Articles | Volume 14, issue 3
https://doi.org/10.5194/amt-14-2261-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-14-2261-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
The world Brewer reference triad – updated performance assessment and new double triad
Air Quality Research Division, Environment and Climate Change Canada,
Toronto, M3H 5T4, Canada
Vitali Fioletov
Air Quality Research Division, Environment and Climate Change Canada,
Toronto, M3H 5T4, Canada
Michael Brohart
Air Quality Research Division, Environment and Climate Change Canada,
Toronto, M3H 5T4, Canada
Volodya Savastiouk
International Ozone Services Inc., Toronto, Canada
Ihab Abboud
Air Quality Research Division, Environment and Climate Change Canada,
Toronto, M3H 5T4, Canada
Akira Ogyu
Air Quality Research Division, Environment and Climate Change Canada,
Toronto, M3H 5T4, Canada
Jonathan Davies
Air Quality Research Division, Environment and Climate Change Canada,
Toronto, M3H 5T4, Canada
Reno Sit
Air Quality Research Division, Environment and Climate Change Canada,
Toronto, M3H 5T4, Canada
Sum Chi Lee
Air Quality Research Division, Environment and Climate Change Canada,
Toronto, M3H 5T4, Canada
Alexander Cede
NASA Goddard Space Flight Center, Greenbelt, MD 20771, USA
LuftBlick, Innsbruck, Austria
Martin Tiefengraber
LuftBlick, Innsbruck, Austria
Department of Atmospheric and Cryospheric Sciences, University of
Innsbruck, Innsbruck, Austria
Moritz Müller
LuftBlick, Innsbruck, Austria
Department of Atmospheric and Cryospheric Sciences, University of
Innsbruck, Innsbruck, Austria
Debora Griffin
Air Quality Research Division, Environment and Climate Change Canada,
Toronto, M3H 5T4, Canada
Chris McLinden
Air Quality Research Division, Environment and Climate Change Canada,
Toronto, M3H 5T4, Canada
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Can Li, Nickolay A. Krotkov, Joanna Joiner, Vitali Fioletov, Chris McLinden, Debora Griffin, Peter J. T. Leonard, Simon Carn, Colin Seftor, and Alexander Vasilkov
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Satellite-derived CO emissions provide new insights into the understanding of global CO emission rates from wildfires. We use TROPOMI satellite data to create a global inventory database of wildfire CO emissions. These satellite-derived wildfire emissions are used for the evaluation and improvement of existing fire emission inventories and to examine how the wildfire CO emissions have changed over the past 2 decades.
Enrico Dammers, Janot Tokaya, Christian Mielke, Kevin Hausmann, Debora Griffin, Chris McLinden, Henk Eskes, and Renske Timmermans
Geosci. Model Dev., 17, 4983–5007, https://doi.org/10.5194/gmd-17-4983-2024, https://doi.org/10.5194/gmd-17-4983-2024, 2024
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Nitrogen dioxide (NOx) is produced by sources such as industry and traffic and is directly linked to negative impacts on health and the environment. The current construction of emission inventories to keep track of NOx emissions is slow and time-consuming. Satellite measurements provide a way to quickly and independently estimate emissions. In this study, we apply a consistent methodology to derive NOx emissions over Germany and illustrate the value of having such a method for fast projections.
Xin Yang, Kimberly Strong, Alison S. Criscitiello, Marta Santos-Garcia, Kristof Bognar, Xiaoyi Zhao, Pierre Fogal, Kaley A. Walker, Sara M. Morris, and Peter Effertz
Atmos. Chem. Phys., 24, 5863–5886, https://doi.org/10.5194/acp-24-5863-2024, https://doi.org/10.5194/acp-24-5863-2024, 2024
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This study uses snow samples collected from a Canadian high Arctic site, Eureka, to demonstrate that surface snow in early spring is a net sink of atmospheric bromine and nitrogen. Surface snow bromide and nitrate are significantly correlated, indicating the oxidation of reactive nitrogen is accelerated by reactive bromine. In addition, we show evidence that snow photochemical release of reactive bromine is very weak, and its emission flux is much smaller than the deposition flux of bromide.
Lukas Fehr, Chris McLinden, Debora Griffin, Daniel Zawada, Doug Degenstein, and Adam Bourassa
Geosci. Model Dev., 16, 7491–7507, https://doi.org/10.5194/gmd-16-7491-2023, https://doi.org/10.5194/gmd-16-7491-2023, 2023
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Vitali E. Fioletov, Chris A. McLinden, Debora Griffin, Nickolay A. Krotkov, Can Li, Joanna Joiner, Nicolas Theys, and Simon Carn
Atmos. Meas. Tech., 16, 5575–5592, https://doi.org/10.5194/amt-16-5575-2023, https://doi.org/10.5194/amt-16-5575-2023, 2023
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Xuanyi Zhang, Mark Gordon, Paul A. Makar, Timothy Jiang, Jonathan Davies, and David Tarasick
Atmos. Chem. Phys., 23, 13647–13664, https://doi.org/10.5194/acp-23-13647-2023, https://doi.org/10.5194/acp-23-13647-2023, 2023
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Measurements of ozone in the atmosphere were made in a forest downwind of oil sands mining and production facilities in northern Alberta. These measurements show that the emissions of other pollutants from oil sands production and processing reduce the amount of ozone in the forest. By using an atmospheric model combined with measurements, we find that the rate at which ozone is absorbed by the forest is lower than typical rates from similar measurements in other forests.
Vitali Fioletov, Xiaoyi Zhao, Ihab Abboud, Michael Brohart, Akira Ogyu, Reno Sit, Sum Chi Lee, Irina Petropavlovskikh, Koji Miyagawa, Bryan J. Johnson, Patrick Cullis, John Booth, Glen McConville, and C. Thomas McElroy
Atmos. Chem. Phys., 23, 12731–12751, https://doi.org/10.5194/acp-23-12731-2023, https://doi.org/10.5194/acp-23-12731-2023, 2023
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Stratospheric ozone within the Southern Hemisphere springtime polar vortex has been a subject of intense research since the discovery of the Antarctic ozone hole. The wintertime ozone in the vortex is less studied. We show that the recent wintertime ozone values over the South Pole were about 12 % below the pre-1980s level; i.e., the decline there was nearly twice as large as that over southern midlatitudes. Thus, wintertime ozone there can be used as an indicator of the ozone layer state.
