Articles | Volume 13, issue 11
https://doi.org/10.5194/amt-13-6255-2020
https://doi.org/10.5194/amt-13-6255-2020
Research article
 | 
20 Nov 2020
Research article |  | 20 Nov 2020

A thermal-dissociation–cavity ring-down spectrometer (TD-CRDS) for the detection of organic nitrates in gas and particle phases

Natalie I. Keehan, Bellamy Brownwood, Andrey Marsavin, Douglas A. Day, and Juliane L. Fry

Related authors

Absorption of volatile organic compounds (VOCs) by polymer tubing: implications for indoor air and use as a simple gas-phase volatility separation technique
Melissa A. Morris, Demetrios Pagonis, Douglas A. Day, Joost A. de Gouw, Paul J. Ziemann, and Jose L. Jimenez
Atmos. Meas. Tech., 17, 1545–1559, https://doi.org/10.5194/amt-17-1545-2024,https://doi.org/10.5194/amt-17-1545-2024, 2024
Short summary
Parameterizations of US wildfire and prescribed fire emission ratios and emission factors based on FIREX-AQ aircraft measurements
Georgios I. Gkatzelis, Matthew M. Coggon, Chelsea E. Stockwell, Rebecca S. Hornbrook, Hannah Allen, Eric C. Apel, Megan M. Bela, Donald R. Blake, Ilann Bourgeois, Steven S. Brown, Pedro Campuzano-Jost, Jason M. St. Clair, James H. Crawford, John D. Crounse, Douglas A. Day, Joshua P. DiGangi, Glenn S. Diskin, Alan Fried, Jessica B. Gilman, Hongyu Guo, Johnathan W. Hair, Hannah S. Halliday, Thomas F. Hanisco, Reem Hannun, Alan Hills, L. Gregory Huey, Jose L. Jimenez, Joseph M. Katich, Aaron Lamplugh, Young Ro Lee, Jin Liao, Jakob Lindaas, Stuart A. McKeen, Tomas Mikoviny, Benjamin A. Nault, J. Andrew Neuman, John B. Nowak, Demetrios Pagonis, Jeff Peischl, Anne E. Perring, Felix Piel, Pamela S. Rickly, Michael A. Robinson, Andrew W. Rollins, Thomas B. Ryerson, Melinda K. Schueneman, Rebecca H. Schwantes, Joshua P. Schwarz, Kanako Sekimoto, Vanessa Selimovic, Taylor Shingler, David J. Tanner, Laura Tomsche, Krystal T. Vasquez, Patrick R. Veres, Rebecca Washenfelder, Petter Weibring, Paul O. Wennberg, Armin Wisthaler, Glenn M. Wolfe, Caroline C. Womack, Lu Xu, Katherine Ball, Robert J. Yokelson, and Carsten Warneke
Atmos. Chem. Phys., 24, 929–956, https://doi.org/10.5194/acp-24-929-2024,https://doi.org/10.5194/acp-24-929-2024, 2024
Short summary
A multi-instrumental approach for calibrating two real-time mass spectrometers using high performance liquid chromatography and positive matrix factorization
Melinda K. Schueneman, Doug A. Day, Dongwook Kim, Pedro Campuzano-Jost, Seonsik Yun, Marla P. DeVault, Anna C. Ziola, Paul J. Ziemann, and Jose L. Jimenez
Aerosol Research Discuss., https://doi.org/10.5194/ar-2023-21,https://doi.org/10.5194/ar-2023-21, 2024
Preprint under review for AR
Short summary
A searchable database and mass spectral comparison tool for the Aerosol Mass Spectrometer (AMS) and the Aerosol Chemical Speciation Monitor (ACSM)
Sohyeon Jeon, Michael J. Walker, Donna T. Sueper, Douglas A. Day, Anne V. Handschy, Jose L. Jimenez, and Brent J. Williams
Atmos. Meas. Tech., 16, 6075–6095, https://doi.org/10.5194/amt-16-6075-2023,https://doi.org/10.5194/amt-16-6075-2023, 2023
Short summary
A comprehensive evaluation of enhanced temperature influence on gas and aerosol chemistry in the lamp-enclosed oxidation flow reactor (OFR) system
Tianle Pan, Andrew T. Lambe, Weiwei Hu, Yicong He, Minghao Hu, Huaishan Zhou, Xinming Wang, Qingqing Hu, Hui Chen, Yue Zhao, Yuanlong Huang, Doug R. Worsnop, Zhe Peng, Melissa A. Morris, Douglas A. Day, Pedro Campuzano-Jost, Jose-Luis Jimenez, and Shantanu H. Jathar
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2023-230,https://doi.org/10.5194/amt-2023-230, 2023
Preprint under review for AMT
Short summary

