Articles | Volume 10, issue 6
https://doi.org/10.5194/amt-10-2077-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-10-2077-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
07 Jun 2017
Research article |
| 07 Jun 2017
Characterization of interferences to in situ observations of δ13CH4 and C2H6 when using a cavity ring-down spectrometer at industrial sites
Sabina Assan
CORRESPONDING AUTHOR
Laboratoire des Sciences du Climat et de l'Environnement, Chaire
BridGES, UMR CNRS-CEA-UVSQ, Gif-sur-Yvette, Ile-de-France, 91191, France
Alexia Baudic
Laboratoire des Sciences du Climat et de l'Environnement, Chaire
BridGES, UMR CNRS-CEA-UVSQ, Gif-sur-Yvette, Ile-de-France, 91191, France
Ali Guemri
Laboratoire des Sciences du Climat et de l'Environnement, Chaire
BridGES, UMR CNRS-CEA-UVSQ, Gif-sur-Yvette, Ile-de-France, 91191, France
Philippe Ciais
Laboratoire des Sciences du Climat et de l'Environnement, Chaire
BridGES, UMR CNRS-CEA-UVSQ, Gif-sur-Yvette, Ile-de-France, 91191, France
Valerie Gros
Laboratoire des Sciences du Climat et de l'Environnement, Chaire
BridGES, UMR CNRS-CEA-UVSQ, Gif-sur-Yvette, Ile-de-France, 91191, France
Felix R. Vogel
Laboratoire des Sciences du Climat et de l'Environnement, Chaire
BridGES, UMR CNRS-CEA-UVSQ, Gif-sur-Yvette, Ile-de-France, 91191, France
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Earth Syst. Sci. Data, 17, 965–1039, https://doi.org/10.5194/essd-17-965-2025, https://doi.org/10.5194/essd-17-965-2025, 2025
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Judith Tettenborn, Daniel Zavala-Araiza, Daan Stroeken, Hossein Maazallahi, Carina van der Veen, Arjan Hensen, Ilona Velzeboer, Pim van den Bulk, Felix Vogel, Lawson Gillespie, Sebastien Ars, James France, David Lowry, Rebecca Fisher, and Thomas Röckmann
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Zhen Zhang, Benjamin Poulter, Joe R. Melton, William J. Riley, George H. Allen, David J. Beerling, Philippe Bousquet, Josep G. Canadell, Etienne Fluet-Chouinard, Philippe Ciais, Nicola Gedney, Peter O. Hopcroft, Akihiko Ito, Robert B. Jackson, Atul K. Jain, Katherine Jensen, Fortunat Joos, Thomas Kleinen, Sara H. Knox, Tingting Li, Xin Li, Xiangyu Liu, Kyle McDonald, Gavin McNicol, Paul A. Miller, Jurek Müller, Prabir K. Patra, Changhui Peng, Shushi Peng, Zhangcai Qin, Ryan M. Riggs, Marielle Saunois, Qing Sun, Hanqin Tian, Xiaoming Xu, Yuanzhi Yao, Yi Xi, Wenxin Zhang, Qing Zhu, Qiuan Zhu, and Qianlai Zhuang
Biogeosciences, 22, 305–321, https://doi.org/10.5194/bg-22-305-2025, https://doi.org/10.5194/bg-22-305-2025, 2025
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Lilian Vallet, Charbel Abdallah, Thomas Lauvaux, Lilian Joly, Michel Ramonet, Philippe Ciais, Morgan Lopez, Irène Xueref-Remy, and Florent Mouillot
Biogeosciences, 22, 213–242, https://doi.org/10.5194/bg-22-213-2025, https://doi.org/10.5194/bg-22-213-2025, 2025
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The 2022 fire season had a huge impact on European temperate forest, with several large fires exhibiting prolonged soil combustion reported. We analyzed CO and CO2 concentration recorded at nearby atmospheric towers, revealing intense smoldering combustion. We refined a fire emission model to incorporate this process. We estimated 7.95 Mteq CO2 fire emission, twice the global estimate. Fires contributed to 1.97 % of France's annual carbon footprint, reducing forest carbon sink by 30 % this year.
Anthony Rey-Pommier, Alexandre Héraud, Frédéric Chevallier, Philippe Ciais, Theodoros Christoudias, Jonilda Kushta, and Jean Sciare
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-410, https://doi.org/10.5194/essd-2024-410, 2024
Revised manuscript accepted for ESSD
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In this study, we estimate emissions of nitrogen oxides (NOx) in 2022 at high-resolution at the global scale, using satellite observations. We provide maps of the emissions and identify several types of sources. Our results are similar to the EDGAR emission inventory. However, differences are found in countries with lower observation densities and lower emissions.
Juliette Bernard, Catherine Prigent, Carlos Jimenez, Etienne Fluet-Chouinard, Bernhard Lehner, Elodie Salmon, Philippe Ciais, Zhen Zhang, Shushi Peng, and Marielle Saunois
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-466, https://doi.org/10.5194/essd-2024-466, 2024
Revised manuscript accepted for ESSD
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Wetlands are responsible for about a third of global emissions of methane, a potent greenhouse gas. We have developed the GIEMS-MethaneCentric (GIEMS-MC) dataset to represent the dynamics of wetland extent on a global scale (0.25°x0.25° resolution, monthly time step). This updated resource combines satellite data and existing wetland databases, covering 1992 to 2020. Consistent maps of other methane-emitting surface waters (lakes, rivers, reservoirs, rice paddies) are also provided.
Jinghui Lian, Olivier Laurent, Mali Chariot, Luc Lienhardt, Michel Ramonet, Hervé Utard, Thomas Lauvaux, François-Marie Bréon, Grégoire Broquet, Karina Cucchi, Laurent Millair, and Philippe Ciais
Atmos. Meas. Tech., 17, 5821–5839, https://doi.org/10.5194/amt-17-5821-2024, https://doi.org/10.5194/amt-17-5821-2024, 2024
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We have designed and deployed a mid-cost medium-precision CO2 sensor monitoring network in Paris since July 2020. The data are automatically calibrated by a newly implemented data processing system. The accuracies of the mid-cost instruments vary from 1.0 to 2.4 ppm for hourly afternoon measurements. Our model–data analyses highlight prospects for integrating mid-cost instrument data with high-precision measurements to improve fine-scale CO2 emission quantification in urban areas.
Josselin Doc, Michel Ramonet, François-Marie Bréon, Delphine Combaz, Mali Chariot, Morgan Lopez, Marc Delmotte, Cristelle Cailteau-Fischbach, Guillaume Nief, Nathanaël Laporte, Thomas Lauvaux, and Philippe Ciais
EGUsphere, https://doi.org/10.5194/egusphere-2024-2826, https://doi.org/10.5194/egusphere-2024-2826, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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Description of the network for measuring greenhouse gas concentrations in the Paris region and analysis of eight years of continuous monitoring.
Thi Lan Anh Dinh, Daniel Goll, Philippe Ciais, and Ronny Lauerwald
Geosci. Model Dev., 17, 6725–6744, https://doi.org/10.5194/gmd-17-6725-2024, https://doi.org/10.5194/gmd-17-6725-2024, 2024
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The study assesses the performance of the dynamic global vegetation model (DGVM) ORCHIDEE in capturing the impact of land-use change on carbon stocks across Europe. Comparisons with observations reveal that the model accurately represents carbon fluxes and stocks. Despite the underestimations in certain land-use conversions, the model describes general trends in soil carbon response to land-use change, aligning with the site observations.
Misa Ishizawa, Douglas Chan, Doug Worthy, Elton Chan, Felix Vogel, Joe R. Melton, and Vivek K. Arora
Atmos. Chem. Phys., 24, 10013–10038, https://doi.org/10.5194/acp-24-10013-2024, https://doi.org/10.5194/acp-24-10013-2024, 2024
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Methane (CH4) emissions in Canada for 2007–2017 were estimated using Canada’s surface greenhouse gas measurements. The estimated emissions show no significant trend, but emission uncertainty was reduced as more measurement sites became available. Notably for climate change, we find the wetland CH4 emissions show a positive correlation with surface air temperature in summer. Canada’s measurement network could monitor future CH4 emission changes and compliance with climate change mitigation goals.
Pierre Tulet, Joel Van Baelen, Pierre Bosser, Jérome Brioude, Aurélie Colomb, Philippe Goloub, Andrea Pazmino, Thierry Portafaix, Michel Ramonet, Karine Sellegri, Melilotus Thyssen, Léa Gest, Nicolas Marquestaut, Dominique Mékiès, Jean-Marc Metzger, Gilles Athier, Luc Blarel, Marc Delmotte, Guillaume Desprairies, Mérédith Dournaux, Gaël Dubois, Valentin Duflot, Kevin Lamy, Lionel Gardes, Jean-François Guillemot, Valérie Gros, Joanna Kolasinski, Morgan Lopez, Olivier Magand, Erwan Noury, Manuel Nunes-Pinharanda, Guillaume Payen, Joris Pianezze, David Picard, Olivier Picard, Sandrine Prunier, François Rigaud-Louise, Michael Sicard, and Benjamin Torres
Earth Syst. Sci. Data, 16, 3821–3849, https://doi.org/10.5194/essd-16-3821-2024, https://doi.org/10.5194/essd-16-3821-2024, 2024
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The MAP-IO program aims to compensate for the lack of atmospheric and oceanographic observations in the Southern Ocean by equipping the ship Marion Dufresne with a set of 17 scientific instruments. This program collected 700 d of measurements under different latitudes, seasons, sea states, and weather conditions. These new data will support the calibration and validation of numerical models and the understanding of the atmospheric composition of this region of Earth.
Minna Ma, Haicheng Zhang, Ronny Lauerwald, Philippe Ciais, and Pierre Regnier
Earth Syst. Dynam. Discuss., https://doi.org/10.5194/esd-2024-29, https://doi.org/10.5194/esd-2024-29, 2024
Revised manuscript accepted for ESD
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A new model (ORCHIDEE-NLAT) was developed to estimate lateral nitrogen (N) transport from land to oceans through rivers at daily step. The model includes transport of water and N, as well as the decomposition of dissolved organic N and particulate organic, and denitrification of dissolved inorganic N. Model evaluations indicate that ORCHIDEE-NLAT reproduce observed rates and seasonal variations of water discharge and total N flow well.
Rodrigo Rivera-Martinez, Pramod Kumar, Olivier Laurent, Gregoire Broquet, Christopher Caldow, Ford Cropley, Diego Santaren, Adil Shah, Cécile Mallet, Michel Ramonet, Leonard Rivier, Catherine Juery, Olivier Duclaux, Caroline Bouchet, Elisa Allegrini, Hervé Utard, and Philippe Ciais
Atmos. Meas. Tech., 17, 4257–4290, https://doi.org/10.5194/amt-17-4257-2024, https://doi.org/10.5194/amt-17-4257-2024, 2024
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We explore the use of metal oxide semiconductors (MOSs) as a low-cost alternative for detecting and measuring CH4 emissions from industrial facilities. MOSs were exposed to several controlled releases to test their accuracy in detecting and quantifying emissions. Two reconstruction models were compared, and emission estimates were computed using a Gaussian dispersion model. Findings show that MOSs can provide accurate emission estimates with a 25 % emission rate error and a 9.5 m location error.
Chuanlong Zhou, Biqing Zhu, Antoine Halff, Steven J. Davis, Zhu Liu, Simon Bowring, Simon Ben Arous, and Philippe Ciais
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-173, https://doi.org/10.5194/essd-2024-173, 2024
Revised manuscript accepted for ESSD
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After Russia's 2022 invasion of Ukraine, Europe's energy dynamics shifted significantly. Our study introduces updated datasets tracking changes in natural gas supply, usage, and transmission within the EU27&UK. We discovered that Europe adapted to losing Russian gas by increasing LNG imports and shifting to renewables. Our insights could shape future energy policies and climate research.
Mengjie Han, Qing Zhao, Xili Wang, Ying-Ping Wang, Philippe Ciais, Haicheng Zhang, Daniel S. Goll, Lei Zhu, Zhe Zhao, Zhixuan Guo, Chen Wang, Wei Zhuang, Fengchang Wu, and Wei Li
Geosci. Model Dev., 17, 4871–4890, https://doi.org/10.5194/gmd-17-4871-2024, https://doi.org/10.5194/gmd-17-4871-2024, 2024
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The impact of biochar (BC) on soil organic carbon (SOC) dynamics is not represented in most land carbon models used for assessing land-based climate change mitigation. Our study develops a BC model that incorporates our current understanding of BC effects on SOC based on a soil carbon model (MIMICS). The BC model can reproduce the SOC changes after adding BC, providing a useful tool to couple dynamic land models to evaluate the effectiveness of BC application for CO2 removal from the atmosphere.
Yi Xi, Chunjing Qiu, Yuan Zhang, Dan Zhu, Shushi Peng, Gustaf Hugelius, Jinfeng Chang, Elodie Salmon, and Philippe Ciais
Geosci. Model Dev., 17, 4727–4754, https://doi.org/10.5194/gmd-17-4727-2024, https://doi.org/10.5194/gmd-17-4727-2024, 2024
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The ORCHIDEE-MICT model can simulate the carbon cycle and hydrology at a sub-grid scale but energy budgets only at a grid scale. This paper assessed the implementation of a multi-tiling energy budget approach in ORCHIDEE-MICT and found warmer surface and soil temperatures, higher soil moisture, and more soil organic carbon across the Northern Hemisphere compared with the original version.
Yitong Yao, Philippe Ciais, Emilie Joetzjer, Wei Li, Lei Zhu, Yujie Wang, Christian Frankenberg, and Nicolas Viovy
Earth Syst. Dynam., 15, 763–778, https://doi.org/10.5194/esd-15-763-2024, https://doi.org/10.5194/esd-15-763-2024, 2024
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Elevated CO2 concentration (eCO2) is critical for shaping the future path of forest carbon uptake, while uncertainties remain about concurrent carbon loss. Here, we found that eCO2 might amplify competition-induced carbon loss, while the extent of drought-induced carbon loss hinges on the balance between heightened biomass density and water-saving benefits. This is the first time that such carbon loss responses to ongoing climate change have been quantified separately over the Amazon rainforest.
Hanqin Tian, Naiqing Pan, Rona L. Thompson, Josep G. Canadell, Parvadha Suntharalingam, Pierre Regnier, Eric A. Davidson, Michael Prather, Philippe Ciais, Marilena Muntean, Shufen Pan, Wilfried Winiwarter, Sönke Zaehle, Feng Zhou, Robert B. Jackson, Hermann W. Bange, Sarah Berthet, Zihao Bian, Daniele Bianchi, Alexander F. Bouwman, Erik T. Buitenhuis, Geoffrey Dutton, Minpeng Hu, Akihiko Ito, Atul K. Jain, Aurich Jeltsch-Thömmes, Fortunat Joos, Sian Kou-Giesbrecht, Paul B. Krummel, Xin Lan, Angela Landolfi, Ronny Lauerwald, Ya Li, Chaoqun Lu, Taylor Maavara, Manfredi Manizza, Dylan B. Millet, Jens Mühle, Prabir K. Patra, Glen P. Peters, Xiaoyu Qin, Peter Raymond, Laure Resplandy, Judith A. Rosentreter, Hao Shi, Qing Sun, Daniele Tonina, Francesco N. Tubiello, Guido R. van der Werf, Nicolas Vuichard, Junjie Wang, Kelley C. Wells, Luke M. Western, Chris Wilson, Jia Yang, Yuanzhi Yao, Yongfa You, and Qing Zhu
Earth Syst. Sci. Data, 16, 2543–2604, https://doi.org/10.5194/essd-16-2543-2024, https://doi.org/10.5194/essd-16-2543-2024, 2024
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Atmospheric concentrations of nitrous oxide (N2O), a greenhouse gas 273 times more potent than carbon dioxide, have increased by 25 % since the preindustrial period, with the highest observed growth rate in 2020 and 2021. This rapid growth rate has primarily been due to a 40 % increase in anthropogenic emissions since 1980. Observed atmospheric N2O concentrations in recent years have exceeded the worst-case climate scenario, underscoring the importance of reducing anthropogenic N2O emissions.
Alice Maison, Lya Lugon, Soo-Jin Park, Alexia Baudic, Christopher Cantrell, Florian Couvidat, Barbara D'Anna, Claudia Di Biagio, Aline Gratien, Valérie Gros, Carmen Kalalian, Julien Kammer, Vincent Michoud, Jean-Eudes Petit, Marwa Shahin, Leila Simon, Myrto Valari, Jérémy Vigneron, Andrée Tuzet, and Karine Sartelet
Atmos. Chem. Phys., 24, 6011–6046, https://doi.org/10.5194/acp-24-6011-2024, https://doi.org/10.5194/acp-24-6011-2024, 2024
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This study presents the development of a bottom-up inventory of urban tree biogenic emissions. Emissions are computed for each tree based on their location and characteristics and are integrated in the regional air quality model WRF-CHIMERE. The impact of these biogenic emissions on air quality is quantified for June–July 2022. Over Paris city, urban trees increase the concentrations of particulate organic matter by 4.6 %, of PM2.5 by 0.6 %, and of ozone by 1.0 % on average over 2 months.
Léna Gurriaran, Yannig Goude, Katsumasa Tanaka, Biqing Zhu, Zhu Deng, Xuanren Song, and Philippe Ciais
Geosci. Model Dev., 17, 2663–2682, https://doi.org/10.5194/gmd-17-2663-2024, https://doi.org/10.5194/gmd-17-2663-2024, 2024
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We developed a data-driven model simulating daily regional power demand based on climate and socioeconomic variables. Our model was applied to eight countries or regions (Australia, Brazil, China, EU, India, Russia, South Africa, US), identifying influential factors and their relationship with power demand. Our findings highlight the significance of economic indicators in addition to temperature, showcasing country-specific variations. This research aids energy planning and emission reduction.
Maud Leriche, Pierre Tulet, Laurent Deguillaume, Frédéric Burnet, Aurélie Colomb, Agnès Borbon, Corinne Jambert, Valentin Duflot, Stéphan Houdier, Jean-Luc Jaffrezo, Mickaël Vaïtilingom, Pamela Dominutti, Manon Rocco, Camille Mouchel-Vallon, Samira El Gdachi, Maxence Brissy, Maroua Fathalli, Nicolas Maury, Bert Verreyken, Crist Amelynck, Niels Schoon, Valérie Gros, Jean-Marc Pichon, Mickael Ribeiro, Eric Pique, Emmanuel Leclerc, Thierry Bourrianne, Axel Roy, Eric Moulin, Joël Barrie, Jean-Marc Metzger, Guillaume Péris, Christian Guadagno, Chatrapatty Bhugwant, Jean-Mathieu Tibere, Arnaud Tournigand, Evelyn Freney, Karine Sellegri, Anne-Marie Delort, Pierre Amato, Muriel Joly, Jean-Luc Baray, Pascal Renard, Angelica Bianco, Anne Réchou, and Guillaume Payen
Atmos. Chem. Phys., 24, 4129–4155, https://doi.org/10.5194/acp-24-4129-2024, https://doi.org/10.5194/acp-24-4129-2024, 2024
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Aerosol particles in the atmosphere play a key role in climate change and air pollution. A large number of aerosol particles are formed from the oxidation of volatile organic compounds (VOCs and secondary organic aerosols – SOA). An important field campaign was organized on Réunion in March–April 2019 to understand the formation of SOA in a tropical atmosphere mostly influenced by VOCs emitted by forest and in the presence of clouds. This work synthesizes the results of this campaign.
Pedro Felipe Arboleda-Obando, Agnès Ducharne, Zun Yin, and Philippe Ciais
Geosci. Model Dev., 17, 2141–2164, https://doi.org/10.5194/gmd-17-2141-2024, https://doi.org/10.5194/gmd-17-2141-2024, 2024
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We show a new irrigation scheme included in the ORCHIDEE land surface model. The new irrigation scheme restrains irrigation due to water shortage, includes water adduction, and represents environmental limits and facilities to access water, due to representing infrastructure in a simple way. Our results show that the new irrigation scheme helps simulate acceptable land surface conditions and fluxes in irrigated areas, even if there are difficulties due to shortcomings and limited information.
Pramod Kumar, Christopher Caldow, Grégoire Broquet, Adil Shah, Olivier Laurent, Camille Yver-Kwok, Sebastien Ars, Sara Defratyka, Susan Warao Gichuki, Luc Lienhardt, Mathis Lozano, Jean-Daniel Paris, Felix Vogel, Caroline Bouchet, Elisa Allegrini, Robert Kelly, Catherine Juery, and Philippe Ciais
Atmos. Meas. Tech., 17, 1229–1250, https://doi.org/10.5194/amt-17-1229-2024, https://doi.org/10.5194/amt-17-1229-2024, 2024
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This study presents a series of mobile measurement campaigns to monitor the CH4 emissions from an active landfill. These measurements are processed using a Gaussian plume model and atmospheric inversion techniques to quantify the landfill CH4 emissions. The methane emission estimates range between ~0.4 and ~7 t CH4 per day, and their variations are analyzed. The robustness of the estimates is assessed depending on the distance of the measurements from the potential sources in the landfill.
Mounia Mostefaoui, Philippe Ciais, Matthew J. McGrath, Philippe Peylin, Prabir K. Patra, and Yolandi Ernst
Earth Syst. Sci. Data, 16, 245–275, https://doi.org/10.5194/essd-16-245-2024, https://doi.org/10.5194/essd-16-245-2024, 2024
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Our aim is to assess African anthropogenic greenhouse gas emissions and removals by using different data products, including inventories and process-based models, and to compare their relative merits with inversion data coming from satellites. We show a good match among the various estimates in terms of overall trends at a regional level and on a decadal basis, but large differences exist even among similar data types, which is a limit to the possibility of verification of country-reported data.
Pauline Buysse, Benjamin Loubet, Raluca Ciuraru, Florence Lafouge, Brigitte Durand, Olivier Zurfluh, Céline Décuq, Olivier Fanucci, Lais Gonzaga Gomez, Jean-Christophe Gueudet, Sandy Bsaibes, Nora Zannoni, and Valérie Gros
EGUsphere, https://doi.org/10.5194/egusphere-2023-2438, https://doi.org/10.5194/egusphere-2023-2438, 2024
Preprint withdrawn
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This research aimed at quantifying biogenic volatile organic compounds (BVOCs) emissions by a rapeseed crop field. Such compounds are precursors of atmospheric pollutants. Our study revealed that methanol, a BVOC that is not very reactive in the atmosphere, is by far the most emitted BVOC, while monoterpenes, being highly reactive, were emitted in larger quantities than expected. Our study therefore points out the potentially more significant contribution of croplands to atmospheric pollution.
Douglas E. J. Worthy, Michele K. Rauh, Lin Huang, Felix R. Vogel, Alina Chivulescu, Kenneth A. Masarie, Ray L. Langenfelds, Paul B. Krummel, Colin E. Allison, Andrew M. Crotwell, Monica Madronich, Gabrielle Pétron, Ingeborg Levin, Samuel Hammer, Sylvia Michel, Michel Ramonet, Martina Schmidt, Armin Jordan, Heiko Moossen, Michael Rothe, Ralph Keeling, and Eric J. Morgan
Atmos. Meas. Tech., 16, 5909–5935, https://doi.org/10.5194/amt-16-5909-2023, https://doi.org/10.5194/amt-16-5909-2023, 2023
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Network compatibility is important for inferring greenhouse gas fluxes at global or regional scales. This study is the first assessment of the measurement agreement among seven individual programs within the World Meteorological Organization community. It compares co-located flask air measurements at the Alert Observatory in Canada over a 17-year period. The results provide stronger confidence in the uncertainty estimation while using those datasets in various data interpretation applications.
Jan De Pue, Sebastian Wieneke, Ana Bastos, José Miguel Barrios, Liyang Liu, Philippe Ciais, Alirio Arboleda, Rafiq Hamdi, Maral Maleki, Fabienne Maignan, Françoise Gellens-Meulenberghs, Ivan Janssens, and Manuela Balzarolo
Biogeosciences, 20, 4795–4818, https://doi.org/10.5194/bg-20-4795-2023, https://doi.org/10.5194/bg-20-4795-2023, 2023
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The gross primary production (GPP) of the terrestrial biosphere is a key source of variability in the global carbon cycle. To estimate this flux, models can rely on remote sensing data (RS-driven), meteorological data (meteo-driven) or a combination of both (hybrid). An intercomparison of 11 models demonstrated that RS-driven models lack the sensitivity to short-term anomalies. Conversely, the simulation of soil moisture dynamics and stress response remains a challenge in meteo-driven models.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Dorothee C. E. Bakker, Judith Hauck, Peter Landschützer, Corinne Le Quéré, Ingrid T. Luijkx, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Peter Anthoni, Leticia Barbero, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Bertrand Decharme, Laurent Bopp, Ida Bagus Mandhara Brasika, Patricia Cadule, Matthew A. Chamberlain, Naveen Chandra, Thi-Tuyet-Trang Chau, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Xinyu Dou, Kazutaka Enyo, Wiley Evans, Stefanie Falk, Richard A. Feely, Liang Feng, Daniel J. Ford, Thomas Gasser, Josefine Ghattas, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Jens Heinke, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Andrew R. Jacobson, Atul Jain, Tereza Jarníková, Annika Jersild, Fei Jiang, Zhe Jin, Fortunat Joos, Etsushi Kato, Ralph F. Keeling, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Arne Körtzinger, Xin Lan, Nathalie Lefèvre, Hongmei Li, Junjie Liu, Zhiqiang Liu, Lei Ma, Greg Marland, Nicolas Mayot, Patrick C. McGuire, Galen A. McKinley, Gesa Meyer, Eric J. Morgan, David R. Munro, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin M. O'Brien, Are Olsen, Abdirahman M. Omar, Tsuneo Ono, Melf Paulsen, Denis Pierrot, Katie Pocock, Benjamin Poulter, Carter M. Powis, Gregor Rehder, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Thais M. Rosan, Jörg Schwinger, Roland Séférian, T. Luke Smallman, Stephen M. Smith, Reinel Sospedra-Alfonso, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Shintaro Takao, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Guido R. van der Werf, Erik van Ooijen, Rik Wanninkhof, Michio Watanabe, Cathy Wimart-Rousseau, Dongxu Yang, Xiaojuan Yang, Wenping Yuan, Xu Yue, Sönke Zaehle, Jiye Zeng, and Bo Zheng
Earth Syst. Sci. Data, 15, 5301–5369, https://doi.org/10.5194/essd-15-5301-2023, https://doi.org/10.5194/essd-15-5301-2023, 2023
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The Global Carbon Budget 2023 describes the methodology, main results, and data sets used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land ecosystems, and the ocean over the historical period (1750–2023). These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Ioannis Cheliotis, Thomas Lauvaux, Jinghui Lian, Theodoros Christoudias, George Georgiou, Alba Badia, Frédéric Chevallier, Pramod Kumar, Yathin Kudupaje, Ruixue Lei, and Philippe Ciais
EGUsphere, https://doi.org/10.5194/egusphere-2023-2487, https://doi.org/10.5194/egusphere-2023-2487, 2023
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A consistent estimation of CO2 emissions is complicated due to the scarcity of CO2 observations. In this study, we showcase the potential to improve the CO2 emissions estimations from the NO2 concentrations based on the NO2-to-CO2 ratio, which should be constant for a source co-emitting NO2 and CO2, by comparing satellite observations with atmospheric chemistry and transport model simulations for NO2 and CO2. Furthermore, we demonstrate the significance of the chemistry in NO2 simulations.
Martin Schwartz, Philippe Ciais, Aurélien De Truchis, Jérôme Chave, Catherine Ottlé, Cedric Vega, Jean-Pierre Wigneron, Manuel Nicolas, Sami Jouaber, Siyu Liu, Martin Brandt, and Ibrahim Fayad
Earth Syst. Sci. Data, 15, 4927–4945, https://doi.org/10.5194/essd-15-4927-2023, https://doi.org/10.5194/essd-15-4927-2023, 2023
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As forests play a key role in climate-related issues, their accurate monitoring is critical to reduce global carbon emissions effectively. Based on open-access remote-sensing sensors, and artificial intelligence methods, we created high-resolution tree height, wood volume, and biomass maps of metropolitan France that outperform previous products. This study, based on freely available data, provides essential information to support climate-efficient forest management policies at a low cost.
Anthony Rey-Pommier, Frédéric Chevallier, Philippe Ciais, Jonilda Kushta, Theodoros Christoudias, I. Safak Bayram, and Jean Sciare
Atmos. Chem. Phys., 23, 13565–13583, https://doi.org/10.5194/acp-23-13565-2023, https://doi.org/10.5194/acp-23-13565-2023, 2023
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We use four years (2019–2022) of TROPOMI NO2 data to map NOx emissions in Qatar. We estimate average monthly emissions for the country and industrial facilities and derive an emission factor for the power sector. Monthly emissions have a weekly cycle reflecting the social norms in Qatar and an annual cycle consistent with the electricity production by gas-fired power plants. Their mean value is lower than the NOx emissions in global inventories but similar to the emissions reported for 2007.
Matthew J. McGrath, Ana Maria Roxana Petrescu, Philippe Peylin, Robbie M. Andrew, Bradley Matthews, Frank Dentener, Juraj Balkovič, Vladislav Bastrikov, Meike Becker, Gregoire Broquet, Philippe Ciais, Audrey Fortems-Cheiney, Raphael Ganzenmüller, Giacomo Grassi, Ian Harris, Matthew Jones, Jürgen Knauer, Matthias Kuhnert, Guillaume Monteil, Saqr Munassar, Paul I. Palmer, Glen P. Peters, Chunjing Qiu, Mart-Jan Schelhaas, Oksana Tarasova, Matteo Vizzarri, Karina Winkler, Gianpaolo Balsamo, Antoine Berchet, Peter Briggs, Patrick Brockmann, Frédéric Chevallier, Giulia Conchedda, Monica Crippa, Stijn N. C. Dellaert, Hugo A. C. Denier van der Gon, Sara Filipek, Pierre Friedlingstein, Richard Fuchs, Michael Gauss, Christoph Gerbig, Diego Guizzardi, Dirk Günther, Richard A. Houghton, Greet Janssens-Maenhout, Ronny Lauerwald, Bas Lerink, Ingrid T. Luijkx, Géraud Moulas, Marilena Muntean, Gert-Jan Nabuurs, Aurélie Paquirissamy, Lucia Perugini, Wouter Peters, Roberto Pilli, Julia Pongratz, Pierre Regnier, Marko Scholze, Yusuf Serengil, Pete Smith, Efisio Solazzo, Rona L. Thompson, Francesco N. Tubiello, Timo Vesala, and Sophia Walther
Earth Syst. Sci. Data, 15, 4295–4370, https://doi.org/10.5194/essd-15-4295-2023, https://doi.org/10.5194/essd-15-4295-2023, 2023
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Accurate estimation of fluxes of carbon dioxide from the land surface is essential for understanding future impacts of greenhouse gas emissions on the climate system. A wide variety of methods currently exist to estimate these sources and sinks. We are continuing work to develop annual comparisons of these diverse methods in order to clarify what they all actually calculate and to resolve apparent disagreement, in addition to highlighting opportunities for increased understanding.
Lilian Vallet, Martin Schwartz, Philippe Ciais, Dave van Wees, Aurelien de Truchis, and Florent Mouillot
Biogeosciences, 20, 3803–3825, https://doi.org/10.5194/bg-20-3803-2023, https://doi.org/10.5194/bg-20-3803-2023, 2023
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This study analyzes the ecological impact of the 2022 summer fire season in France by using high-resolution satellite data. The total biomass loss was 2.553 Mt, equivalent to a 17 % increase of the average natural mortality of all French forests. While Mediterranean forests had a lower biomass loss, there was a drastic increase in burned area and biomass loss over the Atlantic pine forests and temperate forests. This result revisits the distinctiveness of the 2022 fire season.
Lawson David Gillespie, Sébastien Ars, James Phillip Williams, Louise Klotz, Tianjie Feng, Stephanie Gu, Mishaal Kandapath, Amy Mann, Michael Raczkowski, Mary Kang, Felix Vogel, and Debra Wunch
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2023-193, https://doi.org/10.5194/amt-2023-193, 2023
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We investigate techniques for calculating emissions from mobile in situ gas concentrations recorded during downwind plume transects. We find that using the enhancement area to estimate emissions is the most consistent method when comparing different setups and instruments. Observations from a multi year urban methane survey and controlled release experiment are analyzed, and emissions rates for combined sewage overflow basins and a large wastewater treatment plant in Toronto are calculated.
Jean-Philippe Putaud, Enrico Pisoni, Alexander Mangold, Christoph Hueglin, Jean Sciare, Michael Pikridas, Chrysanthos Savvides, Jakub Ondracek, Saliou Mbengue, Alfred Wiedensohler, Kay Weinhold, Maik Merkel, Laurent Poulain, Dominik van Pinxteren, Hartmut Herrmann, Andreas Massling, Claus Nordstroem, Andrés Alastuey, Cristina Reche, Noemí Pérez, Sonia Castillo, Mar Sorribas, Jose Antonio Adame, Tuukka Petaja, Katrianne Lehtipalo, Jarkko Niemi, Véronique Riffault, Joel F. de Brito, Augustin Colette, Olivier Favez, Jean-Eudes Petit, Valérie Gros, Maria I. Gini, Stergios Vratolis, Konstantinos Eleftheriadis, Evangelia Diapouli, Hugo Denier van der Gon, Karl Espen Yttri, and Wenche Aas
Atmos. Chem. Phys., 23, 10145–10161, https://doi.org/10.5194/acp-23-10145-2023, https://doi.org/10.5194/acp-23-10145-2023, 2023
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Many European people are still exposed to levels of air pollution that can affect their health. COVID-19 lockdowns in 2020 were used to assess the impact of the reduction in human mobility on air pollution across Europe by comparing measurement data with values that would be expected if no lockdown had occurred. We show that lockdown measures did not lead to consistent decreases in the concentrations of fine particulate matter suspended in the air, and we investigate why.
