Articles | Volume 14, issue 1
https://doi.org/10.5194/amt-14-595-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-14-595-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
28 Jan 2021
Research article |
| 28 Jan 2021
| 28 Jan 2021
Formaldehyde total column densities over Mexico City: comparison between multi-axis differential optical absorption spectroscopy and solar-absorption Fourier transform infrared measurements
Claudia Rivera Cárdenas
CORRESPONDING AUTHOR
Centro de Ciencias de la Atmósfera, Universidad Nacional Autónoma de México, Mexico City, Mexico
Cesar Guarín
Centro de Ciencias de la Atmósfera, Universidad Nacional Autónoma de México, Mexico City, Mexico
Departamento de Física, Universidad Autónoma Metropolitana, Mexico City, Mexico
Wolfgang Stremme
Centro de Ciencias de la Atmósfera, Universidad Nacional Autónoma de México, Mexico City, Mexico
Martina M. Friedrich
Centro de Ciencias de la Atmósfera, Universidad Nacional Autónoma de México, Mexico City, Mexico
Royal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, 1180, Belgium
Alejandro Bezanilla
Centro de Ciencias de la Atmósfera, Universidad Nacional Autónoma de México, Mexico City, Mexico
Diana Rivera Ramos
Centro de Ciencias de la Atmósfera, Universidad Nacional Autónoma de México, Mexico City, Mexico
Cristina A. Mendoza-Rodríguez
Centro de Ciencias de la Atmósfera, Universidad Nacional Autónoma de México, Mexico City, Mexico
Michel Grutter
Centro de Ciencias de la Atmósfera, Universidad Nacional Autónoma de México, Mexico City, Mexico
Thomas Blumenstock
Institute of Meteorology and Climate Research, Karlsruhe Institute of Technology, Karlsruhe, Germany
Frank Hase
Institute of Meteorology and Climate Research, Karlsruhe Institute of Technology, Karlsruhe, Germany
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Natural emissions from vegetation have a profound impact on air quality for their role in the formation of harmful tropospheric ozone and organic aerosols, yet these emissions are highly uncertain. In this study, we quantify emissions of organic gases over Europe using high-quality satellite measurements of formaldehyde. These satellite observations suggest that emissions from vegetation are much higher than predicted by models, especially in southern Europe.
Tobias D. Schmitt, Jonas Kuhn, Ralph Kleinschek, Benedikt A. Löw, Stefan Schmitt, William Cranton, Martina Schmidt, Sanam N. Vardag, Frank Hase, David W. T. Griffith, and André Butz
Atmos. Meas. Tech., 16, 6097–6110, https://doi.org/10.5194/amt-16-6097-2023, https://doi.org/10.5194/amt-16-6097-2023, 2023
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Our new observatory measures greenhouse gas concentrations of carbon dioxide (CO2) and methane (CH4) along a 1.55 km long light path over the city of Heidelberg, Germany. We compared our measurements with measurements that were taken at a single point at one end of our path. The two mostly agreed but show a significant difference for CO2 with certain wind directions. This is important when using greenhouse gas concentration measurements to observe greenhouse gas emissions of cities.
Hirofumi Ohyama, Matthias M. Frey, Isamu Morino, Kei Shiomi, Masahide Nishihashi, Tatsuya Miyauchi, Hiroko Yamada, Makoto Saito, Masanobu Wakasa, Thomas Blumenstock, and Frank Hase
Atmos. Chem. Phys., 23, 15097–15119, https://doi.org/10.5194/acp-23-15097-2023, https://doi.org/10.5194/acp-23-15097-2023, 2023
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We conducted a field campaign for CO2 column measurements in the Tokyo metropolitan area with three ground-based Fourier transform spectrometers. The model simulations using prior CO2 fluxes were generally in good agreement with the observations. We developed an urban-scale inversion system in which spatially resolved CO2 fluxes and a scaling factor of large point source emissions were estimated. The posterior total CO2 emissions agreed with emission inventories within the posterior uncertainty.
Benedikt A. Löw, Ralph Kleinschek, Vincent Enders, Stanley P. Sander, Thomas J. Pongetti, Tobias D. Schmitt, Frank Hase, Julian Kostinek, and André Butz
Atmos. Meas. Tech., 16, 5125–5144, https://doi.org/10.5194/amt-16-5125-2023, https://doi.org/10.5194/amt-16-5125-2023, 2023
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We developed a portable spectrometer (EM27/SCA) that remotely measures greenhouse gases in the lower atmosphere above a target region. The measurements can deliver insights into local emission patterns. To evaluate its performance, we set up the EM27/SCA above the Los Angeles Basin side by side with a similar non-portable instrument (CLARS-FTS). The precision is promising and the measurements are consistent with CLARS-FTS. In the future, we need to account for light scattering.
Rodriguez Yombo Phaka, Alexis Merlaud, Gaia Pinardi, Martina M. Friedrich, Michel Van Roozendael, Jean-François Müller, Trissevgeni Stavrakou, Isabelle De Smedt, François Hendrick, Ermioni Dimitropoulou, Richard Bopili Mbotia Lepiba, Edmond Phuku Phuati, Buenimio Lomami Djibi, Lars Jacobs, Caroline Fayt, Jean-Pierre Mbungu Tsumbu, and Emmanuel Mahieu
Atmos. Meas. Tech., 16, 5029–5050, https://doi.org/10.5194/amt-16-5029-2023, https://doi.org/10.5194/amt-16-5029-2023, 2023
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We present air quality measurements in Kinshasa, Democratic Republic of the Congo, performed with a newly developed instrument which was installed on a roof of the University of Kinshasa in November 2019. The instrument records spectra of the scattered sunlight, from which we derive the abundances of nitrogen dioxide and formaldehyde, two important pollutants. We compare our ground-based measurements with those of the TROPOspheric Monitoring Instrument (TROPOMI).
Óscar Alvárez, África Barreto, Omaira E. García, Frank Hase, Rosa D. García, Julian Gröbner, Sergio F. León-Luis, Eliezer Sepúlveda, Virgilio Carreño, Antonio Alcántara, Ramón Ramos, A. Fernando Almansa, Stelios Kazadzis, Noémie Taquet, Carlos Toledano, and Emilio Cuevas
Atmos. Meas. Tech., 16, 4861–4884, https://doi.org/10.5194/amt-16-4861-2023, https://doi.org/10.5194/amt-16-4861-2023, 2023
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In this work, we have extended the capabilities of a portable Fourier transform infrared (FTIR) instrument, which was originally designed to provide high-quality greenhouse gas monitoring within COCCON (COllaborative Carbon Column Observing Network). The extension allows the spectrometer to now also provide coincidentally column-integrated aerosol information. This addition of a reference instrument to a global network will be utilised to enhance our understanding of atmospheric chemistry.
Yifan Guan, Gretchen Keppel-Aleks, Scott C. Doney, Christof Petri, Dave Pollard, Debra Wunch, Frank Hase, Hirofumi Ohyama, Isamu Morino, Justus Notholt, Kei Shiomi, Kim Strong, Rigel Kivi, Matthias Buschmann, Nicholas Deutscher, Paul Wennberg, Ralf Sussmann, Voltaire A. Velazco, and Yao Té
Atmos. Chem. Phys., 23, 5355–5372, https://doi.org/10.5194/acp-23-5355-2023, https://doi.org/10.5194/acp-23-5355-2023, 2023
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We characterize spatial–temporal patterns of interannual variability (IAV) in atmospheric CO2 based on NASA’s Orbiting Carbon Observatory-2 (OCO-2). CO2 variation is strongly impacted by climate events, with higher anomalies during El Nino years. We show high correlation in IAV between space-based and ground-based CO2 from long-term sites. Because OCO-2 has near-global coverage, our paper provides a roadmap to study IAV where in situ observation is sparse, such as open oceans and remote lands.
Qiansi Tu, Frank Hase, Zihan Chen, Matthias Schneider, Omaira García, Farahnaz Khosrawi, Shuo Chen, Thomas Blumenstock, Fang Liu, Kai Qin, Jason Cohen, Qin He, Song Lin, Hongyan Jiang, and Dianjun Fang
Atmos. Meas. Tech., 16, 2237–2262, https://doi.org/10.5194/amt-16-2237-2023, https://doi.org/10.5194/amt-16-2237-2023, 2023
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Four-year TROPOMI observations are used to derive tropospheric NO2 emissions in two mega(cities) with high anthropogenic activity. Wind-assigned anomalies are calculated, and the emission rates and spatial patterns are estimated based on a machine learning algorithm. The results are in reasonable agreement with previous studies and the inventory. Our method is quite robust and can be used as a simple method to estimate the emissions of NO2 as well as other gases in other regions.
Ka Lok Chan, Pieter Valks, Klaus-Peter Heue, Ronny Lutz, Pascal Hedelt, Diego Loyola, Gaia Pinardi, Michel Van Roozendael, François Hendrick, Thomas Wagner, Vinod Kumar, Alkis Bais, Ankie Piters, Hitoshi Irie, Hisahiro Takashima, Yugo Kanaya, Yongjoo Choi, Kihong Park, Jihyo Chong, Alexander Cede, Udo Frieß, Andreas Richter, Jianzhong Ma, Nuria Benavent, Robert Holla, Oleg Postylyakov, Claudia Rivera Cárdenas, and Mark Wenig
Earth Syst. Sci. Data, 15, 1831–1870, https://doi.org/10.5194/essd-15-1831-2023, https://doi.org/10.5194/essd-15-1831-2023, 2023
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This paper presents the theoretical basis as well as verification and validation of the Global Ozone Monitoring Experiment-2 (GOME-2) daily and monthly level-3 products.
Kezia Lange, Andreas Richter, Anja Schönhardt, Andreas C. Meier, Tim Bösch, André Seyler, Kai Krause, Lisa K. Behrens, Folkard Wittrock, Alexis Merlaud, Frederik Tack, Caroline Fayt, Martina M. Friedrich, Ermioni Dimitropoulou, Michel Van Roozendael, Vinod Kumar, Sebastian Donner, Steffen Dörner, Bianca Lauster, Maria Razi, Christian Borger, Katharina Uhlmannsiek, Thomas Wagner, Thomas Ruhtz, Henk Eskes, Birger Bohn, Daniel Santana Diaz, Nader Abuhassan, Dirk Schüttemeyer, and John P. Burrows
Atmos. Meas. Tech., 16, 1357–1389, https://doi.org/10.5194/amt-16-1357-2023, https://doi.org/10.5194/amt-16-1357-2023, 2023
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We present airborne imaging DOAS and ground-based stationary and car DOAS measurements conducted during the S5P-VAL-DE-Ruhr campaign in the Rhine-Ruhr region. The measurements are used to validate spaceborne NO2 data products from the Sentinel-5 Precursor TROPOspheric Monitoring Instrument (TROPOMI). Auxiliary data of the TROPOMI NO2 retrieval, such as spatially higher resolved a priori NO2 vertical profiles, surface reflectivity, and cloud treatment are investigated to evaluate their impact.
Farahnaz Khosrawi, Kinya Toride, Kei Yoshimura, Christopher Diekmann, Benjamin Ertl, Frank Hase, and Matthias Schneider
EGUsphere, https://doi.org/10.5194/egusphere-2022-1408, https://doi.org/10.5194/egusphere-2022-1408, 2022
Preprint withdrawn
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We assess with an Observation System Simulation Experiment the potential of mid-tropospheric water isotopologue data for constraining uncertainties in meteorological analysis fields in the tropics. Our assimilation experiments indicate that isotopologue observations have the potential to reduce the uncertainties of diabatic heating rates and precipitation in the tropics and in consequence offer potential for improving meteorological analysis in the tropical regions.
David F. Pollard, Frank Hase, Mahesh Kumar Sha, Darko Dubravica, Carlos Alberti, and Dan Smale
Earth Syst. Sci. Data, 14, 5427–5437, https://doi.org/10.5194/essd-14-5427-2022, https://doi.org/10.5194/essd-14-5427-2022, 2022
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We describe measurements made in Antarctica using an EM27/SUN, a near-infrared, portable, low-resolution spectrometer from which we can retrieve the average atmospheric concentration of several greenhouse gases. We show that these measurements are reliable and comparable to other, similar ground-based measurements. Comparisons to the ESA's Sentinel-5 precursor (S5P) satellite demonstrate the usefulness of these data for satellite validation.
Maximilian Rißmann, Jia Chen, Gregory Osterman, Xinxu Zhao, Florian Dietrich, Moritz Makowski, Frank Hase, and Matthäus Kiel
Atmos. Meas. Tech., 15, 6605–6623, https://doi.org/10.5194/amt-15-6605-2022, https://doi.org/10.5194/amt-15-6605-2022, 2022
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The Orbiting Carbon Observatory 2 (OCO-2) measures atmospheric concentrations of the most potent greenhouse gas, CO2, globally. By comparing its measurements to a ground-based monitoring network in Munich (MUCCnet), we find that the satellite is able to reliably detect urban CO2 concentrations. Furthermore, spatial CO2 differences captured by OCO-2 and MUCCnet are strongly correlated, which indicates that OCO-2 could be helpful in determining urban CO2 emissions from space.
Beatriz Herrera, Alejandro Bezanilla, Thomas Blumenstock, Enrico Dammers, Frank Hase, Lieven Clarisse, Adolfo Magaldi, Claudia Rivera, Wolfgang Stremme, Kimberly Strong, Camille Viatte, Martin Van Damme, and Michel Grutter
Atmos. Chem. Phys., 22, 14119–14132, https://doi.org/10.5194/acp-22-14119-2022, https://doi.org/10.5194/acp-22-14119-2022, 2022
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This work investigates atmospheric ammonia (NH3), a key trace gas with consequences for the environment and human health, in Mexico City. The results from the ground-based and satellite instruments show the variability and spatial distribution of NH3 over this region. NH3 in Mexico City has been increasing for the past 10 years and most of its sources are urban. This work contributes to a better understanding of NH3 sources and variability in urban and remote areas.
Camille Viatte, Rimal Abeed, Shoma Yamanouchi, William C. Porter, Sarah Safieddine, Martin Van Damme, Lieven Clarisse, Beatriz Herrera, Michel Grutter, Pierre-Francois Coheur, Kimberly Strong, and Cathy Clerbaux
Atmos. Chem. Phys., 22, 12907–12922, https://doi.org/10.5194/acp-22-12907-2022, https://doi.org/10.5194/acp-22-12907-2022, 2022
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Large cities can experience high levels of fine particulate matter (PM2.5) pollution linked to ammonia (NH3) mainly emitted from agricultural activities. Using a combination of PM2.5 and NH3 measurements from in situ instruments, satellite infrared spectrometers, and atmospheric model simulations, we have demonstrated the role of NH3 and meteorological conditions on pollution events occurring over Paris, Toronto, and Mexico City.
Omaira E. García, Esther Sanromá, Frank Hase, Matthias Schneider, Sergio Fabián León-Luis, Thomas Blumenstock, Eliezer Sepúlveda, Carlos Torres, Natalia Prats, Alberto Redondas, and Virgilio Carreño
Atmos. Meas. Tech., 15, 4547–4567, https://doi.org/10.5194/amt-15-4547-2022, https://doi.org/10.5194/amt-15-4547-2022, 2022
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Retrieving high-precision concentrations of atmospheric trace gases from FTIR (Fourier transform infrared) spectrometry requires a precise knowledge of the instrumental performance. In this context, this paper examines the impact on the ozone (O3) retrievals of several approaches used to characterise the instrumental line shape (ILS) function of ground-based FTIR spectrometers within NDACC (Network for the Detection of Atmospheric Composition Change).
