Articles | Volume 15, issue 22
https://doi.org/10.5194/amt-15-6669-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/amt-15-6669-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
21 Nov 2022
Research article |
| 21 Nov 2022
| 21 Nov 2022
Long-term validation of MIPAS ESA operational products using MIPAS-B measurements
Karlsruhe Institute of Technology, Institute of Meteorology and
Climate Research, Karlsruhe, Germany
Michael Höpfner
Karlsruhe Institute of Technology, Institute of Meteorology and
Climate Research, Karlsruhe, Germany
Hermann Oelhaf
Karlsruhe Institute of Technology, Institute of Meteorology and
Climate Research, Karlsruhe, Germany
Felix Friedl-Vallon
Karlsruhe Institute of Technology, Institute of Meteorology and
Climate Research, Karlsruhe, Germany
Anne Kleinert
Karlsruhe Institute of Technology, Institute of Meteorology and
Climate Research, Karlsruhe, Germany
Guido Maucher
Karlsruhe Institute of Technology, Institute of Meteorology and
Climate Research, Karlsruhe, Germany
Miriam Sinnhuber
Karlsruhe Institute of Technology, Institute of Meteorology and
Climate Research, Karlsruhe, Germany
Janna Abalichin
Freie Universität Berlin, Institute of Meteorology, Berlin,
Germany
Angelika Dehn
European Space Agency (ESA-ESRIN), Frascati, Italy
Piera Raspollini
Istituto di Fisica Applicata “N. Carrara” (IFAC) del Consiglio
Nazionale delle Ricerche (CNR), Florence, Italy
Related authors
Laura N. Saunders, Kaley A. Walker, Gabriele P. Stiller, Piera Raspollini, Luis F. Millán, Marco Gai, Chris D. Boone, John Gille, Norbert Glatthor, Armin Kleinboehl, Anne Kleinert, Alyn Lambert, Donal Murtaugh, Patrick E. Sheese, Geoffrey C. Toon, and Gerald Wetzel
EGUsphere, https://doi.org/10.5194/egusphere-2026-4651, https://doi.org/10.5194/egusphere-2026-4651, 2026
This preprint is open for discussion and under review for Atmospheric Measurement Techniques (AMT).
Short summary
Short summary
We present a comprehensive evaluation of nitrous oxide (N2O) measurements taken during the 2002–2024 period from five limb-viewing satellite instruments: ACE-FTS, HIRDLS, MIPAS, Aura-MLS, and SMR. Coincident measurements are compared between satellite instruments and with independent reference data from balloon-borne instruments. We show that ACE-FTS, MIPAS, and SMR constitute an excellent 23-year record of N2O measurements that could be used to create an ESA-funded merged dataset in future.
Wolfgang Woiwode, Bärbel Vogel, Valentin Lauther, Jens-Uwe Grooß, Jeremy Harrison, Sören Johansson, Jörn Ungermann, Peter Braesicke, Markus Dick, Andreas Engel, Felix Friedl-Vallon, Norbert Glatthor, Thomas Gulde, Michael Höpfner, Markus Jesswein, Jan Kaumanns, Timo Keber, Anne Kleinert, Erik Kretschmer, Guido Maucher, Tom Neubert, Hans Nordmeyer, Christof Piesch, Felix Plöger, Peter Preusse, Markus Retzlaff, Sebastian Rhode, Heinz Rongen, Georg Schardt, Tanja Schuck, Björn-Martin Sinnhuber, Johannes Strobel, Franziska Trinkl, Ronja Van Luijt, Stefan Versick, C. Michael Volk, Gerald Wetzel, Peter Hoor, and Martin Riese
EGUsphere, https://doi.org/10.5194/egusphere-2026-3271, https://doi.org/10.5194/egusphere-2026-3271, 2026
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
Filaments of CH2Cl2-rich air are revealed by airborne infrared limb-imaging observations in late summer 2023 above the North Pacific, Canada and Alaska and traced back to the Asian Summer Monsoon region. Involving new spectroscopic data, high CH2Cl2 levels were retrieved in the troposphere and moderate enhancements also in air masses with characteristics of the lowermost stratosphere. Mesoscale filaments are shown to transport substantial amounts of CH2Cl2 across the North Pacific.
Gerald Wetzel, Anne Kleinert, Sören Johansson, Felix Friedl-Vallon, Michael Höpfner, Jörn Ungermann, Tom Neubert, Valéry Catoire, Cyril Crevoisier, Andreas Engel, Thomas Gulde, Patrick Jacquet, Oliver Kirner, Erik Kretschmer, Thomas Kulessa, Johannes C. Laube, Guido Maucher, Hans Nordmeyer, Christof Piesch, Peter Preusse, Markus Retzlaff, Georg Schardt, Johan Schillings, Herbert Schneider, Axel Schönfeld, Tanja Schuck, Wolfgang Woiwode, Martin Riese, and Peter Braesicke
Atmos. Meas. Tech., 18, 5873–5894, https://doi.org/10.5194/amt-18-5873-2025, https://doi.org/10.5194/amt-18-5873-2025, 2025
Short summary
Short summary
We present vertical trace gas profiles from the first balloon flight of the newly developed GLORIA-B limb-imaging Fourier-Transform spectrometer. Longer-lived gases are compared to external measurements to assess the quality of the GLORIA-B observations. Diurnal changes of photochemically active species are compared to model simulations. GLORIA-B demonstrates the capability of balloon-borne limb imaging to provide high-resolution vertical profiles of trace gases up to the middle stratosphere.
Florian Voet, Felix Ploeger, Johannes Laube, Peter Preusse, Paul Konopka, Jens-Uwe Grooß, Jörn Ungermann, Björn-Martin Sinnhuber, Michael Höpfner, Bernd Funke, Gerald Wetzel, Sören Johansson, Gabriele Stiller, Eric Ray, and Michaela I. Hegglin
Atmos. Chem. Phys., 25, 3541–3565, https://doi.org/10.5194/acp-25-3541-2025, https://doi.org/10.5194/acp-25-3541-2025, 2025
Short summary
Short summary
This study refines estimates of the stratospheric “age of air”, a measure of how long air circulates in the stratosphere. By analyzing correlations between trace gases measurable by satellites, the research introduces a method that reduces uncertainties and detects small-scale atmospheric features. This improved understanding of stratospheric circulation is crucial for better climate models and predictions, enhancing our ability to assess the impacts of climate change on the atmosphere.
Karolin Voss, Philip Holzbeck, Klaus Pfeilsticker, Ralph Kleinschek, Gerald Wetzel, Blanca Fuentes Andrade, Michael Höpfner, Jörn Ungermann, Björn-Martin Sinnhuber, and André Butz
Atmos. Meas. Tech., 17, 4507–4528, https://doi.org/10.5194/amt-17-4507-2024, https://doi.org/10.5194/amt-17-4507-2024, 2024
Short summary
Short summary
A novel balloon-borne instrument for direct sun and solar occultation measurements of several UV–Vis absorbing gases (e.g. O3, NO2, BrO, IO, and HONO) is described. Its major design features and performance during two stratospheric deployments are discussed. From the measured overhead BrO concentration and a suitable photochemical correction, total stratospheric bromine is inferred to (17.5 ± 2.2) ppt in air masses which entered the stratosphere around early 2017 ± 1 year.
Sören Johansson, Michael Höpfner, Felix Friedl-Vallon, Norbert Glatthor, Thomas Gulde, Vincent Huijnen, Anne Kleinert, Erik Kretschmer, Guido Maucher, Tom Neubert, Hans Nordmeyer, Christof Piesch, Peter Preusse, Martin Riese, Björn-Martin Sinnhuber, Jörn Ungermann, Gerald Wetzel, and Wolfgang Woiwode
Atmos. Chem. Phys., 24, 8125–8138, https://doi.org/10.5194/acp-24-8125-2024, https://doi.org/10.5194/acp-24-8125-2024, 2024
Short summary
Short summary
We present airborne infrared limb sounding GLORIA measurements of ammonia (NH3) in the upper troposphere of air masses within the Asian monsoon and of those connected with biomass burning. Comparing CAMS (Copernicus Atmosphere Monitoring Service) model data, we find that the model reproduces the measured enhanced NH3 within the Asian monsoon well but not that within biomass burning plumes, where no enhanced NH3 is measured in the upper troposphere but considerable amounts are simulated by CAMS.
Sören Johansson, Gerald Wetzel, Felix Friedl-Vallon, Norbert Glatthor, Michael Höpfner, Anne Kleinert, Tom Neubert, Björn-Martin Sinnhuber, and Jörn Ungermann
Atmos. Chem. Phys., 22, 3675–3691, https://doi.org/10.5194/acp-22-3675-2022, https://doi.org/10.5194/acp-22-3675-2022, 2022
Short summary
Short summary
We present GLORIA airborne cross sections of PAN, C2H6, HCOOH, CH3OH, and C2H4 in the South Atlantic UTLS in September/October 2019. Filamentary structures and a large plume were observed. Backward trajectories indicate that measured pollutants come from South America and central Africa. Comparisons to CAMS show structural agreement of the measured distributions. PAN absolute VMRs agree with the GLORIA measurements, C2H6 and HCOOH are simulated too low, and CH3OH and C2H4 are too high.
Paolo Pettinari, Flavio Barbara, Simone Ceccherini, Bianca Maria Dinelli, Marco Gai, Piera Raspollini, Luca Sgheri, Massimo Valeri, Gerald Wetzel, Nicola Zoppetti, and Marco Ridolfi
Atmos. Meas. Tech., 14, 7959–7974, https://doi.org/10.5194/amt-14-7959-2021, https://doi.org/10.5194/amt-14-7959-2021, 2021
Short summary
Short summary
Phosgene (COCl2) is a toxic gas whose presence is a consequence of human activity. Besides its direct injection in the troposphere, stratospheric COCl2 is produced from the decomposition of CCl4, an anthropogenic gas regulated by the Montreal Protocol. As a consequence, COCl2 negative trends characterize the lower and part of the middle stratosphere. However, we find positive trends in the upper troposphere, demonstrating the non-negligible role of other Cl-containing species not yet regulated.
Michael Höpfner, Oliver Kirner, Gerald Wetzel, Björn-Martin Sinnhuber, Florian Haenel, Sören Johansson, Johannes Orphal, Roland Ruhnke, Gabriele Stiller, and Thomas von Clarmann
Atmos. Chem. Phys., 21, 18433–18464, https://doi.org/10.5194/acp-21-18433-2021, https://doi.org/10.5194/acp-21-18433-2021, 2021
Short summary
Short summary
BrONO2 is an important reservoir gas for inorganic stratospheric bromine linked to the chemical cycles of stratospheric ozone depletion. Presently infrared limb sounding is the only way to measure BrONO2 in the atmosphere. We provide global distributions of BrONO2 derived from MIPAS observations 2002–2012. Comparisons with EMAC atmospheric modelling show an overall agreement and enable us to derive an independent estimate of stratospheric bromine of 21.2±1.4pptv based on the BrONO2 measurements.
Mona Kosary, Pasquale Sellitto, Michael Höpfner, Bernd Funke, Alex Hoffmann, Jörn Ungermann, Quentin Errera, Simone Tilmes, and Björn-Martin Sinnhuber
EGUsphere, https://doi.org/10.5194/egusphere-2026-4654, https://doi.org/10.5194/egusphere-2026-4654, 2026
This preprint is open for discussion and under review for Atmospheric Measurement Techniques (AMT).
Short summary
Short summary
We investigated whether future satellites could track changes in the ozone layer if reflective particles were deliberately added high in the atmosphere to cool the planet. Using climate model simulations, we created virtual satellite measurements and compared them with the original data. The method captured the key changes, especially stronger ozone loss and delayed recovery over Antarctica, while showing low artificial distortion. This suggests such satellites could provide important oversight.