Jinghui Lian, Thomas Lauvaux, Hervé Utard, François-Marie Bréon, Grégoire Broquet, Michel Ramonet, Olivier Laurent, Ivonne Albarus, Mali Chariot, Simone Kotthaus, Martial Haeffelin, Olivier Sanchez, Olivier Perrussel, Hugo Anne Denier van der Gon, Stijn Nicolaas Camiel Dellaert, and Philippe Ciais
Atmos. Chem. Phys., 23, 8823–8835, https://doi.org/10.5194/acp-23-8823-2023, https://doi.org/10.5194/acp-23-8823-2023, 2023
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This study quantifies urban CO2 emissions via an atmospheric inversion for the Paris metropolitan area over a 6-year period from 2016 to 2021. Results show a long-term decreasing trend of about 2 % ± 0.6 % per year in the annual CO2 emissions over Paris. We conclude that our current capacity can deliver near-real-time CO2 emission estimates at the city scale in under a month, and the results agree within 10 % with independent estimates from multiple city-scale inventories.
Marc Guevara, Hervé Petetin, Oriol Jorba, Hugo Denier van der Gon, Jeroen Kuenen, Ingrid Super, Claire Granier, Thierno Doumbia, Philippe Ciais, Zhu Liu, Robin D. Lamboll, Sabine Schindlbacher, Bradley Matthews, and Carlos Pérez García-Pando
Atmos. Chem. Phys., 23, 8081–8101, https://doi.org/10.5194/acp-23-8081-2023, https://doi.org/10.5194/acp-23-8081-2023, 2023
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This study provides an intercomparison of European 2020 emission changes derived from official inventories, which are reported by countries under the framework of several international conventions and directives, and non-official near-real-time estimates, the use of which has significantly grown since the COVID-19 outbreak. The results of the work are used to produce recommendations on how best to approach and make use of near-real-time emissions for modelling and monitoring applications.
Adil Shah, Olivier Laurent, Luc Lienhardt, Grégoire Broquet, Rodrigo Rivera Martinez, Elisa Allegrini, and Philippe Ciais
Atmos. Meas. Tech., 16, 3391–3419, https://doi.org/10.5194/amt-16-3391-2023, https://doi.org/10.5194/amt-16-3391-2023, 2023
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As methane (CH4) contributes to global warming, more CH4 measurements are required to better characterise source emissions. Hence, we tested a cheap CH4 sensor for 338 d of landfill sampling. We derived an excellent CH4 response model in a stable environment. However, different types of air with the same CH4 level had diverse sensor responses. We characterised temperature and water vapour response but could not replicate field sampling. Thus, other species may cause sensor interactions.
Xiaojuan Lin, Ronald van der A, Jos de Laat, Henk Eskes, Frédéric Chevallier, Philippe Ciais, Zhu Deng, Yuanhao Geng, Xuanren Song, Xiliang Ni, Da Huo, Xinyu Dou, and Zhu Liu
Atmos. Chem. Phys., 23, 6599–6611, https://doi.org/10.5194/acp-23-6599-2023, https://doi.org/10.5194/acp-23-6599-2023, 2023
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Satellite observations provide evidence for CO2 emission signals from isolated power plants. We use these satellite observations to quantify emissions. We found that for power plants with multiple observations, the correlation of estimated and reported emissions is significantly improved compared to a single observation case. This demonstrates that accurate estimation of power plant emissions can be achieved by monitoring from future satellite missions with more frequent observations.
Leïla Simon, Valérie Gros, Jean-Eudes Petit, François Truong, Roland Sarda-Estève, Carmen Kalalian, Alexia Baudic, Caroline Marchand, and Olivier Favez
Earth Syst. Sci. Data, 15, 1947–1968, https://doi.org/10.5194/essd-15-1947-2023, https://doi.org/10.5194/essd-15-1947-2023, 2023
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Long-term measurements of volatile organic compounds (VOCs) have been set up to better characterize the atmospheric chemistry at the SIRTA national facility (Paris area, France). Results obtained from the first 2 years (2020–2021) confirm the importance of local sources for short-lived compounds and the role played by meteorology and air mass origins in the long-term analysis of VOCs. They also point to a substantial influence of anthropogenic on the monoterpene loadings.
Rodrigo Andres Rivera Martinez, Diego Santaren, Olivier Laurent, Gregoire Broquet, Ford Cropley, Cécile Mallet, Michel Ramonet, Adil Shah, Leonard Rivier, Caroline Bouchet, Catherine Juery, Olivier Duclaux, and Philippe Ciais
Atmos. Meas. Tech., 16, 2209–2235, https://doi.org/10.5194/amt-16-2209-2023, https://doi.org/10.5194/amt-16-2209-2023, 2023
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A network of low-cost sensors is a good alternative to improve the detection of fugitive CH4 emissions. We present the results of four tests conducted with two types of Figaro sensors that were assembled on four chambers in a laboratory experiment: a comparison of five models to reconstruct the CH4 signal, a strategy to reduce the training set size, a detection of age effects in the sensors and a test of the capability to transfer a model between chambers for the same type of sensor.
Shengli Tao, Zurui Ao, Jean-Pierre Wigneron, Sassan Saatchi, Philippe Ciais, Jérôme Chave, Thuy Le Toan, Pierre-Louis Frison, Xiaomei Hu, Chi Chen, Lei Fan, Mengjia Wang, Jiangling Zhu, Xia Zhao, Xiaojun Li, Xiangzhuo Liu, Yanjun Su, Tianyu Hu, Qinghua Guo, Zhiheng Wang, Zhiyao Tang, Yi Y. Liu, and Jingyun Fang
Earth Syst. Sci. Data, 15, 1577–1596, https://doi.org/10.5194/essd-15-1577-2023, https://doi.org/10.5194/essd-15-1577-2023, 2023
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We provide the first long-term (since 1992), high-resolution (8.9 km) satellite radar backscatter data set (LHScat) with a C-band (5.3 GHz) signal dynamic for global lands. LHScat was created by fusing signals from ERS (1992–2001; C-band), QSCAT (1999–2009; Ku-band), and ASCAT (since 2007; C-band). LHScat has been validated against independent ERS-2 signals. It could be used in a variety of studies, such as vegetation monitoring and hydrological modelling.
Ana Maria Roxana Petrescu, Chunjing Qiu, Matthew J. McGrath, Philippe Peylin, Glen P. Peters, Philippe Ciais, Rona L. Thompson, Aki Tsuruta, Dominik Brunner, Matthias Kuhnert, Bradley Matthews, Paul I. Palmer, Oksana Tarasova, Pierre Regnier, Ronny Lauerwald, David Bastviken, Lena Höglund-Isaksson, Wilfried Winiwarter, Giuseppe Etiope, Tuula Aalto, Gianpaolo Balsamo, Vladislav Bastrikov, Antoine Berchet, Patrick Brockmann, Giancarlo Ciotoli, Giulia Conchedda, Monica Crippa, Frank Dentener, Christine D. Groot Zwaaftink, Diego Guizzardi, Dirk Günther, Jean-Matthieu Haussaire, Sander Houweling, Greet Janssens-Maenhout, Massaer Kouyate, Adrian Leip, Antti Leppänen, Emanuele Lugato, Manon Maisonnier, Alistair J. Manning, Tiina Markkanen, Joe McNorton, Marilena Muntean, Gabriel D. Oreggioni, Prabir K. Patra, Lucia Perugini, Isabelle Pison, Maarit T. Raivonen, Marielle Saunois, Arjo J. Segers, Pete Smith, Efisio Solazzo, Hanqin Tian, Francesco N. Tubiello, Timo Vesala, Guido R. van der Werf, Chris Wilson, and Sönke Zaehle
Earth Syst. Sci. Data, 15, 1197–1268, https://doi.org/10.5194/essd-15-1197-2023, https://doi.org/10.5194/essd-15-1197-2023, 2023
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This study updates the state-of-the-art scientific overview of CH4 and N2O emissions in the EU27 and UK in Petrescu et al. (2021a). Yearly updates are needed to improve the different respective approaches and to inform on the development of formal verification systems. It integrates the most recent emission inventories, process-based model and regional/global inversions, comparing them with UNFCCC national GHG inventories, in support to policy to facilitate real-time verification procedures.
Giacomo Grassi, Clemens Schwingshackl, Thomas Gasser, Richard A. Houghton, Stephen Sitch, Josep G. Canadell, Alessandro Cescatti, Philippe Ciais, Sandro Federici, Pierre Friedlingstein, Werner A. Kurz, Maria J. Sanz Sanchez, Raúl Abad Viñas, Ramdane Alkama, Selma Bultan, Guido Ceccherini, Stefanie Falk, Etsushi Kato, Daniel Kennedy, Jürgen Knauer, Anu Korosuo, Joana Melo, Matthew J. McGrath, Julia E. M. S. Nabel, Benjamin Poulter, Anna A. Romanovskaya, Simone Rossi, Hanqin Tian, Anthony P. Walker, Wenping Yuan, Xu Yue, and Julia Pongratz
Earth Syst. Sci. Data, 15, 1093–1114, https://doi.org/10.5194/essd-15-1093-2023, https://doi.org/10.5194/essd-15-1093-2023, 2023
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Striking differences exist in estimates of land-use CO2 fluxes between the national greenhouse gas inventories and the IPCC assessment reports. These differences hamper an accurate assessment of the collective progress under the Paris Agreement. By implementing an approach that conceptually reconciles land-use CO2 flux from national inventories and the global models used by the IPCC, our study is an important step forward for increasing confidence in land-use CO2 flux estimates.
Nasrin Mostafavi Pak, Jacob K. Hedelius, Sébastien Roche, Liz Cunningham, Bianca Baier, Colm Sweeney, Coleen Roehl, Joshua Laughner, Geoffrey Toon, Paul Wennberg, Harrison Parker, Colin Arrowsmith, Joseph Mendonca, Pierre Fogal, Tyler Wizenberg, Beatriz Herrera, Kimberly Strong, Kaley A. Walker, Felix Vogel, and Debra Wunch
Atmos. Meas. Tech., 16, 1239–1261, https://doi.org/10.5194/amt-16-1239-2023, https://doi.org/10.5194/amt-16-1239-2023, 2023
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Ground-based remote sensing instruments in the Total Carbon Column Observing Network (TCCON) measure greenhouse gases in the atmosphere. Consistency between TCCON measurements is crucial to accurately infer changes in atmospheric composition. We use portable remote sensing instruments (EM27/SUN) to evaluate biases between TCCON stations in North America. We also improve the retrievals of EM27/SUN instruments and evaluate the previous (GGG2014) and newest (GGG2020) retrieval algorithms.
Brendan Byrne, David F. Baker, Sourish Basu, Michael Bertolacci, Kevin W. Bowman, Dustin Carroll, Abhishek Chatterjee, Frédéric Chevallier, Philippe Ciais, Noel Cressie, David Crisp, Sean Crowell, Feng Deng, Zhu Deng, Nicholas M. Deutscher, Manvendra K. Dubey, Sha Feng, Omaira E. García, David W. T. Griffith, Benedikt Herkommer, Lei Hu, Andrew R. Jacobson, Rajesh Janardanan, Sujong Jeong, Matthew S. Johnson, Dylan B. A. Jones, Rigel Kivi, Junjie Liu, Zhiqiang Liu, Shamil Maksyutov, John B. Miller, Scot M. Miller, Isamu Morino, Justus Notholt, Tomohiro Oda, Christopher W. O'Dell, Young-Suk Oh, Hirofumi Ohyama, Prabir K. Patra, Hélène Peiro, Christof Petri, Sajeev Philip, David F. Pollard, Benjamin Poulter, Marine Remaud, Andrew Schuh, Mahesh K. Sha, Kei Shiomi, Kimberly Strong, Colm Sweeney, Yao Té, Hanqin Tian, Voltaire A. Velazco, Mihalis Vrekoussis, Thorsten Warneke, John R. Worden, Debra Wunch, Yuanzhi Yao, Jeongmin Yun, Andrew Zammit-Mangion, and Ning Zeng
Earth Syst. Sci. Data, 15, 963–1004, https://doi.org/10.5194/essd-15-963-2023, https://doi.org/10.5194/essd-15-963-2023, 2023
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Changes in the carbon stocks of terrestrial ecosystems result in emissions and removals of CO2. These can be driven by anthropogenic activities (e.g., deforestation), natural processes (e.g., fires) or in response to rising CO2 (e.g., CO2 fertilization). This paper describes a dataset of CO2 emissions and removals derived from atmospheric CO2 observations. This pilot dataset informs current capabilities and future developments towards top-down monitoring and verification systems.
Chuanlong Zhou, Biqing Zhu, Steven J. Davis, Zhu Liu, Antoine Halff, Simon Ben Arous, Hugo de Almeida Rodrigues, and Philippe Ciais
Earth Syst. Sci. Data, 15, 949–961, https://doi.org/10.5194/essd-15-949-2023, https://doi.org/10.5194/essd-15-949-2023, 2023
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Our work aims to analyze sectoral and country-based daily natural gas supply–storage–consumption based on ENTSOG, Eurostat, and multiple datasets in the EU27 and UK. We estimated the magnitude of the Russian gas gap if Russian gas imports were to stop as well as potential short-term solutions to fill this gap. Our datasets could be important in various fields, such as gas/energy consumption and market modeling, carbon emission and climate change research, and policy decision-making.
Valérie Gros, Bernard Bonsang, Roland Sarda-Estève, Anna Nikolopoulos, Katja Metfies, Matthias Wietz, and Ilka Peeken
Biogeosciences, 20, 851–867, https://doi.org/10.5194/bg-20-851-2023, https://doi.org/10.5194/bg-20-851-2023, 2023
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The oceans are both sources and sinks for trace gases important for atmospheric chemistry and marine ecology. Here, we quantified selected trace gases (including the biological metabolites dissolved dimethyl sulfide, methanethiol and isoprene) along a 2500 km transect from the North Atlantic to the Arctic Ocean. In the context of phytoplankton and bacterial communities, our study suggests that methanethiol (rarely measured before) might substantially influence ocean–atmosphere cycling.
Yann Quilcaille, Thomas Gasser, Philippe Ciais, and Olivier Boucher
Geosci. Model Dev., 16, 1129–1161, https://doi.org/10.5194/gmd-16-1129-2023, https://doi.org/10.5194/gmd-16-1129-2023, 2023
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The model OSCAR is a simple climate model, meaning its representation of the Earth system is simplified but calibrated on models of higher complexity. Here, we diagnose its latest version using a total of 99 experiments in a probabilistic framework and under observational constraints. OSCAR v3.1 shows good agreement with observations, complex Earth system models and emerging properties. Some points for improvements are identified, such as the ocean carbon cycle.
Yuan Zhang, Devaraju Narayanappa, Philippe Ciais, Wei Li, Daniel Goll, Nicolas Vuichard, Martin G. De Kauwe, Laurent Li, and Fabienne Maignan
Geosci. Model Dev., 15, 9111–9125, https://doi.org/10.5194/gmd-15-9111-2022, https://doi.org/10.5194/gmd-15-9111-2022, 2022
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There are a few studies to examine if current models correctly represented the complex processes of transpiration. Here, we use a coefficient Ω, which indicates if transpiration is mainly controlled by vegetation processes or by turbulence, to evaluate the ORCHIDEE model. We found a good performance of ORCHIDEE, but due to compensation of biases in different processes, we also identified how different factors control Ω and where the model is wrong. Our method is generic to evaluate other models.
Thomas Bossy, Thomas Gasser, and Philippe Ciais
Geosci. Model Dev., 15, 8831–8868, https://doi.org/10.5194/gmd-15-8831-2022, https://doi.org/10.5194/gmd-15-8831-2022, 2022
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We developed a new simple climate model designed to fill a perceived gap within the existing simple climate models by fulfilling three key requirements: calibration using Bayesian inference, the possibility of coupling with integrated assessment models, and the capacity to explore climate scenarios compatible with limiting climate impacts. Here, we describe the model and its calibration using the latest data from complex CMIP6 models and the IPCC AR6, and we assess its performance.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Luke Gregor, Judith Hauck, Corinne Le Quéré, Ingrid T. Luijkx, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Ramdane Alkama, Almut Arneth, Vivek K. Arora, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Henry C. Bittig, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Wiley Evans, Stefanie Falk, Richard A. Feely, Thomas Gasser, Marion Gehlen, Thanos Gkritzalis, Lucas Gloege, Giacomo Grassi, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Atul K. Jain, Annika Jersild, Koji Kadono, Etsushi Kato, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Peter Landschützer, Nathalie Lefèvre, Keith Lindsay, Junjie Liu, Zhu Liu, Gregg Marland, Nicolas Mayot, Matthew J. McGrath, Nicolas Metzl, Natalie M. Monacci, David R. Munro, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin O'Brien, Tsuneo Ono, Paul I. Palmer, Naiqing Pan, Denis Pierrot, Katie Pocock, Benjamin Poulter, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Carmen Rodriguez, Thais M. Rosan, Jörg Schwinger, Roland Séférian, Jamie D. Shutler, Ingunn Skjelvan, Tobias Steinhoff, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Shintaro Takao, Toste Tanhua, Pieter P. Tans, Xiangjun Tian, Hanqin Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Guido R. van der Werf, Anthony P. Walker, Rik Wanninkhof, Chris Whitehead, Anna Willstrand Wranne, Rebecca Wright, Wenping Yuan, Chao Yue, Xu Yue, Sönke Zaehle, Jiye Zeng, and Bo Zheng
Earth Syst. Sci. Data, 14, 4811–4900, https://doi.org/10.5194/essd-14-4811-2022, https://doi.org/10.5194/essd-14-4811-2022, 2022
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The Global Carbon Budget 2022 describes the datasets and methodology used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, the land ecosystems, and the ocean. These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Yitong Yao, Emilie Joetzjer, Philippe Ciais, Nicolas Viovy, Fabio Cresto Aleina, Jerome Chave, Lawren Sack, Megan Bartlett, Patrick Meir, Rosie Fisher, and Sebastiaan Luyssaert
Geosci. Model Dev., 15, 7809–7833, https://doi.org/10.5194/gmd-15-7809-2022, https://doi.org/10.5194/gmd-15-7809-2022, 2022
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To facilitate more mechanistic modeling of drought effects on forest dynamics, our study implements a hydraulic module to simulate the vertical water flow, change in water storage and percentage loss of stem conductance (PLC). With the relationship between PLC and tree mortality, our model can successfully reproduce the large biomass drop observed under throughfall exclusion. Our hydraulic module provides promising avenues benefiting the prediction for mortality under future drought events.
Arthur Nicolaus Fendrich, Philippe Ciais, Emanuele Lugato, Marco Carozzi, Bertrand Guenet, Pasquale Borrelli, Victoria Naipal, Matthew McGrath, Philippe Martin, and Panos Panagos
Geosci. Model Dev., 15, 7835–7857, https://doi.org/10.5194/gmd-15-7835-2022, https://doi.org/10.5194/gmd-15-7835-2022, 2022
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Currently, spatially explicit models for soil carbon stock can simulate the impacts of several changes. However, they do not incorporate the erosion, lateral transport, and deposition (ETD) of soil material. The present work developed ETD formulation, illustrated model calibration and validation for Europe, and presented the results for a depositional site. We expect that our work advances ETD models' description and facilitates their reproduction and incorporation in land surface models.
Elise Potier, Grégoire Broquet, Yilong Wang, Diego Santaren, Antoine Berchet, Isabelle Pison, Julia Marshall, Philippe Ciais, François-Marie Bréon, and Frédéric Chevallier
Atmos. Meas. Tech., 15, 5261–5288, https://doi.org/10.5194/amt-15-5261-2022, https://doi.org/10.5194/amt-15-5261-2022, 2022
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Atmospheric inversion at local–regional scales over Europe and pseudo-data assimilation are used to evaluate how CO2 and 14CO2 ground-based measurement networks could complement satellite CO2 imagers to monitor fossil fuel (FF) CO2 emissions. This combination significantly improves precision in the FF emission estimates in areas with a dense network but does not strongly support the separation of the FF from the biogenic signals or the spatio-temporal extrapolation of the satellite information.
Jan De Pue, José Miguel Barrios, Liyang Liu, Philippe Ciais, Alirio Arboleda, Rafiq Hamdi, Manuela Balzarolo, Fabienne Maignan, and Françoise Gellens-Meulenberghs
Biogeosciences, 19, 4361–4386, https://doi.org/10.5194/bg-19-4361-2022, https://doi.org/10.5194/bg-19-4361-2022, 2022
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The functioning of ecosystems involves numerous biophysical processes which interact with each other. Land surface models (LSMs) are used to describe these processes and form an essential component of climate models. In this paper, we evaluate the performance of three LSMs and their interactions with soil moisture and vegetation. Though we found room for improvement in the simulation of soil moisture and drought stress, the main cause of errors was related to the simulated growth of vegetation.
Anthony Rey-Pommier, Frédéric Chevallier, Philippe Ciais, Grégoire Broquet, Theodoros Christoudias, Jonilda Kushta, Didier Hauglustaine, and Jean Sciare
Atmos. Chem. Phys., 22, 11505–11527, https://doi.org/10.5194/acp-22-11505-2022, https://doi.org/10.5194/acp-22-11505-2022, 2022
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Emission inventories for air pollutants can be uncertain in developing countries. In order to overcome these uncertainties, we model nitrogen oxide emissions in Egypt using satellite retrievals. We detect a weekly cycle reflecting Egyptian social norms, an annual cycle consistent with electricity consumption and an activity drop due to the COVID-19 pandemic. However, discrepancies with inventories remain high, illustrating the needs for additional data to improve the potential of our method.
Haicheng Zhang, Ronny Lauerwald, Pierre Regnier, Philippe Ciais, Kristof Van Oost, Victoria Naipal, Bertrand Guenet, and Wenping Yuan
Earth Syst. Dynam., 13, 1119–1144, https://doi.org/10.5194/esd-13-1119-2022, https://doi.org/10.5194/esd-13-1119-2022, 2022
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We present a land surface model which can simulate the complete lateral transfer of sediment and carbon from land to ocean through rivers. Our model captures the water, sediment, and organic carbon discharges in European rivers well. Application of our model in Europe indicates that lateral carbon transfer can strongly change regional land carbon budgets by affecting organic carbon distribution and soil moisture.
Pierre Friedlingstein, Matthew W. Jones, Michael O'Sullivan, Robbie M. Andrew, Dorothee C. E. Bakker, Judith Hauck, Corinne Le Quéré, Glen P. Peters, Wouter Peters, Julia Pongratz, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Rob B. Jackson, Simone R. Alin, Peter Anthoni, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Laurent Bopp, Thi Tuyet Trang Chau, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Kim I. Currie, Bertrand Decharme, Laique M. Djeutchouang, Xinyu Dou, Wiley Evans, Richard A. Feely, Liang Feng, Thomas Gasser, Dennis Gilfillan, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Ingrid T. Luijkx, Atul Jain, Steve D. Jones, Etsushi Kato, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Arne Körtzinger, Peter Landschützer, Siv K. Lauvset, Nathalie Lefèvre, Sebastian Lienert, Junjie Liu, Gregg Marland, Patrick C. McGuire, Joe R. Melton, David R. Munro, Julia E. M. S. Nabel, Shin-Ichiro Nakaoka, Yosuke Niwa, Tsuneo Ono, Denis Pierrot, Benjamin Poulter, Gregor Rehder, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Thais M. Rosan, Jörg Schwinger, Clemens Schwingshackl, Roland Séférian, Adrienne J. Sutton, Colm Sweeney, Toste Tanhua, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Francesco Tubiello, Guido R. van der Werf, Nicolas Vuichard, Chisato Wada, Rik Wanninkhof, Andrew J. Watson, David Willis, Andrew J. Wiltshire, Wenping Yuan, Chao Yue, Xu Yue, Sönke Zaehle, and Jiye Zeng
Earth Syst. Sci. Data, 14, 1917–2005, https://doi.org/10.5194/essd-14-1917-2022, https://doi.org/10.5194/essd-14-1917-2022, 2022
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The Global Carbon Budget 2021 describes the data sets and methodology used to quantify the emissions of carbon dioxide and their partitioning among the atmosphere, land, and ocean. These living data are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Carlos Alberti, Frank Hase, Matthias Frey, Darko Dubravica, Thomas Blumenstock, Angelika Dehn, Paolo Castracane, Gregor Surawicz, Roland Harig, Bianca C. Baier, Caroline Bès, Jianrong Bi, Hartmut Boesch, André Butz, Zhaonan Cai, Jia Chen, Sean M. Crowell, Nicholas M. Deutscher, Dragos Ene, Jonathan E. Franklin, Omaira García, David Griffith, Bruno Grouiez, Michel Grutter, Abdelhamid Hamdouni, Sander Houweling, Neil Humpage, Nicole Jacobs, Sujong Jeong, Lilian Joly, Nicholas B. Jones, Denis Jouglet, Rigel Kivi, Ralph Kleinschek, Morgan Lopez, Diogo J. Medeiros, Isamu Morino, Nasrin Mostafavipak, Astrid Müller, Hirofumi Ohyama, Paul I. Palmer, Mahesh Pathakoti, David F. Pollard, Uwe Raffalski, Michel Ramonet, Robbie Ramsay, Mahesh Kumar Sha, Kei Shiomi, William Simpson, Wolfgang Stremme, Youwen Sun, Hiroshi Tanimoto, Yao Té, Gizaw Mengistu Tsidu, Voltaire A. Velazco, Felix Vogel, Masataka Watanabe, Chong Wei, Debra Wunch, Marcia Yamasoe, Lu Zhang, and Johannes Orphal
Atmos. Meas. Tech., 15, 2433–2463, https://doi.org/10.5194/amt-15-2433-2022, https://doi.org/10.5194/amt-15-2433-2022, 2022
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Space-borne greenhouse gas missions require ground-based validation networks capable of providing fiducial reference measurements. Here, considerable refinements of the calibration procedures for the COllaborative Carbon Column Observing Network (COCCON) are presented. Laboratory and solar side-by-side procedures for the characterization of the spectrometers have been refined and extended. Revised calibration factors for XCO2, XCO and XCH4 are provided, incorporating 47 new spectrometers.
Irina Melnikova, Olivier Boucher, Patricia Cadule, Katsumasa Tanaka, Thomas Gasser, Tomohiro Hajima, Yann Quilcaille, Hideo Shiogama, Roland Séférian, Kaoru Tachiiri, Nicolas Vuichard, Tokuta Yokohata, and Philippe Ciais
Earth Syst. Dynam., 13, 779–794, https://doi.org/10.5194/esd-13-779-2022, https://doi.org/10.5194/esd-13-779-2022, 2022
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The deployment of bioenergy crops for capturing carbon from the atmosphere facilitates global warming mitigation via generating negative CO2 emissions. Here, we explored the consequences of large-scale energy crops deployment on the land carbon cycle. The land-use change for energy crops leads to carbon emissions and loss of future potential increase in carbon uptake by natural ecosystems. This impact should be taken into account by the modeling teams and accounted for in mitigation policies.
Zhu Deng, Philippe Ciais, Zitely A. Tzompa-Sosa, Marielle Saunois, Chunjing Qiu, Chang Tan, Taochun Sun, Piyu Ke, Yanan Cui, Katsumasa Tanaka, Xin Lin, Rona L. Thompson, Hanqin Tian, Yuanzhi Yao, Yuanyuan Huang, Ronny Lauerwald, Atul K. Jain, Xiaoming Xu, Ana Bastos, Stephen Sitch, Paul I. Palmer, Thomas Lauvaux, Alexandre d'Aspremont, Clément Giron, Antoine Benoit, Benjamin Poulter, Jinfeng Chang, Ana Maria Roxana Petrescu, Steven J. Davis, Zhu Liu, Giacomo Grassi, Clément Albergel, Francesco N. Tubiello, Lucia Perugini, Wouter Peters, and Frédéric Chevallier
Earth Syst. Sci. Data, 14, 1639–1675, https://doi.org/10.5194/essd-14-1639-2022, https://doi.org/10.5194/essd-14-1639-2022, 2022
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In support of the global stocktake of the Paris Agreement on climate change, we proposed a method for reconciling the results of global atmospheric inversions with data from UNFCCC national greenhouse gas inventories (NGHGIs). Here, based on a new global harmonized database that we compiled from the UNFCCC NGHGIs and a comprehensive framework presented in this study to process the results of inversions, we compared their results of carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O).
Elodie Salmon, Fabrice Jégou, Bertrand Guenet, Line Jourdain, Chunjing Qiu, Vladislav Bastrikov, Christophe Guimbaud, Dan Zhu, Philippe Ciais, Philippe Peylin, Sébastien Gogo, Fatima Laggoun-Défarge, Mika Aurela, M. Syndonia Bret-Harte, Jiquan Chen, Bogdan H. Chojnicki, Housen Chu, Colin W. Edgar, Eugenie S. Euskirchen, Lawrence B. Flanagan, Krzysztof Fortuniak, David Holl, Janina Klatt, Olaf Kolle, Natalia Kowalska, Lars Kutzbach, Annalea Lohila, Lutz Merbold, Włodzimierz Pawlak, Torsten Sachs, and Klaudia Ziemblińska
Geosci. Model Dev., 15, 2813–2838, https://doi.org/10.5194/gmd-15-2813-2022, https://doi.org/10.5194/gmd-15-2813-2022, 2022
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A methane model that features methane production and transport by plants, the ebullition process and diffusion in soil, oxidation to CO2, and CH4 fluxes to the atmosphere has been embedded in the ORCHIDEE-PEAT land surface model, which includes an explicit representation of northern peatlands. This model, ORCHIDEE-PCH4, was calibrated and evaluated on 14 peatland sites. Results show that the model is sensitive to temperature and substrate availability over the top 75 cm of soil depth.
Benjamin Loubet, Pauline Buysse, Lais Gonzaga-Gomez, Florence Lafouge, Raluca Ciuraru, Céline Decuq, Julien Kammer, Sandy Bsaibes, Christophe Boissard, Brigitte Durand, Jean-Christophe Gueudet, Olivier Fanucci, Olivier Zurfluh, Letizia Abis, Nora Zannoni, François Truong, Dominique Baisnée, Roland Sarda-Estève, Michael Staudt, and Valérie Gros
Atmos. Chem. Phys., 22, 2817–2842, https://doi.org/10.5194/acp-22-2817-2022, https://doi.org/10.5194/acp-22-2817-2022, 2022
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Volatile organic compounds (VOCs) are precursors of tropospheric pollutants like ozone or aerosols. Emission by agricultural land was still poorly characterized. We report experimental measurements of ecosystem-scale VOC fluxes above a wheat field with a highly sensitive proton transfer mass spectrometer. We report the fluxes of 123 compounds and confirm that methanol is the most emitted VOC by wheat. The second most emitted compound was C6H4O. Around 75 % of the compounds were deposited.
Céline Gommet, Ronny Lauerwald, Philippe Ciais, Bertrand Guenet, Haicheng Zhang, and Pierre Regnier
Earth Syst. Dynam., 13, 393–418, https://doi.org/10.5194/esd-13-393-2022, https://doi.org/10.5194/esd-13-393-2022, 2022
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Dissolved organic carbon (DOC) leaching from soils into river networks is an important component of the land carbon (C) budget, but its spatiotemporal variation is not yet fully constrained. We use a land surface model to simulate the present-day land C budget at the European scale, including leaching of DOC from the soil. We found average leaching of 14.3 Tg C yr−1 (0.6 % of terrestrial net primary production) with seasonal variations. We determine runoff and temperature to be the main drivers.
Philippe Ciais, Ana Bastos, Frédéric Chevallier, Ronny Lauerwald, Ben Poulter, Josep G. Canadell, Gustaf Hugelius, Robert B. Jackson, Atul Jain, Matthew Jones, Masayuki Kondo, Ingrid T. Luijkx, Prabir K. Patra, Wouter Peters, Julia Pongratz, Ana Maria Roxana Petrescu, Shilong Piao, Chunjing Qiu, Celso Von Randow, Pierre Regnier, Marielle Saunois, Robert Scholes, Anatoly Shvidenko, Hanqin Tian, Hui Yang, Xuhui Wang, and Bo Zheng
Geosci. Model Dev., 15, 1289–1316, https://doi.org/10.5194/gmd-15-1289-2022, https://doi.org/10.5194/gmd-15-1289-2022, 2022
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The second phase of the Regional Carbon Cycle Assessment and Processes (RECCAP) will provide updated quantification and process understanding of CO2, CH4, and N2O emissions and sinks for ten regions of the globe. In this paper, we give definitions, review different methods, and make recommendations for estimating different components of the total land–atmosphere carbon exchange for each region in a consistent and complete approach.
Regina Gonzalez Moguel, Felix Vogel, Sébastien Ars, Hinrich Schaefer, Jocelyn C. Turnbull, and Peter M. J. Douglas
Atmos. Chem. Phys., 22, 2121–2133, https://doi.org/10.5194/acp-22-2121-2022, https://doi.org/10.5194/acp-22-2121-2022, 2022
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Evaluating methane (CH4) sources in the Athabasca oil sands region (AOSR) is crucial to effectively mitigate CH4 emissions. We tested the use of carbon isotopes to estimate source contributions from key CH4 sources in the AOSR and found that 56 ± 18 % of CH4 emissions originated from surface mining and processing facilities, 34 ± 18 % from tailings ponds, and 10 ± < 1 % from wetlands, confirming previous findings and showing that this method can be successfully used to partition CH4 sources.
Lore T. Verryckt, Sara Vicca, Leandro Van Langenhove, Clément Stahl, Dolores Asensio, Ifigenia Urbina, Romà Ogaya, Joan Llusià, Oriol Grau, Guille Peguero, Albert Gargallo-Garriga, Elodie A. Courtois, Olga Margalef, Miguel Portillo-Estrada, Philippe Ciais, Michael Obersteiner, Lucia Fuchslueger, Laynara F. Lugli, Pere-Roc Fernandez-Garberí, Helena Vallicrosa, Melanie Verlinden, Christian Ranits, Pieter Vermeir, Sabrina Coste, Erik Verbruggen, Laëtitia Bréchet, Jordi Sardans, Jérôme Chave, Josep Peñuelas, and Ivan A. Janssens
Earth Syst. Sci. Data, 14, 5–18, https://doi.org/10.5194/essd-14-5-2022, https://doi.org/10.5194/essd-14-5-2022, 2022
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We provide a comprehensive dataset of vertical profiles of photosynthesis and important leaf traits, including leaf N and P concentrations, from two 3-year, large-scale nutrient addition experiments conducted in two tropical rainforests in French Guiana. These data present a unique source of information to further improve model representations of the roles of N and P, and other leaf nutrients, in photosynthesis in tropical forests.