Ermioni Dimitropoulou, François Hendrick, Martina Michaela Friedrich, Frederik Tack, Gaia Pinardi, Alexis Merlaud, Caroline Fayt, Christian Hermans, Frans Fierens, and Michel Van Roozendael
Atmos. Meas. Tech., 15, 4503–4529, https://doi.org/10.5194/amt-15-4503-2022, https://doi.org/10.5194/amt-15-4503-2022, 2022
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A total of 2 years of dual-scan ground-based MAX-DOAS measurements of tropospheric NO2 and aerosols in Uccle (Belgium) have been used to develop a new optimal-estimation-based inversion approach to retrieve horizontal profiles of surface NO2 concentration and aerosol extinction profiles. We show that the combination of an appropriate sampling of TROPOMI pixels by ground-based measurements and an adequate a priori NO2 profile shape in TROPOMI retrievals improves the agreement between datasets.
Qiansi Tu, Matthias Schneider, Frank Hase, Farahnaz Khosrawi, Benjamin Ertl, Jaroslaw Necki, Darko Dubravica, Christopher J. Diekmann, Thomas Blumenstock, and Dianjun Fang
Atmos. Chem. Phys., 22, 9747–9765, https://doi.org/10.5194/acp-22-9747-2022, https://doi.org/10.5194/acp-22-9747-2022, 2022
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Three-year satellite observations and high-resolution model forecast of XCH4 are used to derive CH4 emissions in the USCB region, Poland – a region of intense coal mining activities. The wind-assigned anomalies for two opposite wind directions are calculated and the estimated emission rates are very close to the inventories and in reasonable agreement with the previous studies. Our method is quite robust and can serve as a simple method to estimate CH4 or CO2 emissions for other regions.
Matthias Schneider, Benjamin Ertl, Qiansi Tu, Christopher J. Diekmann, Farahnaz Khosrawi, Amelie N. Röhling, Frank Hase, Darko Dubravica, Omaira E. García, Eliezer Sepúlveda, Tobias Borsdorff, Jochen Landgraf, Alba Lorente, André Butz, Huilin Chen, Rigel Kivi, Thomas Laemmel, Michel Ramonet, Cyril Crevoisier, Jérome Pernin, Martin Steinbacher, Frank Meinhardt, Kimberly Strong, Debra Wunch, Thorsten Warneke, Coleen Roehl, Paul O. Wennberg, Isamu Morino, Laura T. Iraci, Kei Shiomi, Nicholas M. Deutscher, David W. T. Griffith, Voltaire A. Velazco, and David F. Pollard
Atmos. Meas. Tech., 15, 4339–4371, https://doi.org/10.5194/amt-15-4339-2022, https://doi.org/10.5194/amt-15-4339-2022, 2022
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We present a computationally very efficient method for the synergetic use of level 2 remote-sensing data products. We apply the method to IASI vertical profile and TROPOMI total column space-borne methane observations and thus gain sensitivity for the tropospheric methane partial columns, which is not achievable by the individual use of TROPOMI and IASI. These synergetic effects are evaluated theoretically and empirically by inter-comparisons to independent references of TCCON, AirCore, and GAW.
Stefan Noël, Maximilian Reuter, Michael Buchwitz, Jakob Borchardt, Michael Hilker, Oliver Schneising, Heinrich Bovensmann, John P. Burrows, Antonio Di Noia, Robert J. Parker, Hiroshi Suto, Yukio Yoshida, Matthias Buschmann, Nicholas M. Deutscher, Dietrich G. Feist, David W. T. Griffith, Frank Hase, Rigel Kivi, Cheng Liu, Isamu Morino, Justus Notholt, Young-Suk Oh, Hirofumi Ohyama, Christof Petri, David F. Pollard, Markus Rettinger, Coleen Roehl, Constantina Rousogenous, Mahesh Kumar Sha, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Yao Té, Voltaire A. Velazco, Mihalis Vrekoussis, and Thorsten Warneke
Atmos. Meas. Tech., 15, 3401–3437, https://doi.org/10.5194/amt-15-3401-2022, https://doi.org/10.5194/amt-15-3401-2022, 2022
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We present a new version (v3) of the GOSAT and GOSAT-2 FOCAL products.
In addition to an increased number of XCO2 data, v3 also includes products for XCH4 (full-physics and proxy), XH2O and the relative ratio of HDO to H2O (δD). For GOSAT-2, we also present first XCO and XN2O results. All FOCAL data products show reasonable spatial distribution and temporal variations and agree well with TCCON. Global XN2O maps show a gradient from the tropics to higher latitudes on the order of 15 ppb.
Andreas Luther, Julian Kostinek, Ralph Kleinschek, Sara Defratyka, Mila Stanisavljević, Andreas Forstmaier, Alexandru Dandocsi, Leon Scheidweiler, Darko Dubravica, Norman Wildmann, Frank Hase, Matthias M. Frey, Jia Chen, Florian Dietrich, Jarosław Nȩcki, Justyna Swolkień, Christoph Knote, Sanam N. Vardag, Anke Roiger, and André Butz
Atmos. Chem. Phys., 22, 5859–5876, https://doi.org/10.5194/acp-22-5859-2022, https://doi.org/10.5194/acp-22-5859-2022, 2022
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Coal mining is an extensive source of anthropogenic methane emissions. In order to reduce and mitigate methane emissions, it is important to know how much and where the methane is emitted. We estimated coal mining methane emissions in Poland based on atmospheric methane measurements and particle dispersion modeling. In general, our emission estimates suggest higher emissions than expected by previous annual emission reports.
Omaira Elena García, Esther Sanromá, Matthias Schneider, Frank Hase, Sergio Fabián León-Luis, Thomas Blumenstock, Eliezer Sepúlveda, Alberto Redondas, Virgilio Carreño, Carlos Torres, and Natalia Prats
Atmos. Meas. Tech., 15, 2557–2577, https://doi.org/10.5194/amt-15-2557-2022, https://doi.org/10.5194/amt-15-2557-2022, 2022
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Accurate observations of atmospheric ozone (O3) are essential to monitor in detail its key role in atmospheric chemistry. In this context, this paper has assessed the effect of using different retrieval strategies on the quality of O3 products from ground-based NDACC FTIR (Fourier transform infrared) spectrometry, with the aim of providing an improved O3 retrieval that could be applied at any NDACC FTIR station.
Carlos Alberti, Frank Hase, Matthias Frey, Darko Dubravica, Thomas Blumenstock, Angelika Dehn, Paolo Castracane, Gregor Surawicz, Roland Harig, Bianca C. Baier, Caroline Bès, Jianrong Bi, Hartmut Boesch, André Butz, Zhaonan Cai, Jia Chen, Sean M. Crowell, Nicholas M. Deutscher, Dragos Ene, Jonathan E. Franklin, Omaira García, David Griffith, Bruno Grouiez, Michel Grutter, Abdelhamid Hamdouni, Sander Houweling, Neil Humpage, Nicole Jacobs, Sujong Jeong, Lilian Joly, Nicholas B. Jones, Denis Jouglet, Rigel Kivi, Ralph Kleinschek, Morgan Lopez, Diogo J. Medeiros, Isamu Morino, Nasrin Mostafavipak, Astrid Müller, Hirofumi Ohyama, Paul I. Palmer, Mahesh Pathakoti, David F. Pollard, Uwe Raffalski, Michel Ramonet, Robbie Ramsay, Mahesh Kumar Sha, Kei Shiomi, William Simpson, Wolfgang Stremme, Youwen Sun, Hiroshi Tanimoto, Yao Té, Gizaw Mengistu Tsidu, Voltaire A. Velazco, Felix Vogel, Masataka Watanabe, Chong Wei, Debra Wunch, Marcia Yamasoe, Lu Zhang, and Johannes Orphal
Atmos. Meas. Tech., 15, 2433–2463, https://doi.org/10.5194/amt-15-2433-2022, https://doi.org/10.5194/amt-15-2433-2022, 2022
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Space-borne greenhouse gas missions require ground-based validation networks capable of providing fiducial reference measurements. Here, considerable refinements of the calibration procedures for the COllaborative Carbon Column Observing Network (COCCON) are presented. Laboratory and solar side-by-side procedures for the characterization of the spectrometers have been refined and extended. Revised calibration factors for XCO2, XCO and XCH4 are provided, incorporating 47 new spectrometers.
Carlos Alberti, Qiansi Tu, Frank Hase, Maria V. Makarova, Konstantin Gribanov, Stefani C. Foka, Vyacheslav Zakharov, Thomas Blumenstock, Michael Buchwitz, Christopher Diekmann, Benjamin Ertl, Matthias M. Frey, Hamud Kh. Imhasin, Dmitry V. Ionov, Farahnaz Khosrawi, Sergey I. Osipov, Maximilian Reuter, Matthias Schneider, and Thorsten Warneke
Atmos. Meas. Tech., 15, 2199–2229, https://doi.org/10.5194/amt-15-2199-2022, https://doi.org/10.5194/amt-15-2199-2022, 2022
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Satellite and ground-based observations at high latitudes are much sparser than at low or mid latitudes, which makes direct coincident comparisons between remote-sensing observations more difficult. Therefore, a method of scaling continuous CAMS model data to the ground-based observations is developed and used for creating virtual COCCON observations. These adjusted CAMS data are then used for satellite inter-comparison, showing good agreement in both Peterhof and Yekaterinburg cities.
Hisahiro Takashima, Yugo Kanaya, Saki Kato, Martina M. Friedrich, Michel Van Roozendael, Fumikazu Taketani, Takuma Miyakawa, Yuichi Komazaki, Carlos A. Cuevas, Alfonso Saiz-Lopez, and Takashi Sekiya
Atmos. Chem. Phys., 22, 4005–4018, https://doi.org/10.5194/acp-22-4005-2022, https://doi.org/10.5194/acp-22-4005-2022, 2022
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We have undertaken atmospheric iodine monoxide (IO) observations in the global marine boundary layer with a wide latitudinal coverage and sea surface temperature (SST) range. We conclude that atmospheric iodine is abundant over the Western Pacific warm pool, appearing as an iodine fountain, where ozone (O3) minima occur. Our study also found negative correlations between IO and O3 concentrations over IO maxima, which requires reconsideration of the initiation process of halogen activation.
Dimitris Karagkiozidis, Martina Michaela Friedrich, Steffen Beirle, Alkiviadis Bais, François Hendrick, Kalliopi Artemis Voudouri, Ilias Fountoulakis, Angelos Karanikolas, Paraskevi Tzoumaka, Michel Van Roozendael, Dimitris Balis, and Thomas Wagner
Atmos. Meas. Tech., 15, 1269–1301, https://doi.org/10.5194/amt-15-1269-2022, https://doi.org/10.5194/amt-15-1269-2022, 2022
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In this study we focus on the retrieval of aerosol, NO2, and HCHO vertical profiles from multi-axis differential optical absorption spectroscopy (MAX-DOAS) observations for the first time over Thessaloniki, Greece. We use two independent inversion algorithms for the profile retrievals. We evaluate their performance, we intercompare their results, and we validate their products with ancillary data, measured by other co-located reference instruments.
Thomas von Clarmann, Steven Compernolle, and Frank Hase
Atmos. Meas. Tech., 15, 1145–1157, https://doi.org/10.5194/amt-15-1145-2022, https://doi.org/10.5194/amt-15-1145-2022, 2022
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Contrary to the claims put forward in
Evaluation of measurement data – Guide to the expression of uncertainty in measurementissued by the JCGM, the error concept and the uncertainty concept are the same. Arguments in favor of the contrary were found not to be compelling. Neither was any evidence presented that
errorsand
uncertaintiesdefine a different relation between the measured and true values, nor is a Bayesian concept beyond the mere subjective probability referred to.
Matthias Schneider, Benjamin Ertl, Christopher J. Diekmann, Farahnaz Khosrawi, Andreas Weber, Frank Hase, Michael Höpfner, Omaira E. García, Eliezer Sepúlveda, and Douglas Kinnison
Earth Syst. Sci. Data, 14, 709–742, https://doi.org/10.5194/essd-14-709-2022, https://doi.org/10.5194/essd-14-709-2022, 2022
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We present atmospheric H2O, HDO / H2O ratio, N2O, CH4, and HNO3 data generated by the MUSICA IASI processor using thermal nadir spectra measured by the IASI satellite instrument. The data have global daily coverage and are available for the period between October 2014 and June 2021. Multiple possibilities of data reuse are offered by providing each individual data product together with information about retrieval settings and the products' uncertainty and vertical representativeness.
Thomas E. Taylor, Christopher W. O'Dell, David Crisp, Akhiko Kuze, Hannakaisa Lindqvist, Paul O. Wennberg, Abhishek Chatterjee, Michael Gunson, Annmarie Eldering, Brendan Fisher, Matthäus Kiel, Robert R. Nelson, Aronne Merrelli, Greg Osterman, Frédéric Chevallier, Paul I. Palmer, Liang Feng, Nicholas M. Deutscher, Manvendra K. Dubey, Dietrich G. Feist, Omaira E. García, David W. T. Griffith, Frank Hase, Laura T. Iraci, Rigel Kivi, Cheng Liu, Martine De Mazière, Isamu Morino, Justus Notholt, Young-Suk Oh, Hirofumi Ohyama, David F. Pollard, Markus Rettinger, Matthias Schneider, Coleen M. Roehl, Mahesh Kumar Sha, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Yao Té, Voltaire A. Velazco, Mihalis Vrekoussis, Thorsten Warneke, and Debra Wunch
Earth Syst. Sci. Data, 14, 325–360, https://doi.org/10.5194/essd-14-325-2022, https://doi.org/10.5194/essd-14-325-2022, 2022
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We provide an analysis of an 11-year record of atmospheric carbon dioxide (CO2) concentrations derived using an optimal estimation retrieval algorithm on measurements made by the GOSAT satellite. The new product (version 9) shows improvement over the previous version (v7.3) as evaluated against independent estimates of CO2 from ground-based sensors and atmospheric inversion systems. We also compare the new GOSAT CO2 values to collocated estimates from NASA's Orbiting Carbon Observatory-2.
Qiansi Tu, Frank Hase, Matthias Schneider, Omaira García, Thomas Blumenstock, Tobias Borsdorff, Matthias Frey, Farahnaz Khosrawi, Alba Lorente, Carlos Alberti, Juan J. Bustos, André Butz, Virgilio Carreño, Emilio Cuevas, Roger Curcoll, Christopher J. Diekmann, Darko Dubravica, Benjamin Ertl, Carme Estruch, Sergio Fabián León-Luis, Carlos Marrero, Josep-Anton Morgui, Ramón Ramos, Christian Scharun, Carsten Schneider, Eliezer Sepúlveda, Carlos Toledano, and Carlos Torres
Atmos. Chem. Phys., 22, 295–317, https://doi.org/10.5194/acp-22-295-2022, https://doi.org/10.5194/acp-22-295-2022, 2022
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We use different methane ground- and space-based remote sensing data sets for investigating the emission strength of three waste disposal sites close to Madrid. We present a method that uses wind-assigned anomalies for deriving emission strengths from satellite data and estimate their uncertainty to 9–14 %. The emission strengths estimated from the remote sensing data sets are significantly larger than the values published in the official register.