Laura N. Saunders, Kaley A. Walker, Gabriele P. Stiller, Piera Raspollini, Luis F. Millán, Marco Gai, Chris D. Boone, John Gille, Norbert Glatthor, Armin Kleinboehl, Anne Kleinert, Alyn Lambert, Donal Murtaugh, Patrick E. Sheese, Geoffrey C. Toon, and Gerald Wetzel
EGUsphere, https://doi.org/10.5194/egusphere-2026-4651, https://doi.org/10.5194/egusphere-2026-4651, 2026
This preprint is open for discussion and under review for Atmospheric Measurement Techniques (AMT).
Short summary
Short summary
We present a comprehensive evaluation of nitrous oxide (N2O) measurements taken during the 2002–2024 period from five limb-viewing satellite instruments: ACE-FTS, HIRDLS, MIPAS, Aura-MLS, and SMR. Coincident measurements are compared between satellite instruments and with independent reference data from balloon-borne instruments. We show that ACE-FTS, MIPAS, and SMR constitute an excellent 23-year record of N2O measurements that could be used to create an ESA-funded merged dataset in future.
Wolfgang Woiwode, Bärbel Vogel, Valentin Lauther, Jens-Uwe Grooß, Jeremy Harrison, Sören Johansson, Jörn Ungermann, Peter Braesicke, Markus Dick, Andreas Engel, Felix Friedl-Vallon, Norbert Glatthor, Thomas Gulde, Michael Höpfner, Markus Jesswein, Jan Kaumanns, Timo Keber, Anne Kleinert, Erik Kretschmer, Guido Maucher, Tom Neubert, Hans Nordmeyer, Christof Piesch, Felix Plöger, Peter Preusse, Markus Retzlaff, Sebastian Rhode, Heinz Rongen, Georg Schardt, Tanja Schuck, Björn-Martin Sinnhuber, Johannes Strobel, Franziska Trinkl, Ronja Van Luijt, Stefan Versick, C. Michael Volk, Gerald Wetzel, Peter Hoor, and Martin Riese
EGUsphere, https://doi.org/10.5194/egusphere-2026-3271, https://doi.org/10.5194/egusphere-2026-3271, 2026
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
Filaments of CH2Cl2-rich air are revealed by airborne infrared limb-imaging observations in late summer 2023 above the North Pacific, Canada and Alaska and traced back to the Asian Summer Monsoon region. Involving new spectroscopic data, high CH2Cl2 levels were retrieved in the troposphere and moderate enhancements also in air masses with characteristics of the lowermost stratosphere. Mesoscale filaments are shown to transport substantial amounts of CH2Cl2 across the North Pacific.
Jianzhong Ma, Bin Chen, Qianshan He, Xiaolu Yan, Gaili Wang, Siyang Cheng, Benedikt Steil, Christoph Brühl, Holger Tost, Michael Höpfner, Andrea Pozzer, and Jos Lelieveld
Atmos. Chem. Phys., 26, 8125–8144, https://doi.org/10.5194/acp-26-8125-2026, https://doi.org/10.5194/acp-26-8125-2026, 2026
Short summary
Short summary
We use a global atmospheric chemistry and climate model to study the efficiency and effectiveness of the deep convective transport of CO, NH3 and SO2 from the planetary boundary layer into the Asian summer monsoon anticyclone. We find that in contrast to CO and NH3, the SO2 enhancements within the anticyclone are very weak. The wet scavenging over South Asia is more effective for SO2 than NH3 at reducing their amounts reaching the Tibetan Plateau and the Asian summer monsoon anticyclone.
Pasquale Sellitto, Maxim Eremenko, Paola Formenti, Perla Alalam, Michael Höpfner, and Claudia Di Biagio
Atmos. Meas. Tech., 19, 2751–2762, https://doi.org/10.5194/amt-19-2751-2026, https://doi.org/10.5194/amt-19-2751-2026, 2026
Short summary
Short summary
The Far-infrared Outgoing Radiation Understanding and Monitoring (FORUM) mission will bring the first satellite instrument capable of observing the Earth's far infrared (FIR) spectra with a high spectral resolution. FORUM will crucially contribute to water vapour, clouds and surface observations. We found that FORUM will provide also a significant sensitivity to dust aerosol, especially in cases of large burdens of mid-to-long-range transported plumes of dust in the free and upper troposphere.
Pasquale Sellitto, Mona Kosary, Michael Höpfner, Bernd Funke, Alex Hoffmann, Jörn Ungermann, Quentin Errera, Simone Tilmes, and Björn-Martin Sinnhuber
EGUsphere, https://doi.org/10.5194/egusphere-2026-919, https://doi.org/10.5194/egusphere-2026-919, 2026
Short summary
Short summary
To counterbalance human-caused global warming, highly controversial geoengineering techniques, based on stratospheric aerosol injection (SAI), have been proposed as a complement to climate change mitigation. Unilateral or illegal SAI deployments or tests are a risk. We show that existing satellite instruments do not have the capability to detect possible illegal SAI experiments and we propose a future satellite technique, infrared limb emission sounding, that can provide this missing capability.
Quentin Errera, Marc Op de beeck, Stefan Bender, Johannes Flemming, Bernd Funke, Alex Hoffmann, Michael Höpfner, Nathaniel Livesey, Gabriele Poli, Didier Pieroux, Piera Raspollini, and Björn-Martin Sinnhuber
Atmos. Meas. Tech., 19, 2601–2620, https://doi.org/10.5194/amt-19-2601-2026, https://doi.org/10.5194/amt-19-2601-2026, 2026
Short summary
Short summary
The Changing Atmosphere Infra-Red Tomography Explorer (CAIRT) is a satellite mission concept developed to observe, among other, the gradient of ozone and water vapour in the upper troposphere and lower stratosphere where these species have their largest radiative impact. By simulating CAIRT observations and measuring their constrain on an atmospheric model using data assimilation, this study shows that CAIRT specifications are adequate to fulfil this objective.
Tobias Spiegl, Ulrike Langematz, Wenjuan Huo, Jürgen Kröger, Thomas Reddmann, Franziska Kappenberger, Sebastian Wahl, Maryam Ramezani Ziarani, Holger Pohlmann, and Miriam Sinnhuber
EGUsphere, https://doi.org/10.5194/egusphere-2026-126, https://doi.org/10.5194/egusphere-2026-126, 2026
Short summary
Short summary
The SOLCHECK project studied how fluctuations in the Sun’s energy output affect weather and climate. Strong solar storms deplete ozone and raise ultraviolet irradiance, the impact of the 11-year solar cycle depends on stratospheric dynamics, and long-term Grand Solar Minima leave fingerprints in past and future climate states. The large model ensemble explored in SOLCHECK helped to separate the various solar effects from human-driven change and improved our understanding of climate feedbacks.
Gholam Ali Hoshyaripour, Andreas Baer, Sascha Bierbauer, Julia Bruckert, Dominik Brunner, Jochen Förstner, Arash Hamzehloo, Valentin Hanft, Corina Keller, Martina Klose, Pankaj Kumar, Patrick Ludwig, Enrico Metzner, Lisa Muth, Andreas Pauling, Nikolas Porz, Maryam Ramezani Ziarani, Thomas Reddmann, Luca Reißig, Roland Ruhnke, Khompat Satitkovitchai, Axel Seifert, Miriam Sinnhuber, Michael Steiner, Stefan Versick, Heike Vogel, Michael Weimer, Sven Werchner, and Corinna Hoose
Geosci. Model Dev., 19, 1645–1681, https://doi.org/10.5194/gmd-19-1645-2026, https://doi.org/10.5194/gmd-19-1645-2026, 2026
Short summary
Short summary
This paper presents recent advances in ICON-ART, a modeling system that simulates atmospheric composition – such as gases and particles – and their interactions with weather and climate. By integrating updated chemistry, emissions, and aerosol processes, ICON-ART enables detailed, scale-spanning simulations. It supports both scientific research and operational forecasts, contributing to improved air quality, weather and climate predictions.
Liliana Guidetti, Erika Brattich, Simone Ceccherini, Michaela I. Hegglin, Piera Raspollini, Cecilia Tirelli, Nicola Zoppetti, and Ugo Cortesi
Atmos. Meas. Tech., 19, 167–184, https://doi.org/10.5194/amt-19-167-2026, https://doi.org/10.5194/amt-19-167-2026, 2026
Short summary
Short summary
The Complete Data Fusion algorithm is applied to observations from the Michelson Interferometer for Passive Atmospheric Sounding and the Infrared Atmospheric Sounding Interferometer to generate and validate a new ozone dataset against ozone soundings across multiple latitudes. The fusion propagates stratospheric limb information into the troposphere. The dataset shows increased information content and lower uncertainty, improving the study of stratosphere–troposphere ozone intrusions.
Miriam Sinnhuber, Christina Arras, Stefan Bender, Bernd Funke, Hanli Liu, Daniel R. Marsh, Thomas Reddmann, Eugene Rozanov, Timofei Sukhodolov, Monika E. Szelag, and Jan Maik Wissing
Atmos. Chem. Phys., 25, 14719–14734, https://doi.org/10.5194/acp-25-14719-2025, https://doi.org/10.5194/acp-25-14719-2025, 2025
Short summary
Short summary
Nitric oxide in the upper atmosphere varies with solar activity. Observations show that this starts a chain of processes affecting the ozone layer and climate system. This is often underestimated in models. We compare five models which show large differences in simulated NO. Analysis of these discrepancies identify two processes which interact with each other: the balance between atomic and molecular oxygen in the thermosphere, and a poleward - downward transport in the winter thermosphere.
Gerald Wetzel, Anne Kleinert, Sören Johansson, Felix Friedl-Vallon, Michael Höpfner, Jörn Ungermann, Tom Neubert, Valéry Catoire, Cyril Crevoisier, Andreas Engel, Thomas Gulde, Patrick Jacquet, Oliver Kirner, Erik Kretschmer, Thomas Kulessa, Johannes C. Laube, Guido Maucher, Hans Nordmeyer, Christof Piesch, Peter Preusse, Markus Retzlaff, Georg Schardt, Johan Schillings, Herbert Schneider, Axel Schönfeld, Tanja Schuck, Wolfgang Woiwode, Martin Riese, and Peter Braesicke
Atmos. Meas. Tech., 18, 5873–5894, https://doi.org/10.5194/amt-18-5873-2025, https://doi.org/10.5194/amt-18-5873-2025, 2025
Short summary
Short summary
We present vertical trace gas profiles from the first balloon flight of the newly developed GLORIA-B limb-imaging Fourier-Transform spectrometer. Longer-lived gases are compared to external measurements to assess the quality of the GLORIA-B observations. Diurnal changes of photochemically active species are compared to model simulations. GLORIA-B demonstrates the capability of balloon-borne limb imaging to provide high-resolution vertical profiles of trace gases up to the middle stratosphere.
Maryam Ramezani Ziarani, Miriam Sinnhuber, Thomas Reddmann, Bernd Funke, Stefan Bender, and Michael Prather
Geosci. Model Dev., 18, 7891–7905, https://doi.org/10.5194/gmd-18-7891-2025, https://doi.org/10.5194/gmd-18-7891-2025, 2025
Short summary
Short summary
Our study aims to present a new method for incorporating top-down solar forcing into stratospheric ozone relying on linearized ozone scheme. The addition of geomagnetic forcing led to significant ozone losses in the polar upper stratosphere of both hemispheres due to the catalytic cycles involving NOy. In addition to the particle precipitation effect, accounting for solar UV variability in the ICON-ART model leads to the changes in ozone in the tropical stratosphere.
