Articles | Volume 14, issue 10
https://doi.org/10.5194/amt-14-6357-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-14-6357-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
01 Oct 2021
Research article |
| 01 Oct 2021
| 01 Oct 2021
Assessment of online water-soluble brown carbon measuring systems for aircraft sampling
Linghan Zeng
School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, GA, USA
Amy P. Sullivan
Department of Atmospheric Science, Colorado State University, Fort Collins, Colorado, USA
Rebecca A. Washenfelder
Chemical Sciences Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
Jack Dibb
College of Engineering and Physical Sciences, University of New Hampshire, Durham, NH, USA
Eric Scheuer
College of Engineering and Physical Sciences, University of New Hampshire, Durham, NH, USA
Teresa L. Campos
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO, USA
Joseph M. Katich
Chemical Sciences Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, USA
Ezra Levin
Department of Atmospheric Science, Colorado State University, Fort Collins, Colorado, USA
Handix Scientific, Boulder, CO, USA
Michael A. Robinson
Chemical Sciences Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, USA
Department of Chemistry, University of Colorado Boulder, Boulder, CO, USA
Rodney J. Weber
CORRESPONDING AUTHOR
School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, GA, USA
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Atmos. Chem. Phys., 24, 929–956, https://doi.org/10.5194/acp-24-929-2024, https://doi.org/10.5194/acp-24-929-2024, 2024
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Tobias Borsdorff, Teresa Campos, Natalie Kille, Kyle J. Zarzana, Rainer Volkamer, and Jochen Landgraf
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Lixu Jin, Wade Permar, Vanessa Selimovic, Damien Ketcherside, Robert J. Yokelson, Rebecca S. Hornbrook, Eric C. Apel, I-Ting Ku, Jeffrey L. Collett Jr., Amy P. Sullivan, Daniel A. Jaffe, Jeffrey R. Pierce, Alan Fried, Matthew M. Coggon, Georgios I. Gkatzelis, Carsten Warneke, Emily V. Fischer, and Lu Hu
Atmos. Chem. Phys., 23, 5969–5991, https://doi.org/10.5194/acp-23-5969-2023, https://doi.org/10.5194/acp-23-5969-2023, 2023
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Haihui Zhu, Randall V. Martin, Betty Croft, Shixian Zhai, Chi Li, Liam Bindle, Jeffrey R. Pierce, Rachel Y.-W. Chang, Bruce E. Anderson, Luke D. Ziemba, Johnathan W. Hair, Richard A. Ferrare, Chris A. Hostetler, Inderjeet Singh, Deepangsu Chatterjee, Jose L. Jimenez, Pedro Campuzano-Jost, Benjamin A. Nault, Jack E. Dibb, Joshua S. Schwarz, and Andrew Weinheimer
Atmos. Chem. Phys., 23, 5023–5042, https://doi.org/10.5194/acp-23-5023-2023, https://doi.org/10.5194/acp-23-5023-2023, 2023
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Shixian Zhai, Daniel J. Jacob, Drew C. Pendergrass, Nadia K. Colombi, Viral Shah, Laura Hyesung Yang, Qiang Zhang, Shuxiao Wang, Hwajin Kim, Yele Sun, Jin-Soo Choi, Jin-Soo Park, Gan Luo, Fangqun Yu, Jung-Hun Woo, Younha Kim, Jack E. Dibb, Taehyoung Lee, Jin-Seok Han, Bruce E. Anderson, Ke Li, and Hong Liao
Atmos. Chem. Phys., 23, 4271–4281, https://doi.org/10.5194/acp-23-4271-2023, https://doi.org/10.5194/acp-23-4271-2023, 2023
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Anthropogenic fugitive dust in East Asia not only causes severe coarse particulate matter air pollution problems, but also affects fine particulate nitrate. Due to emission control efforts, coarse PM decreased steadily. We find that the decrease of coarse PM is a major driver for a lack of decrease of fine particulate nitrate, as it allows more nitric acid to form fine particulate nitrate. The continuing decrease of coarse PM requires more stringent ammonia and nitrogen oxides emission controls.
Lu Xu, Matthew M. Coggon, Chelsea E. Stockwell, Jessica B. Gilman, Michael A. Robinson, Martin Breitenlechner, Aaron Lamplugh, John D. Crounse, Paul O. Wennberg, J. Andrew Neuman, Gordon A. Novak, Patrick R. Veres, Steven S. Brown, and Carsten Warneke
Atmos. Meas. Tech., 15, 7353–7373, https://doi.org/10.5194/amt-15-7353-2022, https://doi.org/10.5194/amt-15-7353-2022, 2022
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We describe the development and operation of a chemical ionization mass spectrometer using an ammonium–water cluster (NH4+·H2O) as a reagent ion. NH4+·H2O is a highly versatile reagent ion for measurements of a wide range of oxygenated organic compounds. The major product ion is the cluster with NH4+ produced via ligand-switching reactions. The instrumental sensitivities of analytes depend on the binding energy of the analyte–NH4+ cluster; sensitivities can be estimated using voltage scanning.
Pamela S. Rickly, Hongyu Guo, Pedro Campuzano-Jost, Jose L. Jimenez, Glenn M. Wolfe, Ryan Bennett, Ilann Bourgeois, John D. Crounse, Jack E. Dibb, Joshua P. DiGangi, Glenn S. Diskin, Maximilian Dollner, Emily M. Gargulinski, Samuel R. Hall, Hannah S. Halliday, Thomas F. Hanisco, Reem A. Hannun, Jin Liao, Richard Moore, Benjamin A. Nault, John B. Nowak, Jeff Peischl, Claire E. Robinson, Thomas Ryerson, Kevin J. Sanchez, Manuel Schöberl, Amber J. Soja, Jason M. St. Clair, Kenneth L. Thornhill, Kirk Ullmann, Paul O. Wennberg, Bernadett Weinzierl, Elizabeth B. Wiggins, Edward L. Winstead, and Andrew W. Rollins
Atmos. Chem. Phys., 22, 15603–15620, https://doi.org/10.5194/acp-22-15603-2022, https://doi.org/10.5194/acp-22-15603-2022, 2022
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Biomass burning sulfur dioxide (SO2) emission factors range from 0.27–1.1 g kg-1 C. Biomass burning SO2 can quickly form sulfate and organosulfur, but these pathways are dependent on liquid water content and pH. Hydroxymethanesulfonate (HMS) appears to be directly emitted from some fire sources but is not the sole contributor to the organosulfur signal. It is shown that HMS and organosulfur chemistry may be an important S(IV) reservoir with the fate dependent on the surrounding conditions.
Caroline C. Womack, Steven S. Brown, Steven J. Ciciora, Ru-Shan Gao, Richard J. McLaughlin, Michael A. Robinson, Yinon Rudich, and Rebecca A. Washenfelder
Atmos. Meas. Tech., 15, 6643–6652, https://doi.org/10.5194/amt-15-6643-2022, https://doi.org/10.5194/amt-15-6643-2022, 2022
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We present a new miniature instrument to measure nitrogen dioxide (NO2) using cavity-enhanced spectroscopy. NO2 contributes to the formation of pollutants such as ozone and particulate matter, and its concentration can vary widely near sources. We developed this lightweight (3.05 kg) low-power (<35 W) instrument to measure NO2 on uncrewed aircraft vehicles (UAVs) and demonstrate that it has the accuracy and precision needed for atmospheric field measurements.
Youhua Tang, Patrick C. Campbell, Pius Lee, Rick Saylor, Fanglin Yang, Barry Baker, Daniel Tong, Ariel Stein, Jianping Huang, Ho-Chun Huang, Li Pan, Jeff McQueen, Ivanka Stajner, Jose Tirado-Delgado, Youngsun Jung, Melissa Yang, Ilann Bourgeois, Jeff Peischl, Tom Ryerson, Donald Blake, Joshua Schwarz, Jose-Luis Jimenez, James Crawford, Glenn Diskin, Richard Moore, Johnathan Hair, Greg Huey, Andrew Rollins, Jack Dibb, and Xiaoyang Zhang
Geosci. Model Dev., 15, 7977–7999, https://doi.org/10.5194/gmd-15-7977-2022, https://doi.org/10.5194/gmd-15-7977-2022, 2022
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This paper compares two meteorological datasets for driving a regional air quality model: a regional meteorological model using WRF (WRF-CMAQ) and direct interpolation from an operational global model (GFS-CMAQ). In the comparison with surface measurements and aircraft data in summer 2019, these two methods show mixed performance depending on the corresponding meteorological settings. Direct interpolation is found to be a viable method to drive air quality models.
Amy P. Sullivan, Rudra P. Pokhrel, Yingjie Shen, Shane M. Murphy, Darin W. Toohey, Teresa Campos, Jakob Lindaas, Emily V. Fischer, and Jeffrey L. Collett Jr.
Atmos. Chem. Phys., 22, 13389–13406, https://doi.org/10.5194/acp-22-13389-2022, https://doi.org/10.5194/acp-22-13389-2022, 2022
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During the WE-CAN (Western Wildfire Experiment for Cloud Chemistry, Aerosol Absorption and Nitrogen) study, brown carbon (BrC) absorption was measured on the NSF/NCAR C-130 aircraft using a particle-into-liquid sampler and photoacoustic aerosol absorption spectrometer. Approximately 45 % of the BrC absorption in wildfires was observed to be due to water-soluble species. The ratio of BrC absorption to WSOC or ΔCO showed no clear dependence on fire dynamics or the time since emission over 9 h.
Ilann Bourgeois, Jeff Peischl, J. Andrew Neuman, Steven S. Brown, Hannah M. Allen, Pedro Campuzano-Jost, Matthew M. Coggon, Joshua P. DiGangi, Glenn S. Diskin, Jessica B. Gilman, Georgios I. Gkatzelis, Hongyu Guo, Hannah A. Halliday, Thomas F. Hanisco, Christopher D. Holmes, L. Gregory Huey, Jose L. Jimenez, Aaron D. Lamplugh, Young Ro Lee, Jakob Lindaas, Richard H. Moore, Benjamin A. Nault, John B. Nowak, Demetrios Pagonis, Pamela S. Rickly, Michael A. Robinson, Andrew W. Rollins, Vanessa Selimovic, Jason M. St. Clair, David Tanner, Krystal T. Vasquez, Patrick R. Veres, Carsten Warneke, Paul O. Wennberg, Rebecca A. Washenfelder, Elizabeth B. Wiggins, Caroline C. Womack, Lu Xu, Kyle J. Zarzana, and Thomas B. Ryerson
Atmos. Meas. Tech., 15, 4901–4930, https://doi.org/10.5194/amt-15-4901-2022, https://doi.org/10.5194/amt-15-4901-2022, 2022
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Understanding fire emission impacts on the atmosphere is key to effective air quality management and requires accurate measurements. We present a comparison of airborne measurements of key atmospheric species in ambient air and in fire smoke. We show that most instruments performed within instrument uncertainties. In some cases, further work is needed to fully characterize instrument performance. Comparing independent measurements using different techniques is important to assess their accuracy.
Aditya Kumar, R. Bradley Pierce, Ravan Ahmadov, Gabriel Pereira, Saulo Freitas, Georg Grell, Chris Schmidt, Allen Lenzen, Joshua P. Schwarz, Anne E. Perring, Joseph M. Katich, John Hair, Jose L. Jimenez, Pedro Campuzano-Jost, and Hongyu Guo
Atmos. Chem. Phys., 22, 10195–10219, https://doi.org/10.5194/acp-22-10195-2022, https://doi.org/10.5194/acp-22-10195-2022, 2022
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We use the WRF-Chem model with new implementations of GOES-16 wildfire emissions and plume rise based on fire radiative power (FRP) to interpret aerosol observations during the 2019 NASA–NOAA FIREX-AQ field campaign and perform model evaluations. The model shows significant improvements in simulating the variety of aerosol loading environments sampled during FIREX-AQ. Our results also highlight the importance of accurate wildfire diurnal cycle and aerosol chemical mechanisms in models.
Michael A. Robinson, J. Andrew Neuman, L. Gregory Huey, James M. Roberts, Steven S. Brown, and Patrick R. Veres
Atmos. Meas. Tech., 15, 4295–4305, https://doi.org/10.5194/amt-15-4295-2022, https://doi.org/10.5194/amt-15-4295-2022, 2022
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Iodide chemical ionization mass spectrometry (CIMS) is commonly used in atmospheric chemistry laboratory studies and field campaigns. Deployment of the NOAA iodide CIMS instrument in the summer of 2021 indicated a significant and overlooked temperature dependence of the instrument sensitivity. This work explores which analytes are influenced by this phenomena. Additionally, we recommend controls to reduce this effect for future field deployments.
Linghan Zeng, Jack Dibb, Eric Scheuer, Joseph M. Katich, Joshua P. Schwarz, Ilann Bourgeois, Jeff Peischl, Tom Ryerson, Carsten Warneke, Anne E. Perring, Glenn S. Diskin, Joshua P. DiGangi, John B. Nowak, Richard H. Moore, Elizabeth B. Wiggins, Demetrios Pagonis, Hongyu Guo, Pedro Campuzano-Jost, Jose L. Jimenez, Lu Xu, and Rodney J. Weber
Atmos. Chem. Phys., 22, 8009–8036, https://doi.org/10.5194/acp-22-8009-2022, https://doi.org/10.5194/acp-22-8009-2022, 2022
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Wildfires emit aerosol particles containing brown carbon material that affects visibility and global climate and is toxic. Brown carbon is poorly characterized due to measurement limitations, and its evolution in the atmosphere is not well known. We report on aircraft measurements of brown carbon from large wildfires in the western United States. We compare two methods for measuring brown carbon and study the evolution of brown carbon in the smoke as it moved away from the burning regions.
Katherine R. Travis, James H. Crawford, Gao Chen, Carolyn E. Jordan, Benjamin A. Nault, Hwajin Kim, Jose L. Jimenez, Pedro Campuzano-Jost, Jack E. Dibb, Jung-Hun Woo, Younha Kim, Shixian Zhai, Xuan Wang, Erin E. McDuffie, Gan Luo, Fangqun Yu, Saewung Kim, Isobel J. Simpson, Donald R. Blake, Limseok Chang, and Michelle J. Kim
Atmos. Chem. Phys., 22, 7933–7958, https://doi.org/10.5194/acp-22-7933-2022, https://doi.org/10.5194/acp-22-7933-2022, 2022
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The 2016 Korea–United States Air Quality (KORUS-AQ) field campaign provided a unique set of observations to improve our understanding of PM2.5 pollution in South Korea. Models typically have errors in simulating PM2.5 in this region, which is of concern for the development of control measures. We use KORUS-AQ observations to improve our understanding of the mechanisms driving PM2.5 and the implications of model errors for determining PM2.5 that is attributable to local or foreign sources.
Meloë S. F. Kacenelenbogen, Qian Tan, Sharon P. Burton, Otto P. Hasekamp, Karl D. Froyd, Yohei Shinozuka, Andreas J. Beyersdorf, Luke Ziemba, Kenneth L. Thornhill, Jack E. Dibb, Taylor Shingler, Armin Sorooshian, Reed W. Espinosa, Vanderlei Martins, Jose L. Jimenez, Pedro Campuzano-Jost, Joshua P. Schwarz, Matthew S. Johnson, Jens Redemann, and Gregory L. Schuster
Atmos. Chem. Phys., 22, 3713–3742, https://doi.org/10.5194/acp-22-3713-2022, https://doi.org/10.5194/acp-22-3713-2022, 2022
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The impact of aerosols on Earth's radiation budget and human health is important and strongly depends on their composition. One desire of our scientific community is to derive the composition of the aerosol from satellite sensors. However, satellites observe aerosol optical properties (and not aerosol composition) based on remote sensing instrumentation. This study assesses how much aerosol optical properties can tell us about aerosol composition.
Dongwook Kim, Changmin Cho, Seokhan Jeong, Soojin Lee, Benjamin A. Nault, Pedro Campuzano-Jost, Douglas A. Day, Jason C. Schroder, Jose L. Jimenez, Rainer Volkamer, Donald R. Blake, Armin Wisthaler, Alan Fried, Joshua P. DiGangi, Glenn S. Diskin, Sally E. Pusede, Samuel R. Hall, Kirk Ullmann, L. Gregory Huey, David J. Tanner, Jack Dibb, Christoph J. Knote, and Kyung-Eun Min
Atmos. Chem. Phys., 22, 805–821, https://doi.org/10.5194/acp-22-805-2022, https://doi.org/10.5194/acp-22-805-2022, 2022
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CHOCHO was simulated using a 0-D box model constrained by measurements during the KORUS-AQ mission. CHOCHO concentration was high in large cities, aromatics being the most important precursors. Loss path to aerosol was the highest sink, contributing to ~ 20 % of secondary organic aerosol formation. Our work highlights that simple CHOCHO surface uptake approach is valid only for low aerosol conditions and more work is required to understand CHOCHO solubility in high-aerosol conditions.
Jin Liao, Glenn M. Wolfe, Reem A. Hannun, Jason M. St. Clair, Thomas F. Hanisco, Jessica B. Gilman, Aaron Lamplugh, Vanessa Selimovic, Glenn S. Diskin, John B. Nowak, Hannah S. Halliday, Joshua P. DiGangi, Samuel R. Hall, Kirk Ullmann, Christopher D. Holmes, Charles H. Fite, Anxhelo Agastra, Thomas B. Ryerson, Jeff Peischl, Ilann Bourgeois, Carsten Warneke, Matthew M. Coggon, Georgios I. Gkatzelis, Kanako Sekimoto, Alan Fried, Dirk Richter, Petter Weibring, Eric C. Apel, Rebecca S. Hornbrook, Steven S. Brown, Caroline C. Womack, Michael A. Robinson, Rebecca A. Washenfelder, Patrick R. Veres, and J. Andrew Neuman
Atmos. Chem. Phys., 21, 18319–18331, https://doi.org/10.5194/acp-21-18319-2021, https://doi.org/10.5194/acp-21-18319-2021, 2021
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Formaldehyde (HCHO) is an important oxidant precursor and affects the formation of O3 and other secondary pollutants in wildfire plumes. We disentangle the processes controlling HCHO evolution from wildfire plumes sampled by NASA DC-8 during FIREX-AQ. We find that OH abundance rather than normalized OH reactivity is the main driver of fire-to-fire variability in HCHO secondary production and estimate an effective HCHO yield per volatile organic compound molecule oxidized in wildfire plumes.
