Articles | Volume 8, issue 10
https://doi.org/10.5194/amt-8-4521-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-8-4521-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
27 Oct 2015
Research article |
| 27 Oct 2015
The stability and calibration of water vapor isotope ratio measurements during long-term deployments
Department of Atmospheric and Oceanic Sciences, University of Colorado Boulder, Boulder, Colorado, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, Colorado, USA
now at: Joint Institute for the Study of the Atmosphere and Ocean, University of Washington, Seattle, Washington, USA
D. Noone
Department of Atmospheric and Oceanic Sciences, University of Colorado Boulder, Boulder, Colorado, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, Colorado, USA
College of Earth, Ocean, and Atmospheric Sciences, Oregon State University, Corvallis, Oregon, USA
M. Berkelhammer
Department of Earth and Environmental Sciences, University of Illinois at Chicago, Chicago, Illinois, USA
H. C. Steen-Larsen
Laboratoire des Sciences du Climat et de l'Environnement, Gif-sur-Yvette, France
P. Sato
Joint Institute for Marine and Atmospheric Research, NOAA, Hilo, Hawaii, USA
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Manuscript not accepted for further review
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Short summary
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The 4.2 ka event is generally characterized as an approximately 300-year period of major global climate anomaly. However, the climatic manifestation of this event remains unclear in the Indian monsoon domain. Our high-resolution and precisely dated speleothem record from Meghalaya, India, characterizes the event as consisting of a series of multi-decadal droughts between 3.9 and 4.0 ka rather than a singular pulse of multi-centennial drought as previously thought.
Minjie Zheng, Jesper Sjolte, Florian Adolphi, Bo Møllesøe Vinther, Hans Christian Steen-Larsen, Trevor James Popp, and Raimund Muscheler
Clim. Past, 14, 1067–1078, https://doi.org/10.5194/cp-14-1067-2018, https://doi.org/10.5194/cp-14-1067-2018, 2018
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We show the seasonal δ18O data from the NEEM site in northwestern Greenland over the last 150 years. We found that the NEEM summer δ18O signal correlates well with summer temperature in western coastal Greenland, while the NEEM winter δ18O signal correlates well with sea ice concentration in Baffin Bay. In contrast with the winter δ18O data from central/southern Greenland, we find no linkage of NEEM winter δ18O to winter NAO.
Mary E. Whelan, Sinikka T. Lennartz, Teresa E. Gimeno, Richard Wehr, Georg Wohlfahrt, Yuting Wang, Linda M. J. Kooijmans, Timothy W. Hilton, Sauveur Belviso, Philippe Peylin, Róisín Commane, Wu Sun, Huilin Chen, Le Kuai, Ivan Mammarella, Kadmiel Maseyk, Max Berkelhammer, King-Fai Li, Dan Yakir, Andrew Zumkehr, Yoko Katayama, Jérôme Ogée, Felix M. Spielmann, Florian Kitz, Bharat Rastogi, Jürgen Kesselmeier, Julia Marshall, Kukka-Maaria Erkkilä, Lisa Wingate, Laura K. Meredith, Wei He, Rüdiger Bunk, Thomas Launois, Timo Vesala, Johan A. Schmidt, Cédric G. Fichot, Ulli Seibt, Scott Saleska, Eric S. Saltzman, Stephen A. Montzka, Joseph A. Berry, and J. Elliott Campbell
Biogeosciences, 15, 3625–3657, https://doi.org/10.5194/bg-15-3625-2018, https://doi.org/10.5194/bg-15-3625-2018, 2018
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Measurements of the trace gas carbonyl sulfide (OCS) are helpful in quantifying photosynthesis at previously unknowable temporal and spatial scales. While CO2 is both consumed and produced within ecosystems, OCS is mostly produced in the oceans or from specific industries, and destroyed in plant leaves in proportion to CO2. This review summarizes the advancements we have made in the understanding of OCS exchange and applications to vital ecosystem water and carbon cycle questions.
Pirmin Philipp Ebner, Hans Christian Steen-Larsen, Barbara Stenni, Martin Schneebeli, and Aldo Steinfeld
The Cryosphere, 11, 1733–1743, https://doi.org/10.5194/tc-11-1733-2017, https://doi.org/10.5194/tc-11-1733-2017, 2017
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Stable water isotopes (δ18O) obtained from snow and ice samples from polar regions are used to reconstruct past climate variability. We present an experimental study on the effect on the snow isotopic composition by airflow through a snowpack in controlled laboratory conditions. The disequilibrium between snow and vapor isotopes changed the isotopic content of the snow. These measurements suggest that metamorphism and its history affect the snow isotopic composition.
Nathaniel B. Miller, Matthew D. Shupe, Christopher J. Cox, David Noone, P. Ola G. Persson, and Konrad Steffen
The Cryosphere, 11, 497–516, https://doi.org/10.5194/tc-11-497-2017, https://doi.org/10.5194/tc-11-497-2017, 2017
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A comprehensive observational dataset is assembled to investigate atmosphere–Greenland ice sheet interactions and characterize surface temperature variability. The amount the surface temperature warms, due to increases in cloud presence and/or elevated sun angle, varies throughout the annual cycle and is modulated by the responses of latent, sensible and ground heat fluxes. This observationally based study provides process-based relationships, which are useful for evaluation of climate models.
Christoph Florian Schaller, Johannes Freitag, Sepp Kipfstuhl, Thomas Laepple, Hans Christian Steen-Larsen, and Olaf Eisen
The Cryosphere, 10, 1991–2002, https://doi.org/10.5194/tc-10-1991-2016, https://doi.org/10.5194/tc-10-1991-2016, 2016
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Along a traverse through North Greenland in May 2015 we collected snow cores up to 2 m in depth and analyzed their properties (e.g., density). A new technique for this sampling and an adapted algorithm for comparing data sets from different positions and aligning stratigraphic features are presented. We find good agreement of the density layering in the snowpack over hundreds of kilometers. This allows the construction of a representative density profile that is statistically validated.
François Ritter, Hans Christian Steen-Larsen, Martin Werner, Valérie Masson-Delmotte, Anais Orsi, Melanie Behrens, Gerit Birnbaum, Johannes Freitag, Camille Risi, and Sepp Kipfstuhl
The Cryosphere, 10, 1647–1663, https://doi.org/10.5194/tc-10-1647-2016, https://doi.org/10.5194/tc-10-1647-2016, 2016
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We present successful continuous measurements of water vapor isotopes performed in Antarctica in January 2013. The interest is to understand the impact of the water vapor isotopic composition on the near-surface snow isotopes. Our study reveals a diurnal cycle in the snow isotopic composition in phase with the vapor. This finding suggests fractionation during the sublimation of the ice, which has an important consequence on the interpretation of water isotope variations in ice cores.