Xiaoyi Zhao, Vitali Fioletov, Alberto Redondas, Julian Gröbner, Luca Egli, Franz Zeilinger, Javier López-Solano, Alberto Berjón Arroyo, James Kerr, Eliane Maillard Barras, Herman Smit, Michael Brohart, Reno Sit, Akira Ogyu, Ihab Abboud, and Sum Chi Lee
Atmos. Meas. Tech., 16, 2273–2295, https://doi.org/10.5194/amt-16-2273-2023, https://doi.org/10.5194/amt-16-2273-2023, 2023
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The Brewer ozone spectrophotometer is one of the World Meteorological Organization (WMO) Global Atmosphere Watch (GAW)'s standard ozone monitoring instruments since the 1980s. This work is aimed at obtaining answers to (1) why Brewer primary calibration work can only be performed at certain sites (e.g., Izaña and MLO) and (2) what is needed to assure the equivalence of calibration quality from different sites.
Ka Lok Chan, Pieter Valks, Klaus-Peter Heue, Ronny Lutz, Pascal Hedelt, Diego Loyola, Gaia Pinardi, Michel Van Roozendael, François Hendrick, Thomas Wagner, Vinod Kumar, Alkis Bais, Ankie Piters, Hitoshi Irie, Hisahiro Takashima, Yugo Kanaya, Yongjoo Choi, Kihong Park, Jihyo Chong, Alexander Cede, Udo Frieß, Andreas Richter, Jianzhong Ma, Nuria Benavent, Robert Holla, Oleg Postylyakov, Claudia Rivera Cárdenas, and Mark Wenig
Earth Syst. Sci. Data, 15, 1831–1870, https://doi.org/10.5194/essd-15-1831-2023, https://doi.org/10.5194/essd-15-1831-2023, 2023
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This paper presents the theoretical basis as well as verification and validation of the Global Ozone Monitoring Experiment-2 (GOME-2) daily and monthly level-3 products.
Vitali E. Fioletov, Chris A. McLinden, Debora Griffin, Ihab Abboud, Nickolay Krotkov, Peter J. T. Leonard, Can Li, Joanna Joiner, Nicolas Theys, and Simon Carn
Earth Syst. Sci. Data, 15, 75–93, https://doi.org/10.5194/essd-15-75-2023, https://doi.org/10.5194/essd-15-75-2023, 2023
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Sulfur dioxide (SO2) measurements from three satellite instruments were used to update and extend the previously developed global catalogue of large SO2 emission sources. This version 2 of the global catalogue covers the period of 2005–2021 and includes a total of 759 continuously emitting point sources. The catalogue data show an approximate 50 % decline in global SO2 emissions between 2005 and 2021, although emissions were relatively stable during the last 3 years.
Xin Yang, Kimberly Strong, Alison S. Criscitiello, Marta Santos-Garcia, Kristof Bognar, Xiaoyi Zhao, Pierre Fogal, Kaley A. Walker, Sara M. Morris, and Peter Effertz
EGUsphere, https://doi.org/10.5194/egusphere-2022-696, https://doi.org/10.5194/egusphere-2022-696, 2022
Preprint archived
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Snow pack in high Arctic plays a key role in polar atmospheric chemistry, especially in spring when photochemistry becomes active. By sampling surface snow from a Canadian high Arctic location at Eureka, Nunavut (80° N, 86° W), we demonstrate that surface snow is a net sink rather than a source of atmospheric reactive bromine and nitrate. This finding is new and opposite to previous conclusions that snowpack is a large and direct source of reactive bromine in polar spring.
Can Li, Joanna Joiner, Fei Liu, Nickolay A. Krotkov, Vitali Fioletov, and Chris McLinden
Atmos. Meas. Tech., 15, 5497–5514, https://doi.org/10.5194/amt-15-5497-2022, https://doi.org/10.5194/amt-15-5497-2022, 2022
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Satellite observations provide information on the sources of SO2, an important pollutant that affects both air quality and climate. However, these observations suffer from relatively poor data quality due to weak signals of SO2. Here, we use a machine learning technique to analyze satellite SO2 observations in order to reduce the noise and artifacts over relatively clean areas while keeping the signals near pollution sources. This leads to significant improvement in satellite SO2 data.
Katherine L. Hayden, Shao-Meng Li, John Liggio, Michael J. Wheeler, Jeremy J. B. Wentzell, Amy Leithead, Peter Brickell, Richard L. Mittermeier, Zachary Oldham, Cristian M. Mihele, Ralf M. Staebler, Samar G. Moussa, Andrea Darlington, Mengistu Wolde, Daniel Thompson, Jack Chen, Debora Griffin, Ellen Eckert, Jenna C. Ditto, Megan He, and Drew R. Gentner
Atmos. Chem. Phys., 22, 12493–12523, https://doi.org/10.5194/acp-22-12493-2022, https://doi.org/10.5194/acp-22-12493-2022, 2022
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In this study, airborne measurements provided the most detailed characterization, to date, of boreal forest wildfire emissions. Measurements showed a large diversity of air pollutants expanding the volatility range typically reported. A large portion of organic species was unidentified, likely comprised of complex organic compounds. Aircraft-derived emissions improve wildfire chemical speciation and can support reliable model predictions of pollution from boreal forest wildfires.
Mark Weber, Carlo Arosio, Melanie Coldewey-Egbers, Vitali E. Fioletov, Stacey M. Frith, Jeannette D. Wild, Kleareti Tourpali, John P. Burrows, and Diego Loyola
Atmos. Chem. Phys., 22, 6843–6859, https://doi.org/10.5194/acp-22-6843-2022, https://doi.org/10.5194/acp-22-6843-2022, 2022
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Long-term trends in column ozone have been determined from five merged total ozone datasets spanning the period 1978–2020. We show that ozone recovery due to the decline in stratospheric halogens after the 1990s (as regulated by the Montreal Protocol) is evident outside the tropical region and amounts to half a percent per decade. The ozone recovery in the Northern Hemisphere is however compensated for by the negative long-term trend contribution from atmospheric dynamics since the year 2000.
Vitali Fioletov, Chris A. McLinden, Debora Griffin, Nickolay Krotkov, Fei Liu, and Henk Eskes
Atmos. Chem. Phys., 22, 4201–4236, https://doi.org/10.5194/acp-22-4201-2022, https://doi.org/10.5194/acp-22-4201-2022, 2022
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The COVID-19 lockdown had a large impact on anthropogenic emissions and particularly on nitrogen dioxide (NO2). A new method of isolation of background, urban, and industrial components in NO2 is applied to estimate the lockdown impact on each of them. From 16 March to 15 June 2020, urban NO2 declined by −18 % to −28 % in most regions of the world, while background NO2 typically declined by less than −10 %.