Cecilia Tirelli, Simone Ceccherini, Samuele Del Bianco, Bernd Funke, Michael Höpfner, Ugo Cortesi, and Piera Raspollini
Atmos. Meas. Tech., 18, 5619–5636, https://doi.org/10.5194/amt-18-5619-2025, https://doi.org/10.5194/amt-18-5619-2025, 2025
Short summary
Short summary
The Complete Data Fusion is an a posteriori method used to combine remote sensing products from independent observations of the same or proximate air masses. In this study, we extend the algorithm’s applicability to two-dimensional products, testing it with simulated ozone datasets from nadir and limb measurements. Our results show that the exploitation of the tomographic capabilities of future atmospheric sensors maximizes the information extracted from complementary datasets.
Matthias Kohl, Christoph Brühl, Jennifer Schallock, Holger Tost, Patrick Jöckel, Adrian Jost, Steffen Beirle, Michael Höpfner, and Andrea Pozzer
Geosci. Model Dev., 18, 3985–4007, https://doi.org/10.5194/gmd-18-3985-2025, https://doi.org/10.5194/gmd-18-3985-2025, 2025
Short summary
Short summary
SO2 from explosive volcanic eruptions reaching the stratosphere can oxidize and form sulfur aerosols, potentially persisting for several years. We developed a new submodel, Explosive Volcanic ERuptions (EVER), that seamlessly includes stratospheric volcanic SO2 emissions in global numerical simulations based on a novel standard historical model setup, successfully evaluated with satellite observations. Sensitivity studies on the Nabro eruption in 2011 evaluate different emission methods.
Florian Voet, Felix Ploeger, Johannes Laube, Peter Preusse, Paul Konopka, Jens-Uwe Grooß, Jörn Ungermann, Björn-Martin Sinnhuber, Michael Höpfner, Bernd Funke, Gerald Wetzel, Sören Johansson, Gabriele Stiller, Eric Ray, and Michaela I. Hegglin
Atmos. Chem. Phys., 25, 3541–3565, https://doi.org/10.5194/acp-25-3541-2025, https://doi.org/10.5194/acp-25-3541-2025, 2025
Short summary
Short summary
This study refines estimates of the stratospheric “age of air”, a measure of how long air circulates in the stratosphere. By analyzing correlations between trace gases measurable by satellites, the research introduces a method that reduces uncertainties and detects small-scale atmospheric features. This improved understanding of stratospheric circulation is crucial for better climate models and predictions, enhancing our ability to assess the impacts of climate change on the atmosphere.
Frank Hase, Paolo Castracane, Angelika Dehn, Omaira Elena García, David W. T. Griffith, Lukas Heizmann, Nicholas B. Jones, Tomi Karppinen, Rigel Kivi, Martine de Mazière, Justus Notholt, and Mahesh Kumar Sha
Atmos. Meas. Tech., 18, 1257–1267, https://doi.org/10.5194/amt-18-1257-2025, https://doi.org/10.5194/amt-18-1257-2025, 2025
Short summary
Short summary
The primary measurement result delivered by a Fourier transform spectrometer is an interferogram, and the spectrum required for further analysis needs to be calculated from the interferogram by Fourier analysis. The paper deals with technical aspects of this process and shows how the reconstruction of the spectrum can be optimized.
Karolin Voss, Philip Holzbeck, Klaus Pfeilsticker, Ralph Kleinschek, Gerald Wetzel, Blanca Fuentes Andrade, Michael Höpfner, Jörn Ungermann, Björn-Martin Sinnhuber, and André Butz
Atmos. Meas. Tech., 17, 4507–4528, https://doi.org/10.5194/amt-17-4507-2024, https://doi.org/10.5194/amt-17-4507-2024, 2024
Short summary
Short summary
A novel balloon-borne instrument for direct sun and solar occultation measurements of several UV–Vis absorbing gases (e.g. O3, NO2, BrO, IO, and HONO) is described. Its major design features and performance during two stratospheric deployments are discussed. From the measured overhead BrO concentration and a suitable photochemical correction, total stratospheric bromine is inferred to (17.5 ± 2.2) ppt in air masses which entered the stratosphere around early 2017 ± 1 year.
Sören Johansson, Michael Höpfner, Felix Friedl-Vallon, Norbert Glatthor, Thomas Gulde, Vincent Huijnen, Anne Kleinert, Erik Kretschmer, Guido Maucher, Tom Neubert, Hans Nordmeyer, Christof Piesch, Peter Preusse, Martin Riese, Björn-Martin Sinnhuber, Jörn Ungermann, Gerald Wetzel, and Wolfgang Woiwode
Atmos. Chem. Phys., 24, 8125–8138, https://doi.org/10.5194/acp-24-8125-2024, https://doi.org/10.5194/acp-24-8125-2024, 2024
Short summary
Short summary
We present airborne infrared limb sounding GLORIA measurements of ammonia (NH3) in the upper troposphere of air masses within the Asian monsoon and of those connected with biomass burning. Comparing CAMS (Copernicus Atmosphere Monitoring Service) model data, we find that the model reproduces the measured enhanced NH3 within the Asian monsoon well but not that within biomass burning plumes, where no enhanced NH3 is measured in the upper troposphere but considerable amounts are simulated by CAMS.
Arno Keppens, Serena Di Pede, Daan Hubert, Jean-Christopher Lambert, Pepijn Veefkind, Maarten Sneep, Johan De Haan, Mark ter Linden, Thierry Leblanc, Steven Compernolle, Tijl Verhoelst, José Granville, Oindrila Nath, Ann Mari Fjæraa, Ian Boyd, Sander Niemeijer, Roeland Van Malderen, Herman G. J. Smit, Valentin Duflot, Sophie Godin-Beekmann, Bryan J. Johnson, Wolfgang Steinbrecht, David W. Tarasick, Debra E. Kollonige, Ryan M. Stauffer, Anne M. Thompson, Angelika Dehn, and Claus Zehner
Atmos. Meas. Tech., 17, 3969–3993, https://doi.org/10.5194/amt-17-3969-2024, https://doi.org/10.5194/amt-17-3969-2024, 2024
Short summary
Short summary
The Sentinel-5P satellite operated by the European Space Agency has carried the TROPOspheric Monitoring Instrument (TROPOMI) around the Earth since October 2017. This mission also produces atmospheric ozone profile data which are described in detail for May 2018 to April 2023. Independent validation using ground-based reference measurements demonstrates that the operational ozone profile product mostly fully and at least partially complies with all mission requirements.
Benedikt Herkommer, Carlos Alberti, Paolo Castracane, Jia Chen, Angelika Dehn, Florian Dietrich, Nicholas M. Deutscher, Matthias Max Frey, Jochen Groß, Lawson Gillespie, Frank Hase, Isamu Morino, Nasrin Mostafavi Pak, Brittany Walker, and Debra Wunch
Atmos. Meas. Tech., 17, 3467–3494, https://doi.org/10.5194/amt-17-3467-2024, https://doi.org/10.5194/amt-17-3467-2024, 2024
Short summary
Short summary
The Total Carbon Column Observing Network is a network of ground-based Fourier transform infrared (FTIR) spectrometers used mainly for satellite validation. To ensure the highest-quality validation data, the network needs to be highly consistent. This is a major challenge, which so far is solved by site comparisons with airborne in situ measurements. In this work, we describe the use of a portable FTIR spectrometer as a travel standard for evaluating the consistency of TCCON sites.
Karen De Los Ríos, Paulina Ordoñez, Gabriele P. Stiller, Piera Raspollini, Marco Gai, Kaley A. Walker, Cristina Peña-Ortiz, and Luis Acosta
Atmos. Meas. Tech., 17, 3401–3418, https://doi.org/10.5194/amt-17-3401-2024, https://doi.org/10.5194/amt-17-3401-2024, 2024
Short summary
Short summary
This study examines newer versions of H2O and HDO retrievals from Envisat/MIPAS and SCISAT/ACE-FTS. Results reveal a better agreement in stratospheric H2O profiles than in HDO profiles. The H2O tape recorder signal is consistent across databases, but δD tape recorder composites show differences that impact the interpretation of water vapour transport. These findings enhance the need for intercomparisons to refine our insights.
Christina V. Brodowsky, Timofei Sukhodolov, Gabriel Chiodo, Valentina Aquila, Slimane Bekki, Sandip S. Dhomse, Michael Höpfner, Anton Laakso, Graham W. Mann, Ulrike Niemeier, Giovanni Pitari, Ilaria Quaglia, Eugene Rozanov, Anja Schmidt, Takashi Sekiya, Simone Tilmes, Claudia Timmreck, Sandro Vattioni, Daniele Visioni, Pengfei Yu, Yunqian Zhu, and Thomas Peter
Atmos. Chem. Phys., 24, 5513–5548, https://doi.org/10.5194/acp-24-5513-2024, https://doi.org/10.5194/acp-24-5513-2024, 2024
Short summary
Short summary
The aerosol layer is an essential part of the climate system. We characterize the sulfur budget in a volcanically quiescent (background) setting, with a special focus on the sulfate aerosol layer using, for the first time, a multi-model approach. The aim is to identify weak points in the representation of the atmospheric sulfur budget in an intercomparison of nine state-of-the-art coupled global circulation models.
Norbert Glatthor, Thomas von Clarmann, Bernd Funke, Maya García-Comas, Udo Grabowski, Michael Höpfner, Sylvia Kellmann, Michael Kiefer, Alexandra Laeng, Andrea Linden, Manuel López-Puertas, and Gabriele P. Stiller
Atmos. Meas. Tech., 17, 2849–2871, https://doi.org/10.5194/amt-17-2849-2024, https://doi.org/10.5194/amt-17-2849-2024, 2024
Short summary
Short summary
We present global atmospheric methane (CH4) and nitrous oxide (N2O) distributions retrieved from measurements of the MIPAS instrument on board the Environmental Satellite (Envisat) during 2002 to 2012. Monitoring of these gases is of scientific interest because both of them are strong greenhouse gases. We analyze the latest, improved version of calibrated MIPAS measurements. Further, we apply a new retrieval scheme leading to an improved CH4 and N2O data product .
Bernd Funke, Thierry Dudok de Wit, Ilaria Ermolli, Margit Haberreiter, Doug Kinnison, Daniel Marsh, Hilde Nesse, Annika Seppälä, Miriam Sinnhuber, and Ilya Usoskin
Geosci. Model Dev., 17, 1217–1227, https://doi.org/10.5194/gmd-17-1217-2024, https://doi.org/10.5194/gmd-17-1217-2024, 2024
Short summary
Short summary
We outline a road map for the preparation of a solar forcing dataset for the upcoming Phase 7 of the Coupled Model Intercomparison Project (CMIP7), considering the latest scientific advances made in the reconstruction of solar forcing and in the understanding of climate response while also addressing the issues that were raised during CMIP6.
Monali Borthakur, Miriam Sinnhuber, Alexandra Laeng, Thomas Reddmann, Peter Braesicke, Gabriele Stiller, Thomas von Clarmann, Bernd Funke, Ilya Usoskin, Jan Maik Wissing, and Olesya Yakovchuk
Atmos. Chem. Phys., 23, 12985–13013, https://doi.org/10.5194/acp-23-12985-2023, https://doi.org/10.5194/acp-23-12985-2023, 2023
Short summary
Short summary
Reduced ozone levels resulting from ozone depletion mean more exposure to UV radiation, which has various effects on human health. We analysed solar events to see what influence it has on the chemistry of Earth's atmosphere and how this atmospheric chemistry change can affect the ozone. To do this, we used an atmospheric model considering only chemistry and compared it with satellite data. The focus was mainly on the contribution of chlorine, and we found about 10 %–20 % ozone loss due to that.
