Articles | Volume 8, issue 10
https://doi.org/10.5194/amt-8-4521-2015
https://doi.org/10.5194/amt-8-4521-2015
Research article
 | 
27 Oct 2015
Research article |  | 27 Oct 2015

The stability and calibration of water vapor isotope ratio measurements during long-term deployments

A. Bailey, D. Noone, M. Berkelhammer, H. C. Steen-Larsen, and P. Sato

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Cited articles

Aemisegger, F., Sturm, P., Graf, P., Sodemann, H., Pfahl, S., Knohl, A., and Wernli, H.: Measuring variations of δ18O and δ2H in atmospheric water vapour using two commercial laser-based spectrometers: an instrument characterisation study, Atmos. Meas. Tech., 5, 1491–1511, https://doi.org/10.5194/amt-5-1491-2012, 2012.
Aemisegger, F., Pfahl, S., Sodemann, H., Lehner, I., Seneviratne, S. I., and Wernli, H.: Deuterium excess as a proxy for continental moisture recycling and plant transpiration, Atmos. Chem. Phys., 14, 4029–4054, https://doi.org/10.5194/acp-14-4029-2014, 2014.
Bailey, A., Toohey, D., and Noone, D.: Characterizing moisture exchange between the Hawaiian convective boundary layer and free troposphere using stable isotopes in water, J. Geophys. Res., 118, 8208–8221, https://doi.org/10.1002/jgrd.50639, 2013.
Bailey, A., Nusbaumer, J., and Noone, D.: Precipitation efficiency derived from isotope ratios in water vapor distinguishes dynamical and microphysical influences on subtropical atmospheric constituents, J. Geophys. Res., 120, https://doi.org/10.1002/2015JD023403, online first, 2015.
Bastrikov, V., Steen-Larsen, H. C., Masson-Delmotte, V., Gribanov, K., Cattani, O., Jouzel, J., and Zakharov, V.: Continuous measurements of atmospheric water vapour isotopes in western Siberia (Kourovka), Atmos. Meas. Tech., 7, 1763–1776, https://doi.org/10.5194/amt-7-1763-2014, 2014
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Short summary
This study evaluates the long-term stability of concentration-dependent and drift-induced biases in three water vapor isotopic analyzers deployed at two remote field sites. Despite limited data at low humidity and measurement hysteresis, inaccuracies in the concentration-dependence characterization are small, and the bias shows no change with isotope ratio or directional drift. Changes in measurement repeatability that are not characterized by linear drift estimates are a larger source of error.