Articles | Volume 13, issue 2
https://doi.org/10.5194/amt-13-685-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-13-685-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
13 Feb 2020
Research article |
| 13 Feb 2020
| 13 Feb 2020
Evaluating different methods for elevation calibration of MAX-DOAS (Multi AXis Differential Optical Absorption Spectroscopy) instruments during the CINDI-2 campaign
Sebastian Donner
CORRESPONDING AUTHOR
Max Planck Institute for Chemistry, Mainz, Germany
Jonas Kuhn
Max Planck Institute for Chemistry, Mainz, Germany
Institute of Environmental Physics, University of Heidelberg, Heidelberg, Germany
Michel Van Roozendael
BIRA-IASB – Royal Belgian Institute for Space Aeronomy, Brussels, Belgium
Alkiviadis Bais
Laboratory of Atmospheric Physics, Aristotle University of Thessaloniki, Thessaloniki, Greece
Steffen Beirle
Max Planck Institute for Chemistry, Mainz, Germany
Tim Bösch
Institute of Environmental Physics, University of Bremen, Bremen, Germany
Kristof Bognar
Department of Physics, University of Toronto, Toronto, Canada
Ilya Bruchkouski
National Ozone Monitoring Research and Education Center, Belarusian State University (BSU), Minsk, Belarus
Ka Lok Chan
Meteorological Institute, Ludwig-Maximilians-Universität München, Munich, Germany
Steffen Dörner
Max Planck Institute for Chemistry, Mainz, Germany
Theano Drosoglou
Laboratory of Atmospheric Physics, Aristotle University of Thessaloniki, Thessaloniki, Greece
Caroline Fayt
BIRA-IASB – Royal Belgian Institute for Space Aeronomy, Brussels, Belgium
Udo Frieß
Institute of Environmental Physics, University of Heidelberg, Heidelberg, Germany
François Hendrick
BIRA-IASB – Royal Belgian Institute for Space Aeronomy, Brussels, Belgium
Christian Hermans
BIRA-IASB – Royal Belgian Institute for Space Aeronomy, Brussels, Belgium
Junli Jin
CMA Meteorological Observation Center, Beijing, China
Ang Li
Anhui Institute of Optics and Fine Mechanics, Hefei, China
Jianzhong Ma
Chinese Academy of Meteorological Sciences, Beijing, China
Enno Peters
Institute of Environmental Physics, University of Bremen, Bremen, Germany
now at: Institute for the Protection of Maritime Infrastructures, German Aerospace Center (DLR), Bremerhaven, Germany
Gaia Pinardi
BIRA-IASB – Royal Belgian Institute for Space Aeronomy, Brussels, Belgium
Andreas Richter
Institute of Environmental Physics, University of Bremen, Bremen, Germany
Stefan F. Schreier
Institute of Meteorology, University of Natural Resources and Life Sciences, Vienna, Austria
André Seyler
Institute of Environmental Physics, University of Bremen, Bremen, Germany
Kimberly Strong
Department of Physics, University of Toronto, Toronto, Canada
Jan-Lukas Tirpitz
Institute of Environmental Physics, University of Heidelberg, Heidelberg, Germany
Yang Wang
Max Planck Institute for Chemistry, Mainz, Germany
Pinhua Xie
Anhui Institute of Optics and Fine Mechanics, Hefei, China
Jin Xu
Anhui Institute of Optics and Fine Mechanics, Hefei, China
Xiaoyi Zhao
Department of Physics, University of Toronto, Toronto, Canada
now at: Air Quality Research Division, Environment and Climate Change Canada, Toronto, Canada
Thomas Wagner
Max Planck Institute for Chemistry, Mainz, Germany
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Bianca Lauster, Steffen Dörner, Steffen Beirle, Sebastian Donner, Sergey Gromov, Katharina Uhlmannsiek, and Thomas Wagner
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Atmos. Meas. Tech., 14, 481–510, https://doi.org/10.5194/amt-14-481-2021, https://doi.org/10.5194/amt-14-481-2021, 2021
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Jan-Lukas Tirpitz, Udo Frieß, François Hendrick, Carlos Alberti, Marc Allaart, Arnoud Apituley, Alkis Bais, Steffen Beirle, Stijn Berkhout, Kristof Bognar, Tim Bösch, Ilya Bruchkouski, Alexander Cede, Ka Lok Chan, Mirjam den Hoed, Sebastian Donner, Theano Drosoglou, Caroline Fayt, Martina M. Friedrich, Arnoud Frumau, Lou Gast, Clio Gielen, Laura Gomez-Martín, Nan Hao, Arjan Hensen, Bas Henzing, Christian Hermans, Junli Jin, Karin Kreher, Jonas Kuhn, Johannes Lampel, Ang Li, Cheng Liu, Haoran Liu, Jianzhong Ma, Alexis Merlaud, Enno Peters, Gaia Pinardi, Ankie Piters, Ulrich Platt, Olga Puentedura, Andreas Richter, Stefan Schmitt, Elena Spinei, Deborah Stein Zweers, Kimberly Strong, Daan Swart, Frederik Tack, Martin Tiefengraber, René van der Hoff, Michel van Roozendael, Tim Vlemmix, Jan Vonk, Thomas Wagner, Yang Wang, Zhuoru Wang, Mark Wenig, Matthias Wiegner, Folkard Wittrock, Pinhua Xie, Chengzhi Xing, Jin Xu, Margarita Yela, Chengxin Zhang, and Xiaoyi Zhao
Atmos. Meas. Tech., 14, 1–35, https://doi.org/10.5194/amt-14-1-2021, https://doi.org/10.5194/amt-14-1-2021, 2021
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Simon Chabrillat, Samuel Rémy, Quentin Errera, Vincent Huijnen, Christine Bingen, Jonas Debosscher, François Hendrick, Swen Metzger, Adrien Mora, Daniele Minganti, Marc Op de beek, Léa Reisenfeld, Jason E. Williams, Henk Eskes, and Johannes Flemming
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Stefanie Falk, Luca Reißig, Bianca Zilker, Andreas Richter, and Björn-Martin Sinnhuber
Atmos. Chem. Phys., 25, 15653–15682, https://doi.org/10.5194/acp-25-15653-2025, https://doi.org/10.5194/acp-25-15653-2025, 2025
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Ozone depletion events (ODEs) and bromine explosions in the Arctic were studied for 2019/20. Our model underestimated boundary layer height and showed warm biases, affecting ODE simulation. Updates improved coastal ozone agreement but failed to capture strong ODEs. Bromine monoxide (BrO) was overestimated at the surface yet underestimated in columns. Long-term data show declining strong ODEs since 2008, suggesting additional climate-driven factors beyond sea ice age.
Simon Bittner, Andreas Richter, Bianca Zilker, Sebastian Donner, Thomas Wagner, Leonardo M. A. Alvarado, and Mihalis Vrekoussis
EGUsphere, https://doi.org/10.5194/egusphere-2025-5285, https://doi.org/10.5194/egusphere-2025-5285, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
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Atmos. Meas. Tech., 18, 6093–6123, https://doi.org/10.5194/amt-18-6093-2025, https://doi.org/10.5194/amt-18-6093-2025, 2025
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The Greenhouse Gases Observing Satellite-2 (GOSAT-2) is a satellite dedicated to measuring concentrations of greenhouse gases from space. Since its launch, the increase of CH4 and CO2 concentrations in the atmosphere is clear. The datasets obtained from GOSAT-2 are used in the Copernicus atmospheric services to monitor the climate, in light of the Paris Agreement. Here we present robust datasets of these gases from GOSAT-2, including a novel machine learning approach to data quality filtering.
Qinghe Cai, Dongqing Fang, Junli Jin, Xiaoyu Hu, Yuxuan Cao, Tianyi Zhao, Yang Bai, and Yang Zhang
Atmos. Chem. Phys., 25, 14643–14668, https://doi.org/10.5194/acp-25-14643-2025, https://doi.org/10.5194/acp-25-14643-2025, 2025
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This study analyzed PM10 and oxidative potential (OP) in 12 Chinese regions (Jun 2022-May 2023) via Convolutional Neural Networks and Long Short-Term Memory networks (CNN-LSTM) and Positive Matrix Factorization (PMF) at 4 representative sites. PM10 was higher in the northwest, lower in the northeast; urban areas had higher OP. Most sites showed peak PM10 and OP in winter, lowest in summer. Traffic, biomass burning, and coal combustion were major OP contributors.
Melanie Coldewey-Egbers, Diego G. Loyola R., Barry Latter, Richard Siddans, Brian Kerridge, Daan Hubert, Michel van Roozendael, and Michael Eisinger
Atmos. Meas. Tech., 18, 5485–5505, https://doi.org/10.5194/amt-18-5485-2025, https://doi.org/10.5194/amt-18-5485-2025, 2025
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The Global Ozone Monitoring Experiment (GOME)-type Ozone Profile Essential Climate Variable (GOP-ECV) data record provides monthly mean ozone profiles with global coverage from 1995 to 2021 at a spatial resolution of 5° × 5°. Measurements from five nadir-viewing satellite sensors are first harmonized and then merged into a coherent record. The long-term stability of the data record is further improved through scaling the profiles using the GOME-type Total Ozone Essential Climate Variable (GTO-ECV) data record as a reference.
Nasrin Mostafavi Pak, Jonas Hachmeister, Markus Rettinger, Matthias Buschmann, Nicholas M. Deutscher, David W. T. Griffith, Laura T. Iraci, Xin Lan, Erin McGee, Isamu Morino, Dave Pollard, Coleen M. Roehl, Kimberly Strong, Rigel Kivi, and Paul Wennberg
EGUsphere, https://doi.org/10.5194/egusphere-2025-4080, https://doi.org/10.5194/egusphere-2025-4080, 2025
This preprint is open for discussion and under review for Biogeosciences (BG).
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We studied how carbon dioxide (CO2) levels change each year using long-term measurements from twelve sites worldwide. Average growth rates from 2010 to 2024 were about 2.4 ppm/year, with notable year-to-year and regional differences. Natural climate patterns influenced these changes, while temporary shifts in human emissions, such as during COVID‑19, had modest local effects. Monitoring CO2 growth across regions helps track emissions and assess mitigation efforts.
Isolde Glissenaar, Klaas Folkert Boersma, Isidora Anglou, Pieter Rijsdijk, Tijl Verhoelst, Steven Compernolle, Gaia Pinardi, Jean-Christopher Lambert, Michel Van Roozendael, and Henk Eskes
Earth Syst. Sci. Data, 17, 4627–4650, https://doi.org/10.5194/essd-17-4627-2025, https://doi.org/10.5194/essd-17-4627-2025, 2025
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We developed a new global dataset of nitrogen dioxide (NO2) levels in the lower atmosphere, using data from TROPOMI for 2018–2021. This dataset offers improved accuracy and detail compared to earlier versions, meeting high international standards for climate data. By refining how measurement errors are calculated and reduced over time and space, we provide clearer insights into pollution patterns. This work supports better air quality monitoring and informs actions to address pollution globally.
Miriam Latsch, Andreas Richter, John P. Burrows, and Hartmut Bösch
Atmos. Meas. Tech., 18, 4373–4395, https://doi.org/10.5194/amt-18-4373-2025, https://doi.org/10.5194/amt-18-4373-2025, 2025
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This study presents our advanced methods to qualitatively detect ship-related nitrogen dioxide (NO2) signals in TROPOMI satellite data. By applying filtering techniques, we identify numerous global shipping routes, including previously undetected ones, as well as emissions from offshore platforms. Additionally, we compare the filtered satellite data with high-pass-filtered CAMS global model data to estimate the differences between observed and modeled NO2 emissions.
Lara Noppen, Lieven Clarisse, Frederik Tack, Thomas Ruhtz, Martin Van Damme, Michel Van Roozendael, Dirk Schuettemeyer, and Pierre Coheur
Atmos. Meas. Tech., 18, 4183–4205, https://doi.org/10.5194/amt-18-4183-2025, https://doi.org/10.5194/amt-18-4183-2025, 2025
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Current infrared satellite sounders offer high spectral but low spatial resolution, limiting their ability to quantify atmospheric ammonia (NH3) at small scales. Through simulations and analysis of real data, we show that NH3 can be measured effectively from spectra with reduced resolution, either in a contiguous spectral range or in select well-chosen bands. This approach opens possibilities for the development of smaller dedicated instruments for observing NH3 at high spatial resolution.
Roeland Van Malderen, Zhou Zang, Kai-Lan Chang, Robin Björklund, Owen R. Cooper, Jane Liu, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, Valérie Thouret, Pawel Wolff, Peter Effertz, Audrey Gaudel, David W. Tarasick, Herman G. J. Smit, Anne M. Thompson, Ryan M. Stauffer, Debra E. Kollonige, Deniz Poyraz, Gérard Ancellet, Marie-Renée De Backer, Matthias M. Frey, James W. Hannigan, José L. Hernandez, Bryan J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Isamu Morino, Glen McConville, Katrin Müller, Isao Murata, Justus Notholt, Ankie Piters, Maxime Prignon, Richard Querel, Vincenzo Rizi, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, and Ralf Sussmann
Atmos. Chem. Phys., 25, 9905–9935, https://doi.org/10.5194/acp-25-9905-2025, https://doi.org/10.5194/acp-25-9905-2025, 2025
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Tropospheric ozone is an important greenhouse gas and an air pollutant whose distribution and time variability are mainly governed by anthropogenic emissions and dynamics. In this paper, we assess regional trends of tropospheric ozone column amounts, based on two different approaches of merging or synthesizing ground-based observations and their trends within specific regions. Our findings clearly demonstrate regional trend differences but also consistently higher pre-COVID than post-COVID trends.
Huan Yu, Isabelle De Smedt, Nicolas Theys, Maarten Sneep, Pepijn Veefkind, and Michel Van Roozendael
Atmos. Meas. Tech., 18, 4131–4163, https://doi.org/10.5194/amt-18-4131-2025, https://doi.org/10.5194/amt-18-4131-2025, 2025
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We introduce a new cloud retrieval algorithm using the O2–O2 absorption band at 477 nm to generate harmonized cloud datasets from OMI and TROPOMI. The algorithm improves upon the OMI O2–O2 operational cloud algorithm in several aspects. The new approach improves consistency in cloud parameters and NO2 retrievals between two sensors.
Simone Pulimeno, Angelo Lupi, Vito Vitale, Claudia Frangipani, Carlos Toledano, Stelios Kazadzis, Natalia Kouremeti, Christoph Ritter, Sandra Graßl, Kerstin Stebel, Vitali Fioletov, Ihab Abboud, Sandra Blindheim, Lynn Ma, Norm O’Neill, Piotr Sobolewski, Pawan Gupta, Elena Lind, Thomas F. Eck, Antti Hyvärinen, Veijo Aaltonen, Rigel Kivi, Janae Csavina, Dmitry Kabanov, Sergey M. Sakerin, Olga R. Sidorova, Robert S. Stone, Hagen Telg, Laura Riihimaki, Raul R. Cordero, Martin Radenz, Ronny Engelmann, Michel Van Roozendal, Anatoli Chaikovsky, Philippe Goloub, Junji Hisamitsu, and Mauro Mazzola
EGUsphere, https://doi.org/10.5194/egusphere-2025-2527, https://doi.org/10.5194/egusphere-2025-2527, 2025
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This study analyzed aerosols optical properties over the Arctic and Antarctic to measure them even during long periods of darkness. It found that pollution in the Arctic is decreasing, likely due to European emission regulations, while wildfires are becoming a more important source of particles. In Antarctica, particle levels are higher near the coast than inland, and vary by season. These results help us better understand how air pollution and climate are changing at the Earth’s poles.
Chenghao Xu, Jintai Lin, Hao Kong, Junli Jin, Lulu Chen, and Xiaobin Xu
Atmos. Chem. Phys., 25, 9545–9560, https://doi.org/10.5194/acp-25-9545-2025, https://doi.org/10.5194/acp-25-9545-2025, 2025
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We observed a strong increase in deseasonalized ozone at urban stations in the Tibetan Plateau from 2015 to 2019, far exceeding the trend at the baseline station Waliguan and the Tibetan Plateau average trend of four tropospheric ozone products. By combining multiple datasets and modeling approaches, we identified the main contributing factors as more frequent transport passing through the lower layers of high-emission regions and the increase in local and non-local anthropogenic emissions.
Lorenzo Fabris, Nicolas Theys, Lieven Clarisse, Bruno Franco, Jonas Vlietinck, Huan Yu, Hugues Brenot, Thomas Danckaert, Pascal Hedelt, and Michel Van Roozendael
EGUsphere, https://doi.org/10.5194/egusphere-2025-4026, https://doi.org/10.5194/egusphere-2025-4026, 2025
This preprint is open for discussion and under review for Atmospheric Measurement Techniques (AMT).
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In this study, we developed an improved algorithm to retrieve the plume height and column density of sulfur dioxide emitted by volcanoes using data from the spectral band 2 of TROPOMI (S-5P). We tested its sensitivity to various conditions and applied it to real volcanic eruptions. Overall, our approach shows high precision, accuracy and sensitivity, and the results are consistent with other satellite measurements.
Maja Rüth, Nicole Bobrowski, Ellen Bräutigam, Alexander Nies, Jonas Kuhn, Thorsten Hoffmann, Niklas Karbach, Bastien Geil, Ralph Kleinschek, Stefan Schmitt, and Ulrich Platt
EGUsphere, https://doi.org/10.5194/egusphere-2025-3976, https://doi.org/10.5194/egusphere-2025-3976, 2025
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UV absorption and electrochemical O3 sensor measurement techniques suffer from interferences, especially from SO2, which is a main constituent of volcanic plumes. Only chemiluminescence (CL) O3 monitors have no known interference with SO2. However, modern CL O3 monitors are impractical because they are heavy and bulky. We developed and applied a lightweight version of a CL O3 instrument (l.5 kg, shoebox size) and present the result of those drone based CL O3 measurements.
Janek Gödeke, Andreas Richter, Kezia Lange, Peter Maaß, Hyunkee Hong, Hanlim Lee, and Junsung Park
Atmos. Meas. Tech., 18, 3747–3779, https://doi.org/10.5194/amt-18-3747-2025, https://doi.org/10.5194/amt-18-3747-2025, 2025
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The Korean Geostationary Environmental Monitoring Spectrometer (GEMS) monitors trace gases over Asia, e.g., NO2. GEMS provides hourly data, improving the time resolution compared to the daily overpasses by other satellites. For the prediction of hourly surface NO2 over South Korea from GEMS observations and meteorological data, this study shows that machine learning models benefit from this higher time resolution. This is achieved by using observations from previous hours as additional inputs.
Christos Spyrou, Ilias Fountoulakis, Stavros Solomos, Nikolaos Papadimitriou, Alkiviadis Bais, Julian Groebner, Daniela Meloni, and Christos Zerefos
EGUsphere, https://doi.org/10.5194/egusphere-2025-3570, https://doi.org/10.5194/egusphere-2025-3570, 2025
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Dust particles originating from desert areas of the planet have significant radiative impacts on the ground and atmospheric column. The magnitude of the dust radiative effect is dependent on their optical properties and mineralogical content. Therefore, we upgrade the METAL-WRF model to incorporate the direct radiative impact of the minerals in dust. The capabilities of the model to simulate the chemical composition and associated impacts is significantly improved.
Gaia Pinardi, Martina M. Friedrich, Corinne Vigouroux, Bavo Langerock, Isabelle De Smedt, Caroline Fayt, Christian Hermans, Steffen Beirle, Thomas Wagner, Minqiang Zhou, Ting Wang, Pucai Wang, Martine De Mazière, and Michel Van Roozendael
EGUsphere, https://doi.org/10.5194/egusphere-2025-3320, https://doi.org/10.5194/egusphere-2025-3320, 2025
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MultiAXis Differential Optical Absorption Spectroscopy, direct sun DOAS, and Fourier Transform InfraRed are key for formaldehyde satellite validation. We show a -20% bias for MAX-DOAS vertical column data versus direct sun UV and IR measurement at Xianghe, China. Adjustments for vertical sensitivities and a priori profiles reduce differences to less than 2.5%. Using chemical transport models as a priori further decreases the bias, indicating possible improvements for current MAX-DOAS retrievals.
Suvarna Fadnavis, Yasin Elshorbany, Jerald Ziemke, Brice Barret, Alexandru Rap, P. R. Satheesh Chandran, Richard J. Pope, Vijay Sagar, Domenico Taraborrelli, Eric Le Flochmoen, Juan Cuesta, Catherine Wespes, Folkert Boersma, Isolde Glissenaar, Isabelle De Smedt, Michel Van Roozendael, Hervé Petetin, and Isidora Anglou
Atmos. Chem. Phys., 25, 8229–8254, https://doi.org/10.5194/acp-25-8229-2025, https://doi.org/10.5194/acp-25-8229-2025, 2025
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Satellites and model simulations show enhancement in tropospheric ozone, which is highly impacted by human-produced nitrous oxides compared to volatile organic compounds. The increased amount of ozone enhances ozone radiative forcing. The ozone enhancement and associated radiative forcing are the highest over South and East Asia. The emissions of nitrous oxides show a higher influence on shifting ozone photochemical regimes than volatile organic compounds.
Bianca Lauster, Udo Frieß, Jan-Marcus Nasse, Ulrich Platt, and Thomas Wagner
Atmos. Meas. Tech., 18, 3393–3405, https://doi.org/10.5194/amt-18-3393-2025, https://doi.org/10.5194/amt-18-3393-2025, 2025
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Remote sensing measurements of scattered sunlight use the atmospheric absorption of O2–O2 (or O4) to derive cloud and aerosol properties. However, inconsistencies between measurements and radiative transfer simulations were found recently, and, so far, there has been no consensus on how to deal with these appropriately. In this study, long-term long-path differential optical absorption spectroscopy (LP-DOAS) observations were analysed and very good agreement with laboratory measurements was found.
Aki Tsuruta, Akihiko Kuze, Kei Shiomi, Fumie Kataoka, Nobuhiro Kikuchi, Tuula Aalto, Leif Backman, Ella Kivimäki, Maria K. Tenkanen, Kathryn McKain, Omaira E. García, Frank Hase, Rigel Kivi, Isamu Morino, Hirofumi Ohyama, David F. Pollard, Mahesh K. Sha, Kimberly Strong, Ralf Sussmann, Yao Te, Voltaire A. Velazco, Mihalis Vrekoussis, Thorsten Warneke, Minqiang Zhou, and Hiroshi Suto
Atmos. Chem. Phys., 25, 7829–7862, https://doi.org/10.5194/acp-25-7829-2025, https://doi.org/10.5194/acp-25-7829-2025, 2025
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Satellite data bring invaluable information about greenhouse gas emissions globally. We found that a new type of data from the Greenhouse Gas Observing Satellite (GOSAT), which contains information about methane in the lowest layer of Earth's atmosphere, could provide reliable estimates of recent methane emissions when combined with atmospheric modelling. Therefore, the use of such data is encouraged to improve emission quantification methods and advance our understanding of methane cycles.