Mathieu Casado, Amaelle Landais, Valérie Masson-Delmotte, Christophe Genthon, Erik Kerstel, Samir Kassi, Laurent Arnaud, Ghislain Picard, Frederic Prie, Olivier Cattani, Hans-Christian Steen-Larsen, Etienne Vignon, and Peter Cermak
Atmos. Chem. Phys., 16, 8521–8538, https://doi.org/10.5194/acp-16-8521-2016, https://doi.org/10.5194/acp-16-8521-2016, 2016
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Climatic conditions in Concordia are very cold (−55 °C in average) and very dry, imposing difficult conditions to measure the water vapour isotopic composition. New developments in infrared spectroscopy enable now the measurement of isotopic composition in water vapour traces (down to 20 ppmv). Here we present the results results of a first campaign of measurement of isotopic composition of water vapour in Concordia, the site where the 800 000 years long ice core was drilled.
Mary E. Whelan, Timothy W. Hilton, Joseph A. Berry, Max Berkelhammer, Ankur R. Desai, and J. Elliott Campbell
Atmos. Chem. Phys., 16, 3711–3726, https://doi.org/10.5194/acp-16-3711-2016, https://doi.org/10.5194/acp-16-3711-2016, 2016
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We constructed a model of carbonyl sulfide soil exchange sufficient for predicting outcomes in terrestrial ecosystems. Empirical observations combined with soil gas exchange theory reveal simultaneous abiotic production and biotic uptake mechanisms. Measurement of atmospheric carbonyl sulfide is an emerging tool to quantify photosynthesis at important temporal and spatial scales.
V. Masson-Delmotte, H. C. Steen-Larsen, P. Ortega, D. Swingedouw, T. Popp, B. M. Vinther, H. Oerter, A. E. Sveinbjornsdottir, H. Gudlaugsdottir, J. E. Box, S. Falourd, X. Fettweis, H. Gallée, E. Garnier, V. Gkinis, J. Jouzel, A. Landais, B. Minster, N. Paradis, A. Orsi, C. Risi, M. Werner, and J. W. C. White
The Cryosphere, 9, 1481–1504, https://doi.org/10.5194/tc-9-1481-2015, https://doi.org/10.5194/tc-9-1481-2015, 2015
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The deep NEEM ice core provides the oldest Greenland ice core record, enabling improved understanding of the response of ice core records to local climate. Here, we focus on shallow ice cores providing a stack record of accumulation and water-stable isotopes spanning the past centuries. For the first time, we document the ongoing warming in a Greenland ice core. By combining our data with other Greenland ice cores and model results, we characterise the spatio-temporal patterns of variability.
H. C. Steen-Larsen, A. E. Sveinbjörnsdottir, A. J. Peters, V. Masson-Delmotte, M. P. Guishard, G. Hsiao, J. Jouzel, D. Noone, J. K. Warren, and J. W. C. White
Atmos. Chem. Phys., 14, 7741–7756, https://doi.org/10.5194/acp-14-7741-2014, https://doi.org/10.5194/acp-14-7741-2014, 2014
V. Bastrikov, H. C. Steen-Larsen, V. Masson-Delmotte, K. Gribanov, O. Cattani, J. Jouzel, and V. Zakharov
Atmos. Meas. Tech., 7, 1763–1776, https://doi.org/10.5194/amt-7-1763-2014, https://doi.org/10.5194/amt-7-1763-2014, 2014
J.-L. Bonne, V. Masson-Delmotte, O. Cattani, M. Delmotte, C. Risi, H. Sodemann, and H. C. Steen-Larsen
Atmos. Chem. Phys., 14, 4419–4439, https://doi.org/10.5194/acp-14-4419-2014, https://doi.org/10.5194/acp-14-4419-2014, 2014
H. C. Steen-Larsen, V. Masson-Delmotte, M. Hirabayashi, R. Winkler, K. Satow, F. Prié, N. Bayou, E. Brun, K. M. Cuffey, D. Dahl-Jensen, M. Dumont, M. Guillevic, S. Kipfstuhl, A. Landais, T. Popp, C. Risi, K. Steffen, B. Stenni, and A. E. Sveinbjörnsdottír
Clim. Past, 10, 377–392, https://doi.org/10.5194/cp-10-377-2014, https://doi.org/10.5194/cp-10-377-2014, 2014
H. C. Steen-Larsen, S. J. Johnsen, V. Masson-Delmotte, B. Stenni, C. Risi, H. Sodemann, D. Balslev-Clausen, T. Blunier, D. Dahl-Jensen, M. D. Ellehøj, S. Falourd, A. Grindsted, V. Gkinis, J. Jouzel, T. Popp, S. Sheldon, S. B. Simonsen, J. Sjolte, J. P. Steffensen, P. Sperlich, A. E. Sveinbjörnsdóttir, B. M. Vinther, and J. W. C. White
Atmos. Chem. Phys., 13, 4815–4828, https://doi.org/10.5194/acp-13-4815-2013, https://doi.org/10.5194/acp-13-4815-2013, 2013
D. Noone, C. Risi, A. Bailey, M. Berkelhammer, D. P. Brown, N. Buenning, S. Gregory, J. Nusbaumer, D. Schneider, J. Sykes, B. Vanderwende, J. Wong, Y. Meillier, and D. Wolfe
Atmos. Chem. Phys., 13, 1607–1623, https://doi.org/10.5194/acp-13-1607-2013, https://doi.org/10.5194/acp-13-1607-2013, 2013
Related subject area
Subject: Gases | Technique: In Situ Measurement | Topic: Data Processing and Information Retrieval
Intercomparison of fast airborne ozone instruments to measure eddy covariance fluxes: spatial variability in deposition at the ocean surface and evidence for cloud processing
Field assessments on the impact of CO2 concentration fluctuations along with complex-terrain flows on the estimation of the net ecosystem exchange of temperate forests
Multi-instrumental analysis of ozone vertical profiles and total columns in South America: comparison between subtropical and equatorial latitudes
Transferability of machine-learning-based global calibration models for NO2 and NO low-cost sensors
Direct high-precision radon quantification for interpreting high frequency greenhouse gas measurements
Detection and long-term quantification of methane emissions from an active landfill
Research of low-cost air quality monitoring models with different machine learning algorithms
New insights from the Jülich Ozone Sonde Intercomparison Experiment: calibration functions traceable to one ozone reference instrument
Identification of spikes in continuous ground-based in situ time series of CO2, CH4 and CO: an extended experiment within the European ICOS Atmosphere network
Data treatment and corrections for estimating H2O and CO2 isotope fluxes from high-frequency observations
Measurements of volatile organic compounds in ambient air by gas-chromatography and real-time Vocus PTR-TOF-MS: calibrations, instrument background corrections, and introducing a PTR Data Toolkit
Development of low-cost air quality stations for next-generation monitoring networks: calibration and validation of NO2 and O3 sensors
Detecting plumes in mobile air quality monitoring time series with density-based spatial clustering of applications with noise
Characterising the methane gas and environmental response of the Figaro Taguchi Gas Sensor (TGS) 2611-E00
Reducing errors on estimates of the carbon uptake period based on time series of atmospheric CO2
Generalized Kendrick analysis for improved visualization of atmospheric mass spectral data
Determination of NOx emission rates of inland ships from onshore measurements
Data quality enhancement for field experiments in atmospheric chemistry via sequential Monte Carlo filters
A flexible algorithm for network design based on information theory
Real-world wintertime CO, N2O, and CO2 emissions of a central European village