Related subject area

Subject: Gases | Technique: Laboratory Measurement | Topic: Instruments and Platforms
Absorption of volatile organic compounds (VOCs) by polymer tubing: implications for indoor air and use as a simple gas-phase volatility separation technique
Melissa A. Morris, Demetrios Pagonis, Douglas A. Day, Joost A. de Gouw, Paul J. Ziemann, and Jose L. Jimenez
Atmos. Meas. Tech., 17, 1545–1559, https://doi.org/10.5194/amt-17-1545-2024,https://doi.org/10.5194/amt-17-1545-2024, 2024
Short summary
Response of protonated, adduct, and fragmented ions in Vocus proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS)
Fangbing Li, Dan Dan Huang, Linhui Tian, Bin Yuan, Wen Tan, Liang Zhu, Penglin Ye, Douglas Worsnop, Ka In Hoi, Kai Meng Mok, and Yong Jie Li
EGUsphere, https://doi.org/10.5194/egusphere-2024-16,https://doi.org/10.5194/egusphere-2024-16, 2024
Short summary
A flexible device to produce a gas stream with a precisely controlled water vapour mixing ratio and isotope composition based on microdrop dispensing technology
Harald Sodemann, Alena Dekhtyareva, Alvaro Fernandez, Andrew Seidl, and Jenny Maccali
Atmos. Meas. Tech., 16, 5181–5203, https://doi.org/10.5194/amt-16-5181-2023,https://doi.org/10.5194/amt-16-5181-2023, 2023
Short summary
Revision of an open-split-based dual-inlet system for elemental and isotope ratio mass spectrometers with a focus on clumped-isotope measurements
Stephan Räss, Peter Nyfeler, Paul Wheeler, Will Price, and Markus Christian Leuenberger
Atmos. Meas. Tech., 16, 4489–4505, https://doi.org/10.5194/amt-16-4489-2023,https://doi.org/10.5194/amt-16-4489-2023, 2023
Short summary
Characterisation of gaseous iodine species detection using the multi-scheme chemical ionisation inlet 2 with bromide and nitrate chemical ionisation methods
Xu-Cheng He, Jiali Shen, Siddharth Iyer, Paxton Juuti, Jiangyi Zhang, Mrisha Koirala, Mikko M. Kytökari, Douglas R. Worsnop, Matti Rissanen, Markku Kulmala, Norbert M. Maier, Jyri Mikkilä, Mikko Sipilä, and Juha Kangasluoma
Atmos. Meas. Tech., 16, 4461–4487, https://doi.org/10.5194/amt-16-4461-2023,https://doi.org/10.5194/amt-16-4461-2023, 2023
Short summary

Cited articles

Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., Troe, J., and IUPAC Subcommittee: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species, Atmos. Chem. Phys., 6, 3625–4055, https://doi.org/10.5194/acp-6-3625-2006, 2006. 
Browne, E. C., Min, K.-E., Wooldridge, P. J., Apel, E., Blake, D. R., Brune, W. H., Cantrell, C. A., Cubison, M. J., Diskin, G. S., Jimenez, J. L., Weinheimer, A. J., Wennberg, P. O., Wisthaler, A., and Cohen, R. C.: Observations of total RONO2 over the boreal forest: NOx sinks and HNO3 sources, Atmos. Chem. Phys., 13, 4543–4562, https://doi.org/10.5194/acp-13-4543-2013, 2013. 
Brownwood, B., Turdziladze, A., Hohaus, T., Andres, S., Carlsson, P., Fuchs, H., Novelli, A., Tsiligiannis, E., Hallquist, M., Wu, R., Mentel, T., Hantschke, L., Liebmann, J., Brown, S. S., Rohrer, F., Tillmann, R., Reimer, D., Winter, B., Kiendler-Scharr, A., and Fry, J. L.: Gas-particle partitioning and SOA yields of organonitrate products from NO3-initiated oxidation of isoprene under varied chemical regimes, ACS Earth & Space Chem., submitted, 2020. 
Buhr, M. P., Parrish, D. D., Norton, R. B., Fehsenfeld, F. C., Sievers, R. E., and Roberts, J. M.: Contribution of organic nitrates to the total reactive nitrogen budget at a rural eastern U.S. site, J. Geophys. Res., 95, 9809–9816, https://doi.org/10.1029/JD095iD07p09809, 1990. 
Day, D. A., Wooldridge, P. J. ,Dillon, P. J., Thornton, J. A., and Cohen, R. C.: A thermal dissociation laser‐induced fluorescence instrument for in situ detection of NO2, peroxy nitrates, alkyl nitrates, and HNO3, J. Geophys. Res., 107, ACH 4-1–ACH 4-14, https://doi.org/10.1029/2001JD000779, 2002. 
Download
Short summary
This paper describes a new instrument (a thermal-dissociation–cavity ring-down spectrometer, TD-CRDS) for the measurement of key atmospheric gaseous and particle-phase molecules containing the nitrate functional group. Several operational considerations affecting the measurements are described, as well as several characterization experiments comparing the TD-CRDS measurements to analogous measurements from other instruments. Examples are given using a TD-CRDS for ambient and laboratory studies.