Nicole Jacobs, William R. Simpson, Kelly A. Graham, Christopher Holmes, Frank Hase, Thomas Blumenstock, Qiansi Tu, Matthias Frey, Manvendra K. Dubey, Harrison A. Parker, Debra Wunch, Rigel Kivi, Pauli Heikkinen, Justus Notholt, Christof Petri, and Thorsten Warneke
Atmos. Chem. Phys., 21, 16661–16687, https://doi.org/10.5194/acp-21-16661-2021, https://doi.org/10.5194/acp-21-16661-2021, 2021
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Spatial patterns of carbon dioxide seasonal cycle amplitude and summer drawdown timing derived from the OCO-2 satellite over northern high latitudes agree well with corresponding estimates from two models. The Asian boreal forest is anomalous with the largest amplitude and earliest seasonal drawdown. Modeled land contact tracers suggest that accumulated CO2 exchanges during atmospheric transport play a major role in shaping carbon dioxide seasonality in northern high-latitude regions.
Christopher J. Diekmann, Matthias Schneider, Benjamin Ertl, Frank Hase, Omaira García, Farahnaz Khosrawi, Eliezer Sepúlveda, Peter Knippertz, and Peter Braesicke
Earth Syst. Sci. Data, 13, 5273–5292, https://doi.org/10.5194/essd-13-5273-2021, https://doi.org/10.5194/essd-13-5273-2021, 2021
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The joint analysis of different stable water isotopes in water vapour is a powerful tool for investigating atmospheric moisture pathways. This paper presents a novel global and multi-annual dataset of H2O and HDO in mid-tropospheric water vapour by using data from the satellite sensor Metop/IASI. Due to its unique combination of coverage and resolution in space and time, this dataset is highly promising for studying the hydrological cycle and its representation in weather and climate models.
Omaira E. García, Matthias Schneider, Eliezer Sepúlveda, Frank Hase, Thomas Blumenstock, Emilio Cuevas, Ramón Ramos, Jochen Gross, Sabine Barthlott, Amelie N. Röhling, Esther Sanromá, Yenny González, Ángel J. Gómez-Peláez, Mónica Navarro-Comas, Olga Puentedura, Margarita Yela, Alberto Redondas, Virgilio Carreño, Sergio F. León-Luis, Enrique Reyes, Rosa D. García, Pedro P. Rivas, Pedro M. Romero-Campos, Carlos Torres, Natalia Prats, Miguel Hernández, and César López
Atmos. Chem. Phys., 21, 15519–15554, https://doi.org/10.5194/acp-21-15519-2021, https://doi.org/10.5194/acp-21-15519-2021, 2021
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This paper analyses the potential of ground-based Fourier transform infrared (FTIR) solar observations to monitor atmospheric gaseous composition and investigate multiple climate processes. To this end, this work reviews the FTIR programme of one of most relevant ground-based FTIR stations at a global scale, the subtropical Izaña Observatory (IZO, Spain), going over its history during its first 20 years of operation (1999–2018) and exploring its great value for long-term climate research.
Mahesh Kumar Sha, Bavo Langerock, Jean-François L. Blavier, Thomas Blumenstock, Tobias Borsdorff, Matthias Buschmann, Angelika Dehn, Martine De Mazière, Nicholas M. Deutscher, Dietrich G. Feist, Omaira E. García, David W. T. Griffith, Michel Grutter, James W. Hannigan, Frank Hase, Pauli Heikkinen, Christian Hermans, Laura T. Iraci, Pascal Jeseck, Nicholas Jones, Rigel Kivi, Nicolas Kumps, Jochen Landgraf, Alba Lorente, Emmanuel Mahieu, Maria V. Makarova, Johan Mellqvist, Jean-Marc Metzger, Isamu Morino, Tomoo Nagahama, Justus Notholt, Hirofumi Ohyama, Ivan Ortega, Mathias Palm, Christof Petri, David F. Pollard, Markus Rettinger, John Robinson, Sébastien Roche, Coleen M. Roehl, Amelie N. Röhling, Constantina Rousogenous, Matthias Schneider, Kei Shiomi, Dan Smale, Wolfgang Stremme, Kimberly Strong, Ralf Sussmann, Yao Té, Osamu Uchino, Voltaire A. Velazco, Corinne Vigouroux, Mihalis Vrekoussis, Pucai Wang, Thorsten Warneke, Tyler Wizenberg, Debra Wunch, Shoma Yamanouchi, Yang Yang, and Minqiang Zhou
Atmos. Meas. Tech., 14, 6249–6304, https://doi.org/10.5194/amt-14-6249-2021, https://doi.org/10.5194/amt-14-6249-2021, 2021
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This paper presents, for the first time, Sentinel-5 Precursor methane and carbon monoxide validation results covering a period from November 2017 to September 2020. For this study, we used global TCCON and NDACC-IRWG network data covering a wide range of atmospheric and surface conditions across different terrains. We also show the influence of a priori alignment, smoothing uncertainties and the sensitivity of the validation results towards the application of advanced co-location criteria.
Taylor S. Jones, Jonathan E. Franklin, Jia Chen, Florian Dietrich, Kristian D. Hajny, Johannes C. Paetzold, Adrian Wenzel, Conor Gately, Elaine Gottlieb, Harrison Parker, Manvendra Dubey, Frank Hase, Paul B. Shepson, Levi H. Mielke, and Steven C. Wofsy
Atmos. Chem. Phys., 21, 13131–13147, https://doi.org/10.5194/acp-21-13131-2021, https://doi.org/10.5194/acp-21-13131-2021, 2021
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Methane emissions from leaks in natural gas pipes are often a large source in urban areas, but they are difficult to measure on a city-wide scale. Here we use an array of innovative methane sensors distributed around the city of Indianapolis and a new method of combining their data with an atmospheric model to accurately determine the magnitude of these emissions, which are about 70 % larger than predicted. This method can serve as a framework for cities trying to account for their emissions.
Matthias M. Frey, Frank Hase, Thomas Blumenstock, Darko Dubravica, Jochen Groß, Frank Göttsche, Martin Handjaba, Petrus Amadhila, Roland Mushi, Isamu Morino, Kei Shiomi, Mahesh Kumar Sha, Martine de Mazière, and David F. Pollard
Atmos. Meas. Tech., 14, 5887–5911, https://doi.org/10.5194/amt-14-5887-2021, https://doi.org/10.5194/amt-14-5887-2021, 2021
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In this study, we present measurements of carbon dioxide, methane and carbon monoxide from a recently established site in Gobabeb, Namibia. Gobabeb is the first site observing these gases on the African mainland and improves the global coverage of measurement sites. Gobabeb is a hyperarid desert site, offering unique characteristics. Measurements started 2015 as part of the COllaborative Carbon Column Observing Network. We compare our results with other datasets and find a good agreement.
Isabelle De Smedt, Gaia Pinardi, Corinne Vigouroux, Steven Compernolle, Alkis Bais, Nuria Benavent, Folkert Boersma, Ka-Lok Chan, Sebastian Donner, Kai-Uwe Eichmann, Pascal Hedelt, François Hendrick, Hitoshi Irie, Vinod Kumar, Jean-Christopher Lambert, Bavo Langerock, Christophe Lerot, Cheng Liu, Diego Loyola, Ankie Piters, Andreas Richter, Claudia Rivera Cárdenas, Fabian Romahn, Robert George Ryan, Vinayak Sinha, Nicolas Theys, Jonas Vlietinck, Thomas Wagner, Ting Wang, Huan Yu, and Michel Van Roozendael
Atmos. Chem. Phys., 21, 12561–12593, https://doi.org/10.5194/acp-21-12561-2021, https://doi.org/10.5194/acp-21-12561-2021, 2021
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This paper assess the performances of the TROPOMI formaldehyde observations compared to its predecessor OMI at different spatial and temporal scales. We also use a global network of MAX-DOAS instruments to validate both satellite datasets for a large range of HCHO columns. The precision obtained with daily TROPOMI observations is comparable to monthly OMI observations. We present clear detection of weak HCHO column enhancements related to shipping emissions in the Indian Ocean.
Rebecca D. Kutzner, Juan Cuesta, Pascale Chelin, Jean-Eudes Petit, Mokhtar Ray, Xavier Landsheere, Benoît Tournadre, Jean-Charles Dupont, Amandine Rosso, Frank Hase, Johannes Orphal, and Matthias Beekmann
Atmos. Chem. Phys., 21, 12091–12111, https://doi.org/10.5194/acp-21-12091-2021, https://doi.org/10.5194/acp-21-12091-2021, 2021
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Our work investigates the diurnal evolution of atmospheric ammonia concentrations during a major pollution event. It analyses it in regard of both chemical (gas–particle conversion) and physical (vertical mixing, meteorology) processes in the atmosphere. These mechanisms are key for understanding the evolution of the physicochemical state of the atmosphere; therefore, it clearly fits into the scope of Atmospheric Chemistry and Physics.
Farahnaz Khosrawi, Kinya Toride, Kei Yoshimura, Christopher J. Diekmann, Benjamin Ertl, Frank Hase, and Matthias Schneider
Weather Clim. Dynam. Discuss., https://doi.org/10.5194/wcd-2021-49, https://doi.org/10.5194/wcd-2021-49, 2021
Revised manuscript not accepted
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We assess with an Observation System Simulation Experiment the potential of mid-tropospheric water isotopologue data for constraining uncertainties in meteorological analysis fields in the tropics. Our assimilation experiments indicate that isotopologue observations have the potential to reduce the uncertainties of diabatic heating rates and meteorological variables in the tropics and in consequence offer potential for improving meteorological analysis in the tropical regions.
Dmitry V. Ionov, Maria V. Makarova, Frank Hase, Stefani C. Foka, Vladimir S. Kostsov, Carlos Alberti, Thomas Blumenstock, Thorsten Warneke, and Yana A. Virolainen
Atmos. Chem. Phys., 21, 10939–10963, https://doi.org/10.5194/acp-21-10939-2021, https://doi.org/10.5194/acp-21-10939-2021, 2021
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Megacities are a significant source of emissions of various substances in the atmosphere, including carbon dioxide, which is the most important anthropogenic greenhouse gas. In 2019–2020, the Emission Monitoring Mobile Experiment was carried out in St Petersburg, which is the second-largest industrial city in Russia. The results of this experiment, coupled with numerical modelling, helped to estimate the amount of CO2 emitted by the city. This value was twice as high as predicted.
Ilya Stanevich, Dylan B. A. Jones, Kimberly Strong, Martin Keller, Daven K. Henze, Robert J. Parker, Hartmut Boesch, Debra Wunch, Justus Notholt, Christof Petri, Thorsten Warneke, Ralf Sussmann, Matthias Schneider, Frank Hase, Rigel Kivi, Nicholas M. Deutscher, Voltaire A. Velazco, Kaley A. Walker, and Feng Deng
Atmos. Chem. Phys., 21, 9545–9572, https://doi.org/10.5194/acp-21-9545-2021, https://doi.org/10.5194/acp-21-9545-2021, 2021
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We explore the utility of a weak-constraint (WC) four-dimensional variational (4D-Var) data assimilation scheme for mitigating systematic errors in methane simulation in the GEOS-Chem model. We use data from the Greenhouse Gases Observing Satellite (GOSAT) and show that, compared to the traditional 4D-Var approach, the WC scheme improves the agreement between the model and independent observations. We find that the WC corrections to the model provide insight into the source of the errors.
Matthieu Dogniaux, Cyril Crevoisier, Raymond Armante, Virginie Capelle, Thibault Delahaye, Vincent Cassé, Martine De Mazière, Nicholas M. Deutscher, Dietrich G. Feist, Omaira E. Garcia, David W. T. Griffith, Frank Hase, Laura T. Iraci, Rigel Kivi, Isamu Morino, Justus Notholt, David F. Pollard, Coleen M. Roehl, Kei Shiomi, Kimberly Strong, Yao Té, Voltaire A. Velazco, and Thorsten Warneke
Atmos. Meas. Tech., 14, 4689–4706, https://doi.org/10.5194/amt-14-4689-2021, https://doi.org/10.5194/amt-14-4689-2021, 2021
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We present the Adaptable 4A Inversion (5AI), an implementation of the optimal estimation (OE) algorithm, relying on the Automatized Atmospheric Absorption Atlas (4A/OP) radiative transfer model, that enables the retrieval of greenhouse gas atmospheric weighted columns from infrared measurements. It is tested on a sample of Orbiting Carbon Observatory-2 observations, and its results satisfactorily compare to several reference products, thus showing the reliability of 5AI OE implementation.
Stefan Noël, Maximilian Reuter, Michael Buchwitz, Jakob Borchardt, Michael Hilker, Heinrich Bovensmann, John P. Burrows, Antonio Di Noia, Hiroshi Suto, Yukio Yoshida, Matthias Buschmann, Nicholas M. Deutscher, Dietrich G. Feist, David W. T. Griffith, Frank Hase, Rigel Kivi, Isamu Morino, Justus Notholt, Hirofumi Ohyama, Christof Petri, James R. Podolske, David F. Pollard, Mahesh Kumar Sha, Kei Shiomi, Ralf Sussmann, Yao Té, Voltaire A. Velazco, and Thorsten Warneke
Atmos. Meas. Tech., 14, 3837–3869, https://doi.org/10.5194/amt-14-3837-2021, https://doi.org/10.5194/amt-14-3837-2021, 2021
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We present the first GOSAT and GOSAT-2 XCO2 data derived with the FOCAL retrieval algorithm. Comparisons of the GOSAT-FOCAL product with other data reveal long-term agreement within about 1 ppm over 1 decade, differences in seasonal variations of about 0.5 ppm, and a mean regional bias to ground-based TCCON data of 0.56 ppm with a mean scatter of 1.89 ppm. GOSAT-2-FOCAL data are preliminary only, but first comparisons show that they compare well with the GOSAT-FOCAL results and TCCON.
Eloise A. Marais, John F. Roberts, Robert G. Ryan, Henk Eskes, K. Folkert Boersma, Sungyeon Choi, Joanna Joiner, Nader Abuhassan, Alberto Redondas, Michel Grutter, Alexander Cede, Laura Gomez, and Monica Navarro-Comas
Atmos. Meas. Tech., 14, 2389–2408, https://doi.org/10.5194/amt-14-2389-2021, https://doi.org/10.5194/amt-14-2389-2021, 2021
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Nitrogen oxides in the upper troposphere have a profound influence on the global troposphere, but routine reliable observations there are exceedingly rare. We apply cloud-slicing to TROPOMI total columns of nitrogen dioxide (NO2) at high spatial resolution to derive near-global observations of NO2 in the upper troposphere and show consistency with existing datasets. These data offer tremendous potential to address knowledge gaps in this oft underappreciated portion of the atmosphere.