Jean-Eudes Petit, Jean-Charles Dupont, Olivier Favez, Valérie Gros, Yunjiang Zhang, Jean Sciare, Leila Simon, François Truong, Nicolas Bonnaire, Tanguy Amodeo, Robert Vautard, and Martial Haeffelin
Atmos. Chem. Phys., 21, 17167–17183, https://doi.org/10.5194/acp-21-17167-2021, https://doi.org/10.5194/acp-21-17167-2021, 2021
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The COVID-19 outbreak led to lockdowns at national scales in spring 2020. Large cuts in emissions occurred, but the quantitative assessment of their role from observations is hindered by weather and interannual variability. That is why we developed an innovative methodology in order to best characterize the impact of lockdown on atmospheric chemistry. We find that a local decrease in traffic-related pollutants triggered a decrease of secondary aerosols and an increase in ozone.
Adrian Chappell, Nicholas Webb, Mark Hennen, Charles Zender, Philippe Ciais, Kerstin Schepanski, Brandon Edwards, Nancy Ziegler, Sandra Jones, Yves Balkanski, Daniel Tong, John Leys, Stephan Heidenreich, Robert Hynes, David Fuchs, Zhenzhong Zeng, Marie Ekström, Matthew Baddock, Jeffrey Lee, and Tarek Kandakji
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2021-337, https://doi.org/10.5194/gmd-2021-337, 2021
Revised manuscript not accepted
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Dust emissions influence global climate while simultaneously reducing the productive potential and resilience of landscapes to climate stressors, together impacting food security and human health. Our results indicate that tuning dust emission models to dust in the atmosphere has hidden dust emission modelling weaknesses and its poor performance. Our new approach will reduce uncertainty and driven by prognostic albedo improve Earth System Models of aerosol effects on future environmental change.
Ana Bastos, René Orth, Markus Reichstein, Philippe Ciais, Nicolas Viovy, Sönke Zaehle, Peter Anthoni, Almut Arneth, Pierre Gentine, Emilie Joetzjer, Sebastian Lienert, Tammas Loughran, Patrick C. McGuire, Sungmin O, Julia Pongratz, and Stephen Sitch
Earth Syst. Dynam., 12, 1015–1035, https://doi.org/10.5194/esd-12-1015-2021, https://doi.org/10.5194/esd-12-1015-2021, 2021
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Temperate biomes in Europe are not prone to recurrent dry and hot conditions in summer. However, these conditions may become more frequent in the coming decades. Because stress conditions can leave legacies for many years, this may result in reduced ecosystem resilience under recurrent stress. We assess vegetation vulnerability to the hot and dry summers in 2018 and 2019 in Europe and find the important role of inter-annual legacy effects from 2018 in modulating the impacts of the 2019 event.
Alex Resovsky, Michel Ramonet, Leonard Rivier, Jerome Tarniewicz, Philippe Ciais, Martin Steinbacher, Ivan Mammarella, Meelis Mölder, Michal Heliasz, Dagmar Kubistin, Matthias Lindauer, Jennifer Müller-Williams, Sebastien Conil, and Richard Engelen
Atmos. Meas. Tech., 14, 6119–6135, https://doi.org/10.5194/amt-14-6119-2021, https://doi.org/10.5194/amt-14-6119-2021, 2021
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We present a technical description of a statistical methodology for extracting synoptic- and seasonal-length anomalies from greenhouse gas time series. The definition of what represents an anomalous signal is somewhat subjective, which we touch on throughout the paper. We show, however, that the method performs reasonably well in extracting portions of time series influenced by significant North Atlantic Oscillation weather episodes and continent-wide terrestrial biospheric aberrations.
Alexandre Kukui, Michel Chartier, Jinhe Wang, Hui Chen, Sébastien Dusanter, Stéphane Sauvage, Vincent Michoud, Nadine Locoge, Valérie Gros, Thierry Bourrianne, Karine Sellegri, and Jean-Marc Pichon
Atmos. Chem. Phys., 21, 13333–13351, https://doi.org/10.5194/acp-21-13333-2021, https://doi.org/10.5194/acp-21-13333-2021, 2021
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Sulfuric acid, H2SO4, plays a key role in formation of secondary atmospheric aerosol particles. It is generally accepted that the major atmospheric source of H2SO4 is the reaction of OH radicals with SO2. In this study, importance of an additional H2SO4 source via oxidation of SO2 by stabilized Criegee intermediates was estimated based on measurements at a remote site on Cape Corsica. It was found that the oxidation of SO2 by SCI may be an important source of H2SO4, especially during nighttime.
Pramod Kumar, Grégoire Broquet, Camille Yver-Kwok, Olivier Laurent, Susan Gichuki, Christopher Caldow, Ford Cropley, Thomas Lauvaux, Michel Ramonet, Guillaume Berthe, Frédéric Martin, Olivier Duclaux, Catherine Juery, Caroline Bouchet, and Philippe Ciais
Atmos. Meas. Tech., 14, 5987–6003, https://doi.org/10.5194/amt-14-5987-2021, https://doi.org/10.5194/amt-14-5987-2021, 2021
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This study presents a simple atmospheric inversion modeling framework for the localization and quantification of unknown CH4 and CO2 emissions from point sources based on near-surface mobile concentration measurements and a Gaussian plume dispersion model. It is applied for the estimate of a series of brief controlled releases of CH4 and CO2 with a wide range of rates during the TOTAL TADI-2018 experiment. Results indicate a ~10 %–40 % average error on the estimate of the release rates.
Yuanyuan Huang, Phillipe Ciais, Maurizio Santoro, David Makowski, Jerome Chave, Dmitry Schepaschenko, Rose Z. Abramoff, Daniel S. Goll, Hui Yang, Ye Chen, Wei Wei, and Shilong Piao
Earth Syst. Sci. Data, 13, 4263–4274, https://doi.org/10.5194/essd-13-4263-2021, https://doi.org/10.5194/essd-13-4263-2021, 2021
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Roots play a key role in our Earth system. Here we combine 10 307 field measurements of forest root biomass worldwide with global observations of forest structure, climatic conditions, topography, land management and soil characteristics to derive a spatially explicit global high-resolution (~ 1 km) root biomass dataset. In total, 142 ± 25 (95 % CI) Pg of live dry-matter biomass is stored belowground, representing a global average root : shoot biomass ratio of 0.25 ± 0.10.
Yi Yin, Frederic Chevallier, Philippe Ciais, Philippe Bousquet, Marielle Saunois, Bo Zheng, John Worden, A. Anthony Bloom, Robert J. Parker, Daniel J. Jacob, Edward J. Dlugokencky, and Christian Frankenberg
Atmos. Chem. Phys., 21, 12631–12647, https://doi.org/10.5194/acp-21-12631-2021, https://doi.org/10.5194/acp-21-12631-2021, 2021
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The growth of methane, the second-most important anthropogenic greenhouse gas after carbon dioxide, has been accelerating in recent years. Using an ensemble of multi-tracer atmospheric inversions constrained by surface or satellite observations, we show that global methane emissions increased by nearly 1 % per year from 2010–2017, with leading contributions from the tropics and East Asia.
Sara M. Defratyka, Jean-Daniel Paris, Camille Yver-Kwok, Daniel Loeb, James France, Jon Helmore, Nigel Yarrow, Valérie Gros, and Philippe Bousquet
Atmos. Meas. Tech., 14, 5049–5069, https://doi.org/10.5194/amt-14-5049-2021, https://doi.org/10.5194/amt-14-5049-2021, 2021
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We consider the possibility of using the CRDS Picarro G2201-i instrument, originally designed for isotopic CH4 and CO2, for measurements of ethane : methane in near-source conditions. The work involved laboratory tests, a controlled release experiment and mobile measurements. We show the potential of determining ethane : methane with 50 ppb ethane uncertainty. The instrument can correctly estimate the ratio in CH4 enhancements of 1 ppm and more, as can be found at strongly emitting sites.
Yidi Xu, Philippe Ciais, Le Yu, Wei Li, Xiuzhi Chen, Haicheng Zhang, Chao Yue, Kasturi Kanniah, Arthur P. Cracknell, and Peng Gong
Geosci. Model Dev., 14, 4573–4592, https://doi.org/10.5194/gmd-14-4573-2021, https://doi.org/10.5194/gmd-14-4573-2021, 2021
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In this study, we implemented the specific morphology, phenology and harvest process of oil palm in the global land surface model ORCHIDEE-MICT. The improved model generally reproduces the same leaf area index, biomass density and life cycle fruit yield as observations. This explicit representation of oil palm in a global land surface model offers a useful tool for understanding the ecological processes of oil palm growth and assessing the environmental impacts of oil palm plantations.
Jinghui Lian, François-Marie Bréon, Grégoire Broquet, Thomas Lauvaux, Bo Zheng, Michel Ramonet, Irène Xueref-Remy, Simone Kotthaus, Martial Haeffelin, and Philippe Ciais
Atmos. Chem. Phys., 21, 10707–10726, https://doi.org/10.5194/acp-21-10707-2021, https://doi.org/10.5194/acp-21-10707-2021, 2021
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Currently there is growing interest in monitoring city-scale CO2 emissions based on atmospheric CO2 measurements, atmospheric transport modeling, and inversion technique. We analyze the various sources of uncertainty that impact the atmospheric CO2 modeling and that may compromise the potential of this method for the monitoring of CO2 emission over Paris. Results suggest selection criteria for the assimilation of CO2 measurements into the inversion system that aims at retrieving city emissions.
Elisa Bruni, Bertrand Guenet, Yuanyuan Huang, Hugues Clivot, Iñigo Virto, Roberta Farina, Thomas Kätterer, Philippe Ciais, Manuel Martin, and Claire Chenu
Biogeosciences, 18, 3981–4004, https://doi.org/10.5194/bg-18-3981-2021, https://doi.org/10.5194/bg-18-3981-2021, 2021
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Increasing soil organic carbon (SOC) stocks is beneficial for climate change mitigation and food security. One way to enhance SOC stocks is to increase carbon input to the soil. We estimate the amount of carbon input required to reach a 4 % annual increase in SOC stocks in 14 long-term agricultural experiments around Europe. We found that annual carbon input should increase by 43 % under current temperature conditions, by 54 % for a 1 °C warming scenario and by 120 % for a 5 °C warming scenario.
Bowen Cao, Le Yu, Victoria Naipal, Philippe Ciais, Wei Li, Yuanyuan Zhao, Wei Wei, Die Chen, Zhuang Liu, and Peng Gong
Earth Syst. Sci. Data, 13, 2437–2456, https://doi.org/10.5194/essd-13-2437-2021, https://doi.org/10.5194/essd-13-2437-2021, 2021
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In this study, the first 30 m resolution terrace map of China was developed through supervised pixel-based classification using multisource, multi-temporal data based on the Google Earth Engine platform. The classification performed well with an overall accuracy of 94 %. The terrace mapping algorithm can be used to map large-scale terraces in other regions globally, and the terrace map will be valuable for studies on soil erosion, carbon cycle, and ecosystem service assessments.
Ana Maria Roxana Petrescu, Chunjing Qiu, Philippe Ciais, Rona L. Thompson, Philippe Peylin, Matthew J. McGrath, Efisio Solazzo, Greet Janssens-Maenhout, Francesco N. Tubiello, Peter Bergamaschi, Dominik Brunner, Glen P. Peters, Lena Höglund-Isaksson, Pierre Regnier, Ronny Lauerwald, David Bastviken, Aki Tsuruta, Wilfried Winiwarter, Prabir K. Patra, Matthias Kuhnert, Gabriel D. Oreggioni, Monica Crippa, Marielle Saunois, Lucia Perugini, Tiina Markkanen, Tuula Aalto, Christine D. Groot Zwaaftink, Hanqin Tian, Yuanzhi Yao, Chris Wilson, Giulia Conchedda, Dirk Günther, Adrian Leip, Pete Smith, Jean-Matthieu Haussaire, Antti Leppänen, Alistair J. Manning, Joe McNorton, Patrick Brockmann, and Albertus Johannes Dolman
Earth Syst. Sci. Data, 13, 2307–2362, https://doi.org/10.5194/essd-13-2307-2021, https://doi.org/10.5194/essd-13-2307-2021, 2021
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This study is topical and provides a state-of-the-art scientific overview of data availability from bottom-up and top-down CH4 and N2O emissions in the EU27 and UK. The data integrate recent emission inventories with process-based model data and regional/global inversions for the European domain, aiming at reconciling them with official country-level UNFCCC national GHG inventories in support to policy and to facilitate real-time verification procedures.
Ana Maria Roxana Petrescu, Matthew J. McGrath, Robbie M. Andrew, Philippe Peylin, Glen P. Peters, Philippe Ciais, Gregoire Broquet, Francesco N. Tubiello, Christoph Gerbig, Julia Pongratz, Greet Janssens-Maenhout, Giacomo Grassi, Gert-Jan Nabuurs, Pierre Regnier, Ronny Lauerwald, Matthias Kuhnert, Juraj Balkovič, Mart-Jan Schelhaas, Hugo A. C. Denier van der
Gon, Efisio Solazzo, Chunjing Qiu, Roberto Pilli, Igor B. Konovalov, Richard A. Houghton, Dirk Günther, Lucia Perugini, Monica Crippa, Raphael Ganzenmüller, Ingrid T. Luijkx, Pete Smith, Saqr Munassar, Rona L. Thompson, Giulia Conchedda, Guillaume Monteil, Marko Scholze, Ute Karstens, Patrick Brockmann, and Albertus Johannes Dolman
Earth Syst. Sci. Data, 13, 2363–2406, https://doi.org/10.5194/essd-13-2363-2021, https://doi.org/10.5194/essd-13-2363-2021, 2021
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This study is topical and provides a state-of-the-art scientific overview of data availability from bottom-up and top-down CO2 fossil emissions and CO2 land fluxes in the EU27+UK. The data integrate recent emission inventories with ecosystem data, land carbon models and regional/global inversions for the European domain, aiming at reconciling CO2 estimates with official country-level UNFCCC national GHG inventories in support to policy and facilitating real-time verification procedures.
Rui Guo, Jiaoyue Wang, Longfei Bing, Dan Tong, Philippe Ciais, Steven J. Davis, Robbie M. Andrew, Fengming Xi, and Zhu Liu
Earth Syst. Sci. Data, 13, 1791–1805, https://doi.org/10.5194/essd-13-1791-2021, https://doi.org/10.5194/essd-13-1791-2021, 2021
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Using a life-cycle approach, we estimated the CO2 process emission and uptake of cement materials produced and consumed from 1930 to 2019; ~21 Gt of CO2, about 55 % of the total process emission, had been abated through cement carbonation. China contributed the greatest to the cumulative uptake, with more than 6 Gt (~30 % of the world total), while ~59 %, or more than 12 Gt, of the total uptake was attributed to mortar. Cement CO2 uptake makes up a considerable part of the human carbon budget.
Wei Min Hao, Matthew C. Reeves, L. Scott Baggett, Yves Balkanski, Philippe Ciais, Bryce L. Nordgren, Alexander Petkov, Rachel E. Corley, Florent Mouillot, Shawn P. Urbanski, and Chao Yue
Biogeosciences, 18, 2559–2572, https://doi.org/10.5194/bg-18-2559-2021, https://doi.org/10.5194/bg-18-2559-2021, 2021
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We examined the trends in the spatial and temporal distribution of the area burned in northern Eurasia from 2002 to 2016. The annual area burned in this region declined by 53 % during the 15-year period under analysis. Grassland fires in Kazakhstan dominated the fire activity, comprising 47 % of the area burned but accounting for 84 % of the decline. A wetter climate and the increase in grazing livestock in Kazakhstan are the major factors contributing to the decline in the area burned.
Yuan Zhang, Olivier Boucher, Philippe Ciais, Laurent Li, and Nicolas Bellouin
Geosci. Model Dev., 14, 2029–2039, https://doi.org/10.5194/gmd-14-2029-2021, https://doi.org/10.5194/gmd-14-2029-2021, 2021
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We investigated different methods to reconstruct spatiotemporal distribution of the fraction of diffuse radiation (Fdf) to qualify the aerosol impacts on GPP using the ORCHIDEE_DF land surface model. We find that climatological-averaging methods which dampen the variability of Fdf can cause significant bias in the modeled diffuse radiation impacts on GPP. Better methods to reconstruct Fdf are recommended.
Yan Sun, Daniel S. Goll, Jinfeng Chang, Philippe Ciais, Betrand Guenet, Julian Helfenstein, Yuanyuan Huang, Ronny Lauerwald, Fabienne Maignan, Victoria Naipal, Yilong Wang, Hui Yang, and Haicheng Zhang
Geosci. Model Dev., 14, 1987–2010, https://doi.org/10.5194/gmd-14-1987-2021, https://doi.org/10.5194/gmd-14-1987-2021, 2021
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We evaluated the performance of the nutrient-enabled version of the land surface model ORCHIDEE-CNP v1.2 against remote sensing, ground-based measurement networks and ecological databases. The simulated carbon, nitrogen and phosphorus fluxes among different spatial scales are generally in good agreement with data-driven estimates. However, the recent carbon sink in the Northern Hemisphere is substantially underestimated. Potential causes and model development priorities are discussed.
Bruno Ringeval, Christoph Müller, Thomas A. M. Pugh, Nathaniel D. Mueller, Philippe Ciais, Christian Folberth, Wenfeng Liu, Philippe Debaeke, and Sylvain Pellerin
Geosci. Model Dev., 14, 1639–1656, https://doi.org/10.5194/gmd-14-1639-2021, https://doi.org/10.5194/gmd-14-1639-2021, 2021
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We assess how and why global gridded crop models (GGCMs) differ in their simulation of potential yield. We build a GCCM emulator based on generic formalism and fit its parameters against aboveground biomass and yield at harvest simulated by eight GGCMs. Despite huge differences between GGCMs, we show that the calibration of a few key parameters allows the emulator to reproduce the GGCM simulations. Our simple but mechanistic model could help to improve the global simulation of potential yield.
Zun Yin, Catherine Ottlé, Philippe Ciais, Feng Zhou, Xuhui Wang, Polcher Jan, Patrice Dumas, Shushi Peng, Laurent Li, Xudong Zhou, Yan Bo, Yi Xi, and Shilong Piao
Hydrol. Earth Syst. Sci., 25, 1133–1150, https://doi.org/10.5194/hess-25-1133-2021, https://doi.org/10.5194/hess-25-1133-2021, 2021
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We improved the irrigation module in a land surface model ORCHIDEE and developed a dam operation model with the aim to investigate how irrigation and dams affect the streamflow fluctuations of the Yellow River. Results show that irrigation mainly reduces the annual river flow. The dam operation, however, mainly affects streamflow variation. By considering two generic operation rules, flood control and base flow guarantee, our dam model can sustainably improve the simulation accuracy.
Cécile Debevec, Stéphane Sauvage, Valérie Gros, Thérèse Salameh, Jean Sciare, François Dulac, and Nadine Locoge
Atmos. Chem. Phys., 21, 1449–1484, https://doi.org/10.5194/acp-21-1449-2021, https://doi.org/10.5194/acp-21-1449-2021, 2021
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This study provides a better characterization of the seasonal variations in VOC sources impacting the western Mediterranean region, based on a comprehensive chemical composition measured over 25 months at a representative receptor site (Ersa) and by determining factors controlling their temporal variations. Some insights into dominant drivers for VOC concentration variations in Europe are also provided, built on comparisons of Ersa observations with the concomitant ones of 17 European sites.
Diego Santaren, Grégoire Broquet, François-Marie Bréon, Frédéric Chevallier, Denis Siméoni, Bo Zheng, and Philippe Ciais
Atmos. Meas. Tech., 14, 403–433, https://doi.org/10.5194/amt-14-403-2021, https://doi.org/10.5194/amt-14-403-2021, 2021
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Atmospheric transport inversions with synthetic data are used to assess the potential of new satellite observations of atmospheric CO2 to monitor anthropogenic emissions from regions, cities and large industrial plants. The analysis, applied to a large ensemble of sources in western Europe, shows a strong dependence of the results on different characteristics of the spaceborne instrument, on the source emission budgets and spreads, and on the wind conditions.
Adam Hastie, Ronny Lauerwald, Philippe Ciais, Fabrice Papa, and Pierre Regnier
Earth Syst. Dynam., 12, 37–62, https://doi.org/10.5194/esd-12-37-2021, https://doi.org/10.5194/esd-12-37-2021, 2021
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We used a model of the Congo Basin to investigate the transfer of carbon (C) from land (vegetation and soils) to inland waters. We estimate that leaching of C to inland waters, emissions of CO2 from the water surface, and the export of C to the coast have all increased over the last century, driven by increasing atmospheric CO2 levels and climate change. We predict that these trends may continue through the 21st century and call for long-term monitoring of these fluxes.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Judith Hauck, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Stephen Sitch, Corinne Le Quéré, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone Alin, Luiz E. O. C. Aragão, Almut Arneth, Vivek Arora, Nicholas R. Bates, Meike Becker, Alice Benoit-Cattin, Henry C. Bittig, Laurent Bopp, Selma Bultan, Naveen Chandra, Frédéric Chevallier, Louise P. Chini, Wiley Evans, Liesbeth Florentie, Piers M. Forster, Thomas Gasser, Marion Gehlen, Dennis Gilfillan, Thanos Gkritzalis, Luke Gregor, Nicolas Gruber, Ian Harris, Kerstin Hartung, Vanessa Haverd, Richard A. Houghton, Tatiana Ilyina, Atul K. Jain, Emilie Joetzjer, Koji Kadono, Etsushi Kato, Vassilis Kitidis, Jan Ivar Korsbakken, Peter Landschützer, Nathalie Lefèvre, Andrew Lenton, Sebastian Lienert, Zhu Liu, Danica Lombardozzi, Gregg Marland, Nicolas Metzl, David R. Munro, Julia E. M. S. Nabel, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin O'Brien, Tsuneo Ono, Paul I. Palmer, Denis Pierrot, Benjamin Poulter, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Jörg Schwinger, Roland Séférian, Ingunn Skjelvan, Adam J. P. Smith, Adrienne J. Sutton, Toste Tanhua, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Guido van der Werf, Nicolas Vuichard, Anthony P. Walker, Rik Wanninkhof, Andrew J. Watson, David Willis, Andrew J. Wiltshire, Wenping Yuan, Xu Yue, and Sönke Zaehle
Earth Syst. Sci. Data, 12, 3269–3340, https://doi.org/10.5194/essd-12-3269-2020, https://doi.org/10.5194/essd-12-3269-2020, 2020
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The Global Carbon Budget 2020 describes the data sets and methodology used to quantify the emissions of carbon dioxide and their partitioning among the atmosphere, land, and ocean. These living data are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Yilong Wang, Grégoire Broquet, François-Marie Bréon, Franck Lespinas, Michael Buchwitz, Maximilian Reuter, Yasjka Meijer, Armin Loescher, Greet Janssens-Maenhout, Bo Zheng, and Philippe Ciais
Geosci. Model Dev., 13, 5813–5831, https://doi.org/10.5194/gmd-13-5813-2020, https://doi.org/10.5194/gmd-13-5813-2020, 2020
Yuan Zhang, Ana Bastos, Fabienne Maignan, Daniel Goll, Olivier Boucher, Laurent Li, Alessandro Cescatti, Nicolas Vuichard, Xiuzhi Chen, Christof Ammann, M. Altaf Arain, T. Andrew Black, Bogdan Chojnicki, Tomomichi Kato, Ivan Mammarella, Leonardo Montagnani, Olivier Roupsard, Maria J. Sanz, Lukas Siebicke, Marek Urbaniak, Francesco Primo Vaccari, Georg Wohlfahrt, Will Woodgate, and Philippe Ciais
Geosci. Model Dev., 13, 5401–5423, https://doi.org/10.5194/gmd-13-5401-2020, https://doi.org/10.5194/gmd-13-5401-2020, 2020
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We improved the ORCHIDEE LSM by distinguishing diffuse and direct light in canopy and evaluated the new model with observations from 159 sites. Compared with the old model, the new model has better sunny GPP and reproduced the diffuse light fertilization effect observed at flux sites. Our simulations also indicate different mechanisms causing the observed GPP enhancement under cloudy conditions at different times. The new model has the potential to study large-scale impacts of aerosol changes.
Guillaume Monteil, Grégoire Broquet, Marko Scholze, Matthew Lang, Ute Karstens, Christoph Gerbig, Frank-Thomas Koch, Naomi E. Smith, Rona L. Thompson, Ingrid T. Luijkx, Emily White, Antoon Meesters, Philippe Ciais, Anita L. Ganesan, Alistair Manning, Michael Mischurow, Wouter Peters, Philippe Peylin, Jerôme Tarniewicz, Matt Rigby, Christian Rödenbeck, Alex Vermeulen, and Evie M. Walton
Atmos. Chem. Phys., 20, 12063–12091, https://doi.org/10.5194/acp-20-12063-2020, https://doi.org/10.5194/acp-20-12063-2020, 2020
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The paper presents the first results from the EUROCOM project, a regional atmospheric inversion intercomparison exercise involving six European research groups. It aims to produce an estimate of the net carbon flux between the European terrestrial ecosystems and the atmosphere for the period 2006–2015, based on constraints provided by observed CO2 concentrations and using inverse modelling techniques. The use of six different models enables us to investigate the robustness of the results.
Ashish Kumar, Vinayak Sinha, Muhammed Shabin, Haseeb Hakkim, Bernard Bonsang, and Valerie Gros
Atmos. Chem. Phys., 20, 12133–12152, https://doi.org/10.5194/acp-20-12133-2020, https://doi.org/10.5194/acp-20-12133-2020, 2020
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Source apportionment studies require information on the chemical fingerprints of pollution sources to correctly quantify source contributions to ambient composition. These chemical fingerprints vary from region to region, depending on fuel composition and combustion conditions, and are poorly constrained over developing regions such as South Asia. This work characterises the chemical fingerprints of urban and agricultural sources using 49 non-methane hydrocarbons and their environmental impacts.
Thomas Gasser, Léa Crepin, Yann Quilcaille, Richard A. Houghton, Philippe Ciais, and Michael Obersteiner
Biogeosciences, 17, 4075–4101, https://doi.org/10.5194/bg-17-4075-2020, https://doi.org/10.5194/bg-17-4075-2020, 2020
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We combine several lines of evidence to provide a robust estimate of historical CO2 emissions from land use change. Our novel approach leads to reduced uncertainty and identifies key remaining sources of uncertainty and discrepancy.
We also quantify the carbon removal by natural ecosystems that would have occurred if these ecosystems had not been destroyed (mostly via deforestation). Over the last decade, this foregone carbon sink amounted to about 50 % of the actual emissions.
Xianfeng Liu, Xiaoming Feng, Philippe Ciais, and Bojie Fu
Hydrol. Earth Syst. Sci., 24, 3663–3676, https://doi.org/10.5194/hess-24-3663-2020, https://doi.org/10.5194/hess-24-3663-2020, 2020
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Freshwater availability is crucial for sustainable development across the Asian and eastern European regions. Our results indicate widespread decline in terrestrial water storage (TWS) over the region during 2002–2017, primarily due to the intensive over-extraction of groundwater and warmth-induced surface water loss. The findings provide insights into changes in TWS and its components over the Asian and eastern European regions, where there is growing demand for food grains and water supplies.
Bo Zheng, Frédéric Chevallier, Philippe Ciais, Grégoire Broquet, Yilong Wang, Jinghui Lian, and Yuanhong Zhao
Atmos. Chem. Phys., 20, 8501–8510, https://doi.org/10.5194/acp-20-8501-2020, https://doi.org/10.5194/acp-20-8501-2020, 2020
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The Paris Climate Agreement requires all parties to report CO2 emissions regularly. Given the self-reporting nature of this system, it is critical to evaluate the emission reports with independent observation systems. Here we present the direct observations of city CO2 plumes from space and the quantification of CO2 emissions from these observations over the largest emitter country China. The emissions from 46 hot-spot regions representing 13 % of China's total emissions can be well constrained.
Marielle Saunois, Ann R. Stavert, Ben Poulter, Philippe Bousquet, Josep G. Canadell, Robert B. Jackson, Peter A. Raymond, Edward J. Dlugokencky, Sander Houweling, Prabir K. Patra, Philippe Ciais, Vivek K. Arora, David Bastviken, Peter Bergamaschi, Donald R. Blake, Gordon Brailsford, Lori Bruhwiler, Kimberly M. Carlson, Mark Carrol, Simona Castaldi, Naveen Chandra, Cyril Crevoisier, Patrick M. Crill, Kristofer Covey, Charles L. Curry, Giuseppe Etiope, Christian Frankenberg, Nicola Gedney, Michaela I. Hegglin, Lena Höglund-Isaksson, Gustaf Hugelius, Misa Ishizawa, Akihiko Ito, Greet Janssens-Maenhout, Katherine M. Jensen, Fortunat Joos, Thomas Kleinen, Paul B. Krummel, Ray L. Langenfelds, Goulven G. Laruelle, Licheng Liu, Toshinobu Machida, Shamil Maksyutov, Kyle C. McDonald, Joe McNorton, Paul A. Miller, Joe R. Melton, Isamu Morino, Jurek Müller, Fabiola Murguia-Flores, Vaishali Naik, Yosuke Niwa, Sergio Noce, Simon O'Doherty, Robert J. Parker, Changhui Peng, Shushi Peng, Glen P. Peters, Catherine Prigent, Ronald Prinn, Michel Ramonet, Pierre Regnier, William J. Riley, Judith A. Rosentreter, Arjo Segers, Isobel J. Simpson, Hao Shi, Steven J. Smith, L. Paul Steele, Brett F. Thornton, Hanqin Tian, Yasunori Tohjima, Francesco N. Tubiello, Aki Tsuruta, Nicolas Viovy, Apostolos Voulgarakis, Thomas S. Weber, Michiel van Weele, Guido R. van der Werf, Ray F. Weiss, Doug Worthy, Debra Wunch, Yi Yin, Yukio Yoshida, Wenxin Zhang, Zhen Zhang, Yuanhong Zhao, Bo Zheng, Qing Zhu, Qiuan Zhu, and Qianlai Zhuang
Earth Syst. Sci. Data, 12, 1561–1623, https://doi.org/10.5194/essd-12-1561-2020, https://doi.org/10.5194/essd-12-1561-2020, 2020
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Understanding and quantifying the global methane (CH4) budget is important for assessing realistic pathways to mitigate climate change. We have established a consortium of multidisciplinary scientists under the umbrella of the Global Carbon Project to synthesize and stimulate new research aimed at improving and regularly updating the global methane budget. This is the second version of the review dedicated to the decadal methane budget, integrating results of top-down and bottom-up estimates.
James A. Franke, Christoph Müller, Joshua Elliott, Alex C. Ruane, Jonas Jägermeyr, Juraj Balkovic, Philippe Ciais, Marie Dury, Pete D. Falloon, Christian Folberth, Louis François, Tobias Hank, Munir Hoffmann, R. Cesar Izaurralde, Ingrid Jacquemin, Curtis Jones, Nikolay Khabarov, Marian Koch, Michelle Li, Wenfeng Liu, Stefan Olin, Meridel Phillips, Thomas A. M. Pugh, Ashwan Reddy, Xuhui Wang, Karina Williams, Florian Zabel, and Elisabeth J. Moyer
Geosci. Model Dev., 13, 2315–2336, https://doi.org/10.5194/gmd-13-2315-2020, https://doi.org/10.5194/gmd-13-2315-2020, 2020
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Concerns about food security under climate change motivate efforts to better understand future changes in crop yields. Crop models, which represent plant biology, are necessary tools for this purpose since they allow representing future climate, farmer choices, and new agricultural geographies. The Global Gridded Crop Model Intercomparison (GGCMI) Phase 2 experiment, under the Agricultural Model Intercomparison and Improvement Project (AgMIP), is designed to evaluate and improve crop models.
Claudia Grossi, Scott D. Chambers, Olivier Llido, Felix R. Vogel, Victor Kazan, Alessandro Capuana, Sylvester Werczynski, Roger Curcoll, Marc Delmotte, Arturo Vargas, Josep-Anton Morguí, Ingeborg Levin, and Michel Ramonet
Atmos. Meas. Tech., 13, 2241–2255, https://doi.org/10.5194/amt-13-2241-2020, https://doi.org/10.5194/amt-13-2241-2020, 2020
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The sustainable support of radon metrology at the environmental level offers new scientific possibilities for the quantification of greenhouse gas (GHG) emissions and the determination of their source terms as well as for the identification of radioactive sources for the assessment of radiation exposure. This study helps to harmonize the techniques commonly used for atmospheric radon and radon progeny activity concentration measurements.
Ana Maria Roxana Petrescu, Glen P. Peters, Greet Janssens-Maenhout, Philippe Ciais, Francesco N. Tubiello, Giacomo Grassi, Gert-Jan Nabuurs, Adrian Leip, Gema Carmona-Garcia, Wilfried Winiwarter, Lena Höglund-Isaksson, Dirk Günther, Efisio Solazzo, Anja Kiesow, Ana Bastos, Julia Pongratz, Julia E. M. S. Nabel, Giulia Conchedda, Roberto Pilli, Robbie M. Andrew, Mart-Jan Schelhaas, and Albertus J. Dolman
Earth Syst. Sci. Data, 12, 961–1001, https://doi.org/10.5194/essd-12-961-2020, https://doi.org/10.5194/essd-12-961-2020, 2020
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This study is topical and provides a state-of-the-art scientific overview of data availability from bottom-up GHG anthropogenic emissions from agriculture, forestry and other land use (AFOLU) in the EU28. The data integrate recent AFOLU emission inventories with ecosystem data and land carbon models, aiming at reconciling GHG budgets with official country-level UNFCCC inventories. We provide comprehensive emission assessments in support to policy, facilitating real-time verification procedures.
