, and comparing total column ozone and aerosol index retrievals from NOAA OMPS with those from other products.
Matthew S. Johnson, Amir H. Souri, Sajeev Philip, Rajesh Kumar, Aaron Naeger, Jeffrey Geddes, Laura Judd, Scott Janz, Heesung Chong, and John Sullivan
Atmos. Meas. Tech., 16, 2431–2454, https://doi.org/10.5194/amt-16-2431-2023, https://doi.org/10.5194/amt-16-2431-2023, 2023
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Satellites provide vital information for studying the processes controlling ozone formation. Based on the abundance of particular gases in the atmosphere, ozone formation is sensitive to specific human-induced and natural emission sources. However, errors and biases in satellite retrievals hinder this data source’s application for studying ozone formation sensitivity. We conducted a thorough statistical evaluation of two commonly applied satellites for investigating ozone formation sensitivity.
Kezia Lange, Andreas Richter, Anja Schönhardt, Andreas C. Meier, Tim Bösch, André Seyler, Kai Krause, Lisa K. Behrens, Folkard Wittrock, Alexis Merlaud, Frederik Tack, Caroline Fayt, Martina M. Friedrich, Ermioni Dimitropoulou, Michel Van Roozendael, Vinod Kumar, Sebastian Donner, Steffen Dörner, Bianca Lauster, Maria Razi, Christian Borger, Katharina Uhlmannsiek, Thomas Wagner, Thomas Ruhtz, Henk Eskes, Birger Bohn, Daniel Santana Diaz, Nader Abuhassan, Dirk Schüttemeyer, and John P. Burrows
Atmos. Meas. Tech., 16, 1357–1389, https://doi.org/10.5194/amt-16-1357-2023, https://doi.org/10.5194/amt-16-1357-2023, 2023
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We present airborne imaging DOAS and ground-based stationary and car DOAS measurements conducted during the S5P-VAL-DE-Ruhr campaign in the Rhine-Ruhr region. The measurements are used to validate spaceborne NO2 data products from the Sentinel-5 Precursor TROPOspheric Monitoring Instrument (TROPOMI). Auxiliary data of the TROPOMI NO2 retrieval, such as spatially higher resolved a priori NO2 vertical profiles, surface reflectivity, and cloud treatment are investigated to evaluate their impact.
Yolanda Maria Lemes, Christoph Häni, Jesper Nørlem Kamp, and Anders Feilberg
Atmos. Meas. Tech., 16, 1295–1309, https://doi.org/10.5194/amt-16-1295-2023, https://doi.org/10.5194/amt-16-1295-2023, 2023
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The implementation of a new method, line-averaged concentration measurement with a closed-path analyzer, will enable the measurement of fluxes of multiple gases from different types of sources and will evaluate the effects of mitigation strategies on emissions. In addition, this method allows for continuous online measurements that resolve temporal variation in ammonia emissions and the peak emissions of methane.
Prajjwal Rawat, Manish Naja, Evan Fishbein, Pradeep K. Thapliyal, Rajesh Kumar, Piyush Bhardwaj, Aditya Jaiswal, Sugriva N. Tiwari, Sethuraman Venkataramani, and Shyam Lal
Atmos. Meas. Tech., 16, 889–909, https://doi.org/10.5194/amt-16-889-2023, https://doi.org/10.5194/amt-16-889-2023, 2023
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Satellite-based ozone observations have gained importance due to their global coverage. However, satellite-retrieved products are indirect and need to be validated, particularly over mountains. Ozonesondes launched from a Himalayan site are used to assess the Atmospheric Infrared Sounder (AIRS) ozone retrieval. AIRS is shown to overestimate ozone in the upper troposphere and lower stratosphere, while the differences from ozonesondes are more minor in the middle troposphere and stratosphere.
Murali Natarajan, Robert Damadeo, and David Flittner
Atmos. Meas. Tech., 16, 75–87, https://doi.org/10.5194/amt-16-75-2023, https://doi.org/10.5194/amt-16-75-2023, 2023
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Photochemically induced changes in mesospheric O3 concentration at twilight can cause asymmetry in the distribution along the line of sight of solar occultation observations that must be considered in the retrieval algorithm. Correction factors developed from diurnal photochemical model simulations were used to modify the archived SAGE III/ISS mesospheric O3 concentrations. For June 2021 the bias caused by the neglect of diurnal variations is over 30% at 64 km altitude and low latitudes.
Javier Gorroño, Daniel J. Varon, Itziar Irakulis-Loitxate, and Luis Guanter
Atmos. Meas. Tech., 16, 89–107, https://doi.org/10.5194/amt-16-89-2023, https://doi.org/10.5194/amt-16-89-2023, 2023
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We present a methane flux rate retrieval methodology using the Sentinel-2 mission, validating the algorithm for different scenes and plumes. The detection limit is 1000–2000 kg h−1 for homogeneous scenes and temporally invariant surfaces and above 5000 kg h−1 for heterogeneous ones. Dominant quantification errors are wind-related or plume mask-related. For heterogeneous scenes, the surface structure underlying the methane plume can become a dominant source of uncertainty.
Katerina Garane, Ka Lok Chan, Maria-Elissavet Koukouli, Diego Loyola, and Dimitris Balis
Atmos. Meas. Tech., 16, 57–74, https://doi.org/10.5194/amt-16-57-2023, https://doi.org/10.5194/amt-16-57-2023, 2023
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In this work, 2.5 years of TROPOMI/S5P Total Column Water Vapor (TCWV) observations retrieved from the blue wavelength band are validated against co-located precipitable water measurements from NASA AERONET, which uses Cimel Sun photometers globally. Overall, the TCWV product agrees well on a global scale with the ground-based dataset (Pearson correl. coefficient 0.909) and has a mean relative bias of −2.7 ± 4.9 % with respect to the AERONET observations for moderate albedo and cloudiness.
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Short summary
This paper presents the first global data set of atmospheric concentrations of the isotopologues of methane as measured by ACE-FTS. Both CH3D and 13CH4 show enrichment at higher altitudes and some seasonal variation at the poles. After applying a constant correction factor to the CH3D data set, good agreement with existing balloon measurements is achieved. However, 13CH4 still shows a large amount of error. Improved lab measurements of CH4 would help reduce errors in the ACE-FTS data.
This paper presents the first global data set of atmospheric concentrations of the isotopologues...