Michael Kiefer, Dale F. Hurst, Gabriele P. Stiller, Stefan Lossow, Holger Vömel, John Anderson, Faiza Azam, Jean-Loup Bertaux, Laurent Blanot, Klaus Bramstedt, John P. Burrows, Robert Damadeo, Bianca Maria Dinelli, Patrick Eriksson, Maya García-Comas, John C. Gille, Mark Hervig, Yasuko Kasai, Farahnaz Khosrawi, Donal Murtagh, Gerald E. Nedoluha, Stefan Noël, Piera Raspollini, William G. Read, Karen H. Rosenlof, Alexei Rozanov, Christopher E. Sioris, Takafumi Sugita, Thomas von Clarmann, Kaley A. Walker, and Katja Weigel
Atmos. Meas. Tech., 16, 4589–4642, https://doi.org/10.5194/amt-16-4589-2023, https://doi.org/10.5194/amt-16-4589-2023, 2023
Short summary
Short summary
We quantify biases and drifts (and their uncertainties) between the stratospheric water vapor measurement records of 15 satellite-based instruments (SATs, with 31 different retrievals) and balloon-borne frost point hygrometers (FPs) launched at 27 globally distributed stations. These comparisons of measurements during the period 2000–2016 are made using robust, consistent statistical methods. With some exceptions, the biases and drifts determined for most SAT–FP pairs are < 10 % and < 1 % yr−1.
Thomas Reddmann, Miriam Sinnhuber, Jan Maik Wissing, Olesya Yakovchuk, and Ilya Usoskin
Atmos. Chem. Phys., 23, 6989–7000, https://doi.org/10.5194/acp-23-6989-2023, https://doi.org/10.5194/acp-23-6989-2023, 2023
Short summary
Short summary
Recent analyses of isotopic records of ice cores and sediments have shown that very strong explosions may occur on the Sun, perhaps about one such explosion every 1000 years. Such explosions pose a real threat to humankind. It is therefore of great interest to study the impact of such explosions on Earth. We analyzed how the explosions would affect the chemistry of the middle atmosphere and show that the related ozone loss is not dramatic and that the atmosphere will recover within 1 year.
Michael Kiefer, Thomas von Clarmann, Bernd Funke, Maya García-Comas, Norbert Glatthor, Udo Grabowski, Michael Höpfner, Sylvia Kellmann, Alexandra Laeng, Andrea Linden, Manuel López-Puertas, and Gabriele P. Stiller
Atmos. Meas. Tech., 16, 1443–1460, https://doi.org/10.5194/amt-16-1443-2023, https://doi.org/10.5194/amt-16-1443-2023, 2023
Short summary
Short summary
A new ozone data set, derived from radiation measurements of the space-borne instrument MIPAS, is presented. It consists of more than 2 million single ozone profiles from 2002–2012, covering virtually all latitudes and altitudes between 5 and 70 km. Progress in data calibration and processing methods allowed for significant improvement of the data quality, compared to previous data versions. Hence, the data set will help to better understand e.g. the time evolution of ozone in the stratosphere.
Stefano Della Fera, Federico Fabiano, Piera Raspollini, Marco Ridolfi, Ugo Cortesi, Flavio Barbara, and Jost von Hardenberg
Geosci. Model Dev., 16, 1379–1394, https://doi.org/10.5194/gmd-16-1379-2023, https://doi.org/10.5194/gmd-16-1379-2023, 2023
Short summary
Short summary
The long-term comparison between observed and simulated outgoing longwave radiances represents a strict test to evaluate climate model performance. In this work, 9 years of synthetic spectrally resolved radiances, simulated online on the basis of the atmospheric fields predicted by the EC-Earth global climate model (v3.3.3) in clear-sky conditions, are compared to IASI spectral radiance climatology in order to detect model biases in temperature and humidity at different atmospheric levels.
Jennifer Schallock, Christoph Brühl, Christine Bingen, Michael Höpfner, Landon Rieger, and Jos Lelieveld
Atmos. Chem. Phys., 23, 1169–1207, https://doi.org/10.5194/acp-23-1169-2023, https://doi.org/10.5194/acp-23-1169-2023, 2023
Short summary
Short summary
We characterized the influence of volcanic aerosols for the period 1990–2019 and established a volcanic SO2 emission inventory that includes more than 500 eruptions. From limb-based satellite observations of SO2 and extinction, we derive 3D plumes of SO2 perturbations and injected mass by a novel method. We calculate instantaneous radiative forcing with a comprehensive chemisty climate model. Our results show that smaller eruptions can also contribute to the stratospheric aerosol forcing.
Thomas von Clarmann, Norbert Glatthor, Udo Grabowski, Bernd Funke, Michael Kiefer, Anne Kleinert, Gabriele P. Stiller, Andrea Linden, and Sylvia Kellmann
Atmos. Meas. Tech., 15, 6991–7018, https://doi.org/10.5194/amt-15-6991-2022, https://doi.org/10.5194/amt-15-6991-2022, 2022
Short summary
Short summary
Errors of profiles of temperature and mixing ratios retrieved from spectra recorded with the Michelson Interferometer for Passive Atmospheric Sounding are estimated. All known and quantified sources of uncertainty are considered. Some ongoing uncertaities contribute to both the random and to the systematic errors. In some cases, one source of uncertainty propagates onto the error budget via multiple pathways. Problems arise when the correlations of errors to be propagated are unknown.
William G. Read, Gabriele Stiller, Stefan Lossow, Michael Kiefer, Farahnaz Khosrawi, Dale Hurst, Holger Vömel, Karen Rosenlof, Bianca M. Dinelli, Piera Raspollini, Gerald E. Nedoluha, John C. Gille, Yasuko Kasai, Patrick Eriksson, Christopher E. Sioris, Kaley A. Walker, Katja Weigel, John P. Burrows, and Alexei Rozanov
Atmos. Meas. Tech., 15, 3377–3400, https://doi.org/10.5194/amt-15-3377-2022, https://doi.org/10.5194/amt-15-3377-2022, 2022
Short summary
Short summary
This paper attempts to provide an assessment of the accuracy of 21 satellite-based instruments that remotely measure atmospheric humidity in the upper troposphere of the Earth's atmosphere. The instruments made their measurements from 1984 to the present time; however, most of these instruments began operations after 2000, and only a few are still operational. The objective of this study is to quantify the accuracy of each satellite humidity data set.
Irina Mironova, Miriam Sinnhuber, Galina Bazilevskaya, Mark Clilverd, Bernd Funke, Vladimir Makhmutov, Eugene Rozanov, Michelle L. Santee, Timofei Sukhodolov, and Thomas Ulich
Atmos. Chem. Phys., 22, 6703–6716, https://doi.org/10.5194/acp-22-6703-2022, https://doi.org/10.5194/acp-22-6703-2022, 2022
Short summary
Short summary
From balloon measurements, we detected unprecedented, extremely powerful, electron precipitation over the middle latitudes. The robustness of this event is confirmed by satellite observations of electron fluxes and chemical composition, as well as by ground-based observations of the radio signal propagation. The applied chemistry–climate model shows the almost complete destruction of ozone in the mesosphere over the region where high-energy electrons were observed.
Jörn Ungermann, Anne Kleinert, Guido Maucher, Irene Bartolomé, Felix Friedl-Vallon, Sören Johansson, Lukas Krasauskas, and Tom Neubert
Atmos. Meas. Tech., 15, 2503–2530, https://doi.org/10.5194/amt-15-2503-2022, https://doi.org/10.5194/amt-15-2503-2022, 2022
Short summary
Short summary
GLORIA is a 2-D infrared imaging spectrometer operated on two high-flying research aircraft. This paper details our instrument calibration and characterization efforts, which in particular leverage in-flight data almost exclusively and often exploit the novel 2-D nature of the measurements. We show that the instrument surpasses the original instrument specifications and conclude by analyzing how the derived errors affect temperature and ozone retrievals, two of our main derived quantities.
Carlos Alberti, Frank Hase, Matthias Frey, Darko Dubravica, Thomas Blumenstock, Angelika Dehn, Paolo Castracane, Gregor Surawicz, Roland Harig, Bianca C. Baier, Caroline Bès, Jianrong Bi, Hartmut Boesch, André Butz, Zhaonan Cai, Jia Chen, Sean M. Crowell, Nicholas M. Deutscher, Dragos Ene, Jonathan E. Franklin, Omaira García, David Griffith, Bruno Grouiez, Michel Grutter, Abdelhamid Hamdouni, Sander Houweling, Neil Humpage, Nicole Jacobs, Sujong Jeong, Lilian Joly, Nicholas B. Jones, Denis Jouglet, Rigel Kivi, Ralph Kleinschek, Morgan Lopez, Diogo J. Medeiros, Isamu Morino, Nasrin Mostafavipak, Astrid Müller, Hirofumi Ohyama, Paul I. Palmer, Mahesh Pathakoti, David F. Pollard, Uwe Raffalski, Michel Ramonet, Robbie Ramsay, Mahesh Kumar Sha, Kei Shiomi, William Simpson, Wolfgang Stremme, Youwen Sun, Hiroshi Tanimoto, Yao Té, Gizaw Mengistu Tsidu, Voltaire A. Velazco, Felix Vogel, Masataka Watanabe, Chong Wei, Debra Wunch, Marcia Yamasoe, Lu Zhang, and Johannes Orphal
Atmos. Meas. Tech., 15, 2433–2463, https://doi.org/10.5194/amt-15-2433-2022, https://doi.org/10.5194/amt-15-2433-2022, 2022
Short summary
Short summary
Space-borne greenhouse gas missions require ground-based validation networks capable of providing fiducial reference measurements. Here, considerable refinements of the calibration procedures for the COllaborative Carbon Column Observing Network (COCCON) are presented. Laboratory and solar side-by-side procedures for the characterization of the spectrometers have been refined and extended. Revised calibration factors for XCO2, XCO and XCH4 are provided, incorporating 47 new spectrometers.
Piera Raspollini, Enrico Arnone, Flavio Barbara, Massimo Bianchini, Bruno Carli, Simone Ceccherini, Martyn P. Chipperfield, Angelika Dehn, Stefano Della Fera, Bianca Maria Dinelli, Anu Dudhia, Jean-Marie Flaud, Marco Gai, Michael Kiefer, Manuel López-Puertas, David P. Moore, Alessandro Piro, John J. Remedios, Marco Ridolfi, Harjinder Sembhi, Luca Sgheri, and Nicola Zoppetti
Atmos. Meas. Tech., 15, 1871–1901, https://doi.org/10.5194/amt-15-1871-2022, https://doi.org/10.5194/amt-15-1871-2022, 2022
Short summary
Short summary
The MIPAS instrument onboard the ENVISAT satellite provided 10 years of measurements of the atmospheric emission al limb that allow for the retrieval of latitude- and altitude-resolved atmospheric composition. We describe the improvements implemented in the retrieval algorithm used for the full mission reanalysis, which allows for the generation of the global distributions of 21 atmospheric constituents plus temperature with increased accuracy with respect to previously generated data.
Maya Ben-Yami, Hilke Oetjen, Helen Brindley, William Cossich, Dulce Lajas, Tiziano Maestri, Davide Magurno, Piera Raspollini, Luca Sgheri, and Laura Warwick
Atmos. Meas. Tech., 15, 1755–1777, https://doi.org/10.5194/amt-15-1755-2022, https://doi.org/10.5194/amt-15-1755-2022, 2022
Short summary
Short summary
Spectral emissivity is a key property of the Earth's surface. Few measurements exist in the far-infrared, despite recent work showing that its contribution is important for accurate modelling of global climate. In preparation for ESA’s EE9 FORUM mission (launch in 2026), this study takes the first steps towards the development of an operational emissivity retrieval for FORUM by investigating the sensitivity of the emissivity product to different physical and operational parameters.