Yidi Xu, Le Yu, Wei Li, Philippe Ciais, Yuqi Cheng, and Peng Gong
Earth Syst. Sci. Data, 12, 847–867, https://doi.org/10.5194/essd-12-847-2020, https://doi.org/10.5194/essd-12-847-2020, 2020
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The first annual oil palm area dataset (AOPD) for Malaysia and Indonesia from 2001 to 2016 was produced by integrating multiple satellite datasets and a change-detection algorithm (BFAST). This dataset reveals that oil palm plantations have expanded from 5.69 to 19.05 M ha in the two countries during the past 16 years. The AOPD is useful in understanding the deforestation process in Southeast Asia and may serve as land-use change inputs in dynamic global vegetation models.
Didier G. Leibovici, Shaun Quegan, Edward Comyn-Platt, Garry Hayman, Maria Val Martin, Mathieu Guimberteau, Arsène Druel, Dan Zhu, and Philippe Ciais
Biogeosciences, 17, 1821–1844, https://doi.org/10.5194/bg-17-1821-2020, https://doi.org/10.5194/bg-17-1821-2020, 2020
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Analysing the impact of environmental changes due to climate change, e.g. geographical spread of climate-sensitive infections (CSIs) and agriculture crop modelling, may require land surface modelling (LSM) to predict future land surface conditions. There are multiple LSMs to choose from. The paper proposes a multivariate spatio-temporal data science method to understand the inherent uncertainties in four LSMs and the variations between them in Nordic areas for the net primary production.
Wei Li, Philippe Ciais, Elke Stehfest, Detlef van Vuuren, Alexander Popp, Almut Arneth, Fulvio Di Fulvio, Jonathan Doelman, Florian Humpenöder, Anna B. Harper, Taejin Park, David Makowski, Petr Havlik, Michael Obersteiner, Jingmeng Wang, Andreas Krause, and Wenfeng Liu
Earth Syst. Sci. Data, 12, 789–804, https://doi.org/10.5194/essd-12-789-2020, https://doi.org/10.5194/essd-12-789-2020, 2020
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We generated spatially explicit bioenergy crop yields based on field measurements with climate, soil condition and remote-sensing variables as explanatory variables and the machine-learning method. We further compared our yield maps with the maps from three integrated assessment models (IAMs; IMAGE, MAgPIE and GLOBIOM) and found that the median yields in our maps are > 50 % higher than those in the IAM maps.
Hong Xuan Do, Fang Zhao, Seth Westra, Michael Leonard, Lukas Gudmundsson, Julien Eric Stanislas Boulange, Jinfeng Chang, Philippe Ciais, Dieter Gerten, Simon N. Gosling, Hannes Müller Schmied, Tobias Stacke, Camelia-Eliza Telteu, and Yoshihide Wada
Hydrol. Earth Syst. Sci., 24, 1543–1564, https://doi.org/10.5194/hess-24-1543-2020, https://doi.org/10.5194/hess-24-1543-2020, 2020
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We presented a global comparison between observed and simulated trends in a flood index over the 1971–2005 period using the Global Streamflow Indices and Metadata archive and six global hydrological models available through The Inter-Sectoral Impact Model Intercomparison Project. Streamflow simulations over 2006–2099 period robustly project high flood hazard in several regions. These high-flood-risk areas, however, are under-sampled by the current global streamflow databases.
Victoria Naipal, Ronny Lauerwald, Philippe Ciais, Bertrand Guenet, and Yilong Wang
Geosci. Model Dev., 13, 1201–1222, https://doi.org/10.5194/gmd-13-1201-2020, https://doi.org/10.5194/gmd-13-1201-2020, 2020
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In this study we present the Carbon Erosion DYNAMics model (CE-DYNAM) that links sediment dynamics resulting from water erosion with the soil carbon cycle along a cascade of hillslopes, floodplains, and rivers. The model can simulate the removal of soil and carbon from eroding areas and their destination at regional scale. We calibrated and validated the model for the Rhine catchment, and we show that soil erosion is a potential large net carbon sink over the period 1850–2005.
Simon P. K. Bowring, Ronny Lauerwald, Bertrand Guenet, Dan Zhu, Matthieu Guimberteau, Pierre Regnier, Ardalan Tootchi, Agnès Ducharne, and Philippe Ciais
Geosci. Model Dev., 13, 507–520, https://doi.org/10.5194/gmd-13-507-2020, https://doi.org/10.5194/gmd-13-507-2020, 2020
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In this second part of the study, we performed simulations of the carbon and water budget of the Lena catchment with the land surface model ORCHIDEE MICT-LEAK, enabled to simulate dissolved organic carbon (DOC) production in soils and its transport and fate in high-latitude inland waters. We compare simulations using this model to existing data sources to show that it is capable of reproducing dissolved carbon fluxes of potentially great importance for the future of the global permafrost.
Sandy Bsaibes, Mohamad Al Ajami, Kenneth Mermet, François Truong, Sébastien Batut, Christophe Hecquet, Sébastien Dusanter, Thierry Léornadis, Stéphane Sauvage, Julien Kammer, Pierre-Marie Flaud, Emilie Perraudin, Eric Villenave, Nadine Locoge, Valérie Gros, and Coralie Schoemaecker
Atmos. Chem. Phys., 20, 1277–1300, https://doi.org/10.5194/acp-20-1277-2020, https://doi.org/10.5194/acp-20-1277-2020, 2020
Yunjiang Zhang, Olivier Favez, Jean-Eudes Petit, Francesco Canonaco, Francois Truong, Nicolas Bonnaire, Vincent Crenn, Tanguy Amodeo, Andre S. H. Prévôt, Jean Sciare, Valerie Gros, and Alexandre Albinet
Atmos. Chem. Phys., 19, 14755–14776, https://doi.org/10.5194/acp-19-14755-2019, https://doi.org/10.5194/acp-19-14755-2019, 2019
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We present 6-year source apportionment of organic aerosol (OA) achieved with near-continuous online measurements and subsequent receptor model analysis in the Paris region, France. The OA factors presented distinct seasonal patterns, associated with different atmospheric formation processes and roles in air pollution. Limited year-round trends for two primary anthropogenic factors and a biogenic-like secondary factor were observed, while a more oxidized secondary OA showed a decreasing feature.
Pierre Friedlingstein, Matthew W. Jones, Michael O'Sullivan, Robbie M. Andrew, Judith Hauck, Glen P. Peters, Wouter Peters, Julia Pongratz, Stephen Sitch, Corinne Le Quéré, Dorothee C. E. Bakker, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Peter Anthoni, Leticia Barbero, Ana Bastos, Vladislav Bastrikov, Meike Becker, Laurent Bopp, Erik Buitenhuis, Naveen Chandra, Frédéric Chevallier, Louise P. Chini, Kim I. Currie, Richard A. Feely, Marion Gehlen, Dennis Gilfillan, Thanos Gkritzalis, Daniel S. Goll, Nicolas Gruber, Sören Gutekunst, Ian Harris, Vanessa Haverd, Richard A. Houghton, George Hurtt, Tatiana Ilyina, Atul K. Jain, Emilie Joetzjer, Jed O. Kaplan, Etsushi Kato, Kees Klein Goldewijk, Jan Ivar Korsbakken, Peter Landschützer, Siv K. Lauvset, Nathalie Lefèvre, Andrew Lenton, Sebastian Lienert, Danica Lombardozzi, Gregg Marland, Patrick C. McGuire, Joe R. Melton, Nicolas Metzl, David R. Munro, Julia E. M. S. Nabel, Shin-Ichiro Nakaoka, Craig Neill, Abdirahman M. Omar, Tsuneo Ono, Anna Peregon, Denis Pierrot, Benjamin Poulter, Gregor Rehder, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Roland Séférian, Jörg Schwinger, Naomi Smith, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Francesco N. Tubiello, Guido R. van der Werf, Andrew J. Wiltshire, and Sönke Zaehle
Earth Syst. Sci. Data, 11, 1783–1838, https://doi.org/10.5194/essd-11-1783-2019, https://doi.org/10.5194/essd-11-1783-2019, 2019
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The Global Carbon Budget 2019 describes the data sets and methodology used to quantify the emissions of carbon dioxide and their partitioning among the atmosphere, land, and ocean. These living data are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Rupert Holzinger, W. Joe F. Acton, William J. Bloss, Martin Breitenlechner, Leigh R. Crilley, Sébastien Dusanter, Marc Gonin, Valerie Gros, Frank N. Keutsch, Astrid Kiendler-Scharr, Louisa J. Kramer, Jordan E. Krechmer, Baptiste Languille, Nadine Locoge, Felipe Lopez-Hilfiker, Dušan Materić, Sergi Moreno, Eiko Nemitz, Lauriane L. J. Quéléver, Roland Sarda Esteve, Stéphane Sauvage, Simon Schallhart, Roberto Sommariva, Ralf Tillmann, Sergej Wedel, David R. Worton, Kangming Xu, and Alexander Zaytsev
Atmos. Meas. Tech., 12, 6193–6208, https://doi.org/10.5194/amt-12-6193-2019, https://doi.org/10.5194/amt-12-6193-2019, 2019
Jinghui Lian, François-Marie Bréon, Grégoire Broquet, T. Scott Zaccheo, Jeremy Dobler, Michel Ramonet, Johannes Staufer, Diego Santaren, Irène Xueref-Remy, and Philippe Ciais
Atmos. Chem. Phys., 19, 13809–13825, https://doi.org/10.5194/acp-19-13809-2019, https://doi.org/10.5194/acp-19-13809-2019, 2019
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CO2 emissions within urban areas impact nearby and downwind concentrations. A different system, based on bi-wavelength laser measurements, has been deployed over Paris. It samples CO2 concentrations along horizontal lines, between a transceiver and a reflector. In this paper, we analyze the measurements provided by this system, together with the more classical in situ sampling and high-resolution modeling. We focus on the temporal and spatial variability of atmospheric CO2 concentrations.
Ana Bastos, Philippe Ciais, Frédéric Chevallier, Christian Rödenbeck, Ashley P. Ballantyne, Fabienne Maignan, Yi Yin, Marcos Fernández-Martínez, Pierre Friedlingstein, Josep Peñuelas, Shilong L. Piao, Stephen Sitch, William K. Smith, Xuhui Wang, Zaichun Zhu, Vanessa Haverd, Etsushi Kato, Atul K. Jain, Sebastian Lienert, Danica Lombardozzi, Julia E. M. S. Nabel, Philippe Peylin, Benjamin Poulter, and Dan Zhu
Atmos. Chem. Phys., 19, 12361–12375, https://doi.org/10.5194/acp-19-12361-2019, https://doi.org/10.5194/acp-19-12361-2019, 2019
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Here we show that land-surface models improved their ability to simulate the increase in the amplitude of seasonal CO2-cycle exchange (SCANBP) by ecosystems compared to estimates by two atmospheric inversions. We find a dominant role of vegetation growth over boreal Eurasia to the observed increase in SCANBP, strongly driven by CO2 fertilization, and an overall negative effect of temperature on SCANBP. Biases can be explained by the sensitivity of simulated microbial respiration to temperature.
Bo Zheng, Frederic Chevallier, Yi Yin, Philippe Ciais, Audrey Fortems-Cheiney, Merritt N. Deeter, Robert J. Parker, Yilong Wang, Helen M. Worden, and Yuanhong Zhao
Earth Syst. Sci. Data, 11, 1411–1436, https://doi.org/10.5194/essd-11-1411-2019, https://doi.org/10.5194/essd-11-1411-2019, 2019
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We use a multi-species atmospheric Bayesian inversion approach to attribute satellite-observed atmospheric carbon monoxide (CO) variations to its sources and sinks in order to achieve a full closure of the global CO budget during 2000–2017. We identify a declining trend in the global CO budget since 2000, driven by reduced anthropogenic emissions in the US, Europe, and China, as well as by reduced biomass burning emissions globally, especially in equatorial Africa.
Bruno Ringeval, Marko Kvakić, Laurent Augusto, Philippe Ciais, Daniel Goll, Nathaniel D. Mueller, Christoph Müller, Thomas Nesme, Nicolas Vuichard, Xuhui Wang, and Sylvain Pellerin
Biogeosciences Discuss., https://doi.org/10.5194/bg-2019-298, https://doi.org/10.5194/bg-2019-298, 2019
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Crossed fertilization additions lead to the definition of nutrient interaction categories. However, the implications of such categories in terms of nutrient interaction modeling are not clear. We developed a theoretical analysis of nitrogen and phosphorus fertilization experiments, then applied it to current estimates of nutrient limitation in cropland. We found that a true co-limitation could affect up to 42 % of the global maize area when using a given formalism of nutrient interaction.
Simon P. K. Bowring, Ronny Lauerwald, Bertrand Guenet, Dan Zhu, Matthieu Guimberteau, Ardalan Tootchi, Agnès Ducharne, and Philippe Ciais
Geosci. Model Dev., 12, 3503–3521, https://doi.org/10.5194/gmd-12-3503-2019, https://doi.org/10.5194/gmd-12-3503-2019, 2019
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Few Earth system models represent permafrost soil biogeochemistry, contributing to uncertainty in estimating its response and that of the planet to warming. Because the permafrost contains over double the carbon in the present atmosphere, its fate as it is
unlockedby warming is globally significant. One way it can be mobilised is into rivers, the sea, or the atmosphere: a vector previously ignored in climate modelling. We present a model scheme for resolving this vector at a global scale.
Chunjing Qiu, Dan Zhu, Philippe Ciais, Bertrand Guenet, Shushi Peng, Gerhard Krinner, Ardalan Tootchi, Agnès Ducharne, and Adam Hastie
Geosci. Model Dev., 12, 2961–2982, https://doi.org/10.5194/gmd-12-2961-2019, https://doi.org/10.5194/gmd-12-2961-2019, 2019
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We present a model that can simulate the dynamics of peatland area extent and the vertical buildup of peat. The model is validated across a range of northern peatland sites and over the Northern Hemisphere (> 30° N). It is able to reproduce the spatial extent of northern peatlands and peat carbon accumulation over the Holocene.
Yilong Wang, Philippe Ciais, Grégoire Broquet, François-Marie Bréon, Tomohiro Oda, Franck Lespinas, Yasjka Meijer, Armin Loescher, Greet Janssens-Maenhout, Bo Zheng, Haoran Xu, Shu Tao, Kevin R. Gurney, Geoffrey Roest, Diego Santaren, and Yongxian Su
Earth Syst. Sci. Data, 11, 687–703, https://doi.org/10.5194/essd-11-687-2019, https://doi.org/10.5194/essd-11-687-2019, 2019
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We address the question of the global characterization of fossil fuel CO2 emission hotspots that may cause coherent XCO2 plumes in space-borne CO2 images, based on the ODIAC global high-resolution 1 km fossil fuel emission data product. For space imagery with 0.5 ppm precision for a single XCO2 measurement, a total of 11 314 hotspots are identified, covering 72 % of the global emissions. These hotspots define the targets for the purpose of monitoring fossil fuel CO2 emissions from space.
Emmanuel Arzoumanian, Felix R. Vogel, Ana Bastos, Bakhram Gaynullin, Olivier Laurent, Michel Ramonet, and Philippe Ciais
Atmos. Meas. Tech., 12, 2665–2677, https://doi.org/10.5194/amt-12-2665-2019, https://doi.org/10.5194/amt-12-2665-2019, 2019
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We tested commercial lower-cost CO2 sensors in laboratory and field studies to see if they can measure atmospheric CO2 mole fractions with less than 1 ppm bias (with monthly calibration), to allow continuous urban CO2 monitoring.
We find that the sensors' CO2 readings are influenced by temperature, atmospheric pressure and water vapour content, but this can be corrected for by adding sensors (T, p, RH) and carefully calibrating each sensor against a high-precision instrument.
Misa Ishizawa, Douglas Chan, Doug Worthy, Elton Chan, Felix Vogel, and Shamil Maksyutov
Atmos. Chem. Phys., 19, 4637–4658, https://doi.org/10.5194/acp-19-4637-2019, https://doi.org/10.5194/acp-19-4637-2019, 2019
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The Canadian Arctic has the potential for enhanced methane (CH4) emissions under global warming. However, the regional CH4 emission (fluxes) estimates range widely. This study analyzes recent Canadian Arctic CH4 observations and estimates the regional emissions. The additional observations yield robust CH4 flux estimates and enable the partitioning of the CH4 sources into wetland and forest fires. The results indicate that years with warmer summer conditions result in more wetland CH4 emissions.
Felix R. Vogel, Matthias Frey, Johannes Staufer, Frank Hase, Grégoire Broquet, Irène Xueref-Remy, Frédéric Chevallier, Philippe Ciais, Mahesh Kumar Sha, Pascale Chelin, Pascal Jeseck, Christof Janssen, Yao Té, Jochen Groß, Thomas Blumenstock, Qiansi Tu, and Johannes Orphal
Atmos. Chem. Phys., 19, 3271–3285, https://doi.org/10.5194/acp-19-3271-2019, https://doi.org/10.5194/acp-19-3271-2019, 2019
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Providing timely information on greenhouse gas emissions to stakeholders at sub-national scale is an emerging challenge and understanding urban CO2 levels is one key aspect. This study uses atmospheric observations of total column CO2 and compares them to numerical simulations to investigate CO2 levels in the Paris metropolitan area due to natural fluxes and anthropogenic emissions. Our measurements reveal the influence of locally added CO2, which our model is also able to predict.
Matthias Frey, Mahesh K. Sha, Frank Hase, Matthäus Kiel, Thomas Blumenstock, Roland Harig, Gregor Surawicz, Nicholas M. Deutscher, Kei Shiomi, Jonathan E. Franklin, Hartmut Bösch, Jia Chen, Michel Grutter, Hirofumi Ohyama, Youwen Sun, André Butz, Gizaw Mengistu Tsidu, Dragos Ene, Debra Wunch, Zhensong Cao, Omaira Garcia, Michel Ramonet, Felix Vogel, and Johannes Orphal
Atmos. Meas. Tech., 12, 1513–1530, https://doi.org/10.5194/amt-12-1513-2019, https://doi.org/10.5194/amt-12-1513-2019, 2019
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In a 3.5-year long study, the long-term performance of a mobile EM27/SUN spectrometer, used for greenhouse gas observations, is checked with respect to a co-located reference spectrometer. We find that the EM27/SUN is stable on timescales of several years, qualifying it for permanent carbon cycle studies.
The performance of an ensemble of 30 EM27/SUN spectrometers was also tested in the framework of the COllaborative Carbon Column Observing Network (COCCON) and found to be very uniform.
Pierre Laurent, Florent Mouillot, Maria Vanesa Moreno, Chao Yue, and Philippe Ciais
Biogeosciences, 16, 275–288, https://doi.org/10.5194/bg-16-275-2019, https://doi.org/10.5194/bg-16-275-2019, 2019
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Fire propagation and fire size are usually considered to be proportional to fire intensity. We used a global database of fire patch size and fire radiative power, used as a proxy of fire intensity, to test this relationship at a global scale. We showed that in some regions fire size tends to saturate when a regional fire intensity threshold is reached. We concluded that increasing landscape fragmentation limits fire propagation and this effect should be accounted for in global fire modules.
Anja Rammig, Jens Heinke, Florian Hofhansl, Hans Verbeeck, Timothy R. Baker, Bradley Christoffersen, Philippe Ciais, Hannes De Deurwaerder, Katrin Fleischer, David Galbraith, Matthieu Guimberteau, Andreas Huth, Michelle Johnson, Bart Krujit, Fanny Langerwisch, Patrick Meir, Phillip Papastefanou, Gilvan Sampaio, Kirsten Thonicke, Celso von Randow, Christian Zang, and Edna Rödig
Geosci. Model Dev., 11, 5203–5215, https://doi.org/10.5194/gmd-11-5203-2018, https://doi.org/10.5194/gmd-11-5203-2018, 2018
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We propose a generic approach for a pixel-to-point comparison applicable for evaluation of models and remote-sensing products. We provide statistical measures accounting for the uncertainty in ecosystem variables. We demonstrate our approach by comparing simulated values of aboveground biomass, woody productivity and residence time of woody biomass from four dynamic global vegetation models (DGVMs) with measured inventory data from permanent plots in the Amazon rainforest.
Corinne Le Quéré, Robbie M. Andrew, Pierre Friedlingstein, Stephen Sitch, Judith Hauck, Julia Pongratz, Penelope A. Pickers, Jan Ivar Korsbakken, Glen P. Peters, Josep G. Canadell, Almut Arneth, Vivek K. Arora, Leticia Barbero, Ana Bastos, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Philippe Ciais, Scott C. Doney, Thanos Gkritzalis, Daniel S. Goll, Ian Harris, Vanessa Haverd, Forrest M. Hoffman, Mario Hoppema, Richard A. Houghton, George Hurtt, Tatiana Ilyina, Atul K. Jain, Truls Johannessen, Chris D. Jones, Etsushi Kato, Ralph F. Keeling, Kees Klein Goldewijk, Peter Landschützer, Nathalie Lefèvre, Sebastian Lienert, Zhu Liu, Danica Lombardozzi, Nicolas Metzl, David R. Munro, Julia E. M. S. Nabel, Shin-ichiro Nakaoka, Craig Neill, Are Olsen, Tsueno Ono, Prabir Patra, Anna Peregon, Wouter Peters, Philippe Peylin, Benjamin Pfeil, Denis Pierrot, Benjamin Poulter, Gregor Rehder, Laure Resplandy, Eddy Robertson, Matthias Rocher, Christian Rödenbeck, Ute Schuster, Jörg Schwinger, Roland Séférian, Ingunn Skjelvan, Tobias Steinhoff, Adrienne Sutton, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Francesco N. Tubiello, Ingrid T. van der Laan-Luijkx, Guido R. van der Werf, Nicolas Viovy, Anthony P. Walker, Andrew J. Wiltshire, Rebecca Wright, Sönke Zaehle, and Bo Zheng
Earth Syst. Sci. Data, 10, 2141–2194, https://doi.org/10.5194/essd-10-2141-2018, https://doi.org/10.5194/essd-10-2141-2018, 2018
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The Global Carbon Budget 2018 describes the data sets and methodology used to quantify the emissions of carbon dioxide and their partitioning among the atmosphere, land, and ocean. These living data are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Haicheng Zhang, Daniel S. Goll, Stefano Manzoni, Philippe Ciais, Bertrand Guenet, and Yuanyuan Huang
Geosci. Model Dev., 11, 4779–4796, https://doi.org/10.5194/gmd-11-4779-2018, https://doi.org/10.5194/gmd-11-4779-2018, 2018
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Carbon use efficiency (CUE) of decomposers depends strongly on the organic matter quality (C : N ratio) and soil nutrient availability rather than a fixed value. A soil biogeochemical model with flexible CUE can better capture the differences in respiration rate of litter with contrasting C : N ratios and under different levels of mineral N availability than the model with fixed CUE, and well represent the effect of varying litter quality (N content) on SOM formation across temporal scales.
Anastasia Panopoulou, Eleni Liakakou, Valérie Gros, Stéphane Sauvage, Nadine Locoge, Bernard Bonsang, Basil E. Psiloglou, Evangelos Gerasopoulos, and Nikolaos Mihalopoulos
Atmos. Chem. Phys., 18, 16139–16154, https://doi.org/10.5194/acp-18-16139-2018, https://doi.org/10.5194/acp-18-16139-2018, 2018
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This work presents time-resolved data of non-methane hydrocarbons (NMHC) from automatic chromatographs, measured over a period of 5 months in the greater Athens area. The measured concentrations are higher relative to other recent studies for the majority of NMHCs. A remarkable day-to-day variability is also observed. The contributions from traffic and residential heating to NMHCs are investigated, as they were the major sources impacting the air quality during the study period.
Zun Yin, Catherine Ottlé, Philippe Ciais, Matthieu Guimberteau, Xuhui Wang, Dan Zhu, Fabienne Maignan, Shushi Peng, Shilong Piao, Jan Polcher, Feng Zhou, Hyungjun Kim, and other China-Trend-Stream project members
Hydrol. Earth Syst. Sci., 22, 5463–5484, https://doi.org/10.5194/hess-22-5463-2018, https://doi.org/10.5194/hess-22-5463-2018, 2018
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Simulations in China were performed in ORCHIDEE driven by different forcing datasets: GSWP3, PGF, CRU-NCEP, and WFDEI. Simulated soil moisture was compared to several datasets to evaluate the ability of ORCHIDEE in reproducing soil moisture dynamics. Results showed that ORCHIDEE soil moisture coincided well with other datasets in wet areas and in non-irrigated areas. It suggested that the ORCHIDEE-MICT was suitable for further hydrological studies in China.
Igor B. Konovalov, Daria A. Lvova, Matthias Beekmann, Hiren Jethva, Eugene F. Mikhailov, Jean-Daniel Paris, Boris D. Belan, Valerii S. Kozlov, Philippe Ciais, and Meinrat O. Andreae
Atmos. Chem. Phys., 18, 14889–14924, https://doi.org/10.5194/acp-18-14889-2018, https://doi.org/10.5194/acp-18-14889-2018, 2018
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A good knowledge of black carbon (BC) emissions from open biomass burning (BB) is an important prerequisite for reliable climate predictions, especially in the Arctic. This paper introduces a method to constrain a regional budget of BB BC emissions using satellite measurements of the absorption and extinction optical depths and evaluates its potential application in a large Siberian region.
Cécile Debevec, Stéphane Sauvage, Valérie Gros, Karine Sellegri, Jean Sciare, Michael Pikridas, Iasonas Stavroulas, Thierry Leonardis, Vincent Gaudion, Laurence Depelchin, Isabelle Fronval, Roland Sarda-Esteve, Dominique Baisnée, Bernard Bonsang, Chrysanthos Savvides, Mihalis Vrekoussis, and Nadine Locoge
Atmos. Chem. Phys., 18, 14297–14325, https://doi.org/10.5194/acp-18-14297-2018, https://doi.org/10.5194/acp-18-14297-2018, 2018
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This work focuses on the study of the sources and fates of BVOCs and new particle formation (NPF) events in the eastern Mediterranean. NPF events were found on 14 out of 20 days of the campaign. NPF occurred at various condensational sinks and both under polluted and clean atmospheric conditions. Analysis of specific NPF periods of the mixed influence type highlighted that BVOC interactions with anthropogenic compounds enhanced nucleation formation and growth of new particles.
Yilong Wang, Philippe Ciais, Daniel Goll, Yuanyuan Huang, Yiqi Luo, Ying-Ping Wang, A. Anthony Bloom, Grégoire Broquet, Jens Hartmann, Shushi Peng, Josep Penuelas, Shilong Piao, Jordi Sardans, Benjamin D. Stocker, Rong Wang, Sönke Zaehle, and Sophie Zechmeister-Boltenstern
Geosci. Model Dev., 11, 3903–3928, https://doi.org/10.5194/gmd-11-3903-2018, https://doi.org/10.5194/gmd-11-3903-2018, 2018
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We present a new modeling framework called Global Observation-based Land-ecosystems Utilization Model of Carbon, Nitrogen and Phosphorus (GOLUM-CNP) that combines a data-constrained C-cycle analysis with data-driven estimates of N and P inputs and losses and with observed stoichiometric ratios. GOLUM-CNP provides a traceable tool, where a consistency between different datasets of global C, N, and P cycles has been achieved.
Chloé Largeron, Gerhard Krinner, Philippe Ciais, and Claire Brutel-Vuilmet
Geosci. Model Dev., 11, 3279–3297, https://doi.org/10.5194/gmd-11-3279-2018, https://doi.org/10.5194/gmd-11-3279-2018, 2018
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Peatlands are widely present in boreal regions and contain large carbon stocks due to their hydrologic properties and high water content. We have enhanced the global land surface model ORCHIDEE by introducing boreal peatlands. These are considered as a new type of vegetation in the model, with specific hydrological properties for peat soil. In this paper, we focus on the representation of the hydrology of northern peatlands and on the evaluation of the hydrological impact of this implementation.
Victoria Naipal, Philippe Ciais, Yilong Wang, Ronny Lauerwald, Bertrand Guenet, and Kristof Van Oost
Biogeosciences, 15, 4459–4480, https://doi.org/10.5194/bg-15-4459-2018, https://doi.org/10.5194/bg-15-4459-2018, 2018
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We seek to better understand the links between soil erosion by rainfall and the global carbon (C) cycle by coupling a soil erosion model to the C cycle of a land surface model. With this modeling approach we evaluate the effects of soil removal on soil C stocks in the presence of climate change and land use change. We find that accelerated soil erosion leads to a potential SOC removal flux of 74 ±18 Pg of C globally over the period AD 1850–2005, with significant impacts on the land C balance.
Emilie Joetzjer, Fabienne Maignan, Jérôme Chave, Daniel Goll, Ben Poulter, Jonathan Barichivich, Isabelle Maréchaux, Sebastiaan Luyssaert, Matthieu Guimberteau, Kim Naudts, Damien Bonal, and Philippe Ciais
Biogeosciences Discuss., https://doi.org/10.5194/bg-2018-308, https://doi.org/10.5194/bg-2018-308, 2018
Revised manuscript not accepted
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This study explores the relative contributions of tree demographic, canopy structure and hydraulic processes on the Amazonian carbon and water cycles using large-scale process-based model. Our results imply that explicit coupling of the water and carbon cycles improves the representation of biogeochemical cycles and their spatial variability. Representing the variation in the ecological functioning of Amazonia should be the next step to improve the performance and predictive ability of models.
Xin Lin, Philippe Ciais, Philippe Bousquet, Michel Ramonet, Yi Yin, Yves Balkanski, Anne Cozic, Marc Delmotte, Nikolaos Evangeliou, Nuggehalli K. Indira, Robin Locatelli, Shushi Peng, Shilong Piao, Marielle Saunois, Panangady S. Swathi, Rong Wang, Camille Yver-Kwok, Yogesh K. Tiwari, and Lingxi Zhou
Atmos. Chem. Phys., 18, 9475–9497, https://doi.org/10.5194/acp-18-9475-2018, https://doi.org/10.5194/acp-18-9475-2018, 2018
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We simulate CH4 and CO2 using a zoomed global transport model with a horizontal resolution of ~50 km over South and East Asia, as well as a standard model version for comparison. Model performance is evaluated for both gases and versions at multiple timescales against a new collection of surface stations over this key GHG-emitting region. The evaluation at different timescales and comparisons between gases and model versions have implications for possible model improvements and inversions.
Wei Li, Chao Yue, Philippe Ciais, Jinfeng Chang, Daniel Goll, Dan Zhu, Shushi Peng, and Albert Jornet-Puig
Geosci. Model Dev., 11, 2249–2272, https://doi.org/10.5194/gmd-11-2249-2018, https://doi.org/10.5194/gmd-11-2249-2018, 2018
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We implemented four major lignocellulosic bioenergy crops in ORCHIDEE. We added new PFTs, did new parameterizations of photosynthesis, carbon allocation, and phenology based on a compilation of field measurements, and added a specific harvest module. The resulting ORCHIDEE-MICT-BIOENERGY model is evaluated at 296 locations where field measurements of harvested biomass are available, and the new model can generally reproduce the global bioenergy crop yield observations.
Donghai Wu, Philippe Ciais, Nicolas Viovy, Alan K. Knapp, Kevin Wilcox, Michael Bahn, Melinda D. Smith, Sara Vicca, Simone Fatichi, Jakob Zscheischler, Yue He, Xiangyi Li, Akihiko Ito, Almut Arneth, Anna Harper, Anna Ukkola, Athanasios Paschalis, Benjamin Poulter, Changhui Peng, Daniel Ricciuto, David Reinthaler, Guangsheng Chen, Hanqin Tian, Hélène Genet, Jiafu Mao, Johannes Ingrisch, Julia E. S. M. Nabel, Julia Pongratz, Lena R. Boysen, Markus Kautz, Michael Schmitt, Patrick Meir, Qiuan Zhu, Roland Hasibeder, Sebastian Sippel, Shree R. S. Dangal, Stephen Sitch, Xiaoying Shi, Yingping Wang, Yiqi Luo, Yongwen Liu, and Shilong Piao
Biogeosciences, 15, 3421–3437, https://doi.org/10.5194/bg-15-3421-2018, https://doi.org/10.5194/bg-15-3421-2018, 2018
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Our results indicate that most ecosystem models do not capture the observed asymmetric responses under normal precipitation conditions, suggesting an overestimate of the drought effects and/or underestimate of the watering impacts on primary productivity, which may be the result of inadequate representation of key eco-hydrological processes. Collaboration between modelers and site investigators needs to be strengthened to improve the specific processes in ecosystem models in following studies.
Ye Huang, Bertrand Guenet, Philippe Ciais, Ivan A. Janssens, Jennifer L. Soong, Yilong Wang, Daniel Goll, Evgenia Blagodatskaya, and Yuanyuan Huang
Geosci. Model Dev., 11, 2111–2138, https://doi.org/10.5194/gmd-11-2111-2018, https://doi.org/10.5194/gmd-11-2111-2018, 2018
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ORCHIMIC is a modeling effort trying to improve the representation of SOC dynamics in Earth system models (ESM). It has a structure that can be easily incorporated into CENTURY-based ESMs. In ORCHIMIC, key microbial dynamics (i.e., enzyme production, enzymatic decomposition and microbial dormancy) are included. The ORCHIMIC model can also reproduce the observed temporal dynamics of respiration and priming effects; thus it is an improved tool for climate projections and SOC response predictions.
Arineh Cholakian, Matthias Beekmann, Augustin Colette, Isabelle Coll, Guillaume Siour, Jean Sciare, Nicolas Marchand, Florian Couvidat, Jorge Pey, Valerie Gros, Stéphane Sauvage, Vincent Michoud, Karine Sellegri, Aurélie Colomb, Karine Sartelet, Helen Langley DeWitt, Miriam Elser, André S. H. Prévot, Sonke Szidat, and François Dulac
Atmos. Chem. Phys., 18, 7287–7312, https://doi.org/10.5194/acp-18-7287-2018, https://doi.org/10.5194/acp-18-7287-2018, 2018
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In this work, four schemes for the simulation of organic aerosols in the western Mediterranean basin are added to the CHIMERE chemistry–transport model; the resulting simulations are then compared to measurements obtained from ChArMEx. It is concluded that the scheme taking into account the fragmentation and the formation of nonvolatile organic aerosols corresponds better to measurements; the major source of this aerosol in the western Mediterranean is found to be of biogenic origin.