Shixian Zhai, Daniel J. Jacob, Jared F. Brewer, Ke Li, Jonathan M. Moch, Jhoon Kim, Seoyoung Lee, Hyunkwang Lim, Hyun Chul Lee, Su Keun Kuk, Rokjin J. Park, Jaein I. Jeong, Xuan Wang, Pengfei Liu, Gan Luo, Fangqun Yu, Jun Meng, Randall V. Martin, Katherine R. Travis, Johnathan W. Hair, Bruce E. Anderson, Jack E. Dibb, Jose L. Jimenez, Pedro Campuzano-Jost, Benjamin A. Nault, Jung-Hun Woo, Younha Kim, Qiang Zhang, and Hong Liao
Atmos. Chem. Phys., 21, 16775–16791, https://doi.org/10.5194/acp-21-16775-2021, https://doi.org/10.5194/acp-21-16775-2021, 2021
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Geostationary satellite aerosol optical depth (AOD) has tremendous potential for monitoring surface fine particulate matter (PM2.5). Our study explored the physical relationship between AOD and PM2.5 by integrating data from surface networks, aircraft, and satellites with the GEOS-Chem chemical transport model. We quantitatively showed that accurate simulation of aerosol size distributions, boundary layer depths, relative humidity, coarse particles, and diurnal variations in PM2.5 are essential.
Zachary C. J. Decker, Michael A. Robinson, Kelley C. Barsanti, Ilann Bourgeois, Matthew M. Coggon, Joshua P. DiGangi, Glenn S. Diskin, Frank M. Flocke, Alessandro Franchin, Carley D. Fredrickson, Georgios I. Gkatzelis, Samuel R. Hall, Hannah Halliday, Christopher D. Holmes, L. Gregory Huey, Young Ro Lee, Jakob Lindaas, Ann M. Middlebrook, Denise D. Montzka, Richard Moore, J. Andrew Neuman, John B. Nowak, Brett B. Palm, Jeff Peischl, Felix Piel, Pamela S. Rickly, Andrew W. Rollins, Thomas B. Ryerson, Rebecca H. Schwantes, Kanako Sekimoto, Lee Thornhill, Joel A. Thornton, Geoffrey S. Tyndall, Kirk Ullmann, Paul Van Rooy, Patrick R. Veres, Carsten Warneke, Rebecca A. Washenfelder, Andrew J. Weinheimer, Elizabeth Wiggins, Edward Winstead, Armin Wisthaler, Caroline Womack, and Steven S. Brown
Atmos. Chem. Phys., 21, 16293–16317, https://doi.org/10.5194/acp-21-16293-2021, https://doi.org/10.5194/acp-21-16293-2021, 2021
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To understand air quality impacts from wildfires, we need an accurate picture of how wildfire smoke changes chemically both day and night as sunlight changes the chemistry of smoke. We present a chemical analysis of wildfire smoke as it changes from midday through the night. We use aircraft observations from the FIREX-AQ field campaign with a chemical box model. We find that even under sunlight typical
nighttimechemistry thrives and controls the fate of key smoke plume chemical processes.
Charles A. Brock, Karl D. Froyd, Maximilian Dollner, Christina J. Williamson, Gregory Schill, Daniel M. Murphy, Nicholas J. Wagner, Agnieszka Kupc, Jose L. Jimenez, Pedro Campuzano-Jost, Benjamin A. Nault, Jason C. Schroder, Douglas A. Day, Derek J. Price, Bernadett Weinzierl, Joshua P. Schwarz, Joseph M. Katich, Siyuan Wang, Linghan Zeng, Rodney Weber, Jack Dibb, Eric Scheuer, Glenn S. Diskin, Joshua P. DiGangi, ThaoPaul Bui, Jonathan M. Dean-Day, Chelsea R. Thompson, Jeff Peischl, Thomas B. Ryerson, Ilann Bourgeois, Bruce C. Daube, Róisín Commane, and Steven C. Wofsy
Atmos. Chem. Phys., 21, 15023–15063, https://doi.org/10.5194/acp-21-15023-2021, https://doi.org/10.5194/acp-21-15023-2021, 2021
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The Atmospheric Tomography Mission was an airborne study that mapped the chemical composition of the remote atmosphere. From this, we developed a comprehensive description of aerosol properties that provides a unique, global-scale dataset against which models can be compared. The data show the polluted nature of the remote atmosphere in the Northern Hemisphere and quantify the contributions of sea salt, dust, soot, biomass burning particles, and pollution particles to the haziness of the sky.
Jiajue Chai, Jack E. Dibb, Bruce E. Anderson, Claire Bekker, Danielle E. Blum, Eric Heim, Carolyn E. Jordan, Emily E. Joyce, Jackson H. Kaspari, Hannah Munro, Wendell W. Walters, and Meredith G. Hastings
Atmos. Chem. Phys., 21, 13077–13098, https://doi.org/10.5194/acp-21-13077-2021, https://doi.org/10.5194/acp-21-13077-2021, 2021
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Nitrous acid (HONO) derived from wildfire emissions plays a key role in controlling atmospheric oxidation chemistry. However, the HONO budget remains poorly constrained. By combining the field-observed concentrations and novel isotopic composition (N and O) of HONO and nitrogen oxides (NOx), we quantitatively constrained the relative contribution of each pathway to secondary HONO production and the relative importance of major atmospheric oxidants (ozone versus peroxy) in aged wildfire smoke.
Yang Wang, Guangjie Zheng, Michael P. Jensen, Daniel A. Knopf, Alexander Laskin, Alyssa A. Matthews, David Mechem, Fan Mei, Ryan Moffet, Arthur J. Sedlacek, John E. Shilling, Stephen Springston, Amy Sullivan, Jason Tomlinson, Daniel Veghte, Rodney Weber, Robert Wood, Maria A. Zawadowicz, and Jian Wang
Atmos. Chem. Phys., 21, 11079–11098, https://doi.org/10.5194/acp-21-11079-2021, https://doi.org/10.5194/acp-21-11079-2021, 2021
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This paper reports the vertical profiles of trace gas and aerosol properties over the eastern North Atlantic, a region of persistent but diverse subtropical marine boundary layer (MBL) clouds. We examined the key processes that drive the cloud condensation nuclei (CCN) population and how it varies with season and synoptic conditions. This study helps improve the model representation of the aerosol processes in the remote MBL, reducing the simulated aerosol indirect effects.
Yuhan Yang, Dong Gao, and Rodney J. Weber
Atmos. Meas. Tech., 14, 4707–4719, https://doi.org/10.5194/amt-14-4707-2021, https://doi.org/10.5194/amt-14-4707-2021, 2021
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Iron and copper are commonly found in ambient aerosols and have been linked to adverse health effects. We describe a relatively simple benchtop instrument that can be used to quantify these metals in aqueous solutions and verify the method by comparison with inductively coupled plasma mass spectrometry. The approach is based on forming light-absorbing metal–ligand complexes that can be measured with high sensitivity utilizing a long-path liquid waveguide capillary cell.
Hongyu Guo, Pedro Campuzano-Jost, Benjamin A. Nault, Douglas A. Day, Jason C. Schroder, Dongwook Kim, Jack E. Dibb, Maximilian Dollner, Bernadett Weinzierl, and Jose L. Jimenez
Atmos. Meas. Tech., 14, 3631–3655, https://doi.org/10.5194/amt-14-3631-2021, https://doi.org/10.5194/amt-14-3631-2021, 2021
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We utilize a set of high-quality datasets collected during the NASA Atmospheric Tomography Mission to investigate the impact of differences in observable particle sizes across aerosol instruments in aerosol measurement comparisons. Very good agreement was found between chemically and physically derived submicron aerosol volume. Results support a lack of significant unknown biases in the response of an Aerodyne aerosol mass spectrometer (AMS) when sampling remote aerosols across the globe.
Caroline C. Womack, Katherine M. Manfred, Nicholas L. Wagner, Gabriela Adler, Alessandro Franchin, Kara D. Lamb, Ann M. Middlebrook, Joshua P. Schwarz, Charles A. Brock, Steven S. Brown, and Rebecca A. Washenfelder
Atmos. Chem. Phys., 21, 7235–7252, https://doi.org/10.5194/acp-21-7235-2021, https://doi.org/10.5194/acp-21-7235-2021, 2021
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Microscopic particles interact with sunlight and affect the earth's climate in ways that are not fully understood. Aerosols from wildfire smoke present particular challenges due to their complexity in shape and composition. We demonstrate that we can experimentally measure aerosol optical properties for many types of smoke particles, using measurements of smoke from controlled burns, but that the method does not work well for smoke with high soot content.
Athanasios Nenes, Spyros N. Pandis, Maria Kanakidou, Armistead G. Russell, Shaojie Song, Petros Vasilakos, and Rodney J. Weber
Atmos. Chem. Phys., 21, 6023–6033, https://doi.org/10.5194/acp-21-6023-2021, https://doi.org/10.5194/acp-21-6023-2021, 2021
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Ecosystems and air quality are affected by the dry deposition of inorganic reactive nitrogen (Nr, the sum of ammonium and nitrate). Its large variability is driven by the large difference in deposition velocity of N when in the gas or particle phase. Here we show that aerosol liquid water and acidity, by affecting gas–particle partitioning, modulate the dry deposition velocity of NH3, HNO3, and Nr worldwide. These effects explain the rapid accumulation of nitrate aerosol during haze events.
Melinda K. Schueneman, Benjamin A. Nault, Pedro Campuzano-Jost, Duseong S. Jo, Douglas A. Day, Jason C. Schroder, Brett B. Palm, Alma Hodzic, Jack E. Dibb, and Jose L. Jimenez
Atmos. Meas. Tech., 14, 2237–2260, https://doi.org/10.5194/amt-14-2237-2021, https://doi.org/10.5194/amt-14-2237-2021, 2021
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This work focuses on two important properties of the aerosol, acidity, and sulfate composition, which is important for our understanding of aerosol health and environmental impacts. We explore different methods to understand the composition of the aerosol with measurements from a specific instrument and apply those methods to a large dataset. These measurements are confounded by other factors, making it challenging to predict aerosol sulfate composition; pH estimations, however, show promise.
Benjamin A. Nault, Pedro Campuzano-Jost, Douglas A. Day, Hongyu Guo, Duseong S. Jo, Anne V. Handschy, Demetrios Pagonis, Jason C. Schroder, Melinda K. Schueneman, Michael J. Cubison, Jack E. Dibb, Alma Hodzic, Weiwei Hu, Brett B. Palm, and Jose L. Jimenez
Atmos. Meas. Tech., 13, 6193–6213, https://doi.org/10.5194/amt-13-6193-2020, https://doi.org/10.5194/amt-13-6193-2020, 2020
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Collecting particulate matter, or aerosols, onto filters to be analyzed offline is a widely used method to investigate the mass concentration and chemical composition of the aerosol, especially the inorganic portion. Here, we show that acidic aerosol (sulfuric acid) collected onto filters and then exposed to high ammonia mixing ratios (from human emissions) will lead to biases in the ammonium collected onto filters, and the uptake of ammonia is rapid (< 10 s), which impacts the filter data.
Melodie Lao, Leigh R. Crilley, Leyla Salehpoor, Teles C. Furlani, Ilann Bourgeois, J. Andrew Neuman, Andrew W. Rollins, Patrick R. Veres, Rebecca A. Washenfelder, Caroline C. Womack, Cora J. Young, and Trevor C. VandenBoer
Atmos. Meas. Tech., 13, 5873–5890, https://doi.org/10.5194/amt-13-5873-2020, https://doi.org/10.5194/amt-13-5873-2020, 2020
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Nitrous acid (HONO) is a key intermediate in the generation of oxidants and fate of nitrogen oxides in the atmosphere. High-purity calibration sources that produce stable atmospherically relevant levels under field conditions have not been made to date, reducing measurement accuracy. In this study a simple salt-coated tube humidified with water vapor is demonstrated to produce pure stable low levels of HONO, with modifications allowing the generation of higher amounts.
Ilann Bourgeois, Jeff Peischl, Chelsea R. Thompson, Kenneth C. Aikin, Teresa Campos, Hannah Clark, Róisín Commane, Bruce Daube, Glenn W. Diskin, James W. Elkins, Ru-Shan Gao, Audrey Gaudel, Eric J. Hintsa, Bryan J. Johnson, Rigel Kivi, Kathryn McKain, Fred L. Moore, David D. Parrish, Richard Querel, Eric Ray, Ricardo Sánchez, Colm Sweeney, David W. Tarasick, Anne M. Thompson, Valérie Thouret, Jacquelyn C. Witte, Steve C. Wofsy, and Thomas B. Ryerson
Atmos. Chem. Phys., 20, 10611–10635, https://doi.org/10.5194/acp-20-10611-2020, https://doi.org/10.5194/acp-20-10611-2020, 2020
Ifayoyinsola Ibikunle, Andreas Beyersdorf, Pedro Campuzano-Jost, Chelsea Corr, John D. Crounse, Jack Dibb, Glenn Diskin, Greg Huey, Jose-Luis Jimenez, Michelle J. Kim, Benjamin A. Nault, Eric Scheuer, Alex Teng, Paul O. Wennberg, Bruce Anderson, James Crawford, Rodney Weber, and Athanasios Nenes
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-501, https://doi.org/10.5194/acp-2020-501, 2020
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Analysis of observations over South Korea during the NASA/NIER
KORUS-AQ field campaign show that aerosol is fairly acidic (mean pH 2.43 ± 0.68). Aerosol formation is always sensitive to HNO3 levels, especially in highly polluted regions, while it is only exclusively sensitive to NH3 in some rural/remote regions. Nitrate levels accumulate because dry deposition velocity is low. HNO3 reductions achieved by NOx controls can be the most effective PM reduction strategy for all conditions observed.
Yunle Chen, Masayuki Takeuchi, Theodora Nah, Lu Xu, Manjula R. Canagaratna, Harald Stark, Karsten Baumann, Francesco Canonaco, André S. H. Prévôt, L. Gregory Huey, Rodney J. Weber, and Nga L. Ng
Atmos. Chem. Phys., 20, 8421–8440, https://doi.org/10.5194/acp-20-8421-2020, https://doi.org/10.5194/acp-20-8421-2020, 2020
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Two online mass spectrometry instruments, an aerosol mass spectrometer and a chemical ionization mass spectrometer equipped with a filter inlet for gases and aerosols, were deployed at Yorkville, GA, for a comprehensive characterization of organic aerosol. We observed notable secondary organic aerosol formation from isoprene and monoterpenes via different pathways during both day and night, and a series of highly oxidized acid-like compounds was found to be closely related to aged SOA.
Juan Manuel Rincón-Riveros, Maria Alejandra Rincón-Caro, Amy P. Sullivan, Juan Felipe Mendez-Espinosa, Luis Carlos Belalcazar, Miguel Quirama Aguilar, and Ricardo Morales Betancourt
Atmos. Chem. Phys., 20, 7459–7472, https://doi.org/10.5194/acp-20-7459-2020, https://doi.org/10.5194/acp-20-7459-2020, 2020
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Air pollution affects health for millions of people worldwide. This is particularly worrisome for citizens in emerging economies where air quality is often heavily deteriorated. We show how, every year, agricultural burns and forest fires in the grasslands of northern South America increase the concentration of harmful particles in the environment, further worsening air quality for nearly 60 million in this region, even when the fires occur hundreds of kilometers away from urban areas.
Pablo E. Saide, Meng Gao, Zifeng Lu, Daniel L. Goldberg, David G. Streets, Jung-Hun Woo, Andreas Beyersdorf, Chelsea A. Corr, Kenneth L. Thornhill, Bruce Anderson, Johnathan W. Hair, Amin R. Nehrir, Glenn S. Diskin, Jose L. Jimenez, Benjamin A. Nault, Pedro Campuzano-Jost, Jack Dibb, Eric Heim, Kara D. Lamb, Joshua P. Schwarz, Anne E. Perring, Jhoon Kim, Myungje Choi, Brent Holben, Gabriele Pfister, Alma Hodzic, Gregory R. Carmichael, Louisa Emmons, and James H. Crawford
Atmos. Chem. Phys., 20, 6455–6478, https://doi.org/10.5194/acp-20-6455-2020, https://doi.org/10.5194/acp-20-6455-2020, 2020
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Air quality forecasts over the Korean Peninsula captured aerosol optical depth but largely overpredicted surface PM during a Chinese haze transport event. Model deficiency was related to the calculation of optical properties. In order to improve it, aerosol size representation needs to be refined in the calculations, and the representation of aerosol properties, such as size distribution, chemical composition, refractive index, hygroscopicity parameter, and density, needs to be improved.
Dong Gao, Krystal J. Godri Pollitt, James A. Mulholland, Armistead G. Russell, and Rodney J. Weber
Atmos. Chem. Phys., 20, 5197–5210, https://doi.org/10.5194/acp-20-5197-2020, https://doi.org/10.5194/acp-20-5197-2020, 2020
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This study provides a direct intercomparison between two assays for quantifying oxidative potential (OP) of ambient particles: the synthetic respiratory-tract-lining fluid (RTLF) assay and the dithiothreitol (DTT) assay. The results suggest that the DTT assay and the ascorbic acid depletion in RTLF are associated with organic species, transition metal ions, and antagonistic interactions between species. The glutathione depletion in RTLF is strongly dependent on water-soluble copper.