Evaluation of two common source estimation measurement strategies using large-eddy simulation of plume dispersion under neutral atmospheric conditions
Machine learning techniques to improve the field performance of low-cost air quality sensors
Estimation of sulfuric acid concentration using ambient ion composition and concentration data obtained with atmospheric pressure interface time-of-flight ion mass spectrometer
Importance of the Webb, Pearman, and Leuning (WPL) correction for the measurement of small CO2 fluxes
Unravelling a black box: an open-source methodology for the field calibration of small air quality sensors
An algorithm to detect non-background signals in greenhouse gas time series from European tall tower and mountain stations
Mobile atmospheric measurements and local-scale inverse estimation of the location and rates of brief CH4 and CO2 releases from point sources
SIBaR: a new method for background quantification and removal from mobile air pollution measurements
Machine learning calibration of low-cost NO2 and PM10 sensors: non-linear algorithms and their impact on site transferability
The high-frequency response correction of eddy covariance fluxes – Part 2: An experimental approach for analysing noisy measurements of small fluxes
The high-frequency response correction of eddy covariance fluxes – Part 1: An experimental approach and its interdependence with the time-lag estimation
Uncertainty of hourly-average concentration values derived from non-continuous measurements
Emissions relationships in western forest fire plumes – Part 1: Reducing the effect of mixing errors on emission factors
A new method to correct the electrochemical concentration cell (ECC) ozonesonde time response and its implications for “background current” and pump efficiency
Monitoring the compliance of sailing ships with fuel sulfur content regulations using unmanned aerial vehicle (UAV) measurements of ship emissions in open water
High-resolution mapping of urban air quality with heterogeneous observations: a new methodology and its application to Amsterdam
Towards standardized processing of eddy covariance flux measurements of carbonyl sulfide
Integration and calibration of non-dispersive infrared (NDIR) CO2 low-cost sensors and their operation in a sensor network covering Switzerland
Correcting the impact of the isotope composition on the mixing ratio dependency of water vapour isotope measurements with cavity ring-down spectrometers
Correcting high-frequency losses of reactive nitrogen flux measurements
Surface flux estimates derived from UAS-based mole fraction measurements by means of a nocturnal boundary layer budget approach
InnFLUX – an open-source code for conventional and disjunct eddy covariance analysis of trace gas measurements: an urban test case
Accurate measurements of atmospheric carbon dioxide and methane mole fractions at the Siberian coastal site Ambarchik
Traffic-related air pollution near roadways: discerning local impacts from background
Bayesian atmospheric tomography for detection and quantification of methane emissions: application to data from the 2015 Ginninderra release experiment
Evaluating and improving the reliability of gas-phase sensor system calibrations across new locations for ambient measurements and personal exposure monitoring
A novel approach for simple statistical analysis of high-resolution mass spectra
Application of open-path Fourier transform infrared spectroscopy (OP-FTIR) to measure greenhouse gas concentrations from agricultural fields
Flexible approach for quantifying average long-term changes and seasonal cycles of tropospheric trace species
The ICAD (iterative cavity-enhanced DOAS) method
Randall Chiu, Florian Obersteiner, Alessandro Franchin, Teresa Campos, Adriana Bailey, Christopher Webster, Andreas Zahn, and Rainer Volkamer
Atmos. Meas. Tech., 17, 5731–5746, https://doi.org/10.5194/amt-17-5731-2024, https://doi.org/10.5194/amt-17-5731-2024, 2024
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The ozone sink into oceans and marine clouds is seldom studied and highly uncertain. Calculations suggest O3 destruction at aqueous surfaces (ocean, droplets) may be strongly accelerated, but field evidence is missing. Here we compare three fast airborne O3 instruments to measure eddy covariance fluxes of O3 over the remote ocean, in clear and cloudy air. We find O3 fluxes below clouds are consistently directed into clouds, while O3 fluxes into oceans are much smaller and spatially variable.
Dexiong Teng, Jiaojun Zhu, Tian Gao, Fengyuan Yu, Yuan Zhu, Xinhua Zhou, and Bai Yang
Atmos. Meas. Tech., 17, 5581–5599, https://doi.org/10.5194/amt-17-5581-2024, https://doi.org/10.5194/amt-17-5581-2024, 2024
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Dense canopy weakens turbulent mixing, leading to significant CO2 storage (Fs), a key part of net ecosystem exchange (NEE) measured using eddy covariance. Gust-biased Fs measurements complicate NEE estimation in forests with complex terrain. We analyzed gust-induced CO2 fluctuations and their impact on Fs. Fs and its contribution to NEE can be explained by terrain complexity and turbulent mixing. This work highlights how gusts over complex terrain affect the Fs and NEE measurements.
Gabriela Dornelles Bittencourt, Hassan Bencherif, Damaris Kirsch Pinheiro, Nelson Begue, Lucas Vaz Peres, José Valentin Bageston, Douglas Lima de Bem, Francisco Raimundo da Silva, and Tristan Millet
Atmos. Meas. Tech., 17, 5201–5220, https://doi.org/10.5194/amt-17-5201-2024, https://doi.org/10.5194/amt-17-5201-2024, 2024
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The study examines the behavior of ozone at equatorial and subtropical latitudes in South America, in a multi-instrumental analysis. The methodology applied used ozonesondes (SHADOZ/NASA) and satellite data (TIMED/SABER), as well as analysis with ground-based and satellite instruments, allowing a more in-depth study at both latitudes. The main motivation is to understand how latitudinal differences in the observation of ozone content can interfere with the behavior of this trace gas.
Ayah Abu-Hani, Jia Chen, Vigneshkumar Balamurugan, Adrian Wenzel, and Alessandro Bigi
Atmos. Meas. Tech., 17, 3917–3931, https://doi.org/10.5194/amt-17-3917-2024, https://doi.org/10.5194/amt-17-3917-2024, 2024
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This study examined the transferability of machine learning calibration models among low-cost sensor units targeting NO2 and NO. The global models were evaluated under similar and different emission conditions. To counter cross-sensitivity, the study proposed integrating O3 measurements from nearby reference stations, in Switzerland. The models show substantial improvement when O3 measurements are incorporated, which is more pronounced when in regions with elevated O3 concentrations.