Claudia Grossi, Felix R. Vogel, Roger Curcoll, Alba Àgueda, Arturo Vargas, Xavier Rodó, and Josep-Anton Morguí
Atmos. Chem. Phys., 18, 5847–5860, https://doi.org/10.5194/acp-18-5847-2018, https://doi.org/10.5194/acp-18-5847-2018, 2018
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To gain a full picture of the Spanish (and European) GHG balance, understanding of CH4 emissions in different regions is a critical challenge, as is the improvement of bottom-up inventories for all European regions. This study uses, among other elements, GHG, meteorological and 222Rn tracer data from a Spanish region to understand the main causes of temporal variability of GHG mixing ratios. The study can offer new insights into regional emissions by identifying the impacts of changing sources.
Yilong Wang, Grégoire Broquet, Philippe Ciais, Frédéric Chevallier, Felix Vogel, Lin Wu, Yi Yin, Rong Wang, and Shu Tao
Atmos. Chem. Phys., 18, 4229–4250, https://doi.org/10.5194/acp-18-4229-2018, https://doi.org/10.5194/acp-18-4229-2018, 2018
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This paper assesses the potential of atmospheric 14CO2 observations and a global inversion system to solve for fossil fuel CO2 (FFCO2) emissions in Europe. The estimate of monthly emission budgets is largely improved in high emitting regions. The results are sensitive to the observation network and the prior uncertainty. Using a high-resolution transport model and a systematic evaluation of the uncertainty in current emission inventories should improve the potential to retrieve FFCO2 emissions.
Abdelhadi El Yazidi, Michel Ramonet, Philippe Ciais, Gregoire Broquet, Isabelle Pison, Amara Abbaris, Dominik Brunner, Sebastien Conil, Marc Delmotte, Francois Gheusi, Frederic Guerin, Lynn Hazan, Nesrine Kachroudi, Giorgos Kouvarakis, Nikolaos Mihalopoulos, Leonard Rivier, and Dominique Serça
Atmos. Meas. Tech., 11, 1599–1614, https://doi.org/10.5194/amt-11-1599-2018, https://doi.org/10.5194/amt-11-1599-2018, 2018
Marta Camino-Serrano, Bertrand Guenet, Sebastiaan Luyssaert, Philippe Ciais, Vladislav Bastrikov, Bruno De Vos, Bert Gielen, Gerd Gleixner, Albert Jornet-Puig, Klaus Kaiser, Dolly Kothawala, Ronny Lauerwald, Josep Peñuelas, Marion Schrumpf, Sara Vicca, Nicolas Vuichard, David Walmsley, and Ivan A. Janssens
Geosci. Model Dev., 11, 937–957, https://doi.org/10.5194/gmd-11-937-2018, https://doi.org/10.5194/gmd-11-937-2018, 2018
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Global models generally oversimplify the representation of soil organic carbon (SOC), and thus its response to global warming remains uncertain. We present the new soil module ORCHIDEE-SOM, within the global model ORCHIDEE, that refines the representation of SOC dynamics and includes the dissolved organic carbon (DOC) processes. The model is able to reproduce SOC stocks and DOC concentrations in four different ecosystems, opening an opportunity for improved predictions of SOC in global models.
Corinne Le Quéré, Robbie M. Andrew, Pierre Friedlingstein, Stephen Sitch, Julia Pongratz, Andrew C. Manning, Jan Ivar Korsbakken, Glen P. Peters, Josep G. Canadell, Robert B. Jackson, Thomas A. Boden, Pieter P. Tans, Oliver D. Andrews, Vivek K. Arora, Dorothee C. E. Bakker, Leticia Barbero, Meike Becker, Richard A. Betts, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Philippe Ciais, Catherine E. Cosca, Jessica Cross, Kim Currie, Thomas Gasser, Ian Harris, Judith Hauck, Vanessa Haverd, Richard A. Houghton, Christopher W. Hunt, George Hurtt, Tatiana Ilyina, Atul K. Jain, Etsushi Kato, Markus Kautz, Ralph F. Keeling, Kees Klein Goldewijk, Arne Körtzinger, Peter Landschützer, Nathalie Lefèvre, Andrew Lenton, Sebastian Lienert, Ivan Lima, Danica Lombardozzi, Nicolas Metzl, Frank Millero, Pedro M. S. Monteiro, David R. Munro, Julia E. M. S. Nabel, Shin-ichiro Nakaoka, Yukihiro Nojiri, X. Antonio Padin, Anna Peregon, Benjamin Pfeil, Denis Pierrot, Benjamin Poulter, Gregor Rehder, Janet Reimer, Christian Rödenbeck, Jörg Schwinger, Roland Séférian, Ingunn Skjelvan, Benjamin D. Stocker, Hanqin Tian, Bronte Tilbrook, Francesco N. Tubiello, Ingrid T. van der Laan-Luijkx, Guido R. van der Werf, Steven van Heuven, Nicolas Viovy, Nicolas Vuichard, Anthony P. Walker, Andrew J. Watson, Andrew J. Wiltshire, Sönke Zaehle, and Dan Zhu
Earth Syst. Sci. Data, 10, 405–448, https://doi.org/10.5194/essd-10-405-2018, https://doi.org/10.5194/essd-10-405-2018, 2018
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The Global Carbon Budget 2017 describes data sets and methodology to quantify the five major components of the global carbon budget and their uncertainties. It is the 12th annual update and the 6th published in this journal.
Stephanie C. Pugliese, Jennifer G. Murphy, Felix R. Vogel, Michael D. Moran, Junhua Zhang, Qiong Zheng, Craig A. Stroud, Shuzhan Ren, Douglas Worthy, and Gregoire Broquet
Atmos. Chem. Phys., 18, 3387–3401, https://doi.org/10.5194/acp-18-3387-2018, https://doi.org/10.5194/acp-18-3387-2018, 2018
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We developed the Southern Ontario CO2 Emissions (SOCE) inventory, which identifies the spatial and temporal distribution (2.5 km and hourly, respectively) of CO2 emissions from seven source sectors. When the SOCE inventory was used with a chemistry transport model, we found strong agreement between modelled and measured mixing ratios. We were able to quantify that natural gas combustion contributes > 80 % of CO2 emissions at nighttime while on-road emissions contribute > 70 % during the day.
Irène Xueref-Remy, Elsa Dieudonné, Cyrille Vuillemin, Morgan Lopez, Christine Lac, Martina Schmidt, Marc Delmotte, Frédéric Chevallier, François Ravetta, Olivier Perrussel, Philippe Ciais, François-Marie Bréon, Grégoire Broquet, Michel Ramonet, T. Gerard Spain, and Christophe Ampe
Atmos. Chem. Phys., 18, 3335–3362, https://doi.org/10.5194/acp-18-3335-2018, https://doi.org/10.5194/acp-18-3335-2018, 2018
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Urbanized and industrialized areas are the largest source of fossil CO2. This work analyses the atmospheric CO2 variability observed from the first in situ network deployed in the Paris megacity area. Gradients of several ppm are found between the rural, peri-urban and urban sites at the diurnal to the seasonal scales. Wind direction and speed as well as boundary layer dynamics, correlated to highly variable urban emissions, are shown to be key regulator factors of the observed CO2 records.
Chao Yue, Philippe Ciais, and Wei Li
Biogeosciences, 15, 1185–1201, https://doi.org/10.5194/bg-15-1185-2018, https://doi.org/10.5194/bg-15-1185-2018, 2018
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Gross land use change such as shifting cultivation causes carbon emissions because carbon release in cleared forests is larger than absorption in regrowing ones. However, to appropriately account for this process, vegetation models have to represent sub-grid secondary forest dynamics. We found that gross land use emissions can be overestimated if sub-grid secondary forests are neglected in the model. Conversely, rotation lengths of shifting cultivation have a critical role.
Ben Parkes, Dimitri Defrance, Benjamin Sultan, Philippe Ciais, and Xuhui Wang
Earth Syst. Dynam., 9, 119–134, https://doi.org/10.5194/esd-9-119-2018, https://doi.org/10.5194/esd-9-119-2018, 2018
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We present an analysis of three crops in West Africa and their response to short-term climate change in a world where temperatures are 1.5 °C above the preindustrial levels. We show that the number of crop failures for all crops is due to increase in the future climate. We further show the difference in yield change across several West African countries and show that the yields are not expected to increase fast enough to prevent food shortages.
Grégoire Broquet, François-Marie Bréon, Emmanuel Renault, Michael Buchwitz, Maximilian Reuter, Heinrich Bovensmann, Frédéric Chevallier, Lin Wu, and Philippe Ciais
Atmos. Meas. Tech., 11, 681–708, https://doi.org/10.5194/amt-11-681-2018, https://doi.org/10.5194/amt-11-681-2018, 2018
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This study assesses the potential of space-borne imagery of CO2 atmospheric concentrations for monitoring the emissions from the Paris area. Such imagery could be provided by European and American missions in the next decade. It highlights the difficulty to improve current knowledge on CO2 emissions for urban areas with CO2 observations from satellites, and calls for more technological innovations in the remote sensing of CO2 and in the models that exploit it.
Chunjing Qiu, Dan Zhu, Philippe Ciais, Bertrand Guenet, Gerhard Krinner, Shushi Peng, Mika Aurela, Christian Bernhofer, Christian Brümmer, Syndonia Bret-Harte, Housen Chu, Jiquan Chen, Ankur R. Desai, Jiří Dušek, Eugénie S. Euskirchen, Krzysztof Fortuniak, Lawrence B. Flanagan, Thomas Friborg, Mateusz Grygoruk, Sébastien Gogo, Thomas Grünwald, Birger U. Hansen, David Holl, Elyn Humphreys, Miriam Hurkuck, Gerard Kiely, Janina Klatt, Lars Kutzbach, Chloé Largeron, Fatima Laggoun-Défarge, Magnus Lund, Peter M. Lafleur, Xuefei Li, Ivan Mammarella, Lutz Merbold, Mats B. Nilsson, Janusz Olejnik, Mikaell Ottosson-Löfvenius, Walter Oechel, Frans-Jan W. Parmentier, Matthias Peichl, Norbert Pirk, Olli Peltola, Włodzimierz Pawlak, Daniel Rasse, Janne Rinne, Gaius Shaver, Hans Peter Schmid, Matteo Sottocornola, Rainer Steinbrecher, Torsten Sachs, Marek Urbaniak, Donatella Zona, and Klaudia Ziemblinska
Geosci. Model Dev., 11, 497–519, https://doi.org/10.5194/gmd-11-497-2018, https://doi.org/10.5194/gmd-11-497-2018, 2018
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Northern peatlands store large amount of soil carbon and are vulnerable to climate change. We implemented peatland hydrological and carbon accumulation processes into the ORCHIDEE land surface model. The model was evaluated against EC measurements from 30 northern peatland sites. The model generally well reproduced the spatial gradient and temporal variations in GPP and NEE at these sites. Water table depth was not well predicted but had only small influence on simulated NEE.
Chao Yue, Philippe Ciais, Sebastiaan Luyssaert, Wei Li, Matthew J. McGrath, Jinfeng Chang, and Shushi Peng
Geosci. Model Dev., 11, 409–428, https://doi.org/10.5194/gmd-11-409-2018, https://doi.org/10.5194/gmd-11-409-2018, 2018
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Human alteration of land cover has caused CO2 that is stored in forest biomass and soil to be released into the atmosphere and thus contribute to global warming. Global vegetation models that are used to quantify such carbon emissions from land use change traditionally rarely include shifting cultivation and secondary forest age dynamics. In this study, we expanded one vegetation model to include these features. We found that carbon emissions from land use change are estimated to be smaller.
Wei Li, Natasha MacBean, Philippe Ciais, Pierre Defourny, Céline Lamarche, Sophie Bontemps, Richard A. Houghton, and Shushi Peng
Earth Syst. Sci. Data, 10, 219–234, https://doi.org/10.5194/essd-10-219-2018, https://doi.org/10.5194/essd-10-219-2018, 2018
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We evaluated the land cover changes based on plant functional types (PFTs) derived from the newly released annual ESA land cover maps. We addressed the geographical distributions and temporal trends of the translated PFT maps and compared with other datasets commonly used by the land surface model community. Different choices of these datasets for the applications in land surface models are proposed depending on the research purposes.
Matthieu Guimberteau, Dan Zhu, Fabienne Maignan, Ye Huang, Chao Yue, Sarah Dantec-Nédélec, Catherine Ottlé, Albert Jornet-Puig, Ana Bastos, Pierre Laurent, Daniel Goll, Simon Bowring, Jinfeng Chang, Bertrand Guenet, Marwa Tifafi, Shushi Peng, Gerhard Krinner, Agnès Ducharne, Fuxing Wang, Tao Wang, Xuhui Wang, Yilong Wang, Zun Yin, Ronny Lauerwald, Emilie Joetzjer, Chunjing Qiu, Hyungjun Kim, and Philippe Ciais
Geosci. Model Dev., 11, 121–163, https://doi.org/10.5194/gmd-11-121-2018, https://doi.org/10.5194/gmd-11-121-2018, 2018
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Improved projections of future Arctic and boreal ecosystem transformation require improved land surface models that integrate processes specific to these cold biomes. To this end, this study lays out relevant new parameterizations in the ORCHIDEE-MICT land surface model. These describe the interactions between soil carbon, soil temperature and hydrology, and their resulting feedbacks on water and CO2 fluxes, in addition to a recently developed fire module.
Fei Lun, Junguo Liu, Philippe Ciais, Thomas Nesme, Jinfeng Chang, Rong Wang, Daniel Goll, Jordi Sardans, Josep Peñuelas, and Michael Obersteiner
Earth Syst. Sci. Data, 10, 1–18, https://doi.org/10.5194/essd-10-1-2018, https://doi.org/10.5194/essd-10-1-2018, 2018
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We quantified in detail the P budgets in agricultural systems and PUE on global, regional, and national scales from 2002 to 2010. Globally, half of the total P inputs into agricultural systems accumulated in agricultural soils, with the rest lost to bodies of water. There are great differences in P budgets and PUE in agricultural systems on global, regional, and national scales. International trade played a significant role in P redistribution and P in fertilizer and food among countries.
Wei Li, Philippe Ciais, Chao Yue, Thomas Gasser, Shushi Peng, and Ana Bastos
Biogeosciences, 15, 91–103, https://doi.org/10.5194/bg-15-91-2018, https://doi.org/10.5194/bg-15-91-2018, 2018
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We compared the biomass recovery curves from a recent field-based study with those used in bookkeeping models and demonstrated the importance of considering gross forest changes rather than net forest changes. We also derived a critical gross-to-net forest area change ratio, beyond which the sign of carbon flux will be reversed. This critical ratio was further applied to the high-resolution satellite data in the Amazon to distinguish the sensitive regions.
Arsène Druel, Philippe Peylin, Gerhard Krinner, Philippe Ciais, Nicolas Viovy, Anna Peregon, Vladislav Bastrikov, Natalya Kosykh, and Nina Mironycheva-Tokareva
Geosci. Model Dev., 10, 4693–4722, https://doi.org/10.5194/gmd-10-4693-2017, https://doi.org/10.5194/gmd-10-4693-2017, 2017
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To improve the simulation of vegetation–climate feedbacks at high latitudes, three new circumpolar vegetation types were added in the ORCHIDEE land surface model: bryophytes (mosses) and lichens, Arctic shrubs, and Arctic grasses. This article is an introduction to the modification of vegetation distribution and physical behaviour, implying for example lower productivity, roughness, and higher winter albedo or freshwater discharge in the Arctic Ocean.
Ben Langford, James Cash, W. Joe F. Acton, Amy C. Valach, C. Nicholas Hewitt, Silvano Fares, Ignacio Goded, Carsten Gruening, Emily House, Athina-Cerise Kalogridis, Valérie Gros, Richard Schafers, Rick Thomas, Mark Broadmeadow, and Eiko Nemitz
Biogeosciences, 14, 5571–5594, https://doi.org/10.5194/bg-14-5571-2017, https://doi.org/10.5194/bg-14-5571-2017, 2017
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Isoprene flux measurements made above five European oak forests were reviewed to generate new emission potentials. Six variations of the Guenther algorithms were inverted to back out time series of isoprene emission potential, and then an “average” emission potential was determined using one of four commonly used approaches. Our results show that emission potentials can vary by up to a factor of 4 and highlight the need for the community to now harmonize their approach to reduce uncertainty.
Katja Frieler, Stefan Lange, Franziska Piontek, Christopher P. O. Reyer, Jacob Schewe, Lila Warszawski, Fang Zhao, Louise Chini, Sebastien Denvil, Kerry Emanuel, Tobias Geiger, Kate Halladay, George Hurtt, Matthias Mengel, Daisuke Murakami, Sebastian Ostberg, Alexander Popp, Riccardo Riva, Miodrag Stevanovic, Tatsuo Suzuki, Jan Volkholz, Eleanor Burke, Philippe Ciais, Kristie Ebi, Tyler D. Eddy, Joshua Elliott, Eric Galbraith, Simon N. Gosling, Fred Hattermann, Thomas Hickler, Jochen Hinkel, Christian Hof, Veronika Huber, Jonas Jägermeyr, Valentina Krysanova, Rafael Marcé, Hannes Müller Schmied, Ioanna Mouratiadou, Don Pierson, Derek P. Tittensor, Robert Vautard, Michelle van Vliet, Matthias F. Biber, Richard A. Betts, Benjamin Leon Bodirsky, Delphine Deryng, Steve Frolking, Chris D. Jones, Heike K. Lotze, Hermann Lotze-Campen, Ritvik Sahajpal, Kirsten Thonicke, Hanqin Tian, and Yoshiki Yamagata
Geosci. Model Dev., 10, 4321–4345, https://doi.org/10.5194/gmd-10-4321-2017, https://doi.org/10.5194/gmd-10-4321-2017, 2017
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This paper describes the simulation scenario design for the next phase of the Inter-Sectoral Impact Model Intercomparison Project (ISIMIP), which is designed to facilitate a contribution to the scientific basis for the IPCC Special Report on the impacts of 1.5 °C global warming. ISIMIP brings together over 80 climate-impact models, covering impacts on hydrology, biomes, forests, heat-related mortality, permafrost, tropical cyclones, fisheries, agiculture, energy, and coastal infrastructure.
Chao Yue, Philippe Ciais, Ana Bastos, Frederic Chevallier, Yi Yin, Christian Rödenbeck, and Taejin Park
Atmos. Chem. Phys., 17, 13903–13919, https://doi.org/10.5194/acp-17-13903-2017, https://doi.org/10.5194/acp-17-13903-2017, 2017
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The year 2015 appeared as a paradox regarding how global carbon cycle has responded to climate variation: it is the greenest year since 2000 according to satellite observation, but the atmospheric CO2 growth rate is also the highest since 1959. We found that this is due to a only moderate land carbon sink, because high growing-season sink in northern lands has been partly offset by autumn and winter release and the late-year El Niño has led to an abrupt transition to land source in the tropics.
Wei Li, Philippe Ciais, Shushi Peng, Chao Yue, Yilong Wang, Martin Thurner, Sassan S. Saatchi, Almut Arneth, Valerio Avitabile, Nuno Carvalhais, Anna B. Harper, Etsushi Kato, Charles Koven, Yi Y. Liu, Julia E.M.S. Nabel, Yude Pan, Julia Pongratz, Benjamin Poulter, Thomas A. M. Pugh, Maurizio Santoro, Stephen Sitch, Benjamin D. Stocker, Nicolas Viovy, Andy Wiltshire, Rasoul Yousefpour, and Sönke Zaehle
Biogeosciences, 14, 5053–5067, https://doi.org/10.5194/bg-14-5053-2017, https://doi.org/10.5194/bg-14-5053-2017, 2017
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We used several observation-based biomass datasets to constrain the historical land-use change carbon emissions simulated by models. Compared to the range of the original modeled emissions (from 94 to 273 Pg C), the observationally constrained global cumulative emission estimate is 155 ± 50 Pg C (1σ Gaussian error) from 1901 to 2012. Our approach can also be applied to evaluate the LULCC impact of land-based climate mitigation policies.
Hendrik Fuchs, Anna Novelli, Michael Rolletter, Andreas Hofzumahaus, Eva Y. Pfannerstill, Stephan Kessel, Achim Edtbauer, Jonathan Williams, Vincent Michoud, Sebastien Dusanter, Nadine Locoge, Nora Zannoni, Valerie Gros, Francois Truong, Roland Sarda-Esteve, Danny R. Cryer, Charlotte A. Brumby, Lisa K. Whalley, Daniel Stone, Paul W. Seakins, Dwayne E. Heard, Coralie Schoemaecker, Marion Blocquet, Sebastien Coudert, Sebastien Batut, Christa Fittschen, Alexander B. Thames, William H. Brune, Cheryl Ernest, Hartwig Harder, Jennifer B. A. Muller, Thomas Elste, Dagmar Kubistin, Stefanie Andres, Birger Bohn, Thorsten Hohaus, Frank Holland, Xin Li, Franz Rohrer, Astrid Kiendler-Scharr, Ralf Tillmann, Robert Wegener, Zhujun Yu, Qi Zou, and Andreas Wahner
Atmos. Meas. Tech., 10, 4023–4053, https://doi.org/10.5194/amt-10-4023-2017, https://doi.org/10.5194/amt-10-4023-2017, 2017
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Hydroxyl radical reactivity (k(OH)) is closely related to processes that lead to the formation of oxidised, secondary pollutants such as ozone and aerosol. In order to compare the performances of instruments measuring k(OH), experiments were conducted in the simulation chamber SAPHIR. Chemical conditions were chosen either to be representative of the atmosphere or to test potential limitations of instruments. Overall, the results show that instruments are capable of measuring k(OH).
Nora Zannoni, Valerie Gros, Roland Sarda Esteve, Cerise Kalogridis, Vincent Michoud, Sebastien Dusanter, Stephane Sauvage, Nadine Locoge, Aurelie Colomb, and Bernard Bonsang
Atmos. Chem. Phys., 17, 12645–12658, https://doi.org/10.5194/acp-17-12645-2017, https://doi.org/10.5194/acp-17-12645-2017, 2017
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Our paper presents results of hydroxyl radical (OH) reactivity from a field study conducted during summer 2013 in a western Mediterranean coastal site (Corsica, France). Here, the total OH reactivity, measured with the comparative reactivity method, is compared with the summed OH reactivity from the reactive gases measured with a multitude of different technologies. Our results demonstrate the relatively high observed reactivity and the large impact of biogenic compounds.
Ronny Lauerwald, Pierre Regnier, Marta Camino-Serrano, Bertrand Guenet, Matthieu Guimberteau, Agnès Ducharne, Jan Polcher, and Philippe Ciais
Geosci. Model Dev., 10, 3821–3859, https://doi.org/10.5194/gmd-10-3821-2017, https://doi.org/10.5194/gmd-10-3821-2017, 2017
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ORCHILEAK is a new branch of the terrestrial ecosystem model ORCHIDEE that represents dissolved organic carbon (DOC) production from canopy and soils, DOC and CO2 leaching from soils to streams, DOC decomposition, and CO2 evasion to the atmosphere during its lateral transport in rivers, as well as exchange with the soil carbon and litter stocks on floodplains and in swamps. We parameterized and validated ORCHILEAK for the Amazon basin.
Daniel S. Goll, Nicolas Vuichard, Fabienne Maignan, Albert Jornet-Puig, Jordi Sardans, Aurelie Violette, Shushi Peng, Yan Sun, Marko Kvakic, Matthieu Guimberteau, Bertrand Guenet, Soenke Zaehle, Josep Penuelas, Ivan Janssens, and Philippe Ciais
Geosci. Model Dev., 10, 3745–3770, https://doi.org/10.5194/gmd-10-3745-2017, https://doi.org/10.5194/gmd-10-3745-2017, 2017
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We describe a representation of the terrestrial phosphorus cycle for the ORCHIDEE land surface model. The model is able to reproduce the observed shift from nitrogen to phosphorus limited net primary productivity along a soil formation chronosequence in Hawaii, as well as the contrasting responses of net primary productivity to nutrient addition. However, the simulated nutrient use efficiencies are lower, as observed primarily due to biases in the nutrient content and turnover of woody biomass.
Cécile Debevec, Stéphane Sauvage, Valérie Gros, Jean Sciare, Michael Pikridas, Iasonas Stavroulas, Thérèse Salameh, Thierry Leonardis, Vincent Gaudion, Laurence Depelchin, Isabelle Fronval, Roland Sarda-Esteve, Dominique Baisnée, Bernard Bonsang, Chrysanthos Savvides, Mihalis Vrekoussis, and Nadine Locoge
Atmos. Chem. Phys., 17, 11355–11388, https://doi.org/10.5194/acp-17-11355-2017, https://doi.org/10.5194/acp-17-11355-2017, 2017
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An intensive field campaign was conducted in March 2015 in the Eastern Mediterranean region, at a background site of Cyprus. We performed a detailed analysis of the chemical composition of air masses in gas and aerosol phase, and we applied a source apportionment analysis in order to identify the various origins of VOCs. The results suggest that VOCs are mainly of biogenic and regional background origins.
Marielle Saunois, Philippe Bousquet, Ben Poulter, Anna Peregon, Philippe Ciais, Josep G. Canadell, Edward J. Dlugokencky, Giuseppe Etiope, David Bastviken, Sander Houweling, Greet Janssens-Maenhout, Francesco N. Tubiello, Simona Castaldi, Robert B. Jackson, Mihai Alexe, Vivek K. Arora, David J. Beerling, Peter Bergamaschi, Donald R. Blake, Gordon Brailsford, Lori Bruhwiler, Cyril Crevoisier, Patrick Crill, Kristofer Covey, Christian Frankenberg, Nicola Gedney, Lena Höglund-Isaksson, Misa Ishizawa, Akihiko Ito, Fortunat Joos, Heon-Sook Kim, Thomas Kleinen, Paul Krummel, Jean-François Lamarque, Ray Langenfelds, Robin Locatelli, Toshinobu Machida, Shamil Maksyutov, Joe R. Melton, Isamu Morino, Vaishali Naik, Simon O'Doherty, Frans-Jan W. Parmentier, Prabir K. Patra, Changhui Peng, Shushi Peng, Glen P. Peters, Isabelle Pison, Ronald Prinn, Michel Ramonet, William J. Riley, Makoto Saito, Monia Santini, Ronny Schroeder, Isobel J. Simpson, Renato Spahni, Atsushi Takizawa, Brett F. Thornton, Hanqin Tian, Yasunori Tohjima, Nicolas Viovy, Apostolos Voulgarakis, Ray Weiss, David J. Wilton, Andy Wiltshire, Doug Worthy, Debra Wunch, Xiyan Xu, Yukio Yoshida, Bowen Zhang, Zhen Zhang, and Qiuan Zhu
Atmos. Chem. Phys., 17, 11135–11161, https://doi.org/10.5194/acp-17-11135-2017, https://doi.org/10.5194/acp-17-11135-2017, 2017
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Following the Global Methane Budget 2000–2012 published in Saunois et al. (2016), we use the same dataset of bottom-up and top-down approaches to discuss the variations in methane emissions over the period 2000–2012. The changes in emissions are discussed both in terms of trends and quasi-decadal changes. The ensemble gathered here allows us to synthesise the robust changes in terms of regional and sectorial contributions to the increasing methane emissions.
Jakob Zscheischler, Miguel D. Mahecha, Valerio Avitabile, Leonardo Calle, Nuno Carvalhais, Philippe Ciais, Fabian Gans, Nicolas Gruber, Jens Hartmann, Martin Herold, Kazuhito Ichii, Martin Jung, Peter Landschützer, Goulven G. Laruelle, Ronny Lauerwald, Dario Papale, Philippe Peylin, Benjamin Poulter, Deepak Ray, Pierre Regnier, Christian Rödenbeck, Rosa M. Roman-Cuesta, Christopher Schwalm, Gianluca Tramontana, Alexandra Tyukavina, Riccardo Valentini, Guido van der Werf, Tristram O. West, Julie E. Wolf, and Markus Reichstein
Biogeosciences, 14, 3685–3703, https://doi.org/10.5194/bg-14-3685-2017, https://doi.org/10.5194/bg-14-3685-2017, 2017
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Here we synthesize a wide range of global spatiotemporal observational data on carbon exchanges between the Earth surface and the atmosphere. A key challenge was to consistently combining observational products of terrestrial and aquatic surfaces. Our primary goal is to identify today’s key uncertainties and observational shortcomings that would need to be addressed in future measurement campaigns or expansions of in situ observatories.
Vincent Michoud, Jean Sciare, Stéphane Sauvage, Sébastien Dusanter, Thierry Léonardis, Valérie Gros, Cerise Kalogridis, Nora Zannoni, Anaïs Féron, Jean-Eudes Petit, Vincent Crenn, Dominique Baisnée, Roland Sarda-Estève, Nicolas Bonnaire, Nicolas Marchand, H. Langley DeWitt, Jorge Pey, Aurélie Colomb, François Gheusi, Sonke Szidat, Iasonas Stavroulas, Agnès Borbon, and Nadine Locoge
Atmos. Chem. Phys., 17, 8837–8865, https://doi.org/10.5194/acp-17-8837-2017, https://doi.org/10.5194/acp-17-8837-2017, 2017
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The ChArMEx SOP2 field campaign took place from 15 July to 5 August 2013 in the western Mediterranean Basin at Ersa, a remote site in Cape Corse. Exhaustive descriptions of the chemical composition of air masses in gas and aerosol phase were performed. An analysis of these measurements was performed using various source-receptor approaches. This led to the identification of several factors linked to primary sources but also to secondary processes of both biogenic and anthropogenic origin.
Ana Bastos, Anna Peregon, Érico A. Gani, Sergey Khudyaev, Chao Yue, Wei Li, Célia Gouveia, and Philippe Ciais
Biogeosciences Discuss., https://doi.org/10.5194/bg-2017-267, https://doi.org/10.5194/bg-2017-267, 2017
Revised manuscript not accepted
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The ice-core record indicates a stabilization of atmospheric CO2 in the 1940s, which is not captured by the state-of-the-art reconstructions of CO2 sources and sinks.
The 1940s where marked by major socio-economic disruptions due to war. At the same time, very strong warming was registered in the high-latitudes. Here we evaluate the contributions of these two factors to a possible increase in the terrestrial sink not captured in other datasets, using the Former Soviet Union as a case study.
Eleanor J. Burke, Altug Ekici, Ye Huang, Sarah E. Chadburn, Chris Huntingford, Philippe Ciais, Pierre Friedlingstein, Shushi Peng, and Gerhard Krinner
Biogeosciences, 14, 3051–3066, https://doi.org/10.5194/bg-14-3051-2017, https://doi.org/10.5194/bg-14-3051-2017, 2017
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There are large reserves of carbon within the permafrost which might be released to the atmosphere under global warming. Our models suggest this release may cause an additional global temperature increase of 0.005 to 0.2°C by the year 2100 and 0.01 to 0.34°C by the year 2300. Under climate mitigation scenarios this is between 1.5 and 9 % (by 2100) and between 6 and 16 % (by 2300) of the global mean temperature change. There is a large uncertainty associated with these results.
Daniel S. Goll, Alexander J. Winkler, Thomas Raddatz, Ning Dong, Ian Colin Prentice, Philippe Ciais, and Victor Brovkin
Geosci. Model Dev., 10, 2009–2030, https://doi.org/10.5194/gmd-10-2009-2017, https://doi.org/10.5194/gmd-10-2009-2017, 2017
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The response of soil organic carbon decomposition to warming and the interactions between nitrogen and carbon cycling affect the feedbacks between the land carbon cycle and the climate. In the model JSBACH carbon–nitrogen interactions have only a small effect on the feedbacks, whereas modifications of soil organic carbon decomposition have a large effect. The carbon cycle in the improved model is more resilient to climatic changes than in previous version of the model.
Thomas Gasser, Glen P. Peters, Jan S. Fuglestvedt, William J. Collins, Drew T. Shindell, and Philippe Ciais
Earth Syst. Dynam., 8, 235–253, https://doi.org/10.5194/esd-8-235-2017, https://doi.org/10.5194/esd-8-235-2017, 2017
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Emission metrics such as GWP or GTP are used to put non-CO2 species on a
CO2-equivalentscale. In the fifth IPCC report the metrics are inconsistent, as the climate–carbon feedback is included only for CO2 but not for non-CO2 species. Here, we simulate a new impulse response function for the feedback, and we use it to correct the metrics. For instance, 1 g of CH4 is equivalent to 31 g of CO2 (instead of 28 g) following the corrected GWP100 metric. It is 34 g if other factors are also updated.
Christoph Müller, Joshua Elliott, James Chryssanthacopoulos, Almut Arneth, Juraj Balkovic, Philippe Ciais, Delphine Deryng, Christian Folberth, Michael Glotter, Steven Hoek, Toshichika Iizumi, Roberto C. Izaurralde, Curtis Jones, Nikolay Khabarov, Peter Lawrence, Wenfeng Liu, Stefan Olin, Thomas A. M. Pugh, Deepak K. Ray, Ashwan Reddy, Cynthia Rosenzweig, Alex C. Ruane, Gen Sakurai, Erwin Schmid, Rastislav Skalsky, Carol X. Song, Xuhui Wang, Allard de Wit, and Hong Yang
Geosci. Model Dev., 10, 1403–1422, https://doi.org/10.5194/gmd-10-1403-2017, https://doi.org/10.5194/gmd-10-1403-2017, 2017
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Crop models are increasingly used in climate change impact research and integrated assessments. For the Agricultural Model Intercomparison and Improvement Project (AgMIP), 14 global gridded crop models (GGCMs) have supplied crop yield simulations (1980–2010) for maize, wheat, rice and soybean. We evaluate the performance of these models against observational data at global, national and grid cell level. We propose an open-access benchmark system against which future model versions can be tested.