Mahtab Majdzadeh, Craig A. Stroud, Christopher Sioris, Paul A. Makar, Ayodeji Akingunola, Chris McLinden, Xiaoyi Zhao, Michael D. Moran, Ihab Abboud, and Jack Chen
Geosci. Model Dev., 15, 219–249, https://doi.org/10.5194/gmd-15-219-2022, https://doi.org/10.5194/gmd-15-219-2022, 2022
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A new lookup table for aerosol optical properties based on a Mie scattering code was calculated and adopted within an improved version of the photolysis module in the GEM-MACH in-line chemical transport model. The modified version of the photolysis module makes use of online interactive aerosol feedback and applies core-shell parameterizations to the black carbon absorption efficiency based on Bond et al. (2006) to the size bins with black carbon mass fraction of less than 40 %.
Debora Griffin, Chris A. McLinden, Enrico Dammers, Cristen Adams, Chelsea E. Stockwell, Carsten Warneke, Ilann Bourgeois, Jeff Peischl, Thomas B. Ryerson, Kyle J. Zarzana, Jake P. Rowe, Rainer Volkamer, Christoph Knote, Natalie Kille, Theodore K. Koenig, Christopher F. Lee, Drew Rollins, Pamela S. Rickly, Jack Chen, Lukas Fehr, Adam Bourassa, Doug Degenstein, Katherine Hayden, Cristian Mihele, Sumi N. Wren, John Liggio, Ayodeji Akingunola, and Paul Makar
Atmos. Meas. Tech., 14, 7929–7957, https://doi.org/10.5194/amt-14-7929-2021, https://doi.org/10.5194/amt-14-7929-2021, 2021
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Satellite-derived NOx emissions from biomass burning are estimated with TROPOMI observations. Two common emission estimation methods are applied, and sensitivity tests with model output were performed to determine the accuracy of these methods. The effect of smoke aerosols on TROPOMI NO2 columns is estimated and compared to aircraft observations from four different aircraft campaigns measuring biomass burning plumes in 2018 and 2019 in North America.
Nicolas Theys, Vitali Fioletov, Can Li, Isabelle De Smedt, Christophe Lerot, Chris McLinden, Nickolay Krotkov, Debora Griffin, Lieven Clarisse, Pascal Hedelt, Diego Loyola, Thomas Wagner, Vinod Kumar, Antje Innes, Roberto Ribas, François Hendrick, Jonas Vlietinck, Hugues Brenot, and Michel Van Roozendael
Atmos. Chem. Phys., 21, 16727–16744, https://doi.org/10.5194/acp-21-16727-2021, https://doi.org/10.5194/acp-21-16727-2021, 2021
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We present a new algorithm to retrieve sulfur dioxide from space UV measurements. We apply the technique to high-resolution TROPOMI measurements and demonstrate the high sensitivity of the approach to weak SO2 emissions worldwide with an unprecedented limit of detection of 8 kt yr−1. This result has broad implications for atmospheric science studies dealing with improving emission inventories and identifying and quantifying missing sources, in the context of air quality and climate.
Henri Diémoz, Anna Maria Siani, Stefano Casadio, Anna Maria Iannarelli, Giuseppe Rocco Casale, Vladimir Savastiouk, Alexander Cede, Martin Tiefengraber, and Moritz Müller
Earth Syst. Sci. Data, 13, 4929–4950, https://doi.org/10.5194/essd-13-4929-2021, https://doi.org/10.5194/essd-13-4929-2021, 2021
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A 20-year (1996–2017) record of nitrogen dioxide column densities collected in Rome by a Brewer spectrophotometer is presented, together with the novel algorithm employed to re-evaluate the series. The high quality of the data is demonstrated by comparison with reference instrumentation, including a co-located Pandora spectrometer. The data can be used for satellite validation and identification of NO2 trends. The method can be replicated on other instruments of the international Brewer network.
Michaela I. Hegglin, Susann Tegtmeier, John Anderson, Adam E. Bourassa, Samuel Brohede, Doug Degenstein, Lucien Froidevaux, Bernd Funke, John Gille, Yasuko Kasai, Erkki T. Kyrölä, Jerry Lumpe, Donal Murtagh, Jessica L. Neu, Kristell Pérot, Ellis E. Remsberg, Alexei Rozanov, Matthew Toohey, Joachim Urban, Thomas von Clarmann, Kaley A. Walker, Hsiang-Jui Wang, Carlo Arosio, Robert Damadeo, Ryan A. Fuller, Gretchen Lingenfelser, Christopher McLinden, Diane Pendlebury, Chris Roth, Niall J. Ryan, Christopher Sioris, Lesley Smith, and Katja Weigel
Earth Syst. Sci. Data, 13, 1855–1903, https://doi.org/10.5194/essd-13-1855-2021, https://doi.org/10.5194/essd-13-1855-2021, 2021
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An overview of the SPARC Data Initiative is presented, to date the most comprehensive assessment of stratospheric composition measurements spanning 1979–2018. Measurements of 26 chemical constituents obtained from an international suite of space-based limb sounders were compiled into vertically resolved, zonal monthly mean time series. The quality and consistency of these gridded datasets are then evaluated using a climatological validation approach and a range of diagnostics.
Eloise A. Marais, John F. Roberts, Robert G. Ryan, Henk Eskes, K. Folkert Boersma, Sungyeon Choi, Joanna Joiner, Nader Abuhassan, Alberto Redondas, Michel Grutter, Alexander Cede, Laura Gomez, and Monica Navarro-Comas
Atmos. Meas. Tech., 14, 2389–2408, https://doi.org/10.5194/amt-14-2389-2021, https://doi.org/10.5194/amt-14-2389-2021, 2021
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Nitrogen oxides in the upper troposphere have a profound influence on the global troposphere, but routine reliable observations there are exceedingly rare. We apply cloud-slicing to TROPOMI total columns of nitrogen dioxide (NO2) at high spatial resolution to derive near-global observations of NO2 in the upper troposphere and show consistency with existing datasets. These data offer tremendous potential to address knowledge gaps in this oft underappreciated portion of the atmosphere.
Elena Spinei, Martin Tiefengraber, Moritz Müller, Manuel Gebetsberger, Alexander Cede, Luke Valin, James Szykman, Andrew Whitehill, Alexander Kotsakis, Fernando Santos, Nader Abbuhasan, Xiaoyi Zhao, Vitali Fioletov, Sum Chi Lee, and Robert Swap
Atmos. Meas. Tech., 14, 647–663, https://doi.org/10.5194/amt-14-647-2021, https://doi.org/10.5194/amt-14-647-2021, 2021
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Plastics are widely used in everyday life and scientific equipment. This paper presents Delrin plastic off-gassing as a function of temperature on the atmospheric measurements of formaldehyde by Pandora spectroscopic instruments. The sealed telescope assembly containing Delrin components emitted large amounts of formaldehyde at 30–45 °C, interfering with the Pandora measurements. These results have a broader implication since electronic products often experience the same temperature.