Santiago Arellano, Bo Galle, Fredy Apaza, Geoffroy Avard, Charlotte Barrington, Nicole Bobrowski, Claudia Bucarey, Viviana Burbano, Mike Burton, Zoraida Chacón, Gustavo Chigna, Christian Joseph Clarito, Vladimir Conde, Fidel Costa, Maarten De Moor, Hugo Delgado-Granados, Andrea Di Muro, Deborah Fernandez, Gustavo Garzón, Hendra Gunawan, Nia Haerani, Thor H. Hansteen, Silvana Hidalgo, Salvatore Inguaggiato, Mattias Johansson, Christoph Kern, Manne Kihlman, Philippe Kowalski, Pablo Masias, Francisco Montalvo, Joakim Möller, Ulrich Platt, Claudia Rivera, Armando Saballos, Giuseppe Salerno, Benoit Taisne, Freddy Vásconez, Gabriela Velásquez, Fabio Vita, and Mathieu Yalire
Earth Syst. Sci. Data, 13, 1167–1188, https://doi.org/10.5194/essd-13-1167-2021, https://doi.org/10.5194/essd-13-1167-2021, 2021
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This study presents a dataset of volcanic sulfur dioxide (SO2) emissions from 2005–2017. Measurements were obtained by Network for Observation of Volcanic and Atmospheric Change (NOVAC) scanning differential optical absorption spectrometer (ScanDOAS) instruments at 32 volcanoes and processed using a standardized procedure. We show statistics of volcanic gas emissions under a variety of conditions and compare them with averages derived from measurements from space and historical inventories.
Qiansi Tu, Frank Hase, Thomas Blumenstock, Matthias Schneider, Andreas Schneider, Rigel Kivi, Pauli Heikkinen, Benjamin Ertl, Christopher Diekmann, Farahnaz Khosrawi, Michael Sommer, Tobias Borsdorff, and Uwe Raffalski
Atmos. Meas. Tech., 14, 1993–2011, https://doi.org/10.5194/amt-14-1993-2021, https://doi.org/10.5194/amt-14-1993-2021, 2021
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We compare column-averaged dry-air mole fractions of water vapor (XH2O) retrievals from the COllaborative Carbon Column Observing Network (COCCON) with two co-located ground-based spectrometers as references at two boreal sites. Our study supports the assumption that COCCON also delivers a well-characterized XH2O data product. This is the first published study applying COCCON for MUSICA IASI and TROPOMI validation.
Thomas Blumenstock, Frank Hase, Axel Keens, Denis Czurlok, Orfeo Colebatch, Omaira Garcia, David W. T. Griffith, Michel Grutter, James W. Hannigan, Pauli Heikkinen, Pascal Jeseck, Nicholas Jones, Rigel Kivi, Erik Lutsch, Maria Makarova, Hamud K. Imhasin, Johan Mellqvist, Isamu Morino, Tomoo Nagahama, Justus Notholt, Ivan Ortega, Mathias Palm, Uwe Raffalski, Markus Rettinger, John Robinson, Matthias Schneider, Christian Servais, Dan Smale, Wolfgang Stremme, Kimberly Strong, Ralf Sussmann, Yao Té, and Voltaire A. Velazco
Atmos. Meas. Tech., 14, 1239–1252, https://doi.org/10.5194/amt-14-1239-2021, https://doi.org/10.5194/amt-14-1239-2021, 2021
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This study investigates the level of channeling (optical resonances) of each FTIR spectrometer within the Network for the Detection of Atmospheric Composition Change (NDACC). Since the air gap of the beam splitter is a significant source of channeling, we propose new beam splitters with an increased wedge of the air gap. This study shows the potential for reducing channeling in the FTIR spectrometers operated by the NDACC, thereby increasing the quality of recorded spectra across the network.
Maria V. Makarova, Carlos Alberti, Dmitry V. Ionov, Frank Hase, Stefani C. Foka, Thomas Blumenstock, Thorsten Warneke, Yana A. Virolainen, Vladimir S. Kostsov, Matthias Frey, Anatoly V. Poberovskii, Yuri M. Timofeyev, Nina N. Paramonova, Kristina A. Volkova, Nikita A. Zaitsev, Egor Y. Biryukov, Sergey I. Osipov, Boris K. Makarov, Alexander V. Polyakov, Viktor M. Ivakhov, Hamud Kh. Imhasin, and Eugene F. Mikhailov
Atmos. Meas. Tech., 14, 1047–1073, https://doi.org/10.5194/amt-14-1047-2021, https://doi.org/10.5194/amt-14-1047-2021, 2021
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Fundamental understanding of the major processes driving climate change is a key problem which is to be solved, not only on a global but also on a regional scale. The Emission Monitoring Mobile Experiment (EMME) carried out in 2019 with two portable Bruker EM27/SUN spectrometers as core instruments provided new information on the emissions of greenhouse (CO2, CH4) and reactive (CO, NOx) gases from St. Petersburg (Russia), which is the largest northern megacity with a population of 5 million.
Marvin Knapp, Ralph Kleinschek, Frank Hase, Anna Agustí-Panareda, Antje Inness, Jérôme Barré, Jochen Landgraf, Tobias Borsdorff, Stefan Kinne, and André Butz
Earth Syst. Sci. Data, 13, 199–211, https://doi.org/10.5194/essd-13-199-2021, https://doi.org/10.5194/essd-13-199-2021, 2021
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We developed a shipborne variant of a remote sensing spectrometer for direct sunlight measurements of column-averaged atmospheric mixing ratios of carbon dioxide, methane, and carbon monoxide. The instrument was deployed on the research vessel Sonne during a longitudinal transect over the Pacific during June 2019. The campaign yielded more than 32 000 observations which compare excellently to atmospheric composition data from a state-of-the-art model (CAMS) and satellite observations (TROPOMI).
Alba Lorente, Tobias Borsdorff, Andre Butz, Otto Hasekamp, Joost aan de Brugh, Andreas Schneider, Lianghai Wu, Frank Hase, Rigel Kivi, Debra Wunch, David F. Pollard, Kei Shiomi, Nicholas M. Deutscher, Voltaire A. Velazco, Coleen M. Roehl, Paul O. Wennberg, Thorsten Warneke, and Jochen Landgraf
Atmos. Meas. Tech., 14, 665–684, https://doi.org/10.5194/amt-14-665-2021, https://doi.org/10.5194/amt-14-665-2021, 2021
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TROPOMI aboard Sentinel-5P satellite provides methane (CH4) measurements with exceptional temporal and spatial resolution. The study describes a series of improvements developed to retrieve CH4 from TROPOMI. The updated CH4 product features (among others) a more accurate a posteriori correction derived independently of any reference data. The validation of the improved data product shows good agreement with ground-based and satellite measurements, which highlights the quality of the TROPOMI CH4.
Tijl Verhoelst, Steven Compernolle, Gaia Pinardi, Jean-Christopher Lambert, Henk J. Eskes, Kai-Uwe Eichmann, Ann Mari Fjæraa, José Granville, Sander Niemeijer, Alexander Cede, Martin Tiefengraber, François Hendrick, Andrea Pazmiño, Alkiviadis Bais, Ariane Bazureau, K. Folkert Boersma, Kristof Bognar, Angelika Dehn, Sebastian Donner, Aleksandr Elokhov, Manuel Gebetsberger, Florence Goutail, Michel Grutter de la Mora, Aleksandr Gruzdev, Myrto Gratsea, Georg H. Hansen, Hitoshi Irie, Nis Jepsen, Yugo Kanaya, Dimitris Karagkiozidis, Rigel Kivi, Karin Kreher, Pieternel F. Levelt, Cheng Liu, Moritz Müller, Monica Navarro Comas, Ankie J. M. Piters, Jean-Pierre Pommereau, Thierry Portafaix, Cristina Prados-Roman, Olga Puentedura, Richard Querel, Julia Remmers, Andreas Richter, John Rimmer, Claudia Rivera Cárdenas, Lidia Saavedra de Miguel, Valery P. Sinyakov, Wolfgang Stremme, Kimberly Strong, Michel Van Roozendael, J. Pepijn Veefkind, Thomas Wagner, Folkard Wittrock, Margarita Yela González, and Claus Zehner
Atmos. Meas. Tech., 14, 481–510, https://doi.org/10.5194/amt-14-481-2021, https://doi.org/10.5194/amt-14-481-2021, 2021
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This paper reports on the ground-based validation of the NO2 data produced operationally by the TROPOMI instrument on board the Sentinel-5 Precursor satellite. Tropospheric, stratospheric, and total NO2 columns are compared to measurements collected from MAX-DOAS, ZSL-DOAS, and PGN/Pandora instruments respectively. The products are found to satisfy mission requirements in general, though negative mean differences are found at sites with high pollution levels. Potential causes are discussed.
Jan-Lukas Tirpitz, Udo Frieß, François Hendrick, Carlos Alberti, Marc Allaart, Arnoud Apituley, Alkis Bais, Steffen Beirle, Stijn Berkhout, Kristof Bognar, Tim Bösch, Ilya Bruchkouski, Alexander Cede, Ka Lok Chan, Mirjam den Hoed, Sebastian Donner, Theano Drosoglou, Caroline Fayt, Martina M. Friedrich, Arnoud Frumau, Lou Gast, Clio Gielen, Laura Gomez-Martín, Nan Hao, Arjan Hensen, Bas Henzing, Christian Hermans, Junli Jin, Karin Kreher, Jonas Kuhn, Johannes Lampel, Ang Li, Cheng Liu, Haoran Liu, Jianzhong Ma, Alexis Merlaud, Enno Peters, Gaia Pinardi, Ankie Piters, Ulrich Platt, Olga Puentedura, Andreas Richter, Stefan Schmitt, Elena Spinei, Deborah Stein Zweers, Kimberly Strong, Daan Swart, Frederik Tack, Martin Tiefengraber, René van der Hoff, Michel van Roozendael, Tim Vlemmix, Jan Vonk, Thomas Wagner, Yang Wang, Zhuoru Wang, Mark Wenig, Matthias Wiegner, Folkard Wittrock, Pinhua Xie, Chengzhi Xing, Jin Xu, Margarita Yela, Chengxin Zhang, and Xiaoyi Zhao
Atmos. Meas. Tech., 14, 1–35, https://doi.org/10.5194/amt-14-1-2021, https://doi.org/10.5194/amt-14-1-2021, 2021
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Multi-axis differential optical absorption spectroscopy (MAX-DOAS) is a ground-based remote sensing measurement technique that derives atmospheric aerosol and trace gas vertical profiles from skylight spectra. In this study, consistency and reliability of MAX-DOAS profiles are assessed by applying nine different evaluation algorithms to spectral data recorded during an intercomparison campaign in the Netherlands and by comparing the results to colocated supporting observations.
Tobias Borsdorff, Agustín García Reynoso, Gilberto Maldonado, Bertha Mar-Morales, Wolfgang Stremme, Michel Grutter, and Jochen Landgraf
Atmos. Chem. Phys., 20, 15761–15774, https://doi.org/10.5194/acp-20-15761-2020, https://doi.org/10.5194/acp-20-15761-2020, 2020
Robert J. Parker, Alex Webb, Hartmut Boesch, Peter Somkuti, Rocio Barrio Guillo, Antonio Di Noia, Nikoleta Kalaitzi, Jasdeep S. Anand, Peter Bergamaschi, Frederic Chevallier, Paul I. Palmer, Liang Feng, Nicholas M. Deutscher, Dietrich G. Feist, David W. T. Griffith, Frank Hase, Rigel Kivi, Isamu Morino, Justus Notholt, Young-Suk Oh, Hirofumi Ohyama, Christof Petri, David F. Pollard, Coleen Roehl, Mahesh K. Sha, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Yao Té, Voltaire A. Velazco, Thorsten Warneke, Paul O. Wennberg, and Debra Wunch
Earth Syst. Sci. Data, 12, 3383–3412, https://doi.org/10.5194/essd-12-3383-2020, https://doi.org/10.5194/essd-12-3383-2020, 2020
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This work presents the latest release of the University of Leicester GOSAT methane data and acts as the definitive description of this dataset. We detail the processing, validation and evaluation involved in producing these data and highlight its many applications. With now over a decade of global atmospheric methane observations, this dataset has helped, and will continue to help, us better understand the global methane budget and investigate how it may respond to a future changing climate.
Erik Lutsch, Kimberly Strong, Dylan B. A. Jones, Thomas Blumenstock, Stephanie Conway, Jenny A. Fisher, James W. Hannigan, Frank Hase, Yasuko Kasai, Emmanuel Mahieu, Maria Makarova, Isamu Morino, Tomoo Nagahama, Justus Notholt, Ivan Ortega, Mathias Palm, Anatoly V. Poberovskii, Ralf Sussmann, and Thorsten Warneke
Atmos. Chem. Phys., 20, 12813–12851, https://doi.org/10.5194/acp-20-12813-2020, https://doi.org/10.5194/acp-20-12813-2020, 2020
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This paper describes the use of a network of 10 Arctic and midlatitude ground-based FTIR measurement sites to detect enhancements of the wildfire tracers carbon monoxide, hydrogen cyanide, and ethane from 2003 to 2018. A tagged CO GEOS-Chem simulation is used for source attribution and to evaluate the relative contribution of CO sources to the FTIR measurements. The use of FTIR measurements allowed for the emission ratios of hydrogen cyanide and ethane to be quantified.
Ermioni Dimitropoulou, François Hendrick, Gaia Pinardi, Martina M. Friedrich, Alexis Merlaud, Frederik Tack, Helene De Longueville, Caroline Fayt, Christian Hermans, Quentin Laffineur, Frans Fierens, and Michel Van Roozendael
Atmos. Meas. Tech., 13, 5165–5191, https://doi.org/10.5194/amt-13-5165-2020, https://doi.org/10.5194/amt-13-5165-2020, 2020
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We present 1 year of dual-scan ground-based multi-axis differential optical absorption spectroscopy (MAX-DOAS) measurements of aerosol and tropospheric NO2 in Uccle (Belgium). Measuring tropospheric NO2 vertical column densities (VCDs) in different azimuthal directions has a positive effect on comparison with measurements from TROPOMI. We prove that the use of inadequate a priori NO2 profile shape data in the TROPOMI retrieval is responsible for the systematic underestimation of S5P NO2 data.
Yang Wang, Arnoud Apituley, Alkiviadis Bais, Steffen Beirle, Nuria Benavent, Alexander Borovski, Ilya Bruchkouski, Ka Lok Chan, Sebastian Donner, Theano Drosoglou, Henning Finkenzeller, Martina M. Friedrich, Udo Frieß, David Garcia-Nieto, Laura Gómez-Martín, François Hendrick, Andreas Hilboll, Junli Jin, Paul Johnston, Theodore K. Koenig, Karin Kreher, Vinod Kumar, Aleksandra Kyuberis, Johannes Lampel, Cheng Liu, Haoran Liu, Jianzhong Ma, Oleg L. Polyansky, Oleg Postylyakov, Richard Querel, Alfonso Saiz-Lopez, Stefan Schmitt, Xin Tian, Jan-Lukas Tirpitz, Michel Van Roozendael, Rainer Volkamer, Zhuoru Wang, Pinhua Xie, Chengzhi Xing, Jin Xu, Margarita Yela, Chengxin Zhang, and Thomas Wagner
Atmos. Meas. Tech., 13, 5087–5116, https://doi.org/10.5194/amt-13-5087-2020, https://doi.org/10.5194/amt-13-5087-2020, 2020
Nicole Jacobs, William R. Simpson, Debra Wunch, Christopher W. O'Dell, Gregory B. Osterman, Frank Hase, Thomas Blumenstock, Qiansi Tu, Matthias Frey, Manvendra K. Dubey, Harrison A. Parker, Rigel Kivi, and Pauli Heikkinen
Atmos. Meas. Tech., 13, 5033–5063, https://doi.org/10.5194/amt-13-5033-2020, https://doi.org/10.5194/amt-13-5033-2020, 2020
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The boreal forest is the largest seasonally varying biospheric CO2-exchange region on Earth. This region is also undergoing amplified climate warming, leading to concerns about the potential for altered regional carbon exchange. Satellite missions, such as the Orbiting Carbon Observatory-2 (OCO-2) project, can measure CO2 abundance over the boreal forest but need validation for the assurance of accuracy. Therefore, we carried out a ground-based validation of OCO-2 CO2 data at three locations.