Sören Johansson, Gerald Wetzel, Felix Friedl-Vallon, Norbert Glatthor, Michael Höpfner, Anne Kleinert, Tom Neubert, Björn-Martin Sinnhuber, and Jörn Ungermann
Atmos. Chem. Phys., 22, 3675–3691, https://doi.org/10.5194/acp-22-3675-2022, https://doi.org/10.5194/acp-22-3675-2022, 2022
Short summary
Short summary
We present GLORIA airborne cross sections of PAN, C2H6, HCOOH, CH3OH, and C2H4 in the South Atlantic UTLS in September/October 2019. Filamentary structures and a large plume were observed. Backward trajectories indicate that measured pollutants come from South America and central Africa. Comparisons to CAMS show structural agreement of the measured distributions. PAN absolute VMRs agree with the GLORIA measurements, C2H6 and HCOOH are simulated too low, and CH3OH and C2H4 are too high.
Florian Haenel, Wolfgang Woiwode, Jennifer Buchmüller, Felix Friedl-Vallon, Michael Höpfner, Sören Johansson, Farahnaz Khosrawi, Oliver Kirner, Anne Kleinert, Hermann Oelhaf, Johannes Orphal, Roland Ruhnke, Björn-Martin Sinnhuber, Jörn Ungermann, Michael Weimer, and Peter Braesicke
Atmos. Chem. Phys., 22, 2843–2870, https://doi.org/10.5194/acp-22-2843-2022, https://doi.org/10.5194/acp-22-2843-2022, 2022
Short summary
Short summary
We compare remote sensing observations of H2O, O3, HNO3 and clouds in the upper troposphere–lowermost stratosphere during an Arctic winter long-range research flight with simulations by two different state-of-the-art model systems. We find good agreement for dynamical structures, trace gas distributions and clouds. We investigate model biases and sensitivities, with the goal of aiding model development and improving our understanding of processes in the upper troposphere–lowermost stratosphere.
Matthias Schneider, Benjamin Ertl, Christopher J. Diekmann, Farahnaz Khosrawi, Andreas Weber, Frank Hase, Michael Höpfner, Omaira E. García, Eliezer Sepúlveda, and Douglas Kinnison
Earth Syst. Sci. Data, 14, 709–742, https://doi.org/10.5194/essd-14-709-2022, https://doi.org/10.5194/essd-14-709-2022, 2022
Short summary
Short summary
We present atmospheric H2O, HDO / H2O ratio, N2O, CH4, and HNO3 data generated by the MUSICA IASI processor using thermal nadir spectra measured by the IASI satellite instrument. The data have global daily coverage and are available for the period between October 2014 and June 2021. Multiple possibilities of data reuse are offered by providing each individual data product together with information about retrieval settings and the products' uncertainty and vertical representativeness.
Luca Sgheri, Claudio Belotti, Maya Ben-Yami, Giovanni Bianchini, Bernardo Carnicero Dominguez, Ugo Cortesi, William Cossich, Samuele Del Bianco, Gianluca Di Natale, Tomás Guardabrazo, Dulce Lajas, Tiziano Maestri, Davide Magurno, Hilke Oetjen, Piera Raspollini, and Cristina Sgattoni
Atmos. Meas. Tech., 15, 573–604, https://doi.org/10.5194/amt-15-573-2022, https://doi.org/10.5194/amt-15-573-2022, 2022
Short summary
Short summary
The FORUM instrument will look at the Earth's atmosphere from a satellite, covering a spectral range responsible for about 95 % of the radiation lost by our planet. FORUM helps to measure the imbalance between incoming and outgoing radiation that is responsible for the increasing average temperatures on Earth. The end-to-end simulator is a chain of codes that simulates the FORUM measurement process. The goal of the project is to study how the instrument reacts to different retrieval conditions.
Bianca Maria Dinelli, Piera Raspollini, Marco Gai, Luca Sgheri, Marco Ridolfi, Simone Ceccherini, Flavio Barbara, Nicola Zoppetti, Elisa Castelli, Enzo Papandrea, Paolo Pettinari, Angelika Dehn, Anu Dudhia, Michael Kiefer, Alessandro Piro, Jean-Marie Flaud, Manuel López-Puertas, David Moore, John Remedios, and Massimo Bianchini
Atmos. Meas. Tech., 14, 7975–7998, https://doi.org/10.5194/amt-14-7975-2021, https://doi.org/10.5194/amt-14-7975-2021, 2021
Short summary
Short summary
The level-2 v8 database from the measurements of the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), aboard the European Space Agency Envisat satellite, containing atmospheric fields of pressure, temperature, and volume mixing ratio of 21 trace gases, is described in this paper. The database covers all the measurements acquired by MIPAS (from July 2002 to April 2012). The number of species included makes it of particular importance for the studies of stratospheric chemistry.
Paolo Pettinari, Flavio Barbara, Simone Ceccherini, Bianca Maria Dinelli, Marco Gai, Piera Raspollini, Luca Sgheri, Massimo Valeri, Gerald Wetzel, Nicola Zoppetti, and Marco Ridolfi
Atmos. Meas. Tech., 14, 7959–7974, https://doi.org/10.5194/amt-14-7959-2021, https://doi.org/10.5194/amt-14-7959-2021, 2021
Short summary
Short summary
Phosgene (COCl2) is a toxic gas whose presence is a consequence of human activity. Besides its direct injection in the troposphere, stratospheric COCl2 is produced from the decomposition of CCl4, an anthropogenic gas regulated by the Montreal Protocol. As a consequence, COCl2 negative trends characterize the lower and part of the middle stratosphere. However, we find positive trends in the upper troposphere, demonstrating the non-negligible role of other Cl-containing species not yet regulated.
Michael Höpfner, Oliver Kirner, Gerald Wetzel, Björn-Martin Sinnhuber, Florian Haenel, Sören Johansson, Johannes Orphal, Roland Ruhnke, Gabriele Stiller, and Thomas von Clarmann
Atmos. Chem. Phys., 21, 18433–18464, https://doi.org/10.5194/acp-21-18433-2021, https://doi.org/10.5194/acp-21-18433-2021, 2021
Short summary
Short summary
BrONO2 is an important reservoir gas for inorganic stratospheric bromine linked to the chemical cycles of stratospheric ozone depletion. Presently infrared limb sounding is the only way to measure BrONO2 in the atmosphere. We provide global distributions of BrONO2 derived from MIPAS observations 2002–2012. Comparisons with EMAC atmospheric modelling show an overall agreement and enable us to derive an independent estimate of stratospheric bromine of 21.2±1.4pptv based on the BrONO2 measurements.
Daan Hubert, Klaus-Peter Heue, Jean-Christopher Lambert, Tijl Verhoelst, Marc Allaart, Steven Compernolle, Patrick D. Cullis, Angelika Dehn, Christian Félix, Bryan J. Johnson, Arno Keppens, Debra E. Kollonige, Christophe Lerot, Diego Loyola, Matakite Maata, Sukarni Mitro, Maznorizan Mohamad, Ankie Piters, Fabian Romahn, Henry B. Selkirk, Francisco R. da Silva, Ryan M. Stauffer, Anne M. Thompson, J. Pepijn Veefkind, Holger Vömel, Jacquelyn C. Witte, and Claus Zehner
Atmos. Meas. Tech., 14, 7405–7433, https://doi.org/10.5194/amt-14-7405-2021, https://doi.org/10.5194/amt-14-7405-2021, 2021
Short summary
Short summary
We assess the first 2 years of TROPOMI tropical tropospheric ozone column data. Comparisons to reference measurements by ozonesonde and satellite sensors show that TROPOMI bias (−0.1 to +2.3 DU) and precision (1.5 to 2.5 DU) meet mission requirements. Potential causes of bias and its spatio-temporal structure are discussed, as well as ways to identify sampling errors. Our analysis of known geophysical patterns demonstrates the improved performance of TROPOMI with respect to its predecessors.
Mahesh Kumar Sha, Bavo Langerock, Jean-François L. Blavier, Thomas Blumenstock, Tobias Borsdorff, Matthias Buschmann, Angelika Dehn, Martine De Mazière, Nicholas M. Deutscher, Dietrich G. Feist, Omaira E. García, David W. T. Griffith, Michel Grutter, James W. Hannigan, Frank Hase, Pauli Heikkinen, Christian Hermans, Laura T. Iraci, Pascal Jeseck, Nicholas Jones, Rigel Kivi, Nicolas Kumps, Jochen Landgraf, Alba Lorente, Emmanuel Mahieu, Maria V. Makarova, Johan Mellqvist, Jean-Marc Metzger, Isamu Morino, Tomoo Nagahama, Justus Notholt, Hirofumi Ohyama, Ivan Ortega, Mathias Palm, Christof Petri, David F. Pollard, Markus Rettinger, John Robinson, Sébastien Roche, Coleen M. Roehl, Amelie N. Röhling, Constantina Rousogenous, Matthias Schneider, Kei Shiomi, Dan Smale, Wolfgang Stremme, Kimberly Strong, Ralf Sussmann, Yao Té, Osamu Uchino, Voltaire A. Velazco, Corinne Vigouroux, Mihalis Vrekoussis, Pucai Wang, Thorsten Warneke, Tyler Wizenberg, Debra Wunch, Shoma Yamanouchi, Yang Yang, and Minqiang Zhou
Atmos. Meas. Tech., 14, 6249–6304, https://doi.org/10.5194/amt-14-6249-2021, https://doi.org/10.5194/amt-14-6249-2021, 2021
Short summary
Short summary
This paper presents, for the first time, Sentinel-5 Precursor methane and carbon monoxide validation results covering a period from November 2017 to September 2020. For this study, we used global TCCON and NDACC-IRWG network data covering a wide range of atmospheric and surface conditions across different terrains. We also show the influence of a priori alignment, smoothing uncertainties and the sensitivity of the validation results towards the application of advanced co-location criteria.
Cited articles
Bertaux, J. L., Mégie, G., Widemann, T., Chassefière, E., Pellinen,
R., Kyrola, E., Korpela, S., and Simon, P.: Monitoring of ozone trend by
stellar occultations: the GOMOS instrument, Adv. Space Res., 11, 237–242, https://doi.org/10.1016/0273-1177(91)90426-K, 1991.
Bovensmann, H., Burrows, J. P., Buchwitz, M., Frerick, J., Noël, S.,
Rozanov, V. V., Chance, K. V., and Goede, A. P. H.: SCIAMACHY: Mission
Objectives and Measurement Modes, J. Atmos. Sci., 56, 127–150,
https://doi.org/10.1175/1520-0469(1999)056<0127:SMOAMM>2.0.CO;2, 1999.
Bracher, A., Sinnhuber, M., Rozanov, A., and Burrows, J. P.: Using a photochemical model for the validation of NO2 satellite measurements at different solar zenith angles, Atmos. Chem. Phys., 5, 393–408, https://doi.org/10.5194/acp-5-393-2005, 2005.
Brasseur, G. P. and Solomon, S.: Aeronomy of the Middle Atmosphere:
Chemistry and Physics of the Stratosphere and Mesosphere, 3rd revised and
enlarged edn., Atmospheric and Oceanographic Sciences Library, Vol. 32,
Springer, Dordrecht, ISBN: 978-1-4020-3284-4, 2005.
Carpenter, L. J., Reimann, S., Burkholder, J. B., Clerbaux, C., Hall, B. D.,
Hossaini, R., Laube, J. C., and Yvon-Lewis, S. A.: Chapter 1: Update on
Ozone-Depleting Substances (ODSs) and Other Gases of Interest to the
Montreal Protocol, in: Scientific Assessment of Ozone Depletion, edited by:
Ennis, C. A., World Meteorological Organization (WMO), 21–125, ISBN: 978-9966-076-01-4, 2014.