Dafina Kikaj, Edward Chung, Alan D. Griffiths, Scott D. Chambers, Grant Foster, Angelina Wenger, Penelope Pickers, Chris Rennick, Simon O'Doherty, Joseph Pitt, Kieran Stanley, Dickon Young, Leigh S. Fleming, Karina Adcock, and Tim Arnold
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-54, https://doi.org/10.5194/amt-2024-54, 2024
Revised manuscript accepted for AMT
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We present a protocol to enhance confidence in reported atmospheric radon measurements, enabling direct comparisons between sites and integration with GHG measurements. Radon, a natural atmospheric tracer, provides an independent evaluation of transport model performance. The standardized approach ensures radon's use as a metric for model evaluation. Applicable beyond UK observatories, this protocol can benefit larger networks like ICOS or GAW, advancing atmospheric studies worldwide.
Pramod Kumar, Christopher Caldow, Grégoire Broquet, Adil Shah, Olivier Laurent, Camille Yver-Kwok, Sebastien Ars, Sara Defratyka, Susan Warao Gichuki, Luc Lienhardt, Mathis Lozano, Jean-Daniel Paris, Felix Vogel, Caroline Bouchet, Elisa Allegrini, Robert Kelly, Catherine Juery, and Philippe Ciais
Atmos. Meas. Tech., 17, 1229–1250, https://doi.org/10.5194/amt-17-1229-2024, https://doi.org/10.5194/amt-17-1229-2024, 2024
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This study presents a series of mobile measurement campaigns to monitor the CH4 emissions from an active landfill. These measurements are processed using a Gaussian plume model and atmospheric inversion techniques to quantify the landfill CH4 emissions. The methane emission estimates range between ~0.4 and ~7 t CH4 per day, and their variations are analyzed. The robustness of the estimates is assessed depending on the distance of the measurements from the potential sources in the landfill.
Gang Wang, Chunlai Yu, Kai Guo, Haisong Guo, and Yibo Wang
Atmos. Meas. Tech., 17, 181–196, https://doi.org/10.5194/amt-17-181-2024, https://doi.org/10.5194/amt-17-181-2024, 2024
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A low-cost multi-parameter air quality monitoring system (LCS) based on different machine learning algorithms is proposed. The LCS can measure particulate matter (PM) and gas pollutants simultaneously. The performance of the different algorithms (RF, MLR, KNN, BP, GA-BP) with the parameters such as R2 and RMSE are compared and discussed. These measurements indicate the LCS based on the machine learning algorithms can be used to predict the concentrations of PM and gas pollution.
Herman G. J. Smit, Deniz Poyraz, Roeland Van Malderen, Anne M. Thompson, David W. Tarasick, Ryan M. Stauffer, Bryan J. Johnson, and Debra E. Kollonige
Atmos. Meas. Tech., 17, 73–112, https://doi.org/10.5194/amt-17-73-2024, https://doi.org/10.5194/amt-17-73-2024, 2024
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This paper revisits fundamentals of ECC ozonesonde measurements to develop and characterize a methodology to correct for the fast and slow time responses using the JOSIE (Jülich Ozone Sonde Intercomparison Experiment) simulation chamber data. Comparing the new corrected ozonesonde profiles to an accurate ozone UV photometer (OPM) as reference allows us to evaluate the time response correction (TRC) method and to determine calibration functions traceable to one reference with 5 % uncertainty.
Paolo Cristofanelli, Cosimo Fratticioli, Lynn Hazan, Mali Chariot, Cedric Couret, Orestis Gazetas, Dagmar Kubistin, Antti Laitinen, Ari Leskinen, Tuomas Laurila, Matthias Lindauer, Giovanni Manca, Michel Ramonet, Pamela Trisolino, and Martin Steinbacher
Atmos. Meas. Tech., 16, 5977–5994, https://doi.org/10.5194/amt-16-5977-2023, https://doi.org/10.5194/amt-16-5977-2023, 2023
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We investigated the application of two automatic methods for detecting spikes due to local emissions in greenhouse gas (GHG) observations at a subset of sites from the ICOS Atmosphere network. We analysed the sensitivity to the spike frequency of using different methods and settings. We documented the impact of the de-spiking on different temporal aggregations (i.e. hourly, monthly and seasonal averages) of CO2, CH4 and CO 1 min time series.
Robbert P. J. Moonen, Getachew A. Adnew, Oscar K. Hartogensis, Jordi Vilà-Guerau de Arellano, David J. Bonell Fontas, and Thomas Röckmann
Atmos. Meas. Tech., 16, 5787–5810, https://doi.org/10.5194/amt-16-5787-2023, https://doi.org/10.5194/amt-16-5787-2023, 2023
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Isotope fluxes allow for net ecosystem gas exchange fluxes to be partitioned into sub-components like plant assimilation, respiration and transpiration, which can help us better understand the environmental drivers of each partial flux. We share the results of a field campaign isotope fluxes were derived using a combination of laser spectroscopy and eddy covariance. We found lag times and high frequency signal loss in the isotope fluxes we derived and present methods to correct for both.
Andrew R. Jensen, Abigail R. Koss, Ryder B. Hales, and Joost A. de Gouw
Atmos. Meas. Tech., 16, 5261–5285, https://doi.org/10.5194/amt-16-5261-2023, https://doi.org/10.5194/amt-16-5261-2023, 2023
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Quantification of a wide range of volatile organic compounds by proton-transfer-reaction mass spectrometry (PTR-MS) can be achieved with direct calibration of only a subset of compounds, characterization of instrument response, and simple reaction kinetics. We characterized our Vocus PTR-MS and developed a toolkit as a guide through this process. A catalytic zero air generator provided the lowest detection limits, and short, frequent calibrations informed variability in instrument response.
Alice Cavaliere, Lorenzo Brilli, Bianca Patrizia Andreini, Federico Carotenuto, Beniamino Gioli, Tommaso Giordano, Marco Stefanelli, Carolina Vagnoli, Alessandro Zaldei, and Giovanni Gualtieri
Atmos. Meas. Tech., 16, 4723–4740, https://doi.org/10.5194/amt-16-4723-2023, https://doi.org/10.5194/amt-16-4723-2023, 2023
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We assessed calibration models for two low-cost stations equipped with O3 and NO2 metal oxide sensors. Environmental parameters had improved accuracy in linear and black box models. Moreover, interpretability methods like SHapley Additive exPlanations helped identify the physical patterns and potential problems of these models in a field validation. Results showed both sensors performed well with the same linear model form, but unique coefficients were required for intersensor variability.