Mahesh Kumar Sha, Martine De Mazière, Justus Notholt, Thomas Blumenstock, Huilin Chen, Angelika Dehn, David W. T. Griffith, Frank Hase, Pauli Heikkinen, Christian Hermans, Alex Hoffmann, Marko Huebner, Nicholas Jones, Rigel Kivi, Bavo Langerock, Christof Petri, Francis Scolas, Qiansi Tu, and Damien Weidmann
Atmos. Meas. Tech., 13, 4791–4839, https://doi.org/10.5194/amt-13-4791-2020, https://doi.org/10.5194/amt-13-4791-2020, 2020
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We present the results of the 2017 FRM4GHG campaign at the Sodankylä TCCON site aimed at characterising the assessment of several low-cost portable instruments for precise solar absorption measurements of column-averaged dry-air mole fractions of CO2, CH4, and CO. The test instruments provided stable and precise measurements of these gases with quantified small biases. This qualifies the instruments to complement TCCON and expand the global coverage of ground-based measurements of these gases.
Qiansi Tu, Frank Hase, Thomas Blumenstock, Rigel Kivi, Pauli Heikkinen, Mahesh Kumar Sha, Uwe Raffalski, Jochen Landgraf, Alba Lorente, Tobias Borsdorff, Huilin Chen, Florian Dietrich, and Jia Chen
Atmos. Meas. Tech., 13, 4751–4771, https://doi.org/10.5194/amt-13-4751-2020, https://doi.org/10.5194/amt-13-4751-2020, 2020
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Two COCCON instruments are used to observe multiyear greenhouse gases in boreal areas and are compared with the CAMS analysis and S5P satellite data. These three datasets predict greenhouse gas gradients with reasonable agreement. The results indicate that the COCCON instrument has the capability of measuring gradients on regional scales, and observations performed with the portable spectrometers can contribute to inferring sources and sinks and to validating spaceborne greenhouse gases.
Ilya Stanevich, Dylan B. A. Jones, Kimberly Strong, Robert J. Parker, Hartmut Boesch, Debra Wunch, Justus Notholt, Christof Petri, Thorsten Warneke, Ralf Sussmann, Matthias Schneider, Frank Hase, Rigel Kivi, Nicholas M. Deutscher, Voltaire A. Velazco, Kaley A. Walker, and Feng Deng
Geosci. Model Dev., 13, 3839–3862, https://doi.org/10.5194/gmd-13-3839-2020, https://doi.org/10.5194/gmd-13-3839-2020, 2020
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Systematic errors in atmospheric models pose a challenge for inverse modeling studies of methane (CH4) emissions. We evaluated the CH4 simulation in the GEOS-Chem model at the horizontal resolutions of 4° × 5° and 2° × 2.5°. Our analysis identified resolution-dependent biases in the model, which we attributed to discrepancies between the two model resolutions in vertical transport in the troposphere and in stratosphere–troposphere exchange.
Temesgen Yirdaw Berhe, Gizaw Mengistu Tsidu, Thomas Blumenstock, Frank Hase, and Gabriele P. Stiller
Atmos. Meas. Tech., 13, 4079–4096, https://doi.org/10.5194/amt-13-4079-2020, https://doi.org/10.5194/amt-13-4079-2020, 2020
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The retrieved CH4 and N2O VMR and column amounts from Addis Ababa, tropical site, are found to exhibit very good agreement with all coincident satellite observations (MIPAS, MLS, and AIRS). Furthermore, the bias obtained from the comparison is comparable to the precision of FTIR measurement, which allows the use of data in further scientific studies as it represents a unique environment of tropical Africa, a region poorly investigated in the past.
Benoît Tournadre, Pascale Chelin, Mokhtar Ray, Juan Cuesta, Rebecca D. Kutzner, Xavier Landsheere, Audrey Fortems-Cheiney, Jean-Marie Flaud, Frank Hase, Thomas Blumenstock, Johannes Orphal, Camille Viatte, and Claude Camy-Peyret
Atmos. Meas. Tech., 13, 3923–3937, https://doi.org/10.5194/amt-13-3923-2020, https://doi.org/10.5194/amt-13-3923-2020, 2020
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We present some results about ammonia pollution because NH3, mainly emitted by agricultural activities, is a precursor of fine particles. This study is based on the first multiyear time series (2009–2017) of atmospheric NH3 ground-based measurements over the Paris megacity. This pollutant varies seasonally by 2 orders of magnitude, especially in spring. We highlight that this kind of instrument could be easily installed and is very useful for analyzing NH3 in other megacities or source regions.
Corinne Vigouroux, Bavo Langerock, Carlos Augusto Bauer Aquino, Thomas Blumenstock, Zhibin Cheng, Martine De Mazière, Isabelle De Smedt, Michel Grutter, James W. Hannigan, Nicholas Jones, Rigel Kivi, Diego Loyola, Erik Lutsch, Emmanuel Mahieu, Maria Makarova, Jean-Marc Metzger, Isamu Morino, Isao Murata, Tomoo Nagahama, Justus Notholt, Ivan Ortega, Mathias Palm, Gaia Pinardi, Amelie Röhling, Dan Smale, Wolfgang Stremme, Kim Strong, Ralf Sussmann, Yao Té, Michel van Roozendael, Pucai Wang, and Holger Winkler
Atmos. Meas. Tech., 13, 3751–3767, https://doi.org/10.5194/amt-13-3751-2020, https://doi.org/10.5194/amt-13-3751-2020, 2020
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We validate the TROPOMI HCHO product with ground-based FTIR (Fourier-transform infrared) measurements from 25 stations. We find that TROPOMI overestimates HCHO under clean conditions, while it underestimates it at high HCHO levels. Both TROPOMI precision and accuracy reach the pre-launch requirements, and its precision can even be 2 times better. The observed TROPOMI seasonal variability is in agreement with the FTIR data. The TROPOMI random uncertainty and data filtering should be refined.
Arne Babenhauserheide, Frank Hase, and Isamu Morino
Atmos. Meas. Tech., 13, 2697–2710, https://doi.org/10.5194/amt-13-2697-2020, https://doi.org/10.5194/amt-13-2697-2020, 2020
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This paper demonstrates that the carbon dioxide emissions of Tokyo can be estimated from long-term ground-based measurements of column-averaged atmospheric carbon dioxide abundances recorded at the TCCON site Tsukuba.
Youwen Sun, Cheng Liu, Lin Zhang, Mathias Palm, Justus Notholt, Hao Yin, Corinne Vigouroux, Erik Lutsch, Wei Wang, Changong Shan, Thomas Blumenstock, Tomoo Nagahama, Isamu Morino, Emmanuel Mahieu, Kimberly Strong, Bavo Langerock, Martine De Mazière, Qihou Hu, Huifang Zhang, Christof Petri, and Jianguo Liu
Atmos. Chem. Phys., 20, 5437–5456, https://doi.org/10.5194/acp-20-5437-2020, https://doi.org/10.5194/acp-20-5437-2020, 2020
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We present multiyear time series of ground-based Fourier-transform infrared spectroscopy measurements of HCN in densely populated eastern China. The seasonality and interannual variability of tropospheric HCN columns were investigated. The potential sources that drive the observed HCN seasonality and interannual variability were determined using a GEOS-Chem tagged CO simulation, global fire maps, and potential source contribution function values calculated using HYSPLIT back trajectories.
Maximilian Reuter, Michael Buchwitz, Oliver Schneising, Stefan Noël, Heinrich Bovensmann, John P. Burrows, Hartmut Boesch, Antonio Di Noia, Jasdeep Anand, Robert J. Parker, Peter Somkuti, Lianghai Wu, Otto P. Hasekamp, Ilse Aben, Akihiko Kuze, Hiroshi Suto, Kei Shiomi, Yukio Yoshida, Isamu Morino, David Crisp, Christopher W. O'Dell, Justus Notholt, Christof Petri, Thorsten Warneke, Voltaire A. Velazco, Nicholas M. Deutscher, David W. T. Griffith, Rigel Kivi, David F. Pollard, Frank Hase, Ralf Sussmann, Yao V. Té, Kimberly Strong, Sébastien Roche, Mahesh K. Sha, Martine De Mazière, Dietrich G. Feist, Laura T. Iraci, Coleen M. Roehl, Christian Retscher, and Dinand Schepers
Atmos. Meas. Tech., 13, 789–819, https://doi.org/10.5194/amt-13-789-2020, https://doi.org/10.5194/amt-13-789-2020, 2020
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We present new satellite-derived data sets of atmospheric carbon dioxide (CO2) and methane (CH4). The data products are column-averaged dry-air mole fractions of CO2 and CH4, denoted XCO2 and XCH4. The products cover the years 2003–2018 and are merged Level 2 (satellite footprints) and merged Level 3 (gridded at monthly time and 5° x 5° spatial resolution) products obtained from combining several individual sensor products. We present the merging algorithms and product validation results.
Jonas Simon Wilzewski, Anke Roiger, Johan Strandgren, Jochen Landgraf, Dietrich G. Feist, Voltaire A. Velazco, Nicholas M. Deutscher, Isamu Morino, Hirofumi Ohyama, Yao Té, Rigel Kivi, Thorsten Warneke, Justus Notholt, Manvendra Dubey, Ralf Sussmann, Markus Rettinger, Frank Hase, Kei Shiomi, and André Butz
Atmos. Meas. Tech., 13, 731–745, https://doi.org/10.5194/amt-13-731-2020, https://doi.org/10.5194/amt-13-731-2020, 2020
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Through spectral degradation of GOSAT measurements in the 1.6 and 2.0 μm spectral bands, we mimic a single-band, passive satellite sensor for monitoring of CO2 emissions at fine spatial scales. We compare retrievals of XCO2 from these bands to TCCON and native GOSAT retrievals. At spectral resolutions near 1.3 nm, XCO2 retrievals from both bands show promising performance, but the 2.0 μm band is favorable due to better noise performance and the potential to retrieve some aerosol information.
Andreas Schneider, Tobias Borsdorff, Joost aan de Brugh, Franziska Aemisegger, Dietrich G. Feist, Rigel Kivi, Frank Hase, Matthias Schneider, and Jochen Landgraf
Atmos. Meas. Tech., 13, 85–100, https://doi.org/10.5194/amt-13-85-2020, https://doi.org/10.5194/amt-13-85-2020, 2020
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This paper presents a new H2O/HDO data set from TROPOMI short-wave infrared measurements. It is validated against recent ground-based FTIR measurements from the TCCON network. A bias in TCCON HDO (which is not verified) is corrected by fitting a correction factor for the HDO column to match MUSICA δD for common observations. The use of the new TROPOMI data set is demonstrated using a case study of a blocking anticyclone over Europe in July 2018.
Oliver Schneising, Michael Buchwitz, Maximilian Reuter, Heinrich Bovensmann, John P. Burrows, Tobias Borsdorff, Nicholas M. Deutscher, Dietrich G. Feist, David W. T. Griffith, Frank Hase, Christian Hermans, Laura T. Iraci, Rigel Kivi, Jochen Landgraf, Isamu Morino, Justus Notholt, Christof Petri, David F. Pollard, Sébastien Roche, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Voltaire A. Velazco, Thorsten Warneke, and Debra Wunch
Atmos. Meas. Tech., 12, 6771–6802, https://doi.org/10.5194/amt-12-6771-2019, https://doi.org/10.5194/amt-12-6771-2019, 2019
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We introduce an algorithm that is used to simultaneously derive the abundances of the important atmospheric constituents carbon monoxide and methane from the TROPOMI instrument onboard the Sentinel-5 Precursor satellite, which enables the determination of both gases with an unprecedented level of detail on a global scale. The quality of the resulting data sets is assessed and the first results are presented.
Susan S. Kulawik, Sean Crowell, David Baker, Junjie Liu, Kathryn McKain, Colm Sweeney, Sebastien C. Biraud, Steve Wofsy, Christopher W. O'Dell, Paul O. Wennberg, Debra Wunch, Coleen M. Roehl, Nicholas M. Deutscher, Matthäus Kiel, David W. T. Griffith, Voltaire A. Velazco, Justus Notholt, Thorsten Warneke, Christof Petri, Martine De Mazière, Mahesh K. Sha, Ralf Sussmann, Markus Rettinger, Dave F. Pollard, Isamu Morino, Osamu Uchino, Frank Hase, Dietrich G. Feist, Sébastien Roche, Kimberly Strong, Rigel Kivi, Laura Iraci, Kei Shiomi, Manvendra K. Dubey, Eliezer Sepulveda, Omaira Elena Garcia Rodriguez, Yao Té, Pascal Jeseck, Pauli Heikkinen, Edward J. Dlugokencky, Michael R. Gunson, Annmarie Eldering, David Crisp, Brendan Fisher, and Gregory B. Osterman
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2019-257, https://doi.org/10.5194/amt-2019-257, 2019
Publication in AMT not foreseen
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This paper provides a benchmark of OCO-2 v8 and ACOS-GOSAT v7.3 XCO2 and lowermost tropospheric (LMT) errors. The paper focuses on the systematic errors and subtracts out validation, co-location, and random errors, looks at the correlation scale-length (spatially and temporally) of systematic errors, finding that the scale lengths are similar to bias correction scale-lengths. The assimilates of the bias correction term is used to place an error on fluxes estimates.
Jacob K. Hedelius, Tai-Long He, Dylan B. A. Jones, Bianca C. Baier, Rebecca R. Buchholz, Martine De Mazière, Nicholas M. Deutscher, Manvendra K. Dubey, Dietrich G. Feist, David W. T. Griffith, Frank Hase, Laura T. Iraci, Pascal Jeseck, Matthäus Kiel, Rigel Kivi, Cheng Liu, Isamu Morino, Justus Notholt, Young-Suk Oh, Hirofumi Ohyama, David F. Pollard, Markus Rettinger, Sébastien Roche, Coleen M. Roehl, Matthias Schneider, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Colm Sweeney, Yao Té, Osamu Uchino, Voltaire A. Velazco, Wei Wang, Thorsten Warneke, Paul O. Wennberg, Helen M. Worden, and Debra Wunch
Atmos. Meas. Tech., 12, 5547–5572, https://doi.org/10.5194/amt-12-5547-2019, https://doi.org/10.5194/amt-12-5547-2019, 2019
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We seek ways to improve the accuracy of column measurements of carbon monoxide (CO) – an important tracer of pollution – made from the MOPITT satellite instrument. We devise a filtering scheme which reduces the scatter and also eliminates bias among the MOPITT detectors. Compared to ground-based observations, MOPITT measurements are about 6 %–8 % higher. When MOPITT data are implemented in a global assimilation model, they tend to reduce the model mismatch with aircraft measurements.