Tijl Verhoelst, Steven Compernolle, Gaia Pinardi, Jean-Christopher Lambert, Henk J. Eskes, Kai-Uwe Eichmann, Ann Mari Fjæraa, José Granville, Sander Niemeijer, Alexander Cede, Martin Tiefengraber, François Hendrick, Andrea Pazmiño, Alkiviadis Bais, Ariane Bazureau, K. Folkert Boersma, Kristof Bognar, Angelika Dehn, Sebastian Donner, Aleksandr Elokhov, Manuel Gebetsberger, Florence Goutail, Michel Grutter de la Mora, Aleksandr Gruzdev, Myrto Gratsea, Georg H. Hansen, Hitoshi Irie, Nis Jepsen, Yugo Kanaya, Dimitris Karagkiozidis, Rigel Kivi, Karin Kreher, Pieternel F. Levelt, Cheng Liu, Moritz Müller, Monica Navarro Comas, Ankie J. M. Piters, Jean-Pierre Pommereau, Thierry Portafaix, Cristina Prados-Roman, Olga Puentedura, Richard Querel, Julia Remmers, Andreas Richter, John Rimmer, Claudia Rivera Cárdenas, Lidia Saavedra de Miguel, Valery P. Sinyakov, Wolfgang Stremme, Kimberly Strong, Michel Van Roozendael, J. Pepijn Veefkind, Thomas Wagner, Folkard Wittrock, Margarita Yela González, and Claus Zehner
Atmos. Meas. Tech., 14, 481–510, https://doi.org/10.5194/amt-14-481-2021, https://doi.org/10.5194/amt-14-481-2021, 2021
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This paper reports on the ground-based validation of the NO2 data produced operationally by the TROPOMI instrument on board the Sentinel-5 Precursor satellite. Tropospheric, stratospheric, and total NO2 columns are compared to measurements collected from MAX-DOAS, ZSL-DOAS, and PGN/Pandora instruments respectively. The products are found to satisfy mission requirements in general, though negative mean differences are found at sites with high pollution levels. Potential causes are discussed.
Jan-Lukas Tirpitz, Udo Frieß, François Hendrick, Carlos Alberti, Marc Allaart, Arnoud Apituley, Alkis Bais, Steffen Beirle, Stijn Berkhout, Kristof Bognar, Tim Bösch, Ilya Bruchkouski, Alexander Cede, Ka Lok Chan, Mirjam den Hoed, Sebastian Donner, Theano Drosoglou, Caroline Fayt, Martina M. Friedrich, Arnoud Frumau, Lou Gast, Clio Gielen, Laura Gomez-Martín, Nan Hao, Arjan Hensen, Bas Henzing, Christian Hermans, Junli Jin, Karin Kreher, Jonas Kuhn, Johannes Lampel, Ang Li, Cheng Liu, Haoran Liu, Jianzhong Ma, Alexis Merlaud, Enno Peters, Gaia Pinardi, Ankie Piters, Ulrich Platt, Olga Puentedura, Andreas Richter, Stefan Schmitt, Elena Spinei, Deborah Stein Zweers, Kimberly Strong, Daan Swart, Frederik Tack, Martin Tiefengraber, René van der Hoff, Michel van Roozendael, Tim Vlemmix, Jan Vonk, Thomas Wagner, Yang Wang, Zhuoru Wang, Mark Wenig, Matthias Wiegner, Folkard Wittrock, Pinhua Xie, Chengzhi Xing, Jin Xu, Margarita Yela, Chengxin Zhang, and Xiaoyi Zhao
Atmos. Meas. Tech., 14, 1–35, https://doi.org/10.5194/amt-14-1-2021, https://doi.org/10.5194/amt-14-1-2021, 2021
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Multi-axis differential optical absorption spectroscopy (MAX-DOAS) is a ground-based remote sensing measurement technique that derives atmospheric aerosol and trace gas vertical profiles from skylight spectra. In this study, consistency and reliability of MAX-DOAS profiles are assessed by applying nine different evaluation algorithms to spectral data recorded during an intercomparison campaign in the Netherlands and by comparing the results to colocated supporting observations.
Xin Yang, Anne-M. Blechschmidt, Kristof Bognar, Audra McClure-Begley, Sara Morris, Irina Petropavlovskikh, Andreas Richter, Henrik Skov, Kimberly Strong, David W. Tarasick, Taneil Uttal, Mika Vestenius, and Xiaoyi Zhao
Atmos. Chem. Phys., 20, 15937–15967, https://doi.org/10.5194/acp-20-15937-2020, https://doi.org/10.5194/acp-20-15937-2020, 2020
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This is a modelling-based study on Arctic surface ozone, with a particular focus on spring ozone depletion events (i.e. with concentrations < 10 ppbv). Model experiments show that model runs with blowing-snow-sourced sea salt aerosols implemented as a source of reactive bromine can reproduce well large-scale ozone depletion events observed in the Arctic. This study supplies modelling evidence of the proposed mechanism of reactive-bromine release from blowing snow on sea ice (Yang et al., 2008).
Gaia Pinardi, Michel Van Roozendael, François Hendrick, Nicolas Theys, Nader Abuhassan, Alkiviadis Bais, Folkert Boersma, Alexander Cede, Jihyo Chong, Sebastian Donner, Theano Drosoglou, Anatoly Dzhola, Henk Eskes, Udo Frieß, José Granville, Jay R. Herman, Robert Holla, Jari Hovila, Hitoshi Irie, Yugo Kanaya, Dimitris Karagkiozidis, Natalia Kouremeti, Jean-Christopher Lambert, Jianzhong Ma, Enno Peters, Ankie Piters, Oleg Postylyakov, Andreas Richter, Julia Remmers, Hisahiro Takashima, Martin Tiefengraber, Pieter Valks, Tim Vlemmix, Thomas Wagner, and Folkard Wittrock
Atmos. Meas. Tech., 13, 6141–6174, https://doi.org/10.5194/amt-13-6141-2020, https://doi.org/10.5194/amt-13-6141-2020, 2020
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We validate several GOME-2 and OMI tropospheric NO2 products with 23 MAX-DOAS and 16 direct sun instruments distributed worldwide, highlighting large horizontal inhomogeneities at several sites affecting the validation results. We propose a method for quantification and correction. We show the application of such correction reduces the satellite underestimation in almost all heterogeneous cases, but a negative bias remains over the MAX-DOAS and direct sun network ensemble for both satellites.