Yi Yin, Frederic Chevallier, Philippe Ciais, Gregoire Broquet, Anne Cozic, Sophie Szopa, and Yilong Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2017-166, https://doi.org/10.5194/acp-2017-166, 2017
Revised manuscript not accepted
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CO inverse modelling studies have so far reported significant discrepancies between model concentrations optimised with the Measurement of Pollution in the Troposphere (MOPITT) satellite retrievals and surface in-situ measurements. Here, we assess how well a global CTM fits a large variety of independent CO observations before and after assimilating MOPITTv6 retrievals to optimise CO sources/sink and discuss potential sources of errors and their implications for global CO modelling studies.
Matthieu Guimberteau, Philippe Ciais, Agnès Ducharne, Juan Pablo Boisier, Ana Paula Dutra Aguiar, Hester Biemans, Hannes De Deurwaerder, David Galbraith, Bart Kruijt, Fanny Langerwisch, German Poveda, Anja Rammig, Daniel Andres Rodriguez, Graciela Tejada, Kirsten Thonicke, Celso Von Randow, Rita C. S. Von Randow, Ke Zhang, and Hans Verbeeck
Hydrol. Earth Syst. Sci., 21, 1455–1475, https://doi.org/10.5194/hess-21-1455-2017, https://doi.org/10.5194/hess-21-1455-2017, 2017
Thomas Gasser, Philippe Ciais, Olivier Boucher, Yann Quilcaille, Maxime Tortora, Laurent Bopp, and Didier Hauglustaine
Geosci. Model Dev., 10, 271–319, https://doi.org/10.5194/gmd-10-271-2017, https://doi.org/10.5194/gmd-10-271-2017, 2017
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Simple models of the Earth system are useful, especially because of their high computing efficiency. This work describes the OSCAR model: a new simple Earth system model calibrated on state-of-the-art complex models. It will add to the pool of the few simple models currently used by the community, and it will therefore improve the robustness of future studies. Its source code is available upon request.
Lamia Ammoura, Irène Xueref-Remy, Felix Vogel, Valérie Gros, Alexia Baudic, Bernard Bonsang, Marc Delmotte, Yao Té, and Frédéric Chevallier
Atmos. Chem. Phys., 16, 15653–15664, https://doi.org/10.5194/acp-16-15653-2016, https://doi.org/10.5194/acp-16-15653-2016, 2016
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We propose a new approach to estimate urban emission ratios that takes advantage of the enhanced local urban signal in the atmosphere at low wind speed. We apply it to estimate monthly ratios between CO2, CO and some VOCs from atmospheric measurement datasets acquired in the centre of Paris between 2010 and 2014. We find that this approach is little sensitive to the regional background level definition. With this new method, we may reveal spatial and seasonal variability in the ratios in Paris.
Christian Folberth, Joshua Elliott, Christoph Müller, Juraj Balkovic, James Chryssanthacopoulos, Roberto C. Izaurralde, Curtis D. Jones, Nikolay Khabarov, Wenfeng Liu, Ashwan Reddy, Erwin Schmid, Rastislav Skalský, Hong Yang, Almut Arneth, Philippe Ciais, Delphine Deryng, Peter J. Lawrence, Stefan Olin, Thomas A. M. Pugh, Alex C. Ruane, and Xuhui Wang
Biogeosciences Discuss., https://doi.org/10.5194/bg-2016-527, https://doi.org/10.5194/bg-2016-527, 2016
Manuscript not accepted for further review
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Global crop models differ in numerous aspects such as algorithms, parameterization, input data, and management assumptions. This study compares five global crop model frameworks, all based on the same field-scale model, to identify differences induced by the latter three. Results indicate that foremost nutrient supply, soil handling, and crop management induce substantial differences in crop yield estimates whereas crop cultivars primarily result in scaling of yield levels.
Marielle Saunois, Philippe Bousquet, Ben Poulter, Anna Peregon, Philippe Ciais, Josep G. Canadell, Edward J. Dlugokencky, Giuseppe Etiope, David Bastviken, Sander Houweling, Greet Janssens-Maenhout, Francesco N. Tubiello, Simona Castaldi, Robert B. Jackson, Mihai Alexe, Vivek K. Arora, David J. Beerling, Peter Bergamaschi, Donald R. Blake, Gordon Brailsford, Victor Brovkin, Lori Bruhwiler, Cyril Crevoisier, Patrick Crill, Kristofer Covey, Charles Curry, Christian Frankenberg, Nicola Gedney, Lena Höglund-Isaksson, Misa Ishizawa, Akihiko Ito, Fortunat Joos, Heon-Sook Kim, Thomas Kleinen, Paul Krummel, Jean-François Lamarque, Ray Langenfelds, Robin Locatelli, Toshinobu Machida, Shamil Maksyutov, Kyle C. McDonald, Julia Marshall, Joe R. Melton, Isamu Morino, Vaishali Naik, Simon O'Doherty, Frans-Jan W. Parmentier, Prabir K. Patra, Changhui Peng, Shushi Peng, Glen P. Peters, Isabelle Pison, Catherine Prigent, Ronald Prinn, Michel Ramonet, William J. Riley, Makoto Saito, Monia Santini, Ronny Schroeder, Isobel J. Simpson, Renato Spahni, Paul Steele, Atsushi Takizawa, Brett F. Thornton, Hanqin Tian, Yasunori Tohjima, Nicolas Viovy, Apostolos Voulgarakis, Michiel van Weele, Guido R. van der Werf, Ray Weiss, Christine Wiedinmyer, David J. Wilton, Andy Wiltshire, Doug Worthy, Debra Wunch, Xiyan Xu, Yukio Yoshida, Bowen Zhang, Zhen Zhang, and Qiuan Zhu
Earth Syst. Sci. Data, 8, 697–751, https://doi.org/10.5194/essd-8-697-2016, https://doi.org/10.5194/essd-8-697-2016, 2016
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An accurate assessment of the methane budget is important to understand the atmospheric methane concentrations and trends and to provide realistic pathways for climate change mitigation. The various and diffuse sources of methane as well and its oxidation by a very short lifetime radical challenge this assessment. We quantify the methane sources and sinks as well as their uncertainties based on both bottom-up and top-down approaches provided by a broad international scientific community.
Sauveur Belviso, Ilja Marco Reiter, Benjamin Loubet, Valérie Gros, Juliette Lathière, David Montagne, Marc Delmotte, Michel Ramonet, Cerise Kalogridis, Benjamin Lebegue, Nicolas Bonnaire, Victor Kazan, Thierry Gauquelin, Catherine Fernandez, and Bernard Genty
Atmos. Chem. Phys., 16, 14909–14923, https://doi.org/10.5194/acp-16-14909-2016, https://doi.org/10.5194/acp-16-14909-2016, 2016
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The role that soil, foliage, and atmospheric dynamics have on surface OCS exchange in a Mediterranean forest ecosystem in southern France (O3HP) was investigated in June of 2012 and 2013 with essentially a top-down approach. Atmospheric data suggest that the site is appropriate for estimating GPP directly from eddy covariance measurements of OCS fluxes, but it is less adequate for scaling NEE to GPP from observations of vertical gradients of OCS relative to CO2 during the daytime.
Johannes Staufer, Grégoire Broquet, François-Marie Bréon, Vincent Puygrenier, Frédéric Chevallier, Irène Xueref-Rémy, Elsa Dieudonné, Morgan Lopez, Martina Schmidt, Michel Ramonet, Olivier Perrussel, Christine Lac, Lin Wu, and Philippe Ciais
Atmos. Chem. Phys., 16, 14703–14726, https://doi.org/10.5194/acp-16-14703-2016, https://doi.org/10.5194/acp-16-14703-2016, 2016
Shushi Peng, Shilong Piao, Philippe Bousquet, Philippe Ciais, Bengang Li, Xin Lin, Shu Tao, Zhiping Wang, Yuan Zhang, and Feng Zhou
Atmos. Chem. Phys., 16, 14545–14562, https://doi.org/10.5194/acp-16-14545-2016, https://doi.org/10.5194/acp-16-14545-2016, 2016
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Methane is an important greenhouse gas, which accounts for about 20 % of the warming induced by long-lived greenhouse gases since 1750. Anthropogenic methane emissions from China may have been growing rapidly in the past decades because of increased coal mining and fast growing livestock. A good long-term methane emissions dataset is still lacking. Here, we produced a detailed bottom-up inventory of anthropogenic methane emissions from the eight major source sectors in China during 1980–2010.
Corinne Le Quéré, Robbie M. Andrew, Josep G. Canadell, Stephen Sitch, Jan Ivar Korsbakken, Glen P. Peters, Andrew C. Manning, Thomas A. Boden, Pieter P. Tans, Richard A. Houghton, Ralph F. Keeling, Simone Alin, Oliver D. Andrews, Peter Anthoni, Leticia Barbero, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Philippe Ciais, Kim Currie, Christine Delire, Scott C. Doney, Pierre Friedlingstein, Thanos Gkritzalis, Ian Harris, Judith Hauck, Vanessa Haverd, Mario Hoppema, Kees Klein Goldewijk, Atul K. Jain, Etsushi Kato, Arne Körtzinger, Peter Landschützer, Nathalie Lefèvre, Andrew Lenton, Sebastian Lienert, Danica Lombardozzi, Joe R. Melton, Nicolas Metzl, Frank Millero, Pedro M. S. Monteiro, David R. Munro, Julia E. M. S. Nabel, Shin-ichiro Nakaoka, Kevin O'Brien, Are Olsen, Abdirahman M. Omar, Tsuneo Ono, Denis Pierrot, Benjamin Poulter, Christian Rödenbeck, Joe Salisbury, Ute Schuster, Jörg Schwinger, Roland Séférian, Ingunn Skjelvan, Benjamin D. Stocker, Adrienne J. Sutton, Taro Takahashi, Hanqin Tian, Bronte Tilbrook, Ingrid T. van der Laan-Luijkx, Guido R. van der Werf, Nicolas Viovy, Anthony P. Walker, Andrew J. Wiltshire, and Sönke Zaehle
Earth Syst. Sci. Data, 8, 605–649, https://doi.org/10.5194/essd-8-605-2016, https://doi.org/10.5194/essd-8-605-2016, 2016
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The Global Carbon Budget 2016 is the 11th annual update of emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land, and ocean. This data synthesis brings together measurements, statistical information, and analyses of model results in order to provide an assessment of the global carbon budget and their uncertainties for years 1959 to 2015, with a projection for year 2016.
Elton Chan, Douglas Chan, Misa Ishizawa, Felix Vogel, Jerome Brioude, Andy Delcloo, Yuehua Wu, and Baisuo Jin
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2016-213, https://doi.org/10.5194/gmd-2016-213, 2016
Revised manuscript not accepted
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The main objective of this study is to examine the impacts of errors introduced by different components in our newly developed inversion system on flux estimates with a series of controlled experiments. It is very critical for any inversion system to be fully evaluated prior to applying to real observations. As demonstrated, the results can be very sensitive to the model setup and region. It is not reasonable to expect realistic results can always be obtained using the same approach.
Igor B. Konovalov, Evgeny V. Berezin, Philippe Ciais, Grégoire Broquet, Ruslan V. Zhuravlev, and Greet Janssens-Maenhout
Atmos. Chem. Phys., 16, 13509–13540, https://doi.org/10.5194/acp-16-13509-2016, https://doi.org/10.5194/acp-16-13509-2016, 2016
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The knowledge of CO2 emissions from fossil-fuel (FF) burning is of paramount importance both for climate prediction and mitigation policy purposes. The paper introduces a method to indirectly constrain a regional budget of FF CO2 emissions by using satellite measurements of "proxy" chemical species and evaluates its potential in application to a western European region.
Marta Camino-Serrano, Elisabeth Graf Pannatier, Sara Vicca, Sebastiaan Luyssaert, Mathieu Jonard, Philippe Ciais, Bertrand Guenet, Bert Gielen, Josep Peñuelas, Jordi Sardans, Peter Waldner, Sophia Etzold, Guia Cecchini, Nicholas Clarke, Zoran Galić, Laure Gandois, Karin Hansen, Jim Johnson, Uwe Klinck, Zora Lachmanová, Antti-Jussi Lindroos, Henning Meesenburg, Tiina M. Nieminen, Tanja G. M. Sanders, Kasia Sawicka, Walter Seidling, Anne Thimonier, Elena Vanguelova, Arne Verstraeten, Lars Vesterdal, and Ivan A. Janssens
Biogeosciences, 13, 5567–5585, https://doi.org/10.5194/bg-13-5567-2016, https://doi.org/10.5194/bg-13-5567-2016, 2016
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We investigated the long-term trends of dissolved organic carbon (DOC) in soil solution and the drivers of changes in over 100 forest monitoring plots across Europe. An overall increasing trend was detected in the organic layers, but no overall trend was found in the mineral horizons. There are strong interactions between controls acting at local and regional scales. Our findings are relevant for researchers focusing on the link between terrestrial and aquatic ecosystems and for C-cycle models.
Alexia Baudic, Valérie Gros, Stéphane Sauvage, Nadine Locoge, Olivier Sanchez, Roland Sarda-Estève, Cerise Kalogridis, Jean-Eudes Petit, Nicolas Bonnaire, Dominique Baisnée, Olivier Favez, Alexandre Albinet, Jean Sciare, and Bernard Bonsang
Atmos. Chem. Phys., 16, 11961–11989, https://doi.org/10.5194/acp-16-11961-2016, https://doi.org/10.5194/acp-16-11961-2016, 2016
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This article presents ambient air VOC measurements performed in Paris during the MEGAPOLI and FRANCIPOL campaigns (2010). For the first time, we report (O)VOC concentration levels, their temporal variations and their main emission sources. The originality of this study stands in using near-field observations to help strengthen the identification of apportioned sources derived from PMF. An important finding of this work is the high contribution of the wood burning source (50 %) in winter.
Philippe Peylin, Cédric Bacour, Natasha MacBean, Sébastien Leonard, Peter Rayner, Sylvain Kuppel, Ernest Koffi, Abdou Kane, Fabienne Maignan, Frédéric Chevallier, Philippe Ciais, and Pascal Prunet
Geosci. Model Dev., 9, 3321–3346, https://doi.org/10.5194/gmd-9-3321-2016, https://doi.org/10.5194/gmd-9-3321-2016, 2016
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The study describes a carbon cycle data assimilation system that uses satellite observations of vegetation activity, net ecosystem exchange of carbon and water at many sites and atmospheric CO2 concentrations, in order to optimize the parameters of the ORCHIDEE land surface model. The optimized model is able to fit all three data streams leading to a land carbon uptake similar to independent estimates, which opens new perspectives for better prediction of the land carbon balance.
A. M. Yáñez-Serrano, A. C. Nölscher, E. Bourtsoukidis, B. Derstroff, N. Zannoni, V. Gros, M. Lanza, J. Brito, S. M. Noe, E. House, C. N. Hewitt, B. Langford, E. Nemitz, T. Behrendt, J. Williams, P. Artaxo, M. O. Andreae, and J. Kesselmeier
Atmos. Chem. Phys., 16, 10965–10984, https://doi.org/10.5194/acp-16-10965-2016, https://doi.org/10.5194/acp-16-10965-2016, 2016
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This paper provides a general overview of methyl ethyl ketone (MEK) ambient observations in different ecosystems around the world in order to provide insights into the sources, sink and role of MEK in the atmosphere.
Ana Bastos, Philippe Ciais, Jonathan Barichivich, Laurent Bopp, Victor Brovkin, Thomas Gasser, Shushi Peng, Julia Pongratz, Nicolas Viovy, and Cathy M. Trudinger
Biogeosciences, 13, 4877–4897, https://doi.org/10.5194/bg-13-4877-2016, https://doi.org/10.5194/bg-13-4877-2016, 2016
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The ice-core record shows a stabilisation of atmospheric CO2 in the 1940s, despite continued emissions from fossil fuel burning and land-use change (LUC). We use up-to-date reconstructions of the CO2 sources and sinks over the 20th century to evaluate whether these capture the CO2 plateau and to test the previously proposed hypothesis. Both strong terrestrial sink, possibly due to LUC not fully accounted for in the records, and enhanced oceanic uptake are necessary to explain this stall.
Wenli Wang, Annette Rinke, John C. Moore, Duoying Ji, Xuefeng Cui, Shushi Peng, David M. Lawrence, A. David McGuire, Eleanor J. Burke, Xiaodong Chen, Bertrand Decharme, Charles Koven, Andrew MacDougall, Kazuyuki Saito, Wenxin Zhang, Ramdane Alkama, Theodore J. Bohn, Philippe Ciais, Christine Delire, Isabelle Gouttevin, Tomohiro Hajima, Gerhard Krinner, Dennis P. Lettenmaier, Paul A. Miller, Benjamin Smith, Tetsuo Sueyoshi, and Artem B. Sherstiukov
The Cryosphere, 10, 1721–1737, https://doi.org/10.5194/tc-10-1721-2016, https://doi.org/10.5194/tc-10-1721-2016, 2016
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The winter snow insulation is a key process for air–soil temperature coupling and is relevant for permafrost simulations. Differences in simulated air–soil temperature relationships and their modulation by climate conditions are found to be related to the snow model physics. Generally, models with better performance apply multilayer snow schemes.
Jinfeng Chang, Philippe Ciais, Mario Herrero, Petr Havlik, Matteo Campioli, Xianzhou Zhang, Yongfei Bai, Nicolas Viovy, Joanna Joiner, Xuhui Wang, Shushi Peng, Chao Yue, Shilong Piao, Tao Wang, Didier A. Hauglustaine, Jean-Francois Soussana, Anna Peregon, Natalya Kosykh, and Nina Mironycheva-Tokareva
Biogeosciences, 13, 3757–3776, https://doi.org/10.5194/bg-13-3757-2016, https://doi.org/10.5194/bg-13-3757-2016, 2016
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We derived the global maps of grassland management intensity of 1901–2012, including the minimum area of managed grassland with fraction of mown/grazed part. These maps, to our knowledge for the first time, provide global, time-dependent information for drawing up global estimates of management impact on biomass production and yields and for global vegetation models to enable simulations of carbon stocks and GHG budgets beyond simple tuning of grassland productivities to account for management.
Lin Wu, Grégoire Broquet, Philippe Ciais, Valentin Bellassen, Felix Vogel, Frédéric Chevallier, Irène Xueref-Remy, and Yilong Wang
Atmos. Chem. Phys., 16, 7743–7771, https://doi.org/10.5194/acp-16-7743-2016, https://doi.org/10.5194/acp-16-7743-2016, 2016
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This paper advances atmospheric inversion of city CO2 emissions as follows: (1) illustrate how inversion methodology can be tailored to deal with very large urban networks of sensors measuring CO2 concentrations; (2) demonstrate that atmospheric inversion could be a relevant tool of Monitoring, Reporting and Verification (MRV) of city CO2 emissions; (3) clarify the theoretical potential of inversion for reducing uncertainties in the estimates of citywide total and sectoral CO2 emissions.
Khatab Abdalla, Pauline Chivenge, Philippe Ciais, and Vincent Chaplot
Biogeosciences, 13, 3619–3633, https://doi.org/10.5194/bg-13-3619-2016, https://doi.org/10.5194/bg-13-3619-2016, 2016
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Discrepancies exist on the impact of tillage on soil CO2 emissions and on the main soil and environmental controls. Results from a meta-analysis using 174 paired observations comparing CO2 emissions over entire seasons or years from tilled (untilled) soils across different climates, crop types and soil conditions show that on average: (1) tilled soils emit 21 % more CO2 than untilled soils; (2) the difference increase to 29 % in sandy soils from arid climates with low soil organic carbon content.
Stijn Hantson, Almut Arneth, Sandy P. Harrison, Douglas I. Kelley, I. Colin Prentice, Sam S. Rabin, Sally Archibald, Florent Mouillot, Steve R. Arnold, Paulo Artaxo, Dominique Bachelet, Philippe Ciais, Matthew Forrest, Pierre Friedlingstein, Thomas Hickler, Jed O. Kaplan, Silvia Kloster, Wolfgang Knorr, Gitta Lasslop, Fang Li, Stephane Mangeon, Joe R. Melton, Andrea Meyn, Stephen Sitch, Allan Spessa, Guido R. van der Werf, Apostolos Voulgarakis, and Chao Yue
Biogeosciences, 13, 3359–3375, https://doi.org/10.5194/bg-13-3359-2016, https://doi.org/10.5194/bg-13-3359-2016, 2016
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Our ability to predict the magnitude and geographic pattern of past and future fire impacts rests on our ability to model fire regimes. A large variety of models exist, and it is unclear which type of model or degree of complexity is required to model fire adequately at regional to global scales. In this paper we summarize the current state of the art in fire-regime modelling and model evaluation, and outline what lessons may be learned from the Fire Model Intercomparison Project – FireMIP.
Alex Boon, Grégoire Broquet, Deborah J. Clifford, Frédéric Chevallier, David M. Butterfield, Isabelle Pison, Michel Ramonet, Jean-Daniel Paris, and Philippe Ciais
Atmos. Chem. Phys., 16, 6735–6756, https://doi.org/10.5194/acp-16-6735-2016, https://doi.org/10.5194/acp-16-6735-2016, 2016
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We measured carbon dioxide and methane concentrations at four near-ground sites located in London, 2012. We investigated the potential for using these measurements, alongside numerical modelling, to help us to understand urban greenhouse gas emissions. Low-level sites were highly sensitive to local emissions, which questions our ability to use measurements from near-ground sites in cities in some modelling applications. A gradient approach was found to be beneficial to reduce model–data errors.
X. Wu, N. Vuichard, P. Ciais, N. Viovy, N. de Noblet-Ducoudré, X. Wang, V. Magliulo, M. Wattenbach, L. Vitale, P. Di Tommasi, E. J. Moors, W. Jans, J. Elbers, E. Ceschia, T. Tallec, C. Bernhofer, T. Grünwald, C. Moureaux, T. Manise, A. Ligne, P. Cellier, B. Loubet, E. Larmanou, and D. Ripoche
Geosci. Model Dev., 9, 857–873, https://doi.org/10.5194/gmd-9-857-2016, https://doi.org/10.5194/gmd-9-857-2016, 2016
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The response of crops to changing climate and atmospheric CO2 could have large effects on food production, terrestrial carbon, water, energy fluxes and the climate feedbacks. We developed a new process-oriented terrestrial biogeochemical model named ORCHIDEE-CROP (v0), which integrates a generic crop phenology and harvest module into the land surface model ORCHIDEE. Our model has good ability to capture the spatial gradients of crop phenology, carbon and energy-related variables across Europe.
Bertrand Guenet, Fernando Esteban Moyano, Philippe Peylin, Philippe Ciais, and Ivan A Janssens
Geosci. Model Dev., 9, 841–855, https://doi.org/10.5194/gmd-9-841-2016, https://doi.org/10.5194/gmd-9-841-2016, 2016
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We present a simple conceptual model of soil carbon decomposition (PRIM) able to reproduce priming experiments. Parameters were optimized using a Bayesian framework and evaluated against another set of soil incubation. PRIM better fit data than the original, CENTURY-type soil decomposition model. We then compared both models incorporated into the global land biosphere model ORCHIDEE. Both versions reproduced observed decay litter rates, but only ORCHIDEE-PRIM could simulate the observed priming.
C. Yue, P. Ciais, D. Zhu, T. Wang, S. S. Peng, and S. L. Piao
Biogeosciences, 13, 675–690, https://doi.org/10.5194/bg-13-675-2016, https://doi.org/10.5194/bg-13-675-2016, 2016
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The pan-boreal biome (> N45°) removes CO2 from the atmosphere (i.e., it is a carbon sink). Fires can alter this carbon balance because they release CO2 to the atmosphere but also initiate a long-term carbon sink during post-fire vegetation recovery. We found that historical fires of 1850–2009 have a small net sink contribution (~6 %) to the 2000–2009 regional carbon sink, which is a balance between immediate source effect of fires in 2000–2009 and sink effects of those in 1850–1999.
S. Peng, P. Ciais, G. Krinner, T. Wang, I. Gouttevin, A. D. McGuire, D. Lawrence, E. Burke, X. Chen, B. Decharme, C. Koven, A. MacDougall, A. Rinke, K. Saito, W. Zhang, R. Alkama, T. J. Bohn, C. Delire, T. Hajima, D. Ji, D. P. Lettenmaier, P. A. Miller, J. C. Moore, B. Smith, and T. Sueyoshi
The Cryosphere, 10, 179–192, https://doi.org/10.5194/tc-10-179-2016, https://doi.org/10.5194/tc-10-179-2016, 2016
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Soil temperature change is a key indicator of the dynamics of permafrost. Using nine process-based ecosystem models with permafrost processes, a large spread of soil temperature trends across the models. Air temperature and longwave downward radiation are the main drivers of soil temperature trends. Based on an emerging observation constraint method, the total boreal near-surface permafrost area decrease comprised between 39 ± 14 × 103 and 75 ± 14 × 103 km2 yr−1 from 1960 to 2000.
N. MacBean, F. Maignan, P. Peylin, C. Bacour, F.-M. Bréon, and P. Ciais
Biogeosciences, 12, 7185–7208, https://doi.org/10.5194/bg-12-7185-2015, https://doi.org/10.5194/bg-12-7185-2015, 2015
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Previous model evaluation studies have shown that terrestrial biosphere models (TBMs) need a better representation of the leaf phenology, but the model deficiency could be related to incorrect model parameters or inaccurate model structure. This paper presents a framework for optimising the parameters of phenology models that are commonly used in TBMs. It further demonstrates that the optimisation can result in changes to trends in vegetation productivity and an improvement in gross C fluxes.
Y. Yin, F. Chevallier, P. Ciais, G. Broquet, A. Fortems-Cheiney, I. Pison, and M. Saunois
Atmos. Chem. Phys., 15, 13433–13451, https://doi.org/10.5194/acp-15-13433-2015, https://doi.org/10.5194/acp-15-13433-2015, 2015
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We studied the global CO concentration decline over the recent decade with a sophisticated atmospheric inversion system assimilating MOPITT CO retrievals, surface methane and surface methyl chloroform in situ measurements. The inversion interprets the CO concentration decline as a 23% decrease in the CO emissions from 2002 to 2011, twice the negative trend estimated by emission inventories. In contrast to bottom-up inventories, we find negative trends over China and South-east Asia.
C. Le Quéré, R. Moriarty, R. M. Andrew, J. G. Canadell, S. Sitch, J. I. Korsbakken, P. Friedlingstein, G. P. Peters, R. J. Andres, T. A. Boden, R. A. Houghton, J. I. House, R. F. Keeling, P. Tans, A. Arneth, D. C. E. Bakker, L. Barbero, L. Bopp, J. Chang, F. Chevallier, L. P. Chini, P. Ciais, M. Fader, R. A. Feely, T. Gkritzalis, I. Harris, J. Hauck, T. Ilyina, A. K. Jain, E. Kato, V. Kitidis, K. Klein Goldewijk, C. Koven, P. Landschützer, S. K. Lauvset, N. Lefèvre, A. Lenton, I. D. Lima, N. Metzl, F. Millero, D. R. Munro, A. Murata, J. E. M. S. Nabel, S. Nakaoka, Y. Nojiri, K. O'Brien, A. Olsen, T. Ono, F. F. Pérez, B. Pfeil, D. Pierrot, B. Poulter, G. Rehder, C. Rödenbeck, S. Saito, U. Schuster, J. Schwinger, R. Séférian, T. Steinhoff, B. D. Stocker, A. J. Sutton, T. Takahashi, B. Tilbrook, I. T. van der Laan-Luijkx, G. R. van der Werf, S. van Heuven, D. Vandemark, N. Viovy, A. Wiltshire, S. Zaehle, and N. Zeng
Earth Syst. Sci. Data, 7, 349–396, https://doi.org/10.5194/essd-7-349-2015, https://doi.org/10.5194/essd-7-349-2015, 2015
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Accurate assessment of anthropogenic carbon dioxide emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere is important to understand the global carbon cycle, support the development of climate policies, and project future climate change. We describe data sets and a methodology to quantify all major components of the global carbon budget, including their uncertainties, based on a range of data and models and their interpretation by a broad scientific community.
N. Kadygrov, G. Broquet, F. Chevallier, L. Rivier, C. Gerbig, and P. Ciais
Atmos. Chem. Phys., 15, 12765–12787, https://doi.org/10.5194/acp-15-12765-2015, https://doi.org/10.5194/acp-15-12765-2015, 2015
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We study the potential of the European Integrated Carbon Observing System (ICOS) atmospheric network for estimating European CO2 ecosystem fluxes. Regional atmospheric inversions with synthetic data are used to derive it in terms of statistical uncertainty. This potential is high in western Europe and future extensions of the network will increase it in eastern Europe. Future improvements of the models underlying the inversion should also significantly decrease uncertainties at high resolution.
X. Lin, N. K. Indira, M. Ramonet, M. Delmotte, P. Ciais, B. C. Bhatt, M. V. Reddy, D. Angchuk, S. Balakrishnan, S. Jorphail, T. Dorjai, T. T. Mahey, S. Patnaik, M. Begum, C. Brenninkmeijer, S. Durairaj, R. Kirubagaran, M. Schmidt, P. S. Swathi, N. V. Vinithkumar, C. Yver Kwok, and V. K. Gaur
Atmos. Chem. Phys., 15, 9819–9849, https://doi.org/10.5194/acp-15-9819-2015, https://doi.org/10.5194/acp-15-9819-2015, 2015
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We present 5-year flask measurements (2007–2011) of greenhouse gases (GHGs) at three atmospheric stations in India. The results suggest significant sources of CO2, CH4, N2O, CO, and H2 over S and NE India, while SF6 sources are weak. The seasonal cycles for each species reflect the seasonality of sources/sinks and influences of the Indian monsoon circulations. The data show potential to infer regional patterns of GHG fluxes and atmospheric transport over this under-documented region.
E. Chan, D. Chan, M. Ishizawa, F. Vogel, J. Brioude, A. Delcloo, Y. Wu, and B. Jin
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-22715-2015, https://doi.org/10.5194/acpd-15-22715-2015, 2015
Revised manuscript not accepted
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This paper uses synthetic data experiments to investigate the impacts of different error sources associated with prior flux, transport model and optimisation method on the atmospheric greenhouse gas inverse estimates. Results indicate that estimation errors are dominated by the transport model error and can propagate to the flux estimates non-linearly. It is necessary to obtain stable and realistic results in synthetic data experiments before a real observation-based inversion is performed.
A. I. Stegehuis, R. Vautard, P. Ciais, A. J. Teuling, D. G. Miralles, and M. Wild
Geosci. Model Dev., 8, 2285–2298, https://doi.org/10.5194/gmd-8-2285-2015, https://doi.org/10.5194/gmd-8-2285-2015, 2015
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Many climate models have difficulties in properly reproducing climate extremes such as heat wave conditions. We use a regional climate model with different atmospheric physics schemes to simulate the heat wave events of 2003 in western Europe and 2010 in Russia. The five best-performing and diverse physics scheme combinations may be used in the future to perform heat wave analysis and to investigate the impact of climate change in summer in Europe.
L. Molina, G. Broquet, P. Imbach, F. Chevallier, B. Poulter, D. Bonal, B. Burban, M. Ramonet, L. V. Gatti, S. C. Wofsy, J. W. Munger, E. Dlugokencky, and P. Ciais
Atmos. Chem. Phys., 15, 8423–8438, https://doi.org/10.5194/acp-15-8423-2015, https://doi.org/10.5194/acp-15-8423-2015, 2015
D. Zhu, S. S. Peng, P. Ciais, N. Viovy, A. Druel, M. Kageyama, G. Krinner, P. Peylin, C. Ottlé, S. L. Piao, B. Poulter, D. Schepaschenko, and A. Shvidenko
Geosci. Model Dev., 8, 2263–2283, https://doi.org/10.5194/gmd-8-2263-2015, https://doi.org/10.5194/gmd-8-2263-2015, 2015
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This study presents a new parameterization of the vegetation dynamics module in the process-based ecosystem model ORCHIDEE for mid- to high-latitude regions, showing significant improvements in the modeled distribution of tree functional types north of 40°N. A new set of metrics is proposed to quantify the performance of ORCHIDEE, which integrates uncertainties in the observational data sets.
M. A. Rawlins, A. D. McGuire, J. S. Kimball, P. Dass, D. Lawrence, E. Burke, X. Chen, C. Delire, C. Koven, A. MacDougall, S. Peng, A. Rinke, K. Saito, W. Zhang, R. Alkama, T. J. Bohn, P. Ciais, B. Decharme, I. Gouttevin, T. Hajima, D. Ji, G. Krinner, D. P. Lettenmaier, P. Miller, J. C. Moore, B. Smith, and T. Sueyoshi
Biogeosciences, 12, 4385–4405, https://doi.org/10.5194/bg-12-4385-2015, https://doi.org/10.5194/bg-12-4385-2015, 2015
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We used outputs from nine models to better understand land-atmosphere CO2 exchanges across Northern Eurasia over the period 1960-1990. Model estimates were assessed against independent ground and satellite measurements. We find that the models show a weakening of the CO2 sink over time; the models tend to overestimate respiration, causing an underestimate in NEP; the model range in regional NEP is twice the multimodel mean. Residence time for soil carbon decreased, amid a gain in carbon storage.
C. E. Yver Kwok, D. Müller, C. Caldow, B. Lebègue, J. G. Mønster, C. W. Rella, C. Scheutz, M. Schmidt, M. Ramonet, T. Warneke, G. Broquet, and P. Ciais
Atmos. Meas. Tech., 8, 2853–2867, https://doi.org/10.5194/amt-8-2853-2015, https://doi.org/10.5194/amt-8-2853-2015, 2015
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This study presents two methods for estimating methane emissions from a waste water treatment plant (WWTP) along with results from a measurement campaign at a WWTP in Valence, France. We show that the tracer release method is suitable to quantify facility emissions, while the chamber measurements, provide insights into individual processes. We confirm that the open basins are not a major source of CH4 on the WWTP but that the pretreatment and sludge treatment are the main emitters.