Roeland Van Malderen, Anne M. Thompson, Debra E. Kollonige, Ryan M. Stauffer, Herman G. J. Smit, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, Valérie Thouret, Pawel Wolff, Peter Effertz, David W. Tarasick, Deniz Poyraz, Gérard Ancellet, Marie-Renée De Backer, Stéphanie Evan, Victoria Flood, Matthias M. Frey, James W. Hannigan, José L. Hernandez, Marco Iarlori, Bryan J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Glen McConville, Katrin Müller, Tomoo Nagahama, Justus Notholt, Ankie Piters, Natalia Prats, Richard Querel, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, and Ralf Sussmann
Atmos. Chem. Phys., 25, 7187–7225, https://doi.org/10.5194/acp-25-7187-2025, https://doi.org/10.5194/acp-25-7187-2025, 2025
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Tropospheric ozone is an important greenhouse gas and is an air pollutant. The time variability of tropospheric ozone is mainly driven by anthropogenic emissions. In this paper, we study the distribution and time variability of ozone from harmonized ground-based observations from five different measurement techniques. Our findings provide clear standard references for atmospheric models and evolving tropospheric ozone satellite data for the 2000–2022 period.
Matthias Kohl, Christoph Brühl, Jennifer Schallock, Holger Tost, Patrick Jöckel, Adrian Jost, Steffen Beirle, Michael Höpfner, and Andrea Pozzer
Geosci. Model Dev., 18, 3985–4007, https://doi.org/10.5194/gmd-18-3985-2025, https://doi.org/10.5194/gmd-18-3985-2025, 2025
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SO2 from explosive volcanic eruptions reaching the stratosphere can oxidize and form sulfur aerosols, potentially persisting for several years. We developed a new submodel, Explosive Volcanic ERuptions (EVER), that seamlessly includes stratospheric volcanic SO2 emissions in global numerical simulations based on a novel standard historical model setup, successfully evaluated with satellite observations. Sensitivity studies on the Nabro eruption in 2011 evaluate different emission methods.
Ramina Alwarda, Kristof Bognar, Xiaoyi Zhao, Vitali Fioletov, Jonathan Davies, Sum Chi Lee, Debora Griffin, Alexandru Lupu, Udo Frieß, Alexander Cede, Yushan Su, and Kimberly Strong
Atmos. Meas. Tech., 18, 2397–2423, https://doi.org/10.5194/amt-18-2397-2025, https://doi.org/10.5194/amt-18-2397-2025, 2025
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Nitrogen dioxide (NO2) is a pollutant with a short lifetime and large variability, but there are limited measurements of its distribution in the lower atmosphere. We present a new 3-year dataset of NO2 vertical profiles in Toronto, Canada, and evaluate it using NO2 from satellite and surface monitoring networks and simulations by an air quality forecast model. We quantify and explain the differences among the datasets to provide information that can be used to understand NO2 variability.
Huanhuan Yan, Andreas Richter, Xingying Zhang, Anja Schönhardt, and Thomas Visarius
EGUsphere, https://doi.org/10.5194/egusphere-2025-2177, https://doi.org/10.5194/egusphere-2025-2177, 2025
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The Ozone Monitoring Suite (OMS) launched in August 2023 is a new Chinese hyperspectral UV-VIS instrument. This study used the OMS measurements and Differential Optical Absorption Spectroscopy (DOAS) inversion to for the first time retrieve global SO2 columns from OMS. The results show that the OMS SO2 retrievals exhibit good stability over clean oceanic regions, successfully capture volcanic SO2 plumes, and effectively detect the elevated SO2 columns from anthropogenic emissions.
Yuhang Zhang, Huan Yu, Isabelle De Smedt, Jintai Lin, Nicolas Theys, Michel Van Roozendael, Gaia Pinardi, Steven Compernolle, Ruijing Ni, Fangxuan Ren, Sijie Wang, Lulu Chen, Jos Van Geffen, Mengyao Liu, Alexander M. Cede, Martin Tiefengraber, Alexis Merlaud, Martina M. Friedrich, Andreas Richter, Ankie Piters, Vinod Kumar, Vinayak Sinha, Thomas Wagner, Yongjoo Choi, Hisahiro Takashima, Yugo Kanaya, Hitoshi Irie, Robert Spurr, Wenfu Sun, and Lorenzo Fabris
Atmos. Meas. Tech., 18, 1561–1589, https://doi.org/10.5194/amt-18-1561-2025, https://doi.org/10.5194/amt-18-1561-2025, 2025
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We developed an advanced algorithm for global retrieval of TROPOspheric Monitoring Instrument (TROPOMI) HCHO and NO2 vertical column densities with much improved consistency. Sensitivity tests demonstrate the complexity and nonlinear interactions of auxiliary parameters in the air mass factor calculation. An improved agreement is found with measurements from a global ground-based instrument network. The scientific retrieval provides a useful source of information for studies combining HCHO and NO2.
Renzhi Hu, Guoxian Zhang, Haotian Cai, Jingyi Guo, Keding Lu, Xin Li, Shengrong Lou, Zhaofeng Tan, Changjin Hu, Pinhua Xie, and Wenqing Liu
Atmos. Chem. Phys., 25, 3011–3028, https://doi.org/10.5194/acp-25-3011-2025, https://doi.org/10.5194/acp-25-3011-2025, 2025
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A full suite of radical measurements (OH, HO2, RO2, and kOH) was established to accurately elucidate the limitations of oxidation in a chemically complex atmosphere. Sensitivity tests revealed that the incorporation of complex processes enabled a balance in both radical concentrations and coordinate ratios, effectively addressing the deficiency in the ozone generation mechanism. The full-chain radical detection bridged the gap between the photochemistry and the intensive oxidation level.
Jonas Hachmeister, Debra Wunch, Erin McGee, Kimberly Strong, Rigel Kivi, Justus Notholt, Thorsten Warneke, and Matthias Buschmann
EGUsphere, https://doi.org/10.5194/egusphere-2024-4055, https://doi.org/10.5194/egusphere-2024-4055, 2025
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Methane measurements from the Total Carbon Column Observing Network (TCCON) are important for climate research, especially in the Arctic where few measurements are available. We show that during early spring systematic errors are present in these data that are correlated to the presence of the polar vortex. These errors occur due to the usage of wrong methane prior shapes in the retrieval and can be alleviated by modifying the prior shape accordingly.
Jiangman Xu, Ang Li, Zhaokun Hu, Hairong Zhang, and Min Qin
Atmos. Meas. Tech., 18, 865–879, https://doi.org/10.5194/amt-18-865-2025, https://doi.org/10.5194/amt-18-865-2025, 2025
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This article introduces an experimental system for rapidly acquiring trace gas profiles using multi-channel spectroscopy, significantly enhancing the time resolution of spectral collection. The fast synchronous multi-axis differential optical absorption spectroscopy (FS MAX-DOAS) successfully obtains gas profiles. This work can also be integrated with mobile platforms for navigational observation research, which is crucial for making mobile MAX-DOAS profile measurements.
Amir H. Souri, Gonzalo González Abad, Glenn M. Wolfe, Tijl Verhoelst, Corinne Vigouroux, Gaia Pinardi, Steven Compernolle, Bavo Langerock, Bryan N. Duncan, and Matthew S. Johnson
Atmos. Chem. Phys., 25, 2061–2086, https://doi.org/10.5194/acp-25-2061-2025, https://doi.org/10.5194/acp-25-2061-2025, 2025
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We establish a simple yet robust relationship between ozone production rates and geophysical parameters obtained from several intensive atmospheric composition campaigns. We show that satellite remote sensing data can effectively constrain these parameters, enabling us to produce the first global maps of ozone production rates with unprecedented resolution.
Jan-Lukas Tirpitz, Santo Fedele Colosimo, Nathaniel Brockway, Robert Spurr, Matt Christi, Samuel Hall, Kirk Ullmann, Johnathan Hair, Taylor Shingler, Rodney Weber, Jack Dibb, Richard Moore, Elizabeth Wiggins, Vijay Natraj, Nicolas Theys, and Jochen Stutz
Atmos. Chem. Phys., 25, 1989–2015, https://doi.org/10.5194/acp-25-1989-2025, https://doi.org/10.5194/acp-25-1989-2025, 2025
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We combine plume composition data from the 2019 NASA FIREX-AQ campaign with state-of-the-art radiative transfer modeling techniques to calculate distributions of actinic flux and photolysis frequencies in a wildfire plume. Excellent agreement of the model and observations demonstrates the applicability of this approach to constrain photochemistry in such plumes. We identify limiting factors for the modeling accuracy and discuss spatial and spectral features of the distributions.
Kelley C. Wells, Dylan B. Millet, Jared F. Brewer, Vivienne H. Payne, Karen E. Cady-Pereira, Rick Pernak, Susan Kulawik, Corinne Vigouroux, Nicholas Jones, Emmanuel Mahieu, Maria Makarova, Tomoo Nagahama, Ivan Ortega, Mathias Palm, Kimberly Strong, Matthias Schneider, Dan Smale, Ralf Sussmann, and Minqiang Zhou
Atmos. Meas. Tech., 18, 695–716, https://doi.org/10.5194/amt-18-695-2025, https://doi.org/10.5194/amt-18-695-2025, 2025
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Atmospheric volatile organic compounds (VOCs) affect both air quality and climate. Satellite measurements can help us to assess and predict their global impacts. We present new decadal (2012–2023) measurements of four key VOCs – methanol, ethene, ethyne, and hydrogen cyanide (HCN) – from the Cross-track Infrared Sounder. The measurements reflect emissions from major forests, wildfires, and industry and provide new information to advance understanding of these sources and their changes over time.
Chengxin Zhang, Xinhan Niu, Hongyu Wu, Zhipeng Ding, Ka Lok Chan, Jhoon Kim, Thomas Wagner, and Cheng Liu
Atmos. Chem. Phys., 25, 759–770, https://doi.org/10.5194/acp-25-759-2025, https://doi.org/10.5194/acp-25-759-2025, 2025
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This research utilizes hourly air pollution observations from the world’s first geostationary satellite to develop a spatiotemporal neural network model for full-coverage surface NO2 pollution prediction over the next 24 hours, achieving outstanding forecasting performance and efficacy. These results highlight the profound impact of geostationary satellite observations in advancing air quality forecasting models, thereby contributing to future models for health exposure to air pollution.
Vitali Fioletov, Chris A. McLinden, Debora Griffin, Xiaoyi Zhao, and Henk Eskes
Atmos. Chem. Phys., 25, 575–596, https://doi.org/10.5194/acp-25-575-2025, https://doi.org/10.5194/acp-25-575-2025, 2025
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Satellite data were used to estimate urban per capita emissions for 261 major cities worldwide. Three components in tropospheric NO2 data (background NO2, NO2 from urban sources, and NO2 from industrial point sources) were isolated, and then each of these components was analyzed separately. The largest per capita emissions were found in the Middle East and the smallest in India and southern Africa. Urban weekend emissions are 20 %–50 % less than workday emissions for all regions except China.
Seunghwan Seo, Si-Wan Kim, Kyoung-Min Kim, Andreas Richter, Kezia Lange, John P. Burrows, Junsung Park, Hyunkee Hong, Hanlim Lee, Ukkyo Jeong, Jung-Hun Woo, and Jhoon Kim
Atmos. Meas. Tech., 18, 115–128, https://doi.org/10.5194/amt-18-115-2025, https://doi.org/10.5194/amt-18-115-2025, 2025
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Over the Seoul metropolitan area, tropospheric NO2 vertical column densities from the Geostationary Environment Monitoring Spectrometer show distinct seasonal features. Also, varying a priori data have substantial impacts on the observed NO2 columns. The a priori data from different chemical transport models resulted in differences of up to −18.3 %. Notably, diurnal patterns of observed NO2 columns are similar for all datasets, although their a priori data exhibit contrasting diurnal patterns.
Fanhao Meng, Baobin Han, Min Qin, Wu Fang, Ke Tang, Dou Shao, Zhitang Liao, Jun Duan, Yan Feng, Yong Huang, Ting Ni, and Pinhua Xie
Atmos. Chem. Phys., 24, 14191–14208, https://doi.org/10.5194/acp-24-14191-2024, https://doi.org/10.5194/acp-24-14191-2024, 2024
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Comprehensive observations of HONO and NOx fluxes were conducted over paddy fields in the Huaihe River Basin. Consecutive peaks in HONO and NO fluxes suggest a potentially enhanced release of HONO and NO due to soil tillage, whereas waterlogged soil may inhibit microbial nitrification processes following irrigation. Notably, biological processes and light-driven NO2 reactions at the surface may serve as sources of HONO and influence the local HONO budget during rotary tillage.
Xiaoyi Zhao, Vitali Fioletov, Debora Griffin, Chris McLinden, Ralf Staebler, Cristian Mihele, Kevin Strawbridge, Jonathan Davies, Ihab Abboud, Sum Chi Lee, Alexander Cede, Martin Tiefengraber, and Robert Swap
Atmos. Meas. Tech., 17, 6889–6912, https://doi.org/10.5194/amt-17-6889-2024, https://doi.org/10.5194/amt-17-6889-2024, 2024
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This study explores differences between remote sensing and in situ instruments in terms of their vertical, horizontal, and temporal sampling differences. Understanding and resolving these differences are critical for future analyses linking satellite, ground-based remote sensing, and in situ observations in air quality monitoring. It shows that the meteorological conditions (wind directions, speed, and boundary layer conditions) will strongly affect the agreement between the two measurements.
Leon Kuhn, Steffen Beirle, Sergey Osipov, Andrea Pozzer, and Thomas Wagner
Atmos. Meas. Tech., 17, 6485–6516, https://doi.org/10.5194/amt-17-6485-2024, https://doi.org/10.5194/amt-17-6485-2024, 2024
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This paper presents a new machine learning model that allows us to compute NO2 concentration profiles from satellite observations. A neural network was trained on synthetic data from the regional chemistry and transport model WRF-Chem. This is the first model of its kind. We present a thorough model validation study, covering various seasons and regions of the world.
Eunjo S. Ha, Rokjin J. Park, Hyeong-Ahn Kwon, Gitaek T. Lee, Sieun D. Lee, Seunga Shin, Dong-Won Lee, Hyunkee Hong, Christophe Lerot, Isabelle De Smedt, Thomas Danckaert, Francois Hendrick, and Hitoshi Irie
Atmos. Meas. Tech., 17, 6369–6384, https://doi.org/10.5194/amt-17-6369-2024, https://doi.org/10.5194/amt-17-6369-2024, 2024
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In this study, we evaluated the GEMS glyoxal products by comparing them with TROPOMI and MAX-DOAS measurements. GEMS and TROPOMI VCDs present similar spatial distributions. Monthly variations in GEMS VCDs and TROPOMI and MAX-DOAS VCDs differ in northeastern Asia, which we attributed to a polluted reference spectrum and high NO2 concentrations. GEMS glyoxal products with unparalleled temporal resolution would enrich our understanding of VOC emissions and diurnal variation.
Kezia Lange, Andreas Richter, Tim Bösch, Bianca Zilker, Miriam Latsch, Lisa K. Behrens, Chisom M. Okafor, Hartmut Bösch, John P. Burrows, Alexis Merlaud, Gaia Pinardi, Caroline Fayt, Martina M. Friedrich, Ermioni Dimitropoulou, Michel Van Roozendael, Steffen Ziegler, Simona Ripperger-Lukosiunaite, Leon Kuhn, Bianca Lauster, Thomas Wagner, Hyunkee Hong, Donghee Kim, Lim-Seok Chang, Kangho Bae, Chang-Keun Song, Jong-Uk Park, and Hanlim Lee
Atmos. Meas. Tech., 17, 6315–6344, https://doi.org/10.5194/amt-17-6315-2024, https://doi.org/10.5194/amt-17-6315-2024, 2024
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Instruments for air quality observations on geostationary satellites provide multiple observations per day and allow for the analysis of the diurnal variation of important air pollutants such as nitrogen dioxide (NO2) over large areas. The South Korean instrument GEMS, launched in February 2020, is the first instrument in geostationary orbit and covers a large part of Asia. Our investigations show the observed diurnal evolution of NO2 at different measurement sites.
Theodore K. Koenig, François Hendrick, Douglas Kinnison, Christopher F. Lee, Michel Van Roozendael, and Rainer Volkamer
Atmos. Meas. Tech., 17, 5911–5934, https://doi.org/10.5194/amt-17-5911-2024, https://doi.org/10.5194/amt-17-5911-2024, 2024
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Atmospheric bromine destroys ozone, impacts oxidation capacity, and oxidizes mercury into its toxic form. We constrain bromine by remote sensing of BrO from a mountaintop. Previous measurements retrieved two to three pieces of information vertically; we apply new methods to get five and a half vertically and two more in time. We compare with aircraft measurements to validate the methods and look at variations in BrO over the Pacific.
Tim Trent, Marc Schröder, Shu-Peng Ho, Steffen Beirle, Ralf Bennartz, Eva Borbas, Christian Borger, Helene Brogniez, Xavier Calbet, Elisa Castelli, Gilbert P. Compo, Wesley Ebisuzaki, Ulrike Falk, Frank Fell, John Forsythe, Hans Hersbach, Misako Kachi, Shinya Kobayashi, Robert E. Kursinski, Diego Loyola, Zhengzao Luo, Johannes K. Nielsen, Enzo Papandrea, Laurence Picon, Rene Preusker, Anthony Reale, Lei Shi, Laura Slivinski, Joao Teixeira, Tom Vonder Haar, and Thomas Wagner
Atmos. Chem. Phys., 24, 9667–9695, https://doi.org/10.5194/acp-24-9667-2024, https://doi.org/10.5194/acp-24-9667-2024, 2024
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In a warmer future, water vapour will spend more time in the atmosphere, changing global rainfall patterns. In this study, we analysed the performance of 28 water vapour records between 1988 and 2014. We find sensitivity to surface warming generally outside expected ranges, attributed to breakpoints in individual record trends and differing representations of climate variability. The implication is that longer records are required for high confidence in assessing climate trends.
Henk Eskes, Athanasios Tsikerdekis, Melanie Ades, Mihai Alexe, Anna Carlin Benedictow, Yasmine Bennouna, Lewis Blake, Idir Bouarar, Simon Chabrillat, Richard Engelen, Quentin Errera, Johannes Flemming, Sebastien Garrigues, Jan Griesfeller, Vincent Huijnen, Luka Ilić, Antje Inness, John Kapsomenakis, Zak Kipling, Bavo Langerock, Augustin Mortier, Mark Parrington, Isabelle Pison, Mikko Pitkänen, Samuel Remy, Andreas Richter, Anja Schoenhardt, Michael Schulz, Valerie Thouret, Thorsten Warneke, Christos Zerefos, and Vincent-Henri Peuch
Atmos. Chem. Phys., 24, 9475–9514, https://doi.org/10.5194/acp-24-9475-2024, https://doi.org/10.5194/acp-24-9475-2024, 2024
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The Copernicus Atmosphere Monitoring Service (CAMS) provides global analyses and forecasts of aerosols and trace gases in the atmosphere. On 27 June 2023 a major upgrade, Cy48R1, became operational. Comparisons with in situ, surface remote sensing, aircraft, and balloon and satellite observations show that the new CAMS system is a significant improvement. The results quantify the skill of CAMS to forecast impactful events, such as wildfires, dust storms and air pollution peaks.
Zen Mariani, Sara M. Morris, Taneil Uttal, Elena Akish, Robert Crawford, Laura Huang, Jonathan Day, Johanna Tjernström, Øystein Godøy, Lara Ferrighi, Leslie M. Hartten, Jareth Holt, Christopher J. Cox, Ewan O'Connor, Roberta Pirazzini, Marion Maturilli, Giri Prakash, James Mather, Kimberly Strong, Pierre Fogal, Vasily Kustov, Gunilla Svensson, Michael Gallagher, and Brian Vasel
Earth Syst. Sci. Data, 16, 3083–3124, https://doi.org/10.5194/essd-16-3083-2024, https://doi.org/10.5194/essd-16-3083-2024, 2024
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During the Year of Polar Prediction (YOPP), we increased measurements in the polar regions and have made dedicated efforts to centralize and standardize all of the different types of datasets that have been collected to facilitate user uptake and model–observation comparisons. This paper is an overview of those efforts and a description of the novel standardized Merged Observation Data Files (MODFs), including a description of the sites, data format, and instruments.
Matías Osorio, Alejandro Agesta, Tim Bösch, Nicolás Casaballe, Andreas Richter, Leonardo M. A. Alvarado, and Erna Frins
Atmos. Chem. Phys., 24, 7447–7465, https://doi.org/10.5194/acp-24-7447-2024, https://doi.org/10.5194/acp-24-7447-2024, 2024
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This study concerns the detection and quantification of long-transport emissions of a biomass burning event, which represents a major source of air pollutants, due to the release of large amounts of aerosols and chemical species into the atmosphere. The quantification was done using ground-based observations (which play an important role in assessing the abundance of trace gases and aerosols) over Montevideo (Uruguay) and using satellite observations.
Steffen Beirle and Thomas Wagner
Atmos. Meas. Tech., 17, 3439–3453, https://doi.org/10.5194/amt-17-3439-2024, https://doi.org/10.5194/amt-17-3439-2024, 2024
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We present a new method for estimating emissions and lifetimes for nitrogen oxides emitted from large cities by using satellite NO2 observations combined with wind fields. The estimate is based on the simultaneous evaluation of the downwind plumes for opposing wind directions. This allows us to derive seasonal mean emissions and lifetimes for 100 cities around the globe.
Xin Yang, Kimberly Strong, Alison S. Criscitiello, Marta Santos-Garcia, Kristof Bognar, Xiaoyi Zhao, Pierre Fogal, Kaley A. Walker, Sara M. Morris, and Peter Effertz
Atmos. Chem. Phys., 24, 5863–5886, https://doi.org/10.5194/acp-24-5863-2024, https://doi.org/10.5194/acp-24-5863-2024, 2024
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This study uses snow samples collected from a Canadian high Arctic site, Eureka, to demonstrate that surface snow in early spring is a net sink of atmospheric bromine and nitrogen. Surface snow bromide and nitrate are significantly correlated, indicating the oxidation of reactive nitrogen is accelerated by reactive bromine. In addition, we show evidence that snow photochemical release of reactive bromine is very weak, and its emission flux is much smaller than the deposition flux of bromide.