Laura M. Judd, Jassim A. Al-Saadi, James J. Szykman, Lukas C. Valin, Scott J. Janz, Matthew G. Kowalewski, Henk J. Eskes, J. Pepijn Veefkind, Alexander Cede, Moritz Mueller, Manuel Gebetsberger, Robert Swap, R. Bradley Pierce, Caroline R. Nowlan, Gonzalo González Abad, Amin Nehrir, and David Williams
Atmos. Meas. Tech., 13, 6113–6140, https://doi.org/10.5194/amt-13-6113-2020, https://doi.org/10.5194/amt-13-6113-2020, 2020
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This paper evaluates Sentinel-5P TROPOMI v1.2 NO2 tropospheric columns over New York City using data from airborne mapping spectrometers and a network of ground-based spectrometers (Pandora) collected in 2018. These evaluations consider impacts due to cloud parameters, a priori profile assumptions, and spatial and temporal variability. Overall, TROPOMI tropospheric NO2 columns appear to have a low bias in this region.
Holger Vömel, Herman G. J. Smit, David Tarasick, Bryan Johnson, Samuel J. Oltmans, Henry Selkirk, Anne M. Thompson, Ryan M. Stauffer, Jacquelyn C. Witte, Jonathan Davies, Roeland van Malderen, Gary A. Morris, Tatsumi Nakano, and Rene Stübi
Atmos. Meas. Tech., 13, 5667–5680, https://doi.org/10.5194/amt-13-5667-2020, https://doi.org/10.5194/amt-13-5667-2020, 2020
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The time response of electrochemical concentration cell (ECC) ozonesondes points to at least two distinct reaction pathways with time constants of approximately 20 s and 25 min. Properly considering these time constants eliminates the need for a poorly defined "background" and allows reducing ad hoc corrections based on laboratory tests. This reduces the uncertainty of ECC ozonesonde measurements throughout the profile and especially in regions of low ozone and strong gradients of ozone.
Cited articles
Antón, M., López, M., Vilaplana, J. M., Kroon, M., McPeters, R.,
Bañón, M., and Serrano, A.: Validation of OMI-TOMS and OMI-DOAS total
ozone column using five Brewer spectroradiometers at the Iberian peninsula,
J. Geophys. Res., 114, D14307, https://doi.org/10.1029/2009jd012003, 2009.
Bais, A. F., Zerefos, C. S., and McElroy, C.: Solar UVB measurements with the double- and single-monochromator Brewer ozone spectrophotometers, Geophys. Res. Lett., 23, 833–836, 1996.
Bass, A. M. and Paur, R. J.: The ultraviolet cross-sections of ozone: I. The measurements, in: Atmospheric Ozone, Springer, Germany, 606–610, 1985.
Bhartia, P. K. and Wellemeyer, C. W.: OMI TOMS-V8 Total O3 algorithm, algorithm theoretical baseline document: OMI ozone products, NASA Goddard Space Flight Center, Greenbelt, Md., 2002.
Brewer, A. W.: A replacement for the Dobson spectrophotometer?, Pure Appl. Geophys., 106, 919–927, 1973.
Cede, A.: Manual for Blick Software Suite 1.6, available at: https://www.pandonia-global-network.org/wp-content/uploads/2019/11/BlickSoftwareSuite_Manual_v1-7.pdf (last access: 10 March 2021), 2019.
Cede, A., Herman, J., Richter, A., Krotkov, N., and Burrows, J.: Measurements of nitrogen dioxide total column amounts using a Brewer double spectrophotometer in direct Sun mode, J. Geophys. Res., 111, D05304, https://doi.org/10.1029/2005JD006585, 2006.
Cede, A., Tiefengraber, M., Gebetsberger, M., and Kreuter, M.: TN on PGN products “correct use” guidelines, Pandonia Global Network, available at:
https://www.pandonia-global-network.org/wp-content/uploads/2020/01/LuftBlick_FRM4AQ_PGNUserGuidelines_RP_2019009_v1.pdf (last access: 13 November 2020), 2019.
Dee, D. P., Uppala, S. M., Simmons, A. J., Berrisford, P., Poli, P., Kobayashi, S., Andrae, U., Balmaseda, M. A., Balsamo, G., Bauer, P., Bechtold, P., Beljaars, A. C. M., van de Berg, L., Bidlot, J., Bormann, N., Delsol, C., Dragani, R., Fuentes, M., Geer, A. J., Haimberger, L., Healy, S. B., Hersbach, H., Hólm, E. V., Isaksen, L., Kållberg, P., Köhler, M., Matricardi, M., McNally, A. P., Monge-Sanz, B. M., Morcrette, J. J., Park, B. K., Peubey, C., de Rosnay, P., Tavolato, C., Thépaut, J. N., and Vitart, F.: The ERA-Interim reanalysis: configuration and performance of the data assimilation system, Q. J. Roy. Meteor. Soc., 137, 553–597, https://doi.org/10.1002/qj.828, 2011.
Dobson, G. M. B.: Forty Years' Research on Atmospheric Ozone at Oxford: a History, Appl. Optics., 7, 387–405, https://doi.org/10.1364/ao.7.000387, 1968.
Farman, J. C., Gardiner, B. G., and Shanklin, J. D.: Large losses of total ozone in Antarctica reveal seasonal ClOx/NOx interaction, Nature, 315, 207–210, https://doi.org/10.1038/315207a0, 1985.
Fioletov, V. E. and Ogyu, A.: Brewer Processing Software, available at: ftp://exp-studies.tor.ec.gc.ca/pub/Brewer_Processing_Software/brewer_processing_software.pdf (last access: 1 June 2020), 2008.
Fioletov, V. E., Griffioen, E., Kerr, J. B., Wardle, D. I., and Uchino, O.: Influence of volcanic sulfur dioxide on spectral UV irradiance as measured by Brewer Spectrophotometers, Geophys. Res. Lett., 25, 1665–1668, https://doi.org/10.1029/98GL51305, 1998.
Fioletov, V. E., Kerr, J. B., Hare, E. W., Labow, G. J., and McPeters, R. D.: An assessment of the world ground-based total ozone network performance from the comparison with satellite data, J. Geophys. Res., 104, 1737–1747, https://doi.org/10.1029/1998JD100046, 1999.
Fioletov, V. E., Kerr, J. B., Wardle, D. I., and Wu, E.: Correction of stray light for the Brewer single monochromator, in: Proceedings of the Quadrennial Ozone Symposium, Hokkaido University, Sapporo, Japan, 3–8 July 2000, p. 37, 2000.
Fioletov, V. E., Kerr, J. B., Wardle, D. I., Krotkov, N. A., and Herman, J. R.: Comparison of Brewer ultraviolet irradiance measurements with total ozone mapping spectrometer satellite retrievals, Opt. Eng., 41, 3051–3062, https://doi.org/10.1117/1.1516818, 2002.