Blake Actkinson and Robert J. Griffin
Atmos. Meas. Tech., 16, 3547–3559, https://doi.org/10.5194/amt-16-3547-2023, https://doi.org/10.5194/amt-16-3547-2023, 2023
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Data collected using air quality instrumentation deployed on automobiles and driven repeatedly in Houston neighborhoods are analyzed using a novel machine learning technique. The aim is to separate large plumes from the rest of the data in order to identify the sources of the highest levels of the pollutants. The number and nature of these plumes are characterized spatially and can be linked to emissions from different types of motor vehicles.
Adil Shah, Olivier Laurent, Luc Lienhardt, Grégoire Broquet, Rodrigo Rivera Martinez, Elisa Allegrini, and Philippe Ciais
Atmos. Meas. Tech., 16, 3391–3419, https://doi.org/10.5194/amt-16-3391-2023, https://doi.org/10.5194/amt-16-3391-2023, 2023
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As methane (CH4) contributes to global warming, more CH4 measurements are required to better characterise source emissions. Hence, we tested a cheap CH4 sensor for 338 d of landfill sampling. We derived an excellent CH4 response model in a stable environment. However, different types of air with the same CH4 level had diverse sensor responses. We characterised temperature and water vapour response but could not replicate field sampling. Thus, other species may cause sensor interactions.
Theertha Kariyathan, Ana Bastos, Julia Marshall, Wouter Peters, Pieter Tans, and Markus Reichstein
Atmos. Meas. Tech., 16, 3299–3312, https://doi.org/10.5194/amt-16-3299-2023, https://doi.org/10.5194/amt-16-3299-2023, 2023
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The timing and duration of the carbon uptake period (CUP) are sensitive to the occurrence of major phenological events, which are influenced by recent climate change. This study presents an ensemble-based approach for quantifying the timing and duration of the CUP and their uncertainty when derived from atmospheric CO2 measurements with noise and gaps. The CUP metrics derived with the approach are more robust and have less uncertainty than when estimated with the conventional methods.
Mitchell W. Alton, Harald J. Stark, Manjula R. Canagaratna, and Eleanor C. Browne
Atmos. Meas. Tech., 16, 3273–3282, https://doi.org/10.5194/amt-16-3273-2023, https://doi.org/10.5194/amt-16-3273-2023, 2023
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Mass spectrometric measurements of atmospheric composition routinely detect hundreds of different ions of varying chemical composition, creating challenges for visualization and data interpretation. We present a new analysis technique to facilitate visualization, while providing greater chemical insight. Additionally, it can aid in identifying the chemical composition of ions. A graphical user interface for performing the analysis is introduced and freely available, enabling broad applications.
Kai Krause, Folkard Wittrock, Andreas Richter, Dieter Busch, Anton Bergen, John P. Burrows, Steffen Freitag, and Olesia Halbherr
Atmos. Meas. Tech., 16, 1767–1787, https://doi.org/10.5194/amt-16-1767-2023, https://doi.org/10.5194/amt-16-1767-2023, 2023
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Inland shipping is an important source of nitrogen oxides (NOx). The amount of emitted NOx depends on the characteristics of the individual vessels and the traffic density. Ship emissions are often characterised by the amount of emitted NOx per unit of burnt fuel, and further knowledge about fuel consumption is needed to quantify the total emissions caused by ship traffic. In this study, a new approach to derive absolute emission rates (in g s−1) from onshore measurements is presented.
Lenard L. Röder, Patrick Dewald, Clara M. Nussbaumer, Jan Schuladen, John N. Crowley, Jos Lelieveld, and Horst Fischer
Atmos. Meas. Tech., 16, 1167–1178, https://doi.org/10.5194/amt-16-1167-2023, https://doi.org/10.5194/amt-16-1167-2023, 2023
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Field experiments in atmospheric chemistry provide insights into chemical interactions of our atmosphere. However, high data coverage and accuracy are needed to enable further analysis. In this study, we explore a statistical method that combines knowledge about the chemical reactions with information from measurements to increase the quality of field experiment datasets. We test the algorithm for several applications and discuss limitations that depend on the specific variable and the dynamics.
Rona L. Thompson and Ignacio Pisso
Atmos. Meas. Tech., 16, 235–246, https://doi.org/10.5194/amt-16-235-2023, https://doi.org/10.5194/amt-16-235-2023, 2023
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Atmospheric networks are used for monitoring air quality and greenhouse gases and can provide essential information about the sources and sinks. The design of the network, specifically where to place the observations, is a critical question in order to maximize the information provided while minimizing the cost. Here, a novel method of designing atmospheric networks is presented with two examples, one on monitoring sources of methane and the second on monitoring fossil fuel emissions of CO2.
László Haszpra, Zoltán Barcza, Zita Ferenczi, Roland Hollós, Anikó Kern, and Natascha Kljun
Atmos. Meas. Tech., 15, 5019–5031, https://doi.org/10.5194/amt-15-5019-2022, https://doi.org/10.5194/amt-15-5019-2022, 2022
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A novel approach is used for the determination of greenhouse gas (GHG) emissions of small rural settlements, which may significantly differ from those of urban regions and have hardly been studied yet. Among other results, it turned out that wintertime nitrous oxide emission is significantly underestimated in the official emission inventories. Given the large number of such settlements, the underestimation may also distort the national total emission values reported to international databases.
Anja Ražnjević, Chiel van Heerwaarden, and Maarten Krol
Atmos. Meas. Tech., 15, 3611–3628, https://doi.org/10.5194/amt-15-3611-2022, https://doi.org/10.5194/amt-15-3611-2022, 2022
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We evaluate two widely used observational techniques (Other Test Method (OTM) 33A and car drive-bys) that estimate point source gas emissions. We performed our analysis on high-resolution plume dispersion simulation. For car drive-bys we found that at least 15 repeated measurements were needed to get within 40 % of the true emissions. OTM 33A produced large errors in estimation (50 %–200 %) due to its sensitivity to dispersion coefficients and underlying simplifying assumptions.
Tony Bush, Nick Papaioannou, Felix Leach, Francis D. Pope, Ajit Singh, G. Neil Thomas, Brian Stacey, and Suzanne Bartington
Atmos. Meas. Tech., 15, 3261–3278, https://doi.org/10.5194/amt-15-3261-2022, https://doi.org/10.5194/amt-15-3261-2022, 2022
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Poor air quality is a human health risk which demands high-spatiotemporal-resolution monitoring data to manage. Low-cost air quality sensors present a convenient pathway to delivering these needs, compared to traditional methods, but bring methodological challenges which can limit operational ability. In this study within Oxford, UK, we develop machine learning methods to improve the quality of low-cost sensors for NO2, PM10 (particulate matter) and PM2.5 and demonstrate their effectiveness.