Heesung Chong, Gonzalo González Abad, Caroline R. Nowlan, Christopher Chan Miller, Alfonso Saiz-Lopez, Rafael P. Fernandez, Hyeong-Ahn Kwon, Zolal Ayazpour, Huiqun Wang, Amir H. Souri, Xiong Liu, Kelly Chance, Ewan O'Sullivan, Jhoon Kim, Ja-Ho Koo, William R. Simpson, François Hendrick, Richard Querel, Glen Jaross, Colin Seftor, and Raid M. Suleiman
Atmos. Meas. Tech., 17, 2873–2916, https://doi.org/10.5194/amt-17-2873-2024, https://doi.org/10.5194/amt-17-2873-2024, 2024
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We present a new bromine monoxide (BrO) product derived using radiances measured from OMPS-NM on board the Suomi-NPP satellite. This product provides nearly a decade of global stratospheric and tropospheric column retrievals, a feature that is currently rare in publicly accessible datasets. Both stratospheric and tropospheric columns from OMPS-NM demonstrate robust performance, exhibiting good agreement with ground-based observations collected at three stations (Lauder, Utqiagvik, and Harestua).
Joshua L. Laughner, Geoffrey C. Toon, Joseph Mendonca, Christof Petri, Sébastien Roche, Debra Wunch, Jean-Francois Blavier, David W. T. Griffith, Pauli Heikkinen, Ralph F. Keeling, Matthäus Kiel, Rigel Kivi, Coleen M. Roehl, Britton B. Stephens, Bianca C. Baier, Huilin Chen, Yonghoon Choi, Nicholas M. Deutscher, Joshua P. DiGangi, Jochen Gross, Benedikt Herkommer, Pascal Jeseck, Thomas Laemmel, Xin Lan, Erin McGee, Kathryn McKain, John Miller, Isamu Morino, Justus Notholt, Hirofumi Ohyama, David F. Pollard, Markus Rettinger, Haris Riris, Constantina Rousogenous, Mahesh Kumar Sha, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Yao Té, Voltaire A. Velazco, Steven C. Wofsy, Minqiang Zhou, and Paul O. Wennberg
Earth Syst. Sci. Data, 16, 2197–2260, https://doi.org/10.5194/essd-16-2197-2024, https://doi.org/10.5194/essd-16-2197-2024, 2024
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This paper describes a new version, called GGG2020, of a data set containing column-integrated observations of greenhouse and related gases (including CO2, CH4, CO, and N2O) made by ground stations located around the world. Compared to the previous version (GGG2014), improvements have been made toward site-to-site consistency. This data set plays a key role in validating space-based greenhouse gas observations and in understanding the carbon cycle.
Gitaek T. Lee, Rokjin J. Park, Hyeong-Ahn Kwon, Eunjo S. Ha, Sieun D. Lee, Seunga Shin, Myoung-Hwan Ahn, Mina Kang, Yong-Sang Choi, Gyuyeon Kim, Dong-Won Lee, Deok-Rae Kim, Hyunkee Hong, Bavo Langerock, Corinne Vigouroux, Christophe Lerot, Francois Hendrick, Gaia Pinardi, Isabelle De Smedt, Michel Van Roozendael, Pucai Wang, Heesung Chong, Yeseul Cho, and Jhoon Kim
Atmos. Chem. Phys., 24, 4733–4749, https://doi.org/10.5194/acp-24-4733-2024, https://doi.org/10.5194/acp-24-4733-2024, 2024
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This study evaluates the Geostationary Environment Monitoring Spectrometer (GEMS) HCHO product by comparing its vertical column densities (VCDs) with those of TROPOMI and ground-based observations. Based on some sensitivity tests, obtaining radiance references under clear-sky conditions significantly improves HCHO retrieval quality. GEMS HCHO VCDs captured seasonal and diurnal variations well during the first year of observation, showing consistency with TROPOMI and ground-based observations.
Kyriakoula Papachristopoulou, Ilias Fountoulakis, Alkiviadis F. Bais, Basil E. Psiloglou, Nikolaos Papadimitriou, Ioannis-Panagiotis Raptis, Andreas Kazantzidis, Charalampos Kontoes, Maria Hatzaki, and Stelios Kazadzis
Atmos. Meas. Tech., 17, 1851–1877, https://doi.org/10.5194/amt-17-1851-2024, https://doi.org/10.5194/amt-17-1851-2024, 2024
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The upgraded systems SENSE2 and NextSENSE2 focus on improving the quality of solar nowcasting and forecasting. SENSE2 provides real-time estimates of solar irradiance across a wide region every 15 min. NextSENSE2 offers short-term forecasts of irradiance up to 3 h ahead. Evaluation with actual data showed that the instantaneous comparison yields the most discrepancies due to the uncertainties of cloud-related information and satellite versus ground-based spatial representativeness limitations.
Fei Liu, Steffen Beirle, Joanna Joiner, Sungyeon Choi, Zhining Tao, K. Emma Knowland, Steven J. Smith, Daniel Q. Tong, Siqi Ma, Zachary T. Fasnacht, and Thomas Wagner
Atmos. Chem. Phys., 24, 3717–3728, https://doi.org/10.5194/acp-24-3717-2024, https://doi.org/10.5194/acp-24-3717-2024, 2024
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Using satellite data, we developed a coupled method independent of the chemical transport model to map NOx emissions across US cities. After validating our technique with synthetic data, we charted NOx emissions from 2018–2021 in 39 cities. Our results closely matched EPA estimates but also highlighted some inconsistencies in both magnitude and spatial distribution. This research can help refine strategies for monitoring and managing air quality.
Jean-François Müller, Trissevgeni Stavrakou, Glenn-Michael Oomen, Beata Opacka, Isabelle De Smedt, Alex Guenther, Corinne Vigouroux, Bavo Langerock, Carlos Augusto Bauer Aquino, Michel Grutter, James Hannigan, Frank Hase, Rigel Kivi, Erik Lutsch, Emmanuel Mahieu, Maria Makarova, Jean-Marc Metzger, Isamu Morino, Isao Murata, Tomoo Nagahama, Justus Notholt, Ivan Ortega, Mathias Palm, Amelie Röhling, Wolfgang Stremme, Kimberly Strong, Ralf Sussmann, Yao Té, and Alan Fried
Atmos. Chem. Phys., 24, 2207–2237, https://doi.org/10.5194/acp-24-2207-2024, https://doi.org/10.5194/acp-24-2207-2024, 2024
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Formaldehyde observations from satellites can be used to constrain the emissions of volatile organic compounds, but those observations have biases. Using an atmospheric model, aircraft and ground-based remote sensing data, we quantify these biases, propose a correction to the data, and assess the consequence of this correction for the evaluation of emissions.
Weijun Quan, Zhenfa Wang, Lin Qiao, Xiangdong Zheng, Junli Jin, Yinruo Li, Xiaomei Yin, Zhiqiang Ma, and Martin Wild
Earth Syst. Sci. Data, 16, 961–983, https://doi.org/10.5194/essd-16-961-2024, https://doi.org/10.5194/essd-16-961-2024, 2024
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Radiation components play important roles in various fields such as the Earth’s surface radiation budget, ecosystem productivity, and human health. In this study, a dataset consisting of quality-assured daily data of nine radiation components is presented based on the in situ measurements at the Shangdianzi regional GAW station in China during 2013–2022. The dataset can be applied in the validation of satellite products and numerical models and investigation of atmospheric radiation.
Blanca Fuentes Andrade, Michael Buchwitz, Maximilian Reuter, Heinrich Bovensmann, Andreas Richter, Hartmut Boesch, and John P. Burrows
Atmos. Meas. Tech., 17, 1145–1173, https://doi.org/10.5194/amt-17-1145-2024, https://doi.org/10.5194/amt-17-1145-2024, 2024
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We developed a method to estimate CO2 emissions from localized sources, such as power plants, using satellite data and applied it to estimate CO2 emissions from the Bełchatów Power Station (Poland). As the detection of CO2 emission plumes from satellite data is difficult, we used observations of co-emitted NO2 to constrain the emission plume region. Our results agree with CO2 emission estimations based on the power-plant-generated power and emission factors.
Guoxian Zhang, Renzhi Hu, Pinhua Xie, Changjin Hu, Xiaoyan Liu, Liujun Zhong, Haotian Cai, Bo Zhu, Shiyong Xia, Xiaofeng Huang, Xin Li, and Wenqing Liu
Atmos. Chem. Phys., 24, 1825–1839, https://doi.org/10.5194/acp-24-1825-2024, https://doi.org/10.5194/acp-24-1825-2024, 2024
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Comprehensive observation of HOx radicals was conducted at a coastal site in the Pearl River Delta. Radical chemistry was influenced by different air masses in a time-dependent way. Land mass promotes a more active photochemical process, with daily averages of 7.1 × 106 and 5.2 × 108 cm−3 for OH and HO2 respectively. The rapid oxidation process was accompanied by a higher diurnal HONO concentration, which influences the ozone-sensitive system and eventually magnifies the background ozone.
Victoria A. Flood, Kimberly Strong, Cynthia H. Whaley, Kaley A. Walker, Thomas Blumenstock, James W. Hannigan, Johan Mellqvist, Justus Notholt, Mathias Palm, Amelie N. Röhling, Stephen Arnold, Stephen Beagley, Rong-You Chien, Jesper Christensen, Makoto Deushi, Srdjan Dobricic, Xinyi Dong, Joshua S. Fu, Michael Gauss, Wanmin Gong, Joakim Langner, Kathy S. Law, Louis Marelle, Tatsuo Onishi, Naga Oshima, David A. Plummer, Luca Pozzoli, Jean-Christophe Raut, Manu A. Thomas, Svetlana Tsyro, and Steven Turnock
Atmos. Chem. Phys., 24, 1079–1118, https://doi.org/10.5194/acp-24-1079-2024, https://doi.org/10.5194/acp-24-1079-2024, 2024
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It is important to understand the composition of the Arctic atmosphere and how it is changing. Atmospheric models provide simulations that can inform policy. This study examines simulations of CH4, CO, and O3 by 11 models. Model performance is assessed by comparing results matched in space and time to measurements from five high-latitude ground-based infrared spectrometers. This work finds that models generally underpredict the concentrations of these gases in the Arctic troposphere.
Thomas Wagner and Jānis Puķīte
Atmos. Meas. Tech., 17, 277–297, https://doi.org/10.5194/amt-17-277-2024, https://doi.org/10.5194/amt-17-277-2024, 2024
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We present a radiance calibration method based on the comparison of measurements and radiative transfer simulations of the zenith-scattered sun radiance during twilight. Cloud-free conditions are required. The method can be applied to measurements in the filed, and no laboratory measurements are required. The accuracy is estimated to range from about 4 % at 340 nm to about 10 % at 700 nm.
Glenn-Michael Oomen, Jean-François Müller, Trissevgeni Stavrakou, Isabelle De Smedt, Thomas Blumenstock, Rigel Kivi, Maria Makarova, Mathias Palm, Amelie Röhling, Yao Té, Corinne Vigouroux, Martina M. Friedrich, Udo Frieß, François Hendrick, Alexis Merlaud, Ankie Piters, Andreas Richter, Michel Van Roozendael, and Thomas Wagner
Atmos. Chem. Phys., 24, 449–474, https://doi.org/10.5194/acp-24-449-2024, https://doi.org/10.5194/acp-24-449-2024, 2024
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Natural emissions from vegetation have a profound impact on air quality for their role in the formation of harmful tropospheric ozone and organic aerosols, yet these emissions are highly uncertain. In this study, we quantify emissions of organic gases over Europe using high-quality satellite measurements of formaldehyde. These satellite observations suggest that emissions from vegetation are much higher than predicted by models, especially in southern Europe.
Leon Kuhn, Steffen Beirle, Vinod Kumar, Sergey Osipov, Andrea Pozzer, Tim Bösch, Rajesh Kumar, and Thomas Wagner
Atmos. Chem. Phys., 24, 185–217, https://doi.org/10.5194/acp-24-185-2024, https://doi.org/10.5194/acp-24-185-2024, 2024
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NO₂ is an important air pollutant. It was observed that the WRF-Chem model shows significant deviations in NO₂ abundance when compared to measurements. We use a 1-month simulation over central Europe to show that these deviations can be mostly resolved by reparameterization of the vertical mixing routine. In order to validate our results, they are compared to in situ, satellite, and MAX-DOAS measurements.
Meeta Cesler-Maloney, William Simpson, Jonas Kuhn, Jochen Stutz, Jennie Thomas, Tjarda Roberts, Deanna Huff, and Sol Cooperdock
EGUsphere, https://doi.org/10.5194/egusphere-2023-3082, https://doi.org/10.5194/egusphere-2023-3082, 2024
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We used a one-dimensional model to simulate how pollution in Fairbanks, Alaska, accumulates in shallow layers near the ground when temperature inversions are present. We find pollution accumulates in a 20 m to 50 m thick layer. The model agrees with observations of SO2 pollution using only home heating emissions sources, which shows that ground-based sources dominate sulfur pollution in downtown Fairbanks. Air residence times in downtown are only a few hours, limiting chemical transformations.
Andrea Pazmiño, Florence Goutail, Sophie Godin-Beekmann, Alain Hauchecorne, Jean-Pierre Pommereau, Martyn P. Chipperfield, Wuhu Feng, Franck Lefèvre, Audrey Lecouffe, Michel Van Roozendael, Nis Jepsen, Georg Hansen, Rigel Kivi, Kimberly Strong, and Kaley A. Walker
Atmos. Chem. Phys., 23, 15655–15670, https://doi.org/10.5194/acp-23-15655-2023, https://doi.org/10.5194/acp-23-15655-2023, 2023
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The vortex-averaged ozone loss over the last 3 decades is evaluated for both polar regions using the passive ozone tracer of the chemical transport model TOMCAT/SLIMCAT and total ozone observations from the SAOZ network and MSR2 reanalysis. Three metrics were developed to compute ozone trends since 2000. The study confirms the ozone recovery in the Antarctic and shows a potential sign of quantitative detection of ozone recovery in the Arctic that needs to be robustly confirmed in the future.
Tobias D. Schmitt, Jonas Kuhn, Ralph Kleinschek, Benedikt A. Löw, Stefan Schmitt, William Cranton, Martina Schmidt, Sanam N. Vardag, Frank Hase, David W. T. Griffith, and André Butz
Atmos. Meas. Tech., 16, 6097–6110, https://doi.org/10.5194/amt-16-6097-2023, https://doi.org/10.5194/amt-16-6097-2023, 2023
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Our new observatory measures greenhouse gas concentrations of carbon dioxide (CO2) and methane (CH4) along a 1.55 km long light path over the city of Heidelberg, Germany. We compared our measurements with measurements that were taken at a single point at one end of our path. The two mostly agreed but show a significant difference for CO2 with certain wind directions. This is important when using greenhouse gas concentration measurements to observe greenhouse gas emissions of cities.
Simon Warnach, Holger Sihler, Christian Borger, Nicole Bobrowski, Steffen Beirle, Ulrich Platt, and Thomas Wagner
Atmos. Meas. Tech., 16, 5537–5573, https://doi.org/10.5194/amt-16-5537-2023, https://doi.org/10.5194/amt-16-5537-2023, 2023
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BrO inside volcanic gas plumes but can be used in combination with SO2 to characterize the volcanic property and its activity state. High-quality satellite observations can provide a global inventory of this important quantity. This paper investigates how to accurately detect BrO inside volcanic plumes from the satellite UV spectrum. A sophisticated novel non-volcanic background correction scheme is presented, and systematic errors including cross-interference with formaldehyde are minimized.
Rodriguez Yombo Phaka, Alexis Merlaud, Gaia Pinardi, Martina M. Friedrich, Michel Van Roozendael, Jean-François Müller, Trissevgeni Stavrakou, Isabelle De Smedt, François Hendrick, Ermioni Dimitropoulou, Richard Bopili Mbotia Lepiba, Edmond Phuku Phuati, Buenimio Lomami Djibi, Lars Jacobs, Caroline Fayt, Jean-Pierre Mbungu Tsumbu, and Emmanuel Mahieu
Atmos. Meas. Tech., 16, 5029–5050, https://doi.org/10.5194/amt-16-5029-2023, https://doi.org/10.5194/amt-16-5029-2023, 2023
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We present air quality measurements in Kinshasa, Democratic Republic of the Congo, performed with a newly developed instrument which was installed on a roof of the University of Kinshasa in November 2019. The instrument records spectra of the scattered sunlight, from which we derive the abundances of nitrogen dioxide and formaldehyde, two important pollutants. We compare our ground-based measurements with those of the TROPOspheric Monitoring Instrument (TROPOMI).
Yuhang Zhang, Jintai Lin, Jhoon Kim, Hanlim Lee, Junsung Park, Hyunkee Hong, Michel Van Roozendael, Francois Hendrick, Ting Wang, Pucai Wang, Qin He, Kai Qin, Yongjoo Choi, Yugo Kanaya, Jin Xu, Pinhua Xie, Xin Tian, Sanbao Zhang, Shanshan Wang, Siyang Cheng, Xinghong Cheng, Jianzhong Ma, Thomas Wagner, Robert Spurr, Lulu Chen, Hao Kong, and Mengyao Liu
Atmos. Meas. Tech., 16, 4643–4665, https://doi.org/10.5194/amt-16-4643-2023, https://doi.org/10.5194/amt-16-4643-2023, 2023
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Our tropospheric NO2 vertical column density product with high spatiotemporal resolution is based on the Geostationary Environment Monitoring Spectrometer (GEMS) and named POMINO–GEMS. Strong hotspot signals and NO2 diurnal variations are clearly seen. Validations with multiple satellite products and ground-based, mobile car and surface measurements exhibit the overall great performance of the POMINO–GEMS product, indicating its capability for application in environmental studies.
Vitali Fioletov, Xiaoyi Zhao, Ihab Abboud, Michael Brohart, Akira Ogyu, Reno Sit, Sum Chi Lee, Irina Petropavlovskikh, Koji Miyagawa, Bryan J. Johnson, Patrick Cullis, John Booth, Glen McConville, and C. Thomas McElroy
Atmos. Chem. Phys., 23, 12731–12751, https://doi.org/10.5194/acp-23-12731-2023, https://doi.org/10.5194/acp-23-12731-2023, 2023
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Stratospheric ozone within the Southern Hemisphere springtime polar vortex has been a subject of intense research since the discovery of the Antarctic ozone hole. The wintertime ozone in the vortex is less studied. We show that the recent wintertime ozone values over the South Pole were about 12 % below the pre-1980s level; i.e., the decline there was nearly twice as large as that over southern midlatitudes. Thus, wintertime ozone there can be used as an indicator of the ozone layer state.
Herizo Narivelo, Paul David Hamer, Virginie Marécal, Luke Surl, Tjarda Roberts, Sophie Pelletier, Béatrice Josse, Jonathan Guth, Mickaël Bacles, Simon Warnach, Thomas Wagner, Stefano Corradini, Giuseppe Salerno, and Lorenzo Guerrieri
Atmos. Chem. Phys., 23, 10533–10561, https://doi.org/10.5194/acp-23-10533-2023, https://doi.org/10.5194/acp-23-10533-2023, 2023
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Volcanic emissions emit large quantities of gases and primary aerosols that can play an important role in atmospheric chemistry. We present a study of the fate of volcanic bromine emissions from the eruption of Mount Etna around Christmas 2018. Using a numerical model and satellite observations, we analyse the impact of the volcanic plume and how it modifies the composition of the air over the whole Mediterranean basin, in particular on tropospheric ozone through the bromine-explosion cycle.
Bianca Zilker, Andreas Richter, Anne-Marlene Blechschmidt, Peter von der Gathen, Ilias Bougoudis, Sora Seo, Tim Bösch, and John Philip Burrows
Atmos. Chem. Phys., 23, 9787–9814, https://doi.org/10.5194/acp-23-9787-2023, https://doi.org/10.5194/acp-23-9787-2023, 2023
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During Arctic spring, near-surface ozone is depleted by bromine released from salty sea ice and/or snow-covered areas under certain meteorological conditions. To study this ozone depletion and the prevailing meteorological conditions, two ozone data sets from Ny-Ålesund, Svalbard, have been evaluated. We found that during ozone depletion events lower pressure over the Barents Sea and higher pressure in the Icelandic Low area led to a transport of cold polar air from the north to Ny-Ålesund.
Shoma Yamanouchi, Stephanie Conway, Kimberly Strong, Orfeo Colebatch, Erik Lutsch, Sébastien Roche, Jeffrey Taylor, Cynthia H. Whaley, and Aldona Wiacek
Earth Syst. Sci. Data, 15, 3387–3418, https://doi.org/10.5194/essd-15-3387-2023, https://doi.org/10.5194/essd-15-3387-2023, 2023
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Nineteen years of atmospheric composition measurements made at the University of Toronto Atmospheric Observatory (TAO; 43.66° N, 79.40° W; 174 m.a.s.l.) are presented. These are retrieved from Fourier transform infrared (FTIR) solar absorption spectra recorded with a spectrometer from May 2002 to December 2020. The retrievals have been optimized for fourteen species: O3, HCl, HF, HNO3, CH4, C2H6, CO, HCN, N2O, C2H2, H2CO, CH3OH, HCOOH, and NH3.
Steffen Beirle, Christian Borger, Adrian Jost, and Thomas Wagner
Earth Syst. Sci. Data, 15, 3051–3073, https://doi.org/10.5194/essd-15-3051-2023, https://doi.org/10.5194/essd-15-3051-2023, 2023
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We present a catalog of nitrogen oxide emissions from point sources (like power plants or metal smelters) based on satellite observations of NO2 combined with meteorological wind fields.
Christian Borger, Steffen Beirle, and Thomas Wagner
Earth Syst. Sci. Data, 15, 3023–3049, https://doi.org/10.5194/essd-15-3023-2023, https://doi.org/10.5194/essd-15-3023-2023, 2023
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This study presents a long-term data set of monthly mean total column water vapour (TCWV) based on measurements of the Ozone Monitoring Instrument (OMI) covering the time range from January 2005 to December 2020. We describe how the TCWV values are retrieved from UV–Vis satellite spectra and demonstrate that the OMI TCWV data set is in good agreement with various different reference data sets. Moreover, we also show that it fulfills typical stability requirements for climate data records.