Fioletov, V. E., Kerr, J. B., McElroy, C. T., Wardle, D. I., Savastiouk, V., and Grajnar, T. S.: The Brewer reference triad, Geophys. Res. Lett., 32, L20805, https://doi.org/10.1029/2005GL024244., 2005.
Fioletov, V. E., McLinden, C. A., McElroy, C. T., and Savastiouk, V.: New method for deriving total ozone from Brewer zenith sky observations, J. Geophys. Res., 116, D08301, https://doi.org/10.1029/2010JD015399, 2011.
Flynn, L., Long, C., Wu, X., Evans, R., Beck, C. T., Petropavlovskikh, I., McConville, G., Yu, W., Zhang, Z., Niu, J., Beach, E., Hao, Y., Pan, C., Sen, B., Novicki, M., Zhou, S., and Seftor, C.: Performance of the Ozone Mapping and Profiler Suite (OMPS) products, J. Geophys. Res., 119, 6181–6195, https://doi.org/10.1002/2013JD020467, 2014.
Garane, K., Koukouli, M.-E., Verhoelst, T., Lerot, C., Heue, K.-P., Fioletov, V., Balis, D., Bais, A., Bazureau, A., Dehn, A., Goutail, F., Granville, J., Griffin, D., Hubert, D., Keppens, A., Lambert, J.-C., Loyola, D., McLinden, C., Pazmino, A., Pommereau, J.-P., Redondas, A., Romahn, F., Valks, P., Van Roozendael, M., Xu, J., Zehner, C., Zerefos, C., and Zimmer, W.: TROPOMI/S5P total ozone column data: global ground-based validation and consistency with other satellite missions, Atmos. Meas. Tech., 12, 5263–5287, https://doi.org/10.5194/amt-12-5263-2019, 2019.
Global Modeling and Assimilation Office (GMAO): MERRA-2 tavg1_2d_slv_Nx: 2d,1-Hourly,Time-Averaged,Single-Level,Assimilation,Single-Level Diagnostics V5.12.4, Greenbelt, MD, USA, Goddard Earth Sciences Data and Information Services Center (GES DISC), https://doi.org/10.5067/VJAFPLI1CSIV, 2015.
Goddard Space Flight Center, Nasa: SBUV
data, available at: https://acd-ext.gsfc.nasa.gov/anonftp/toms/sbuv/AGGREGATED/sbuv_aggregated_toronto_065.txt, last access: 10 March 2021a.
Goddard Space Flight Center, Nasa: OMI data, available at: https://avdc.gsfc.nasa.gov/pub/data/satellite/Aura/OMI/V03/L2OVP/OMDOAO3/aura_omi_l2ovp_omdoao3_v03_toronto_065.txt, last access: 10 March 2021b.
Goddard Space Flight Center, Nasa: OMI data, available at: https://avdc.gsfc.nasa.gov/pub/data/satellite/Aura/OMI/V03/L2OVP/OMTO3/aura_omi_l2ovp_omto3_v8.5_toronto_065.txt, last access: 10 March 2021c.
Government of Canada: Total Ozone – hourly observations, Data set, https://doi.org/10.14287/10000003, 2021.
Gueymard, C. A.: The sun's total and spectral irradiance for solar energy applications and solar radiation models, Sol. Energy, 76, 423–453, https://doi.org/10.1016/j.solener.2003.08.039, 2004.
Herman, J., Cede, A., Spinei, E., Mount, G., Tzortziou, M. and Abuhassan, N.: NO2 column amounts from ground-based Pandora and MFDOAS spectrometers using the direct-sun DOAS technique: Intercomparisons and application to OMI validation, J. Geophys. Res., 114, D13307, https://doi.org/10.1029/2009JD011848, 2009.
Herman, J., Evans, R., Cede, A., Abuhassan, N., Petropavlovskikh, I., and McConville, G.: Comparison of ozone retrievals from the Pandora spectrometer system and Dobson spectrophotometer in Boulder, Colorado, Atmos. Meas. Tech., 8, 3407–3418, https://doi.org/10.5194/amt-8-3407-2015, 2015.
Jaross, G.: OMPS-NPP L2 NM Ozone (O3) Total Column swath orbital V2, Greenbelt, MD, USA, Goddard Earth Sciences Data and Information Services Center (GES DISC), https://doi.org/10.5067/0WF4HAAZ0VHK, 2017.
Karppinen, T., Redondas, A., García, R. D., Lakkala, K., McElroy, C. T., and Kyrö, E.: Compensating for the Effects of Stray Light in Single-Monochromator Brewer Spectrophotometer Ozone Retrieval, Atmos.-Ocean, 53, 66–73, https://doi.org/10.1080/07055900.2013.871499, 2015.
Kazadzis, S., Bais, A., Kouremeti, N., Gerasopoulos, E., Garane, K., Blumthaler, M., Schallhart, B., and Cede, A.: Direct spectral measurements with a Brewer spectroradiometer: absolute calibration and aerosol optical depth retrieval, Appl. Opt., 44, 1681–1690, https://doi.org/10.1364/AO.44.001681, 2005.
Kerr, J. B.: New methodology for deriving total ozone and other atmospheric variables from Brewer spectrophotometer direct sun spectra, J. Geophys. Res., 107, 4731, https://doi.org/10.1029/2001JD001227, 2002.
Kerr, J. B.: The Brewer Spectrophotometer, in UV Radiation in Global Climate Change: Measurements, Modeling and Effects on Ecosystems, edited by: Gao, W., Slusser, J. R., and Schmoldt, D. L., Springer, Berlin, Heidelberg, 160–191, 2010.
Kerr, J. B., McElroy, C. T., and Olafson, R. A.: Measurements of ozone with the Brewer ozone spectrophotometer, in: Proceedings of the Quadrennial Ozone Symposium, Boulder, USA, 4–9 August 1980, 74–79, 1981.
Kerr, J. B., Evans, W. F. J., and Asbridge, I. A.: Recalibration of Dobson Field Spectrophotometers with a Travelling Brewer Spectrophotometer Standard, in Atmospheric Ozone, edited by: Zerefos, C. S. and Ghazi, A., Springer, Netherlands, Dordrecht, 381–386, 1985.
Kerr, J. B., Asbridge, I. A., and Evans, W. F. J.: Intercomparison of total ozone measured by the Brewer and Dobson spectrophotometers at Toronto, J. Geophys. Res., 93, 11129–11140, https://doi.org/10.1029/JD093iD09p11129, 1988.
Kerr, J. B., McElroy, C. T., and Wardle, D. I.: The Brewer instrument calibration center 1984–1996, in: Proceedings of the Quadrennial Ozone Symposium, L'Aquila, Italy, 12–21 September 1996, pp. 915–918, 1998.