Chirkov, M., Stiller, G. P., Laeng, A., Kellmann, S., von Clarmann, T., Boone, C. D., Elkins, J. W., Engel, A., Glatthor, N., Grabowski, U., Harth, C. M., Kiefer, M., Kolonjari, F., Krummel, P. B., Linden, A., Lunder, C. R., Miller, B. R., Montzka, S. A., Mühle, J., O'Doherty, S., Orphal, J., Prinn, R. G., Toon, G., Vollmer, M. K., Walker, K. A., Weiss, R. F., Wiegele, A., and Young, D.: Global HCFC-22 measurements with MIPAS: retrieval, validation, global distribution and its evolution over 2005–2012, Atmos. Chem. Phys., 16, 3345–3368, https://doi.org/10.5194/acp-16-3345-2016, 2016.
Cortesi, U., Lambert, J. C., De Clercq, C., Bianchini, G., Blumenstock, T., Bracher, A., Castelli, E., Catoire, V., Chance, K. V., De Mazière, M., Demoulin, P., Godin-Beekmann, S., Jones, N., Jucks, K., Keim, C., Kerzenmacher, T., Kuellmann, H., Kuttippurath, J., Iarlori, M., Liu, G. Y., Liu, Y., McDermid, I. S., Meijer, Y. J., Mencaraglia, F., Mikuteit, S., Oelhaf, H., Piccolo, C., Pirre, M., Raspollini, P., Ravegnani, F., Reburn, W. J., Redaelli, G., Remedios, J. J., Sembhi, H., Smale, D., Steck, T., Taddei, A., Varotsos, C., Vigouroux, C., Waterfall, A., Wetzel, G., and Wood, S.: Geophysical validation of MIPAS-ENVISAT operational ozone data, Atmos. Chem. Phys., 7, 4807–4867, https://doi.org/10.5194/acp-7-4807-2007,
2007.
Crutzen, P. J.: The possible importance of CSO for the sulfate layer of the
stratosphere, Geophys. Res. Lett., 3, 73–76,
https://doi.org/10.1029/GL003i002p00073, 1976.
Dessler, A. E., Schoeberl, M. R., Wang, T., Davis, S. M., Rosenlof, K. H.,
and Vernier, J.-P.: Variations of stratospheric water vapor over the past
three decades, J. Geophys. Res.-Atmos., 119, 12588–12598,
https://doi.org/10.1002/2014JD021712, 2014.
Dhomse, S. S., Feng, W., Montzka, S. A., Hossaini, R., Keeble, J., Pyle, J.
A., Daniel, J. S., and Chipperfield, M. P.: Delay in recovery of the
Antarctic ozone hole from unexpected CFC-11 emissions, Nature
Communications, 10, 5781, https://doi.org/10.1038/s41467-019-13717-x, 2019.
Dinelli, B. M., Raspollini, P., Gai, M., Sgheri, L., Ridolfi, M., Ceccherini, S., Barbara, F., Zoppetti, N., Castelli, E., Papandrea, E., Pettinari, P., Dehn, A., Dudhia, A., Kiefer, M., Piro, A., Flaud, J.-M., López-Puertas, M., Moore, D., Remedios, J., and Bianchini, M.: The ESA MIPAS/Envisat level2-v8 dataset: 10 years of measurements retrieved with ORM v8.22, Atmos. Meas. Tech., 14, 7975–7998, https://doi.org/10.5194/amt-14-7975-2021, 2021.
Dudhia, A., Jay, V. L., and Rodgers, C. D.: Microwindow selection for
high-spectral-resolution sounders, Appl. Optics, 41, 3665–3673,
https://doi.org/10.1364/AO.41.003665, 2002.
Engel, A., Bönisch, H., Schwarzenberger, T., Haase, H.-P., Grunow, K., Abalichin, J., and Sala, S.: Long-term validation of ESA operational retrieval (version 6.0) of MIPAS Envisat vertical profiles of methane, nitrous oxide, CFC11, and CFC12 using balloon-borne observations and trajectory matching, Atmos. Meas. Tech., 9, 1051–1062, https://doi.org/10.5194/amt-9-1051-2016, 2016.
ESA: ESA declares end of mission for Envisat, ESA,
https://www.esa.int/Applications/Observing_the_Earth/Envisat/ESA_declares_end_of_mission_for_Envisat (last access: 12 July 2022), 2012.
ESA: Envisat MIPAS L2 – Temperature, pressure and atmospheric constituents profiles product, Version 8.22, ESA [data set], https://doi.org/10.5270/EN1-c8hgqx4, 2021a.
ESA: New Envisat MIPAS L2 dataset reprocessed with ORM v822 available –
Earth Online, ESA [data set], https://earth.esa.int/eogateway/news/new-envisat-
mipas-l2-dataset-reprocessed-with-orm-v822-available
(last access: 12 July 2022), 2021b.
Fischer, H., Birk, M., Blom, C., Carli, B., Carlotti, M., von Clarmann, T., Delbouille, L., Dudhia, A., Ehhalt, D., Endemann, M., Flaud, J. M., Gessner, R., Kleinert, A., Koopman, R., Langen, J., López-Puertas, M., Mosner, P., Nett, H., Oelhaf, H., Perron, G., Remedios, J., Ridolfi, M., Stiller, G., and Zander, R.: MIPAS: an instrument for atmospheric and climate research, Atmos. Chem. Phys., 8, 2151–2188, https://doi.org/10.5194/acp-8-2151-2008, 2008.
Friedl-Vallon, F., Maucher, G., Seefeldner, M., Trieschmann, O., Kleinert,
A., Lengel, A., Keim, C., Oelhaf, H., and Fischer, H.: Design and
characterization of the balloon-borne Michelson Interferometer for Passive
Atmospheric Sounding (MIPAS-B2), Appl. Optics, 43, p. 3335,
https://doi.org/10.1364/AO.43.003335, 2004.
Fu, D., Boone, C. D., Bernath, P. F., Walker, K. A., Nassar, R., Manney, G.
L., and McLeod, S. D.: Global phosgene observations from the Atmospheric
Chemistry Experiment (ACE) mission, Geophys. Res. Lett., 34, L17815,
https://doi.org/10.1029/2007GL029942, 2007.
Glatthor, N., von Clarmann, T., Stiller, G. P., Funke, B., Koukouli, M. E., Fischer, H., Grabowski, U., Höpfner, M., Kellmann, S., and Linden, A.: Large-scale upper tropospheric pollution observed by MIPAS HCN and C2H6 global distributions, Atmos. Chem. Phys., 9, 9619–9634, https://doi.org/10.5194/acp-9-9619-2009, 2009.
Glatthor, N., Höpfner, M., Leyser, A., Stiller, G. P., von Clarmann, T., Grabowski, U., Kellmann, S., Linden, A., Sinnhuber, B.-M., Krysztofiak, G., and Walker, K. A.: Global carbonyl sulfide (OCS) measured by MIPAS/Envisat during 2002–2012, Atmos. Chem. Phys., 17, 2631–2652, https://doi.org/10.5194/acp-17-2631-2017, 2017.
Grunow, K.: Anwendung von Trajektorien zur ENVISAT-Validierung und zur
Untersuchung der Luftmassenherkunft in der Stratosphäre, PhD thesis, Free
University Berlin, Berlin, Germany, ISBN: 978-3899599336, 2009.
Harrison, J. J.: New and improved infrared absorption cross sections for dichlorodifluoromethane (CFC-12), Atmos. Meas. Tech., 8, 3197–3207, https://doi.org/10.5194/amt-8-3197-2015, 2015.
Harrison, J. J.: New and improved infrared absorption cross sections for chlorodifluoromethane (HCFC-22), Atmos. Meas. Tech., 9, 2593–2601, https://doi.org/10.5194/amt-9-2593-2016, 2016.
Harrison, J. J., Chipperfield, M. P., Dudhia, A., Cai, S., Dhomse, S., Boone, C. D., and Bernath, P. F.: Satellite observations of stratospheric carbonyl fluoride, Atmos. Chem. Phys., 14, 11915–11933, https://doi.org/10.5194/acp-14-11915-2014, 2014.
Harrison, J. J., Boone, C. D., and Bernath, P. F.: New and improved
infra-red absorption cross sections and ACE-FTS retrievals of carbon
tetrachloride (CCl4), J. Quant. Spectrosc. Ra., 186, 139–149,
https://doi.org/10.1016/j.jqsrt.2016.04.025, 2017.
Hegglin, M. I., Tegtmeier, S., Anderson, J., Bourassa, A. E., Brohede, S., Degenstein, D., Froidevaux, L., Funke, B., Gille, J., Kasai, Y., Kyrölä, E. T., Lumpe, J., Murtagh, D., Neu, J. L., Pérot, K., Remsberg, E. E., Rozanov, A., Toohey, M., Urban, J., von Clarmann, T., Walker, K. A., Wang, H.-J., Arosio, C., Damadeo, R., Fuller, R. A., Lingenfelser, G., McLinden, C., Pendlebury, D., Roth, C., Ryan, N. J., Sioris, C., Smith, L., and Weigel, K.: Overview and update of the SPARC Data Initiative: comparison of stratospheric composition measurements from satellite limb sounders, Earth Syst. Sci. Data, 13, 1855–1903, https://doi.org/10.5194/essd-13-1855-2021, 2021.
Höpfner, M., Oelhaf, H., Wetzel, G., Friedl-Vallon, F., Kleinert, A.,
Lengel, A., Maucher, G., Nordmeyer, H., Glatthor, N., Stiller, G., Clarmann,
T. v., Fischer, H., Kröger, C., and Deshler, T.: Evidence of scattering
of tropospheric radiation by PSCs in mid-IR limb emission spectra: MIPAS-B
observations and KOPRA simulations, Geophys. Res. Lett., 29, 119-1–119-4,
https://doi.org/10.1029/2001GL014443, 2002.
Hubert, D., Keppens, A., Granville, J., and Lambert, J.-C.: Validation
report: comparison of MIPAS ORM 8.22 to ground-based data
TN-BIRA-IASB-MultiTASTE-Phase-F-MIPAS-ORM8-Iss1-RevB, https://earth.esa.int/eogateway/documents/20142/37627/TN-
BIRA-IASB-MultiTASTE-Phase-F-MIPAS-ORM8-Iss1-RevB.pdf
(last access: 12 July 2022), 2020.
Khosrawi, F., Lossow, S., Stiller, G. P., Rosenlof, K. H., Urban, J., Burrows, J. P., Damadeo, R. P., Eriksson, P., García-Comas, M., Gille, J. C., Kasai, Y., Kiefer, M., Nedoluha, G. E., Noël, S., Raspollini, P., Read, W. G., Rozanov, A., Sioris, C. E., Walker, K. A., and Weigel, K.: The SPARC water vapour assessment II: comparison of stratospheric and lower mesospheric water vapour time series observed from satellites, Atmos. Meas. Tech., 11, 4435–4463, https://doi.org/10.5194/amt-11-4435-2018, 2018.
Kindler, T. P., Chameides, W. L., Wine, P. H., Cunnold, D. M., Alyea, F. N.,
and Franklin, J. A.: The fate of atmospheric phosgene and the stratospheric
chlorine loadings of its parent compounds: CCl4, C2Cl4,
C2HCl3, CH3CCl3, and CHCl3, J. Geophys. Res., 100,
1235–1251, https://doi.org/10.1029/94JD02518, 1995.
Ko, M. K. W. and Dak Sze, N.: A 2-D model calculation of atmospheric
lifetimes for N2O, CFC-11 and CFC-12, Nature, 297, 317–319,
https://doi.org/10.1038/297317a0, 1982.