Lisa J. Beck, Siegfried Schobesberger, Mikko Sipilä, Veli-Matti Kerminen, and Markku Kulmala
Atmos. Meas. Tech., 15, 1957–1965, https://doi.org/10.5194/amt-15-1957-2022, https://doi.org/10.5194/amt-15-1957-2022, 2022
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Sulfuric acid is known to be a main compound in atmospheric new particle formation. Yet, its concentration is very low, which leads to challenges in detecting it. In our study, we derive the sulfuric acid concentration from measurements of ambient ions with a mass spectrometer. Our validation shows that the theoretical approach using the bisulfate ion and its clusters with H2SO4 captures the sulfuric acid concentration very well during daytime.
Katharina Jentzsch, Julia Boike, and Thomas Foken
Atmos. Meas. Tech., 14, 7291–7296, https://doi.org/10.5194/amt-14-7291-2021, https://doi.org/10.5194/amt-14-7291-2021, 2021
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Very small CO2 fluxes are measured at night in Arctic regions. If the sensible heat flux is not close to zero under these conditions, the WPL correction will take values on the order of the flux. A special quality control is proposed for these cases.
Seán Schmitz, Sherry Towers, Guillermo Villena, Alexandre Caseiro, Robert Wegener, Dieter Klemp, Ines Langer, Fred Meier, and Erika von Schneidemesser
Atmos. Meas. Tech., 14, 7221–7241, https://doi.org/10.5194/amt-14-7221-2021, https://doi.org/10.5194/amt-14-7221-2021, 2021
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The last 2 decades have seen substantial technological advances in the development of low-cost air pollution instruments. This study introduces a seven-step methodology for the field calibration of low-cost sensors with user-friendly guidelines, open-access code, and a discussion of common barriers. Our goal with this work is to push for standardized reporting of methods, make critical data processing steps clear for users, and encourage responsible use in the scientific community and beyond.
Alex Resovsky, Michel Ramonet, Leonard Rivier, Jerome Tarniewicz, Philippe Ciais, Martin Steinbacher, Ivan Mammarella, Meelis Mölder, Michal Heliasz, Dagmar Kubistin, Matthias Lindauer, Jennifer Müller-Williams, Sebastien Conil, and Richard Engelen
Atmos. Meas. Tech., 14, 6119–6135, https://doi.org/10.5194/amt-14-6119-2021, https://doi.org/10.5194/amt-14-6119-2021, 2021
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We present a technical description of a statistical methodology for extracting synoptic- and seasonal-length anomalies from greenhouse gas time series. The definition of what represents an anomalous signal is somewhat subjective, which we touch on throughout the paper. We show, however, that the method performs reasonably well in extracting portions of time series influenced by significant North Atlantic Oscillation weather episodes and continent-wide terrestrial biospheric aberrations.
Pramod Kumar, Grégoire Broquet, Camille Yver-Kwok, Olivier Laurent, Susan Gichuki, Christopher Caldow, Ford Cropley, Thomas Lauvaux, Michel Ramonet, Guillaume Berthe, Frédéric Martin, Olivier Duclaux, Catherine Juery, Caroline Bouchet, and Philippe Ciais
Atmos. Meas. Tech., 14, 5987–6003, https://doi.org/10.5194/amt-14-5987-2021, https://doi.org/10.5194/amt-14-5987-2021, 2021
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This study presents a simple atmospheric inversion modeling framework for the localization and quantification of unknown CH4 and CO2 emissions from point sources based on near-surface mobile concentration measurements and a Gaussian plume dispersion model. It is applied for the estimate of a series of brief controlled releases of CH4 and CO2 with a wide range of rates during the TOTAL TADI-2018 experiment. Results indicate a ~10 %–40 % average error on the estimate of the release rates.
Blake Actkinson, Katherine Ensor, and Robert J. Griffin
Atmos. Meas. Tech., 14, 5809–5821, https://doi.org/10.5194/amt-14-5809-2021, https://doi.org/10.5194/amt-14-5809-2021, 2021
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This paper describes the development of a new method used to estimate background from mobile monitoring time series. The method is tested on a previously published dataset, applied to an extensive mobile dataset, and compared with other previously published techniques used to estimate background. The results suggest that the method is a promising framework for background estimation.
Peer Nowack, Lev Konstantinovskiy, Hannah Gardiner, and John Cant
Atmos. Meas. Tech., 14, 5637–5655, https://doi.org/10.5194/amt-14-5637-2021, https://doi.org/10.5194/amt-14-5637-2021, 2021
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Machine learning (ML) calibration techniques could be an effective way to improve the performance of low-cost air pollution sensors. Here we provide novel insights from case studies within the urban area of London, UK, where we compared the performance of three ML techniques to calibrate low-cost measurements of NO2 and PM10. In particular, we highlight the key issue of the method-dependent robustness in maintaining calibration skill after transferring sensors to different measurement sites.
Toprak Aslan, Olli Peltola, Andreas Ibrom, Eiko Nemitz, Üllar Rannik, and Ivan Mammarella
Atmos. Meas. Tech., 14, 5089–5106, https://doi.org/10.5194/amt-14-5089-2021, https://doi.org/10.5194/amt-14-5089-2021, 2021
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Vertical turbulent fluxes of gases measured by the eddy covariance (EC) technique are subject to high-frequency losses. There are different methods used to describe this low-pass filtering effect and to correct the measured fluxes. In this study, we analysed the systematic uncertainty related to this correction for various attenuation and signal-to-noise ratios. A new and robust transfer function method is finally proposed.
Olli Peltola, Toprak Aslan, Andreas Ibrom, Eiko Nemitz, Üllar Rannik, and Ivan Mammarella
Atmos. Meas. Tech., 14, 5071–5088, https://doi.org/10.5194/amt-14-5071-2021, https://doi.org/10.5194/amt-14-5071-2021, 2021
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Gas fluxes measured by the eddy covariance (EC) technique are subject to filtering due to non-ideal instrumentation. For linear first-order systems this filtering causes also a time lag between vertical wind speed and gas signal which is additional to the gas travel time in the sampling line. The effect of this additional time lag on EC fluxes is ignored in current EC data processing routines. Here we show that this oversight biases EC fluxes and hence propose an approach to rectify this bias.
László Haszpra and Ernő Prácser
Atmos. Meas. Tech., 14, 3561–3571, https://doi.org/10.5194/amt-14-3561-2021, https://doi.org/10.5194/amt-14-3561-2021, 2021
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Most of the tall-tower greenhouse gas observatories apply a single gas analyzer for the sequential sampling of several intakes along the tower. The non-continuous sampling at each intake introduces excess uncertainty to the calculated hourly-average concentrations used in several applications. Based on real-world measurements, the paper systematically assesses this type of uncertainty.