Tobias Borsdorff, Joost aan de Brugh, Andreas Schneider, Alba Lorente, Manfred Birk, Georg Wagner, Rigel Kivi, Frank Hase, Dietrich G. Feist, Ralf Sussmann, Markus Rettinger, Debra Wunch, Thorsten Warneke, and Jochen Landgraf
Atmos. Meas. Tech., 12, 5443–5455, https://doi.org/10.5194/amt-12-5443-2019, https://doi.org/10.5194/amt-12-5443-2019, 2019
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The study presents possible improvements of the TROPOMI CO dataset, which is a primary product of ESA's Sentinel-5P mission. We discuss the use of different molecular spectroscopic databases in the CO retrieval, the induced biases between TROPOMI CO and TCCON validation measurements, and the latitudinally dependent bias between TROPOMI CO and the CAMS-IFS model. Additionally, two methods for the stripe correction of single TROPOMI CO orbits are presented.
Andreas Luther, Ralph Kleinschek, Leon Scheidweiler, Sara Defratyka, Mila Stanisavljevic, Andreas Forstmaier, Alexandru Dandocsi, Sebastian Wolff, Darko Dubravica, Norman Wildmann, Julian Kostinek, Patrick Jöckel, Anna-Leah Nickl, Theresa Klausner, Frank Hase, Matthias Frey, Jia Chen, Florian Dietrich, Jarosław Nȩcki, Justyna Swolkień, Andreas Fix, Anke Roiger, and André Butz
Atmos. Meas. Tech., 12, 5217–5230, https://doi.org/10.5194/amt-12-5217-2019, https://doi.org/10.5194/amt-12-5217-2019, 2019
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Methane ventilated from hard coal mines in the Upper Silesian
Coal Basin in Poland is measured with a mobile Fourier transform spectrometer EM27/SUN. The instrument was mounted on a truck driving in stop-and-go patterns downwind of the methane sources. The emissions are estimated with the cross-sectional flux method. Calculated emissions are in broad agreement with the E-PRTR database. Wind-related errors on the methane estimates dominate the error budget and typically amount to 20 %.
Xinxu Zhao, Julia Marshall, Stephan Hachinger, Christoph Gerbig, Matthias Frey, Frank Hase, and Jia Chen
Atmos. Chem. Phys., 19, 11279–11302, https://doi.org/10.5194/acp-19-11279-2019, https://doi.org/10.5194/acp-19-11279-2019, 2019
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The Weather Research and Forecasting model (WRF), coupled with greenhouse gas (GHG) modules (WRF-GHG), is considered to be a suitable basis for precise GHG transport analysis in urban areas, especially when combined with differential column methodology (DCM). DCM is an effective method not only for comparing models to observations independently of biases caused, for example, by initial conditions, but also for detecting and understanding sources of GHG emissions quantitatively in urban areas.
Temesgen Yirdaw Berhe, Gizaw Mengistu Tsidu, Thomas Blumenstock, Frank Hase, Thomas von Clarmann, Justus Notholt, and Emmanuel Mahieu
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2019-209, https://doi.org/10.5194/amt-2019-209, 2019
Revised manuscript not accepted
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This study aims to assess the latitudinal variation of MIPAS version
V5R_CH4_220 and V5R_CH4_224 uncertainty. Furthermore, we analyze the relationship between these uncertainties and the variability of water vapor. Mainly, the high uncertainty found in tropics for MIPAS CH4 220 is highly associated with variability of water vapour. However, this effect has been reduced in the new updated MIPAS CH4 224 datasets due to jointly fitted water profile with methane.
Martina Michaela Friedrich, Claudia Rivera, Wolfgang Stremme, Zuleica Ojeda, Josué Arellano, Alejandro Bezanilla, José Agustín García-Reynoso, and Michel Grutter
Atmos. Meas. Tech., 12, 2545–2565, https://doi.org/10.5194/amt-12-2545-2019, https://doi.org/10.5194/amt-12-2545-2019, 2019
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We present a new numerical code to retrieve NO2 vertical column densities (VCDs) and concentrations from previously retrieved slanted columns from spectroscopic measurements in the visible and ultraviolet spectral ranges in different vertical viewing directions. We use this code on 1.5 years of data from a measurement station located in the south of Mexico City and compare daily and monthly averages to averages of in situ measurements. We show daily NO2 VCD time series for a few example days.
Udo Frieß, Steffen Beirle, Leonardo Alvarado Bonilla, Tim Bösch, Martina M. Friedrich, François Hendrick, Ankie Piters, Andreas Richter, Michel van Roozendael, Vladimir V. Rozanov, Elena Spinei, Jan-Lukas Tirpitz, Tim Vlemmix, Thomas Wagner, and Yang Wang
Atmos. Meas. Tech., 12, 2155–2181, https://doi.org/10.5194/amt-12-2155-2019, https://doi.org/10.5194/amt-12-2155-2019, 2019
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Multi-axis differential optical absorption spectroscopy (MAX-DOAS) is a widely used measurement technique for the detection of a variety of atmospheric trace gases. It enables the retrieval of aerosol and trace gas vertical profiles in the atmospheric boundary layer using appropriate retrieval algorithms. In this study, the ability of eight profile retrieval algorithms to reconstruct vertical profiles is assessed on the basis of synthetic measurements.
Debra Wunch, Dylan B. A. Jones, Geoffrey C. Toon, Nicholas M. Deutscher, Frank Hase, Justus Notholt, Ralf Sussmann, Thorsten Warneke, Jeroen Kuenen, Hugo Denier van der Gon, Jenny A. Fisher, and Joannes D. Maasakkers
Atmos. Chem. Phys., 19, 3963–3980, https://doi.org/10.5194/acp-19-3963-2019, https://doi.org/10.5194/acp-19-3963-2019, 2019
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We used five atmospheric observatories in Europe measuring total column dry-air mole fractions of methane and carbon monoxide to infer methane emissions in the area between the observatories. We find that the methane emissions are overestimated by the state-of-the-art inventories, and that this is likely due, at least in part, to the inventory disaggregation. We find that there is significant uncertainty in the carbon monoxide inventories that requires further investigation.
Julian Kostinek, Anke Roiger, Kenneth J. Davis, Colm Sweeney, Joshua P. DiGangi, Yonghoon Choi, Bianca Baier, Frank Hase, Jochen Groß, Maximilian Eckl, Theresa Klausner, and André Butz
Atmos. Meas. Tech., 12, 1767–1783, https://doi.org/10.5194/amt-12-1767-2019, https://doi.org/10.5194/amt-12-1767-2019, 2019
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We demonstrate the successful adaption of a laser-based spectrometer for airborne in situ trace gas measurements. The modified instrument allows for precise and simultaneous airborne observation of five climatologically relevant gases. We further report on instrument performance during a first field deployment over the eastern and central USA.
Felix R. Vogel, Matthias Frey, Johannes Staufer, Frank Hase, Grégoire Broquet, Irène Xueref-Remy, Frédéric Chevallier, Philippe Ciais, Mahesh Kumar Sha, Pascale Chelin, Pascal Jeseck, Christof Janssen, Yao Té, Jochen Groß, Thomas Blumenstock, Qiansi Tu, and Johannes Orphal
Atmos. Chem. Phys., 19, 3271–3285, https://doi.org/10.5194/acp-19-3271-2019, https://doi.org/10.5194/acp-19-3271-2019, 2019
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Providing timely information on greenhouse gas emissions to stakeholders at sub-national scale is an emerging challenge and understanding urban CO2 levels is one key aspect. This study uses atmospheric observations of total column CO2 and compares them to numerical simulations to investigate CO2 levels in the Paris metropolitan area due to natural fluxes and anthropogenic emissions. Our measurements reveal the influence of locally added CO2, which our model is also able to predict.
Matthias Frey, Mahesh K. Sha, Frank Hase, Matthäus Kiel, Thomas Blumenstock, Roland Harig, Gregor Surawicz, Nicholas M. Deutscher, Kei Shiomi, Jonathan E. Franklin, Hartmut Bösch, Jia Chen, Michel Grutter, Hirofumi Ohyama, Youwen Sun, André Butz, Gizaw Mengistu Tsidu, Dragos Ene, Debra Wunch, Zhensong Cao, Omaira Garcia, Michel Ramonet, Felix Vogel, and Johannes Orphal
Atmos. Meas. Tech., 12, 1513–1530, https://doi.org/10.5194/amt-12-1513-2019, https://doi.org/10.5194/amt-12-1513-2019, 2019
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In a 3.5-year long study, the long-term performance of a mobile EM27/SUN spectrometer, used for greenhouse gas observations, is checked with respect to a co-located reference spectrometer. We find that the EM27/SUN is stable on timescales of several years, qualifying it for permanent carbon cycle studies.
The performance of an ensemble of 30 EM27/SUN spectrometers was also tested in the framework of the COllaborative Carbon Column Observing Network (COCCON) and found to be very uniform.
Minqiang Zhou, Bavo Langerock, Kelley C. Wells, Dylan B. Millet, Corinne Vigouroux, Mahesh Kumar Sha, Christian Hermans, Jean-Marc Metzger, Rigel Kivi, Pauli Heikkinen, Dan Smale, David F. Pollard, Nicholas Jones, Nicholas M. Deutscher, Thomas Blumenstock, Matthias Schneider, Mathias Palm, Justus Notholt, James W. Hannigan, and Martine De Mazière
Atmos. Meas. Tech., 12, 1393–1408, https://doi.org/10.5194/amt-12-1393-2019, https://doi.org/10.5194/amt-12-1393-2019, 2019
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N2O is an important atmospheric gas which is observed by two ground-based FTIR networks (TCCON and NDACC). The difference between NDACC and TCCON XN2O measurements is discussed. It is found that the bias between the two networks is within their combined uncertainties. However, TCCON measurements are affected by a priori profiles. In addition, the TCCON and NDACC N2O measurements are compared with the GEOS-Chem model simulations.
Christopher W. O'Dell, Annmarie Eldering, Paul O. Wennberg, David Crisp, Michael R. Gunson, Brendan Fisher, Christian Frankenberg, Matthäus Kiel, Hannakaisa Lindqvist, Lukas Mandrake, Aronne Merrelli, Vijay Natraj, Robert R. Nelson, Gregory B. Osterman, Vivienne H. Payne, Thomas E. Taylor, Debra Wunch, Brian J. Drouin, Fabiano Oyafuso, Albert Chang, James McDuffie, Michael Smyth, David F. Baker, Sourish Basu, Frédéric Chevallier, Sean M. R. Crowell, Liang Feng, Paul I. Palmer, Mavendra Dubey, Omaira E. García, David W. T. Griffith, Frank Hase, Laura T. Iraci, Rigel Kivi, Isamu Morino, Justus Notholt, Hirofumi Ohyama, Christof Petri, Coleen M. Roehl, Mahesh K. Sha, Kimberly Strong, Ralf Sussmann, Yao Te, Osamu Uchino, and Voltaire A. Velazco
Atmos. Meas. Tech., 11, 6539–6576, https://doi.org/10.5194/amt-11-6539-2018, https://doi.org/10.5194/amt-11-6539-2018, 2018
Tobias Borsdorff, Joost aan de Brugh, Haili Hu, Otto Hasekamp, Ralf Sussmann, Markus Rettinger, Frank Hase, Jochen Gross, Matthias Schneider, Omaira Garcia, Wolfgang Stremme, Michel Grutter, Dietrich G. Feist, Sabrina G. Arnold, Martine De Mazière, Mahesh Kumar Sha, David F. Pollard, Matthäus Kiel, Coleen Roehl, Paul O. Wennberg, Geoffrey C. Toon, and Jochen Landgraf
Atmos. Meas. Tech., 11, 5507–5518, https://doi.org/10.5194/amt-11-5507-2018, https://doi.org/10.5194/amt-11-5507-2018, 2018
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On 13 October 2017, the S5-P satellite was launched with TROPOMI as its only payload. One of the primary products is atmospheric CO observed with daily global coverage and spatial resolution of 7 × 7 km2. The new dataset allows the sensing of CO enhancements above cities and industrial areas and can track pollution transport from biomass burning regions. Through validation with ground-based TCCON measurements we show that the CO data product is already well within the mission requirement.
Corinne Vigouroux, Carlos Augusto Bauer Aquino, Maite Bauwens, Cornelis Becker, Thomas Blumenstock, Martine De Mazière, Omaira García, Michel Grutter, César Guarin, James Hannigan, Frank Hase, Nicholas Jones, Rigel Kivi, Dmitry Koshelev, Bavo Langerock, Erik Lutsch, Maria Makarova, Jean-Marc Metzger, Jean-François Müller, Justus Notholt, Ivan Ortega, Mathias Palm, Clare Paton-Walsh, Anatoly Poberovskii, Markus Rettinger, John Robinson, Dan Smale, Trissevgeni Stavrakou, Wolfgang Stremme, Kim Strong, Ralf Sussmann, Yao Té, and Geoffrey Toon
Atmos. Meas. Tech., 11, 5049–5073, https://doi.org/10.5194/amt-11-5049-2018, https://doi.org/10.5194/amt-11-5049-2018, 2018
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A few ground-based stations have provided time series of HCHO columns until now, which was not optimal for providing good diagnostics for satellite or model validation. In this work, HCHO time series have been determined in a harmonized way at 21 stations ensuring, in addition to a better spatial and level of abundances coverage, that internal biases within the network have been minimized. This data set shows consistent good agreement with model data and is ready for future satellite validation.
Christian Borger, Matthias Schneider, Benjamin Ertl, Frank Hase, Omaira E. García, Michael Sommer, Michael Höpfner, Stephen A. Tjemkes, and Xavier Calbet
Atmos. Meas. Tech., 11, 4981–5006, https://doi.org/10.5194/amt-11-4981-2018, https://doi.org/10.5194/amt-11-4981-2018, 2018
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In this paper MUSICA IASI tropospheric water vapour profile retrievals are evaluated by performing theoretical error assessments and comparisons to GRUAN radiosonde measurements. We show that the vertical water vapour distribution is well captured from 1 km above the ground up to the tropopause. Largest error sources are unrecognized clouds and uncertainties in atmospheric temperature, which can reach about 25 %.
Omaira E. García, Matthias Schneider, Benjamin Ertl, Eliezer Sepúlveda, Christian Borger, Christopher Diekmann, Andreas Wiegele, Frank Hase, Sabine Barthlott, Thomas Blumenstock, Uwe Raffalski, Angel Gómez-Peláez, Martin Steinbacher, Ludwig Ries, and Angel M. de Frutos
Atmos. Meas. Tech., 11, 4171–4215, https://doi.org/10.5194/amt-11-4171-2018, https://doi.org/10.5194/amt-11-4171-2018, 2018
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This work presents the CH4 and N2O products of the MUSICA IASI processor. We analytically assess precisions of 1.5–3 %, good sensitivity in the UTLS region (for CH4 and N2O) and a possibility for retrieving free-tropospheric CH4 at low latitudes independently from CH4 in the UTLS. This is confirmed by comparison to HIPPO profile data (covering a large latitudinal range), continuous GAW data (covering 9 years) and NDACC FTIR data (covering 10 years and three different climate zones).
Lianghai Wu, Otto Hasekamp, Haili Hu, Jochen Landgraf, Andre Butz, Joost aan de Brugh, Ilse Aben, Dave F. Pollard, David W. T. Griffith, Dietrich G. Feist, Dmitry Koshelev, Frank Hase, Geoffrey C. Toon, Hirofumi Ohyama, Isamu Morino, Justus Notholt, Kei Shiomi, Laura Iraci, Matthias Schneider, Martine de Mazière, Ralf Sussmann, Rigel Kivi, Thorsten Warneke, Tae-Young Goo, and Yao Té
Atmos. Meas. Tech., 11, 3111–3130, https://doi.org/10.5194/amt-11-3111-2018, https://doi.org/10.5194/amt-11-3111-2018, 2018
Youwen Sun, Mathias Palm, Cheng Liu, Frank Hase, David Griffith, Christine Weinzierl, Christof Petri, Wei Wang, and Justus Notholt
Atmos. Meas. Tech., 11, 2879–2896, https://doi.org/10.5194/amt-11-2879-2018, https://doi.org/10.5194/amt-11-2879-2018, 2018
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We simulated instrumental line shape (ILS) degradations with respect to typical types of misalignment, and compared their influence on each NDACC gas. The requirements to suppress the ILS-degradation-related biases within a specified accuracy for all NDACC gases were deduced.