Robert G. Ryan, Eloise A. Marais, Eleanor Gershenson-Smith, Robbie Ramsay, Jan-Peter Muller, Jan-Lukas Tirpitz, and Udo Frieß
Atmos. Chem. Phys., 23, 7121–7139, https://doi.org/10.5194/acp-23-7121-2023, https://doi.org/10.5194/acp-23-7121-2023, 2023
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We describe the first data retrieval from a newly installed instrument providing measurements of vertical profiles of air pollution over Central London during heatwaves in summer 2022. We use these observations with surface air quality network measurements to support interpretation that an exponential increase in biogenic emissions of isoprene during heatwaves provides the limiting ingredient for severe ozone pollution, leading to non-compliance with the national ozone air quality standard.
Theano Drosoglou, Ioannis-Panagiotis Raptis, Massimo Valeri, Stefano Casadio, Francesca Barnaba, Marcos Herreras-Giralda, Anton Lopatin, Oleg Dubovik, Gabriele Brizzi, Fabrizio Niro, Monica Campanelli, and Stelios Kazadzis
Atmos. Meas. Tech., 16, 2989–3014, https://doi.org/10.5194/amt-16-2989-2023, https://doi.org/10.5194/amt-16-2989-2023, 2023
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Aerosol optical properties derived from sun photometers depend on the optical depth of trace gases absorbing solar radiation at specific spectral ranges. Various networks use satellite-based climatologies to account for this or neglect their effect. In this work, we evaluate the effect of NO2 absorption in aerosol retrievals from AERONET and SKYNET over two stations in Rome, Italy, with relatively high NO2 spatiotemporal variations, using NO2 data from the Pandora network and the TROPOMI sensor.
Yifan Guan, Gretchen Keppel-Aleks, Scott C. Doney, Christof Petri, Dave Pollard, Debra Wunch, Frank Hase, Hirofumi Ohyama, Isamu Morino, Justus Notholt, Kei Shiomi, Kim Strong, Rigel Kivi, Matthias Buschmann, Nicholas Deutscher, Paul Wennberg, Ralf Sussmann, Voltaire A. Velazco, and Yao Té
Atmos. Chem. Phys., 23, 5355–5372, https://doi.org/10.5194/acp-23-5355-2023, https://doi.org/10.5194/acp-23-5355-2023, 2023
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We characterize spatial–temporal patterns of interannual variability (IAV) in atmospheric CO2 based on NASA’s Orbiting Carbon Observatory-2 (OCO-2). CO2 variation is strongly impacted by climate events, with higher anomalies during El Nino years. We show high correlation in IAV between space-based and ground-based CO2 from long-term sites. Because OCO-2 has near-global coverage, our paper provides a roadmap to study IAV where in situ observation is sparse, such as open oceans and remote lands.
Xiaoyi Zhao, Vitali Fioletov, Alberto Redondas, Julian Gröbner, Luca Egli, Franz Zeilinger, Javier López-Solano, Alberto Berjón Arroyo, James Kerr, Eliane Maillard Barras, Herman Smit, Michael Brohart, Reno Sit, Akira Ogyu, Ihab Abboud, and Sum Chi Lee
Atmos. Meas. Tech., 16, 2273–2295, https://doi.org/10.5194/amt-16-2273-2023, https://doi.org/10.5194/amt-16-2273-2023, 2023
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The Brewer ozone spectrophotometer is one of the World Meteorological Organization (WMO) Global Atmosphere Watch (GAW)'s standard ozone monitoring instruments since the 1980s. This work is aimed at obtaining answers to (1) why Brewer primary calibration work can only be performed at certain sites (e.g., Izaña and MLO) and (2) what is needed to assure the equivalence of calibration quality from different sites.
Ka Lok Chan, Pieter Valks, Klaus-Peter Heue, Ronny Lutz, Pascal Hedelt, Diego Loyola, Gaia Pinardi, Michel Van Roozendael, François Hendrick, Thomas Wagner, Vinod Kumar, Alkis Bais, Ankie Piters, Hitoshi Irie, Hisahiro Takashima, Yugo Kanaya, Yongjoo Choi, Kihong Park, Jihyo Chong, Alexander Cede, Udo Frieß, Andreas Richter, Jianzhong Ma, Nuria Benavent, Robert Holla, Oleg Postylyakov, Claudia Rivera Cárdenas, and Mark Wenig
Earth Syst. Sci. Data, 15, 1831–1870, https://doi.org/10.5194/essd-15-1831-2023, https://doi.org/10.5194/essd-15-1831-2023, 2023
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This paper presents the theoretical basis as well as verification and validation of the Global Ozone Monitoring Experiment-2 (GOME-2) daily and monthly level-3 products.
Viktoria F. Sofieva, Monika Szelag, Johanna Tamminen, Carlo Arosio, Alexei Rozanov, Mark Weber, Doug Degenstein, Adam Bourassa, Daniel Zawada, Michael Kiefer, Alexandra Laeng, Kaley A. Walker, Patrick Sheese, Daan Hubert, Michel van Roozendael, Christian Retscher, Robert Damadeo, and Jerry D. Lumpe
Atmos. Meas. Tech., 16, 1881–1899, https://doi.org/10.5194/amt-16-1881-2023, https://doi.org/10.5194/amt-16-1881-2023, 2023
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The paper presents the updated SAGE-CCI-OMPS+ climate data record of monthly zonal mean ozone profiles. This dataset covers the stratosphere and combines measurements by nine limb and occultation satellite instruments (SAGE II, OSIRIS, MIPAS, SCIAMACHY, GOMOS, ACE-FTS, OMPS-LP, POAM III, and SAGE III/ISS). The update includes new versions of MIPAS, ACE-FTS, and OSIRIS datasets and introduces data from additional sensors (POAM III and SAGE III/ISS) and retrieval processors (OMPS-LP).
Kai Krause, Folkard Wittrock, Andreas Richter, Dieter Busch, Anton Bergen, John P. Burrows, Steffen Freitag, and Olesia Halbherr
Atmos. Meas. Tech., 16, 1767–1787, https://doi.org/10.5194/amt-16-1767-2023, https://doi.org/10.5194/amt-16-1767-2023, 2023
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Inland shipping is an important source of nitrogen oxides (NOx). The amount of emitted NOx depends on the characteristics of the individual vessels and the traffic density. Ship emissions are often characterised by the amount of emitted NOx per unit of burnt fuel, and further knowledge about fuel consumption is needed to quantify the total emissions caused by ship traffic. In this study, a new approach to derive absolute emission rates (in g s−1) from onshore measurements is presented.
Thomas Wagner, Simon Warnach, Steffen Beirle, Nicole Bobrowski, Adrian Jost, Janis Puķīte, and Nicolas Theys
Atmos. Meas. Tech., 16, 1609–1662, https://doi.org/10.5194/amt-16-1609-2023, https://doi.org/10.5194/amt-16-1609-2023, 2023
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We investigate 3D effects of volcanic plumes on the retrieval results of satellite and ground-based UV–Vis observations. With its small ground pixels of 3.5 x 5.5 km², the TROPOMI instrument can detect much smaller volcanic plumes than previous instruments. At the same time, 3D effects become important. The effect of horizontal photon paths especially can lead to a strong underestimation of the derived plume contents of up to > 50 %, which can be further increased for strong absorbers like SO2.
Siyang Cheng, Xinghong Cheng, Jianzhong Ma, Xiangde Xu, Wenqian Zhang, Jinguang Lv, Gang Bai, Bing Chen, Siying Ma, Steffen Ziegler, Sebastian Donner, and Thomas Wagner
Atmos. Chem. Phys., 23, 3655–3677, https://doi.org/10.5194/acp-23-3655-2023, https://doi.org/10.5194/acp-23-3655-2023, 2023
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We made mobile MAX-DOAS measurements in the background atmosphere over the Tibetan Plateau in summer 2021. We retrieved the tropospheric NO2 and HCHO vertical column densities (VCDs) along extended driving routes and found a decreasing trend of the VCDs with altitude. Elevated NO2 VCDs along the driving routes could be attributed to enhanced traffic emissions from the towns crossed. The spatio-temporal distribution of the HCHO VCDs correlated strongly with the surface temperature.
Kezia Lange, Andreas Richter, Anja Schönhardt, Andreas C. Meier, Tim Bösch, André Seyler, Kai Krause, Lisa K. Behrens, Folkard Wittrock, Alexis Merlaud, Frederik Tack, Caroline Fayt, Martina M. Friedrich, Ermioni Dimitropoulou, Michel Van Roozendael, Vinod Kumar, Sebastian Donner, Steffen Dörner, Bianca Lauster, Maria Razi, Christian Borger, Katharina Uhlmannsiek, Thomas Wagner, Thomas Ruhtz, Henk Eskes, Birger Bohn, Daniel Santana Diaz, Nader Abuhassan, Dirk Schüttemeyer, and John P. Burrows
Atmos. Meas. Tech., 16, 1357–1389, https://doi.org/10.5194/amt-16-1357-2023, https://doi.org/10.5194/amt-16-1357-2023, 2023
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We present airborne imaging DOAS and ground-based stationary and car DOAS measurements conducted during the S5P-VAL-DE-Ruhr campaign in the Rhine-Ruhr region. The measurements are used to validate spaceborne NO2 data products from the Sentinel-5 Precursor TROPOspheric Monitoring Instrument (TROPOMI). Auxiliary data of the TROPOMI NO2 retrieval, such as spatially higher resolved a priori NO2 vertical profiles, surface reflectivity, and cloud treatment are investigated to evaluate their impact.
Udo Frieß, Karin Kreher, Richard Querel, Holger Schmithüsen, Dan Smale, Rolf Weller, and Ulrich Platt
Atmos. Chem. Phys., 23, 3207–3232, https://doi.org/10.5194/acp-23-3207-2023, https://doi.org/10.5194/acp-23-3207-2023, 2023
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Reactive bromine compounds, emitted by the sea ice during polar spring, play an important role in the atmospheric chemistry of the coastal regions of Antarctica. We investigate the sources and impacts of reactive bromine in detail using many years of measurements at two Antarctic sites located at opposite sides of the Antarctic continent. Using a multitude of meteorological observations, we were able to identify the main triggers and source regions for reactive bromine in Antarctica.
Nasrin Mostafavi Pak, Jacob K. Hedelius, Sébastien Roche, Liz Cunningham, Bianca Baier, Colm Sweeney, Coleen Roehl, Joshua Laughner, Geoffrey Toon, Paul Wennberg, Harrison Parker, Colin Arrowsmith, Joseph Mendonca, Pierre Fogal, Tyler Wizenberg, Beatriz Herrera, Kimberly Strong, Kaley A. Walker, Felix Vogel, and Debra Wunch
Atmos. Meas. Tech., 16, 1239–1261, https://doi.org/10.5194/amt-16-1239-2023, https://doi.org/10.5194/amt-16-1239-2023, 2023
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Ground-based remote sensing instruments in the Total Carbon Column Observing Network (TCCON) measure greenhouse gases in the atmosphere. Consistency between TCCON measurements is crucial to accurately infer changes in atmospheric composition. We use portable remote sensing instruments (EM27/SUN) to evaluate biases between TCCON stations in North America. We also improve the retrievals of EM27/SUN instruments and evaluate the previous (GGG2014) and newest (GGG2020) retrieval algorithms.
Brendan Byrne, David F. Baker, Sourish Basu, Michael Bertolacci, Kevin W. Bowman, Dustin Carroll, Abhishek Chatterjee, Frédéric Chevallier, Philippe Ciais, Noel Cressie, David Crisp, Sean Crowell, Feng Deng, Zhu Deng, Nicholas M. Deutscher, Manvendra K. Dubey, Sha Feng, Omaira E. García, David W. T. Griffith, Benedikt Herkommer, Lei Hu, Andrew R. Jacobson, Rajesh Janardanan, Sujong Jeong, Matthew S. Johnson, Dylan B. A. Jones, Rigel Kivi, Junjie Liu, Zhiqiang Liu, Shamil Maksyutov, John B. Miller, Scot M. Miller, Isamu Morino, Justus Notholt, Tomohiro Oda, Christopher W. O'Dell, Young-Suk Oh, Hirofumi Ohyama, Prabir K. Patra, Hélène Peiro, Christof Petri, Sajeev Philip, David F. Pollard, Benjamin Poulter, Marine Remaud, Andrew Schuh, Mahesh K. Sha, Kei Shiomi, Kimberly Strong, Colm Sweeney, Yao Té, Hanqin Tian, Voltaire A. Velazco, Mihalis Vrekoussis, Thorsten Warneke, John R. Worden, Debra Wunch, Yuanzhi Yao, Jeongmin Yun, Andrew Zammit-Mangion, and Ning Zeng
Earth Syst. Sci. Data, 15, 963–1004, https://doi.org/10.5194/essd-15-963-2023, https://doi.org/10.5194/essd-15-963-2023, 2023
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Changes in the carbon stocks of terrestrial ecosystems result in emissions and removals of CO2. These can be driven by anthropogenic activities (e.g., deforestation), natural processes (e.g., fires) or in response to rising CO2 (e.g., CO2 fertilization). This paper describes a dataset of CO2 emissions and removals derived from atmospheric CO2 observations. This pilot dataset informs current capabilities and future developments towards top-down monitoring and verification systems.
Amir H. Souri, Matthew S. Johnson, Glenn M. Wolfe, James H. Crawford, Alan Fried, Armin Wisthaler, William H. Brune, Donald R. Blake, Andrew J. Weinheimer, Tijl Verhoelst, Steven Compernolle, Gaia Pinardi, Corinne Vigouroux, Bavo Langerock, Sungyeon Choi, Lok Lamsal, Lei Zhu, Shuai Sun, Ronald C. Cohen, Kyung-Eun Min, Changmin Cho, Sajeev Philip, Xiong Liu, and Kelly Chance
Atmos. Chem. Phys., 23, 1963–1986, https://doi.org/10.5194/acp-23-1963-2023, https://doi.org/10.5194/acp-23-1963-2023, 2023
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We have rigorously characterized different sources of error in satellite-based HCHO / NO2 tropospheric columns, a widely used metric for diagnosing near-surface ozone sensitivity. Specifically, the errors were categorized/quantified into (i) an inherent chemistry error, (ii) the decoupled relationship between columns and the near-surface concentration, (iii) the spatial representativeness error of ground satellite pixels, and (iv) the satellite retrieval errors.
John Douros, Henk Eskes, Jos van Geffen, K. Folkert Boersma, Steven Compernolle, Gaia Pinardi, Anne-Marlene Blechschmidt, Vincent-Henri Peuch, Augustin Colette, and Pepijn Veefkind
Geosci. Model Dev., 16, 509–534, https://doi.org/10.5194/gmd-16-509-2023, https://doi.org/10.5194/gmd-16-509-2023, 2023
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We focus on the challenges associated with comparing atmospheric composition models with satellite products such as tropospheric NO2 columns. The aim is to highlight the methodological difficulties and propose sound ways of doing such comparisons. Building on the comparisons, a new satellite product is proposed and made available, which takes advantage of higher-resolution, regional atmospheric modelling to improve estimates of troposheric NO2 columns over Europe.
Katerina Garane, Ka Lok Chan, Maria-Elissavet Koukouli, Diego Loyola, and Dimitris Balis
Atmos. Meas. Tech., 16, 57–74, https://doi.org/10.5194/amt-16-57-2023, https://doi.org/10.5194/amt-16-57-2023, 2023
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In this work, 2.5 years of TROPOMI/S5P Total Column Water Vapor (TCWV) observations retrieved from the blue wavelength band are validated against co-located precipitable water measurements from NASA AERONET, which uses Cimel Sun photometers globally. Overall, the TCWV product agrees well on a global scale with the ground-based dataset (Pearson correl. coefficient 0.909) and has a mean relative bias of −2.7 ± 4.9 % with respect to the AERONET observations for moderate albedo and cloudiness.
Bianca Lauster, Steffen Dörner, Carl-Fredrik Enell, Udo Frieß, Myojeong Gu, Janis Puķīte, Uwe Raffalski, and Thomas Wagner
Atmos. Chem. Phys., 22, 15925–15942, https://doi.org/10.5194/acp-22-15925-2022, https://doi.org/10.5194/acp-22-15925-2022, 2022
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Polar stratospheric clouds (PSCs) are an important component in ozone chemistry. Here, we use two differential optical absorption spectroscopy (DOAS) instruments in the Antarctic and Arctic to investigate the occurrence of PSCs based on the colour index, i.e. the colour of the zenith sky. Additionally using radiative transfer simulations, the variability and the seasonal cycle of PSC occurrence are analysed and an unexpectedly high signal during spring suggests the influence of volcanic aerosol.
Ali Jalali, Kaley A. Walker, Kimberly Strong, Rebecca R. Buchholz, Merritt N. Deeter, Debra Wunch, Sébastien Roche, Tyler Wizenberg, Erik Lutsch, Erin McGee, Helen M. Worden, Pierre Fogal, and James R. Drummond
Atmos. Meas. Tech., 15, 6837–6863, https://doi.org/10.5194/amt-15-6837-2022, https://doi.org/10.5194/amt-15-6837-2022, 2022
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This study validates MOPITT version 8 carbon monoxide measurements over the Canadian high Arctic for the period 2006 to 2019. The MOPITT products from different detector pixels and channels are compared with ground-based measurements from the Polar Environment Atmospheric Research Laboratory (PEARL) in Eureka, Nunavut, Canada. These results show good consistency between the satellite and ground-based measurements and provide guidance on the usage of these MOPITT data at high latitudes.
Beatriz Herrera, Alejandro Bezanilla, Thomas Blumenstock, Enrico Dammers, Frank Hase, Lieven Clarisse, Adolfo Magaldi, Claudia Rivera, Wolfgang Stremme, Kimberly Strong, Camille Viatte, Martin Van Damme, and Michel Grutter
Atmos. Chem. Phys., 22, 14119–14132, https://doi.org/10.5194/acp-22-14119-2022, https://doi.org/10.5194/acp-22-14119-2022, 2022
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This work investigates atmospheric ammonia (NH3), a key trace gas with consequences for the environment and human health, in Mexico City. The results from the ground-based and satellite instruments show the variability and spatial distribution of NH3 over this region. NH3 in Mexico City has been increasing for the past 10 years and most of its sources are urban. This work contributes to a better understanding of NH3 sources and variability in urban and remote areas.
Miriam Latsch, Andreas Richter, Henk Eskes, Maarten Sneep, Ping Wang, Pepijn Veefkind, Ronny Lutz, Diego Loyola, Athina Argyrouli, Pieter Valks, Thomas Wagner, Holger Sihler, Michel van Roozendael, Nicolas Theys, Huan Yu, Richard Siddans, and John P. Burrows
Atmos. Meas. Tech., 15, 6257–6283, https://doi.org/10.5194/amt-15-6257-2022, https://doi.org/10.5194/amt-15-6257-2022, 2022
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The article investigates different S5P TROPOMI cloud retrieval algorithms for tropospheric trace gas retrievals. The cloud products show differences primarily over snow and ice and for scenes under sun glint. Some issues regarding across-track dependence are found for the cloud fractions as well as for the cloud heights.
Maximilian Herrmann, Moritz Schöne, Christian Borger, Simon Warnach, Thomas Wagner, Ulrich Platt, and Eva Gutheil
Atmos. Chem. Phys., 22, 13495–13526, https://doi.org/10.5194/acp-22-13495-2022, https://doi.org/10.5194/acp-22-13495-2022, 2022
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Ozone depletion events (ODEs) are a common occurrence in the boundary layer during Arctic spring. Ozone is depleted by bromine species in an autocatalytic reaction cycle. Previous modeling studies assumed an infinite bromine source at the ground. An alternative emission scheme is presented in which a finite amount of bromide in the snow is tracked over time. The Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) is used to study ODEs in the Arctic from February to May 2019.
Xin Yang, Kimberly Strong, Alison S. Criscitiello, Marta Santos-Garcia, Kristof Bognar, Xiaoyi Zhao, Pierre Fogal, Kaley A. Walker, Sara M. Morris, and Peter Effertz
EGUsphere, https://doi.org/10.5194/egusphere-2022-696, https://doi.org/10.5194/egusphere-2022-696, 2022
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Snow pack in high Arctic plays a key role in polar atmospheric chemistry, especially in spring when photochemistry becomes active. By sampling surface snow from a Canadian high Arctic location at Eureka, Nunavut (80° N, 86° W), we demonstrate that surface snow is a net sink rather than a source of atmospheric reactive bromine and nitrate. This finding is new and opposite to previous conclusions that snowpack is a large and direct source of reactive bromine in polar spring.
Huan Yu, Claudia Emde, Arve Kylling, Ben Veihelmann, Bernhard Mayer, Kerstin Stebel, and Michel Van Roozendael
Atmos. Meas. Tech., 15, 5743–5768, https://doi.org/10.5194/amt-15-5743-2022, https://doi.org/10.5194/amt-15-5743-2022, 2022
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In this study, we have investigated the impact of 3D clouds on the tropospheric NO2 retrieval from UV–visible sensors. We applied standard NO2 retrieval methods including cloud corrections to synthetic data generated by the 3D radiative transfer model. A sensitivity study was done for synthetic data, and dependencies on various parameters were investigated. Possible mitigation strategies were investigated and compared based on 3D simulations and observed data.
Camille Viatte, Rimal Abeed, Shoma Yamanouchi, William C. Porter, Sarah Safieddine, Martin Van Damme, Lieven Clarisse, Beatriz Herrera, Michel Grutter, Pierre-Francois Coheur, Kimberly Strong, and Cathy Clerbaux
Atmos. Chem. Phys., 22, 12907–12922, https://doi.org/10.5194/acp-22-12907-2022, https://doi.org/10.5194/acp-22-12907-2022, 2022
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Large cities can experience high levels of fine particulate matter (PM2.5) pollution linked to ammonia (NH3) mainly emitted from agricultural activities. Using a combination of PM2.5 and NH3 measurements from in situ instruments, satellite infrared spectrometers, and atmospheric model simulations, we have demonstrated the role of NH3 and meteorological conditions on pollution events occurring over Paris, Toronto, and Mexico City.
