Articles | Volume 8, issue 11
Atmos. Meas. Tech., 8, 4803–4815, 2015
https://doi.org/10.5194/amt-8-4803-2015
Atmos. Meas. Tech., 8, 4803–4815, 2015
https://doi.org/10.5194/amt-8-4803-2015

Research article 18 Nov 2015

Research article | 18 Nov 2015

Characterization of trace metals on soot aerosol particles with the SP-AMS: detection and quantification

S. Carbone et al.

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Cited articles

Alfarra, M. R., Coe, H., Allan, J. D., Bower, K. N., Boudries, H., Canagaratna, M. R., Jimenez, J. L., Jayne, J. T., Garforth, A., Li, S.-M., and Worsnop, D. R..: Characterization of urban and rural organic articulate in the Lower Fraser Valley using two Aerodyne aerosol mass spectrometers, Atmos. Environ., 38, 5745–5758, 2004.
Allan, J. D., Coe, H., Bower, K. N., Williams, P. I., Gallagher, M. W., Alfarra, M. R., Jimenez, J. L., Worsnop, D. R., Jayne, J. T., Canagaratna, M. R., Nemitz, E., and McDonald A. G.: Quantitative sampling using an Aerodyne Aerosol Mass Spectrometer. Part 2: Measurements of fine particulate chemical composition in two UK cities, J. Geophys. Res., 108, 4091, https://doi.org/10.1029/2002JD002359, 2003.
Allan, J. D., Delia, A. E., Coe, H., Bower, K. N., Alfarra, M. R., Jimenez, J. L., Middlebrook, A. M., Drewnick, F., Onasch, T. B., and Canagaratna, M. R.: A generalised method for the extraction of chemically resolved mass spectra from Aerodyne aerosol mass spectrometer data, J. Aerosol Sci., 35, 909–922, 2004.
Allen, A. G., Nemitz, E., Shia, J. P., Harrison, R. M., and Greenwood, J. C.: Size distributions of trace metals in atmospheric aerosols in the United Kingdom, Atmos. Environ., 35, 4581–4591, 2001.
Ago, H. Kugler, T., Cacialli, F., Salaneck, W. R., Shaffer, M. S. P., Windle, A. H., and Friend, R. H.: Work Functions and Surface Functional Groups of Multiwall Carbon Nanotubes, J. Phys. Chem. B, 103, 8116–8121, 1999.
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The purpose of this study was to develop a method for the quantification of trace metal content in black carbon aerosol in real time, such as combustion-related emissions, by using the SP-AMS. The properties of 13 different trace metals (Na, Al, Ca, V, Cr, Fe, Mn, Ni, Cu, Zn, Rb, Sr and Ba) were investigated in a controlled laboratory experiment. The results from the laboratory tests were applied to study fine particles in emissions of a heavy-fuel-oil-fired heating station.