Kramarova, N. A., Nash, E. R., Newman, P. A., Bhartia, P. K., McPeters, R. D., Rault, D. F., Seftor, C. J., Xu, P. Q., and Labow, G. J.: Measuring the Antarctic ozone hole with the new Ozone Mapping and Profiler Suite (OMPS), Atmos. Chem. Phys., 14, 2353–2361, https://doi.org/10.5194/acp-14-2353-2014, 2014.
Kroon, M., Veefkind, J. P., Sneep, M., McPeters, R. D., Bhartia, P. K., and Levelt, P. F.: Comparing OMI-TOMS and OMI-DOAS total ozone column data, J. Geophys. Res., 113, D16S28, https://doi.org/10.1029/2007jd008798, 2008.
Kurucz, R. L.: New atlases for solar flux, irradiance, central intensity, and limb intensity, Memorie della Società Astronomica Italiana Supplement, 8, 189–191, 2005.
Kyrö, E.: Intercomparison of total ozone data from Nimbus 7 TOMS, the Brewer UV Spectrophotometer and SAOZ UV-Visible Spectrophotometer at High Latitudes Observatory, Sodankylä, Geophys. Res. Lett., 20, 571–574, https://doi.org/10.1029/93GL00806, 1993.
Labow, G. J., McPeters, R. D., Bhartia, P. K., and Kramarova, N.: A comparison of 40 years of SBUV measurements of column ozone with data from the Dobson/Brewer network, J. Geophys. Res., 118, 7370–7378,
https://doi.org/10.1002/jgrd.50503, 2013.
León-Luis, S. F., Redondas, A., Carreño, V., López-Solano, J., Berjón, A., Hernández-Cruz, B., and Santana-Díaz, D.: Internal consistency of the Regional Brewer Calibration Centre for Europe triad during the period 2005–2016, Atmos. Meas. Tech., 11, 4059–4072, https://doi.org/10.5194/amt-11-4059-2018, 2018.
Marenco, F., di Sarra, A., and Luisi, J. D.: Methodology for determining aerosol optical depth from brewer 300–320-nm ozone measurements, Appl. Opt., 41, 1805–1814, https://doi.org/10.1364/AO.41.001805, 2002.
McPeters, R. D., Bhartia, P. K., Krueger, A. J., Herman, J. R., Wellemeyer, C. G., Seftor, C. J., Jaross, G., Torres, O., Moy, L., Labow, G., Byerly, W., Taylor, S. L., Swissler, T., and Cebula, R. P.: Earth Probe Total Ozone Mapping Spectrometer (TOMS) Data Products User's Guide, available at: https://ozoneaq.gsfc.nasa.gov/media/docs/epusrguide.pdf (last access: 10 March 2021), 1998.
Netherlands Space Office: Total Ozone Column, available at: http://www.tropomi.eu/data-products/total-ozone-column (last
access: 10 March 2021), 2019.
Pandonia Global Network: Pandora 103 total column ozone data at Downsview, Toronto, Canada, available at: http://data.pandonia-global-network.org/Downsview/Pandora103s1/L2/Pandora103s1_Downsview_L2Tot_rout0p1-7.txt, last access: 10 March 2021.
Ramaswamy, V., Schwarzkopf, M. D., and Shine, K. P.: Radiative forcing of climate from halocarbon-induced global stratospheric ozone loss, Nature, 355, 810–812, 1992.
Redondas, A., Evans, R., Stuebi, R., Köhler, U., and Weber, M.: Evaluation of the use of five laboratory-determined ozone absorption cross sections in Brewer and Dobson retrieval algorithms, Atmos. Chem. Phys., 14, 1635–1648, https://doi.org/10.5194/acp-14-1635-2014, 2014.
Redondas, A., Carreño, V., León-Luis, S. F., Hernández-Cruz, B., López-Solano, J., Rodriguez-Franco, J. J., Vilaplana, J. M., Gröbner, J., Rimmer, J., Bais, A. F., Savastiouk, V., Moreta, J. R., Boulkelia, L., Jepsen, N., Wilson, K. M., Shirotov, V., and Karppinen, T.: EUBREWNET RBCC-E Huelva 2015 Ozone Brewer Intercomparison, Atmos. Chem. Phys., 18, 9441–9455, https://doi.org/10.5194/acp-18-9441-2018, 2018.
Rienecker, M. M., Suarez, M. J., Gelaro, R., Todling, R., Bacmeister, J., Liu, E., Bosilovich, M. G., Schubert, S. D., Takacs, L., and Kim, G.-K.: MERRA: NASA's modern-era retrospective analysis for research and applications, J. Climate, 24, 3624–3648, 2011.
Rimmer, J. S., Redondas, A., and Karppinen, T.: EuBrewNet – A European Brewer network (COST Action ES1207), an overview, Atmos. Chem. Phys., 18, 10347–10353, https://doi.org/10.5194/acp-18-10347-2018, 2018.
Savastiouk, V.: Improvements to the direct-sun ozone observations taken with the Brewer spectrophotometer, PhD Thesis, York University, Canada, 2006.
Serdyuchenko, A., Gorshelev, V., Weber, M., Chehade, W., and Burrows, J. P.: High spectral resolution ozone absorption cross-sections – Part 2: Temperature dependence, Atmos. Meas. Tech., 7, 625–636, https://doi.org/10.5194/amt-7-625-2014, 2014.
Siani, A. M., Frasca, F., Scarlatti, F., Religi, A., Diémoz, H., Casale, G. R., Pedone, M., and Savastiouk, V.: Examination on total ozone column retrievals by Brewer spectrophotometry using different processing software, Atmos. Meas. Tech., 11, 5105–5123, https://doi.org/10.5194/amt-11-5105-2018, 2018.
Solomon, S., Garcia, R. R., Rowland, F. S., and Wuebbles, D. J.: On the depletion of Antarctic ozone, Nature, 321, 755–758, https://doi.org/10.1038/321755a0, 1986.
Staehelin, J., Renaud, A., Bader, J., McPeters, R., Viatte, P., Hoegger, B., Bugnion, V., Giroud, M., and Schill, H.: Total ozone series at Arosa (Switzerland): Homogenization and data comparison, J. Geophys. Res., 103, 5827–5841, https://doi.org/10.1029/97JD02402, 1998.
Stolarski, R. S., Krueger, A. J., Schoeberl, M. R., McPeters, R. D., Newman, P. A., and Alpert, J. C.: Nimbus 7 satellite measurements of the springtime Antarctic ozone decrease, Nature, 322, 808–811, https://doi.org/10.1038/322808a0, 1986.