Kremser, S., Thomason, L. W., Hobe, M. von, Hermann, M., Deshler, T.,
Timmreck, C., Toohey, M., Stenke, A., Schwarz, J. P., Weigel, R.,
Fueglistaler, S., Prata, F. J., Vernier, J.-P., Schlager, H., Barnes, J. E.,
Antuña-Marrero, J.-C., Fairlie, D., Palm, M., Mahieu, E., Notholt, J.,
Rex, M., Bingen, C., Vanhellemont, F., Bourassa, A., Plane, J. M. C.,
Klocke, D., Carn, S. A., Clarisse, L., Trickl, T., Neely, R., James, A. D.,
Rieger, L., Wilson, J. C., and Meland, B.: Stratospheric
aerosol – Observations, processes, and impact on climate, Rev. Geophys., 54,
278–335, https://doi.org/10.1002/2015RG000511, 2016.
Li, Q., Jacob, D. J., Yantosca, R. M., Heald, C. L., Singh, H. B., Koike,
M., Zhao, Y., Sachse, G. W., and Streets, D. G.: A global three-dimensional
model analysis of the atmospheric budgets of HCN and CH3CN: Constraints
from aircraft and ground measurements, J. Geophys. Res., 108, 8827,
https://doi.org/10.1029/2002JD003075, 2003.
Lossow, S., Hurst, D. F., Rosenlof, K. H., Stiller, G. P., von Clarmann, T., Brinkop, S., Dameris, M., Jöckel, P., Kinnison, D. E., Plieninger, J., Plummer, D. A., Ploeger, F., Read, W. G., Remsberg, E. E., Russell, J. M., and Tao, M.: Trend differences in lower stratospheric water vapour between Boulder and the zonal mean and their role in understanding fundamental observational discrepancies, Atmos. Chem. Phys., 18, 8331–8351, https://doi.org/10.5194/acp-18-8331-2018, 2018.
Lossow, S., Khosrawi, F., Kiefer, M., Walker, K. A., Bertaux, J.-L., Blanot, L., Russell, J. M., Remsberg, E. E., Gille, J. C., Sugita, T., Sioris, C. E., Dinelli, B. M., Papandrea, E., Raspollini, P., García-Comas, M., Stiller, G. P., von Clarmann, T., Dudhia, A., Read, W. G., Nedoluha, G. E., Damadeo, R. P., Zawodny, J. M., Weigel, K., Rozanov, A., Azam, F., Bramstedt, K., Noël, S., Burrows, J. P., Sagawa, H., Kasai, Y., Urban, J., Eriksson, P., Murtagh, D. P., Hervig, M. E., Högberg, C., Hurst, D. F., and Rosenlof, K. H.: The SPARC water vapour assessment II: profile-to-profile comparisons of stratospheric and lower mesospheric water vapour data sets obtained from satellites, Atmos. Meas. Tech., 12, 2693–2732, https://doi.org/10.5194/amt-12-2693-2019, 2019.
Manney, G. L., Michelsen, H. A., Bevilacqua, R. M., Gunson, M. R., Irion, F.
W., Livesey, N. J., Oberheide, J., Riese, M., Russell, J. M., Toon, G. C.,
and Zawodny, J. M.: Comparison of satellite ozone observations in coincident
air masses in early November 1994, J. Geophys. Res., 106, 9923–9943, 2001.
Michelsen, H. A., Manney, G. L., Gunson, M. R., and Zander, R.: Correlations
of stratospheric abundances of NOy, O3, N2O, and CH4
derived from ATMOS measurements, J. Geophys. Res., 103, 28347–28359, https://doi.org/10.1029/98JD02850, 1998.
Naujokat, B. and Grunow, K.: The stratospheric Arctic winter 2002/03:
Balloon flight planning by trajectory calculations, in: 16th ESA Symposium on European Rocket and Balloon Programmes and Related Research, 2–5 June 2003, Sankt Gallen, Switzerland, edited by: Warmbein, B., ESA Publications Division, Noordwijk, ESA SP-530, ISBN 92-9092-840-9, 421–425, 2003.
Parker, R. J., Remedios, J. J., Moore, D. P., and Kanawade, V. P.: Acetylene C2H2 retrievals from MIPAS data and regions of enhanced upper tropospheric concentrations in August 2003, Atmos. Chem. Phys., 11, 10243–10257, https://doi.org/10.5194/acp-11-10243-2011, 2011.
Payan, S., Camy-Peyret, C., Oelhaf, H., Wetzel, G., Maucher, G., Keim, C., Pirre, M., Huret, N., Engel, A., Volk, M. C., Kuellmann, H., Kuttippurath, J., Cortesi, U., Bianchini, G., Mencaraglia, F., Raspollini, P., Redaelli, G., Vigouroux, C., De Mazière, M., Mikuteit, S., Blumenstock, T., Velazco, V., Notholt, J., Mahieu, E., Duchatelet, P., Smale, D., Wood, S., Jones, N., Piccolo, C., Payne, V., Bracher, A., Glatthor, N., Stiller, G., Grunow, K., Jeseck, P., Te, Y., and Butz, A.: Validation of version-4.61 methane and nitrous oxide observed by MIPAS, Atmos. Chem. Phys., 9, 413–442, https://doi.org/10.5194/acp-9-413-2009, 2009.
Pettinari, P., Barbara, F., Ceccherini, S., Dinelli, B. M., Gai, M., Raspollini, P., Sgheri, L., Valeri, M., Wetzel, G., Zoppetti, N., and Ridolfi, M.: Phosgene distribution derived from MIPAS ESA v8 data: intercomparisons and trends, Atmos. Meas. Tech., 14, 7959–7974, https://doi.org/10.5194/amt-14-7959-2021, 2021.
Phillips, D. L.: A technique for the numerical solution of certain integral
equations of the first kind, J. ACM, 9, 84–97, https://doi.org/10.1145/321105.321114, 1962.
Prinn, R. G., Weiss, R. F., Fraser, P. J., Simmonds, P. G., Cunnold, D. M.,
Alyea, F. N., O'Doherty, S., Salameh, P., Miller, B. R., Huang, J., Wang, R.
H. J., Hartley, D. E., Harth, C., Steele, L. P., Sturrock, G., Midgley, P.
M., and McCulloch, A.: A history of chemically and radiatively important
gases in air deduced from ALE/GAGE/AGAGE, J. Geophys. Res., 105,
17751–17792, https://doi.org/10.1029/2000JD900141, 2000.
Raspollini, P., Belotti, C., Burgess, A., Carli, B., Carlotti, M., Ceccherini, S., Dinelli, B. M., Dudhia, A., Flaud, J.-M., Funke, B., Höpfner, M., López-Puertas, M., Payne, V., Piccolo, C., Remedios, J. J., Ridolfi, M., and Spang, R.: MIPAS level 2 operational analysis, Atmos. Chem. Phys., 6, 5605–5630, https://doi.org/10.5194/acp-6-5605-2006, 2006.
Raspollini, P., Carli, B., Carlotti, M., Ceccherini, S., Dehn, A., Dinelli, B. M., Dudhia, A., Flaud, J.-M., López-Puertas, M., Niro, F., Remedios, J. J., Ridolfi, M., Sembhi, H., Sgheri, L., and von Clarmann, T.: Ten years of MIPAS measurements with ESA Level 2 processor V6 – Part 1: Retrieval algorithm and diagnostics of the products, Atmos. Meas. Tech., 6, 2419–2439, https://doi.org/10.5194/amt-6-2419-2013, 2013.
Raspollini, P., Piro, A., Hubert, D., Keppens, A., Lambert, J.-C., Wetzel,
G., Moore, D., Ceccherini, S., Gai, M., Barbara, F., and Zoppetti, N.:
Environmental Satellite (ENVISAT) Michelson Interferometer for Passive
Atmospheric Sounding (MIPAS), ESA Level 2 version 8.22 products – product
quality readme file,
https://earth.esa.int/eogateway/documents/20142/37627/README_V8_issue_1.0_20201221.pdf (last access: 12 July 2022), 2020.
Raspollini, P., Arnone, E., Barbara, F., Bianchini, M., Carli, B., Ceccherini, S., Chipperfield, M. P., Dehn, A., Della Fera, S., Dinelli, B. M., Dudhia, A., Flaud, J.-M., Gai, M., Kiefer, M., López-Puertas, M., Moore, D. P., Piro, A., Remedios, J. J., Ridolfi, M., Sembhi, H., Sgheri, L., and Zoppetti, N.: Level 2 processor and auxiliary data for ESA Version 8 final full mission analysis of MIPAS measurements on ENVISAT, Atmos. Meas. Tech., 15, 1871–1901, https://doi.org/10.5194/amt-15-1871-2022, 2022.
Renard, J.-B., Berthet, G., Brogniez, C., Catoire, V., Fussen, D., Goutail,
F., Oelhaf, H., Pommereau, J.-P., Roscoe, H. K., Wetzel, G., Chartier, M.,
Robert, C., Balois, J.-Y., Verwaerde, C., Auriol, F., François, P.,
Gaubicher, B., and Wursteisen, P.: Validation of GOMOS-Envisat vertical
profiles of O3, NO2, NO3, and aerosol extinction using
balloon-borne instruments and analysis of the retrievals, J. Geophys. Res., 113, A02302, https://doi.org/10.1029/2007JA012345, 2008.
Ridolfi, M., Carli, B., Carlotti, M., Clarmann, T. von, Dinelli, B. M.,
Dudhia, A., Flaud, J.-M., Höpfner, M., Morris, P. E., Raspollini, P.,
Stiller, G., and Wells, R. J.: Optimized forward model and retrieval scheme
for MIPAS near-real-time data processing, Appl. Optics, 39, 1323–1340,
https://doi.org/10.1364/AO.39.001323, 2000.
Ridolfi, M., Blum, U., Carli, B., Catoire, V., Ceccherini, S., Claude, H., De Clercq, C., Fricke, K. H., Friedl-Vallon, F., Iarlori, M., Keckhut, P., Kerridge, B., Lambert, J.-C., Meijer, Y. J., Mona, L., Oelhaf, H., Pappalardo, G., Pirre, M., Rizi, V., Robert, C., Swart, D., von Clarmann, T., Waterfall, A., and Wetzel, G.: Geophysical validation of temperature retrieved by the ESA processor from MIPAS/ENVISAT atmospheric limb-emission measurements, Atmos. Chem. Phys., 7, 4459–4487, https://doi.org/10.5194/acp-7-4459-2007, 2007.
Rodgers, C. D.: Inverse methods for atmospheric sounding, 2nd edn., World Scientific, ISBN: 978-981-02-2740-1, 2000.
Rothman, L. S., Gordon, I. E., Barbe, A., Benner, D., Bernath, P. F., Birk,
M., Boudon, V., Brown, L. R., Campargue, A., Champion, J.-P., Chance, K.,
Coudert, L. H., Dana, V., Devi, V. M., Fally, S., Flaud, J.-M., Gamache, R.
R., Goldman, A., Jacquemart, D., Kleiner, I., Lacome, N., Lafferty, W. J.,
Mandin, J.-Y., Massie, S. T., Mikhailenko, S. N., Miller, C. E.,
Moazzen-Ahmadi, N., Naumenko, O. V., Nikitin, A. V., Orphal, J., Perevalov,
V. I., Perrin, A., Predoi-Cross, A., Rinsland, C. P., Rotger, M.,
Šimečková, M., Smith, M., Sung, K., Tashkun, S. A., Tennyson, J., Toth, R. A., Vandaele, A. C., and Vander Auwera, J.: The HITRAN 2008 molecular spectroscopic database, J. Quant. Spectrosc. Ra., 110, 533–572,
https://doi.org/10.1016/j.jqsrt.2009.02.013, 2009.
Rudolph, J.: The tropospheric distribution and budget of ethane, J. Geophys.
Res., 100, 11369–11381, https://doi.org/10.1029/95JD00693, 1995.
Sagawa, H., Sato, T. O., Baron, P., Dupuy, E., Livesey, N., Urban, J., von Clarmann, T., de Lange, A., Wetzel, G., Connor, B. J., Kagawa, A., Murtagh, D., and Kasai, Y.: Comparison of SMILES ClO profiles with satellite, balloon-borne and ground-based measurements, Atmos. Meas. Tech., 6, 3325–3347, https://doi.org/10.5194/amt-6-3325-2013, 2013.