Martine De Mazière, Anne M. Thompson, Michael J. Kurylo, Jeannette D. Wild, Germar Bernhard, Thomas Blumenstock, Geir O. Braathen, James W. Hannigan, Jean-Christopher Lambert, Thierry Leblanc, Thomas J. McGee, Gerald Nedoluha, Irina Petropavlovskikh, Gunther Seckmeyer, Paul C. Simon, Wolfgang Steinbrecht, and Susan E. Strahan
Atmos. Chem. Phys., 18, 4935–4964, https://doi.org/10.5194/acp-18-4935-2018, https://doi.org/10.5194/acp-18-4935-2018, 2018
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This paper serves as an introduction to the special issue "Twenty-five years of operations of the Network for the Detection of Atmospheric Composition Change (NDACC)". It describes the origins of the network, its actual status, and some perspectives for its future evolution in the context of atmospheric sciences.
Yana A. Virolainen, Yury M. Timofeyev, Vladimir S. Kostsov, Dmitry V. Ionov, Vladislav V. Kalinnikov, Maria V. Makarova, Anatoly V. Poberovsky, Nikita A. Zaitsev, Hamud H. Imhasin, Alexander V. Polyakov, Matthias Schneider, Frank Hase, Sabine Barthlott, and Thomas Blumenstock
Atmos. Meas. Tech., 10, 4521–4536, https://doi.org/10.5194/amt-10-4521-2017, https://doi.org/10.5194/amt-10-4521-2017, 2017
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Water vapour is one of the most important gases in the Earth’s atmosphere and plays a unique role in climate and weather forming. Cross-comparison of different systems for monitoring the atmospheric integrated water vapour (IWV) measurements is an essential part of their testing and validation protocol. We compare coincident measurements of IWV by different techniques over Saint Petersburg (Russia), assess their quality in various atmospheric conditions, and give recommendation for data users.
Kevin S. Olsen, Kimberly Strong, Kaley A. Walker, Chris D. Boone, Piera Raspollini, Johannes Plieninger, Whitney Bader, Stephanie Conway, Michel Grutter, James W. Hannigan, Frank Hase, Nicholas Jones, Martine de Mazière, Justus Notholt, Matthias Schneider, Dan Smale, Ralf Sussmann, and Naoko Saitoh
Atmos. Meas. Tech., 10, 3697–3718, https://doi.org/10.5194/amt-10-3697-2017, https://doi.org/10.5194/amt-10-3697-2017, 2017
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The primary instrument on the Greenhouse gases Observing SATellite (GOSAT) is the Thermal And Near infrared Sensor for carbon Observations (TANSO) Fourier transform spectrometer (FTS). TANSO-FTS has a thermal infrared channel to retrieve vertical profiles of CO2 and CH4 volume mixing ratios in the troposphere. We compare the retrieved vertical profiles of CH4 from TANSO-FTS with those from two other spaceborne FTSs and with ground-based FTS observatories to assess their quality.
Wolfgang Steinbrecht, Lucien Froidevaux, Ryan Fuller, Ray Wang, John Anderson, Chris Roth, Adam Bourassa, Doug Degenstein, Robert Damadeo, Joe Zawodny, Stacey Frith, Richard McPeters, Pawan Bhartia, Jeannette Wild, Craig Long, Sean Davis, Karen Rosenlof, Viktoria Sofieva, Kaley Walker, Nabiz Rahpoe, Alexei Rozanov, Mark Weber, Alexandra Laeng, Thomas von Clarmann, Gabriele Stiller, Natalya Kramarova, Sophie Godin-Beekmann, Thierry Leblanc, Richard Querel, Daan Swart, Ian Boyd, Klemens Hocke, Niklaus Kämpfer, Eliane Maillard Barras, Lorena Moreira, Gerald Nedoluha, Corinne Vigouroux, Thomas Blumenstock, Matthias Schneider, Omaira García, Nicholas Jones, Emmanuel Mahieu, Dan Smale, Michael Kotkamp, John Robinson, Irina Petropavlovskikh, Neil Harris, Birgit Hassler, Daan Hubert, and Fiona Tummon
Atmos. Chem. Phys., 17, 10675–10690, https://doi.org/10.5194/acp-17-10675-2017, https://doi.org/10.5194/acp-17-10675-2017, 2017
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Thanks to the 1987 Montreal Protocol and its amendments, ozone-depleting chlorine (and bromine) in the stratosphere has declined slowly since the late 1990s. Improved and extended long-term ozone profile observations from satellites and ground-based stations confirm that ozone is responding as expected and has increased by about 2 % per decade since 2000 in the upper stratosphere, around 40 km altitude. At lower altitudes, however, ozone has not changed significantly since 2000.
Eddy F. Plaza-Medina, Wolfgang Stremme, Alejandro Bezanilla, Michel Grutter, Matthias Schneider, Frank Hase, and Thomas Blumenstock
Atmos. Meas. Tech., 10, 2703–2725, https://doi.org/10.5194/amt-10-2703-2017, https://doi.org/10.5194/amt-10-2703-2017, 2017
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We present data and error estimations of O3 profiles retrieved from spectra measured by a medium- and a high-resolution FTIR spectrometer (located at 2260 m and 3985 m a.s.l.). Above the tropopause both data sets agree well and in accordance with the estimated errors. We introduce a product that combines the two FTIR retrieval results, and a comparison to Mexico City in situ data indicates that the combined product is able to capture the highly varying boundary layer O3 concentrations.
Enrico Dammers, Mark W. Shephard, Mathias Palm, Karen Cady-Pereira, Shannon Capps, Erik Lutsch, Kim Strong, James W. Hannigan, Ivan Ortega, Geoffrey C. Toon, Wolfgang Stremme, Michel Grutter, Nicholas Jones, Dan Smale, Jacob Siemons, Kevin Hrpcek, Denis Tremblay, Martijn Schaap, Justus Notholt, and Jan Willem Erisman
Atmos. Meas. Tech., 10, 2645–2667, https://doi.org/10.5194/amt-10-2645-2017, https://doi.org/10.5194/amt-10-2645-2017, 2017
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Presented here is the validation of the CrIS fast physical retrieval (CFPR) NH3 column and profile measurements using ground-based Fourier transform infrared (FTIR) observations. The overall FTIR and CrIS total columns have a positive correlation of r = 0.77 (N = 218) with very little bias (a slope of 1.02). Furthermore, we find that CrIS and FTIR profile comparison differences are mostly within the range of the estimated retrieval uncertainties, with differences in the range of ~ 20 to 40 %.
Jorge L. Baylon, Wolfgang Stremme, Michel Grutter, Frank Hase, and Thomas Blumenstock
Atmos. Meas. Tech., 10, 2425–2434, https://doi.org/10.5194/amt-10-2425-2017, https://doi.org/10.5194/amt-10-2425-2017, 2017
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In this investigation we analyze two common optical configurations to retrieve CO2 total column amounts from solar absorption infrared spectra. The noise errors using either a KBr or CaF2 beam splitter, a main component of a Fourier transform infrared spectrometer, are quantified in order to assess the relative precisions of the measurements. A 3-year XCO2 time series at the high-altitude site of Altzomoni in central Mexico presents clear annual and diurnal cycles and a trend of +2.2 ppm yr-1.
Debra Wunch, Paul O. Wennberg, Gregory Osterman, Brendan Fisher, Bret Naylor, Coleen M. Roehl, Christopher O'Dell, Lukas Mandrake, Camille Viatte, Matthäus Kiel, David W. T. Griffith, Nicholas M. Deutscher, Voltaire A. Velazco, Justus Notholt, Thorsten Warneke, Christof Petri, Martine De Maziere, Mahesh K. Sha, Ralf Sussmann, Markus Rettinger, David Pollard, John Robinson, Isamu Morino, Osamu Uchino, Frank Hase, Thomas Blumenstock, Dietrich G. Feist, Sabrina G. Arnold, Kimberly Strong, Joseph Mendonca, Rigel Kivi, Pauli Heikkinen, Laura Iraci, James Podolske, Patrick W. Hillyard, Shuji Kawakami, Manvendra K. Dubey, Harrison A. Parker, Eliezer Sepulveda, Omaira E. García, Yao Te, Pascal Jeseck, Michael R. Gunson, David Crisp, and Annmarie Eldering
Atmos. Meas. Tech., 10, 2209–2238, https://doi.org/10.5194/amt-10-2209-2017, https://doi.org/10.5194/amt-10-2209-2017, 2017
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This paper describes the comparisons between NASA's Orbiting Carbon Observatory (OCO-2) column-averaged dry-air mole fractions of CO2 with its primary ground-based validation network, the Total Carbon Column Observing Network (TCCON). The paper shows that while the standard bias correction reduces much of the spurious variability in the satellite measurements, residual biases remain.
Rebecca R. Buchholz, Merritt N. Deeter, Helen M. Worden, John Gille, David P. Edwards, James W. Hannigan, Nicholas B. Jones, Clare Paton-Walsh, David W. T. Griffith, Dan Smale, John Robinson, Kimberly Strong, Stephanie Conway, Ralf Sussmann, Frank Hase, Thomas Blumenstock, Emmanuel Mahieu, and Bavo Langerock
Atmos. Meas. Tech., 10, 1927–1956, https://doi.org/10.5194/amt-10-1927-2017, https://doi.org/10.5194/amt-10-1927-2017, 2017
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The study presents the first systematic use of ground-based remote-sensing data from the Network for the Detection of Atmospheric Composition Change (NDACC) to validate satellite-based Measurements of Pollution in the Troposphere (MOPITT) total column carbon monoxide (CO). MOPITT generally shows low bias with respect to the ground-based instruments. The geographic and temporal dependence of validation results are determined. Our findings inform some recommendations for using MOPITT measurements.
Liang Feng, Paul I. Palmer, Hartmut Bösch, Robert J. Parker, Alex J. Webb, Caio S. C. Correia, Nicholas M. Deutscher, Lucas G. Domingues, Dietrich G. Feist, Luciana V. Gatti, Emanuel Gloor, Frank Hase, Rigel Kivi, Yi Liu, John B. Miller, Isamu Morino, Ralf Sussmann, Kimberly Strong, Osamu Uchino, Jing Wang, and Andreas Zahn
Atmos. Chem. Phys., 17, 4781–4797, https://doi.org/10.5194/acp-17-4781-2017, https://doi.org/10.5194/acp-17-4781-2017, 2017
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We use the GEOS-Chem global 3-D model of atmospheric chemistry and transport and an ensemble Kalman filter to simultaneously infer regional fluxes of methane (CH4) and carbon dioxide (CO2) directly from GOSAT retrievals of XCH4:XCO2, using sparse ground-based CH4 and CO2 mole fraction data to anchor the ratio. Our results show that assimilation of GOSAT data significantly reduced the posterior uncertainty and changed the a priori spatial distribution of CH4 emissions.
Enno Peters, Gaia Pinardi, André Seyler, Andreas Richter, Folkard Wittrock, Tim Bösch, Michel Van Roozendael, François Hendrick, Theano Drosoglou, Alkiviadis F. Bais, Yugo Kanaya, Xiaoyi Zhao, Kimberly Strong, Johannes Lampel, Rainer Volkamer, Theodore Koenig, Ivan Ortega, Olga Puentedura, Mónica Navarro-Comas, Laura Gómez, Margarita Yela González, Ankie Piters, Julia Remmers, Yang Wang, Thomas Wagner, Shanshan Wang, Alfonso Saiz-Lopez, David García-Nieto, Carlos A. Cuevas, Nuria Benavent, Richard Querel, Paul Johnston, Oleg Postylyakov, Alexander Borovski, Alexander Elokhov, Ilya Bruchkouski, Haoran Liu, Cheng Liu, Qianqian Hong, Claudia Rivera, Michel Grutter, Wolfgang Stremme, M. Fahim Khokhar, Junaid Khayyam, and John P. Burrows
Atmos. Meas. Tech., 10, 955–978, https://doi.org/10.5194/amt-10-955-2017, https://doi.org/10.5194/amt-10-955-2017, 2017
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This work is about harmonization of differential optical absorption spectroscopy retrieval codes, which is a remote sensing technique widely used to derive atmospheric trace gas amounts. The study is based on ground-based measurements performed during the Multi-Axis DOAS Comparison campaign for Aerosols and Trace gases (MAD-CAT) in Mainz, Germany, in summer 2013. In total, 17 international groups working in the field of the DOAS technique participated in this study.
Whitney Bader, Benoît Bovy, Stephanie Conway, Kimberly Strong, Dan Smale, Alexander J. Turner, Thomas Blumenstock, Chris Boone, Martine Collaud Coen, Ancelin Coulon, Omaira Garcia, David W. T. Griffith, Frank Hase, Petra Hausmann, Nicholas Jones, Paul Krummel, Isao Murata, Isamu Morino, Hideaki Nakajima, Simon O'Doherty, Clare Paton-Walsh, John Robinson, Rodrigue Sandrin, Matthias Schneider, Christian Servais, Ralf Sussmann, and Emmanuel Mahieu
Atmos. Chem. Phys., 17, 2255–2277, https://doi.org/10.5194/acp-17-2255-2017, https://doi.org/10.5194/acp-17-2255-2017, 2017
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An increase of 0.31 ± 0.03 % year−1 of atmospheric methane is reported using 10 years of solar observations performed at 10 ground-based stations since 2005. These trend agree with a GEOS-Chem-tagged simulation that accounts for the contribution of each emission source and one sink in the total methane. The GEOS-Chem simulation shows that anthropogenic emissions from coal mining and gas and oil transport and exploration have played a major role in the increase methane since 2005.
Matthias Schneider, Christian Borger, Andreas Wiegele, Frank Hase, Omaira E. García, Eliezer Sepúlveda, and Martin Werner
Atmos. Meas. Tech., 10, 507–525, https://doi.org/10.5194/amt-10-507-2017, https://doi.org/10.5194/amt-10-507-2017, 2017
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The characteristics of {H2O,δD} pair space-based remote sensing data depend on the atmospheric and surface conditions, which compromises their usage for model evaluation studies. This paper shows how the problem can be overcome by simulating MUSICA MetOp/IASI {H2O,δD} remote sensing products for any given model atmosphere. The remote sensing retrieval simulator is freely provided as a MATLAB and Python routine.
Natalie Kille, Sunil Baidar, Philip Handley, Ivan Ortega, Roman Sinreich, Owen R. Cooper, Frank Hase, James W. Hannigan, Gabriele Pfister, and Rainer Volkamer
Atmos. Meas. Tech., 10, 373–392, https://doi.org/10.5194/amt-10-373-2017, https://doi.org/10.5194/amt-10-373-2017, 2017
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This article describes a new instrument for measuring and quantifying emission fluxes. It introduces the instrument using the solar occultation flux method. Results are presented from the FRAPPE field campaign near Denver, Colorado, from 2014. Calculations of emissions of sources are presented from FRAPPE and compared to emission inventories. Finally, structure functions are calculated to facilitate the future comparison of high-resolution measurements with low resolution satellite measurements.