Kostas Eleftheratos, John Kapsomenakis, Ilias Fountoulakis, Christos S. Zerefos, Patrick Jöckel, Martin Dameris, Alkiviadis F. Bais, Germar Bernhard, Dimitra Kouklaki, Kleareti Tourpali, Scott Stierle, J. Ben Liley, Colette Brogniez, Frédérique Auriol, Henri Diémoz, Stana Simic, Irina Petropavlovskikh, Kaisa Lakkala, and Kostas Douvis
Atmos. Chem. Phys., 22, 12827–12855, https://doi.org/10.5194/acp-22-12827-2022, https://doi.org/10.5194/acp-22-12827-2022, 2022
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We present the future evolution of DNA-active ultraviolet (UV) radiation in view of increasing greenhouse gases (GHGs) and decreasing ozone depleting substances (ODSs). It is shown that DNA-active UV radiation might increase after 2050 between 50° N–50° S due to GHG-induced reductions in clouds and ozone, something that is likely not to happen at high latitudes, where DNA-active UV radiation will continue its downward trend mainly due to stratospheric ozone recovery from the reduction in ODSs.
John T. Sullivan, Arnoud Apituley, Nora Mettig, Karin Kreher, K. Emma Knowland, Marc Allaart, Ankie Piters, Michel Van Roozendael, Pepijn Veefkind, Jerry R. Ziemke, Natalya Kramarova, Mark Weber, Alexei Rozanov, Laurence Twigg, Grant Sumnicht, and Thomas J. McGee
Atmos. Chem. Phys., 22, 11137–11153, https://doi.org/10.5194/acp-22-11137-2022, https://doi.org/10.5194/acp-22-11137-2022, 2022
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A TROPOspheric Monitoring Instrument (TROPOMI) validation campaign (TROLIX-19) was held in the Netherlands in September 2019. The research presented here focuses on using ozone lidars from NASA’s Goddard Space Flight Center to better evaluate the characterization of ozone throughout TROLIX-19 as compared to balloon-borne, space-borne and ground-based passive measurements, as well as a global coupled chemistry meteorology model.
Nicolas Theys, Christophe Lerot, Hugues Brenot, Jeroen van Gent, Isabelle De Smedt, Lieven Clarisse, Mike Burton, Matthew Varnam, Catherine Hayer, Benjamin Esse, and Michel Van Roozendael
Atmos. Meas. Tech., 15, 4801–4817, https://doi.org/10.5194/amt-15-4801-2022, https://doi.org/10.5194/amt-15-4801-2022, 2022
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Sulfur dioxide plume height after a volcanic eruption is an important piece of information for many different scientific studies and applications. Satellite UV retrievals are useful in this respect, but available algorithms have shown so far limited sensitivity to SO2 height. Here we present a new technique to improve the retrieval of SO2 plume height for SO2 columns as low as 5 DU. We demonstrate the algorithm using TROPOMI measurements and compare with other height estimates.
Christian Borger, Steffen Beirle, and Thomas Wagner
Atmos. Chem. Phys., 22, 10603–10621, https://doi.org/10.5194/acp-22-10603-2022, https://doi.org/10.5194/acp-22-10603-2022, 2022
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In this study, we analyse trends of total column water vapour (TCWV) using multiple years of satellite observations and find, on the global average, an increase in the TCWV amount by about 0.21 % per year. Further investigations of the hydrological cycle reveal that the assumption of temporally invariant relative humidity is not always fulfilled and that the response of the global water vapour turnover time to global warming is 2 to 3 times higher than previously reported values.
Pieternel F. Levelt, Deborah C. Stein Zweers, Ilse Aben, Maite Bauwens, Tobias Borsdorff, Isabelle De Smedt, Henk J. Eskes, Christophe Lerot, Diego G. Loyola, Fabian Romahn, Trissevgeni Stavrakou, Nicolas Theys, Michel Van Roozendael, J. Pepijn Veefkind, and Tijl Verhoelst
Atmos. Chem. Phys., 22, 10319–10351, https://doi.org/10.5194/acp-22-10319-2022, https://doi.org/10.5194/acp-22-10319-2022, 2022
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Using the COVID-19 lockdown periods as an example, we show how Sentinel-5P/TROPOMI trace gas data (NO2, SO2, CO, HCHO and CHOCHO) can be used to understand impacts on air quality for regions and cities around the globe. We also provide information for both experienced and inexperienced users about how we created the data using state-of-the-art algorithms, where to get the data, methods taking meteorological and seasonal variability into consideration, and insights for future studies.
Ermioni Dimitropoulou, François Hendrick, Martina Michaela Friedrich, Frederik Tack, Gaia Pinardi, Alexis Merlaud, Caroline Fayt, Christian Hermans, Frans Fierens, and Michel Van Roozendael
Atmos. Meas. Tech., 15, 4503–4529, https://doi.org/10.5194/amt-15-4503-2022, https://doi.org/10.5194/amt-15-4503-2022, 2022
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A total of 2 years of dual-scan ground-based MAX-DOAS measurements of tropospheric NO2 and aerosols in Uccle (Belgium) have been used to develop a new optimal-estimation-based inversion approach to retrieve horizontal profiles of surface NO2 concentration and aerosol extinction profiles. We show that the combination of an appropriate sampling of TROPOMI pixels by ground-based measurements and an adequate a priori NO2 profile shape in TROPOMI retrievals improves the agreement between datasets.
Matthias Schneider, Benjamin Ertl, Qiansi Tu, Christopher J. Diekmann, Farahnaz Khosrawi, Amelie N. Röhling, Frank Hase, Darko Dubravica, Omaira E. García, Eliezer Sepúlveda, Tobias Borsdorff, Jochen Landgraf, Alba Lorente, André Butz, Huilin Chen, Rigel Kivi, Thomas Laemmel, Michel Ramonet, Cyril Crevoisier, Jérome Pernin, Martin Steinbacher, Frank Meinhardt, Kimberly Strong, Debra Wunch, Thorsten Warneke, Coleen Roehl, Paul O. Wennberg, Isamu Morino, Laura T. Iraci, Kei Shiomi, Nicholas M. Deutscher, David W. T. Griffith, Voltaire A. Velazco, and David F. Pollard
Atmos. Meas. Tech., 15, 4339–4371, https://doi.org/10.5194/amt-15-4339-2022, https://doi.org/10.5194/amt-15-4339-2022, 2022
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We present a computationally very efficient method for the synergetic use of level 2 remote-sensing data products. We apply the method to IASI vertical profile and TROPOMI total column space-borne methane observations and thus gain sensitivity for the tropospheric methane partial columns, which is not achievable by the individual use of TROPOMI and IASI. These synergetic effects are evaluated theoretically and empirically by inter-comparisons to independent references of TCCON, AirCore, and GAW.
Kristof Bognar, Susann Tegtmeier, Adam Bourassa, Chris Roth, Taran Warnock, Daniel Zawada, and Doug Degenstein
Atmos. Chem. Phys., 22, 9553–9569, https://doi.org/10.5194/acp-22-9553-2022, https://doi.org/10.5194/acp-22-9553-2022, 2022
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We quantify recent changes in stratospheric ozone (outside the polar regions) using a combination of three satellite datasets. We find that upper stratospheric ozone have increased significantly since 2000, although the recovery shows an unexpected pause in the Northern Hemisphere. Combined with the likely decrease in ozone in the lower stratosphere, this presents an interesting challenge for predicting the future of the ozone layer.
Minqiang Zhou, Bavo Langerock, Pucai Wang, Corinne Vigouroux, Qichen Ni, Christian Hermans, Bart Dils, Nicolas Kumps, Weidong Nan, and Martine De Mazière
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-354, https://doi.org/10.5194/acp-2022-354, 2022
Revised manuscript not accepted
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The ground-based FTIR measurements at Xianghe provide carbon monoxide (CO), acetylene (C2H2), ethane (C2H6), formaldehyde (H2CO), and hydrogen cyanide (HCN) total columns between June 2018 and November 2021. The retrieval strategies, retrieval information, and uncertainties of these five important trace gases are presented and discussed. This study provides an insight into the time series, variations, and correlations of these five species in North China.
Sieglinde Callewaert, Jérôme Brioude, Bavo Langerock, Valentin Duflot, Dominique Fonteyn, Jean-François Müller, Jean-Marc Metzger, Christian Hermans, Nicolas Kumps, Michel Ramonet, Morgan Lopez, Emmanuel Mahieu, and Martine De Mazière
Atmos. Chem. Phys., 22, 7763–7792, https://doi.org/10.5194/acp-22-7763-2022, https://doi.org/10.5194/acp-22-7763-2022, 2022
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A regional atmospheric transport model is used to analyze the factors contributing to CO2, CH4, and CO observations at Réunion Island. We show that the surface observations are dominated by local fluxes and dynamical processes, while the column data are influenced by larger-scale mechanisms such as biomass burning plumes. The model is able to capture the measured time series well; however, the results are highly dependent on accurate boundary conditions and high-resolution emission inventories.
Arve Kylling, Claudia Emde, Huan Yu, Michel van Roozendael, Kerstin Stebel, Ben Veihelmann, and Bernhard Mayer
Atmos. Meas. Tech., 15, 3481–3495, https://doi.org/10.5194/amt-15-3481-2022, https://doi.org/10.5194/amt-15-3481-2022, 2022
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Atmospheric trace gases such as nitrogen dioxide (NO2) may be measured by satellite instruments sensitive to solar ultraviolet–visible radiation reflected from Earth and its atmosphere. For a single pixel, clouds in neighbouring pixels may affect the radiation and hence the retrieved trace gas amount. We found that for a solar zenith angle less than about 40° this cloud-related NO2 bias is typically below 10 %, while for larger solar zenith angles the NO2 bias is on the order of tens of percent.
Gaia Pinardi, Michel Van Roozendael, François Hendrick, Andreas Richter, Pieter Valks, Ramina Alwarda, Kristof Bognar, Udo Frieß, José Granville, Myojeong Gu, Paul Johnston, Cristina Prados-Roman, Richard Querel, Kimberly Strong, Thomas Wagner, Folkard Wittrock, and Margarita Yela Gonzalez
Atmos. Meas. Tech., 15, 3439–3463, https://doi.org/10.5194/amt-15-3439-2022, https://doi.org/10.5194/amt-15-3439-2022, 2022
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We report on the GOME-2A and GOME-2B OClO dataset (2007 to 2016, from the EUMETSAT's AC SAF) validation using data from nine NDACC zenith-scattered-light DOAS (ZSL-DOAS) instruments distributed in both the Arctic and Antarctic. Specific sensitivity tests are performed on the ground-based data to estimate the impact of the different OClO DOAS analysis settings and their typical errors. Good agreement is found for both the inter-annual variability and the overall OClO seasonal behavior.
Stefan Noël, Maximilian Reuter, Michael Buchwitz, Jakob Borchardt, Michael Hilker, Oliver Schneising, Heinrich Bovensmann, John P. Burrows, Antonio Di Noia, Robert J. Parker, Hiroshi Suto, Yukio Yoshida, Matthias Buschmann, Nicholas M. Deutscher, Dietrich G. Feist, David W. T. Griffith, Frank Hase, Rigel Kivi, Cheng Liu, Isamu Morino, Justus Notholt, Young-Suk Oh, Hirofumi Ohyama, Christof Petri, David F. Pollard, Markus Rettinger, Coleen Roehl, Constantina Rousogenous, Mahesh Kumar Sha, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Yao Té, Voltaire A. Velazco, Mihalis Vrekoussis, and Thorsten Warneke
Atmos. Meas. Tech., 15, 3401–3437, https://doi.org/10.5194/amt-15-3401-2022, https://doi.org/10.5194/amt-15-3401-2022, 2022
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We present a new version (v3) of the GOSAT and GOSAT-2 FOCAL products.
In addition to an increased number of XCO2 data, v3 also includes products for XCH4 (full-physics and proxy), XH2O and the relative ratio of HDO to H2O (δD). For GOSAT-2, we also present first XCO and XN2O results. All FOCAL data products show reasonable spatial distribution and temporal variations and agree well with TCCON. Global XN2O maps show a gradient from the tropics to higher latitudes on the order of 15 ppb.
Melanie Coldewey-Egbers, Diego G. Loyola, Christophe Lerot, and Michel Van Roozendael
Atmos. Chem. Phys., 22, 6861–6878, https://doi.org/10.5194/acp-22-6861-2022, https://doi.org/10.5194/acp-22-6861-2022, 2022
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Monitoring the long-term evolution of ozone and the evaluation of trends is essential to assess the efficacy of the Montreal Protocol and its amendments. The first signs of recovery as a consequence of decreasing amounts of ozone-depleting substances have been reported, but the impact needs to be investigated in more detail. In the Southern Hemisphere significant positive trends were found, but in the Northern Hemisphere the expected increase is still not yet visible.
M. Dolores Andrés Hernández, Andreas Hilboll, Helmut Ziereis, Eric Förster, Ovid O. Krüger, Katharina Kaiser, Johannes Schneider, Francesca Barnaba, Mihalis Vrekoussis, Jörg Schmidt, Heidi Huntrieser, Anne-Marlene Blechschmidt, Midhun George, Vladyslav Nenakhov, Theresa Harlass, Bruna A. Holanda, Jennifer Wolf, Lisa Eirenschmalz, Marc Krebsbach, Mira L. Pöhlker, Anna B. Kalisz Hedegaard, Linlu Mei, Klaus Pfeilsticker, Yangzhuoran Liu, Ralf Koppmann, Hans Schlager, Birger Bohn, Ulrich Schumann, Andreas Richter, Benjamin Schreiner, Daniel Sauer, Robert Baumann, Mariano Mertens, Patrick Jöckel, Markus Kilian, Greta Stratmann, Christopher Pöhlker, Monica Campanelli, Marco Pandolfi, Michael Sicard, José L. Gómez-Amo, Manuel Pujadas, Katja Bigge, Flora Kluge, Anja Schwarz, Nikos Daskalakis, David Walter, Andreas Zahn, Ulrich Pöschl, Harald Bönisch, Stephan Borrmann, Ulrich Platt, and John P. Burrows
Atmos. Chem. Phys., 22, 5877–5924, https://doi.org/10.5194/acp-22-5877-2022, https://doi.org/10.5194/acp-22-5877-2022, 2022
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EMeRGe provides a unique set of in situ and remote sensing airborne measurements of trace gases and aerosol particles along selected flight routes in the lower troposphere over Europe. The interpretation uses also complementary collocated ground-based and satellite measurements. The collected data help to improve the current understanding of the complex spatial distribution of trace gases and aerosol particles resulting from mixing, transport, and transformation of pollution plumes over Europe.
Jan-Lukas Tirpitz, Udo Frieß, Robert Spurr, and Ulrich Platt
Atmos. Meas. Tech., 15, 2077–2098, https://doi.org/10.5194/amt-15-2077-2022, https://doi.org/10.5194/amt-15-2077-2022, 2022
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MAX-DOAS is a widely used measurement technique for the remote detection of atmospheric aerosol and trace gases. It relies on the analysis of ultra-violet and visible radiation spectra of skylight. To date, information contained in the skylight's polarisation state has not been utilised. On the basis of synthetic data, we carried out sensitivity analyses to assess the potential of polarimetry for MAX-DOAS applications.
Jos van Geffen, Henk Eskes, Steven Compernolle, Gaia Pinardi, Tijl Verhoelst, Jean-Christopher Lambert, Maarten Sneep, Mark ter Linden, Antje Ludewig, K. Folkert Boersma, and J. Pepijn Veefkind
Atmos. Meas. Tech., 15, 2037–2060, https://doi.org/10.5194/amt-15-2037-2022, https://doi.org/10.5194/amt-15-2037-2022, 2022
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Nitrogen dioxide (NO2) is one of the main data products measured by the Tropospheric Monitoring Instrument (TROPOMI) on the Sentinel-5 Precursor (S5P) satellite. This study describes improvements in the TROPOMI NO2 retrieval leading to version v2.2, operational since 1 July 2021. It compares results with previous versions v1.2–v1.4 and with Ozone Monitoring Instrument (OMI) and ground-based measurements.
Hisahiro Takashima, Yugo Kanaya, Saki Kato, Martina M. Friedrich, Michel Van Roozendael, Fumikazu Taketani, Takuma Miyakawa, Yuichi Komazaki, Carlos A. Cuevas, Alfonso Saiz-Lopez, and Takashi Sekiya
Atmos. Chem. Phys., 22, 4005–4018, https://doi.org/10.5194/acp-22-4005-2022, https://doi.org/10.5194/acp-22-4005-2022, 2022
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We have undertaken atmospheric iodine monoxide (IO) observations in the global marine boundary layer with a wide latitudinal coverage and sea surface temperature (SST) range. We conclude that atmospheric iodine is abundant over the Western Pacific warm pool, appearing as an iodine fountain, where ozone (O3) minima occur. Our study also found negative correlations between IO and O3 concentrations over IO maxima, which requires reconsideration of the initiation process of halogen activation.
Gerrit Kuhlmann, Ka Lok Chan, Sebastian Donner, Ying Zhu, Marc Schwaerzel, Steffen Dörner, Jia Chen, Andreas Hueni, Duc Hai Nguyen, Alexander Damm, Annette Schütt, Florian Dietrich, Dominik Brunner, Cheng Liu, Brigitte Buchmann, Thomas Wagner, and Mark Wenig
Atmos. Meas. Tech., 15, 1609–1629, https://doi.org/10.5194/amt-15-1609-2022, https://doi.org/10.5194/amt-15-1609-2022, 2022
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Nitrogen dioxide (NO2) is an air pollutant whose concentration often exceeds air quality guideline values, especially in urban areas. To map the spatial distribution of NO2 in Munich, we conducted the Munich NO2 Imaging Campaign (MuNIC), where NO2 was measured with stationary, mobile, and airborne in situ and remote sensing instruments. The campaign provides a unique dataset that has been used to compare the different instruments and to study the spatial variability of NO2 and its sources.
Claudia Emde, Huan Yu, Arve Kylling, Michel van Roozendael, Kerstin Stebel, Ben Veihelmann, and Bernhard Mayer
Atmos. Meas. Tech., 15, 1587–1608, https://doi.org/10.5194/amt-15-1587-2022, https://doi.org/10.5194/amt-15-1587-2022, 2022
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Retrievals of trace gas concentrations from satellite observations can be affected by clouds in the vicinity, either by shadowing or by scattering of radiation from clouds in the clear region. We used a Monte Carlo radiative transfer model to generate synthetic satellite observations, which we used to test retrieval algorithms and to quantify the error of retrieved NO2 vertical column density due to cloud scattering.
Leon Kuhn, Jonas Kuhn, Thomas Wagner, and Ulrich Platt
Atmos. Meas. Tech., 15, 1395–1414, https://doi.org/10.5194/amt-15-1395-2022, https://doi.org/10.5194/amt-15-1395-2022, 2022
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We present a novel instrument for imaging measurements of NO2 with high spatiotemporal resolution based on gas correlation spectroscopy, called the GCS NO2 camera. The instrument works by placing two gas cells (cuvettes) in front of two photosensor arrays, one filled with air and one filled with a high concentration of NO2, acting as a non-dispersive spectral filter. NO2 images are then generated on the basis of the signal ratio of the two channels in the spectral region of 430–445 nm.
Dimitris Karagkiozidis, Martina Michaela Friedrich, Steffen Beirle, Alkiviadis Bais, François Hendrick, Kalliopi Artemis Voudouri, Ilias Fountoulakis, Angelos Karanikolas, Paraskevi Tzoumaka, Michel Van Roozendael, Dimitris Balis, and Thomas Wagner
Atmos. Meas. Tech., 15, 1269–1301, https://doi.org/10.5194/amt-15-1269-2022, https://doi.org/10.5194/amt-15-1269-2022, 2022
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In this study we focus on the retrieval of aerosol, NO2, and HCHO vertical profiles from multi-axis differential optical absorption spectroscopy (MAX-DOAS) observations for the first time over Thessaloniki, Greece. We use two independent inversion algorithms for the profile retrievals. We evaluate their performance, we intercompare their results, and we validate their products with ancillary data, measured by other co-located reference instruments.
Kezia Lange, Andreas Richter, and John P. Burrows
Atmos. Chem. Phys., 22, 2745–2767, https://doi.org/10.5194/acp-22-2745-2022, https://doi.org/10.5194/acp-22-2745-2022, 2022
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In this study, we investigated short time variability of NOx emissions and lifetimes on a global scale. We combined 2 years of satellite Sentinel-5P TROPOMI tropospheric NO2 column data with wind data. Fifty NOx sources distributed around the world are analyzed. The retrieved emissions show a clear seasonal dependence. NOx lifetime shows a latitudinal dependence but only a week seasonal dependence. NOx emissions show a clear weekly pattern which in contrast is not visible for NOx lifetimes.
Steffen Beirle, Christian Borger, Steffen Dörner, Vinod Kumar, and Thomas Wagner
Atmos. Meas. Tech., 15, 987–1006, https://doi.org/10.5194/amt-15-987-2022, https://doi.org/10.5194/amt-15-987-2022, 2022
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We present a formalism that relates the vertical column density (VCD) of the oxygen collision complex O4 to surface values of temperature and pressure, based on physical laws. In addition, we propose an empirical modification which also accounts for surface relative humidity (RH). This allows for simple and quick but still accurate calculation of the O4 VCD without the need for constructing full vertical profiles, which is expected to be useful in particular for MAX-DOAS applications.
Thomas E. Taylor, Christopher W. O'Dell, David Crisp, Akhiko Kuze, Hannakaisa Lindqvist, Paul O. Wennberg, Abhishek Chatterjee, Michael Gunson, Annmarie Eldering, Brendan Fisher, Matthäus Kiel, Robert R. Nelson, Aronne Merrelli, Greg Osterman, Frédéric Chevallier, Paul I. Palmer, Liang Feng, Nicholas M. Deutscher, Manvendra K. Dubey, Dietrich G. Feist, Omaira E. García, David W. T. Griffith, Frank Hase, Laura T. Iraci, Rigel Kivi, Cheng Liu, Martine De Mazière, Isamu Morino, Justus Notholt, Young-Suk Oh, Hirofumi Ohyama, David F. Pollard, Markus Rettinger, Matthias Schneider, Coleen M. Roehl, Mahesh Kumar Sha, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Yao Té, Voltaire A. Velazco, Mihalis Vrekoussis, Thorsten Warneke, and Debra Wunch
Earth Syst. Sci. Data, 14, 325–360, https://doi.org/10.5194/essd-14-325-2022, https://doi.org/10.5194/essd-14-325-2022, 2022
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We provide an analysis of an 11-year record of atmospheric carbon dioxide (CO2) concentrations derived using an optimal estimation retrieval algorithm on measurements made by the GOSAT satellite. The new product (version 9) shows improvement over the previous version (v7.3) as evaluated against independent estimates of CO2 from ground-based sensors and atmospheric inversion systems. We also compare the new GOSAT CO2 values to collocated estimates from NASA's Orbiting Carbon Observatory-2.