Havala O. T. Pye, Athanasios Nenes, Becky Alexander, Andrew P. Ault, Mary C. Barth, Simon L. Clegg, Jeffrey L. Collett Jr., Kathleen M. Fahey, Christopher J. Hennigan, Hartmut Herrmann, Maria Kanakidou, James T. Kelly, I-Ting Ku, V. Faye McNeill, Nicole Riemer, Thomas Schaefer, Guoliang Shi, Andreas Tilgner, John T. Walker, Tao Wang, Rodney Weber, Jia Xing, Rahul A. Zaveri, and Andreas Zuend
Atmos. Chem. Phys., 20, 4809–4888, https://doi.org/10.5194/acp-20-4809-2020, https://doi.org/10.5194/acp-20-4809-2020, 2020
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Acid rain is recognized for its impacts on human health and ecosystems, and programs to mitigate these effects have had implications for atmospheric acidity. Historical measurements indicate that cloud and fog droplet acidity has changed in recent decades in response to controls on emissions from human activity, while the limited trend data for suspended particles indicate acidity may be relatively constant. This review synthesizes knowledge on the acidity of atmospheric particles and clouds.
Alma Hodzic, Pedro Campuzano-Jost, Huisheng Bian, Mian Chin, Peter R. Colarco, Douglas A. Day, Karl D. Froyd, Bernd Heinold, Duseong S. Jo, Joseph M. Katich, John K. Kodros, Benjamin A. Nault, Jeffrey R. Pierce, Eric Ray, Jacob Schacht, Gregory P. Schill, Jason C. Schroder, Joshua P. Schwarz, Donna T. Sueper, Ina Tegen, Simone Tilmes, Kostas Tsigaridis, Pengfei Yu, and Jose L. Jimenez
Atmos. Chem. Phys., 20, 4607–4635, https://doi.org/10.5194/acp-20-4607-2020, https://doi.org/10.5194/acp-20-4607-2020, 2020
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Organic aerosol (OA) is a key source of uncertainty in aerosol climate effects. We present the first pole-to-pole OA characterization during the NASA Atmospheric Tomography aircraft mission. OA has a strong seasonal and zonal variability, with the highest levels in summer and over fire-influenced regions and the lowest ones in the southern high latitudes. We show that global models predict the OA distribution well but not the relative contribution of OA emissions vs. chemical production.
Athanasios Nenes, Spyros N. Pandis, Rodney J. Weber, and Armistead Russell
Atmos. Chem. Phys., 20, 3249–3258, https://doi.org/10.5194/acp-20-3249-2020, https://doi.org/10.5194/acp-20-3249-2020, 2020
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We show that aerosol acidity (pH) and liquid water content naturally emerge as previously ignored parameters that drive particulate matter formation in the atmosphere, and its sensitivity to emissions of ammonia and nitric acid. The simple framework presented is easily applied to ambient measurements or model output, and it provides the
chemical regimeof PM sensitivity to ammonia and nitric acid availability.
Aoxing Zhang, Yuhang Wang, Yuzhong Zhang, Rodney J. Weber, Yongjia Song, Ziming Ke, and Yufei Zou
Atmos. Chem. Phys., 20, 1901–1920, https://doi.org/10.5194/acp-20-1901-2020, https://doi.org/10.5194/acp-20-1901-2020, 2020
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Black carbon (BC) and brown carbon (BrC) are light-absorbing carbonaceous aerosols. We developed a module to simulate the emissions, atmospheric processing and direct radiative effect of BrC in the Community Earth System Model (CESM). We found that globally BrC is a significant absorber and is more centered in the tropical free troposphere compared to BC. The contribution of BrC heating to the Hadley circulation and latitudinal expansion of the tropics is comparable to BC heating.
Michael A. Battaglia Jr., Rodney J. Weber, Athanasios Nenes, and Christopher J. Hennigan
Atmos. Chem. Phys., 19, 14607–14620, https://doi.org/10.5194/acp-19-14607-2019, https://doi.org/10.5194/acp-19-14607-2019, 2019
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The effects of water-soluble organic carbon (WSOC) on aerosol pH were characterized for aqueous-phase particles containing a mixture of inorganics and organics. The ISORROPIA-II and E-AIM models were used in conjunction with AIOMFAC to quantify the effect of organics on aerosol pH through (1) changes to the aerosol liquid water content and (2) changes to the hydrogen ion activity coefficient. The study included both organic acids and nonacids, at RH levels ranging from 70 to 90 %.
Jiajue Chai, David J. Miller, Eric Scheuer, Jack Dibb, Vanessa Selimovic, Robert Yokelson, Kyle J. Zarzana, Steven S. Brown, Abigail R. Koss, Carsten Warneke, and Meredith Hastings
Atmos. Meas. Tech., 12, 6303–6317, https://doi.org/10.5194/amt-12-6303-2019, https://doi.org/10.5194/amt-12-6303-2019, 2019
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Isotopic analysis offers a potential tool to distinguish between sources and interpret transformation pathways of atmospheric species. We applied recently developed techniques in our lab to characterize the isotopic composition of reactive nitrogen species (NOx, HONO, HNO3, pNO3-) in fresh biomass burning emissions. Intercomparison with other techniques confirms the suitability of our methods, allowing for future applications of our techniques in a variety of environments.
Karl D. Froyd, Daniel M. Murphy, Charles A. Brock, Pedro Campuzano-Jost, Jack E. Dibb, Jose-Luis Jimenez, Agnieszka Kupc, Ann M. Middlebrook, Gregory P. Schill, Kenneth L. Thornhill, Christina J. Williamson, James C. Wilson, and Luke D. Ziemba
Atmos. Meas. Tech., 12, 6209–6239, https://doi.org/10.5194/amt-12-6209-2019, https://doi.org/10.5194/amt-12-6209-2019, 2019
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Single-particle mass spectrometer (SPMS) instruments characterize the composition of individual aerosol particles in real time. We present a new method that combines SPMS composition with independently measured particle size distributions to determine absolute number, surface area, volume, and mass concentrations of mineral dust, biomass burning, sea salt, and other climate-relevant atmospheric particle types, with a fast time response applicable to aircraft sampling.
Peter J. Marinescu, Ezra J. T. Levin, Don Collins, Sonia M. Kreidenweis, and Susan C. van den Heever
Atmos. Chem. Phys., 19, 11985–12006, https://doi.org/10.5194/acp-19-11985-2019, https://doi.org/10.5194/acp-19-11985-2019, 2019
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We characterized and provided fits for the seasonal aerosol size distributions (7 nm–14 µm diameter) at a North American, long–term surface site (SGP), which can be applied to models. Key cycles on timescales of several hours to weeks were also assessed using power spectra for various aerosol size ranges. One key finding is the consistent presence of diurnal cycles in the smallest particles in each season, providing insights into the formation and roles of new particle formation at SGP.
Huisheng Bian, Karl Froyd, Daniel M. Murphy, Jack Dibb, Anton Darmenov, Mian Chin, Peter R. Colarco, Arlindo da Silva, Tom L. Kucsera, Gregory Schill, Hongbin Yu, Paul Bui, Maximilian Dollner, Bernadett Weinzierl, and Alexander Smirnov
Atmos. Chem. Phys., 19, 10773–10785, https://doi.org/10.5194/acp-19-10773-2019, https://doi.org/10.5194/acp-19-10773-2019, 2019
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We address the GEOS-GOCART sea salt simulations constrained by NASA EVS ATom measurements, as well as those by MODIS and the AERONET MAN. The study covers remote regions over the Pacific, Atlantic, and Southern oceans from near the surface to ~ 12 km altitude and covers both summer and winter seasons. Important sea salt fields, e.g., mass mixing ratio, vertical distribution, size distribution, and marine aerosol AOD, as well as their relationship to relative humidity and emissions, are examined.
Xin Chen, Dylan B. Millet, Hanwant B. Singh, Armin Wisthaler, Eric C. Apel, Elliot L. Atlas, Donald R. Blake, Ilann Bourgeois, Steven S. Brown, John D. Crounse, Joost A. de Gouw, Frank M. Flocke, Alan Fried, Brian G. Heikes, Rebecca S. Hornbrook, Tomas Mikoviny, Kyung-Eun Min, Markus Müller, J. Andrew Neuman, Daniel W. O'Sullivan, Jeff Peischl, Gabriele G. Pfister, Dirk Richter, James M. Roberts, Thomas B. Ryerson, Stephen R. Shertz, Chelsea R. Thompson, Victoria Treadaway, Patrick R. Veres, James Walega, Carsten Warneke, Rebecca A. Washenfelder, Petter Weibring, and Bin Yuan
Atmos. Chem. Phys., 19, 9097–9123, https://doi.org/10.5194/acp-19-9097-2019, https://doi.org/10.5194/acp-19-9097-2019, 2019
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Volatile organic compounds (VOCs) affect air quality and modify the lifetimes of other pollutants. We combine a high-resolution 3-D atmospheric model with an ensemble of aircraft observations to perform an integrated analysis of the VOC budget over North America. We find that biogenic emissions provide the main source of VOC reactivity even in most major cities. Our findings point to key gaps in current models related to oxygenated VOCs and to the distribution of VOCs in the free troposphere.
Charles A. Brock, Christina Williamson, Agnieszka Kupc, Karl D. Froyd, Frank Erdesz, Nicholas Wagner, Matthews Richardson, Joshua P. Schwarz, Ru-Shan Gao, Joseph M. Katich, Pedro Campuzano-Jost, Benjamin A. Nault, Jason C. Schroder, Jose L. Jimenez, Bernadett Weinzierl, Maximilian Dollner, ThaoPaul Bui, and Daniel M. Murphy
Atmos. Meas. Tech., 12, 3081–3099, https://doi.org/10.5194/amt-12-3081-2019, https://doi.org/10.5194/amt-12-3081-2019, 2019
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From 2016 to 2018 a NASA aircraft profiled the atmosphere from 180 m to ~12 km from the Arctic to the Antarctic over both the Pacific and Atlantic oceans. This program, ATom, sought to sample atmospheric chemical composition to compare with global climate models. We describe the how measurements of particulate matter were made during ATom, and show that the instrument performance was excellent. Data from this project can be used with confidence to evaluate models and compare with satellites.
Jenny P. S. Wong, Maria Tsagkaraki, Irini Tsiodra, Nikolaos Mihalopoulos, Kalliopi Violaki, Maria Kanakidou, Jean Sciare, Athanasios Nenes, and Rodney J. Weber
Atmos. Chem. Phys., 19, 7319–7334, https://doi.org/10.5194/acp-19-7319-2019, https://doi.org/10.5194/acp-19-7319-2019, 2019
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Biomass burning is a major source of light-absorbing organic species in atmospheric aerosols, and it can play an important role in climate and atmospheric chemistry. Through a combination of laboratory experiments and field observations, this work demonstrated that the light absorption properties of aged biomass burning organic aerosols are dominated by high-molecular-weight compounds. In addition, we found that total hydrated sugars may be a robust tracer for aged biomass burning aerosols.
Daniel M. Murphy, Karl D. Froyd, Huisheng Bian, Charles A. Brock, Jack E. Dibb, Joshua P. DiGangi, Glenn Diskin, Maximillian Dollner, Agnieszka Kupc, Eric M. Scheuer, Gregory P. Schill, Bernadett Weinzierl, Christina J. Williamson, and Pengfei Yu
Atmos. Chem. Phys., 19, 4093–4104, https://doi.org/10.5194/acp-19-4093-2019, https://doi.org/10.5194/acp-19-4093-2019, 2019
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We present the first data on the concentration of sea-salt aerosol throughout most of the depth of the troposphere and a wide range of latitudes. Sea-salt concentrations in the upper troposphere are very small. This puts stringent limits on how sea-salt aerosol affects halogen and nitric acid chemistry there. With a widely distributed source, sea-salt aerosol provides an excellent test of wet scavenging and vertical transport of aerosols in chemical transport models.
Nick Jordan, Connie Z. Ye, Satyaki Ghosh, Rebecca A. Washenfelder, Steven S. Brown, and Hans D. Osthoff
Atmos. Meas. Tech., 12, 1277–1293, https://doi.org/10.5194/amt-12-1277-2019, https://doi.org/10.5194/amt-12-1277-2019, 2019
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A new spectrometer to measure abundances of the atmospheric trace gases nitrogen dioxide and iodine is described. The spectrometer uses a light-emitting diode between 470 and 540 nm and two highly reflective mirrors to yield an effective absorption path of 6.3 km. We remeasured scattering cross sections of common atmospheric gases in the cyan region and present sample NO2 measurements that agreed with those made with a laser-based instrument.
Katherine B. Benedict, Yong Zhou, Barkley C. Sive, Anthony J. Prenni, Kristi A. Gebhart, Emily V. Fischer, Ashley Evanoski-Cole, Amy P. Sullivan, Sara Callahan, Bret A. Schichtel, Huiting Mao, Ying Zhou, and Jeffrey L. Collett Jr.
Atmos. Chem. Phys., 19, 499–521, https://doi.org/10.5194/acp-19-499-2019, https://doi.org/10.5194/acp-19-499-2019, 2019
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Rocky Mountain National Park experiences high ozone concentrations that can exceed the National Ambient Air Quality Standard. As part of the FRAPPÉ field campaign, a suite of volatile organic compounds were measured to characterize the sources of ozone precursors that contribute to high ozone in the park. These measurements indicate emissions from the Front Range in Colorado tied to oil and gas operations, urban areas, and the stratosphere contribute to episodes of elevated ozone.
Benjamin A. Nault, Pedro Campuzano-Jost, Douglas A. Day, Jason C. Schroder, Bruce Anderson, Andreas J. Beyersdorf, Donald R. Blake, William H. Brune, Yonghoon Choi, Chelsea A. Corr, Joost A. de Gouw, Jack Dibb, Joshua P. DiGangi, Glenn S. Diskin, Alan Fried, L. Gregory Huey, Michelle J. Kim, Christoph J. Knote, Kara D. Lamb, Taehyoung Lee, Taehyun Park, Sally E. Pusede, Eric Scheuer, Kenneth L. Thornhill, Jung-Hun Woo, and Jose L. Jimenez
Atmos. Chem. Phys., 18, 17769–17800, https://doi.org/10.5194/acp-18-17769-2018, https://doi.org/10.5194/acp-18-17769-2018, 2018
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Aerosol impacts visibility and human health in large cities. Sources of aerosols are still highly uncertain, especially for cities surrounded by numerous other cities. We use observations collected during the Korea–United States Air Quality study to determine sources of organic aerosol (OA). We find that secondary OA (SOA) is rapidly produced over Seoul, South Korea, and that the sources of the SOA originate from short-lived hydrocarbons, which originate from local emissions.
Hongyu Guo, Athanasios Nenes, and Rodney J. Weber
Atmos. Chem. Phys., 18, 17307–17323, https://doi.org/10.5194/acp-18-17307-2018, https://doi.org/10.5194/acp-18-17307-2018, 2018
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Overprediction of fine-particle ammonium-sulfate molar ratios (R) by thermodynamic models is suggested as evidence for organic aerosol limiting the condensation of ammonia onto particles, with significant impacts on aerosol chemistry. We find that the effects of small amounts of salt and dust, combined with measurement artifacts, explain the discrepancy in R. These results are highly insensitive to mixing state. This means that aerosol predictions are much more robust than thought before.
Kaitlyn J. Suski, Tom C. J. Hill, Ezra J. T. Levin, Anna Miller, Paul J. DeMott, and Sonia M. Kreidenweis
Atmos. Chem. Phys., 18, 13755–13771, https://doi.org/10.5194/acp-18-13755-2018, https://doi.org/10.5194/acp-18-13755-2018, 2018
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The harvesting of crops emits large amounts of particles into the air. These particles can form and interact with clouds to alter cloud properties and precipitation, but the magnitude of these effects is unknown. This study looked at the ability of harvest particles to form ice in clouds by sampling with an ice nucleation chamber downwind of fields being harvested. Some crops emitted large amounts of ice-nucleating particles, and harvest emissions are mixtures of organics, soil, and minerals.
Theodora Nah, Yi Ji, David J. Tanner, Hongyu Guo, Amy P. Sullivan, Nga Lee Ng, Rodney J. Weber, and L. Gregory Huey
Atmos. Meas. Tech., 11, 5087–5104, https://doi.org/10.5194/amt-11-5087-2018, https://doi.org/10.5194/amt-11-5087-2018, 2018
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The sources and atmospheric chemistry of gas-phase organic acids are currently poorly understood, due in part to the limited range of measurement techniques available. We evaluated the use of SF6− as a sensitive and selective chemical ionization reagent ion for real-time measurements of gas-phase organic acids at a rural site in Yorkville, Georgia. We found that ambient concentrations of organic acids ranged from a few ppt to several ppb, and are dependent on ambient temperature.
Petros Vasilakos, Armistead Russell, Rodney Weber, and Athanasios Nenes
Atmos. Chem. Phys., 18, 12765–12775, https://doi.org/10.5194/acp-18-12765-2018, https://doi.org/10.5194/acp-18-12765-2018, 2018
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In this work, we investigated the role of emission reductions on aerosol acidity and particulate nitrate. We found that models exhibit positive biases in pH predictions, attributed to very high levels of crustal elements (Mg, Ca, K) in model simulations, which in turn led to an increasing aerosol pH trend over the past decade and allowed nitrate to become an important component of aerosol, which is inconsistent with the measurements, highlighting the importance of accurate pH prediction.
Hongyu Guo, Rene Otjes, Patrick Schlag, Astrid Kiendler-Scharr, Athanasios Nenes, and Rodney J. Weber
Atmos. Chem. Phys., 18, 12241–12256, https://doi.org/10.5194/acp-18-12241-2018, https://doi.org/10.5194/acp-18-12241-2018, 2018
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Reduction in ammonia has been proposed as a way to lower fine particle mass and improve air quality, but gas-phase ammonia is linked to agricultural productivity. We assess the feasibility of ammonia control at a variety of locations through an aerosol thermodynamic analysis. We show that aerosol response to ammonia control is highly nonlinear and only becomes effective when ambient particle pH drops below approximately 3. Particle pH is a relevant aerosol air quality parameter.