K. Frieler, A. Levermann, J. Elliott, J. Heinke, A. Arneth, M. F. P. Bierkens, P. Ciais, D. B. Clark, D. Deryng, P. Döll, P. Falloon, B. Fekete, C. Folberth, A. D. Friend, C. Gellhorn, S. N. Gosling, I. Haddeland, N. Khabarov, M. Lomas, Y. Masaki, K. Nishina, K. Neumann, T. Oki, R. Pavlick, A. C. Ruane, E. Schmid, C. Schmitz, T. Stacke, E. Stehfest, Q. Tang, D. Wisser, V. Huber, F. Piontek, L. Warszawski, J. Schewe, H. Lotze-Campen, and H. J. Schellnhuber
Earth Syst. Dynam., 6, 447–460, https://doi.org/10.5194/esd-6-447-2015, https://doi.org/10.5194/esd-6-447-2015, 2015
K. Nishina, A. Ito, P. Falloon, A. D. Friend, D. J. Beerling, P. Ciais, D. B. Clark, R. Kahana, E. Kato, W. Lucht, M. Lomas, R. Pavlick, S. Schaphoff, L. Warszawaski, and T. Yokohata
Earth Syst. Dynam., 6, 435–445, https://doi.org/10.5194/esd-6-435-2015, https://doi.org/10.5194/esd-6-435-2015, 2015
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Our study focused on uncertainties in terrestrial C cycling under newly developed scenarios with CMIP5. This study presents first results for examining relative uncertainties of projected terrestrial C cycling in multiple projection components. Only using our new model inter-comparison project data sets enables us to evaluate various uncertainty sources in projection periods. The information on relative uncertainties is useful for climate science and climate change impact evaluation.
E. Joetzjer, C. Delire, H. Douville, P. Ciais, B. Decharme, D. Carrer, H. Verbeeck, M. De Weirdt, and D. Bonal
Geosci. Model Dev., 8, 1709–1727, https://doi.org/10.5194/gmd-8-1709-2015, https://doi.org/10.5194/gmd-8-1709-2015, 2015
R. Wang, Y. Balkanski, O. Boucher, L. Bopp, A. Chappell, P. Ciais, D. Hauglustaine, J. Peñuelas, and S. Tao
Atmos. Chem. Phys., 15, 6247–6270, https://doi.org/10.5194/acp-15-6247-2015, https://doi.org/10.5194/acp-15-6247-2015, 2015
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This study makes a first attempt to estimate the temporal trend of Fe emissions from anthropogenic and natural combustion sources from 1960 to 2007 and the emissions of Fe from mineral dust based on a recent mineralogical database. The new emission inventory is introduced into a global aerosol model. The simulated total Fe and soluble Fe concentrations in surface air as well as the deposition of total Fe are evaluated by observations over major continental and oceanic regions globally.
C. Le Quéré, R. Moriarty, R. M. Andrew, G. P. Peters, P. Ciais, P. Friedlingstein, S. D. Jones, S. Sitch, P. Tans, A. Arneth, T. A. Boden, L. Bopp, Y. Bozec, J. G. Canadell, L. P. Chini, F. Chevallier, C. E. Cosca, I. Harris, M. Hoppema, R. A. Houghton, J. I. House, A. K. Jain, T. Johannessen, E. Kato, R. F. Keeling, V. Kitidis, K. Klein Goldewijk, C. Koven, C. S. Landa, P. Landschützer, A. Lenton, I. D. Lima, G. Marland, J. T. Mathis, N. Metzl, Y. Nojiri, A. Olsen, T. Ono, S. Peng, W. Peters, B. Pfeil, B. Poulter, M. R. Raupach, P. Regnier, C. Rödenbeck, S. Saito, J. E. Salisbury, U. Schuster, J. Schwinger, R. Séférian, J. Segschneider, T. Steinhoff, B. D. Stocker, A. J. Sutton, T. Takahashi, B. Tilbrook, G. R. van der Werf, N. Viovy, Y.-P. Wang, R. Wanninkhof, A. Wiltshire, and N. Zeng
Earth Syst. Sci. Data, 7, 47–85, https://doi.org/10.5194/essd-7-47-2015, https://doi.org/10.5194/essd-7-47-2015, 2015
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Carbon dioxide (CO2) emissions from human activities (burning fossil fuels and cement production, deforestation and other land-use change) are set to rise again in 2014.
This study (updated yearly) makes an accurate assessment of anthropogenic CO2 emissions and their redistribution between the atmosphere, ocean, and terrestrial biosphere in order to better understand the global carbon cycle, support the development of climate policies, and project future climate change.
C. Yue, P. Ciais, P. Cadule, K. Thonicke, and T. T. van Leeuwen
Geosci. Model Dev., 8, 1321–1338, https://doi.org/10.5194/gmd-8-1321-2015, https://doi.org/10.5194/gmd-8-1321-2015, 2015
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We conducted parallel simulations using a global land surface model, with and without fires being included, respectively. When the anthropogenic land cover change fire is excluded, we find that natural wildfires have reduced the global land carbon uptake by 0.3Pg C per year over 1901-2012. This is equivalent to 20% of the land carbon uptake in a world without fire. This fire-induced reduction in carbon uptake could be partly explained by climate variability, in particular the ENSO events.
F. M. Bréon, G. Broquet, V. Puygrenier, F. Chevallier, I. Xueref-Remy, M. Ramonet, E. Dieudonné, M. Lopez, M. Schmidt, O. Perrussel, and P. Ciais
Atmos. Chem. Phys., 15, 1707–1724, https://doi.org/10.5194/acp-15-1707-2015, https://doi.org/10.5194/acp-15-1707-2015, 2015
S. Sitch, P. Friedlingstein, N. Gruber, S. D. Jones, G. Murray-Tortarolo, A. Ahlström, S. C. Doney, H. Graven, C. Heinze, C. Huntingford, S. Levis, P. E. Levy, M. Lomas, B. Poulter, N. Viovy, S. Zaehle, N. Zeng, A. Arneth, G. Bonan, L. Bopp, J. G. Canadell, F. Chevallier, P. Ciais, R. Ellis, M. Gloor, P. Peylin, S. L. Piao, C. Le Quéré, B. Smith, Z. Zhu, and R. Myneni
Biogeosciences, 12, 653–679, https://doi.org/10.5194/bg-12-653-2015, https://doi.org/10.5194/bg-12-653-2015, 2015
E. Joetzjer, C. Delire, H. Douville, P. Ciais, B. Decharme, R. Fisher, B. Christoffersen, J. C. Calvet, A. C. L. da Costa, L. V. Ferreira, and P. Meir
Geosci. Model Dev., 7, 2933–2950, https://doi.org/10.5194/gmd-7-2933-2014, https://doi.org/10.5194/gmd-7-2933-2014, 2014
L. Ammoura, I. Xueref-Remy, V. Gros, A. Baudic, B. Bonsang, J.-E. Petit, O. Perrussel, N. Bonnaire, J. Sciare, and F. Chevallier
Atmos. Chem. Phys., 14, 12871–12882, https://doi.org/10.5194/acp-14-12871-2014, https://doi.org/10.5194/acp-14-12871-2014, 2014
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We present the first study of CO2, VOCs and NOx measured all together in a road tunnel around the Paris megacity with the aim to quantify the ratios of these species co-emitted within traffic emissions. It allows us to independently assess some of the ratios provided in the latest Paris emission inventory. It also reveals a large variability of the ratios to CO2, implying that traffic does not have a unique imprint in the urban plume, but rather leaves various signatures.
M. Van Oijen, J. Balkovi, C. Beer, D. R. Cameron, P. Ciais, W. Cramer, T. Kato, M. Kuhnert, R. Martin, R. Myneni, A. Rammig, S. Rolinski, J.-F. Soussana, K. Thonicke, M. Van der Velde, and L. Xu
Biogeosciences, 11, 6357–6375, https://doi.org/10.5194/bg-11-6357-2014, https://doi.org/10.5194/bg-11-6357-2014, 2014
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We use a new risk analysis method, and six vegetation models, to analyse how climate change may alter drought risks in European ecosystems. The conclusions are (1) drought will pose increasing risks to productivity in the Mediterranean area; (2) this is because severe droughts will become more frequent, not because ecosystems will become more vulnerable; (3) future C sequestration will be at risk because carbon gain in primary productivity will be more affected than carbon loss in respiration.
C. Yue, P. Ciais, P. Cadule, K. Thonicke, S. Archibald, B. Poulter, W. M. Hao, S. Hantson, F. Mouillot, P. Friedlingstein, F. Maignan, and N. Viovy
Geosci. Model Dev., 7, 2747–2767, https://doi.org/10.5194/gmd-7-2747-2014, https://doi.org/10.5194/gmd-7-2747-2014, 2014
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ORCHIDEE-SPITFIRE model could moderately capture the decadal trend and variation of burned area during the 20th century, and the spatial and temporal patterns of contemporary vegetation fires. The model has a better performance in simulating fires for regions dominated by climate-driven fires, such as boreal forests. However, it has limited capability to reproduce the infrequent but important large fires in different ecosystems, where urgent model improvement is needed in the future.
A. Agustí-Panareda, S. Massart, F. Chevallier, S. Boussetta, G. Balsamo, A. Beljaars, P. Ciais, N. M. Deutscher, R. Engelen, L. Jones, R. Kivi, J.-D. Paris, V.-H. Peuch, V. Sherlock, A. T. Vermeulen, P. O. Wennberg, and D. Wunch
Atmos. Chem. Phys., 14, 11959–11983, https://doi.org/10.5194/acp-14-11959-2014, https://doi.org/10.5194/acp-14-11959-2014, 2014
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This paper presents a new operational CO2 forecast product as part of the Copernicus Atmospheric Services suite of atmospheric composition products, using the state-of-the-art numerical weather prediction model from the European Centre of Medium-Range Weather Forecasts.
The evaluation with independent observations shows that the forecast has skill in predicting the synoptic variability of CO2. The online simulation of CO2 fluxes from vegetation contributes to this skill.
I. B. Konovalov, E. V. Berezin, P. Ciais, G. Broquet, M. Beekmann, J. Hadji-Lazaro, C. Clerbaux, M. O. Andreae, J. W. Kaiser, and E.-D. Schulze
Atmos. Chem. Phys., 14, 10383–10410, https://doi.org/10.5194/acp-14-10383-2014, https://doi.org/10.5194/acp-14-10383-2014, 2014
J. P. Boisier, N. de Noblet-Ducoudré, and P. Ciais
Hydrol. Earth Syst. Sci., 18, 3571–3590, https://doi.org/10.5194/hess-18-3571-2014, https://doi.org/10.5194/hess-18-3571-2014, 2014
B. P. Guillod, B. Orlowsky, D. Miralles, A. J. Teuling, P. D. Blanken, N. Buchmann, P. Ciais, M. Ek, K. L. Findell, P. Gentine, B. R. Lintner, R. L. Scott, B. Van den Hurk, and S. I. Seneviratne
Atmos. Chem. Phys., 14, 8343–8367, https://doi.org/10.5194/acp-14-8343-2014, https://doi.org/10.5194/acp-14-8343-2014, 2014
J. B. Fisher, M. Sikka, W. C. Oechel, D. N. Huntzinger, J. R. Melton, C. D. Koven, A. Ahlström, M. A. Arain, I. Baker, J. M. Chen, P. Ciais, C. Davidson, M. Dietze, B. El-Masri, D. Hayes, C. Huntingford, A. K. Jain, P. E. Levy, M. R. Lomas, B. Poulter, D. Price, A. K. Sahoo, K. Schaefer, H. Tian, E. Tomelleri, H. Verbeeck, N. Viovy, R. Wania, N. Zeng, and C. E. Miller
Biogeosciences, 11, 4271–4288, https://doi.org/10.5194/bg-11-4271-2014, https://doi.org/10.5194/bg-11-4271-2014, 2014
M. Schmidt, M. Lopez, C. Yver Kwok, C. Messager, M. Ramonet, B. Wastine, C. Vuillemin, F. Truong, B. Gal, E. Parmentier, O. Cloué, and P. Ciais
Atmos. Meas. Tech., 7, 2283–2296, https://doi.org/10.5194/amt-7-2283-2014, https://doi.org/10.5194/amt-7-2283-2014, 2014
R. Kretschmer, C. Gerbig, U. Karstens, G. Biavati, A. Vermeulen, F. Vogel, S. Hammer, and K. U. Totsche
Atmos. Chem. Phys., 14, 7149–7172, https://doi.org/10.5194/acp-14-7149-2014, https://doi.org/10.5194/acp-14-7149-2014, 2014
P. Ciais, A. J. Dolman, A. Bombelli, R. Duren, A. Peregon, P. J. Rayner, C. Miller, N. Gobron, G. Kinderman, G. Marland, N. Gruber, F. Chevallier, R. J. Andres, G. Balsamo, L. Bopp, F.-M. Bréon, G. Broquet, R. Dargaville, T. J. Battin, A. Borges, H. Bovensmann, M. Buchwitz, J. Butler, J. G. Canadell, R. B. Cook, R. DeFries, R. Engelen, K. R. Gurney, C. Heinze, M. Heimann, A. Held, M. Henry, B. Law, S. Luyssaert, J. Miller, T. Moriyama, C. Moulin, R. B. Myneni, C. Nussli, M. Obersteiner, D. Ojima, Y. Pan, J.-D. Paris, S. L. Piao, B. Poulter, S. Plummer, S. Quegan, P. Raymond, M. Reichstein, L. Rivier, C. Sabine, D. Schimel, O. Tarasova, R. Valentini, R. Wang, G. van der Werf, D. Wickland, M. Williams, and C. Zehner
Biogeosciences, 11, 3547–3602, https://doi.org/10.5194/bg-11-3547-2014, https://doi.org/10.5194/bg-11-3547-2014, 2014
A. Valade, P. Ciais, N. Vuichard, N. Viovy, A. Caubel, N. Huth, F. Marin, and J.-F. Martiné
Geosci. Model Dev., 7, 1225–1245, https://doi.org/10.5194/gmd-7-1225-2014, https://doi.org/10.5194/gmd-7-1225-2014, 2014
C. Rumpel, V. Chaplot, P. Ciais, A. Chabbi, B. Bouahom, and C. Valentin
Biogeosciences, 11, 3299–3305, https://doi.org/10.5194/bg-11-3299-2014, https://doi.org/10.5194/bg-11-3299-2014, 2014
C. Le Quéré, G. P. Peters, R. J. Andres, R. M. Andrew, T. A. Boden, P. Ciais, P. Friedlingstein, R. A. Houghton, G. Marland, R. Moriarty, S. Sitch, P. Tans, A. Arneth, A. Arvanitis, D. C. E. Bakker, L. Bopp, J. G. Canadell, L. P. Chini, S. C. Doney, A. Harper, I. Harris, J. I. House, A. K. Jain, S. D. Jones, E. Kato, R. F. Keeling, K. Klein Goldewijk, A. Körtzinger, C. Koven, N. Lefèvre, F. Maignan, A. Omar, T. Ono, G.-H. Park, B. Pfeil, B. Poulter, M. R. Raupach, P. Regnier, C. Rödenbeck, S. Saito, J. Schwinger, J. Segschneider, B. D. Stocker, T. Takahashi, B. Tilbrook, S. van Heuven, N. Viovy, R. Wanninkhof, A. Wiltshire, and S. Zaehle
Earth Syst. Sci. Data, 6, 235–263, https://doi.org/10.5194/essd-6-235-2014, https://doi.org/10.5194/essd-6-235-2014, 2014
X. Wu, F. Babst, P. Ciais, D. Frank, M. Reichstein, M. Wattenbach, C. Zang, and M. D. Mahecha
Biogeosciences, 11, 3057–3068, https://doi.org/10.5194/bg-11-3057-2014, https://doi.org/10.5194/bg-11-3057-2014, 2014
M. Guimberteau, A. Ducharne, P. Ciais, J. P. Boisier, S. Peng, M. De Weirdt, and H. Verbeeck
Geosci. Model Dev., 7, 1115–1136, https://doi.org/10.5194/gmd-7-1115-2014, https://doi.org/10.5194/gmd-7-1115-2014, 2014
C. Szczypta, J.-C. Calvet, F. Maignan, W. Dorigo, F. Baret, and P. Ciais
Geosci. Model Dev., 7, 931–946, https://doi.org/10.5194/gmd-7-931-2014, https://doi.org/10.5194/gmd-7-931-2014, 2014
K. Nishina, A. Ito, D. J. Beerling, P. Cadule, P. Ciais, D. B. Clark, P. Falloon, A. D. Friend, R. Kahana, E. Kato, R. Keribin, W. Lucht, M. Lomas, T. T. Rademacher, R. Pavlick, S. Schaphoff, N. Vuichard, L. Warszawaski, and T. Yokohata
Earth Syst. Dynam., 5, 197–209, https://doi.org/10.5194/esd-5-197-2014, https://doi.org/10.5194/esd-5-197-2014, 2014
S. X. Fang, L. X. Zhou, P. P. Tans, P. Ciais, M. Steinbacher, L. Xu, and T. Luan
Atmos. Chem. Phys., 14, 2541–2554, https://doi.org/10.5194/acp-14-2541-2014, https://doi.org/10.5194/acp-14-2541-2014, 2014
R. Valentini, A. Arneth, A. Bombelli, S. Castaldi, R. Cazzolla Gatti, F. Chevallier, P. Ciais, E. Grieco, J. Hartmann, M. Henry, R. A. Houghton, M. Jung, W. L. Kutsch, Y. Malhi, E. Mayorga, L. Merbold, G. Murray-Tortarolo, D. Papale, P. Peylin, B. Poulter, P. A. Raymond, M. Santini, S. Sitch, G. Vaglio Laurin, G. R. van der Werf, C. A. Williams, and R. J. Scholes
Biogeosciences, 11, 381–407, https://doi.org/10.5194/bg-11-381-2014, https://doi.org/10.5194/bg-11-381-2014, 2014
J. F. Chang, N. Viovy, N. Vuichard, P. Ciais, T. Wang, A. Cozic, R. Lardy, A.-I. Graux, K. Klumpp, R. Martin, and J.-F. Soussana
Geosci. Model Dev., 6, 2165–2181, https://doi.org/10.5194/gmd-6-2165-2013, https://doi.org/10.5194/gmd-6-2165-2013, 2013
B. Guenet, F. E. Moyano, N. Vuichard, G. J. D. Kirk, P. H. Bellamy, S. Zaehle, and P. Ciais
Geosci. Model Dev., 6, 2153–2163, https://doi.org/10.5194/gmd-6-2153-2013, https://doi.org/10.5194/gmd-6-2153-2013, 2013
F. Souty, B. Dorin, T. Brunelle, P. Dumas, and P. Ciais
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmdd-6-6975-2013, https://doi.org/10.5194/gmdd-6-6975-2013, 2013
Revised manuscript has not been submitted
C. Yue, P. Ciais, S. Luyssaert, P. Cadule, J. Harden, J. Randerson, V. Bellassen, T. Wang, S. L. Piao, B. Poulter, and N. Viovy
Biogeosciences, 10, 8233–8252, https://doi.org/10.5194/bg-10-8233-2013, https://doi.org/10.5194/bg-10-8233-2013, 2013
E. Joetzjer, H. Douville, C. Delire, P. Ciais, B. Decharme, and S. Tyteca
Hydrol. Earth Syst. Sci., 17, 4885–4895, https://doi.org/10.5194/hess-17-4885-2013, https://doi.org/10.5194/hess-17-4885-2013, 2013
C. E. Yver-Kwok, D. Müller, C. Caldow, B. Lebegue, J. G. Mønster, C. W. Rella, C. Scheutz, M. Schmidt, M. Ramonet, T. Warneke, G. Broquet, and P. Ciais
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amtd-6-9181-2013, https://doi.org/10.5194/amtd-6-9181-2013, 2013
Revised manuscript not accepted
B. Mueller, M. Hirschi, C. Jimenez, P. Ciais, P. A. Dirmeyer, A. J. Dolman, J. B. Fisher, M. Jung, F. Ludwig, F. Maignan, D. G. Miralles, M. F. McCabe, M. Reichstein, J. Sheffield, K. Wang, E. F. Wood, Y. Zhang, and S. I. Seneviratne
Hydrol. Earth Syst. Sci., 17, 3707–3720, https://doi.org/10.5194/hess-17-3707-2013, https://doi.org/10.5194/hess-17-3707-2013, 2013
E. V. Berezin, I. B. Konovalov, P. Ciais, A. Richter, S. Tao, G. Janssens-Maenhout, M. Beekmann, and E.-D. Schulze
Atmos. Chem. Phys., 13, 9415–9438, https://doi.org/10.5194/acp-13-9415-2013, https://doi.org/10.5194/acp-13-9415-2013, 2013
G. Broquet, F. Chevallier, F.-M. Bréon, N. Kadygrov, M. Alemanno, F. Apadula, S. Hammer, L. Haszpra, F. Meinhardt, J. A. Morguí, J. Necki, S. Piacentino, M. Ramonet, M. Schmidt, R. L. Thompson, A. T. Vermeulen, C. Yver, and P. Ciais
Atmos. Chem. Phys., 13, 9039–9056, https://doi.org/10.5194/acp-13-9039-2013, https://doi.org/10.5194/acp-13-9039-2013, 2013
M. Roland, P. Serrano-Ortiz, A. S. Kowalski, Y. Goddéris, E. P. Sánchez-Cañete, P. Ciais, F. Domingo, S. Cuezva, S. Sanchez-Moral, B. Longdoz, D. Yakir, R. Van Grieken, J. Schott, C. Cardell, and I. A. Janssens
Biogeosciences, 10, 5009–5017, https://doi.org/10.5194/bg-10-5009-2013, https://doi.org/10.5194/bg-10-5009-2013, 2013
T. Gasser and P. Ciais
Earth Syst. Dynam., 4, 171–186, https://doi.org/10.5194/esd-4-171-2013, https://doi.org/10.5194/esd-4-171-2013, 2013
R. Wang, S. Tao, P. Ciais, H. Z. Shen, Y. Huang, H. Chen, G. F. Shen, B. Wang, W. Li, Y. Y. Zhang, Y. Lu, D. Zhu, Y. C. Chen, X. P. Liu, W. T. Wang, X. L. Wang, W. X. Liu, B. G. Li, and S. L. Piao
Atmos. Chem. Phys., 13, 5189–5203, https://doi.org/10.5194/acp-13-5189-2013, https://doi.org/10.5194/acp-13-5189-2013, 2013
C. Le Quéré, R. J. Andres, T. Boden, T. Conway, R. A. Houghton, J. I. House, G. Marland, G. P. Peters, G. R. van der Werf, A. Ahlström, R. M. Andrew, L. Bopp, J. G. Canadell, P. Ciais, S. C. Doney, C. Enright, P. Friedlingstein, C. Huntingford, A. K. Jain, C. Jourdain, E. Kato, R. F. Keeling, K. Klein Goldewijk, S. Levis, P. Levy, M. Lomas, B. Poulter, M. R. Raupach, J. Schwinger, S. Sitch, B. D. Stocker, N. Viovy, S. Zaehle, and N. Zeng
Earth Syst. Sci. Data, 5, 165–185, https://doi.org/10.5194/essd-5-165-2013, https://doi.org/10.5194/essd-5-165-2013, 2013
B. Guenet, T. Eglin, N. Vasilyeva, P. Peylin, P. Ciais, and C. Chenu
Biogeosciences, 10, 2379–2392, https://doi.org/10.5194/bg-10-2379-2013, https://doi.org/10.5194/bg-10-2379-2013, 2013
M. Ménégoz, G. Krinner, Y. Balkanski, A. Cozic, O. Boucher, and P. Ciais
The Cryosphere, 7, 537–554, https://doi.org/10.5194/tc-7-537-2013, https://doi.org/10.5194/tc-7-537-2013, 2013
J. P. Boisier, N. de Noblet-Ducoudré, and P. Ciais
Biogeosciences, 10, 1501–1516, https://doi.org/10.5194/bg-10-1501-2013, https://doi.org/10.5194/bg-10-1501-2013, 2013
F. R. Vogel, L. Huang, D. Ernst, L. Giroux, S. Racki, and D. E. J. Worthy
Atmos. Meas. Tech., 6, 301–308, https://doi.org/10.5194/amt-6-301-2013, https://doi.org/10.5194/amt-6-301-2013, 2013
P. K. Patra, J. G. Canadell, R. A. Houghton, S. L. Piao, N.-H. Oh, P. Ciais, K. R. Manjunath, A. Chhabra, T. Wang, T. Bhattacharya, P. Bousquet, J. Hartman, A. Ito, E. Mayorga, Y. Niwa, P. A. Raymond, V. V. S. S. Sarma, and R. Lasco
Biogeosciences, 10, 513–527, https://doi.org/10.5194/bg-10-513-2013, https://doi.org/10.5194/bg-10-513-2013, 2013
B. Ringeval, P. O. Hopcroft, P. J. Valdes, P. Ciais, G. Ramstein, A. J. Dolman, and M. Kageyama
Clim. Past, 9, 149–171, https://doi.org/10.5194/cp-9-149-2013, https://doi.org/10.5194/cp-9-149-2013, 2013
Related subject area
Subject: Gases | Technique: Laboratory Measurement | Topic: Instruments and Platforms
Influence of ambient NO and NO2 on the quantification of total peroxy nitrates (ΣPNs) and total alkyl nitrates (ΣANs) by thermal dissociation cavity ring-down spectroscopy (TD-CRDS)
Product ion distributions using H3O+ proton-transfer-reaction time-of-flight mass spectrometry (PTR-ToF-MS): mechanisms, transmission effects, and instrument-to-instrument variability
Simultaneous measurement of greenhouse gases (CH4, CO2 and N2O) using a simplified gas chromatography system
Measuring acetylene with a cavity ring-down spectroscopy gas analyser and its use as a tracer to quantify methane emissions
A new portable sampler of atmospheric methane for radiocarbon measurements
High-precision oxygen isotope (δ18O) measurements of atmospheric dioxygen using optical-feedback cavity-enhanced absorption spectroscopy (OF-CEAS)
Triple oxygen isotope composition of CO2 in the upper troposphere and stratosphere
Water vapor stable isotope memory effects of common tubing materials
Evaluation of a reduced-pressure chemical ion reactor utilizing adduct ionization for the detection of gaseous organic and inorganic species
Ammonium CI-Orbitrap: a tool for characterizing the reactivity of oxygenated organic molecules
A high-accuracy dynamic dilution method for generating reference gas mixtures of carbonyl sulfide at sub-nanomole-per-mole levels for long-term atmospheric observation
Optimizing the iodide-adduct chemical ionization mass spectrometry (CIMS) quantitative method for toluene oxidation intermediates: experimental insights into functional-group differences
Characterization of a new Teflon chamber and on-line analysis of isomeric multifunctional photooxidation products
A versatile water vapor generation module for vapor isotope calibration and liquid isotope measurements
Extraction, purification, and clumped isotope analysis of methane (Δ13CDH3 and Δ12CD2H2) from sources and the atmosphere
Response of protonated, adduct, and fragmented ions in Vocus proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS)
Absorption of volatile organic compounds (VOCs) by polymer tubing: implications for indoor air and use as a simple gas-phase volatility separation technique
A flexible device to produce a gas stream with a precisely controlled water vapour mixing ratio and isotope composition based on microdrop dispensing technology
Revision of an open-split-based dual-inlet system for elemental and isotope ratio mass spectrometers with a focus on clumped-isotope measurements
Characterisation of gaseous iodine species detection using the multi-scheme chemical ionisation inlet 2 with bromide and nitrate chemical ionisation methods
A novel inlet for enriching concentrations of reactive organic gases in low sampling flows
Characterizing the automatic radon flux transfer standard system Autoflux: laboratory calibration and field experiments
Influence of ozone and humidity on PTR-MS and GC-MS VOC measurements with and without a Na2S2O3 ozone scrubber
Laser-induced sublimation extraction for centimeter-resolution multi-species greenhouse gas analysis on ice cores
Ozone reactivity measurement of biogenic volatile organic compound emissions
Comparison of two photolytic calibration methods for nitrous acid
Measurement of enantiomer percentages for five monoterpenes from six conifer species by cartridge-tube-based passive sampling adsorption–thermal desorption (ps-ATD)
Identification, monitoring, and reaction kinetics of reactive trace species using time-resolved mid-infrared quantum cascade laser absorption spectroscopy: development, characterisation, and initial results for the CH2OO Criegee intermediate
Air pollution monitoring: development of ammonia (NH3) dynamic reference gas mixtures at nanomoles per mole levels to improve the lack of traceability of measurements
Formaldehyde and glyoxal measurement deploying a selected ion flow tube mass spectrometer (SIFT-MS)
Fragmentation inside proton-transfer-reaction-based mass spectrometers limits the detection of ROOR and ROOH peroxides
MULTICHARME: a modified Chernin-type multi-pass cell designed for IR and THz long-path absorption measurements in the CHARME atmospheric simulation chamber
Silicone tube humidity generator
A source for the continuous generation of pure and quantifiable HONO mixtures
Photochemical method for removing methane interference for improved gas analysis
A simulation chamber for absorption spectroscopy in planetary atmospheres
An automated system for trace gas flux measurements from plant foliage and other plant compartments
Simultaneous measurement of δ13C, δ18O and δ17O of atmospheric CO2 – performance assessment of a dual-laser absorption spectrometer
Measurement of iodine species and sulfuric acid using bromide chemical ionization mass spectrometers
A method for resolving changes in atmospheric He ∕ N2 as an indicator of fossil fuel extraction and stratospheric circulation
Application of chemical derivatization techniques combined with chemical ionization mass spectrometry to detect stabilized Criegee intermediates and peroxy radicals in the gas phase
Atomic emission detector with gas chromatographic separation and cryogenic pre-concentration (CryoTrap–GC–AED) for atmospheric trace gas measurements
New technique for high-precision, simultaneous measurements of CH4, N2O and CO2 concentrations; isotopic and elemental ratios of N2, O2 and Ar; and total air content in ice cores by wet extraction
High-precision laser spectrometer for multiple greenhouse gas analysis in 1 mL air from ice core samples
A thermal-dissociation–cavity ring-down spectrometer (TD-CRDS) for the detection of organic nitrates in gas and particle phases
Interference from alkenes in chemiluminescent NOx measurements
Calibration of an airborne HOx instrument using the All Pressure Altitude-based Calibrator for HOx Experimentation (APACHE)
Measurement of ammonia, amines and iodine compounds using protonated water cluster chemical ionization mass spectrometry
An instrument for in situ measurement of total ozone reactivity
Portable calibrator for NO based on the photolysis of N2O and a combined NO2∕NO∕O3 source for field calibrations of air pollution monitors
Laura Wüst, Patrick Dewald, Gunther N. T. E. Türk, Jos Lelieveld, and John N. Crowley
Atmos. Meas. Tech., 18, 1943–1959, https://doi.org/10.5194/amt-18-1943-2025, https://doi.org/10.5194/amt-18-1943-2025, 2025
Short summary
Short summary
Detection of NO2 via cavity ring-down spectroscopy (CRDS) after thermal dissociation (TD) of alkyl and peroxy nitrates can be used to detect total atmospheric organic nitrates originating from the interaction between biogenic emissions of volatile organic compounds and nitrogen oxides of anthropogenic origin. Here we present an improved TD-CRDS technique that avoids systematic bias resulting from secondary chemistry in the heated inlets and that can be deployed in regions with strong biogenic emissions.
Michael F. Link, Megan S. Claflin, Christina E. Cecelski, Ayomide A. Akande, Delaney Kilgour, Paul A. Heine, Matthew Coggon, Chelsea E. Stockwell, Andrew Jensen, Jie Yu, Han N. Huynh, Jenna C. Ditto, Carsten Warneke, William Dresser, Keighan Gemmell, Spiro Jorga, Rileigh L. Robertson, Joost de Gouw, Timothy Bertram, Jonathan P. D. Abbatt, Nadine Borduas-Dedekind, and Dustin Poppendieck
Atmos. Meas. Tech., 18, 1013–1038, https://doi.org/10.5194/amt-18-1013-2025, https://doi.org/10.5194/amt-18-1013-2025, 2025
Short summary
Short summary
Proton-transfer-reaction mass spectrometry (PTR-MS) is widely used for the measurement of volatile organic compounds (VOCs) both indoors and outdoors. An analytical challenge for PTR-MS measurements is the formation of unintended measurement interferences, product ion distributions (PIDs), that may appear in the data as VOCs of interest. We developed a method for quantifying PID formation and use interlaboratory comparison data to put quantitative constraints on PID formation.
Michał Bucha, Dominika Lewicka-Szczebak, and Piotr Wójtowicz
Atmos. Meas. Tech., 18, 897–908, https://doi.org/10.5194/amt-18-897-2025, https://doi.org/10.5194/amt-18-897-2025, 2025
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We present a method for the determination of greenhouse gases (CH4, CO2, N2O) using a chromatographic system with a barrier ion discharge detector (BID) and a Carboxen 1010 capillary column. The system omits the need for an electron capture detector (ECD) containing radiogenic components for N2O analysis and a flame ionisation detector (FID) with a methaniser for CO2 samples. This simplification reduces analytical costs, facilitates instrument maintenance and improves measurement robustness.
Adil Shah, Olivier Laurent, Pramod Kumar, Grégoire Broquet, Loïc Loigerot, Timothé Depelchin, Mathis Lozano, Camille Yver Kwok, Carole Philippon, Clément Romand, Elisa Allegrini, Matthieu Trombetti, and Philippe Ciais
EGUsphere, https://doi.org/10.5194/egusphere-2024-4089, https://doi.org/10.5194/egusphere-2024-4089, 2025
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Acetylene mole fraction measurements from the Picarro G2203 were characterised. Abnormal sensor behaviour was observed in wet conditions. A dry linear calibration was derived, although this was invalid below 1.2 ppb due to unstable measurements. The instrument was used to measure acetylene as a methane tracer at a landfill site. Fluxes were derived from fourteen downwind transects using both raw and calibrated acetylene mole fraction, with raw measurements resulting in 8 % flux underestimation.