Robert B. Chatfield, Meinrat O. Andreae, ARCTAS Science Team, and SEAC4RS Science Team
Atmos. Meas. Tech., 13, 7069–7096, https://doi.org/10.5194/amt-13-7069-2020, https://doi.org/10.5194/amt-13-7069-2020, 2020
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Forest burning affects air pollution and global climate. A NASA aircraft studied fire emissions including the Rim Fire near Yosemite. We found frequent confusions between the actual fire emission factors and other effects on the air samples. Effects on CO2 and CO can originate far upwind; the gases can mix variably into a smoke plume. We devised a theory of constant features in plumes. A statistical mixed-effects analysis of a co-emitted tracers model disentangles such mixing from fire effects.
Holger Vömel, Herman G. J. Smit, David Tarasick, Bryan Johnson, Samuel J. Oltmans, Henry Selkirk, Anne M. Thompson, Ryan M. Stauffer, Jacquelyn C. Witte, Jonathan Davies, Roeland van Malderen, Gary A. Morris, Tatsumi Nakano, and Rene Stübi
Atmos. Meas. Tech., 13, 5667–5680, https://doi.org/10.5194/amt-13-5667-2020, https://doi.org/10.5194/amt-13-5667-2020, 2020
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The time response of electrochemical concentration cell (ECC) ozonesondes points to at least two distinct reaction pathways with time constants of approximately 20 s and 25 min. Properly considering these time constants eliminates the need for a poorly defined "background" and allows reducing ad hoc corrections based on laboratory tests. This reduces the uncertainty of ECC ozonesonde measurements throughout the profile and especially in regions of low ozone and strong gradients of ozone.
Fan Zhou, Liwei Hou, Rui Zhong, Wei Chen, Xunpeng Ni, Shengda Pan, Ming Zhao, and Bowen An
Atmos. Meas. Tech., 13, 4899–4909, https://doi.org/10.5194/amt-13-4899-2020, https://doi.org/10.5194/amt-13-4899-2020, 2020
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On 15 July 2019, using an unmanned aerial vehicle (UAV), maritime authorities ferreted out a sailing ship whose fuel sulfur content (FSC) failed to meet Chinese regulations. This was the first time that a sailing ship had been caught for having failed the FSC regulations in China. The UAV system, method, and monitoring result utilized are discussed in this paper. We recommend that emissions from sailing ships be monitored more often in the open water in the future.
Bas Mijling
Atmos. Meas. Tech., 13, 4601–4617, https://doi.org/10.5194/amt-13-4601-2020, https://doi.org/10.5194/amt-13-4601-2020, 2020
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Many cities are experimenting with networks of low-cost sensors, complementary to their reference stations. Often the observations are published as dots on a map, as spatial interpolation is far from trivial. A new methodology to assimilate observations of different accuracy in a generic urban-air-quality model is introduced. It can be used for mapping local air quality based on reference measurements only or as a framework to integrate low-cost measurements next to official measurements.
Kukka-Maaria Kohonen, Pasi Kolari, Linda M. J. Kooijmans, Huilin Chen, Ulli Seibt, Wu Sun, and Ivan Mammarella
Atmos. Meas. Tech., 13, 3957–3975, https://doi.org/10.5194/amt-13-3957-2020, https://doi.org/10.5194/amt-13-3957-2020, 2020
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Biosphere–atmosphere gas exchange (flux) measurements of carbonyl sulfide (COS) are becoming popular for estimating biospheric photosynthesis. To compare COS flux measurements across different measurement sites, we need standardized protocols for data processing. We analyze how various data processing steps affect the calculated COS flux and how they differ from carbon dioxide (CO2) flux processing steps, and we aim to settle on a set of recommended protocols for COS flux calculation.
Michael Müller, Peter Graf, Jonas Meyer, Anastasia Pentina, Dominik Brunner, Fernando Perez-Cruz, Christoph Hüglin, and Lukas Emmenegger
Atmos. Meas. Tech., 13, 3815–3834, https://doi.org/10.5194/amt-13-3815-2020, https://doi.org/10.5194/amt-13-3815-2020, 2020
Yongbiao Weng, Alexandra Touzeau, and Harald Sodemann
Atmos. Meas. Tech., 13, 3167–3190, https://doi.org/10.5194/amt-13-3167-2020, https://doi.org/10.5194/amt-13-3167-2020, 2020
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We find that the known mixing ratio dependence of laser spectrometers for water vapour isotope measurements varies with isotope composition. We have developed a scheme to correct for this isotope-composition-dependent bias. The correction is most substantial at low mixing ratios. Stability tests indicate that the first-order dependency is a constant instrument characteristic. Water vapour isotope measurements at low mixing ratios can now be corrected by following our proposed procedure.
Pascal Wintjen, Christof Ammann, Frederik Schrader, and Christian Brümmer
Atmos. Meas. Tech., 13, 2923–2948, https://doi.org/10.5194/amt-13-2923-2020, https://doi.org/10.5194/amt-13-2923-2020, 2020
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With recent technological advances it is now possible to measure the exchange of trace gases between the land surface and the atmosphere. When using the so-called eddy-covariance method, certain corrections need to be applied to account for attenuation in the flux signal. These losses were found to be setup- and site-specific and can be up to 38 % for reactive nitrogen fluxes. We evaluated five different methods and recommend using an empirical version with locally measured cospectra.
Martin Kunz, Jost V. Lavric, Rainer Gasche, Christoph Gerbig, Richard H. Grant, Frank-Thomas Koch, Marcus Schumacher, Benjamin Wolf, and Matthias Zeeman
Atmos. Meas. Tech., 13, 1671–1692, https://doi.org/10.5194/amt-13-1671-2020, https://doi.org/10.5194/amt-13-1671-2020, 2020
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The nocturnal boundary layer (NBL) budget method enables the quantification of gas fluxes between ecosystems and the atmosphere under nocturnal stable stratification, a condition under which standard approaches struggle. However, up to now the application of the NBL method has been limited by difficulties in obtaining the required measurements. We show how an unmanned aircraft system (UAS) equipped with a carbon dioxide analyser can make this method more accessible.
Marcus Striednig, Martin Graus, Tilmann D. Märk, and Thomas G. Karl
Atmos. Meas. Tech., 13, 1447–1465, https://doi.org/10.5194/amt-13-1447-2020, https://doi.org/10.5194/amt-13-1447-2020, 2020
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The current work summarizes a long-term effort to provide an open-source code for the analysis of turbulent fluctuations of trace gases in the atmosphere by eddy covariance and disjunct eddy covariance, with a special focus on reactive gases that participate in atmospheric chemistry. The performance of the code is successfully evaluated based on measurements of minute fluxes of non-methane volatile organic compounds into the urban atmosphere.