Theodora Nah, Hongyu Guo, Amy P. Sullivan, Yunle Chen, David J. Tanner, Athanasios Nenes, Armistead Russell, Nga Lee Ng, L. Gregory Huey, and Rodney J. Weber
Atmos. Chem. Phys., 18, 11471–11491, https://doi.org/10.5194/acp-18-11471-2018, https://doi.org/10.5194/acp-18-11471-2018, 2018
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We present measurements from a field study conducted in an agriculturally intensive region in the southeastern US during the fall of 2016 to investigate how NH3 affects particle acidity and SOA formation via gas–particle partitioning of semi-volatile organic acids. For this study, higher NH3 concentrations relative to what has been measured in the region in previous studies had minor effects on PM1 organic acids and their influence on the overall organic aerosol and PM1 mass concentrations.
Roya Bahreini, Ravan Ahmadov, Stu A. McKeen, Kennedy T. Vu, Justin H. Dingle, Eric C. Apel, Donald R. Blake, Nicola Blake, Teresa L. Campos, Chris Cantrell, Frank Flocke, Alan Fried, Jessica B. Gilman, Alan J. Hills, Rebecca S. Hornbrook, Greg Huey, Lisa Kaser, Brian M. Lerner, Roy L. Mauldin, Simone Meinardi, Denise D. Montzka, Dirk Richter, Jason R. Schroeder, Meghan Stell, David Tanner, James Walega, Peter Weibring, and Andrew Weinheimer
Atmos. Chem. Phys., 18, 8293–8312, https://doi.org/10.5194/acp-18-8293-2018, https://doi.org/10.5194/acp-18-8293-2018, 2018
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We measured organic aerosol (OA) and relevant trace gases during FRAPPÉ in the Colorado Front Range, with the goal of characterizing summertime OA formation. Our results indicate a significant production of secondary OA (SOA) in this region. About 2 μg m−3 of OA was present at background CO levels, suggesting contribution of non-combustion sources to SOA. Contribution of oil- and gas-related activities to anthropogenic SOA was modeled to be ~38 %. Biogenic SOA contributed to >40 % of OA.
Chelsea E. Stockwell, Agnieszka Kupc, Bartłomiej Witkowski, Ranajit K. Talukdar, Yong Liu, Vanessa Selimovic, Kyle J. Zarzana, Kanako Sekimoto, Carsten Warneke, Rebecca A. Washenfelder, Robert J. Yokelson, Ann M. Middlebrook, and James M. Roberts
Atmos. Meas. Tech., 11, 2749–2768, https://doi.org/10.5194/amt-11-2749-2018, https://doi.org/10.5194/amt-11-2749-2018, 2018
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This work investigates the total conversion of particle-bound nitrogen and organic carbon across platinum and molybdenum catalysts followed by NO–O3 chemiluminescence and nondispersive infrared CO2 detection. We show the instrument is an accurate particle mass measurement method and demonstrate its ability to calibrate particle mass measurement instrumentation through comparisons with a calibrated particle-into-liquid sampler coupled to an electrospray ionization source of a mass spectrometer.
Jingyi Li, Jingqiu Mao, Arlene M. Fiore, Ronald C. Cohen, John D. Crounse, Alex P. Teng, Paul O. Wennberg, Ben H. Lee, Felipe D. Lopez-Hilfiker, Joel A. Thornton, Jeff Peischl, Ilana B. Pollack, Thomas B. Ryerson, Patrick Veres, James M. Roberts, J. Andrew Neuman, John B. Nowak, Glenn M. Wolfe, Thomas F. Hanisco, Alan Fried, Hanwant B. Singh, Jack Dibb, Fabien Paulot, and Larry W. Horowitz
Atmos. Chem. Phys., 18, 2341–2361, https://doi.org/10.5194/acp-18-2341-2018, https://doi.org/10.5194/acp-18-2341-2018, 2018
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We present the first comprehensive model evaluation of summertime reactive oxidized nitrogen using a high-resolution chemistry–climate model with up-to-date isoprene oxidation chemistry, along with a series of observations from aircraft campaigns and ground measurement networks from 2004 to 2013 over the Southeast US. We investigate the impact of NOx emission reductions on changes in reactive nitrogen speciation and export efficiency as well as ozone in the past and future decade.
Katherine M. Manfred, Rebecca A. Washenfelder, Nicholas L. Wagner, Gabriela Adler, Frank Erdesz, Caroline C. Womack, Kara D. Lamb, Joshua P. Schwarz, Alessandro Franchin, Vanessa Selimovic, Robert J. Yokelson, and Daniel M. Murphy
Atmos. Chem. Phys., 18, 1879–1894, https://doi.org/10.5194/acp-18-1879-2018, https://doi.org/10.5194/acp-18-1879-2018, 2018
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In this study, we use a new laser imaging nephelometer to measure the bulk aerosol scattering phase function for biomass burning aerosol from controlled fires. By comparing measurements to models for spherical and fractal particles, we demonstrate that the dominant morphology varies by fuel type. This instrument has unique capabilities to directly measure how morphology affects optical properties, and can be used in the future for important validations of remote sensing retrievals.
Xuan Wang, Colette L. Heald, Jiumeng Liu, Rodney J. Weber, Pedro Campuzano-Jost, Jose L. Jimenez, Joshua P. Schwarz, and Anne E. Perring
Atmos. Chem. Phys., 18, 635–653, https://doi.org/10.5194/acp-18-635-2018, https://doi.org/10.5194/acp-18-635-2018, 2018
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Brown carbon (BrC) contributes significantly to uncertainty in estimating the global direct radiative effect (DRE) of aerosols. We develop a global model simulation of BrC and test it against BrC absorption measurements from two aircraft campaigns in the continental United States. We suggest that BrC DRE has been overestimated previously due to the lack of observational constraints from direct measurements and omission of the effects of photochemical whitening.
Theodore K. Koenig, Rainer Volkamer, Sunil Baidar, Barbara Dix, Siyuan Wang, Daniel C. Anderson, Ross J. Salawitch, Pamela A. Wales, Carlos A. Cuevas, Rafael P. Fernandez, Alfonso Saiz-Lopez, Mathew J. Evans, Tomás Sherwen, Daniel J. Jacob, Johan Schmidt, Douglas Kinnison, Jean-François Lamarque, Eric C. Apel, James C. Bresch, Teresa Campos, Frank M. Flocke, Samuel R. Hall, Shawn B. Honomichl, Rebecca Hornbrook, Jørgen B. Jensen, Richard Lueb, Denise D. Montzka, Laura L. Pan, J. Michael Reeves, Sue M. Schauffler, Kirk Ullmann, Andrew J. Weinheimer, Elliot L. Atlas, Valeria Donets, Maria A. Navarro, Daniel Riemer, Nicola J. Blake, Dexian Chen, L. Gregory Huey, David J. Tanner, Thomas F. Hanisco, and Glenn M. Wolfe
Atmos. Chem. Phys., 17, 15245–15270, https://doi.org/10.5194/acp-17-15245-2017, https://doi.org/10.5194/acp-17-15245-2017, 2017
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Tropospheric inorganic bromine (BrO and Bry) shows a C-shaped profile over the tropical western Pacific Ocean, and supports previous speculation that marine convection is a source for inorganic bromine from sea salt to the upper troposphere. The Bry profile in the tropical tropopause layer (TTL) is complex, suggesting that the total Bry budget in the TTL is not closed without considering aerosol bromide. The implications for atmospheric composition and bromine sources are discussed.
Carlena J. Ebben, Tamara L. Sparks, Paul J. Wooldridge, Teresa L. Campos, Christopher A. Cantrell, Roy L. Mauldin, Andrew J. Weinheimer, and Ronald C. Cohen
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2017-671, https://doi.org/10.5194/acp-2017-671, 2017
Revised manuscript has not been submitted
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We use observations from the FRAPPÉ campaign to examine the evolution of reactive nitrogen as it is transported from Denver. We provide estimates for dilution rates, chemical lifetimes, and deposition rates. While dilution is the primary loss process in the immediate outflow from Denver, chemically, a majority of NOx is converted to HNO3 and is subsequently deposited. Understanding the evolution of reactive nitrogen informs how urban emissions affect air quality in the surrounding regions.
Dong Gao, Ting Fang, Vishal Verma, Linghan Zeng, and Rodney J. Weber
Atmos. Meas. Tech., 10, 2821–2835, https://doi.org/10.5194/amt-10-2821-2017, https://doi.org/10.5194/amt-10-2821-2017, 2017
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This work compares three methods to determine the optimal approach for quantifying the total oxidative potential (OP) of fine particles collected with filters using the dithiothreitol (DTT) assay. An automated system has been developed to facilitate the total OP measurements for use in generation of large data sets needed for epidemiology studies. The results from this study show that the water-insoluble components contribute to PM2.5 OP and the related DTT-active species are largely secondary.
Christopher Chan Miller, Daniel J. Jacob, Eloise A. Marais, Karen Yu, Katherine R. Travis, Patrick S. Kim, Jenny A. Fisher, Lei Zhu, Glenn M. Wolfe, Thomas F. Hanisco, Frank N. Keutsch, Jennifer Kaiser, Kyung-Eun Min, Steven S. Brown, Rebecca A. Washenfelder, Gonzalo González Abad, and Kelly Chance
Atmos. Chem. Phys., 17, 8725–8738, https://doi.org/10.5194/acp-17-8725-2017, https://doi.org/10.5194/acp-17-8725-2017, 2017
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The use of satellite glyoxal observations for estimating isoprene emissions has been limited by knowledge of the glyoxal yield from isoprene. We use SENEX aircraft observations over the southeast US to evaluate glyoxal yields from isoprene in a 3-D atmospheric model. The SENEX observations support a pathway for glyoxal formation in pristine regions that we propose here, which may have implications for improving isoprene emissions estimates from upcoming high-resolution geostationary satellites.
Hongyu Guo, Jiumeng Liu, Karl D. Froyd, James M. Roberts, Patrick R. Veres, Patrick L. Hayes, Jose L. Jimenez, Athanasios Nenes, and Rodney J. Weber
Atmos. Chem. Phys., 17, 5703–5719, https://doi.org/10.5194/acp-17-5703-2017, https://doi.org/10.5194/acp-17-5703-2017, 2017
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Fine particle pH is linked to many environmental impacts by affecting particle concentration and composition. Predicted Pasadena, CA (CalNex campaign), PM1 pH is 1.9 and PM2.5 pH 2.7, the latter higher due to sea salts. The model predicted gas–particle partitionings of HNO3–NO3−, NH3–NH4+, and HCl–Cl− are in good agreement, verifying the model predictions. A summary of contrasting locations in the US and eastern Mediterranean shows fine particles are generally highly acidic, with pH below 3.
Wing Y. Tuet, Yunle Chen, Lu Xu, Shierly Fok, Dong Gao, Rodney J. Weber, and Nga L. Ng
Atmos. Chem. Phys., 17, 839–853, https://doi.org/10.5194/acp-17-839-2017, https://doi.org/10.5194/acp-17-839-2017, 2017
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Secondary organic aerosols (SOA) comprise a significant fraction of particulate matter (PM) and may have health implications. The water-soluble oxidative potentials of various SOA systems were determined using dithiothreitol consumption. Results from this study demonstrate that precursor identity was more influential than reaction condition in determining SOA oxidative potential and highlight a need to consider SOA contributions from anthropogenic hydrocarbons to PM-induced health effects.
Havala O. T. Pye, Benjamin N. Murphy, Lu Xu, Nga L. Ng, Annmarie G. Carlton, Hongyu Guo, Rodney Weber, Petros Vasilakos, K. Wyat Appel, Sri Hapsari Budisulistiorini, Jason D. Surratt, Athanasios Nenes, Weiwei Hu, Jose L. Jimenez, Gabriel Isaacman-VanWertz, Pawel K. Misztal, and Allen H. Goldstein
Atmos. Chem. Phys., 17, 343–369, https://doi.org/10.5194/acp-17-343-2017, https://doi.org/10.5194/acp-17-343-2017, 2017
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We use a chemical transport model to examine how organic compounds in the atmosphere interact with water present in particles. Organic compounds themselves lead to water uptake, and organic compounds interact with water associated with inorganic compounds in the rural southeast atmosphere. Including interactions of organic compounds with water requires a treatment of nonideality to more accurately represent aerosol observations during the Southern Oxidant and Aerosol Study (SOAS) 2013.
Katherine R. Travis, Daniel J. Jacob, Jenny A. Fisher, Patrick S. Kim, Eloise A. Marais, Lei Zhu, Karen Yu, Christopher C. Miller, Robert M. Yantosca, Melissa P. Sulprizio, Anne M. Thompson, Paul O. Wennberg, John D. Crounse, Jason M. St. Clair, Ronald C. Cohen, Joshua L. Laughner, Jack E. Dibb, Samuel R. Hall, Kirk Ullmann, Glenn M. Wolfe, Illana B. Pollack, Jeff Peischl, Jonathan A. Neuman, and Xianliang Zhou
Atmos. Chem. Phys., 16, 13561–13577, https://doi.org/10.5194/acp-16-13561-2016, https://doi.org/10.5194/acp-16-13561-2016, 2016
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Ground-level ozone pollution in the Southeast US involves complex chemistry driven by anthropogenic emissions of nitrogen oxides (NOx) and biogenic emissions of isoprene. We find that US NOx emissions are overestimated nationally by as much as 50 % and that reducing model emissions by this amount results in good agreement with SEAC4RS aircraft measurements in August and September 2013. Observations of nitrate wet deposition fluxes and satellite NO2 columns further support this result.
Amelia F. Longo, David J. Vine, Laura E. King, Michelle Oakes, Rodney J. Weber, Lewis Gregory Huey, Armistead G. Russell, and Ellery D. Ingall
Atmos. Chem. Phys., 16, 13389–13398, https://doi.org/10.5194/acp-16-13389-2016, https://doi.org/10.5194/acp-16-13389-2016, 2016
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New synchrotron-based techniques were applied to characterize the oxidation state and composition of sulfur in ambient aerosol and emission sources. Individual particles were found to contain surprisingly high levels of elemental sulfur, a form of sulfur found in only one of the emission sources analyzed. We also show metal sulfates as a key component of urban aerosols. These metal sulfate phases are highly soluble and are indicative of acidic processes transforming metals in the environment.
Kennedy T. Vu, Justin H. Dingle, Roya Bahreini, Patrick J. Reddy, Eric C. Apel, Teresa L. Campos, Joshua P. DiGangi, Glenn S. Diskin, Alan Fried, Scott C. Herndon, Alan J. Hills, Rebecca S. Hornbrook, Greg Huey, Lisa Kaser, Denise D. Montzka, John B. Nowak, Sally E. Pusede, Dirk Richter, Joseph R. Roscioli, Glen W. Sachse, Stephen Shertz, Meghan Stell, David Tanner, Geoffrey S. Tyndall, James Walega, Peter Weibring, Andrew J. Weinheimer, Gabriele Pfister, and Frank Flocke
Atmos. Chem. Phys., 16, 12039–12058, https://doi.org/10.5194/acp-16-12039-2016, https://doi.org/10.5194/acp-16-12039-2016, 2016
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In this manuscript, we report on airborne measurements of non-refractory composition and optical extinction along with relevant trace gases during a unique surface mesoscale circulation event, namely the Denver Cyclone, in Colorado, USA, during in July–August 2014. The focus of this paper is to investigate how meteorological conditions associated with the Denver Cyclone impacted air quality of the Colorado Front Range.
Justin H. Dingle, Kennedy Vu, Roya Bahreini, Eric C. Apel, Teresa L. Campos, Frank Flocke, Alan Fried, Scott Herndon, Alan J. Hills, Rebecca S. Hornbrook, Greg Huey, Lisa Kaser, Denise D. Montzka, John B. Nowak, Mike Reeves, Dirk Richter, Joseph R. Roscioli, Stephen Shertz, Meghan Stell, David Tanner, Geoff Tyndall, James Walega, Petter Weibring, and Andrew Weinheimer
Atmos. Chem. Phys., 16, 11207–11217, https://doi.org/10.5194/acp-16-11207-2016, https://doi.org/10.5194/acp-16-11207-2016, 2016
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The focus of this paper was to use gas-phase tracers and aerosol composition to characterize the influence of the different sources on optical extinction (RH = 22 %) and summertime visibility in the Colorado Front Range. Our analysis indicates that aerosol nitrate contributed significantly to optical extinction in agriculturally influenced air masses, while in other plumes, organics could explain most of the observed variability in optical extinction.
Matthew J. Alvarado, Chantelle R. Lonsdale, Helen L. Macintyre, Huisheng Bian, Mian Chin, David A. Ridley, Colette L. Heald, Kenneth L. Thornhill, Bruce E. Anderson, Michael J. Cubison, Jose L. Jimenez, Yutaka Kondo, Lokesh K. Sahu, Jack E. Dibb, and Chien Wang
Atmos. Chem. Phys., 16, 9435–9455, https://doi.org/10.5194/acp-16-9435-2016, https://doi.org/10.5194/acp-16-9435-2016, 2016
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Understanding the scattering and absorption of light by aerosols is necessary for understanding air quality and climate change. We used data from the 2008 ARCTAS campaign to evaluate aerosol optical property models using a closure methodology that separates errors in these models from other errors in aerosol emissions, chemistry, or transport. We find that the models on average perform reasonably well, and make suggestions for how remaining biases could be reduced.