Giulia Zazzeri, Lukas Wacker, Negar Haghipour, Philip Gautschi, Thomas Laemmel, Sönke Szidat, and Heather Graven
Atmos. Meas. Tech., 18, 319–325, https://doi.org/10.5194/amt-18-319-2025, https://doi.org/10.5194/amt-18-319-2025, 2025
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Radiocarbon (14C) is an optimal tracer of methane (CH4) emissions, as 14C measurements enable distinguishing between fossil methane and biogenic methane. However, these measurements are particularly challenging, mainly due to technical difficulties in the sampling procedure. We made the sample extraction much simpler and time efficient, providing a new technology that can be used by any research group, with the goal of expanding 14C measurements for an improved understanding of methane sources.
Clément Piel, Daniele Romanini, Morgane Farradèche, Justin Chaillot, Clémence Paul, Nicolas Bienville, Thomas Lauwers, Joana Sauze, Kévin Jaulin, Frédéric Prié, and Amaëlle Landais
Atmos. Meas. Tech., 17, 6647–6658, https://doi.org/10.5194/amt-17-6647-2024, https://doi.org/10.5194/amt-17-6647-2024, 2024
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This paper introduces a new optical gas analyzer based on an optical-feedback cavity-enhanced absorption spectroscopy (OF-CEAS) technique enabling high-temporal-resolution and high-precision measurements of oxygen isotopes (δ18O) and dioxygen (O2) concentration of atmospheric O2 (respectively 0.06 ‰ and 0.002 % over 10 min integration). The results underscore the good agreement with isotope ratio mass spectrometry measurements and the ability of the instrument to monitor biological processes.
Getachew Agmuas Adnew, Gerbrand Koren, Neha Mehendale, Sergey Gromov, Maarten Krol, and Thomas Röckmann
EGUsphere, https://doi.org/10.5194/egusphere-2024-3231, https://doi.org/10.5194/egusphere-2024-3231, 2024
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This study presents high-precision measurements of ∆′17O(CO2). Key findings include the extension of the N2O-∆′17O correlation to the upper troposphere and the identification of significant differences in the N2O-∆′17O slope in StratoClim samples. Additionally, the ∆′17O measurements are used to estimate global stratospheric production and surface removal of ∆′17O, providing an independent estimate of global vegetation CO2 exchange.
Alexandra L. Meyer and Lisa R. Welp
Atmos. Meas. Tech., 17, 6193–6212, https://doi.org/10.5194/amt-17-6193-2024, https://doi.org/10.5194/amt-17-6193-2024, 2024
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Water molecules stick to air intake tubing wall surfaces, smoothing measurements of fast isotopic variability in the atmosphere. We tested this stickiness and saw small differences in isotopic signal speed between materials, tubing inner dimensions, and isotopic switch direction, although no consistent temperature effects. Researchers can confidently compare measurements across observation systems using different commonly used tubing materials and plan for optimal inlet designs of new systems.
Matthieu Riva, Veronika Pospisilova, Carla Frege, Sebastien Perrier, Priyanka Bansal, Spiro Jorga, Patrick Sturm, Joel A. Thornton, Urs Rohner, and Felipe Lopez-Hilfiker
Atmos. Meas. Tech., 17, 5887–5901, https://doi.org/10.5194/amt-17-5887-2024, https://doi.org/10.5194/amt-17-5887-2024, 2024
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We present a newly designed reduced-pressure chemical ionization reactor for detection of gas-phase organic and inorganic species. The system operates through the combined use of vacuum ultraviolet ionization and photosensitizers to generate numerous adduct ionization schemes. As a result, it offers the ability to simultaneously measure a wide variety of organic and inorganic species in terms of compound volatility and functionality, while being largely independent of changes in sample humidity.
Dandan Li, Dongyu Wang, Lucia Caudillo, Wiebke Scholz, Mingyi Wang, Sophie Tomaz, Guillaume Marie, Mihnea Surdu, Elias Eccli, Xianda Gong, Loic Gonzalez-Carracedo, Manuel Granzin, Joschka Pfeifer, Birte Rörup, Benjamin Schulze, Pekka Rantala, Sébastien Perrier, Armin Hansel, Joachim Curtius, Jasper Kirkby, Neil M. Donahue, Christian George, Imad El-Haddad, and Matthieu Riva
Atmos. Meas. Tech., 17, 5413–5428, https://doi.org/10.5194/amt-17-5413-2024, https://doi.org/10.5194/amt-17-5413-2024, 2024
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Due to the analytical challenges of measuring organic vapors, it remains challenging to identify and quantify organic molecules present in the atmosphere. Here, we explore the performance of the Orbitrap chemical ionization mass spectrometer (CI-Orbitrap) using ammonium ion chemistry. This study shows that ammonium-ion-based chemistry associated with the high mass resolution of the Orbitrap mass analyzer can measure almost all inclusive compounds.
Hideki Nara, Takuya Saito, Taku Umezawa, and Yasunori Tohjima
Atmos. Meas. Tech., 17, 5187–5200, https://doi.org/10.5194/amt-17-5187-2024, https://doi.org/10.5194/amt-17-5187-2024, 2024
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We have developed a high-accuracy dynamic dilution system for generating reference gas mixtures containing carbonyl sulfide (COS). Although COS at ambient levels generally has poor storage stability, our approach involves the dilution of a gas mixture containing micromole-per-mole levels of COS, the stability of which was validated for more than 1 decade. The developed system has excellent dilution performance and will facilitate accurate instrumental calibration for atmospheric COS observation.
Mengdi Song, Shuyu He, Xin Li, Ying Liu, Shengrong Lou, Sihua Lu, Limin Zeng, and Yuanhang Zhang
Atmos. Meas. Tech., 17, 5113–5127, https://doi.org/10.5194/amt-17-5113-2024, https://doi.org/10.5194/amt-17-5113-2024, 2024
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We introduce detailed and improved quantitation and semi-quantitation methods of iodide-adduct time-of-flight chemical ionization mass spectrometry (I-CIMS) to measure toluene oxidation intermediates. We assess the experimental sensitivity of various functional group species and their binding energy with iodide ions in I-CIMS. A novel classification approach was introduced to significantly enhance the accuracy of semi-quantitative methods (improving R2 values from 0.52 to beyond 0.88).
Finja Löher, Esther Borrás, Amalia Muñoz, and Anke Christine Nölscher
Atmos. Meas. Tech., 17, 4553–4579, https://doi.org/10.5194/amt-17-4553-2024, https://doi.org/10.5194/amt-17-4553-2024, 2024
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We constructed and characterized a new indoor Teflon atmospheric simulation chamber. We evaluated wall losses, photolysis rates, and secondary reactions of multifunctional photooxidation products in the chamber. To measure these products on-line, we combined chromatographic and mass spectrometric analyses to obtain both isomeric information and a high temporal resolution. For method validation, we studied the formation yields of the main ring-retaining products of toluene.
Hans Christian Steen-Larsen and Daniele Zannoni
Atmos. Meas. Tech., 17, 4391–4409, https://doi.org/10.5194/amt-17-4391-2024, https://doi.org/10.5194/amt-17-4391-2024, 2024
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The water vapor generation module is completely scalable, allowing autonomous calibrations to use N standards and providing integration times only restricted by sample availability. We document improved reproducibility in 17O-excess liquid measurements. This module makes spectroscopy measurements comparable to mass spectrometry. We document that the vapor generation module can be used to analyze instrument performance and for vapor isotope calibration during field campaign measurements.
Malavika Sivan, Thomas Röckmann, Carina van der Veen, and Maria Elena Popa
Atmos. Meas. Tech., 17, 2687–2705, https://doi.org/10.5194/amt-17-2687-2024, https://doi.org/10.5194/amt-17-2687-2024, 2024
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We have set up a measurement system for methane-clumped isotopologues. We have built an extraction and purification system to extract pure methane for these measurements, for samples of various origins, including atmospheric air, for which we need to process about 1000 L of air for one measurement. We report here the technical setup for extraction and measurements, as well as the calibration, and we give an overview of the samples measured so far.
Fangbing Li, Dan Dan Huang, Linhui Tian, Bin Yuan, Wen Tan, Liang Zhu, Penglin Ye, Douglas Worsnop, Ka In Hoi, Kai Meng Mok, and Yong Jie Li
Atmos. Meas. Tech., 17, 2415–2427, https://doi.org/10.5194/amt-17-2415-2024, https://doi.org/10.5194/amt-17-2415-2024, 2024
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The responses of protonated, adduct, and fragmented ions of 21 volatile organic compounds (VOCs) were investigated with varying instrument settings and relative humidity (RH) in a Vocus proton-transfer-reaction mass spectrometer (PTR-MS). The protonated ions of most VOCs studied show < 15 % variation in sensitivity, except for some long-chain aldehydes. The relationship between sensitivity and PTR rate constant is complicated by the influences from ion transmission and protonated ion fraction.
Melissa A. Morris, Demetrios Pagonis, Douglas A. Day, Joost A. de Gouw, Paul J. Ziemann, and Jose L. Jimenez
Atmos. Meas. Tech., 17, 1545–1559, https://doi.org/10.5194/amt-17-1545-2024, https://doi.org/10.5194/amt-17-1545-2024, 2024
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Polymer absorption of volatile organic compounds (VOCs) is important to characterize for atmospheric sampling setups (as interactions cause sampling delays) and indoor air quality. Here we test different polymer materials and quantify their absorptive capacities through modeling. We found the main polymers in carpets to be highly absorptive, acting as large reservoirs for indoor pollution. We also demonstrated how polymer tubes can be used as a low-cost gas separation technique.
Harald Sodemann, Alena Dekhtyareva, Alvaro Fernandez, Andrew Seidl, and Jenny Maccali
Atmos. Meas. Tech., 16, 5181–5203, https://doi.org/10.5194/amt-16-5181-2023, https://doi.org/10.5194/amt-16-5181-2023, 2023
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We describe a device that allows one to produce a continuous stream of water vapour with a specified level of humidity. As a main innovation, we can mix waters with different water isotope composition. Through a series of tests we show that the performance characteristics of the device are in line with specifications. We present two laboratory applications where the device proves useful, first in characterizing instruments, and second for the analysis of water contained in stalagmites.
Stephan Räss, Peter Nyfeler, Paul Wheeler, Will Price, and Markus Christian Leuenberger
Atmos. Meas. Tech., 16, 4489–4505, https://doi.org/10.5194/amt-16-4489-2023, https://doi.org/10.5194/amt-16-4489-2023, 2023
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Due to technological advances clumped-isotope studies have gained importance in recent years. Typically, these studies are performed with high-resolution isotope ratio mass spectrometers (IRMSs) along with a changeover-valve-based dual-inlet system (DIS). We are taking a different approach, namely performing clumped-isotope measurements with a compact low-resolution IRMS with an open-split-based DIS. Currently, we are working with pure-oxygen gas for which we are providing a proof of concept.
Xu-Cheng He, Jiali Shen, Siddharth Iyer, Paxton Juuti, Jiangyi Zhang, Mrisha Koirala, Mikko M. Kytökari, Douglas R. Worsnop, Matti Rissanen, Markku Kulmala, Norbert M. Maier, Jyri Mikkilä, Mikko Sipilä, and Juha Kangasluoma
Atmos. Meas. Tech., 16, 4461–4487, https://doi.org/10.5194/amt-16-4461-2023, https://doi.org/10.5194/amt-16-4461-2023, 2023
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In this study, the upgraded multi-scheme chemical ionisation inlet 2 is presented. Sulfuric acid, hypoiodous acid, iodine, sulfur dioxide, and hydroperoxyl radicals are calibrated, and the improved ion optics allow us to detect sulfuric acid and iodine-containing molecules at as low as a few parts per quadrillion by volume. Additionally, we confirm the reliable detection of iodic acid using both the nitrate and bromide chemical ionisation methods under atmospherically relevant conditions.
Namrata Shanmukh Panji and Gabriel Isaacman-VanWertz
Atmos. Meas. Tech., 16, 4319–4330, https://doi.org/10.5194/amt-16-4319-2023, https://doi.org/10.5194/amt-16-4319-2023, 2023
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Measuring volatile organic compounds (VOCs) in the atmosphere is crucial for understanding air quality and environmental impact. Since these compounds are present in low concentrations, preconcentration of samples is often necessary for accurate detection. To address this issue, we have developed a novel inlet that uses selective permeation to concentrate organic gases in small sample flows. This device offers a promising approach for accurately detecting low levels of VOCs in the atmosphere.
Claudia Grossi, Daniel Rabago, Scott Chambers, Carlos Sáinz, Roger Curcoll, Peter P. S. Otáhal, Eliška Fialová, Luis Quindos, and Arturo Vargas
Atmos. Meas. Tech., 16, 2655–2672, https://doi.org/10.5194/amt-16-2655-2023, https://doi.org/10.5194/amt-16-2655-2023, 2023
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The automatic and low-maintenance radon flux system Autoflux, completed with environmental soil and atmosphere sensors, has been theoretically and experimentally characterized and calibrated under laboratory conditions to be used as transfer standard for in situ measurements. It will offer for the first time long-term measurements to validate radon flux maps used by the climate and the radiation protection communities for assessing the radon gas emissions in the atmosphere.
Lisa Ernle, Monika Akima Ringsdorf, and Jonathan Williams
Atmos. Meas. Tech., 16, 1179–1194, https://doi.org/10.5194/amt-16-1179-2023, https://doi.org/10.5194/amt-16-1179-2023, 2023
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Atmospheric ozone can induce artefacts in volatile organic compound measurements. Laboratory tests were made using GC-MS and PTR-MS aircraft systems under tropospheric and stratospheric conditions of humidity and ozone, with and without sodium thiosulfate filter scrubbers. Ozone in dry air produces some carbonyls and degrades alkenes. The scrubber lifetime depends on ozone concentration, flow rate and humidity. For the troposphere with scrubber, no significant artefacts were found over 14 d.
Lars Mächler, Daniel Baggenstos, Florian Krauss, Jochen Schmitt, Bernhard Bereiter, Remo Walther, Christoph Reinhard, Béla Tuzson, Lukas Emmenegger, and Hubertus Fischer
Atmos. Meas. Tech., 16, 355–372, https://doi.org/10.5194/amt-16-355-2023, https://doi.org/10.5194/amt-16-355-2023, 2023
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We present a new method to extract the gases from ice cores and measure their greenhouse gas composition. The ice is sublimated continuously with a near-infrared laser, releasing the gases, which are then analyzed on a laser absorption spectrometer. The main advantage over previous efforts is a low effective resolution of 1–2 cm. This capability is crucial for the analysis of highly thinned ice, as expected from ongoing drilling efforts to extend ice core history further back in time.
Detlev Helmig, Alex Guenther, Jacques Hueber, Ryan Daly, Wei Wang, Jeong-Hoo Park, Anssi Liikanen, and Arnaud P. Praplan
Atmos. Meas. Tech., 15, 5439–5454, https://doi.org/10.5194/amt-15-5439-2022, https://doi.org/10.5194/amt-15-5439-2022, 2022
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This research demonstrates a new method for determination of the chemical reactivity of volatile organic compounds that are emitted from the leaves and needles of trees. These measurements allow elucidating if and how much of these emissions and their associated reactivity are captured and quantified by currently applicable chemical analysis methods.
Andrew J. Lindsay and Ezra C. Wood
Atmos. Meas. Tech., 15, 5455–5464, https://doi.org/10.5194/amt-15-5455-2022, https://doi.org/10.5194/amt-15-5455-2022, 2022
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Nitrous acid (HONO) is an important source of the main atmospheric oxidant – the hydroxyl radical (OH). Advances in nitrous acid measurement techniques and calibration methods therefore improve our understanding of atmospheric oxidation processes. In this paper, we present two calibration methods based on photo-dissociating water vapor. These calibration methods are useful alternatives to conventional calibrations that involve a reacting hydrogen chloride vapor with sodium nitrite.
Ying Wang, Wentai Luo, Todd N. Rosenstiel, and James F. Pankow
Atmos. Meas. Tech., 15, 4651–4661, https://doi.org/10.5194/amt-15-4651-2022, https://doi.org/10.5194/amt-15-4651-2022, 2022
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A rapid, sensitive, and precise analytical method was developed for measuring the fractional amounts of the (−) and (+) forms of chiral enantiomeric forms of monoterpenes in air containing biogenic plant emissions. The method uses passive air sampling onto adsorption–thermal desorption (ATD) gas sampling cartridge tubes; this is followed by automatable thermal desorption onto a chiral gas chromatography (GC) column, followed by detection with mass spectrometry (MS).
Zara S. Mir, Matthew Jamieson, Nicholas R. Greenall, Paul W. Seakins, Mark A. Blitz, and Daniel Stone
Atmos. Meas. Tech., 15, 2875–2887, https://doi.org/10.5194/amt-15-2875-2022, https://doi.org/10.5194/amt-15-2875-2022, 2022
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In this work we describe the development and characterisation of an experiment using laser flash photolysis coupled with time-resolved mid-infrared (mid-IR) quantum cascade laser (QCL) absorption spectroscopy, with initial results reported for measurements of the infrared spectrum, kinetics, and product yields for the reaction of the CH2OO Criegee intermediate with SO2. This work has significance for the identification and measurement of reactive trace species in complex systems.
Tatiana Macé, Maitane Iturrate-Garcia, Céline Pascale, Bernhard Niederhauser, Sophie Vaslin-Reimann, and Christophe Sutour
Atmos. Meas. Tech., 15, 2703–2718, https://doi.org/10.5194/amt-15-2703-2022, https://doi.org/10.5194/amt-15-2703-2022, 2022
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LNE developed, with the company 2M PROCESS, a gas reference generator to dynamically generate NH3 reference gas mixtures in the air at very low fractions between 1 and 400 nmol/mol. The procedure defined by LNE for calibrating NH3 analyzers used for monitoring air quality guarantees relative expanded uncertainties lower than 2 % for this measurement range. The results of a comparison organized between METAS and LNE allowed the validation of LNE's reference generator and calibration procedure.
Antonia G. Zogka, Manolis N. Romanias, and Frederic Thevenet
Atmos. Meas. Tech., 15, 2001–2019, https://doi.org/10.5194/amt-15-2001-2022, https://doi.org/10.5194/amt-15-2001-2022, 2022
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We emphasize the application of SIFT-MS to detect two important atmospheric pollutants, i.e., formaldehyde (FM) and glyoxal (GL). FM and GL are secondary products formed by volatile organic compound oxidation in indoor and outdoor environments and play a key role in air quality and climate. We show that SIFT-MS is able to monitor these species selectively and in real time, overcoming the limitations of other, classical analytical techniques used to monitor these species in the atmosphere.
Haiyan Li, Thomas Golin Almeida, Yuanyuan Luo, Jian Zhao, Brett B. Palm, Christopher D. Daub, Wei Huang, Claudia Mohr, Jordan E. Krechmer, Theo Kurtén, and Mikael Ehn
Atmos. Meas. Tech., 15, 1811–1827, https://doi.org/10.5194/amt-15-1811-2022, https://doi.org/10.5194/amt-15-1811-2022, 2022
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This work evaluated the potential for PTR-based mass spectrometers to detect ROOR and ROOH peroxides both experimentally and through computations. Laboratory experiments using a Vocus PTR observed only noisy signals of potential dimers during α-pinene ozonolysis and a few small signals of dimeric compounds during cyclohexene ozonolysis. Quantum chemical calculations for model ROOR and ROOH systems showed that most of these peroxides should fragment partially following protonation.
Jean Decker, Éric Fertein, Jonas Bruckhuisen, Nicolas Houzel, Pierre Kulinski, Bo Fang, Weixiong Zhao, Francis Hindle, Guillaume Dhont, Robin Bocquet, Gaël Mouret, Cécile Coeur, and Arnaud Cuisset
Atmos. Meas. Tech., 15, 1201–1215, https://doi.org/10.5194/amt-15-1201-2022, https://doi.org/10.5194/amt-15-1201-2022, 2022
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We present a multiple pass system developed for the CHamber for Atmospheric Reactivity and Metrology of the Environment. This multi-pass cell allows monitoring of atmospheric species at trace levels by high-resolution spectroscopy with long interaction path lengths in the IR and for the first time in the terahertz range. Interesting prospects are highlighted in this frequency domain, such as a high degree of selectivity or the possibility to monitor in real-time atmospheric processes.
Robert F. Berg, Nicola Chiodo, and Eric Georgin
Atmos. Meas. Tech., 15, 819–832, https://doi.org/10.5194/amt-15-819-2022, https://doi.org/10.5194/amt-15-819-2022, 2022
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We made a humidity generator that adds water vapor to a flowing gas. Its range of humidity is useful for calibrating balloon-borne probes to the Earth's stratosphere. The generator’s novel feature is a saturator that comprises 5 m of silicone tubing immersed in water. The length was enough to ensure that the saturator’s output was independent of the dimensions and permeability of the tube. This simple, low-cost design provides an accuracy that is acceptable for many applications.
Guillermo Villena and Jörg Kleffmann
Atmos. Meas. Tech., 15, 627–637, https://doi.org/10.5194/amt-15-627-2022, https://doi.org/10.5194/amt-15-627-2022, 2022
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A continuous source for the generation of pure HONO mixtures was developed and characterized, which is based on the Henry's law solubility of HONO in acidic aqueous solutions. The source shows a fast time response and an excellent long-term stability and can be easily adjusted to HONO mixing ratios in the range 0.05–500 ppb. A general equation based on Henry's law is developed, whereby the HONO concentration of the source can be absolutely calculated with an accuracy of better than 10 %.
Merve Polat, Jesper Baldtzer Liisberg, Morten Krogsbøll, Thomas Blunier, and Matthew S. Johnson
Atmos. Meas. Tech., 14, 8041–8067, https://doi.org/10.5194/amt-14-8041-2021, https://doi.org/10.5194/amt-14-8041-2021, 2021
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We have designed a process for removing methane from a gas stream so that nitrous oxide can be measured without interference. These are both key long-lived greenhouse gases frequently studied in relation to ice cores, plants, water treatment and so on. However, many researchers are not aware of the problem of methane interference, and in addition there have not been good methods available for solving the problem. Here we present and evaluate such a method.
Marcel Snels, Stefania Stefani, Angelo Boccaccini, David Biondi, and Giuseppe Piccioni
Atmos. Meas. Tech., 14, 7187–7197, https://doi.org/10.5194/amt-14-7187-2021, https://doi.org/10.5194/amt-14-7187-2021, 2021
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A novel simulation chamber, PASSxS (Planetary Atmosphere Simulation System for Spectroscopy), has been developed for absorption measurements with a Fourier transform spectrometer (FTS) and possibly a cavity ring-down (CRD) spectrometer, with a sample temperature ranging from 100 K up to 550 K, while the pressure of the gas can be varied up to 60 bar. These temperature and pressure ranges cover a significant part of the planetary atmospheres in the solar system and possibly extrasolar planets.
Lukas Kohl, Markku Koskinen, Tatu Polvinen, Salla Tenhovirta, Kaisa Rissanen, Marjo Patama, Alessandro Zanetti, and Mari Pihlatie
Atmos. Meas. Tech., 14, 4445–4460, https://doi.org/10.5194/amt-14-4445-2021, https://doi.org/10.5194/amt-14-4445-2021, 2021
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We present ShoTGa-FluMS, a measurement system designed for continuous and automated measurements of trace gas and volatile organic compound (VOC) fluxes from plant shoots. ShoTGa-FluMS uses transparent shoot enclosures equipped with cooling elements, automatically replaces fixated CO2, and removes transpired water from the enclosure, thus solving multiple technical problems that have so far prevented automated plant shoot trace gas flux measurements.
Pharahilda M. Steur, Hubertus A. Scheeren, Dave D. Nelson, J. Barry McManus, and Harro A. J. Meijer
Atmos. Meas. Tech., 14, 4279–4304, https://doi.org/10.5194/amt-14-4279-2021, https://doi.org/10.5194/amt-14-4279-2021, 2021
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For understanding the sources and sinks of atmospheric CO2, measurement of stable isotopes has proven to be highly valuable. We present a new method using laser absorption spectroscopy to simultaneously conduct measurements of three CO2 isotopes, directly on dry-air samples. This new method reduces sample preparation time significantly, compared to the conventional method in which measurements are conducted on pure CO2, and avoids measurement biases introduced by CO2 extraction.
Mingyi Wang, Xu-Cheng He, Henning Finkenzeller, Siddharth Iyer, Dexian Chen, Jiali Shen, Mario Simon, Victoria Hofbauer, Jasper Kirkby, Joachim Curtius, Norbert Maier, Theo Kurtén, Douglas R. Worsnop, Markku Kulmala, Matti Rissanen, Rainer Volkamer, Yee Jun Tham, Neil M. Donahue, and Mikko Sipilä
Atmos. Meas. Tech., 14, 4187–4202, https://doi.org/10.5194/amt-14-4187-2021, https://doi.org/10.5194/amt-14-4187-2021, 2021
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Atmospheric iodine species are often short-lived with low abundance and have thus been challenging to measure. We show that the bromide chemical ionization mass spectrometry, compatible with both the atmospheric pressure and reduced pressure interfaces, can simultaneously detect various gas-phase iodine species. Combining calibration experiments and quantum chemical calculations, we quantify detection sensitivities to HOI, HIO3, I2, and H2SO4, giving detection limits down to < 106 molec. cm-3.
Benjamin Birner, William Paplawsky, Jeffrey Severinghaus, and Ralph F. Keeling
Atmos. Meas. Tech., 14, 2515–2527, https://doi.org/10.5194/amt-14-2515-2021, https://doi.org/10.5194/amt-14-2515-2021, 2021
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The atmospheric helium-to-nitrogen ratio is a promising indicator for circulation changes in the upper atmosphere and fossil fuel burning by humans. We present a very precise analysis method to determine changes in the helium-to-nitrogen ratio of air samples. The method relies on stabilizing the gas flow to a mass spectrometer and continuous removal of reactive gases. These advances enable new insights and monitoring possibilities for anthropogenic and natural processes.
Alexander Zaytsev, Martin Breitenlechner, Anna Novelli, Hendrik Fuchs, Daniel A. Knopf, Jesse H. Kroll, and Frank N. Keutsch
Atmos. Meas. Tech., 14, 2501–2513, https://doi.org/10.5194/amt-14-2501-2021, https://doi.org/10.5194/amt-14-2501-2021, 2021
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We have developed an online method for speciated measurements of organic peroxy radicals and stabilized Criegee intermediates using chemical derivatization combined with chemical ionization mass spectrometry. Chemical derivatization prevents secondary radical reactions and eliminates potential interferences. Comparison between our measurements and results from numeric modeling shows that the method can be used for the quantification of a wide range of atmospheric radicals and intermediates.
Einar Karu, Mengze Li, Lisa Ernle, Carl A. M. Brenninkmeijer, Jos Lelieveld, and Jonathan Williams
Atmos. Meas. Tech., 14, 1817–1831, https://doi.org/10.5194/amt-14-1817-2021, https://doi.org/10.5194/amt-14-1817-2021, 2021
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A gas measurement device was developed to measure trace gases (ppt level) in the air based on an atomic emission detector. It combines a cryogenic pre-concentrator (CryoTrap), a gas chromatograph (GC), and a new high-resolution atomic emission detector (AED). The CryoTrap–GC–AED instrumental setup, limits of detection, and elemental performance are presented and discussed. Two measurement case studies are reported: one in a Finnish boreal forest and the other based on an aircraft campaign.
Ikumi Oyabu, Kenji Kawamura, Kyotaro Kitamura, Remi Dallmayr, Akihiro Kitamura, Chikako Sawada, Jeffrey P. Severinghaus, Ross Beaudette, Anaïs Orsi, Satoshi Sugawara, Shigeyuki Ishidoya, Dorthe Dahl-Jensen, Kumiko Goto-Azuma, Shuji Aoki, and Takakiyo Nakazawa
Atmos. Meas. Tech., 13, 6703–6731, https://doi.org/10.5194/amt-13-6703-2020, https://doi.org/10.5194/amt-13-6703-2020, 2020
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Air in polar ice cores provides information on past atmosphere and climate. We present a new method for simultaneously measuring eight gases (CH4, N2O and CO2 concentrations; isotopic ratios of N2 and O2; elemental ratios between N2, O2 and Ar; and total air content) from single ice-core samples with high precision.
Bernhard Bereiter, Béla Tuzson, Philipp Scheidegger, André Kupferschmid, Herbert Looser, Lars Mächler, Daniel Baggenstos, Jochen Schmitt, Hubertus Fischer, and Lukas Emmenegger
Atmos. Meas. Tech., 13, 6391–6406, https://doi.org/10.5194/amt-13-6391-2020, https://doi.org/10.5194/amt-13-6391-2020, 2020
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The record of past greenhouse gas composition from ice cores is crucial for our understanding of global climate change. Deciphering this archive requires highly accurate and spatially resolved analysis of the very small amount of gas that is trapped in the ice. This is achieved with a mid-IR laser absorption spectrometer that provides simultaneous, high-precision measurements of CH4, N2O, CO2, and δ13C(CO2) and which will be coupled to a quantitative sublimation extraction method.
Natalie I. Keehan, Bellamy Brownwood, Andrey Marsavin, Douglas A. Day, and Juliane L. Fry
Atmos. Meas. Tech., 13, 6255–6269, https://doi.org/10.5194/amt-13-6255-2020, https://doi.org/10.5194/amt-13-6255-2020, 2020
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This paper describes a new instrument (a thermal-dissociation–cavity ring-down spectrometer, TD-CRDS) for the measurement of key atmospheric gaseous and particle-phase molecules containing the nitrate functional group. Several operational considerations affecting the measurements are described, as well as several characterization experiments comparing the TD-CRDS measurements to analogous measurements from other instruments. Examples are given using a TD-CRDS for ambient and laboratory studies.
Mohammed S. Alam, Leigh R. Crilley, James D. Lee, Louisa J. Kramer, Christian Pfrang, Mónica Vázquez-Moreno, Milagros Ródenas, Amalia Muñoz, and William J. Bloss
Atmos. Meas. Tech., 13, 5977–5991, https://doi.org/10.5194/amt-13-5977-2020, https://doi.org/10.5194/amt-13-5977-2020, 2020
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We report on the interference arising in measurements of nitrogen oxides (NOx) from the presence of a range of alkenes in sampled air when using the most widespread air quality monitoring technique for chemiluminescence detection. Interferences of up to 11 % are reported, depending upon the alkene present and conditions used. Such interferences may be of substantial importance for the interpretation of ambient NOx data, particularly for high volatile organic compound and low NOx environments.
Daniel Marno, Cheryl Ernest, Korbinian Hens, Umar Javed, Thomas Klimach, Monica Martinez, Markus Rudolf, Jos Lelieveld, and Hartwig Harder
Atmos. Meas. Tech., 13, 2711–2731, https://doi.org/10.5194/amt-13-2711-2020, https://doi.org/10.5194/amt-13-2711-2020, 2020
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In this study, a calibration device for OH and HO2 instruments is characterized at pressures of 275 to 1000 mbar, allowing instrument pressure sensitivity to be quantified to an accuracy of 22 % (1σ). Computational fluid dynamic simulations supporting the understanding of interactions between generated HOx and the instrument inlet led to enhanced determination of factors affecting instrument sensitivity.
Joschka Pfeifer, Mario Simon, Martin Heinritzi, Felix Piel, Lena Weitz, Dongyu Wang, Manuel Granzin, Tatjana Müller, Steffen Bräkling, Jasper Kirkby, Joachim Curtius, and Andreas Kürten
Atmos. Meas. Tech., 13, 2501–2522, https://doi.org/10.5194/amt-13-2501-2020, https://doi.org/10.5194/amt-13-2501-2020, 2020
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Ammonia is an important atmospheric trace gas that affects secondary aerosol formation and, together with sulfuric acid, the formation of new particles. A measurement technique is presented that uses high-resolution mass spectrometry and protonated water clusters for the ultrasensitive detection of ammonia at single-digit parts per trillion by volume levels. The instrument is further capable of measuring amines and a suite of iodine compounds at sub-parts per trillion by volume levels.
Roberto Sommariva, Louisa J. Kramer, Leigh R. Crilley, Mohammed S. Alam, and William J. Bloss
Atmos. Meas. Tech., 13, 1655–1670, https://doi.org/10.5194/amt-13-1655-2020, https://doi.org/10.5194/amt-13-1655-2020, 2020
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Ozone is a key atmospheric pollutant formed through chemical processing of natural and anthropogenic emissions and removed by reaction with organic compounds emitted by plants. We describe a new instrument – the
Total Ozone Reactivity Systemor TORS – that measures the total loss of ozone in the troposphere. The objective of the TORS instrument is to provide an estimate of the organic compounds emitted by plants which are not measured and thus to improve our understanding of the ozone budget.
John W. Birks, Andrew A. Turnipseed, Peter C. Andersen, Craig J. Williford, Stanley Strunk, Brian Carpenter, and Christine A. Ennis
Atmos. Meas. Tech., 13, 1001–1018, https://doi.org/10.5194/amt-13-1001-2020, https://doi.org/10.5194/amt-13-1001-2020, 2020
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We describe a portable calibration source of nitric oxide (NO) based on the photolysis of nitrous oxide. Combining this with a previous photolytic ozone (O3) source yields a calibrator that produces known mixing ratios of NO, O3, and nitrogen dioxide (NO2); NO2 is produced by the reaction of NO with O3. This portable
NO2/NO/O3 calibration source requires no external gas cylinders and can be used as a standard to calibrate O3 and NOx air pollution monitors in the field.
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Short summary
This study is dedicated to improving measurement methods when using a Cavity Ring Down Spectroscopy instrument to measure methane at sites with elevated ethane concentrations such as Oil and Gas sites. The research was undertaken after measurements of natural gas samples suggested biased δ13CH4 results. Two instruments were extensively tested to characterize the cross sensitivities to ethane and δ13CH4 and propose corrections. Results indicate that it is imperative to account for the biases.
This study is dedicated to improving measurement methods when using a Cavity Ring Down...