Friedemann Reum, Mathias Göckede, Jost V. Lavric, Olaf Kolle, Sergey Zimov, Nikita Zimov, Martijn Pallandt, and Martin Heimann
Atmos. Meas. Tech., 12, 5717–5740, https://doi.org/10.5194/amt-12-5717-2019, https://doi.org/10.5194/amt-12-5717-2019, 2019
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We present continuous in situ measurements of atmospheric CO2 and CH4 mole fractions at the new station Ambarchik, located in northeastern Siberia. We describe the site, measurements and quality control, characterize the signals in comparison with data from Barrow, Alaska, and show which regions the measurements are sensitive to. Ambarchik data are available upon request.
Nathan Hilker, Jonathan M. Wang, Cheol-Heon Jeong, Robert M. Healy, Uwayemi Sofowote, Jerzy Debosz, Yushan Su, Michael Noble, Anthony Munoz, Geoff Doerksen, Luc White, Céline Audette, Dennis Herod, Jeffrey R. Brook, and Greg J. Evans
Atmos. Meas. Tech., 12, 5247–5261, https://doi.org/10.5194/amt-12-5247-2019, https://doi.org/10.5194/amt-12-5247-2019, 2019
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Increased interest in monitoring air quality near roadways, combined with traffic's often unclear contribution to elevated concentrations, has created a need for better interpretation of these data. Using 2 years of measurements collected during a near-road monitoring project in Canada, this paper contrasts three methods for estimating the fraction of roadside pollution resulting from on-road traffic. Robustness of these methods was compared with tandem measurements at background locations.
Laura Cartwright, Andrew Zammit-Mangion, Sangeeta Bhatia, Ivan Schroder, Frances Phillips, Trevor Coates, Karita Negandhi, Travis Naylor, Martin Kennedy, Steve Zegelin, Nick Wokker, Nicholas M. Deutscher, and Andrew Feitz
Atmos. Meas. Tech., 12, 4659–4676, https://doi.org/10.5194/amt-12-4659-2019, https://doi.org/10.5194/amt-12-4659-2019, 2019
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Despite extensive research, emission detection and quantification of greenhouse gases (GHGs) remain an open problem. This article presents a novel statistical framework for detecting and quantifying methane emissions and showcases its efficacy on data collected from different instruments in the 2015 Ginninderra controlled-release experiment. The developed techniques can be used to aid GHG emission reduction schemes by, for example, detecting and quantifying leaks from carbon storage facilities.
Sharad Vikram, Ashley Collier-Oxandale, Michael H. Ostertag, Massimiliano Menarini, Camron Chermak, Sanjoy Dasgupta, Tajana Rosing, Michael Hannigan, and William G. Griswold
Atmos. Meas. Tech., 12, 4211–4239, https://doi.org/10.5194/amt-12-4211-2019, https://doi.org/10.5194/amt-12-4211-2019, 2019
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Low-cost air quality sensors are enabling people to collect data to better understand their local environment and potential exposures. However, there is some concern regarding how reliable the calibrations of these sensors are in new and different environments. To explore this issue, our team colocated sensors at three different sites with high-quality monitoring instruments to compare to. We explored the transferability of calibration models as well as approaches to improve reliability.
Yanjun Zhang, Otso Peräkylä, Chao Yan, Liine Heikkinen, Mikko Äijälä, Kaspar R. Daellenbach, Qiaozhi Zha, Matthieu Riva, Olga Garmash, Heikki Junninen, Pentti Paatero, Douglas Worsnop, and Mikael Ehn
Atmos. Meas. Tech., 12, 3761–3776, https://doi.org/10.5194/amt-12-3761-2019, https://doi.org/10.5194/amt-12-3761-2019, 2019
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Recent advancements in atmospheric mass spectrometry provide large amounts of new information but at the same time present considerable challenges for the data analysis, for example, in high-resolution peak identification and separation. To address these problems, this study presents a simple and novel method, which succeeds in analyzing both synthetic and ambient datasets. We believe it will become a powerful approach in the data analysis of mass spectra.
Cheng-Hsien Lin, Richard H. Grant, Albert J. Heber, and Cliff T. Johnston
Atmos. Meas. Tech., 12, 3403–3415, https://doi.org/10.5194/amt-12-3403-2019, https://doi.org/10.5194/amt-12-3403-2019, 2019
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The open-path FTIR (OP-FTIR) is often used to measure the atmospheric gas composition and concentrations. The OP-FTIR, however, is sensitive to the changed ambient factors, which likely led to quantitative biases. This study developed methods to minimize the effect of the ambient temperature and humidity on N2O/CO2 quantification. These methods can help the users who implement the OP-FTIR to estimate gas fluxes in the agroecosystem achieve more precise and accurate estimations.
David D. Parrish, Richard G. Derwent, Simon O'Doherty, and Peter G. Simmonds
Atmos. Meas. Tech., 12, 3383–3394, https://doi.org/10.5194/amt-12-3383-2019, https://doi.org/10.5194/amt-12-3383-2019, 2019
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We present a flexible method that employs a power series expansion and Fourier series analysis to characterize the average long-term change and seasonal cycle, respectively, from a time series of observations of a trace atmospheric species. This approach maximizes the statistically significant information derived, including non-linear aspects of the long-term trends, without over fitting the data. Generally, a small set of parameter values (e.g., 7 or 8) provides this characterization.
Martin Horbanski, Denis Pöhler, Johannes Lampel, and Ulrich Platt
Atmos. Meas. Tech., 12, 3365–3381, https://doi.org/10.5194/amt-12-3365-2019, https://doi.org/10.5194/amt-12-3365-2019, 2019
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ICAD allows a precise in situ measurement of gases like NO2 in a relatively simple and compact setup. The main advantage in comparison to most other optical methods is that it does not require a stable total light intensity. This allows a simpler and mobile instrument setup and additionally it features no observed cross-interferences. We validated the high quality for an ICAD NO2 instrument in different inter-comparisons with a detection limit of 0.02 ppbv.
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Aemisegger, F., Pfahl, S., Sodemann, H., Lehner, I., Seneviratne, S. I., and Wernli, H.: Deuterium excess as a proxy for continental moisture recycling and plant transpiration, Atmos. Chem. Phys., 14, 4029–4054, https://doi.org/10.5194/acp-14-4029-2014, 2014.
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Short summary
This study evaluates the long-term stability of concentration-dependent and drift-induced biases in three water vapor isotopic analyzers deployed at two remote field sites. Despite limited data at low humidity and measurement hysteresis, inaccuracies in the concentration-dependence characterization are small, and the bias shows no change with isotope ratio or directional drift. Changes in measurement repeatability that are not characterized by linear drift estimates are a larger source of error.
This study evaluates the long-term stability of concentration-dependent and drift-induced biases...