Carsten Warneke, Michael Trainer, Joost A. de Gouw, David D. Parrish, David W. Fahey, A. R. Ravishankara, Ann M. Middlebrook, Charles A. Brock, James M. Roberts, Steven S. Brown, Jonathan A. Neuman, Brian M. Lerner, Daniel Lack, Daniel Law, Gerhard Hübler, Iliana Pollack, Steven Sjostedt, Thomas B. Ryerson, Jessica B. Gilman, Jin Liao, John Holloway, Jeff Peischl, John B. Nowak, Kenneth C. Aikin, Kyung-Eun Min, Rebecca A. Washenfelder, Martin G. Graus, Mathew Richardson, Milos Z. Markovic, Nick L. Wagner, André Welti, Patrick R. Veres, Peter Edwards, Joshua P. Schwarz, Timothy Gordon, William P. Dube, Stuart A. McKeen, Jerome Brioude, Ravan Ahmadov, Aikaterini Bougiatioti, Jack J. Lin, Athanasios Nenes, Glenn M. Wolfe, Thomas F. Hanisco, Ben H. Lee, Felipe D. Lopez-Hilfiker, Joel A. Thornton, Frank N. Keutsch, Jennifer Kaiser, Jingqiu Mao, and Courtney D. Hatch
Atmos. Meas. Tech., 9, 3063–3093, https://doi.org/10.5194/amt-9-3063-2016, https://doi.org/10.5194/amt-9-3063-2016, 2016
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In this paper we describe the experimental approach, the science goals and early results of the NOAA SENEX campaign, which was focused on studying the interactions between biogenic and anthropogenic emissions to form secondary pollutants.
During SENEX, the NOAA WP-3D aircraft conducted 20 research flights between 27 May and 10 July 2013 based out of Smyrna, TN. The SENEX flights included day- and nighttime flights in the Southeast as well as flights over areas with intense shale gas extraction.
Amy P. Sullivan, Natasha Hodas, Barbara J. Turpin, Kate Skog, Frank N. Keutsch, Stefania Gilardoni, Marco Paglione, Matteo Rinaldi, Stefano Decesari, Maria Cristina Facchini, Laurent Poulain, Hartmut Herrmann, Alfred Wiedensohler, Eiko Nemitz, Marsailidh M. Twigg, and Jeffrey L. Collett Jr.
Atmos. Chem. Phys., 16, 8095–8108, https://doi.org/10.5194/acp-16-8095-2016, https://doi.org/10.5194/acp-16-8095-2016, 2016
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This paper presents the results from our measurements and approach for the investigation of aqueous secondary organic aerosol (aqSOA) formation in the ambient atmosphere. When local aqSOA formation was observed, a correlation of water-soluble organic carbon with organic aerosol, aerosol liquid water, relative humidity, and aerosol nitrate was found. Key factors of local aqSOA production include air mass stagnation, formation of local nitrate overnight, and significant amounts of ammonia.
Charles A. Brock, Nicholas L. Wagner, Bruce E. Anderson, Alexis R. Attwood, Andreas Beyersdorf, Pedro Campuzano-Jost, Annmarie G. Carlton, Douglas A. Day, Glenn S. Diskin, Timothy D. Gordon, Jose L. Jimenez, Daniel A. Lack, Jin Liao, Milos Z. Markovic, Ann M. Middlebrook, Nga L. Ng, Anne E. Perring, Matthews S. Richardson, Joshua P. Schwarz, Rebecca A. Washenfelder, Andre Welti, Lu Xu, Luke D. Ziemba, and Daniel M. Murphy
Atmos. Chem. Phys., 16, 4987–5007, https://doi.org/10.5194/acp-16-4987-2016, https://doi.org/10.5194/acp-16-4987-2016, 2016
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Microscopic pollution particles make the atmosphere look hazy and also cool the earth by sending sunlight back to space. When the air is moist, these particles swell with water and scatter even more sunlight. We showed that particles formed from organic material – which dominates particulate pollution in the southeastern U.S. – does not take up water very effectively, toward the low end of most previous studies. We also found a better way to mathematically describe this swelling process.
Weruka Rattanavaraha, Kevin Chu, Sri Hapsari Budisulistiorini, Matthieu Riva, Ying-Hsuan Lin, Eric S. Edgerton, Karsten Baumann, Stephanie L. Shaw, Hongyu Guo, Laura King, Rodney J. Weber, Miranda E. Neff, Elizabeth A. Stone, John H. Offenberg, Zhenfa Zhang, Avram Gold, and Jason D. Surratt
Atmos. Chem. Phys., 16, 4897–4914, https://doi.org/10.5194/acp-16-4897-2016, https://doi.org/10.5194/acp-16-4897-2016, 2016
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The mechanisms by which specific anthropogenic pollutants enhance isoprene SOA in ambient PM2.5 remain unclear. As one aspect of an investigation to examine how anthropogenic pollutants influence isoprene-derived SOA formation, high-volume PM2.5 filter samples were collected from Birmingham, AL, during the 2013 Southern Oxidant and Aerosol Study (SOAS). Isoprene SOA tracers were measured from these samples and compared to gas and aerosol data collected from the SEARCH network.
Aikaterini Bougiatioti, Panayiota Nikolaou, Iasonas Stavroulas, Giorgos Kouvarakis, Rodney Weber, Athanasios Nenes, Maria Kanakidou, and Nikolaos Mihalopoulos
Atmos. Chem. Phys., 16, 4579–4591, https://doi.org/10.5194/acp-16-4579-2016, https://doi.org/10.5194/acp-16-4579-2016, 2016
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Atmospheric aerosols and relevant parameters were measured in the eastern Mediterranean during summer and fall 2012. Submicron aerosol water can contribute up to 33 % of total mass, and 27.5 % of this can be associated with organics. Using these data, the pH of the submicron aerosols was calculated to be highly acidic, varying from 0.5 to 2.8 and independently of air masses origin. Such pH values could increase nutrient availability and thus sea water productivity of the Mediterranean Sea.
Karen Yu, Daniel J. Jacob, Jenny A. Fisher, Patrick S. Kim, Eloise A. Marais, Christopher C. Miller, Katherine R. Travis, Lei Zhu, Robert M. Yantosca, Melissa P. Sulprizio, Ron C. Cohen, Jack E. Dibb, Alan Fried, Tomas Mikoviny, Thomas B. Ryerson, Paul O. Wennberg, and Armin Wisthaler
Atmos. Chem. Phys., 16, 4369–4378, https://doi.org/10.5194/acp-16-4369-2016, https://doi.org/10.5194/acp-16-4369-2016, 2016
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Increasing the spatial resolution of a chemical transport model may improve simulations but can be computationally expensive. Using observations from the SEAC4RS aircraft campaign, we find that at higher spatial resolutions, models are better able to simulate the chemical pathways of ozone precursors, but the overall effect on regional mean concentrations is small. This implies that for continental boundary layer applications, coarse resolution models are adequate.
Ting Fang, Vishal Verma, Josephine T. Bates, Joseph Abrams, Mitchel Klein, Matthew J. Strickland, Stefanie E. Sarnat, Howard H. Chang, James A. Mulholland, Paige E. Tolbert, Armistead G. Russell, and Rodney J. Weber
Atmos. Chem. Phys., 16, 3865–3879, https://doi.org/10.5194/acp-16-3865-2016, https://doi.org/10.5194/acp-16-3865-2016, 2016
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Ascorbic acid (AA) and Dithiothreitol (DTT) assay measures of water-soluble PM2.5 oxidative potential (OP) are compared in terms of spatiotemporal trends, chemical selectivity, sources, and health impacts based on an epidemiological study with backcast estimated OP. Both assays point to metals from brake/tire wear, but only the DTT assay also identifies organics from combustion. DTT is associated with emergency department visits for asthma/wheeze and congestive heart failure, whereas AA is not.
K.-E. Min, R. A. Washenfelder, W. P. Dubé, A. O. Langford, P. M. Edwards, K. J. Zarzana, J. Stutz, K. Lu, F. Rohrer, Y. Zhang, and S. S. Brown
Atmos. Meas. Tech., 9, 423–440, https://doi.org/10.5194/amt-9-423-2016, https://doi.org/10.5194/amt-9-423-2016, 2016
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We have developed a two-channel broadband cavity enhanced absorption spectrometer for field measurements of glyoxal, methylglyoxal, nitrous acid, nitrogen dioxide, and water. We have successfully deployed this instrument during two aircraft and two ground-based field campaigns. The demonstrated precision (2σ) for retrievals of CHOCHO, HONO, and NO2 are 34, 350, and 80 parts per trillion (pptv) in 5 s, with accuracy of 5.8, 9.0 and 5.0 %.
V. Shah, L. Jaeglé, L. E. Gratz, J. L. Ambrose, D. A. Jaffe, N. E. Selin, S. Song, T. L. Campos, F. M. Flocke, M. Reeves, D. Stechman, M. Stell, J. Festa, J. Stutz, A. J. Weinheimer, D. J. Knapp, D. D. Montzka, G. S. Tyndall, E. C. Apel, R. S. Hornbrook, A. J. Hills, D. D. Riemer, N. J. Blake, C. A. Cantrell, and R. L. Mauldin III
Atmos. Chem. Phys., 16, 1511–1530, https://doi.org/10.5194/acp-16-1511-2016, https://doi.org/10.5194/acp-16-1511-2016, 2016
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We present airborne observations of mercury over the southeastern USA during summer. Higher concentrations of oxidized mercury were observed in clean, dry air masses descending in the subtropical anti-cyclones. We used an atmospheric model to simulate the chemistry and transport of mercury. We found reasonable agreement with the observations when the modeled oxidation of elemental mercury was increased, suggesting fast cycling between elemental and oxidized mercury.
A. J. Prenni, D. E. Day, A. R. Evanoski-Cole, B. C. Sive, A. Hecobian, Y. Zhou, K. A. Gebhart, J. L. Hand, A. P. Sullivan, Y. Li, M. I. Schurman, Y. Desyaterik, W. C. Malm, J. L. Collett Jr., and B. A. Schichtel
Atmos. Chem. Phys., 16, 1401–1416, https://doi.org/10.5194/acp-16-1401-2016, https://doi.org/10.5194/acp-16-1401-2016, 2016
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The Bakken formation contains billions of barrels of oil and gas trapped in rock and shale. Horizontal drilling and hydraulic fracturing methods have allowed for extraction of these resources, leading to exponential growth of oil production in the region. Along with this development has come an increase in associated emissions to the atmosphere. This paper describes a field study (BAQS) aimed at better understanding the impacts of these emissions on air quality in nearby federal lands.
T. Chubb, Y. Huang, J. Jensen, T. Campos, S. Siems, and M. Manton
Atmos. Chem. Phys., 16, 971–987, https://doi.org/10.5194/acp-16-971-2016, https://doi.org/10.5194/acp-16-971-2016, 2016
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The remote Southern Ocean is known to be one of the most pristine environments on the planet, but we found that cloud droplet and aerosol concentrations during one research flight in June 2009 were higher than expected. We were unable to attribute this to continental aerosol sources, and we hypothesize that strong winds resulted in local aerosol production in the form of sea salt. This has several consequences for climate modelling and cloud physics research.
R. A. Washenfelder, A. R. Attwood, J. M. Flores, K. J. Zarzana, Y. Rudich, and S. S. Brown
Atmos. Meas. Tech., 9, 41–52, https://doi.org/10.5194/amt-9-41-2016, https://doi.org/10.5194/amt-9-41-2016, 2016
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Formaldehyde is the most abundant aldehyde in the atmosphere and plays an important role in photochemistry. Broadband cavity-enhanced absorption spectroscopy uses a high finesse cavity to obtain effective path lengths of kilometers. We use a diode-pumped plasma lamp and custom cavity mirrors to extend this technique further into the ultraviolet spectral region, and we achieve detection limits of hundreds of parts per trillion in 1 min for formaldehyde and nitrogen dioxide.
C. E. Jordan, B. E. Anderson, A. J. Beyersdorf, C. A. Corr, J. E. Dibb, M. E. Greenslade, R. F. Martin, R. H. Moore, E. Scheuer, M. A. Shook, K. L. Thornhill, D. Troop, E. L. Winstead, and L. D. Ziemba
Atmos. Meas. Tech., 8, 4755–4771, https://doi.org/10.5194/amt-8-4755-2015, https://doi.org/10.5194/amt-8-4755-2015, 2015
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We describe a new instrument developed to observe ambient atmospheric aerosol extinction spectra from 300 to 700nm. Laboratory tests were performed to demonstrate that the instrument compares well with theoretical calculations over that spectral range, as well as with commercially available instrumentation measuring aerosol extinction at three visible wavelengths. The unique spectral data will be used to explore linkages between ambient aerosol optical properties, chemistry, and microphysics.
T. Fang, H. Guo, V. Verma, R. E. Peltier, and R. J. Weber
Atmos. Chem. Phys., 15, 11667–11682, https://doi.org/10.5194/acp-15-11667-2015, https://doi.org/10.5194/acp-15-11667-2015, 2015
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This work presented a new method of quantifying water-soluble elements in PM2.5 aqueous extracts (N~500) with an X-ray fluorescence analyzer. The results indicate that water-soluble elements had marked spatial and temporal patterns. Four sources were resolved: brake/tire wear, biomass burning, secondary formation, and mineral dust. The findings have informed studies on aerosol oxidative potential and provided insights into the health effects of water-soluble metals, especially Cu, Fe, Mn and Zn.
K. M. Cerully, A. Bougiatioti, J. R. Hite Jr., H. Guo, L. Xu, N. L. Ng, R. Weber, and A. Nenes
Atmos. Chem. Phys., 15, 8679–8694, https://doi.org/10.5194/acp-15-8679-2015, https://doi.org/10.5194/acp-15-8679-2015, 2015
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The hygroscopicity of SE US aerosol is mostly water-soluble, with a hygroscopicity that is insensitive to partial volatilization in a thermodenuder.
The most and least oxidized components of the aerosol are the most hygroscopic of organic constituents.
No clear relationship was found between organic aerosol hygroscopicity and oxygen-to-carbon ratio.
The aerosol factors covary in a way that induces the observed diurnal invariance in total organic hygroscopicity.
J. Liu, E. Scheuer, J. Dibb, G. S. Diskin, L. D. Ziemba, K. L. Thornhill, B. E. Anderson, A. Wisthaler, T. Mikoviny, J. J. Devi, M. Bergin, A. E. Perring, M. Z. Markovic, J. P. Schwarz, P. Campuzano-Jost, D. A. Day, J. L. Jimenez, and R. J. Weber
Atmos. Chem. Phys., 15, 7841–7858, https://doi.org/10.5194/acp-15-7841-2015, https://doi.org/10.5194/acp-15-7841-2015, 2015
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Brown carbon (BrC) is found throughout the US continental troposphere during a summer of extensive biomass burning and its prevalence relative to black carbon (BC) increases with altitude. A radiative transfer model based on direct measurements of aerosol scattering and absorption by BC and BrC shows BrC reduces top-of-atmosphere forcing by 20%. A method to estimate BrC radiative forcing efficiencies from surface-based measurements is provided.
J. Kaiser, G. M. Wolfe, K. E. Min, S. S. Brown, C. C. Miller, D. J. Jacob, J. A. deGouw, M. Graus, T. F. Hanisco, J. Holloway, J. Peischl, I. B. Pollack, T. B. Ryerson, C. Warneke, R. A. Washenfelder, and F. N. Keutsch
Atmos. Chem. Phys., 15, 7571–7583, https://doi.org/10.5194/acp-15-7571-2015, https://doi.org/10.5194/acp-15-7571-2015, 2015
L. Xu, S. Suresh, H. Guo, R. J. Weber, and N. L. Ng
Atmos. Chem. Phys., 15, 7307–7336, https://doi.org/10.5194/acp-15-7307-2015, https://doi.org/10.5194/acp-15-7307-2015, 2015
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Year-long comprehensive characterization of ambient aerosol was performed in both rural and urban sites in the southeastern US as part of Southeastern Center of Air Pollution and Epidemiology (SCAPE) study and Southeastern Oxidant and Aerosol Study (SOAS). Three independent methods were applied to estimate the concentration of particle-phase organic nitrates. The spatial distribution of organic aerosol is investigated by comparing simultaneous HR-ToF-AMS and ACSM measurements at different sites.
L. K. Emmons, S. R. Arnold, S. A. Monks, V. Huijnen, S. Tilmes, K. S. Law, J. L. Thomas, J.-C. Raut, I. Bouarar, S. Turquety, Y. Long, B. Duncan, S. Steenrod, S. Strode, J. Flemming, J. Mao, J. Langner, A. M. Thompson, D. Tarasick, E. C. Apel, D. R. Blake, R. C. Cohen, J. Dibb, G. S. Diskin, A. Fried, S. R. Hall, L. G. Huey, A. J. Weinheimer, A. Wisthaler, T. Mikoviny, J. Nowak, J. Peischl, J. M. Roberts, T. Ryerson, C. Warneke, and D. Helmig
Atmos. Chem. Phys., 15, 6721–6744, https://doi.org/10.5194/acp-15-6721-2015, https://doi.org/10.5194/acp-15-6721-2015, 2015
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Eleven 3-D tropospheric chemistry models have been compared and evaluated with observations in the Arctic during the International Polar Year (IPY 2008). Large differences are seen among the models, particularly related to the model chemistry of volatile organic compounds (VOCs) and reactive nitrogen (NOx, PAN, HNO3) partitioning. Consistency among the models in the underestimation of CO, ethane and propane indicates the emission inventory is too low for these compounds.
P. L. Hayes, A. G. Carlton, K. R. Baker, R. Ahmadov, R. A. Washenfelder, S. Alvarez, B. Rappenglück, J. B. Gilman, W. C. Kuster, J. A. de Gouw, P. Zotter, A. S. H. Prévôt, S. Szidat, T. E. Kleindienst, J. H. Offenberg, P. K. Ma, and J. L. Jimenez
Atmos. Chem. Phys., 15, 5773–5801, https://doi.org/10.5194/acp-15-5773-2015, https://doi.org/10.5194/acp-15-5773-2015, 2015
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(1) Four different parameterizations for the formation and chemical evolution of secondary organic aerosol (SOA) are evaluated using a box model representing the Los Angeles region during the CalNex campaign.
(2) The SOA formed only from the oxidation of VOCs is insufficient to explain the observed SOA concentrations.
(3) The amount of SOA mass formed from diesel vehicle emissions is estimated to be 16-27%.
(4) Modeled SOA depends strongly on the P-S/IVOC volatility distribution.