Fei Liu, Zhining Tao, Steffen Beirle, Joanna Joiner, Yasuko Yoshida, Steven J. Smith, K. Emma Knowland, and Thomas Wagner
Atmos. Chem. Phys., 22, 1333–1349, https://doi.org/10.5194/acp-22-1333-2022, https://doi.org/10.5194/acp-22-1333-2022, 2022
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In this work, we present a novel method to infer NOx emissions and lifetimes based on tropospheric NO2 observations together with reanalysis wind fields for cities located in polluted backgrounds. We evaluate the accuracy of the method using synthetic NO2 observations derived from a high-resolution model simulation. Our work provides an estimate for uncertainties in satellite-derived emissions inferred from chemical transport model (CTM)-independent approaches.
Tobias Küchler, Stefan Noël, Heinrich Bovensmann, John Philip Burrows, Thomas Wagner, Christian Borger, Tobias Borsdorff, and Andreas Schneider
Atmos. Meas. Tech., 15, 297–320, https://doi.org/10.5194/amt-15-297-2022, https://doi.org/10.5194/amt-15-297-2022, 2022
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We applied the air-mass-corrected differential optical absorption spectroscopy (AMC-DOAS) method to derive total column water vapour (TCWV) from Sentinel-5P measurements and compared it to independent data sets. The correlation coefficients of typically more than 0.9 and the small deviations up to 2.5 kg m−2 reveal good agreement between our data product and other TCWV data sets. In particular for the different Sentinel-5P water vapour products, the deviations are around 1 kg m−2.
Mahtab Majdzadeh, Craig A. Stroud, Christopher Sioris, Paul A. Makar, Ayodeji Akingunola, Chris McLinden, Xiaoyi Zhao, Michael D. Moran, Ihab Abboud, and Jack Chen
Geosci. Model Dev., 15, 219–249, https://doi.org/10.5194/gmd-15-219-2022, https://doi.org/10.5194/gmd-15-219-2022, 2022
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A new lookup table for aerosol optical properties based on a Mie scattering code was calculated and adopted within an improved version of the photolysis module in the GEM-MACH in-line chemical transport model. The modified version of the photolysis module makes use of online interactive aerosol feedback and applies core-shell parameterizations to the black carbon absorption efficiency based on Bond et al. (2006) to the size bins with black carbon mass fraction of less than 40 %.
Baoye Hu, Jun Duan, Youwei Hong, Lingling Xu, Mengren Li, Yahui Bian, Min Qin, Wu Fang, Pinhua Xie, and Jinsheng Chen
Atmos. Chem. Phys., 22, 371–393, https://doi.org/10.5194/acp-22-371-2022, https://doi.org/10.5194/acp-22-371-2022, 2022
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There has been a lack of research into HONO in coastal cities with low concentrations of PM2.5, but strong sunlight and high humidity. Insufficient research on coastal cities with good air quality has resulted in certain obstacles to assessing the photochemical processes in these areas. Furthermore, HONO contributes to the atmospheric photochemistry depending on the season. Therefore, observations of HONO across four seasons in the southeastern coastal area of China are urgently needed.
Jānis Puķīte, Christian Borger, Steffen Dörner, Myojeong Gu, and Thomas Wagner
Atmos. Chem. Phys., 22, 245–272, https://doi.org/10.5194/acp-22-245-2022, https://doi.org/10.5194/acp-22-245-2022, 2022
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Chlorine dioxide (OClO) is an indicator for chlorine activation. New OClO data by TROPOMI (S5P) are interpreted in a meteorological context and related to CALIOP PSC observations. We report very high OClO levels for the northern hemispheric winter 2019/20 with an extraordinarily long period with a stable polar vortex. A minor stratospheric warming in the Southern Hemisphere was also observed in September 2019, where usual OClO values rapidly deactivated 1–2 weeks earlier.
Jonas Kuhn, Nicole Bobrowski, Thomas Wagner, and Ulrich Platt
Atmos. Meas. Tech., 14, 7873–7892, https://doi.org/10.5194/amt-14-7873-2021, https://doi.org/10.5194/amt-14-7873-2021, 2021
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We propose spectrograph implementations using Fabry–Pérot interferometers for atmospheric trace gas remote sensing. Compared with widely used grating spectrographs, we find substantial light throughput and mobility advantages for high resolving powers. Besides lowering detection limits and increasing the spatial and temporal resolution of many atmospheric trace gas measurements, this approach might enable remote sensing of further important gases such as tropospheric OH radicals.
Christophe Lerot, François Hendrick, Michel Van Roozendael, Leonardo M. A. Alvarado, Andreas Richter, Isabelle De Smedt, Nicolas Theys, Jonas Vlietinck, Huan Yu, Jeroen Van Gent, Trissevgeni Stavrakou, Jean-François Müller, Pieter Valks, Diego Loyola, Hitoshi Irie, Vinod Kumar, Thomas Wagner, Stefan F. Schreier, Vinayak Sinha, Ting Wang, Pucai Wang, and Christian Retscher
Atmos. Meas. Tech., 14, 7775–7807, https://doi.org/10.5194/amt-14-7775-2021, https://doi.org/10.5194/amt-14-7775-2021, 2021
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Global measurements of glyoxal tropospheric columns from the satellite instrument TROPOMI are presented. Such measurements can contribute to the estimation of atmospheric emissions of volatile organic compounds. This new glyoxal product has been fully characterized with a comprehensive error budget, with comparison with other satellite data sets as well as with validation based on independent ground-based remote sensing glyoxal observations.
Tyler Wizenberg, Kimberly Strong, Kaley Walker, Erik Lutsch, Tobias Borsdorff, and Jochen Landgraf
Atmos. Meas. Tech., 14, 7707–7728, https://doi.org/10.5194/amt-14-7707-2021, https://doi.org/10.5194/amt-14-7707-2021, 2021
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CO is an important atmospheric gas that influences both air quality and the climate. Here, we compare CO measurements from TROPOMI with those from ACE-FTS and an Arctic ground-based FTS at Eureka, Nunavut, to further characterize the accuracy of TROPOMI measurements. CO columns from the instruments agree well but show larger differences at high latitudes. Despite this, the results fall within the TROPOMI accuracy target, indicating good data quality at high latitudes.
Jānis Puķīte, Christian Borger, Steffen Dörner, Myojeong Gu, Udo Frieß, Andreas Carlos Meier, Carl-Fredrik Enell, Uwe Raffalski, Andreas Richter, and Thomas Wagner
Atmos. Meas. Tech., 14, 7595–7625, https://doi.org/10.5194/amt-14-7595-2021, https://doi.org/10.5194/amt-14-7595-2021, 2021
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Chlorine dioxide (OClO) is used as an indicator for chlorine activation. We present a new differential optical absorption spectroscopy retrieval algorithm for OClO from measurements of TROPOMI on the Sentinel-5P satellite. To achieve a substantially improved accuracy for the weak absorber OClO, we consider several additional fit parameters accounting for various higher-order spectral effects. The retrieved OClO slant column densities are compared with ground-based zenith sky measurements.
Joseph Mendonca, Ray Nassar, Christopher W. O'Dell, Rigel Kivi, Isamu Morino, Justus Notholt, Christof Petri, Kimberly Strong, and Debra Wunch
Atmos. Meas. Tech., 14, 7511–7524, https://doi.org/10.5194/amt-14-7511-2021, https://doi.org/10.5194/amt-14-7511-2021, 2021
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Machine learning has become an important tool for pattern recognition in many applications. In this study, we used a neural network to improve the data quality of OCO-2 measurements made at northern high latitudes. The neural network was trained and used as a binary classifier to filter out bad OCO-2 measurements in order to increase the accuracy and precision of OCO-2 XCO2 measurements in the Boreal and Arctic regions.
Song Liu, Pieter Valks, Gaia Pinardi, Jian Xu, Ka Lok Chan, Athina Argyrouli, Ronny Lutz, Steffen Beirle, Ehsan Khorsandi, Frank Baier, Vincent Huijnen, Alkiviadis Bais, Sebastian Donner, Steffen Dörner, Myrto Gratsea, François Hendrick, Dimitris Karagkiozidis, Kezia Lange, Ankie J. M. Piters, Julia Remmers, Andreas Richter, Michel Van Roozendael, Thomas Wagner, Mark Wenig, and Diego G. Loyola
Atmos. Meas. Tech., 14, 7297–7327, https://doi.org/10.5194/amt-14-7297-2021, https://doi.org/10.5194/amt-14-7297-2021, 2021
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In this work, an improved tropospheric NO2 retrieval algorithm from TROPOMI measurements over Europe is presented. The stratospheric estimation is implemented with correction for the dependency of the stratospheric NO2 on the viewing geometry. The AMF calculation is implemented using improved surface albedo, a priori NO2 profiles, and cloud correction. The improved tropospheric NO2 data show good correlations with ground-based MAX-DOAS measurements.
Nicolas Theys, Vitali Fioletov, Can Li, Isabelle De Smedt, Christophe Lerot, Chris McLinden, Nickolay Krotkov, Debora Griffin, Lieven Clarisse, Pascal Hedelt, Diego Loyola, Thomas Wagner, Vinod Kumar, Antje Innes, Roberto Ribas, François Hendrick, Jonas Vlietinck, Hugues Brenot, and Michel Van Roozendael
Atmos. Chem. Phys., 21, 16727–16744, https://doi.org/10.5194/acp-21-16727-2021, https://doi.org/10.5194/acp-21-16727-2021, 2021
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We present a new algorithm to retrieve sulfur dioxide from space UV measurements. We apply the technique to high-resolution TROPOMI measurements and demonstrate the high sensitivity of the approach to weak SO2 emissions worldwide with an unprecedented limit of detection of 8 kt yr−1. This result has broad implications for atmospheric science studies dealing with improving emission inventories and identifying and quantifying missing sources, in the context of air quality and climate.
Hugues Brenot, Nicolas Theys, Lieven Clarisse, Jeroen van Gent, Daniel R. Hurtmans, Sophie Vandenbussche, Nikolaos Papagiannopoulos, Lucia Mona, Timo Virtanen, Andreas Uppstu, Mikhail Sofiev, Luca Bugliaro, Margarita Vázquez-Navarro, Pascal Hedelt, Michelle Maree Parks, Sara Barsotti, Mauro Coltelli, William Moreland, Simona Scollo, Giuseppe Salerno, Delia Arnold-Arias, Marcus Hirtl, Tuomas Peltonen, Juhani Lahtinen, Klaus Sievers, Florian Lipok, Rolf Rüfenacht, Alexander Haefele, Maxime Hervo, Saskia Wagenaar, Wim Som de Cerff, Jos de Laat, Arnoud Apituley, Piet Stammes, Quentin Laffineur, Andy Delcloo, Robertson Lennart, Carl-Herbert Rokitansky, Arturo Vargas, Markus Kerschbaum, Christian Resch, Raimund Zopp, Matthieu Plu, Vincent-Henri Peuch, Michel Van Roozendael, and Gerhard Wotawa
Nat. Hazards Earth Syst. Sci., 21, 3367–3405, https://doi.org/10.5194/nhess-21-3367-2021, https://doi.org/10.5194/nhess-21-3367-2021, 2021
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The purpose of the EUNADICS-AV (European Natural Airborne Disaster Information and Coordination System for Aviation) prototype early warning system (EWS) is to develop the combined use of harmonised data products from satellite, ground-based and in situ instruments to produce alerts of airborne hazards (volcanic, dust, smoke and radionuclide clouds), satisfying the requirement of aviation air traffic management (ATM) stakeholders (https://cordis.europa.eu/project/id/723986).
Ulrich Platt, Thomas Wagner, Jonas Kuhn, and Thomas Leisner
Atmos. Meas. Tech., 14, 6867–6883, https://doi.org/10.5194/amt-14-6867-2021, https://doi.org/10.5194/amt-14-6867-2021, 2021
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Absorption spectroscopy of scattered sunlight is extremely useful for the analysis of atmospheric trace gas distributions. A central parameter for the achievable sensitivity of spectroscopic instruments is the light throughput, which can be enhanced in a number of ways. We present new ideas and considerations of how instruments could be optimized. Particular emphasis is on arrays of massively parallel instruments. Such arrays can reduce the size and weight of instruments by orders of magnitude.
Mahesh Kumar Sha, Bavo Langerock, Jean-François L. Blavier, Thomas Blumenstock, Tobias Borsdorff, Matthias Buschmann, Angelika Dehn, Martine De Mazière, Nicholas M. Deutscher, Dietrich G. Feist, Omaira E. García, David W. T. Griffith, Michel Grutter, James W. Hannigan, Frank Hase, Pauli Heikkinen, Christian Hermans, Laura T. Iraci, Pascal Jeseck, Nicholas Jones, Rigel Kivi, Nicolas Kumps, Jochen Landgraf, Alba Lorente, Emmanuel Mahieu, Maria V. Makarova, Johan Mellqvist, Jean-Marc Metzger, Isamu Morino, Tomoo Nagahama, Justus Notholt, Hirofumi Ohyama, Ivan Ortega, Mathias Palm, Christof Petri, David F. Pollard, Markus Rettinger, John Robinson, Sébastien Roche, Coleen M. Roehl, Amelie N. Röhling, Constantina Rousogenous, Matthias Schneider, Kei Shiomi, Dan Smale, Wolfgang Stremme, Kimberly Strong, Ralf Sussmann, Yao Té, Osamu Uchino, Voltaire A. Velazco, Corinne Vigouroux, Mihalis Vrekoussis, Pucai Wang, Thorsten Warneke, Tyler Wizenberg, Debra Wunch, Shoma Yamanouchi, Yang Yang, and Minqiang Zhou
Atmos. Meas. Tech., 14, 6249–6304, https://doi.org/10.5194/amt-14-6249-2021, https://doi.org/10.5194/amt-14-6249-2021, 2021
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This paper presents, for the first time, Sentinel-5 Precursor methane and carbon monoxide validation results covering a period from November 2017 to September 2020. For this study, we used global TCCON and NDACC-IRWG network data covering a wide range of atmospheric and surface conditions across different terrains. We also show the influence of a priori alignment, smoothing uncertainties and the sensitivity of the validation results towards the application of advanced co-location criteria.
Minqiang Zhou, Bavo Langerock, Corinne Vigouroux, Bart Dils, Christian Hermans, Nicolas Kumps, Weidong Nan, Jean-Marc Metzger, Emmanuel Mahieu, Ting Wang, Pucai Wang, and Martine De Mazière
Atmos. Meas. Tech., 14, 6233–6247, https://doi.org/10.5194/amt-14-6233-2021, https://doi.org/10.5194/amt-14-6233-2021, 2021
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NO is a key active trace gas in the atmosphere, which affects the atmospheric environment and human health. In this study, we show that the tropospheric and stratospheric NO partial columns can be observed from the ground-based FTIR measurements at a polluted site (Xianghe, China), but only stratospheric NO partial columns can be observed at a background site (Maïdo, Reunion Island). The variations in the NO observed by the FTIR measurements at the two sites are analyzed and discussed.
Bert Verreyken, Crist Amelynck, Niels Schoon, Jean-François Müller, Jérôme Brioude, Nicolas Kumps, Christian Hermans, Jean-Marc Metzger, Aurélie Colomb, and Trissevgeni Stavrakou
Atmos. Chem. Phys., 21, 12965–12988, https://doi.org/10.5194/acp-21-12965-2021, https://doi.org/10.5194/acp-21-12965-2021, 2021
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We present a 2-year dataset of trace gas concentrations, specifically an array of volatile organic compounds (VOCs), recorded at the Maïdo observatory, a remote tropical high-altitude site located on a small island in the southwest Indian Ocean. We found that island-scale transport is an important driver for the daily cycle of VOC concentrations. During the day, surface emissions from the island affect the atmospheric composition at Maïdo greatly, while at night this impact is strongly reduced.
Xin Tian, Yang Wang, Steffen Beirle, Pinhua Xie, Thomas Wagner, Jin Xu, Ang Li, Steffen Dörner, Bo Ren, and Xiaomei Li
Atmos. Chem. Phys., 21, 12867–12894, https://doi.org/10.5194/acp-21-12867-2021, https://doi.org/10.5194/acp-21-12867-2021, 2021
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The performances of two MAX-DOAS inversion algorithms were evaluated for various aerosol pollution scenarios. One inversion algorithm is based on optimal estimation; the other uses a parameterized approach. In this analysis, three types of profile shapes for aerosols and NO2 were considered: exponential, Boltzmann, and Gaussian. The evaluation results can effectively guide the application of the two inversion algorithms in the actual atmosphere and improve the accuracy of the actual inversion.
Bjorn Stevens, Sandrine Bony, David Farrell, Felix Ament, Alan Blyth, Christopher Fairall, Johannes Karstensen, Patricia K. Quinn, Sabrina Speich, Claudia Acquistapace, Franziska Aemisegger, Anna Lea Albright, Hugo Bellenger, Eberhard Bodenschatz, Kathy-Ann Caesar, Rebecca Chewitt-Lucas, Gijs de Boer, Julien Delanoë, Leif Denby, Florian Ewald, Benjamin Fildier, Marvin Forde, Geet George, Silke Gross, Martin Hagen, Andrea Hausold, Karen J. Heywood, Lutz Hirsch, Marek Jacob, Friedhelm Jansen, Stefan Kinne, Daniel Klocke, Tobias Kölling, Heike Konow, Marie Lothon, Wiebke Mohr, Ann Kristin Naumann, Louise Nuijens, Léa Olivier, Robert Pincus, Mira Pöhlker, Gilles Reverdin, Gregory Roberts, Sabrina Schnitt, Hauke Schulz, A. Pier Siebesma, Claudia Christine Stephan, Peter Sullivan, Ludovic Touzé-Peiffer, Jessica Vial, Raphaela Vogel, Paquita Zuidema, Nicola Alexander, Lyndon Alves, Sophian Arixi, Hamish Asmath, Gholamhossein Bagheri, Katharina Baier, Adriana Bailey, Dariusz Baranowski, Alexandre Baron, Sébastien Barrau, Paul A. Barrett, Frédéric Batier, Andreas Behrendt, Arne Bendinger, Florent Beucher, Sebastien Bigorre, Edmund Blades, Peter Blossey, Olivier Bock, Steven Böing, Pierre Bosser, Denis Bourras, Pascale Bouruet-Aubertot, Keith Bower, Pierre Branellec, Hubert Branger, Michal Brennek, Alan Brewer, Pierre-Etienne Brilouet, Björn Brügmann, Stefan A. Buehler, Elmo Burke, Ralph Burton, Radiance Calmer, Jean-Christophe Canonici, Xavier Carton, Gregory Cato Jr., Jude Andre Charles, Patrick Chazette, Yanxu Chen, Michal T. Chilinski, Thomas Choularton, Patrick Chuang, Shamal Clarke, Hugh Coe, Céline Cornet, Pierre Coutris, Fleur Couvreux, Susanne Crewell, Timothy Cronin, Zhiqiang Cui, Yannis Cuypers, Alton Daley, Gillian M. Damerell, Thibaut Dauhut, Hartwig Deneke, Jean-Philippe Desbios, Steffen Dörner, Sebastian Donner, Vincent Douet, Kyla Drushka, Marina Dütsch, André Ehrlich, Kerry Emanuel, Alexandros Emmanouilidis, Jean-Claude Etienne, Sheryl Etienne-Leblanc, Ghislain Faure, Graham Feingold, Luca Ferrero, Andreas Fix, Cyrille Flamant, Piotr Jacek Flatau, Gregory R. Foltz, Linda Forster, Iulian Furtuna, Alan Gadian, Joseph Galewsky, Martin Gallagher, Peter Gallimore, Cassandra Gaston, Chelle Gentemann, Nicolas Geyskens, Andreas Giez, John Gollop, Isabelle Gouirand, Christophe Gourbeyre, Dörte de Graaf, Geiske E. de Groot, Robert Grosz, Johannes Güttler, Manuel Gutleben, Kashawn Hall, George Harris, Kevin C. Helfer, Dean Henze, Calvert Herbert, Bruna Holanda, Antonio Ibanez-Landeta, Janet Intrieri, Suneil Iyer, Fabrice Julien, Heike Kalesse, Jan Kazil, Alexander Kellman, Abiel T. Kidane, Ulrike Kirchner, Marcus Klingebiel, Mareike Körner, Leslie Ann Kremper, Jan Kretzschmar, Ovid Krüger, Wojciech Kumala, Armin Kurz, Pierre L'Hégaret, Matthieu Labaste, Tom Lachlan-Cope, Arlene Laing, Peter Landschützer, Theresa Lang, Diego Lange, Ingo Lange, Clément Laplace, Gauke Lavik, Rémi Laxenaire, Caroline Le Bihan, Mason Leandro, Nathalie Lefevre, Marius Lena, Donald Lenschow, Qiang Li, Gary Lloyd, Sebastian Los, Niccolò Losi, Oscar Lovell, Christopher Luneau, Przemyslaw Makuch, Szymon Malinowski, Gaston Manta, Eleni Marinou, Nicholas Marsden, Sebastien Masson, Nicolas Maury, Bernhard Mayer, Margarette Mayers-Als, Christophe Mazel, Wayne McGeary, James C. McWilliams, Mario Mech, Melina Mehlmann, Agostino Niyonkuru Meroni, Theresa Mieslinger, Andreas Minikin, Peter Minnett, Gregor Möller, Yanmichel Morfa Avalos, Caroline Muller, Ionela Musat, Anna Napoli, Almuth Neuberger, Christophe Noisel, David Noone, Freja Nordsiek, Jakub L. Nowak, Lothar Oswald, Douglas J. Parker, Carolyn Peck, Renaud Person, Miriam Philippi, Albert Plueddemann, Christopher Pöhlker, Veronika Pörtge, Ulrich Pöschl, Lawrence Pologne, Michał Posyniak, Marc Prange, Estefanía Quiñones Meléndez, Jule Radtke, Karim Ramage, Jens Reimann, Lionel Renault, Klaus Reus, Ashford Reyes, Joachim Ribbe, Maximilian Ringel, Markus Ritschel, Cesar B. Rocha, Nicolas Rochetin, Johannes Röttenbacher, Callum Rollo, Haley Royer, Pauline Sadoulet, Leo Saffin, Sanola Sandiford, Irina Sandu, Michael Schäfer, Vera Schemann, Imke Schirmacher, Oliver Schlenczek, Jerome Schmidt, Marcel Schröder, Alfons Schwarzenboeck, Andrea Sealy, Christoph J. Senff, Ilya Serikov, Samkeyat Shohan, Elizabeth Siddle, Alexander Smirnov, Florian Späth, Branden Spooner, M. Katharina Stolla, Wojciech Szkółka, Simon P. de Szoeke, Stéphane Tarot, Eleni Tetoni, Elizabeth Thompson, Jim Thomson, Lorenzo Tomassini, Julien Totems, Alma Anna Ubele, Leonie Villiger, Jan von Arx, Thomas Wagner, Andi Walther, Ben Webber, Manfred Wendisch, Shanice Whitehall, Anton Wiltshire, Allison A. Wing, Martin Wirth, Jonathan Wiskandt, Kevin Wolf, Ludwig Worbes, Ethan Wright, Volker Wulfmeyer, Shanea Young, Chidong Zhang, Dongxiao Zhang, Florian Ziemen, Tobias Zinner, and Martin Zöger
Earth Syst. Sci. Data, 13, 4067–4119, https://doi.org/10.5194/essd-13-4067-2021, https://doi.org/10.5194/essd-13-4067-2021, 2021
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The EUREC4A field campaign, designed to test hypothesized mechanisms by which clouds respond to warming and benchmark next-generation Earth-system models, is presented. EUREC4A comprised roughly 5 weeks of measurements in the downstream winter trades of the North Atlantic – eastward and southeastward of Barbados. It was the first campaign that attempted to characterize the full range of processes and scales influencing trade wind clouds.