Singh, H. B., Herlth, D., Kolyer, R., Chatfield, R., Viezee, W., Salas, L.
J., Chen, Y., Bradshaw, J. D., Sandholm, S. T., Talbot, R., Gregory, G. L.,
Anderson, B., Sachse, G. W., Browell, E., Bachmeier, A. S., Blake, D. R.,
Heikes, B., Jacob, D., and Fuelberg, H. E.: Impact of biomass burning
emissions on the composition of the South Atlantic troposphere: Reactive
nitrogen and ozone, J. Geophys. Res., 101, 24203–24219,
https://doi.org/10.1029/96JD01018, 1996.
Sinnhuber, M., Burrows, J. P., Chipperfield, M. P., Jackman, C. H.,
Kallenrode, M.-B., Künzi, K. F., and Quack, M.: A model study of the
impact of magnetic field structure on atmospheric composition during solar
proton events, Geophys. Res. Lett., 30, 1781, https://doi.org/10.1029/2003GL017265, 2003.
SPARC: The SPARC Data Initiative: Assessment of stratospheric trace gas and
aerosol climatologies from satellite limb sounders, edited by: Hegglin, M. I. and Tegtmeier, S., SPARC Report No. 8, WCRP-5/2017, https://www.sparc-climate.org/publications/sparc-reports/ (last access: 22 September 2022), 2017.
Stiller, G. P., Clarmann, T. von, Funke, B., Glatthor, N., Hase, F.,
Höpfner, M., and Linden, A.: Sensitivity of trace gas abundances
retrievals from infrared limb emission spectra to simplifying approximations
in radiative transfer modelling, J. Quant. Spectrosc. Ra., 72, 249–280,
https://doi.org/10.1016/S0022-4073(01)00123-6, 2002.
Tchana, F. K., Lafferty, W. J., Flaud, J.-M., Manceron, L., and Ndao, M.:
High-resolution analysis of the ν1 and ν5 bands of phosgene 35Cl2CO and 35Cl37ClCO, Mol. Phys., 113, 3241–3246, https://doi.org/10.1080/00268976.2015.1015638, 2015.
Tikhonov, A. N.: On the solution of ill-posed problems and the method of
regularization, Dokl. Acad. Nauk SSSR, 151, 501–504, 1963.
Toon, G. C., Blavier, J.-F., Sen, B., and Drouin, B. J.: Atmospheric
COCl2 measured by solar occultation spectrometry, Geophys. Res. Lett.,
28, 2835–2838, https://doi.org/10.1029/2000GL012156, 2001.
Valeri, M., Carlotti, M., Flaud, J.-M., Raspollini, P., Ridolfi, M., and Dinelli, B. M.: Phosgene in the UTLS: seasonal and latitudinal variations from MIPAS observations, Atmos. Meas. Tech., 9, 4655–4663, https://doi.org/10.5194/amt-9-4655-2016, 2016.
Valeri, M., Barbara, F., Boone, C., Ceccherini, S., Gai, M., Maucher, G., Raspollini, P., Ridolfi, M., Sgheri, L., Wetzel, G., and Zoppetti, N.: CCl4 distribution derived from MIPAS ESA v7 data: intercomparisons, trend, and lifetime estimation, Atmos. Chem. Phys., 17, 10143–10162, https://doi.org/10.5194/acp-17-10143-2017, 2017.
von Clarmann, T. and Johansson, S.: Chlorine nitrate in the atmosphere, Atmos. Chem. Phys., 18, 15363–15386, https://doi.org/10.5194/acp-18-15363-2018, 2018.
von Clarmann, T., Höpfner, M., Kellmann, S., Linden, A., Chauhan, S., Funke, B., Grabowski, U., Glatthor, N., Kiefer, M., Schieferdecker, T., Stiller, G. P., and Versick, S.: Retrieval of temperature, H2O, O3, HNO3, CH4, N2O, ClONO2 and ClO from MIPAS reduced resolution nominal mode limb emission measurements, Atmos. Meas. Tech., 2, 159–175, https://doi.org/10.5194/amt-2-159-2009, 2009.
Wang, D. Y., Höpfner, M., Blom, C. E., Ward, W. E., Fischer, H., Blumenstock, T., Hase, F., Keim, C., Liu, G. Y., Mikuteit, S., Oelhaf, H., Wetzel, G., Cortesi, U., Mencaraglia, F., Bianchini, G., Redaelli, G., Pirre, M., Catoire, V., Huret, N., Vigouroux, C., De Mazière, M., Mahieu, E., Demoulin, P., Wood, S., Smale, D., Jones, N., Nakajima, H., Sugita, T., Urban, J., Murtagh, D., Boone, C. D., Bernath, P. F., Walker, K. A., Kuttippurath, J., Kleinböhl, A., Toon, G., and Piccolo, C.: Validation of MIPAS HNO3 operational data, Atmos. Chem. Phys., 7, 4905–4934, https://doi.org/10.5194/acp-7-4905-2007, 2007.
Wetzel, G., Oelhaf, H., Friedl-Vallon, F., Kleinert, A., Lengel, A.,
Maucher, G., Nordmeyer, H., Ruhnke, R., Nakajima, H., Sasano, Y., Sugita,
T., and Yokota, T.: Intercomparison and validation of ILAS-II version 1.4
target parameters with MIPAS-B measurements, J. Geophys. Res., 111, D11S06,
https://doi.org/10.1029/2005JD006287, 2006.
Wetzel, G., Bracher, A., Funke, B., Goutail, F., Hendrick, F., Lambert, J.-C., Mikuteit, S., Piccolo, C., Pirre, M., Bazureau, A., Belotti, C., Blumenstock, T., De Mazière, M., Fischer, H., Huret, N., Ionov, D., López-Puertas, M., Maucher, G., Oelhaf, H., Pommereau, J.-P., Ruhnke, R., Sinnhuber, M., Stiller, G., Van Roozendael, M., and Zhang, G.: Validation of MIPAS-ENVISAT NO2 operational data, Atmos. Chem. Phys., 7, 3261–3284, https://doi.org/10.5194/acp-7-3261-2007, 2007.
Wetzel, G., Sugita, T., Nakajima, H., Tanaka, T., Yokota, T., Friedl-Vallon, F., Kleinert, A., Maucher, G., and Oelhaf, H.: Technical Note: Intercomparison of ILAS-II version 2 and 1.4 trace species with MIPAS-B measurements, Atmos. Chem. Phys., 8, 1119–1126, https://doi.org/10.5194/acp-8-1119-2008, 2008.
Wetzel, G., Oelhaf, H., Kirner, O., Ruhnke, R., Friedl-Vallon, F., Kleinert, A., Maucher, G., Fischer, H., Birk, M., Wagner, G., and Engel, A.: First remote sensing measurements of ClOOCl along with ClO and ClONO2 in activated and deactivated Arctic vortex conditions using new ClOOCl IR absorption cross sections, Atmos. Chem. Phys., 10, 931–945, https://doi.org/10.5194/acp-10-931-2010, 2010.
Wetzel, G., Oelhaf, H., Kirner, O., Friedl-Vallon, F., Ruhnke, R., Ebersoldt, A., Kleinert, A., Maucher, G., Nordmeyer, H., and Orphal, J.: Diurnal variations of reactive chlorine and nitrogen oxides observed by MIPAS-B inside the January 2010 Arctic vortex, Atmos. Chem. Phys., 12, 6581–6592, https://doi.org/10.5194/acp-12-6581-2012, 2012.
Wetzel, G., Oelhaf, H., Berthet, G., Bracher, A., Cornacchia, C., Feist, D. G., Fischer, H., Fix, A., Iarlori, M., Kleinert, A., Lengel, A., Milz, M., Mona, L., Müller, S. C., Ovarlez, J., Pappalardo, G., Piccolo, C., Raspollini, P., Renard, J.-B., Rizi, V., Rohs, S., Schiller, C., Stiller, G., Weber, M., and Zhang, G.: Validation of MIPAS-ENVISAT H2O operational data collected between July 2002 and March 2004, Atmos. Chem. Phys., 13, 5791–5811, https://doi.org/10.5194/acp-13-5791-2013, 2013a.
Wetzel, G., Oelhaf, H., Friedl-Vallon, F., Kleinert, A., Maucher, G.,
Nordmeyer, H., and Orphal, J.: Long-term intercomparison of MIPAS additional
species ClONO2, N2O5, CFC-11, and CFC-12 with MIPAS-B
measurements, Ann. Geophys., 56, 6329, https://doi.org/10.4401/ag-6329, 2013b.
Wetzel, G., Oelhaf, H., Birk, M., de Lange, A., Engel, A., Friedl-Vallon, F., Kirner, O., Kleinert, A., Maucher, G., Nordmeyer, H., Orphal, J., Ruhnke, R., Sinnhuber, B.-M., and Vogt, P.: Partitioning and budget of inorganic and organic chlorine species observed by MIPAS-B and TELIS in the Arctic in March 2011, Atmos. Chem. Phys., 15, 8065–8076, https://doi.org/10.5194/acp-15-8065-2015, 2015.
Wetzel, G., Höpfner, M., and Oelhaf, H.: CCN #2: Support to MIPAS
level 2 processor verification and validation - Phase F: Report to
MS6_2: L1v8/L2v8 FM comparison for GL1-GL3; Long-term
validation of MIPAS ESA operational products using MIPAS-B measurements,
https://earth.esa.int/eogateway/documents/20142/37627/kit_ccn_2_esa_tn-fr_2020_01.pdf (last access: 12 July 2022), 2020.
Wiegele, A., Glatthor, N., Höpfner, M., Grabowski, U., Kellmann, S., Linden, A., Stiller, G., and von Clarmann, T.: Global distributions of C2H6, C2H2, HCN, and PAN retrieved from MIPAS reduced spectral resolution measurements, Atmos. Meas. Tech., 5, 723–734, https://doi.org/10.5194/amt-5-723-2012, 2012.
Xiao, Y., Logan, J. A., Jacob, D. J., Hudman, R. C., Yantosca, R., and
Blake, D. R.: Global budget of ethane and regional constraints on U.S.
sources, J. Geophys. Res., 113, D21306, https://doi.org/10.1029/2007JD009415, 2008.
Yokouchi, Y., Noijiri, Y., Barrie, L. A., Toom-Sauntry, D., Machida, T.,
Inuzuka, Y., Akimoto, H., Li, H. J., Fujinuma, Y., and Aoki, S.: A strong
source of methyl chloride to the atmosphere from tropical coastal land,
Nature, 403, 295–298, https://doi.org/10.1038/35002049, 2000.
Zhang, G., Wetzel, G., Oelhaf, H., Friedl-Vallon, F., Kleinert, A., Lengel,
A., Maucher, G., Nordmeyer, H., Grunow, K., and Fischer, H.: Validation of
atmospheric chemistry measurements from MIPAS, SCIAMACHY, GOMOS onboard
ENVISAT by observations of balloon-borne MIPAS-B, Sci, China Earth Sci., 53,
1533–1541, https://doi.org/10.1007/s11430-010-3059-3, 2010.
Short summary
Satellite measurements of stratospheric trace gases are essential for monitoring distributions and trends of these species on a global scale. Here, we compare the final MIPAS ESA Level 2 version 8 data (temperature and trace gases) with measurements obtained with the balloon version of MIPAS in terms of data agreement of both sensors, including combined errors. For most gases, we find a 5 % to 20 % agreement of the retrieved vertical profiles of both MIPAS instruments in the lower stratosphere.
Satellite measurements of stratospheric trace gases are essential for monitoring distributions...