R. Volkamer, S. Baidar, T. L. Campos, S. Coburn, J. P. DiGangi, B. Dix, E. W. Eloranta, T. K. Koenig, B. Morley, I. Ortega, B. R. Pierce, M. Reeves, R. Sinreich, S. Wang, M. A. Zondlo, and P. A. Romashkin
Atmos. Meas. Tech., 8, 2121–2148, https://doi.org/10.5194/amt-8-2121-2015, https://doi.org/10.5194/amt-8-2121-2015, 2015
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Tropospheric halogens and small oxygenated VOC (OVOC) modify tropospheric HOx and NOx, O3 and aerosols. We have measured bromine monoxide (BrO), iodine monoxide (IO), glyoxal (CHOCHO) profiles from research aircraft in the tropical troposphere and compare with ship- and aircraft-based in situ sensors. Our measurements point to the need to improve the representation of halogens and organic carbon sources in atmospheric models.
H. Guo, L. Xu, A. Bougiatioti, K. M. Cerully, S. L. Capps, J. R. Hite Jr., A. G. Carlton, S.-H. Lee, M. H. Bergin, N. L. Ng, A. Nenes, and R. J. Weber
Atmos. Chem. Phys., 15, 5211–5228, https://doi.org/10.5194/acp-15-5211-2015, https://doi.org/10.5194/acp-15-5211-2015, 2015
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Particle pH can affect many aerosol processes, including gas-particle partitioning, SOA formation, and mobilization of toxic redox metals. pH is challenging to directly measure and often improperly characterized by proxies like ion balances or molar ratios of measured aerosol ionic species. We present a detailed analysis predicting pH with a thermodynamic model, verify the prediction, and test pH sensitivity to model inputs based on data from the SOAS field campaign.
J. W. Taylor, J. D. Allan, D. Liu, M. Flynn, R. Weber, X. Zhang, B. L. Lefer, N. Grossberg, J. Flynn, and H. Coe
Atmos. Meas. Tech., 8, 1701–1718, https://doi.org/10.5194/amt-8-1701-2015, https://doi.org/10.5194/amt-8-1701-2015, 2015
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When using the SP2 to report black carbon core/shell coating thickness, the core density and refractive index must be estimated from literature values. We systematically vary the assumed parameters and the instrument calibration, and quantify the effects in the derived coatings. The technique is highly sensitive to the core refractive index but has only a minor sensitivity to the core density and coating refractive index. We identify the most appropriate values to use in future analysis.
C. J. Hennigan, J. Izumi, A. P. Sullivan, R. J. Weber, and A. Nenes
Atmos. Chem. Phys., 15, 2775–2790, https://doi.org/10.5194/acp-15-2775-2015, https://doi.org/10.5194/acp-15-2775-2015, 2015
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We show that the ion balance and molar ratio methods are unsuitable for use as aerosol pH proxies. Our recommendation is that 1) thermodynamic equilibrium models constrained by both gas and aerosol inputs run in the forward (open) mode, and 2) the phase partitioning of ammonia provides the best predictions of aerosol pH. Given the significance of acidity for numerous chemical processes in the atmosphere, the implications of this study are important and far reaching.
B. Yuan, P. R. Veres, C. Warneke, J. M. Roberts, J. B. Gilman, A. Koss, P. M. Edwards, M. Graus, W. C. Kuster, S.-M. Li, R. J. Wild, S. S. Brown, W. P. Dubé, B. M. Lerner, E. J. Williams, J. E. Johnson, P. K. Quinn, T. S. Bates, B. Lefer, P. L. Hayes, J. L. Jimenez, R. J. Weber, R. Zamora, B. Ervens, D. B. Millet, B. Rappenglück, and J. A. de Gouw
Atmos. Chem. Phys., 15, 1975–1993, https://doi.org/10.5194/acp-15-1975-2015, https://doi.org/10.5194/acp-15-1975-2015, 2015
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In this work, secondary formation of formic acid at an urban site and a site in an oil and gas production region is studied. We investigated various gas phase formation pathways of formic acid, including those recently proposed, using a box model. The contributions from aerosol-related processes, fog events and air-snow exchange to formic acid are also quantified.
T. Fang, V. Verma, H. Guo, L. E. King, E. S. Edgerton, and R. J. Weber
Atmos. Meas. Tech., 8, 471–482, https://doi.org/10.5194/amt-8-471-2015, https://doi.org/10.5194/amt-8-471-2015, 2015
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This work summarizes a newly developed semi-automated system for quantifying the oxidative potential of aerosol aqueous extracts using the dithiothreitol (DTT) assay. 500 sample analyses indicate that DTT activity in the southeast US is likely not dominated by a unique local source, and sources change with season. The unique large data set generated with the technique described in this paper allows new studies on DTT sources and investigating linkages between reactive oxygen species and health.
V. Verma, T. Fang, H. Guo, L. King, J. T. Bates, R. E. Peltier, E. Edgerton, A. G. Russell, and R. J. Weber
Atmos. Chem. Phys., 14, 12915–12930, https://doi.org/10.5194/acp-14-12915-2014, https://doi.org/10.5194/acp-14-12915-2014, 2014
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The major emission sources of the reactive oxygen species (ROS) associated with ambient particulate matter in the southeastern United States were identified. The study shows biomass burning and secondary aerosol formation as the major sources contributing to the ROS-generating capability of ambient particles. The ubiquitous nature of these two sources suggests widespread population exposures to the toxic aerosol components.
Y. You, V. P. Kanawade, J. A. de Gouw, A. B. Guenther, S. Madronich, M. R. Sierra-Hernández, M. Lawler, J. N. Smith, S. Takahama, G. Ruggeri, A. Koss, K. Olson, K. Baumann, R. J. Weber, A. Nenes, H. Guo, E. S. Edgerton, L. Porcelli, W. H. Brune, A. H. Goldstein, and S.-H. Lee
Atmos. Chem. Phys., 14, 12181–12194, https://doi.org/10.5194/acp-14-12181-2014, https://doi.org/10.5194/acp-14-12181-2014, 2014
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Amiens play important roles in atmospheric secondary aerosol formation and human health, but the fast response measurements of amines are lacking. Here we show measurements in a southeastern US forest and a moderately polluted midwestern site. Our results show that gas to particle conversion is an important process that controls ambient amine concentrations and that biomass burning is an important source of amines.
T. K. V. Nguyen, M. D. Petters, S. R. Suda, H. Guo, R. J. Weber, and A. G. Carlton
Atmos. Chem. Phys., 14, 10911–10930, https://doi.org/10.5194/acp-14-10911-2014, https://doi.org/10.5194/acp-14-10911-2014, 2014
A. P. Sullivan, A. A. May, T. Lee, G. R. McMeeking, S. M. Kreidenweis, S. K. Akagi, R. J. Yokelson, S. P. Urbanski, and J. L. Collett Jr.
Atmos. Chem. Phys., 14, 10535–10545, https://doi.org/10.5194/acp-14-10535-2014, https://doi.org/10.5194/acp-14-10535-2014, 2014
S. H. Budisulistiorini, M. R. Canagaratna, P. L. Croteau, K. Baumann, E. S. Edgerton, M. S. Kollman, N. L. Ng, V. Verma, S. L. Shaw, E. M. Knipping, D. R. Worsnop, J. T. Jayne, R.J. Weber, and J. D. Surratt
Atmos. Meas. Tech., 7, 1929–1941, https://doi.org/10.5194/amt-7-1929-2014, https://doi.org/10.5194/amt-7-1929-2014, 2014
C. Knote, A. Hodzic, J. L. Jimenez, R. Volkamer, J. J. Orlando, S. Baidar, J. Brioude, J. Fast, D. R. Gentner, A. H. Goldstein, P. L. Hayes, W. B. Knighton, H. Oetjen, A. Setyan, H. Stark, R. Thalman, G. Tyndall, R. Washenfelder, E. Waxman, and Q. Zhang
Atmos. Chem. Phys., 14, 6213–6239, https://doi.org/10.5194/acp-14-6213-2014, https://doi.org/10.5194/acp-14-6213-2014, 2014
C. J. Young, R. A. Washenfelder, P. M. Edwards, D. D. Parrish, J. B. Gilman, W. C. Kuster, L. H. Mielke, H. D. Osthoff, C. Tsai, O. Pikelnaya, J. Stutz, P. R. Veres, J. M. Roberts, S. Griffith, S. Dusanter, P. S. Stevens, J. Flynn, N. Grossberg, B. Lefer, J. S. Holloway, J. Peischl, T. B. Ryerson, E. L. Atlas, D. R. Blake, and S. S. Brown
Atmos. Chem. Phys., 14, 3427–3440, https://doi.org/10.5194/acp-14-3427-2014, https://doi.org/10.5194/acp-14-3427-2014, 2014
M. Diao, M. A. Zondlo, A. J. Heymsfield, L. M. Avallone, M. E. Paige, S. P. Beaton, T. Campos, and D. C. Rogers
Atmos. Chem. Phys., 14, 2639–2656, https://doi.org/10.5194/acp-14-2639-2014, https://doi.org/10.5194/acp-14-2639-2014, 2014
S. S. Brown, W. P. Dubé, R. Bahreini, A. M. Middlebrook, C. A. Brock, C. Warneke, J. A. de Gouw, R. A. Washenfelder, E. Atlas, J. Peischl, T. B. Ryerson, J. S. Holloway, J. P. Schwarz, R. Spackman, M. Trainer, D. D. Parrish, F. C. Fehshenfeld, and A. R. Ravishankara
Atmos. Chem. Phys., 13, 11317–11337, https://doi.org/10.5194/acp-13-11317-2013, https://doi.org/10.5194/acp-13-11317-2013, 2013
Y. Cheng, G. Engling, K.-B. He, F.-K. Duan, Y.-L. Ma, Z.-Y. Du, J.-M. Liu, M. Zheng, and R. J. Weber
Atmos. Chem. Phys., 13, 7765–7781, https://doi.org/10.5194/acp-13-7765-2013, https://doi.org/10.5194/acp-13-7765-2013, 2013
C. M. Carmagnola, F. Domine, M. Dumont, P. Wright, B. Strellis, M. Bergin, J. Dibb, G. Picard, Q. Libois, L. Arnaud, and S. Morin
The Cryosphere, 7, 1139–1160, https://doi.org/10.5194/tc-7-1139-2013, https://doi.org/10.5194/tc-7-1139-2013, 2013
L. E. King and R. J. Weber
Atmos. Meas. Tech., 6, 1647–1658, https://doi.org/10.5194/amt-6-1647-2013, https://doi.org/10.5194/amt-6-1647-2013, 2013
T. H. Bertram, A. E. Perring, P. J. Wooldridge, J. Dibb, M. A. Avery, and R. C. Cohen
Atmos. Chem. Phys., 13, 4617–4630, https://doi.org/10.5194/acp-13-4617-2013, https://doi.org/10.5194/acp-13-4617-2013, 2013
R. A. Washenfelder, J. M. Flores, C. A. Brock, S. S. Brown, and Y. Rudich
Atmos. Meas. Tech., 6, 861–877, https://doi.org/10.5194/amt-6-861-2013, https://doi.org/10.5194/amt-6-861-2013, 2013
T. L. Lathem, A. J. Beyersdorf, K. L. Thornhill, E. L. Winstead, M. J. Cubison, A. Hecobian, J. L. Jimenez, R. J. Weber, B. E. Anderson, and A. Nenes
Atmos. Chem. Phys., 13, 2735–2756, https://doi.org/10.5194/acp-13-2735-2013, https://doi.org/10.5194/acp-13-2735-2013, 2013
Related subject area
Subject: Aerosols | Technique: In Situ Measurement | Topic: Instruments and Platforms
Deriving the hygroscopicity of ambient particles using low-cost optical particle counters
Fast and sensitive measurements of sub-3 nm particles using Condensation Particle Counters For Atmospheric Rapid Measurements (CPC FARM)
Performance evaluation of an online monitor based on X-ray fluorescence for detecting elemental concentrations in ambient particulate matter
Simulations of the collection of mesospheric dust particles with a rocket instrument
Characterisation of particle single-scattering albedo with a modified airborne dual-wavelength CAPS monitor
Use of an uncrewed aerial system to investigate aerosol direct and indirect radiative forcing effects in the marine atmosphere
Characterization of the airborne aerosol inlet and transport system used during the A-LIFE aircraft field experiment
Large-scale automated emission measurement of individual vehicles with point sampling
Development of a cascade impactor optimized for size-fractionated analysis of aerosol metal content by total reflection X-ray fluorescence spectroscopy (TXRF)
Modular Multiplatform Compatible Air Measurement System (MoMuCAMS): a new modular platform for boundary layer aerosol and trace gas vertical measurements in extreme environments
Two new multirotor uncrewed aerial vehicles (UAVs) for glaciogenic cloud seeding and aerosol measurements within the CLOUDLAB project
Real-time pollen identification using holographic imaging and fluorescence measurements
Assessing potential indicators of aerosol wet scavenging during long-range transport
Next-generation ice-nucleating particle sampling on board aircraft: characterization of the High-volume flow aERosol particle filter sAmpler (HERA)
Development and characterization of the Portable Ice Nucleation Chamber 2 (PINCii)
The four-wavelength Photoacoustic Aerosol Absorption Spectrometer (PAAS-4λ)
Improved counting statistics of an ultrafine differential mobility particle size spectrometer system
Performance evaluation of the Alphasense OPC-N3 and Plantower PMS5003 sensor in measuring dust events in the Salt Lake Valley, Utah
Source apportionment of black carbon and combustion-related CO2 for the determination of source-specific emission factors
CAMP: an instrumented platform for balloon-borne aerosol particle studies in the lower atmosphere
New method to determine black carbon mass size distribution
The realization of autonomous, aircraft-based, real-time aerosol mass spectrometry in the upper troposphere and lower stratosphere
A study on the performance of low-cost sensors for source apportionment at an urban background site
A dual-wavelength photothermal aerosol absorption monitor: design, calibration and performance
A high-transmission axial ion mobility classifier for mass–mobility measurements of atmospheric ions
Design, characterization, and first field deployment of a novel aircraft-based aerosol mass spectrometer combining the laser ablation and flash vaporization techniques
An instrument for direct measurement of emissions: cooling tower example
The Aerosol Research Observation Station (AEROS)
Laser imaging nephelometer for aircraft deployment
A new method to quantify particulate sodium and potassium salts (nitrate, chloride, and sulfate) by thermal desorption aerosol mass spectrometry
Evaluating the PurpleAir monitor as an aerosol light scattering instrument
Undersizing of aged African biomass burning aerosol by an ultra-high-sensitivity aerosol spectrometer
Evaluation methods for low-cost particulate matter sensors
Simulation-aided characterization of a versatile water-based condensation particle counter for atmospheric airborne research
Development of an in situ dual-channel thermal desorption gas chromatography instrument for consistent quantification of volatile, intermediate-volatility and semivolatile organic compounds
Characterizing the performance of a POPS miniaturized optical particle counter when operated on a quadcopter drone
A low-cost monitor for simultaneous measurement of fine particulate matter and aerosol optical depth – Part 3: Automation and design improvements
Rapid measurement of RH-dependent aerosol hygroscopic growth using a humidity-controlled fast integrated mobility spectrometer (HFIMS)
Detection of ship plumes from residual fuel operation in emission control areas using single-particle mass spectrometry
Highly time-resolved characterization of carbonaceous aerosols using a two-wavelength Sunset thermal–optical carbon analyzer
Captive Aerosol Growth and Evolution (CAGE) chamber system to investigate particle growth due to secondary aerosol formation
Design and characterization of a new oxidation flow reactor for laboratory and long-term ambient studies
A reel-down instrument system for profile measurements of water vapor, temperature, clouds, and aerosol beneath constant-altitude scientific balloons
Airborne extractive electrospray mass spectrometry measurements of the chemical composition of organic aerosol
A semicontinuous study on the ecotoxicity of atmospheric particles using a versatile aerosol concentration enrichment system (VACES): development and field characterization
A novel rocket-borne ion mass spectrometer with large mass range: instrument description and first-flight results
Detailed characterization of the CAPS single-scattering albedo monitor (CAPS PMssa) as a field-deployable instrument for measuring aerosol light absorption with the extinction-minus-scattering method
New in situ aerosol hyperspectral optical measurements over 300–700 nm – Part 1: Spectral Aerosol Extinction (SpEx) instrument field validation during the KORUS-OC cruise
New in situ aerosol hyperspectral optical measurements over 300–700 nm – Part 2: Extinction, total absorption, water- and methanol-soluble absorption observed during the KORUS-OC cruise
Continuous online monitoring of ice-nucleating particles: development of the automated Horizontal Ice Nucleation Chamber (HINC-Auto)
Wei-Chieh Huang, Hui-Ming Hung, Ching-Wei Chu, Wei-Chun Hwang, and Shih-Chun Candice Lung
Atmos. Meas. Tech., 17, 6073–6084, https://doi.org/10.5194/amt-17-6073-2024, https://doi.org/10.5194/amt-17-6073-2024, 2024
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This study investigates aerosol properties crucial for health, cloud formation, and climate impact. Employing a low-cost sensor system, we assess hygroscopicity of particulate matter (PM) and the ability to influence cloud formation to improve the reported PM concentrations from low-cost sensors. The study introduces an alternate methodology for assessing aerosol hygroscopicity, offering insights into atmospheric science, air quality, and cloud dynamics.
Darren Cheng, Stavros Amanatidis, Gregory S. Lewis, and Coty N. Jen
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-157, https://doi.org/10.5194/amt-2024-157, 2024
Revised manuscript accepted for AMT
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This study describes a new instrument, the Condensation Particle Counter For Atmospheric Rapid Measurements (CPC FARM), to measure sub-3 nm size distribution at high time resolution and sensitivity. The CPC FARM is compared to traditionally used particle mobility sizers during a new particle formation campaign to study rapidly changing sub-3 nm in Pittsburgh, PA.
