Articles | Volume 8, issue 12
https://doi.org/10.5194/amt-8-5289-2015
https://doi.org/10.5194/amt-8-5289-2015
Research article
 | 
18 Dec 2015
Research article |  | 18 Dec 2015

Gas adsorption and desorption effects on cylinders and their importance for long-term gas records

M. C. Leuenberger, M. F. Schibig, and P. Nyfeler

Related authors

The Antarctic Ice Core Chronology 2023 (AICC2023) chronological framework and associated timescale for the European Project for Ice Coring in Antarctica (EPICA) Dome C ice core
Marie Bouchet, Amaëlle Landais, Antoine Grisart, Frédéric Parrenin, Frédéric Prié, Roxanne Jacob, Elise Fourré, Emilie Capron, Dominique Raynaud, Vladimir Ya Lipenkov, Marie-France Loutre, Thomas Extier, Anders Svensson, Etienne Legrain, Patricia Martinerie, Markus Leuenberger, Wei Jiang, Florian Ritterbusch, Zheng-Tian Lu, and Guo-Min Yang
Clim. Past, 19, 2257–2286, https://doi.org/10.5194/cp-19-2257-2023,https://doi.org/10.5194/cp-19-2257-2023, 2023
Short summary
Revision of an open-split-based dual-inlet system for elemental and isotope ratio mass spectrometers with a focus on clumped-isotope measurements
Stephan Räss, Peter Nyfeler, Paul Wheeler, Will Price, and Markus Christian Leuenberger
Atmos. Meas. Tech., 16, 4489–4505, https://doi.org/10.5194/amt-16-4489-2023,https://doi.org/10.5194/amt-16-4489-2023, 2023
Short summary
Multi-proxy speleothem-based reconstruction of mid-MIS 3 climate in South Africa
Jenny Maccali, Anna Nele Meckler, Stein-Erik Lauritzen, Torill Brekken, Helen Aase Rokkan, Alvaro Fernandez, Yves Krüger, Jane Adigun, Stéphane Affolter, and Markus Leuenberger
Clim. Past, 19, 1847–1862, https://doi.org/10.5194/cp-19-1847-2023,https://doi.org/10.5194/cp-19-1847-2023, 2023
Short summary
Analysis of high gas concentration and flux measurements at Swiss Beromünster tall tower
Andreas Plach, Rolf Rüfenacht, Simone Kotthaus, and Markus Leuenberger
EGUsphere, https://doi.org/10.5194/egusphere-2022-1019,https://doi.org/10.5194/egusphere-2022-1019, 2022
Preprint archived
Short summary
High-resolution inverse modelling of European CH4 emissions using the novel FLEXPART-COSMO TM5 4DVAR inverse modelling system
Peter Bergamaschi, Arjo Segers, Dominik Brunner, Jean-Matthieu Haussaire, Stephan Henne, Michel Ramonet, Tim Arnold, Tobias Biermann, Huilin Chen, Sebastien Conil, Marc Delmotte, Grant Forster, Arnoud Frumau, Dagmar Kubistin, Xin Lan, Markus Leuenberger, Matthias Lindauer, Morgan Lopez, Giovanni Manca, Jennifer Müller-Williams, Simon O'Doherty, Bert Scheeren, Martin Steinbacher, Pamela Trisolino, Gabriela Vítková, and Camille Yver Kwok
Atmos. Chem. Phys., 22, 13243–13268, https://doi.org/10.5194/acp-22-13243-2022,https://doi.org/10.5194/acp-22-13243-2022, 2022
Short summary