Kai Krause, Folkard Wittrock, Andreas Richter, Stefan Schmitt, Denis Pöhler, Andreas Weigelt, and John P. Burrows
Atmos. Meas. Tech., 14, 5791–5807, https://doi.org/10.5194/amt-14-5791-2021, https://doi.org/10.5194/amt-14-5791-2021, 2021
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Ships are an important source of key pollutants. Usually, these are measured aboard the ship or on the coast using in situ instruments. This study shows how active optical remote sensing can be used to measure ship emissions and how to determine emission rates of individual ships out of those measurements. These emission rates are valuable input for the assessment of the influence of shipping emissions in regions close to the shipping lanes.
Isabelle De Smedt, Gaia Pinardi, Corinne Vigouroux, Steven Compernolle, Alkis Bais, Nuria Benavent, Folkert Boersma, Ka-Lok Chan, Sebastian Donner, Kai-Uwe Eichmann, Pascal Hedelt, François Hendrick, Hitoshi Irie, Vinod Kumar, Jean-Christopher Lambert, Bavo Langerock, Christophe Lerot, Cheng Liu, Diego Loyola, Ankie Piters, Andreas Richter, Claudia Rivera Cárdenas, Fabian Romahn, Robert George Ryan, Vinayak Sinha, Nicolas Theys, Jonas Vlietinck, Thomas Wagner, Ting Wang, Huan Yu, and Michel Van Roozendael
Atmos. Chem. Phys., 21, 12561–12593, https://doi.org/10.5194/acp-21-12561-2021, https://doi.org/10.5194/acp-21-12561-2021, 2021
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This paper assess the performances of the TROPOMI formaldehyde observations compared to its predecessor OMI at different spatial and temporal scales. We also use a global network of MAX-DOAS instruments to validate both satellite datasets for a large range of HCHO columns. The precision obtained with daily TROPOMI observations is comparable to monthly OMI observations. We present clear detection of weak HCHO column enhancements related to shipping emissions in the Indian Ocean.
Panagiotis G. Kosmopoulos, Stelios Kazadzis, Alois W. Schmalwieser, Panagiotis I. Raptis, Kyriakoula Papachristopoulou, Ilias Fountoulakis, Akriti Masoom, Alkiviadis F. Bais, Julia Bilbao, Mario Blumthaler, Axel Kreuter, Anna Maria Siani, Kostas Eleftheratos, Chrysanthi Topaloglou, Julian Gröbner, Bjørn Johnsen, Tove M. Svendby, Jose Manuel Vilaplana, Lionel Doppler, Ann R. Webb, Marina Khazova, Hugo De Backer, Anu Heikkilä, Kaisa Lakkala, Janusz Jaroslawski, Charikleia Meleti, Henri Diémoz, Gregor Hülsen, Barbara Klotz, John Rimmer, and Charalampos Kontoes
Atmos. Meas. Tech., 14, 5657–5699, https://doi.org/10.5194/amt-14-5657-2021, https://doi.org/10.5194/amt-14-5657-2021, 2021
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Large-scale retrievals of the ultraviolet index (UVI) in real time by exploiting the modern Earth observation data and techniques are capable of forming operational early warning systems that raise awareness among citizens of the health implications of high UVI doses. In this direction a novel UVI operating system, the so-called UVIOS, was introduced for massive outputs, while its performance was tested against ground-based measurements revealing a dependence on the input quality and resolution.
Anoop S. Mahajan, Mriganka S. Biswas, Steffen Beirle, Thomas Wagner, Anja Schönhardt, Nuria Benavent, and Alfonso Saiz-Lopez
Atmos. Chem. Phys., 21, 11829–11842, https://doi.org/10.5194/acp-21-11829-2021, https://doi.org/10.5194/acp-21-11829-2021, 2021
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Iodine plays a vital role in oxidation chemistry over Antarctica, with past observations showing highly elevated levels of iodine oxide (IO) leading to severe depletion of boundary layer ozone. We present IO observations over three summers (2015–2017) at the Indian Antarctic bases of Bharati and Maitri. IO was observed during all campaigns with mixing ratios below 2 pptv, which is lower than the peak levels observed in West Antarctica, showing the differences in regional chemistry and emissions.
Stefan F. Schreier, Tim Bösch, Andreas Richter, Kezia Lange, Michael Revesz, Philipp Weihs, Mihalis Vrekoussis, and Christoph Lotteraner
Atmos. Meas. Tech., 14, 5299–5318, https://doi.org/10.5194/amt-14-5299-2021, https://doi.org/10.5194/amt-14-5299-2021, 2021
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This paper reports on the evaluation of aerosol profiling products retrieved from ground-based MAX-DOAS instruments using the BOREAS algorithm. Aerosol extinction profiles, near-surface aerosol extinction, and aerosol optical depth are compared to measurements collected with ceilometer, sun photometer, and in situ instruments. We show that these MAX-DOAS aerosol profiling products provide useful information to study spatial and temporal variations above the urban area of Vienna.
Vinod Kumar, Julia Remmers, Steffen Beirle, Joachim Fallmann, Astrid Kerkweg, Jos Lelieveld, Mariano Mertens, Andrea Pozzer, Benedikt Steil, Marc Barra, Holger Tost, and Thomas Wagner
Atmos. Meas. Tech., 14, 5241–5269, https://doi.org/10.5194/amt-14-5241-2021, https://doi.org/10.5194/amt-14-5241-2021, 2021
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We present high-resolution regional atmospheric chemistry model simulations focused around Germany. We highlight the importance of spatial resolution of the model itself as well as the input emissions inventory and short-scale temporal variability of emissions for simulations. We propose a consistent approach for evaluating the simulated vertical distribution of NO2 using MAX-DOAS measurements while also considering its spatial sensitivity volume and change in sensitivity within this volume.
Ilya Stanevich, Dylan B. A. Jones, Kimberly Strong, Martin Keller, Daven K. Henze, Robert J. Parker, Hartmut Boesch, Debra Wunch, Justus Notholt, Christof Petri, Thorsten Warneke, Ralf Sussmann, Matthias Schneider, Frank Hase, Rigel Kivi, Nicholas M. Deutscher, Voltaire A. Velazco, Kaley A. Walker, and Feng Deng
Atmos. Chem. Phys., 21, 9545–9572, https://doi.org/10.5194/acp-21-9545-2021, https://doi.org/10.5194/acp-21-9545-2021, 2021
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We explore the utility of a weak-constraint (WC) four-dimensional variational (4D-Var) data assimilation scheme for mitigating systematic errors in methane simulation in the GEOS-Chem model. We use data from the Greenhouse Gases Observing Satellite (GOSAT) and show that, compared to the traditional 4D-Var approach, the WC scheme improves the agreement between the model and independent observations. We find that the WC corrections to the model provide insight into the source of the errors.
Steffen Beirle, Christian Borger, Steffen Dörner, Henk Eskes, Vinod Kumar, Adrianus de Laat, and Thomas Wagner
Earth Syst. Sci. Data, 13, 2995–3012, https://doi.org/10.5194/essd-13-2995-2021, https://doi.org/10.5194/essd-13-2995-2021, 2021
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A catalog of point sources of nitrogen oxides was created using satellite observations of NO2. Key for the identification of point sources was the divergence, i.e., the difference between upwind and downwind levels of NO2.
The catalog lists 451 locations, of which 242 could be automatically matched to power plants. Other point sources are metal smelters, cement plants, or industrial areas. The catalog thus allows checking and improving of existing emission inventories.
Matthieu Dogniaux, Cyril Crevoisier, Raymond Armante, Virginie Capelle, Thibault Delahaye, Vincent Cassé, Martine De Mazière, Nicholas M. Deutscher, Dietrich G. Feist, Omaira E. Garcia, David W. T. Griffith, Frank Hase, Laura T. Iraci, Rigel Kivi, Isamu Morino, Justus Notholt, David F. Pollard, Coleen M. Roehl, Kei Shiomi, Kimberly Strong, Yao Té, Voltaire A. Velazco, and Thorsten Warneke
Atmos. Meas. Tech., 14, 4689–4706, https://doi.org/10.5194/amt-14-4689-2021, https://doi.org/10.5194/amt-14-4689-2021, 2021
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We present the Adaptable 4A Inversion (5AI), an implementation of the optimal estimation (OE) algorithm, relying on the Automatized Atmospheric Absorption Atlas (4A/OP) radiative transfer model, that enables the retrieval of greenhouse gas atmospheric weighted columns from infrared measurements. It is tested on a sample of Orbiting Carbon Observatory-2 observations, and its results satisfactorily compare to several reference products, thus showing the reliability of 5AI OE implementation.
Florian Dinger, Timo Kleinbek, Steffen Dörner, Nicole Bobrowski, Ulrich Platt, Thomas Wagner, Martha Ibarra, and Eveling Espinoza
Atmos. Chem. Phys., 21, 9367–9404, https://doi.org/10.5194/acp-21-9367-2021, https://doi.org/10.5194/acp-21-9367-2021, 2021
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Monitoring magnitude or chemical composition of volcanic gas emissions can help to forecast volcanic eruptions and provides empirical data on the impact of volcanoes on the chemistry in the local and global atmosphere. This study reports and discusses continuous time series of the sulfur and bromine emission fluxes of Masaya from 2014 to 2020. We observed an annual cyclicity in the BrO / SO2 molar ratio, possibly caused by the annual variability in the atmospheric humidity.
Holger Sihler, Steffen Beirle, Steffen Dörner, Marloes Gutenstein-Penning de Vries, Christoph Hörmann, Christian Borger, Simon Warnach, and Thomas Wagner
Atmos. Meas. Tech., 14, 3989–4031, https://doi.org/10.5194/amt-14-3989-2021, https://doi.org/10.5194/amt-14-3989-2021, 2021
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MICRU is an algorithm for the retrieval of effective cloud fractions (CFs) from satellite measurements. CFs describe the amount of clouds, which have a significant impact on the vertical sensitivity profile of trace gases like NO2 and HCHO. MICRU retrieves small CFs with an accuracy of 0.04 over the entire satellite swath. It features an empirical surface reflectivity model accounting for physical anisotropy (BRDF, sun glitter) and instrumental effects. MICRU is also applicable to imager data.
Thomas Wagner, Steffen Dörner, Steffen Beirle, Sebastian Donner, and Stefan Kinne
Atmos. Meas. Tech., 14, 3871–3893, https://doi.org/10.5194/amt-14-3871-2021, https://doi.org/10.5194/amt-14-3871-2021, 2021
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We compare measured and simulated O4 absorptions for conditions of extremely low aerosol optical depth, for which the uncertainties related to imperfect knowledge of aerosol properties do not significantly affect the comparison results. The simulations underestimate the measurements by 15 % to 20 %. Even if no aerosols are considered, the simulated O4 absorptions are systematically lower than the measurements. Our results indicate a fundamental inconsistency between simulations and measurements.
Maximilian Herrmann, Holger Sihler, Udo Frieß, Thomas Wagner, Ulrich Platt, and Eva Gutheil
Atmos. Chem. Phys., 21, 7611–7638, https://doi.org/10.5194/acp-21-7611-2021, https://doi.org/10.5194/acp-21-7611-2021, 2021
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Time-dependent 3D numerical simulations of tropospheric bromine release and ozone depletion events (ODEs) in the Arctic polar spring of 2009 are compared to observations. Simulation results agree well with the observations at both Utqiaġvik, Alaska, and at Summit, Greenland. In a parameter study, different settings for the bromine release mechanism are evaluated. An enhancement of the bromine release mechanism improves the agreement regarding the occurrence of ODEs with the observations.
Viktoria F. Sofieva, Monika Szeląg, Johanna Tamminen, Erkki Kyrölä, Doug Degenstein, Chris Roth, Daniel Zawada, Alexei Rozanov, Carlo Arosio, John P. Burrows, Mark Weber, Alexandra Laeng, Gabriele P. Stiller, Thomas von Clarmann, Lucien Froidevaux, Nathaniel Livesey, Michel van Roozendael, and Christian Retscher
Atmos. Chem. Phys., 21, 6707–6720, https://doi.org/10.5194/acp-21-6707-2021, https://doi.org/10.5194/acp-21-6707-2021, 2021
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The MErged GRIdded Dataset of Ozone Profiles is a long-term (2001–2018) stratospheric ozone profile climate data record with resolved longitudinal structure that combines the data from six limb satellite instruments. The dataset can be used for various analyses, some of which are discussed in the paper. In particular, regionally and vertically resolved ozone trends are evaluated, including trends in the polar regions.
Sébastien Roche, Kimberly Strong, Debra Wunch, Joseph Mendonca, Colm Sweeney, Bianca Baier, Sébastien C. Biraud, Joshua L. Laughner, Geoffrey C. Toon, and Brian J. Connor
Atmos. Meas. Tech., 14, 3087–3118, https://doi.org/10.5194/amt-14-3087-2021, https://doi.org/10.5194/amt-14-3087-2021, 2021
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We evaluate CO2 profile retrievals from ground-based near-infrared solar absorption spectra after implementing several improvements to the GFIT2 retrieval algorithm. Realistic errors in the a priori temperature profile (~ 2 °C in the lower troposphere) are found to be the leading source of differences between the retrieved and true CO2 profiles, differences that are larger than typical CO2 variability. A temperature retrieval or correction is critical to improve CO2 profile retrieval results.
Thomas Wagner, Steffen Beirle, Steffen Dörner, Christian Borger, and Roeland Van Malderen
Atmos. Chem. Phys., 21, 5315–5353, https://doi.org/10.5194/acp-21-5315-2021, https://doi.org/10.5194/acp-21-5315-2021, 2021
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A global long-term (1995–2015) data set of total column water vapour (TCWV) derived from satellite observations is used to quantify the influence of teleconnections. Based on a newly developed empirical method more than 40 teleconnection indices are significantly detected in our global TCWV data set. After orthogonalisation, only 20 indices are left significant. The global distribution of the cumulative influence of teleconnection indices is strongest in the tropics and high latitudes.
Ioanna Skoulidou, Maria-Elissavet Koukouli, Astrid Manders, Arjo Segers, Dimitris Karagkiozidis, Myrto Gratsea, Dimitris Balis, Alkiviadis Bais, Evangelos Gerasopoulos, Trisevgeni Stavrakou, Jos van Geffen, Henk Eskes, and Andreas Richter
Atmos. Chem. Phys., 21, 5269–5288, https://doi.org/10.5194/acp-21-5269-2021, https://doi.org/10.5194/acp-21-5269-2021, 2021
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The performance of LOTOS-EUROS v2.2.001 regional chemical transport model NO2 simulations is investigated over Greece from June to December 2018. Comparison with in situ NO2 measurements shows a spatial correlation coefficient of 0.86, while the model underestimates the concentrations mostly during daytime (12 to 15:00 local time). Further, the simulated tropospheric NO2 columns are evaluated against ground-based MAX-DOAS NO2 measurements and S5P/TROPOMI observations for July and December 2018.
Xiaoyi Zhao, Vitali Fioletov, Michael Brohart, Volodya Savastiouk, Ihab Abboud, Akira Ogyu, Jonathan Davies, Reno Sit, Sum Chi Lee, Alexander Cede, Martin Tiefengraber, Moritz Müller, Debora Griffin, and Chris McLinden
Atmos. Meas. Tech., 14, 2261–2283, https://doi.org/10.5194/amt-14-2261-2021, https://doi.org/10.5194/amt-14-2261-2021, 2021
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The Brewer spectrophotometer is one of the main instruments for measurements of atmospheric total column ozone. The global Brewer network largely relies on the world reference instruments (the Brewer triad) operated by Environment and Climate Change Canada since the early 1980s. This study provides an updated assessment (1999–2019) of the reference instrument performance, in terms of random uncertainties and long-term stability.
Julian Rüdiger, Alexandra Gutmann, Nicole Bobrowski, Marcello Liotta, J. Maarten de Moor, Rolf Sander, Florian Dinger, Jan-Lukas Tirpitz, Martha Ibarra, Armando Saballos, María Martínez, Elvis Mendoza, Arnoldo Ferrufino, John Stix, Juan Valdés, Jonathan M. Castro, and Thorsten Hoffmann
Atmos. Chem. Phys., 21, 3371–3393, https://doi.org/10.5194/acp-21-3371-2021, https://doi.org/10.5194/acp-21-3371-2021, 2021
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We present an innovative approach to study halogen chemistry in the plume of Masaya volcano in Nicaragua. An unique data set was collected using multiple techniques, including drones. These data enabled us to determine the fraction of activation of the respective halogens at various plume ages, where in-mixing of ambient air causes chemical reactions. An atmospheric chemistry box model was employed to further examine the field results and help our understanding of volcanic plume chemistry.
Thomas Blumenstock, Frank Hase, Axel Keens, Denis Czurlok, Orfeo Colebatch, Omaira Garcia, David W. T. Griffith, Michel Grutter, James W. Hannigan, Pauli Heikkinen, Pascal Jeseck, Nicholas Jones, Rigel Kivi, Erik Lutsch, Maria Makarova, Hamud K. Imhasin, Johan Mellqvist, Isamu Morino, Tomoo Nagahama, Justus Notholt, Ivan Ortega, Mathias Palm, Uwe Raffalski, Markus Rettinger, John Robinson, Matthias Schneider, Christian Servais, Dan Smale, Wolfgang Stremme, Kimberly Strong, Ralf Sussmann, Yao Té, and Voltaire A. Velazco
Atmos. Meas. Tech., 14, 1239–1252, https://doi.org/10.5194/amt-14-1239-2021, https://doi.org/10.5194/amt-14-1239-2021, 2021
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This study investigates the level of channeling (optical resonances) of each FTIR spectrometer within the Network for the Detection of Atmospheric Composition Change (NDACC). Since the air gap of the beam splitter is a significant source of channeling, we propose new beam splitters with an increased wedge of the air gap. This study shows the potential for reducing channeling in the FTIR spectrometers operated by the NDACC, thereby increasing the quality of recorded spectra across the network.
Shoma Yamanouchi, Camille Viatte, Kimberly Strong, Erik Lutsch, Dylan B. A. Jones, Cathy Clerbaux, Martin Van Damme, Lieven Clarisse, and Pierre-Francois Coheur
Atmos. Meas. Tech., 14, 905–921, https://doi.org/10.5194/amt-14-905-2021, https://doi.org/10.5194/amt-14-905-2021, 2021
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Ammonia (NH3) is a major source of pollution in the air. As such, there have been increasing efforts to measure the atmospheric abundance of NH3 and its spatial and temporal variability. In this study, long-term measurements of NH3 over Toronto, Canada, derived from multiscale datasets are examined. These NH3 datasets were compared to each other and to a model to better understand NH3 variability and to assess model performance.
Bianca Lauster, Steffen Dörner, Steffen Beirle, Sebastian Donner, Sergey Gromov, Katharina Uhlmannsiek, and Thomas Wagner
Atmos. Meas. Tech., 14, 769–783, https://doi.org/10.5194/amt-14-769-2021, https://doi.org/10.5194/amt-14-769-2021, 2021
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In urban areas, road traffic is a dominant source of nitrogen oxides. In this study, two multi-axis differential optical absorption spectroscopy (MAX-DOAS) instruments on opposite sides of a motorway were used to measure the nitrogen dioxide absorption near Mainz, Germany. Total nitrogen oxide emissions are estimated for the occurring traffic flux. We show that the measured emissions systematically exceed the maximum expected emissions calculated from the European emission standards.
Myrto Gratsea, Tim Bösch, Panagiotis Kokkalis, Andreas Richter, Mihalis Vrekoussis, Stelios Kazadzis, Alexandra Tsekeri, Alexandros Papayannis, Maria Mylonaki, Vassilis Amiridis, Nikos Mihalopoulos, and Evangelos Gerasopoulos
Atmos. Meas. Tech., 14, 749–767, https://doi.org/10.5194/amt-14-749-2021, https://doi.org/10.5194/amt-14-749-2021, 2021
Frederik Tack, Alexis Merlaud, Marian-Daniel Iordache, Gaia Pinardi, Ermioni Dimitropoulou, Henk Eskes, Bart Bomans, Pepijn Veefkind, and Michel Van Roozendael
Atmos. Meas. Tech., 14, 615–646, https://doi.org/10.5194/amt-14-615-2021, https://doi.org/10.5194/amt-14-615-2021, 2021
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We assess the TROPOMI tropospheric NO2 product (OFFL v1.03.01; 3.5 km × 7 km at nadir observations) based on coinciding airborne APEX reference observations (~75 m × 120 m), acquired over polluted regions in Belgium. The TROPOMI NO2 product meets the mission requirements in terms of precision and accuracy. However, we show that TROPOMI is biased low over polluted areas, mainly due to the limited spatial resolution of a priori input for the AMF computation.