Ivonne Trebs, Céline Lett, Andreas Krein, Erika Matsumoto Kawaguchi, and Jürgen Junk
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-134, https://doi.org/10.5194/amt-2024-134, 2024
Revised manuscript accepted for AMT
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This study explores the effectiveness of the Horiba PX-375 monitor for analyzing the elemental composition of airborne particulate matter (PM). Understanding this composition of PM is important for identifying its sources, assessing potential health risks, and developing strategies to reduce air pollution. The PX-375 monitor proved to be a valuable tool for ongoing air quality monitoring studies and could be particularly useful as pollution levels and sources change in the future.
Adrien Pineau, Henriette Trollvik, Herman Greaker, Sveinung Olsen, Yngve Eilertsen, and Ingrid Mann
Atmos. Meas. Tech., 17, 3843–3861, https://doi.org/10.5194/amt-17-3843-2024, https://doi.org/10.5194/amt-17-3843-2024, 2024
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The mesosphere, part of the upper atmosphere, contains small solid dust particles, mostly made up of material from interplanetary space. We are preparing an experiment to collect such particles during a rocket flight. A new instrument has been designed and numerical simulations have been performed to investigate the airflow nearby as well as its dust collection efficiency. The collected dust particles will be further analyzed in the laboratory in order to study their chemical composition.
Chenjie Yu, Edouard Pangui, Kevin Tu, Mathieu Cazaunau, Maxime Feingesicht, Landsheere Xavier, Thierry Bourrianne, Vincent Michoud, Christopher Cantrell, Timothy B. Onasch, Andrew Freedman, and Paola Formenti
Atmos. Meas. Tech., 17, 3419–3437, https://doi.org/10.5194/amt-17-3419-2024, https://doi.org/10.5194/amt-17-3419-2024, 2024
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To meet the requirements for measuring aerosol optical properties on airborne platforms and conducting dual-wavelength measurements, we introduced A2S2, an airborne dual-wavelength cavity-attenuated phase-shift single monitor. This study reports the results in the laboratory and an aircraft campaign over Paris and its surrounding regions. The results demonstrate A2S2's reliability in measuring aerosol optical properties at both wavelengths and its suitability for future aircraft campaigns.
Patricia K. Quinn, Timothy S. Bates, Derek J. Coffman, James E. Johnson, and Lucia M. Upchurch
Atmos. Meas. Tech., 17, 3157–3170, https://doi.org/10.5194/amt-17-3157-2024, https://doi.org/10.5194/amt-17-3157-2024, 2024
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An uncrewed aerial observing system has been developed for the measurement of vertical profiles of aerosol and cloud properties that affect Earth's radiation balance. The system was successfully deployed from a ship and from a coastal site and flown autonomously up to 3050 m and for 4.5 h. These results indicate the potential of the observing system to make routine, operational flights from ships and land to characterize aerosol interactions with radiation and clouds.
Manuel Schöberl, Maximilian Dollner, Josef Gasteiger, Petra Seibert, Anne Tipka, and Bernadett Weinzierl
Atmos. Meas. Tech., 17, 2761–2776, https://doi.org/10.5194/amt-17-2761-2024, https://doi.org/10.5194/amt-17-2761-2024, 2024
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Transporting a representative aerosol sample to instrumentation inside a research aircraft remains a challenge due to losses or enhancements of particles in the aerosol sampling system. Here, we present sampling efficiencies and the cutoff diameter for the DLR Falcon aerosol sampling system as a function of true airspeed by comparing the in-cabin and the out-cabin particle number size distributions observed during the A-LIFE aircraft mission.
Markus Knoll, Martin Penz, Hannes Juchem, Christina Schmidt, Denis Pöhler, and Alexander Bergmann
Atmos. Meas. Tech., 17, 2481–2505, https://doi.org/10.5194/amt-17-2481-2024, https://doi.org/10.5194/amt-17-2481-2024, 2024
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Exhaust emissions from combustion-based vehicles are negatively affecting human health and our environment. In particular, a small share (< 20 %) of poorly maintained or tampered vehicles are responsible for the majority (60 %–90 %) of traffic-related emissions. The emissions from vehicles are currently not properly monitored during their lifetime. We present a roadside measurement technique, called
point sampling, which can be used to monitor vehicle emissions throughout their life cycle.
Claudio Crazzolara and Andreas Held
Atmos. Meas. Tech., 17, 2183–2194, https://doi.org/10.5194/amt-17-2183-2024, https://doi.org/10.5194/amt-17-2183-2024, 2024
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Our paper describes the development of a collection device that can be used to collect airborne dust particles classified according to their size. This collection device is optimized for a special analysis method based on X-ray fluorescence so that particles can be collected from the air and analyzed with high sensitivity. This enables the determination of the content of heavy metals in the airborne particle fraction, which are of health-relevant significance.
Roman Pohorsky, Andrea Baccarini, Julie Tolu, Lenny H. E. Winkel, and Julia Schmale
Atmos. Meas. Tech., 17, 731–754, https://doi.org/10.5194/amt-17-731-2024, https://doi.org/10.5194/amt-17-731-2024, 2024
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This manuscript presents a new tethered-balloon-based platform for in situ vertical measurements of aerosols and trace gases in the lower atmosphere of polar and alpine regions. The system can host various instrumental setups to target different research questions and features new instruments, in particular a miniaturized scanning electrical mobility spectrometer, deployed for the first time in a tethered balloon.
Anna J. Miller, Fabiola Ramelli, Christopher Fuchs, Nadja Omanovic, Robert Spirig, Huiying Zhang, Ulrike Lohmann, Zamin A. Kanji, and Jan Henneberger
Atmos. Meas. Tech., 17, 601–625, https://doi.org/10.5194/amt-17-601-2024, https://doi.org/10.5194/amt-17-601-2024, 2024
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We present a method for aerosol and cloud research using two uncrewed aerial vehicles (UAVs). The UAVs have a propeller heating mechanism that allows flights in icing conditions, which has so far been a limitation for cloud research with UAVs. One UAV burns seeding flares, producing a plume of particles that causes ice formation in supercooled clouds. The second UAV measures aerosol size distributions and is used for measuring the seeding plume or for characterizing the boundary layer.
Sophie Erb, Elias Graf, Yanick Zeder, Simone Lionetti, Alexis Berne, Bernard Clot, Gian Lieberherr, Fiona Tummon, Pascal Wullschleger, and Benoît Crouzy
Atmos. Meas. Tech., 17, 441–451, https://doi.org/10.5194/amt-17-441-2024, https://doi.org/10.5194/amt-17-441-2024, 2024
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In this study, we focus on an automatic bioaerosol measurement instrument and investigate the impact of using its fluorescence measurement for pollen identification. The fluorescence signal is used together with a pair of images from the same instrument to identify single pollen grains via neural networks. We test whether considering fluorescence as a supplementary input improves the pollen identification performance by comparing three different neural networks.
Miguel Ricardo A. Hilario, Avelino F. Arellano, Ali Behrangi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Michael A. Shook, Luke D. Ziemba, and Armin Sorooshian
Atmos. Meas. Tech., 17, 37–55, https://doi.org/10.5194/amt-17-37-2024, https://doi.org/10.5194/amt-17-37-2024, 2024
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Wet scavenging strongly influences aerosol lifetime and interactions but is a large uncertainty in global models. We present a method to identify meteorological variables relevant for estimating wet scavenging. During long-range transport over the tropical western Pacific, relative humidity and the frequency of humid conditions are better predictors of scavenging than precipitation. This method can be applied to other regions, and our findings can inform scavenging parameterizations in models.
Sarah Grawe, Conrad Jentzsch, Jonas Schaefer, Heike Wex, Stephan Mertes, and Frank Stratmann
Atmos. Meas. Tech., 16, 4551–4570, https://doi.org/10.5194/amt-16-4551-2023, https://doi.org/10.5194/amt-16-4551-2023, 2023
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Measurements of ice-nucleating particle (INP) concentrations are valuable for the simulation of cloud properties. In recent years, filter sampling in combination with offline INP measurements has become increasingly popular. However, most sampling is ground-based, and the vertical transport of INPs is not well quantified. The High-volume flow aERosol particle filter sAmpler (HERA) for applications on board aircraft was developed to expand the sparse dataset of INP concentrations at cloud level.
Dimitri Castarède, Zoé Brasseur, Yusheng Wu, Zamin A. Kanji, Markus Hartmann, Lauri Ahonen, Merete Bilde, Markku Kulmala, Tuukka Petäjä, Jan B. C. Pettersson, Berko Sierau, Olaf Stetzer, Frank Stratmann, Birgitta Svenningsson, Erik Swietlicki, Quynh Thu Nguyen, Jonathan Duplissy, and Erik S. Thomson
Atmos. Meas. Tech., 16, 3881–3899, https://doi.org/10.5194/amt-16-3881-2023, https://doi.org/10.5194/amt-16-3881-2023, 2023
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Clouds play a key role in Earth’s climate by influencing the surface energy budget. Certain types of atmospheric aerosols, called ice-nucleating particles (INPs), induce the formation of ice in clouds and, thus, often initiate precipitation formation. The Portable Ice Nucleation Chamber 2 (PINCii) is a new instrument developed to study ice formation and to conduct ambient measurements of INPs, allowing us to investigate the sources and properties of the atmospheric aerosols that can act as INPs.
Franz Martin Schnaiter, Claudia Linke, Eija Asmi, Henri Servomaa, Antti-Pekka Hyvärinen, Sho Ohata, Yutaka Kondo, and Emma Järvinen
Atmos. Meas. Tech., 16, 2753–2769, https://doi.org/10.5194/amt-16-2753-2023, https://doi.org/10.5194/amt-16-2753-2023, 2023
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Light-absorbing particles from combustion processes are important contributors to climate warming. Their highly variable spectral light absorption properties need to be monitored in the field. Commonly used methods show measurement artefacts that are difficult to correct. We introduce a new instrument that is based on the photoacoustic effect. Long-term operation in the Finnish Arctic demonstrates the applicability of the new instrument for unattended light absorption monitoring.
Dominik Stolzenburg, Tiia Laurila, Pasi Aalto, Joonas Vanhanen, Tuukka Petäjä, and Juha Kangasluoma
Atmos. Meas. Tech., 16, 2471–2483, https://doi.org/10.5194/amt-16-2471-2023, https://doi.org/10.5194/amt-16-2471-2023, 2023
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Size-distribution measurements of ultrafine particles are of special interest as they can be used to estimate the atmospheric significance of new particle formation, a process which is thought to influence the global climate. Here we show that improved counting statistics in size-distribution measurements through the usage of higher sampling flows can significantly reduce the uncertainties in such calculations.
Kamaljeet Kaur and Kerry E. Kelly
Atmos. Meas. Tech., 16, 2455–2470, https://doi.org/10.5194/amt-16-2455-2023, https://doi.org/10.5194/amt-16-2455-2023, 2023
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We evaluated the AlphaSense OPC-N3 and PMS5003 compared to federal equivalent method (FEM) PM10 measurements in the Salt Lake Valley during five dust events. Before correction, the OPC-N3 agreed well, but the PMS PM10 measurements correlated poorly with the FEM. After correcting the PMS with a PM2.5 / PM10 ratio-based factor, the PMS PM10 correlations improved significantly. This suggests the possibility of better resolved spatial estimates of PM10 using PMS measurements and PM2.5 / PM10 ratios.
Balint Alfoldy, Asta Gregorič, Matic Ivančič, Irena Ježek, and Martin Rigler
Atmos. Meas. Tech., 16, 135–152, https://doi.org/10.5194/amt-16-135-2023, https://doi.org/10.5194/amt-16-135-2023, 2023
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Atmospheric concentrations and source apportionment (SA) of black carbon (BC) and CO2 were determined in an urban environment during a heating season. BC particles were attributed to two major sources: traffic and heating. The BC SA was implemented by an Aethalometer model used for the SA of CO2 supposing that the source-specific CO2 components are correlated with the corresponding BC. Source-specific emission factors were determined as a ratio of corresponding BC and CO2 components.
Christian Pilz, Sebastian Düsing, Birgit Wehner, Thomas Müller, Holger Siebert, Jens Voigtländer, and Michael Lonardi
Atmos. Meas. Tech., 15, 6889–6905, https://doi.org/10.5194/amt-15-6889-2022, https://doi.org/10.5194/amt-15-6889-2022, 2022
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Tethered balloon observations are highly valuable for aerosol studies in the lowest part of the atmosphere. This study presents a newly developed platform called CAMP with four aerosol instruments for balloon-borne measurements in the Arctic. Laboratory characterizations and evaluations of the instruments and results of a first field deployment are shown. A case study highlights CAMP's capabilities and the importance of airborne aerosol studies for interpretation of ground-based observations.
Weilun Zhao, Gang Zhao, Ying Li, Song Guo, Nan Ma, Lizi Tang, Zirui Zhang, and Chunsheng Zhao
Atmos. Meas. Tech., 15, 6807–6817, https://doi.org/10.5194/amt-15-6807-2022, https://doi.org/10.5194/amt-15-6807-2022, 2022
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A new method to determine black carbon mass size distribution (BCMSD) was proposed using the size-resolved absorption coefficient measured by an aerodynamic aerosol classifier in tandem with an aethalometer. This new method fills the gap in the high-time-resolution measurement of BCMSD ranging from upper submicron particle sizes to larger than 1 µm. This method can be applied to field measurement of BCMSD extensively for better understanding BC aging and better estimating the BC climate effect.
Antonis Dragoneas, Sergej Molleker, Oliver Appel, Andreas Hünig, Thomas Böttger, Markus Hermann, Frank Drewnick, Johannes Schneider, Ralf Weigel, and Stephan Borrmann
Atmos. Meas. Tech., 15, 5719–5742, https://doi.org/10.5194/amt-15-5719-2022, https://doi.org/10.5194/amt-15-5719-2022, 2022
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The ERICA is a specially designed aerosol particle mass spectrometer for in situ, real-time chemical composition analysis of aerosols. It can operate completely autonomously, in the absence of an instrument operator. Its design has enabled its operation under harsh conditions, like those experienced in the upper troposphere and lower stratosphere, aboard unpressurized high-altitude research aircraft. The instrument has successfully participated in several aircraft operations around the world.
Dimitrios Bousiotis, David C. S. Beddows, Ajit Singh, Molly Haugen, Sebastián Diez, Pete M. Edwards, Adam Boies, Roy M. Harrison, and Francis D. Pope
Atmos. Meas. Tech., 15, 4047–4061, https://doi.org/10.5194/amt-15-4047-2022, https://doi.org/10.5194/amt-15-4047-2022, 2022
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In the last decade, low-cost sensors have revolutionised the field of air quality monitoring. This paper extends the ability of low-cost sensors to not only measure air pollution, but also to understand where the pollution comes from. This "source apportionment" is a critical step in air quality management to allow for the mitigation of air pollution. The techniques developed in this paper have the potential for great impact in both research and industrial applications.
Luka Drinovec, Uroš Jagodič, Luka Pirker, Miha Škarabot, Mario Kurtjak, Kristijan Vidović, Luca Ferrero, Bradley Visser, Jannis Röhrbein, Ernest Weingartner, Daniel M. Kalbermatter, Konstantina Vasilatou, Tobias Bühlmann, Celine Pascale, Thomas Müller, Alfred Wiedensohler, and Griša Močnik
Atmos. Meas. Tech., 15, 3805–3825, https://doi.org/10.5194/amt-15-3805-2022, https://doi.org/10.5194/amt-15-3805-2022, 2022
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A new photothermal interferometer (PTAAM-2λ) for artefact-free determination of the aerosol absorption coefficient at two wavelengths is presented. The instrument is calibrated with NO2 and polydisperse nigrosin, resulting in very low uncertainties of the absorption coefficients: 4 % at 532 nm and 6 % at 1064 nm. The instrument’s performance makes the PTAAM-2λ a strong candidate for reference measurements of the aerosol absorption coefficient.
Markus Leiminger, Lukas Fischer, Sophia Brilke, Julian Resch, Paul Martin Winkler, Armin Hansel, and Gerhard Steiner
Atmos. Meas. Tech., 15, 3705–3720, https://doi.org/10.5194/amt-15-3705-2022, https://doi.org/10.5194/amt-15-3705-2022, 2022
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We developed an axial ion mobility classifier coupled to an atmospheric-pressure interface time-of-flight (APi-TOF) mass spectrometer to measure size-segregated atmospheric ions. We characterize the performance of the novel instrument with bipolar-electrospray-generated ion mobility standards and compare the results with CFD simulations and a simplified numerical particle-tracking model. Ultimately, we report first mass–mobility measurements of atmospheric ions in Innsbruck, Austria.
Andreas Hünig, Oliver Appel, Antonis Dragoneas, Sergej Molleker, Hans-Christian Clemen, Frank Helleis, Thomas Klimach, Franziska Köllner, Thomas Böttger, Frank Drewnick, Johannes Schneider, and Stephan Borrmann
Atmos. Meas. Tech., 15, 2889–2921, https://doi.org/10.5194/amt-15-2889-2022, https://doi.org/10.5194/amt-15-2889-2022, 2022
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We have serially combined the two well-established methods for in situ real-time measurement of fine particle chemical composition, the single-particle laser ablation method and the flash evaporation with electron impact ionization method, into a novel instrument. Here we present the design; instrument characteristics, as derived from laboratory and field measurements; and results from the first field deployment during the 2017 StratoClim aircraft campaign.
Christopher D. Wallis, Mason D. Leandro, Patrick Y. Chuang, and Anthony S. Wexler
Atmos. Meas. Tech., 15, 2547–2556, https://doi.org/10.5194/amt-15-2547-2022, https://doi.org/10.5194/amt-15-2547-2022, 2022
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Measuring emissions from stacks requires techniques to address a broad range of conditions and measurement challenges. Here we describe an instrument package held by a crane above a stack to characterize both wet droplet and dried aerosol emissions from cooling tower spray drift in situ. The instrument package characterizes the velocity, size distribution, and concentration of the wet droplet emissions and the mass concentration and elemental composition of the dried PM2.5 and PM10 emissions.