Related subject area

Subject: Gases | Technique: Laboratory Measurement | Topic: Validation and Intercomparisons
A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO3 ToFCIMS) sensitivity study
Stéphanie Alage, Vincent Michoud, Sergio Harb, Bénédicte Picquet-Varrault, Manuela Cirtog, Avinash Kumar, Matti Rissanen, and Christopher Cantrell
Atmos. Meas. Tech., 17, 4709–4724, https://doi.org/10.5194/amt-17-4709-2024,https://doi.org/10.5194/amt-17-4709-2024, 2024
Short summary
Two new 222Rn emanation sources – a comparison study
Tanita J. Ballé, Stefan Röttger, Florian Mertes, Anja Honig, Petr Kovar, Petr P. S. Otáhal, and Annette Röttger
Atmos. Meas. Tech., 17, 2055–2065, https://doi.org/10.5194/amt-17-2055-2024,https://doi.org/10.5194/amt-17-2055-2024, 2024
Short summary
A traceable and continuous flow calibration method for gaseous elemental mercury at low ambient concentrations
Teodor D. Andron, Warren T. Corns, Igor Živković, Saeed Waqar Ali, Sreekanth Vijayakumaran Nair, and Milena Horvat
Atmos. Meas. Tech., 17, 1217–1228, https://doi.org/10.5194/amt-17-1217-2024,https://doi.org/10.5194/amt-17-1217-2024, 2024
Short summary
Measurements of atmospheric C10–C15 biogenic volatile organic compounds (BVOCs) with sorbent tubes
Heidi Hellén, Toni Tykkä, Simon Schallhart, Evdokia Stratigou, Thérèse Salameh, and Maitane Iturrate-Garcia
Atmos. Meas. Tech., 17, 315–333, https://doi.org/10.5194/amt-17-315-2024,https://doi.org/10.5194/amt-17-315-2024, 2024
Short summary
Results of a long-term international comparison of greenhouse gas and isotope measurements at the Global Atmosphere Watch (GAW) Observatory in Alert, Nunavut, Canada
Douglas E. J. Worthy, Michele K. Rauh, Lin Huang, Felix R. Vogel, Alina Chivulescu, Kenneth A. Masarie, Ray L. Langenfelds, Paul B. Krummel, Colin E. Allison, Andrew M. Crotwell, Monica Madronich, Gabrielle Pétron, Ingeborg Levin, Samuel Hammer, Sylvia Michel, Michel Ramonet, Martina Schmidt, Armin Jordan, Heiko Moossen, Michael Rothe, Ralph Keeling, and Eric J. Morgan
Atmos. Meas. Tech., 16, 5909–5935, https://doi.org/10.5194/amt-16-5909-2023,https://doi.org/10.5194/amt-16-5909-2023, 2023
Short summary

Cited articles

Bender, M. L., Tans, P. P., Ellis, J. T., Orchardo, J., and Habfast, K.: A high-precision isotope ratio mass-spectrometry method for measuring the O2 N2 ratio of air, Geochim. Cosmochim. Ac., 58, 4751–4758, 1994.
Berhanu, T. A., Satar, E., Schanda, R., Nyfeler, P., Moret, H., Brunner, D., Oney, B., and Leuenberger, M.: Measurements of greenhouse gases at Beromünster tall tower station in Switzerland, Atmos. Meas. Tech. Discuss., 8, 10793–10822, https://doi.org/10.5194/amtd-8-10793-2015, 2015.
Brunauer, S., Emmett, P. H., and Teller, E.: Adsorption of Gases in Multimolecular Layers, J. Am. Chem. Soc., 60, 309–319, 1938.
Chen, H.: Long-term stability of calibration gases in cylinders for CO2, CH4, CO, N2O, and SF6, in 17th WMO(IAEA meeting on Carbon Dioxide , other greenhouse gases and related measurement techniques (GGMT-2013), edited by: WMO/IAEA, Chinese Meterological Administration, Beijing, China, 2013.
Freundlich, H. M. F.: Über die Adsorption in Lösungen., Z. Phys. Chem., 57, 385–470, 1906.
Download
Short summary
Adsorption/desorption effects of trace gases in gas cylinders were investigated. Our measurements indicate a rather strong effect on steel cylinders for CO2 that becomes easily visible through enhanced concentrations for low (<20 bars) gas pressure. Much smaller effects are observed for CO and CH4. Significantly smaller effects are measured for all gas species investigated on aluminium cylinders. Careful selection of gas cylinders for high-precision calibration purposes is recommended.