Elena Spinei, Martin Tiefengraber, Moritz Müller, Manuel Gebetsberger, Alexander Cede, Luke Valin, James Szykman, Andrew Whitehill, Alexander Kotsakis, Fernando Santos, Nader Abbuhasan, Xiaoyi Zhao, Vitali Fioletov, Sum Chi Lee, and Robert Swap
Atmos. Meas. Tech., 14, 647–663, https://doi.org/10.5194/amt-14-647-2021, https://doi.org/10.5194/amt-14-647-2021, 2021
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Plastics are widely used in everyday life and scientific equipment. This paper presents Delrin plastic off-gassing as a function of temperature on the atmospheric measurements of formaldehyde by Pandora spectroscopic instruments. The sealed telescope assembly containing Delrin components emitted large amounts of formaldehyde at 30–45 °C, interfering with the Pandora measurements. These results have a broader implication since electronic products often experience the same temperature.
Tijl Verhoelst, Steven Compernolle, Gaia Pinardi, Jean-Christopher Lambert, Henk J. Eskes, Kai-Uwe Eichmann, Ann Mari Fjæraa, José Granville, Sander Niemeijer, Alexander Cede, Martin Tiefengraber, François Hendrick, Andrea Pazmiño, Alkiviadis Bais, Ariane Bazureau, K. Folkert Boersma, Kristof Bognar, Angelika Dehn, Sebastian Donner, Aleksandr Elokhov, Manuel Gebetsberger, Florence Goutail, Michel Grutter de la Mora, Aleksandr Gruzdev, Myrto Gratsea, Georg H. Hansen, Hitoshi Irie, Nis Jepsen, Yugo Kanaya, Dimitris Karagkiozidis, Rigel Kivi, Karin Kreher, Pieternel F. Levelt, Cheng Liu, Moritz Müller, Monica Navarro Comas, Ankie J. M. Piters, Jean-Pierre Pommereau, Thierry Portafaix, Cristina Prados-Roman, Olga Puentedura, Richard Querel, Julia Remmers, Andreas Richter, John Rimmer, Claudia Rivera Cárdenas, Lidia Saavedra de Miguel, Valery P. Sinyakov, Wolfgang Stremme, Kimberly Strong, Michel Van Roozendael, J. Pepijn Veefkind, Thomas Wagner, Folkard Wittrock, Margarita Yela González, and Claus Zehner
Atmos. Meas. Tech., 14, 481–510, https://doi.org/10.5194/amt-14-481-2021, https://doi.org/10.5194/amt-14-481-2021, 2021
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This paper reports on the ground-based validation of the NO2 data produced operationally by the TROPOMI instrument on board the Sentinel-5 Precursor satellite. Tropospheric, stratospheric, and total NO2 columns are compared to measurements collected from MAX-DOAS, ZSL-DOAS, and PGN/Pandora instruments respectively. The products are found to satisfy mission requirements in general, though negative mean differences are found at sites with high pollution levels. Potential causes are discussed.
Martin Dameris, Diego G. Loyola, Matthias Nützel, Melanie Coldewey-Egbers, Christophe Lerot, Fabian Romahn, and Michel van Roozendael
Atmos. Chem. Phys., 21, 617–633, https://doi.org/10.5194/acp-21-617-2021, https://doi.org/10.5194/acp-21-617-2021, 2021
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Record low ozone values were observed in March 2020. Dynamical and chemical circumstances leading to low ozone values in spring 2020 are discussed and are compared to similar dynamical conditions in the Northern Hemisphere in 1996/1997 and 2010/2011. 2019/2020 showed an unusual persistent polar vortex with low stratospheric temperatures, which were permanently below 195 K at 50 hPa. This enabled enhanced formation of polar stratospheric clouds and a subsequent clear reduction of total ozone.
Christopher Fuchs, Jonas Kuhn, Nicole Bobrowski, and Ulrich Platt
Atmos. Meas. Tech., 14, 295–307, https://doi.org/10.5194/amt-14-295-2021, https://doi.org/10.5194/amt-14-295-2021, 2021
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We present first measurements of volcanic SO2 emissions with a novel imaging technique for atmospheric trace gases in the UV and visible spectral range. Periodic spectral Fabry–Pérot interferometer transmission features are matched to differential absorption cross sections of the investigated trace gas, yielding high selectivity and sensitivity. The technique can be extended to measure many other trace gases with high spatio-temporal resolution.
Jan-Lukas Tirpitz, Udo Frieß, François Hendrick, Carlos Alberti, Marc Allaart, Arnoud Apituley, Alkis Bais, Steffen Beirle, Stijn Berkhout, Kristof Bognar, Tim Bösch, Ilya Bruchkouski, Alexander Cede, Ka Lok Chan, Mirjam den Hoed, Sebastian Donner, Theano Drosoglou, Caroline Fayt, Martina M. Friedrich, Arnoud Frumau, Lou Gast, Clio Gielen, Laura Gomez-Martín, Nan Hao, Arjan Hensen, Bas Henzing, Christian Hermans, Junli Jin, Karin Kreher, Jonas Kuhn, Johannes Lampel, Ang Li, Cheng Liu, Haoran Liu, Jianzhong Ma, Alexis Merlaud, Enno Peters, Gaia Pinardi, Ankie Piters, Ulrich Platt, Olga Puentedura, Andreas Richter, Stefan Schmitt, Elena Spinei, Deborah Stein Zweers, Kimberly Strong, Daan Swart, Frederik Tack, Martin Tiefengraber, René van der Hoff, Michel van Roozendael, Tim Vlemmix, Jan Vonk, Thomas Wagner, Yang Wang, Zhuoru Wang, Mark Wenig, Matthias Wiegner, Folkard Wittrock, Pinhua Xie, Chengzhi Xing, Jin Xu, Margarita Yela, Chengxin Zhang, and Xiaoyi Zhao
Atmos. Meas. Tech., 14, 1–35, https://doi.org/10.5194/amt-14-1-2021, https://doi.org/10.5194/amt-14-1-2021, 2021
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Multi-axis differential optical absorption spectroscopy (MAX-DOAS) is a ground-based remote sensing measurement technique that derives atmospheric aerosol and trace gas vertical profiles from skylight spectra. In this study, consistency and reliability of MAX-DOAS profiles are assessed by applying nine different evaluation algorithms to spectral data recorded during an intercomparison campaign in the Netherlands and by comparing the results to colocated supporting observations.
Xin Yang, Anne-M. Blechschmidt, Kristof Bognar, Audra McClure-Begley, Sara Morris, Irina Petropavlovskikh, Andreas Richter, Henrik Skov, Kimberly Strong, David W. Tarasick, Taneil Uttal, Mika Vestenius, and Xiaoyi Zhao
Atmos. Chem. Phys., 20, 15937–15967, https://doi.org/10.5194/acp-20-15937-2020, https://doi.org/10.5194/acp-20-15937-2020, 2020
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This is a modelling-based study on Arctic surface ozone, with a particular focus on spring ozone depletion events (i.e. with concentrations < 10 ppbv). Model experiments show that model runs with blowing-snow-sourced sea salt aerosols implemented as a source of reactive bromine can reproduce well large-scale ozone depletion events observed in the Arctic. This study supplies modelling evidence of the proposed mechanism of reactive-bromine release from blowing snow on sea ice (Yang et al., 2008).
Kaisa Lakkala, Jukka Kujanpää, Colette Brogniez, Nicolas Henriot, Antti Arola, Margit Aun, Frédérique Auriol, Alkiviadis F. Bais, Germar Bernhard, Veerle De Bock, Maxime Catalfamo, Christine Deroo, Henri Diémoz, Luca Egli, Jean-Baptiste Forestier, Ilias Fountoulakis, Katerina Garane, Rosa Delia Garcia, Julian Gröbner, Seppo Hassinen, Anu Heikkilä, Stuart Henderson, Gregor Hülsen, Bjørn Johnsen, Niilo Kalakoski, Angelos Karanikolas, Tomi Karppinen, Kevin Lamy, Sergio F. León-Luis, Anders V. Lindfors, Jean-Marc Metzger, Fanny Minvielle, Harel B. Muskatel, Thierry Portafaix, Alberto Redondas, Ricardo Sanchez, Anna Maria Siani, Tove Svendby, and Johanna Tamminen
Atmos. Meas. Tech., 13, 6999–7024, https://doi.org/10.5194/amt-13-6999-2020, https://doi.org/10.5194/amt-13-6999-2020, 2020
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The TROPOspheric Monitoring Instrument (TROPOMI) onboard the Sentinel-5 Precursor (S5P) satellite was launched on 13 October 2017 to provide the atmospheric composition for atmosphere and climate research. Ground-based data from 25 sites located in Arctic, subarctic, temperate, equatorial and Antarctic
areas were used for the validation of the TROPOMI surface ultraviolet (UV) radiation product. For most sites 60 %–80 % of TROPOMI data was within ± 20 % of ground-based data.
Robert J. Parker, Alex Webb, Hartmut Boesch, Peter Somkuti, Rocio Barrio Guillo, Antonio Di Noia, Nikoleta Kalaitzi, Jasdeep S. Anand, Peter Bergamaschi, Frederic Chevallier, Paul I. Palmer, Liang Feng, Nicholas M. Deutscher, Dietrich G. Feist, David W. T. Griffith, Frank Hase, Rigel Kivi, Isamu Morino, Justus Notholt, Young-Suk Oh, Hirofumi Ohyama, Christof Petri, David F. Pollard, Coleen Roehl, Mahesh K. Sha, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Yao Té, Voltaire A. Velazco, Thorsten Warneke, Paul O. Wennberg, and Debra Wunch
Earth Syst. Sci. Data, 12, 3383–3412, https://doi.org/10.5194/essd-12-3383-2020, https://doi.org/10.5194/essd-12-3383-2020, 2020
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This work presents the latest release of the University of Leicester GOSAT methane data and acts as the definitive description of this dataset. We detail the processing, validation and evaluation involved in producing these data and highlight its many applications. With now over a decade of global atmospheric methane observations, this dataset has helped, and will continue to help, us better understand the global methane budget and investigate how it may respond to a future changing climate.
Ke Tang, Min Qin, Wu Fang, Jun Duan, Fanhao Meng, Kaidi Ye, Helu Zhang, Pinhua Xie, Yabai He, Wenbin Xu, Jianguo Liu, and Wenqing Liu
Atmos. Meas. Tech., 13, 6487–6499, https://doi.org/10.5194/amt-13-6487-2020, https://doi.org/10.5194/amt-13-6487-2020, 2020
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We present an improved instrument for the simultaneous detection of atmospheric nitrous acid (HONO) and nitrogen dioxide (NO2). The robustness of the system is verified by simulating the influence of the relative change in light intensity on the measurement results. The instrument's capability to make fast high-sensitivity measurements of HONO and NO2 is of great significance for understanding the source of HONO and studying its role in atmospheric chemistry.
Cited articles
Bruchkouski, I., Dziomin, V., and Krasouski, A.: Seasonal variability of the
atmospheric trace constituents in Antarctica, 35th Canadian
Symposium of Remote Sensing (IGARSS-2014), https://doi.org/10.1109/IGARSS.2014.6947387, 2014. a
Cantrell, C. A.: Technical Note: Review of methods for linear least-squares fitting of data and application to atmospheric chemistry problems, Atmos. Chem. Phys., 8, 5477–5487, https://doi.org/10.5194/acp-8-5477-2008, 2008. a
Clémer, K., Van Roozendael, M., Fayt, C., Hendrick, F., Hermans, C., Pinardi, G., Spurr, R., Wang, P., and De Mazière, M.: Multiple wavelength retrieval of tropospheric aerosol optical properties from MAXDOAS measurements in Beijing, Atmos. Meas. Tech., 3, 863–878, https://doi.org/10.5194/amt-3-863-2010, 2010. a, b
Donner, S.: Mobile MAX-DOAS measurements of the tropospheric formaldehyde
column in the Rhein-Main region, Master's thesis, University of Mainz, Mainz, available at: http://hdl.handle.net/11858/00-001M-0000-002C-EB17-2 (last access: 31 January 2020), 2016. a
Drosoglou, T., Bais, A. F., Zyrichidou, I., Kouremeti, N., Poupkou, A., Liora, N., Giannaros, C., Koukouli, M. E., Balis, D., and Melas, D.: Comparisons of ground-based tropospheric NO2 MAX-DOAS measurements to satellite observations with the aid of an air quality model over the Thessaloniki area, Greece, Atmos. Chem. Phys., 17, 5829–5849, https://doi.org/10.5194/acp-17-5829-2017, 2017. a
Fraser, A., Adams, C., Drummond, J. R., Goutail, F., Manney, G., and Strong,
K.: “The Polar Environment Atmospheric Research Laboratory UV-visible
Ground-Based Spectrometer: First measurements of O3, NO2, BrO, and OClO
columns”, J. Quant. Spectrosc. Ra., 110,
986–1004, https://doi.org/10.1016/j.jqsrt.2009.02.034, 2009. a
Frieß, U., Monks, P., Remedios, J., Rozanov, A., Sinreich, R., Wagner, T.,
and Platt, U.: MAX-DOAS O4 measurements: A new technique to derive
information on atmospheric aerosols: 2. Modeling studies, J. Geophys. Res.-Atmos., 111, https://doi.org/10.1029/2005JD006618, 2006. a
Frieß, U., Klein Baltink, H., Beirle, S., Clémer, K., Hendrick, F., Henzing, B., Irie, H., de Leeuw, G., Li, A., Moerman, M. M., van Roozendael, M., Shaiganfar, R., Wagner, T., Wang, Y., Xie, P., Yilmaz, S., and Zieger, P.: Intercomparison of aerosol extinction profiles retrieved from MAX-DOAS measurements, Atmos. Meas. Tech., 9, 3205–3222, https://doi.org/10.5194/amt-9-3205-2016, 2016. a
Hönninger, G. and Platt, U.: Observations of BrO and its vertical
distribution during surface ozone depletion at Alert, Atmos. Environ., 36, 2481–2489, 2002. a
Hönninger, G., von Friedeburg, C., and Platt, U.: Multi axis differential optical absorption spectroscopy (MAX-DOAS), Atmos. Chem. Phys., 4, 231–254, https://doi.org/10.5194/acp-4-231-2004, 2004. a, b, c
Irie, H., Kanaya, Y., Akimoto, H., Iwabuchi, H., Shimizu, A., and Aoki, K.: First retrieval of tropospheric aerosol profiles using MAX-DOAS and comparison with lidar and sky radiometer measurements, Atmos. Chem. Phys., 8, 341–350, https://doi.org/10.5194/acp-8-341-2008, 2008. a, b
Kreher, K., Van Roozendael, M., Hendrick, F., Apituley, A., Dimitropoulou, E., Frieß, U., Richter, A., Wagner, T., Abuhassan, N., Ang, L., Anguas, M., Bais, A., Benavent, N., Bösch, T., Bognar, K., Borovski, A., Bruchkouski, I., Cede, A., Chan, K. L., Donner, S., Drosoglou, T., Fayt, C., Finkenzeller, H., Garcia-Nieto, D., Gielen, C., Gómez-Martín, L., Hao, N., Herman, J. R., Hermans, C., Hoque, S., Irie, H., Jin, J., Johnston, P., Khayyam Butt, J., Khokhar, F., Koenig, T. K., Kuhn, J., Kumar, V., Lampel, J., Liu, C., Ma, J., Merlaud, A., Mishra, A. K., Müller, M., Navarro-Comas, M., Ostendorf, M., Pazmino, A., Peters, E., Pinardi, G., Pinharanda, M., Piters, A., Platt, U., Postylyakov, O., Prados-Roman, C., Puentedura, O., Querel, R., Saiz-Lopez, A., Schönhardt, A., Schreier, S. F., Seyler, A., Sinha, V., Spinei, E., Strong, K., Tack, F., Tian, X., Tiefengraber, M., Tirpitz, J.-L., van Gent, J., Volkamer, R., Vrekoussis, M., Wang, S., Wang, Z., Wenig, M., Wittrock, F., Xie, P. H., Xu, J., Yela, M., Zhang, C., and Zhao, X.: Intercomparison of NO2, O4, O3 and HCHO slant column measurements by MAX-DOAS and zenith-sky UV-Visible spectrometers during the CINDI-2 campaign, Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2019-157, in review, 2019. a, b, c, d, e
Lampel, J., Frieß, U., and Platt, U.: The impact of vibrational Raman scattering of air on DOAS measurements of atmospheric trace gases, Atmos. Meas. Tech., 8, 3767–3787, https://doi.org/10.5194/amt-8-3767-2015, 2015. a, b
Peters, E., Wittrock, F., Großmann, K., Frieß, U., Richter, A., and Burrows, J. P.: Formaldehyde and nitrogen dioxide over the remote western Pacific Ocean: SCIAMACHY and GOME-2 validation using ship-based MAX-DOAS observations, Atmos. Chem. Phys., 12, 11179–11197, https://doi.org/10.5194/acp-12-11179-2012, 2012. a
Pinardi, G., Van Roozendael, M., Abuhassan, N., Adams, C., Cede, A., Clémer, K., Fayt, C., Frieß, U., Gil, M., Herman, J., Hermans, C., Hendrick, F., Irie, H., Merlaud, A., Navarro Comas, M., Peters, E., Piters, A. J. M., Puentedura, O., Richter, A., Schönhardt, A., Shaiganfar, R., Spinei, E., Strong, K., Takashima, H., Vrekoussis, M., Wagner, T., Wittrock, F., and Yilmaz, S.: MAX-DOAS formaldehyde slant column measurements during CINDI: intercomparison and analysis improvement, Atmos. Meas. Tech., 6, 167–185, https://doi.org/10.5194/amt-6-167-2013, 2013. a
Piters, A. J. M., Boersma, K. F., Kroon, M., Hains, J. C., Van Roozendael, M., Wittrock, F., Abuhassan, N., Adams, C., Akrami, M., Allaart, M. A. F., Apituley, A., Beirle, S., Bergwerff, J. B., Berkhout, A. J. C., Brunner, D., Cede, A., Chong, J., Clémer, K., Fayt, C., Frieß, U., Gast, L. F. L., Gil-Ojeda, M., Goutail, F., Graves, R., Griesfeller, A., Großmann, K., Hemerijckx, G., Hendrick, F., Henzing, B., Herman, J., Hermans, C., Hoexum, M., van der Hoff, G. R., Irie, H., Johnston, P. V., Kanaya, Y., Kim, Y. J., Klein Baltink, H., Kreher, K., de Leeuw, G., Leigh, R., Merlaud, A., Moerman, M. M., Monks, P. S., Mount, G. H., Navarro-Comas, M., Oetjen, H., Pazmino, A., Perez-Camacho, M., Peters, E., du Piesanie, A., Pinardi, G., Puentedura, O., Richter, A., Roscoe, H. K., Schönhardt, A., Schwarzenbach, B., Shaiganfar, R., Sluis, W., Spinei, E., Stolk, A. P., Strong, K., Swart, D. P. J., Takashima, H., Vlemmix, T., Vrekoussis, M., Wagner, T., Whyte, C., Wilson, K. M., Yela, M., Yilmaz, S., Zieger, P., and Zhou, Y.: The Cabauw Intercomparison campaign for Nitrogen Dioxide measuring Instruments (CINDI): design, execution, and early results, Atmos. Meas. Tech., 5, 457–485, https://doi.org/10.5194/amt-5-457-2012, 2012.
a, b
Roscoe, H. K., Van Roozendael, M., Fayt, C., du Piesanie, A., Abuhassan, N., Adams, C., Akrami, M., Cede, A., Chong, J., Clémer, K., Friess, U., Gil Ojeda, M., Goutail, F., Graves, R., Griesfeller, A., Grossmann, K., Hemerijckx, G., Hendrick, F., Herman, J., Hermans, C., Irie, H., Johnston, P. V., Kanaya, Y., Kreher, K., Leigh, R., Merlaud, A., Mount, G. H., Navarro, M., Oetjen, H., Pazmino, A., Perez-Camacho, M., Peters, E., Pinardi, G., Puentedura, O., Richter, A., Schönhardt, A., Shaiganfar, R., Spinei, E., Strong, K., Takashima, H., Vlemmix, T., Vrekoussis, M., Wagner, T., Wittrock, F., Yela, M., Yilmaz, S., Boersma, F., Hains, J., Kroon, M., Piters, A., and Kim, Y. J.: Intercomparison of slant column measurements of NO2 and O4 by MAX-DOAS and zenith-sky UV and visible spectrometers, Atmos. Meas. Tech., 3, 1629–1646, https://doi.org/10.5194/amt-3-1629-2010, 2010. a, b
Schreier, S. F., Richter, A., Peters, E., Ostendorf, M., Schmalwieser, A. W.,
Weihs, P., and Burrows, J. P.: Dual ground-based MAX-DOAS observations in
Vienna, Austria: Evaluation of horizontal and temporal NO2, HCHO, and
CHOCHO distributions and comparison with independent data sets, Atmos. Environ., 5, https://doi.org/10.1016/j.aeaoa.2019.100059,
2019. a
Van Roozendael, M., Fayt, C., Post, P., Hermans, C., and Lambert, J. C.:
Retrieval of Tropospheric BrO and NO2 from UV-Visible Observations, Springer, Heidelberg, 155–165, https://doi.org/10.1007/978-3-642-18875-6_19, 2004. a
Wagner, T., Dix, B., Friedeburg, C. v., Frieß, U., Sanghavi, S., Sinreich,
R., and Platt, U.: MAX-DOAS O4 measurements – a new technique to derive
information on atmospheric aerosols, (I) Principles and information content,
J. Geophys. Res.-Atmos., 109, D22205, https://doi.org/10.1029/2004JD004904, 2004. a
Wagner, T., Beirle, S., Brauers, T., Deutschmann, T., Frieß, U., Hak, C., Halla, J. D., Heue, K. P., Junkermann, W., Li, X., Platt, U., and Pundt-Gruber, I.: Inversion of tropospheric profiles of aerosol extinction and HCHO and NO2 mixing ratios from MAX-DOAS observations in Milano during the summer of 2003 and comparison with independent data sets, Atmos. Meas. Tech., 4, 2685–2715, https://doi.org/10.5194/amt-4-2685-2011, 2011. a, b
Wittrock, F., Oetjen, H., Richter, A., Fietkau, S., Medeke, T., Rozanov, A., and Burrows, J. P.: MAX-DOAS measurements of atmospheric trace gases in Ny-Ålesund – Radiative transfer studies and their application, Atmos. Chem. Phys., 4, 955–966, https://doi.org/10.5194/acp-4-955-2004, 2004. a
Short summary
The calibration of the elevation angles of MAX-DOAS instruments is important for the correct interpretation of such MAX-DOAS measurements. We present and evaluate different methods for the elevation calibration of MAX-DOAS instruments which were applied during the CINDI-2 field campaign.
The calibration of the elevation angles of MAX-DOAS instruments is important for the correct...