Karin Ardon-Dryer, Mary C. Kelley, Xia Xueting, and Yuval Dryer
Atmos. Meas. Tech., 15, 2345–2360, https://doi.org/10.5194/amt-15-2345-2022, https://doi.org/10.5194/amt-15-2345-2022, 2022
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The Aerosol Research Observation Station (AEROS) located in West Texas was designed to continuously measure atmospheric particles, including different particulate matter sizes, total particle number concentration, and size distribution. This article provides a description of AEROS as well as an intercomparison of the different instruments using laboratory and atmospheric particles, showing similar concentration as well to distinguish between various pollution events (natural vs. anthropogenic).
Adam T. Ahern, Frank Erdesz, Nicholas L. Wagner, Charles A. Brock, Ming Lyu, Kyra Slovacek, Richard H. Moore, Elizabeth B. Wiggins, and Daniel M. Murphy
Atmos. Meas. Tech., 15, 1093–1105, https://doi.org/10.5194/amt-15-1093-2022, https://doi.org/10.5194/amt-15-1093-2022, 2022
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Particles in the atmosphere play a significant role in climate change by scattering light back into space, reducing the amount of energy available to be absorbed by greenhouse gases. We built a new instrument to measure what direction light is scattered by particles, e.g., wildfire smoke. This is important because, depending on the angle of the sun, some particles scatter light into space (cooling the planet), but some light is also scattered towards the Earth (not cooling the planet).
Yuya Kobayashi and Nobuyuki Takegawa
Atmos. Meas. Tech., 15, 833–844, https://doi.org/10.5194/amt-15-833-2022, https://doi.org/10.5194/amt-15-833-2022, 2022
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We propose a new method to quantify particulate sodium and potassium salts (nitrate, chloride, and sulfate) by using a refractory aerosol thermal desorption mass spectrometer (rTDMS). The combination of a graphite particle collector and a carbon dioxide laser enables high desorption temperature. Laboratory experiments showed that major ion signals originating from sodium or potassium salts were clearly detected, associated with the increase in the desorption temperature by laser heating.
James R. Ouimette, William C. Malm, Bret A. Schichtel, Patrick J. Sheridan, Elisabeth Andrews, John A. Ogren, and W. Patrick Arnott
Atmos. Meas. Tech., 15, 655–676, https://doi.org/10.5194/amt-15-655-2022, https://doi.org/10.5194/amt-15-655-2022, 2022
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We show that the low-cost PurpleAir sensor can be characterized as a cell-reciprocal nephelometer. At two very different locations (Mauna Loa Observatory in Hawaii and the Table Mountain rural site in Colorado), the PurpleAir measurements are highly correlated with the submicrometer aerosol scattering coefficient measured by a research-grade integrating nephelometer. These results imply that, with care, PurpleAir data may be used to evaluate climate and air quality models.
Steven G. Howell, Steffen Freitag, Amie Dobracki, Nikolai Smirnow, and Arthur J. Sedlacek III
Atmos. Meas. Tech., 14, 7381–7404, https://doi.org/10.5194/amt-14-7381-2021, https://doi.org/10.5194/amt-14-7381-2021, 2021
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Small particles in the air have important effects on visibility, clouds, and human health. For the ORACLES project we got a new particle sizing instrument that is fast, works over the most important particle sizes, and avoids some of the issues that plague other optical particle sizers. Unfortunately it sees some particles much smaller than they really are, likely because they heat up and evaporate. We show a crude correction and speculate why these particles heat up much more than expected.
Jeffrey K. Bean
Atmos. Meas. Tech., 14, 7369–7379, https://doi.org/10.5194/amt-14-7369-2021, https://doi.org/10.5194/amt-14-7369-2021, 2021
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Understanding and improving the quality of data generated from low-cost air quality sensors are crucial steps in using these sensors. This work investigates how averaging time, choice of reference instrument, and the observation of higher pollutant concentrations can impact the perceived performance of low-cost sensors in an evaluation. The influence of these factors should be considered when comparing one sensor to another or determining if a sensor can produce data that fit a specific need.
Fan Mei, Steven Spielman, Susanne Hering, Jian Wang, Mikhail S. Pekour, Gregory Lewis, Beat Schmid, Jason Tomlinson, and Maynard Havlicek
Atmos. Meas. Tech., 14, 7329–7340, https://doi.org/10.5194/amt-14-7329-2021, https://doi.org/10.5194/amt-14-7329-2021, 2021
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This study focuses on understanding a versatile water-based condensation particle counter (vWCPC 3789) performance under various ambient pressure conditions (500–1000 hPa). A vWCPC has the advantage of avoiding health and safety concerns. However, its performance characterization under low pressure is rare but crucial for ensuring successful airborne deployment. This paper provides advanced knowledge of operating a vWCPC 3789 to capture the spatial variations of atmospheric aerosols.
Rebecca A. Wernis, Nathan M. Kreisberg, Robert J. Weber, Yutong Liang, John Jayne, Susanne Hering, and Allen H. Goldstein
Atmos. Meas. Tech., 14, 6533–6550, https://doi.org/10.5194/amt-14-6533-2021, https://doi.org/10.5194/amt-14-6533-2021, 2021
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cTAG is a new scientific instrument that measures concentrations of organic chemicals in the atmosphere. cTAG is the first instrument capable of measuring small, light chemicals as well as heavier chemicals and everything in between on a single detector, every hour. In this work we explain how cTAG works and some of the tests we performed to verify that it works properly and reliably. We also present measurements of alkanes that suggest they have three dominant sources in a Bay Area suburb.
Zixia Liu, Martin Osborne, Karen Anderson, Jamie D. Shutler, Andy Wilson, Justin Langridge, Steve H. L. Yim, Hugh Coe, Suresh Babu, Sreedharan K. Satheesh, Paquita Zuidema, Tao Huang, Jack C. H. Cheng, and James Haywood
Atmos. Meas. Tech., 14, 6101–6118, https://doi.org/10.5194/amt-14-6101-2021, https://doi.org/10.5194/amt-14-6101-2021, 2021
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This paper first validates the performance of an advanced aerosol observation instrument POPS against a reference instrument and examines any biases introduced by operating it on a quadcopter drone. The results show the POPS performs relatively well on the ground. The impact of the UAV rotors on the POPS is small at low wind speeds, but when operating under higher wind speeds, larger discrepancies occur. It appears that the POPS measures sub-micron aerosol particles more accurately on the UAV.
Eric A. Wendt, Casey Quinn, Christian L'Orange, Daniel D. Miller-Lionberg, Bonne Ford, Jeffrey R. Pierce, John Mehaffy, Michael Cheeseman, Shantanu H. Jathar, David H. Hagan, Zoey Rosen, Marilee Long, and John Volckens
Atmos. Meas. Tech., 14, 6023–6038, https://doi.org/10.5194/amt-14-6023-2021, https://doi.org/10.5194/amt-14-6023-2021, 2021
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Fine particulate matter air pollution is one of the leading contributors to adverse health outcomes on the planet. Here, we describe the design and validation of a low-cost, compact, and autonomous instrument capable of measuring particulate matter levels directly, via mass sampling, and optically, via mass and sunlight extinction measurements. We demonstrate the instrument's accuracy relative to reference measurements and its potential for community-level sampling.
Jiaoshi Zhang, Steven Spielman, Yang Wang, Guangjie Zheng, Xianda Gong, Susanne Hering, and Jian Wang
Atmos. Meas. Tech., 14, 5625–5635, https://doi.org/10.5194/amt-14-5625-2021, https://doi.org/10.5194/amt-14-5625-2021, 2021
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In this study, we present a newly developed instrument, the humidity-controlled fast integrated mobility spectrometer (HFIMS), for fast measurements of aerosol hygroscopic growth. The HFIMS can measure the distributions of particle hygroscopic growth factors at six diameters from 35 to 265 nm under five RH levels from 20 to 85 % within 25 min. The HFIMS significantly advances our capability of characterizing the hygroscopic growth of atmospheric aerosols over a wide range of relative humidities.
Johannes Passig, Julian Schade, Robert Irsig, Lei Li, Xue Li, Zhen Zhou, Thomas Adam, and Ralf Zimmermann
Atmos. Meas. Tech., 14, 4171–4185, https://doi.org/10.5194/amt-14-4171-2021, https://doi.org/10.5194/amt-14-4171-2021, 2021
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Ships are major sources of air pollution; however, monitoring of ship emissions outside harbours is a challenging task. We optimized single-particle mass spectrometry (SPMS) for the detection of bunker fuel emissions and demonstrate the detection of individual ship plumes from more than 10 km in distance. The approach works independently of background air pollution and also when ships use exhaust-cleaning scrubbers. We discuss the potential and limits of SPMS-based monitoring of ship plumes.
Mengying Bao, Yan-Lin Zhang, Fang Cao, Yu-Chi Lin, Yuhang Wang, Xiaoyan Liu, Wenqi Zhang, Meiyi Fan, Feng Xie, Robert Cary, Joshua Dixon, and Lihua Zhou
Atmos. Meas. Tech., 14, 4053–4068, https://doi.org/10.5194/amt-14-4053-2021, https://doi.org/10.5194/amt-14-4053-2021, 2021
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We introduce a two-wavelength method for brown C measurements with a modified Sunset carbon analyzer. We defined the enhanced concentrations and gave the possibility of providing an indicator of brown C. Compared with the strong local sources of organic and elemental C, we found that differences in EC mainly originated from regional transport. Biomass burning emissions significantly contributed to high differences in EC concentrations during the heavy biomass burning periods.
Candice L. Sirmollo, Don R. Collins, Jordan M. McCormick, Cassandra F. Milan, Matthew H. Erickson, James H. Flynn, Rebecca J. Sheesley, Sascha Usenko, Henry W. Wallace, Alexander A. T. Bui, Robert J. Griffin, Matthew Tezak, Sean M. Kinahan, and Joshua L. Santarpia
Atmos. Meas. Tech., 14, 3351–3370, https://doi.org/10.5194/amt-14-3351-2021, https://doi.org/10.5194/amt-14-3351-2021, 2021
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The newly developed portable 1 m3 CAGE chamber systems were characterized using data acquired during a 2-month field study in 2016 in a forested area north of Houston, TX, USA. Concentrations of several oxidant and organic compounds measured in the chamber were found to closely agree with those calculated with a zero-dimensional model. By tracking the modes of injected monodisperse particles, a pattern change was observed for hourly averaged growth rates between late summer and early fall.
Ningjin Xu and Don R. Collins
Atmos. Meas. Tech., 14, 2891–2906, https://doi.org/10.5194/amt-14-2891-2021, https://doi.org/10.5194/amt-14-2891-2021, 2021
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Oxidation flow reactors (OFRs) are frequently used to study atmospheric chemistry and aerosol formation by accelerating by up to 10 000 times the reactions that can take hours, days, or even weeks in the atmosphere. Here we present the design and evaluation of a new all-Teflon OFR. The computational, laboratory, and field use data we present demonstrate that the PFA OFR is suitable for a range of applications, including the study of rapidly changing ambient concentrations.
Lars E. Kalnajs, Sean M. Davis, J. Douglas Goetz, Terry Deshler, Sergey Khaykin, Alex St. Clair, Albert Hertzog, Jerome Bordereau, and Alexey Lykov
Atmos. Meas. Tech., 14, 2635–2648, https://doi.org/10.5194/amt-14-2635-2021, https://doi.org/10.5194/amt-14-2635-2021, 2021
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This work introduces a novel instrument system for high-resolution atmospheric profiling, which lowers and retracts a suspended instrument package beneath drifting long-duration balloons. During a 100 d circumtropical flight, the instrument collected over a hundred 2 km profiles of temperature, water vapor, clouds, and aerosol at 1 m resolution, yielding unprecedented geographic sampling and vertical resolution measurements of the tropical tropopause layer.
Demetrios Pagonis, Pedro Campuzano-Jost, Hongyu Guo, Douglas A. Day, Melinda K. Schueneman, Wyatt L. Brown, Benjamin A. Nault, Harald Stark, Kyla Siemens, Alex Laskin, Felix Piel, Laura Tomsche, Armin Wisthaler, Matthew M. Coggon, Georgios I. Gkatzelis, Hannah S. Halliday, Jordan E. Krechmer, Richard H. Moore, David S. Thomson, Carsten Warneke, Elizabeth B. Wiggins, and Jose L. Jimenez
Atmos. Meas. Tech., 14, 1545–1559, https://doi.org/10.5194/amt-14-1545-2021, https://doi.org/10.5194/amt-14-1545-2021, 2021
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We describe the airborne deployment of an extractive electrospray time-of-flight mass spectrometer (EESI-MS). The instrument provides a quantitative 1 Hz measurement of the chemical composition of organic aerosol up to altitudes of
7 km, with single-compound detection limits as low as 50 ng per standard cubic meter.
Xiaona Shang, Ling Li, Xinlian Zhang, Huihui Kang, Guodong Sui, Gehui Wang, Xingnan Ye, Hang Xiao, and Jianmin Chen
Atmos. Meas. Tech., 14, 1037–1045, https://doi.org/10.5194/amt-14-1037-2021, https://doi.org/10.5194/amt-14-1037-2021, 2021
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Oxidative stress can be used to evaluate not only adverse health effects but also adverse ecological effects. However, little research uses eco-toxicological assay to assess the risks posed by particle matter to non-human biomes. One important reason might be that the concentration of toxic components of atmospheric particles is far below the high detection limit of eco-toxic measurement. To solve the rapid detection problem, we extended a VACES for ecotoxicity aerosol measurement.
Joan Stude, Heinfried Aufmhoff, Hans Schlager, Markus Rapp, Frank Arnold, and Boris Strelnikov
Atmos. Meas. Tech., 14, 983–993, https://doi.org/10.5194/amt-14-983-2021, https://doi.org/10.5194/amt-14-983-2021, 2021
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In this paper we describe the instrument ROMARA and show data from the first flight on a research rocket.
On the way through the atmosphere, the instrument detects positive and negative, natural occurring ions before returning back to ground.
ROMARA was successfully launched together with other instruments into a special radar echo.
We detected typical, light ions of positive and negative charge and heavy negative ions, but no heavy positive ions.
Rob L. Modini, Joel C. Corbin, Benjamin T. Brem, Martin Irwin, Michele Bertò, Rosaria E. Pileci, Prodromos Fetfatzis, Kostas Eleftheriadis, Bas Henzing, Marcel M. Moerman, Fengshan Liu, Thomas Müller, and Martin Gysel-Beer
Atmos. Meas. Tech., 14, 819–851, https://doi.org/10.5194/amt-14-819-2021, https://doi.org/10.5194/amt-14-819-2021, 2021
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Extinction-minus-scattering is an important method for measuring aerosol light absorption, but its application in the field presents a number of challenges. A recently developed instrument based on this method – the CAPS PMssa – has the potential to overcome some of these challenges. We present a compilation of theory, lab measurements, and field examples to characterize this instrument and show the conditions under which it can deliver reliable absorption measurements for atmospheric aerosols.
Carolyn E. Jordan, Ryan M. Stauffer, Brian T. Lamb, Charles H. Hudgins, Kenneth L. Thornhill, Gregory L. Schuster, Richard H. Moore, Ewan C. Crosbie, Edward L. Winstead, Bruce E. Anderson, Robert F. Martin, Michael A. Shook, Luke D. Ziemba, Andreas J. Beyersdorf, Claire E. Robinson, Chelsea A. Corr, and Maria A. Tzortziou
Atmos. Meas. Tech., 14, 695–713, https://doi.org/10.5194/amt-14-695-2021, https://doi.org/10.5194/amt-14-695-2021, 2021
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First field data from a custom-built in situ instrument measuring hyperspectral (300–700 nm, 0.8 nm resolution) ambient atmospheric aerosol extinction are presented. The advantage of this capability is that it can be directly linked to other in situ techniques that measure physical and chemical properties of atmospheric aerosols. Second-order polynomials provided a better fit to the data than traditional power law fits, yielding greater discrimination among distinct ambient aerosol populations.
Carolyn E. Jordan, Ryan M. Stauffer, Brian T. Lamb, Michael Novak, Antonio Mannino, Ewan C. Crosbie, Gregory L. Schuster, Richard H. Moore, Charles H. Hudgins, Kenneth L. Thornhill, Edward L. Winstead, Bruce E. Anderson, Robert F. Martin, Michael A. Shook, Luke D. Ziemba, Andreas J. Beyersdorf, Claire E. Robinson, Chelsea A. Corr, and Maria A. Tzortziou
Atmos. Meas. Tech., 14, 715–736, https://doi.org/10.5194/amt-14-715-2021, https://doi.org/10.5194/amt-14-715-2021, 2021
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In situ measurements of ambient atmospheric aerosol hyperspectral (300–700 nm) optical properties (extinction, total absorption, water- and methanol-soluble absorption) were observed around the Korean peninsula. Such in situ observations provide a direct link between ambient aerosol optical properties and their physicochemical properties. The benefit of hyperspectral measurements is evident as simple mathematical functions could not fully capture the observed spectral detail of ambient aerosols.
Cyril Brunner and Zamin A. Kanji
Atmos. Meas. Tech., 14, 269–293, https://doi.org/10.5194/amt-14-269-2021, https://doi.org/10.5194/amt-14-269-2021, 2021
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Subvisual microscopic particles in the atmosphere are needed to act as seeds for cloud droplets or ice crystals to form. The microscopic particles, called ice-nucleating particles (INPs), form ice crystals and are rare, and their properties are not well understood, in part because measuring them is challenging and time consuming, and to date has not been automated. Here, we present the first online instrument that can continuously and autonomously measure INP concentration at 243 K.
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Short summary
Three online systems for measuring water-soluble brown carbon are compared. A mist chamber and two different particle-into-liquid samplers were deployed on separate research aircraft targeting wildfires and followed a similar detection method using a long-path liquid waveguide with a spectrometer to measure the light absorption from 300 to 700 nm. Detection limits, signal hysteresis and other sampling issues are compared, and further improvements of these liquid-based systems are provided.
Three online systems for measuring water-soluble brown carbon are compared. A mist chamber and...