Stolarski, R. S., Bloomfield, P., McPeters, R. D., and Herman, J. R.: Total Ozone trends deduced from Nimbus 7 Toms data, Geophys. Res. Lett., 18, 1015–1018, https://doi.org/10.1029/91gl01302, 1991.
Stübi, R., Schill, H., Klausen, J., Vuilleumier, L., Gröbner, J., Egli, L., and Ruffieux, D.: On the compatibility of Brewer total column ozone measurements in two adjacent valleys (Arosa and Davos) in the Swiss Alps, Atmos. Meas. Tech., 10, 4479–4490, https://doi.org/10.5194/amt-10-4479-2017, 2017a.
Stübi, R., Schill, H., Klausen, J., Vuilleumier, L., and Ruffieux, D.: Reproducibility of total ozone column monitoring by the Arosa Brewer spectrophotometer triad, J. Geophys. Res., 122, 4735–4745,
https://doi.org/10.1002/2016JD025735, 2017b.
Thuillier, G., Floyd, L., Woods, T. N., Cebula, R., Hilsenrath, E., Hersé, M., and Labs, D.: Solar irradiance reference spectra for two solar active levels, Adv. Space Res., 34, 256–261,
https://doi.org/10.1016/j.asr.2002.12.004, 2004.
Tzortziou, M., Herman, J. R., Cede, A., and Abuhassan, N.: High precision, absolute total column ozone measurements from the Pandora spectrometer system: Comparisons with data from a Brewer double monochromator and Aura OMI, J. Geophys. Res., 117, D16303, https://doi.org/10.1029/2012JD017814, 2012.
Van Hoosier, M. E.: Solar ultraviolet spectral irradiance data with increased wavelength and irradiance accuracy, in: Proceedings of Ultraviolet Atmospheric and Space Remote Sensing: Methods and Instrumentation, International Society for Optics and Photonics, Denver, CO, United States, 4-9 August 1996, 57–64, 1996.
Vaziri Zanjani, Z., Moeini, O., McElroy, T., Barton, D., and Savastiouk, V.: A calibration procedure which accounts for non-linearity in single-monochromator Brewer ozone spectrophotometer measurements, Atmos. Meas. Tech., 12, 271–279, https://doi.org/10.5194/amt-12-271-2019, 2019.
Veefkind, J. P. , de Haan, J. F., Brinksma, E. J., Kroon, M., and Levelt, P. F.: Total ozone from the ozone monitoring instrument (OMI) using the DOAS technique, IEEE T. Geosci. Remote, 44, 1239–1244,
https://doi.org/10.1109/tgrs.2006.871204, 2006.
Verhoelst, T., Granville, J., Hendrick, F., Köhler, U., Lerot, C., Pommereau, J.-P., Redondas, A., Van Roozendael, M., and Lambert, J.-C.: Metrology of ground-based satellite validation: co-location mismatch and smoothing issues of total ozone comparisons, Atmos. Meas. Tech., 8, 5039–5062, https://doi.org/10.5194/amt-8-5039-2015, 2015.
Wardle, D. I., McElroy, C. T., Kerr, J. B., Wu, E., and Lamb, K.: Laboratory tests on the double Brewer spectrophotometer, in: Proceedings of the Quadrennial Ozone Symposium, L'Aquila, Italy, 12–21 September 1996, 997–1000, 1996.
Wargan, K., Labow, G., Frith, S., Pawson, S., Livesey, N., and Partyka, G.: Evaluation of the Ozone Fields in NASA's MERRA-2 Reanalysis, J. Climate, 30, 2961–2988, https://doi.org/10.1175/JCLI-D-16-0699.1, 2017.
WMO: World Meteorological Organization Global Atmosphere Watch – Global Atmosphere Watch Measurements Guide, WMO TD No. 1073, available at: https://library.wmo.int/doc_num.php?explnum_id=4632 (last
access: 24 November 2020), 2001.
WMO: Scientific assessment of ozone depletion: 2018, Global Ozone Research and Monitoring Project, World Meteorological Organization, Geneva, Switzerland, 2018.
Zerefos, C. S., Eleftheratos, K., Kapsomenakis, J., Solomos, S., Inness, A., Balis, D., Redondas, A., Eskes, H., Allaart, M., Amiridis, V., Dahlback, A., De Bock, V., Diémoz, H., Engelmann, R., Eriksen, P., Fioletov, V., Gröbner, J., Heikkilä, A., Petropavlovskikh, I., Jarosławski, J., Josefsson, W., Karppinen, T., Köhler, U., Meleti, C., Repapis, C., Rimmer, J., Savinykh, V., Shirotov, V., Siani, A. M., Smedley, A. R. D., Stanek, M., and Stübi, R.: Detecting volcanic sulfur dioxide plumes in the Northern Hemisphere using the Brewer spectrophotometers, other networks, and satellite observations, Atmos. Chem. Phys., 17, 551–574, https://doi.org/10.5194/acp-17-551-2017, 2017.
Zhao, X., Fioletov, V., Cede, A., Davies, J., and Strong, K.: Accuracy, precision, and temperature dependence of Pandora total ozone measurements estimated from a comparison with the Brewer triad in Toronto, Atmos. Meas. Tech., 9, 5747–5761, https://doi.org/10.5194/amt-9-5747-2016, 2016.
Zhao, X., Weaver, D., Bognar, K., Manney, G., Millán, L., Yang, X., Eloranta, E., Schneider, M., and Strong, K.: Cyclone-induced surface ozone and HDO depletion in the Arctic, Atmos. Chem. Phys., 17, 14955–14974, https://doi.org/10.5194/acp-17-14955-2017, 2017.
Zhao, X., Bognar, K., Fioletov, V., Pazmino, A., Goutail, F., Millán, L., Manney, G., Adams, C., and Strong, K.: Assessing the impact of clouds on ground-based UV–visible total column ozone measurements in the high Arctic, Atmos. Meas. Tech., 12, 2463–2483, https://doi.org/10.5194/amt-12-2463-2019, 2019.
Zoogman, P., Jacob, D. J., Chance, K., Liu, X., Lin, M., Fiore, A., and Travis, K.: Monitoring high-ozone events in the US Intermountain West using TEMPO geostationary satellite observations, Atmos. Chem. Phys., 14, 6261–6271, https://doi.org/10.5194/acp-14-6261-2014, 2014.
Short summary
The Brewer spectrophotometer is one of the main instruments for measurements of atmospheric total column ozone. The global Brewer network largely relies on the world reference instruments (the Brewer triad) operated by Environment and Climate Change Canada since the early 1980s. This study provides an updated assessment (1999–2019) of the reference instrument performance, in terms of random uncertainties and long-term stability.
The Brewer spectrophotometer is one of the main instruments for measurements of atmospheric...