Sabine Barthlott, Matthias Schneider, Frank Hase, Thomas Blumenstock, Matthäus Kiel, Darko Dubravica, Omaira E. García, Eliezer Sepúlveda, Gizaw Mengistu Tsidu, Samuel Takele Kenea, Michel Grutter, Eddy F. Plaza-Medina, Wolfgang Stremme, Kim Strong, Dan Weaver, Mathias Palm, Thorsten Warneke, Justus Notholt, Emmanuel Mahieu, Christian Servais, Nicholas Jones, David W. T. Griffith, Dan Smale, and John Robinson
Earth Syst. Sci. Data, 9, 15–29, https://doi.org/10.5194/essd-9-15-2017, https://doi.org/10.5194/essd-9-15-2017, 2017
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Tropospheric water vapour isotopologue distributions have been consistently generated and quality-filtered for 12 globally distributed ground-based FTIR sites. The products are provided as two data types. The first type is best-suited for tropospheric water vapour distribution studies. The second type is needed for analysing moisture pathways by means of {H2O,δD}-pair distributions. This paper describes the data types and gives recommendations for their correct usage.
André Butz, Anna Solvejg Dinger, Nicole Bobrowski, Julian Kostinek, Lukas Fieber, Constanze Fischerkeller, Giovanni Bruno Giuffrida, Frank Hase, Friedrich Klappenbach, Jonas Kuhn, Peter Lübcke, Lukas Tirpitz, and Qiansi Tu
Atmos. Meas. Tech., 10, 1–14, https://doi.org/10.5194/amt-10-1-2017, https://doi.org/10.5194/amt-10-1-2017, 2017
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Remote sensing of the gaseous composition of non-eruptive, passively degassing volcanic plumes can be a tool for volcano monitoring. Here, we report on a field study that demonstrates the feasibility of remotely measuring the volcanic enhancements of carbon dioxide, hydrogen fluoride, hydrogen chloride, sulfur dioxide, and bromine monoxide in the plume of Mt. Etna using portable spectroscopic instrumentation sampling the plume several kilometers downwind of the source.
Michael Höpfner, Rainer Volkamer, Udo Grabowski, Michel Grutter, Johannes Orphal, Gabriele Stiller, Thomas von Clarmann, and Gerald Wetzel
Atmos. Chem. Phys., 16, 14357–14369, https://doi.org/10.5194/acp-16-14357-2016, https://doi.org/10.5194/acp-16-14357-2016, 2016
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Ammonia (NH3) in the atmosphere is important because of its influence on aerosol and cloud formation and its increasing anthropogenic emissions. We report the first detection of NH3 in the upper troposphere by the analysis of infrared limb emission spectra measured by the MIPAS instrument on Envisat. We have found enhanced values of NH3 within the Asian summer monsoon upper troposphere, where it might contribute to the composition of the Asian tropopause aerosol layer.
Katherine M. Saad, Debra Wunch, Nicholas M. Deutscher, David W. T. Griffith, Frank Hase, Martine De Mazière, Justus Notholt, David F. Pollard, Coleen M. Roehl, Matthias Schneider, Ralf Sussmann, Thorsten Warneke, and Paul O. Wennberg
Atmos. Chem. Phys., 16, 14003–14024, https://doi.org/10.5194/acp-16-14003-2016, https://doi.org/10.5194/acp-16-14003-2016, 2016
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Current approaches to constrain the global methane budget assimilate total column measurements into models, but model biases can impact results. We use tropospheric methane columns to evaluate model transport errors and identify a seasonal time lag in the Northern Hemisphere troposphere masked by stratospheric compensating effects. We find systematic biases in the stratosphere will alias into model-derived emissions estimates, especially those in the high Northern latitudes that vary seasonally.
Andreas Ostler, Ralf Sussmann, Prabir K. Patra, Sander Houweling, Marko De Bruine, Gabriele P. Stiller, Florian J. Haenel, Johannes Plieninger, Philippe Bousquet, Yi Yin, Marielle Saunois, Kaley A. Walker, Nicholas M. Deutscher, David W. T. Griffith, Thomas Blumenstock, Frank Hase, Thorsten Warneke, Zhiting Wang, Rigel Kivi, and John Robinson
Atmos. Meas. Tech., 9, 4843–4859, https://doi.org/10.5194/amt-9-4843-2016, https://doi.org/10.5194/amt-9-4843-2016, 2016
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Our evaluation of column-averaged methane (XCH4) in models and TCCON reveals latitudinal biases between 0.4 % and 2.1 % originating from an inter-model spread in stratospheric CH4. Substituting model stratospheric CH4 fields by satellite data significantly reduces the large XCH4 bias observed for one model. For other models, showing only minor biases, the impact is ambiguous; i.e., the satellite uncertainty range hinders a more accurate model evaluation needed to improve inverse modeling.
Gaétane Ronsmans, Bavo Langerock, Catherine Wespes, James W. Hannigan, Frank Hase, Tobias Kerzenmacher, Emmanuel Mahieu, Matthias Schneider, Dan Smale, Daniel Hurtmans, Martine De Mazière, Cathy Clerbaux, and Pierre-François Coheur
Atmos. Meas. Tech., 9, 4783–4801, https://doi.org/10.5194/amt-9-4783-2016, https://doi.org/10.5194/amt-9-4783-2016, 2016
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HNO3 concentrations are obtained from the IASI instrument and the data set is characterized for the first time in terms of vertical profiles, averaging kernels and error profiles. A validation is also conducted through a comparison with ground-based FTIR measurements, with good results. The data set is then used to analyse HNO3 spatial and temporal variability for the year 2011. The latitudinal gradient and the large seasonal variability in polar regions are well represented with IASI data.
Cristina Robles-Gonzalez, Mónica Navarro-Comas, Olga Puentedura, Matthias Schneider, Frank Hase, Omaira Garcia, Thomas Blumenstock, and Manuel Gil-Ojeda
Atmos. Meas. Tech., 9, 4471–4485, https://doi.org/10.5194/amt-9-4471-2016, https://doi.org/10.5194/amt-9-4471-2016, 2016
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The comparison of observations performed by different techniques and satellite instruments is important. An intercomparison of the stratospheric NO2 derived from ground-based and satellite instruments has been carried out over the Izaña subtropical site. The importance of the use of the effective solar zenith angle when comparing noon measurements with twilight measurements of photochemically active species is highlighted. All instruments show positive trends in NO2 stratospheric column.
Enrico Dammers, Mathias Palm, Martin Van Damme, Corinne Vigouroux, Dan Smale, Stephanie Conway, Geoffrey C. Toon, Nicholas Jones, Eric Nussbaumer, Thorsten Warneke, Christof Petri, Lieven Clarisse, Cathy Clerbaux, Christian Hermans, Erik Lutsch, Kim Strong, James W. Hannigan, Hideaki Nakajima, Isamu Morino, Beatriz Herrera, Wolfgang Stremme, Michel Grutter, Martijn Schaap, Roy J. Wichink Kruit, Justus Notholt, Pierre-F. Coheur, and Jan Willem Erisman
Atmos. Chem. Phys., 16, 10351–10368, https://doi.org/10.5194/acp-16-10351-2016, https://doi.org/10.5194/acp-16-10351-2016, 2016
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Atmospheric ammonia (NH3) measured by the IASI satellite instrument is compared to observations from ground-based FTIR instruments. The seasonal cycles of NH3 in both datasets are consistent for most sites. Correlations are found to be high at sites with considerable NH3 levels, whereas correlations are lower at sites with low NH3 levels close to the detection limit of the IASI instrument. The study's results further indicate that the IASI-NH3 product performs better than earlier estimates.
Makoto Inoue, Isamu Morino, Osamu Uchino, Takahiro Nakatsuru, Yukio Yoshida, Tatsuya Yokota, Debra Wunch, Paul O. Wennberg, Coleen M. Roehl, David W. T. Griffith, Voltaire A. Velazco, Nicholas M. Deutscher, Thorsten Warneke, Justus Notholt, John Robinson, Vanessa Sherlock, Frank Hase, Thomas Blumenstock, Markus Rettinger, Ralf Sussmann, Esko Kyrö, Rigel Kivi, Kei Shiomi, Shuji Kawakami, Martine De Mazière, Sabrina G. Arnold, Dietrich G. Feist, Erica A. Barrow, James Barney, Manvendra Dubey, Matthias Schneider, Laura T. Iraci, James R. Podolske, Patrick W. Hillyard, Toshinobu Machida, Yousuke Sawa, Kazuhiro Tsuboi, Hidekazu Matsueda, Colm Sweeney, Pieter P. Tans, Arlyn E. Andrews, Sebastien C. Biraud, Yukio Fukuyama, Jasna V. Pittman, Eric A. Kort, and Tomoaki Tanaka
Atmos. Meas. Tech., 9, 3491–3512, https://doi.org/10.5194/amt-9-3491-2016, https://doi.org/10.5194/amt-9-3491-2016, 2016
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In this study, we correct the biases of GOSAT XCO2 and XCH4 using TCCON data. To evaluate the effectiveness of our correction method, uncorrected/corrected GOSAT data are compared to independent XCO2 and XCH4 data derived from aircraft measurements. Consequently, we suggest that this method is effective for reducing the biases of the GOSAT data. We consider that our work provides GOSAT data users with valuable information and contributes to the further development of studies on greenhouse gases.
Matthias Schneider, Andreas Wiegele, Sabine Barthlott, Yenny González, Emanuel Christner, Christoph Dyroff, Omaira E. García, Frank Hase, Thomas Blumenstock, Eliezer Sepúlveda, Gizaw Mengistu Tsidu, Samuel Takele Kenea, Sergio Rodríguez, and Javier Andrey
Atmos. Meas. Tech., 9, 2845–2875, https://doi.org/10.5194/amt-9-2845-2016, https://doi.org/10.5194/amt-9-2845-2016, 2016
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Tropospheric {H2O,δD} pairs can be observed by remote sensing techniques, but the data quality strongly depends on a comprehensive consideration of the complex nature and a careful calibration of the remote sensing data pairs. This paper reviews the quality assurance/documentation activities of the MUSICA project and demonstrates that MUSICA’s ground-based FTIR and space-based IASI {H2O,δD} pair products are accurate and can be generated at a global scale with high resolution and for long periods.
Dietrich G. Feist, Sabrina G. Arnold, Frank Hase, and Dirk Ponge
Atmos. Meas. Tech., 9, 2381–2391, https://doi.org/10.5194/amt-9-2381-2016, https://doi.org/10.5194/amt-9-2381-2016, 2016
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Optical equipment is usually not made for harsh environments. At our atmospheric observation site on Ascension Island, commercially available optical mirrors were destroyed within weeks after being installed outside. To be able to continue our observations, we had to develop rugged optical mirrors that are able to sustain sea salt spray, volcanic dust, and regular cleaning without loosing their reflectivity and without adverse effects on the retrieval quality.
Omaira Elena García, Eliezer Sepúlveda, Matthias Schneider, Frank Hase, Thomas August, Thomas Blumenstock, Sven Kühl, Rosemary Munro, Ángel Jesús Gómez-Peláez, Tim Hultberg, Alberto Redondas, Sabine Barthlott, Andreas Wiegele, Yenny González, and Esther Sanromá
Atmos. Meas. Tech., 9, 2315–2333, https://doi.org/10.5194/amt-9-2315-2016, https://doi.org/10.5194/amt-9-2315-2016, 2016
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Atmospheric remote sounding from space is fundamental for investigating the processes driving climate change. However, for a correct scientific interpretation of these records a documentation of their quality is required. In this context, this paper exploits the high potential of the Izaña Atmospheric Observatory, as a ground-based reference site, to perform the first comprehensive validation of the EUMETSAT atmospheric trace gas products O3, CH4, N2O, CO and CO2 of the remote sensor IASI.
Frank Hase, Matthias Frey, Matthäus Kiel, Thomas Blumenstock, Roland Harig, Axel Keens, and Johannes Orphal
Atmos. Meas. Tech., 9, 2303–2313, https://doi.org/10.5194/amt-9-2303-2016, https://doi.org/10.5194/amt-9-2303-2016, 2016
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We describe an extension of a portable FTIR (Fourier transform infrafed) spectrometer dedicated to the measurement of column-averaged abundances of greenhouse gases in the atmosphere. The measurement principle is based on a spectrally resolved solar absorption observation (trace gas amounts are deduced from the strength of near-infrared absorption bands). The dual-channel set-up presented here allows co-observing CO while maintaining the highly favourable characteristics of the original device.
Matthäus Kiel, Frank Hase, Thomas Blumenstock, and Oliver Kirner
Atmos. Meas. Tech., 9, 2223–2239, https://doi.org/10.5194/amt-9-2223-2016, https://doi.org/10.5194/amt-9-2223-2016, 2016
Susan Kulawik, Debra Wunch, Christopher O'Dell, Christian Frankenberg, Maximilian Reuter, Tomohiro Oda, Frederic Chevallier, Vanessa Sherlock, Michael Buchwitz, Greg Osterman, Charles E. Miller, Paul O. Wennberg, David Griffith, Isamu Morino, Manvendra K. Dubey, Nicholas M. Deutscher, Justus Notholt, Frank Hase, Thorsten Warneke, Ralf Sussmann, John Robinson, Kimberly Strong, Matthias Schneider, Martine De Mazière, Kei Shiomi, Dietrich G. Feist, Laura T. Iraci, and Joyce Wolf
Atmos. Meas. Tech., 9, 683–709, https://doi.org/10.5194/amt-9-683-2016, https://doi.org/10.5194/amt-9-683-2016, 2016
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To accurately estimate source and sink locations of carbon dioxide, systematic errors in satellite measurements and models must be characterized. This paper examines two satellite data sets (GOSAT, launched 2009, and SCIAMACHY, launched 2002), and two models (CarbonTracker and MACC) vs. the TCCON CO2 validation data set. We assess biases and errors by season and latitude, satellite performance under averaging, and diurnal variability. Our findings are useful for assimilation of satellite data.
M. Kiel, D. Wunch, P. O. Wennberg, G. C. Toon, F. Hase, and T. Blumenstock
Atmos. Meas. Tech., 9, 669–682, https://doi.org/10.5194/amt-9-669-2016, https://doi.org/10.5194/amt-9-669-2016, 2016
Sébastien Massart, Anna Agustí-Panareda, Jens Heymann, Michael Buchwitz, Frédéric Chevallier, Maximilian Reuter, Michael Hilker, John P. Burrows, Nicholas M. Deutscher, Dietrich G. Feist, Frank Hase, Ralf Sussmann, Filip Desmet, Manvendra K. Dubey, David W. T. Griffith, Rigel Kivi, Christof Petri, Matthias Schneider, and Voltaire A. Velazco
Atmos. Chem. Phys., 16, 1653–1671, https://doi.org/10.5194/acp-16-1653-2016, https://doi.org/10.5194/acp-16-1653-2016, 2016
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This study presents the European Centre for Medium-Range Weather Forecasts (ECMWF) monitoring of atmospheric CO2 using measurements from the Greenhouse gases Observing Satellite (GOSAT). We show that the modelled CO2 has a better precision than standard CO2 satellite products compared to ground-based measurements. We also present the CO2 forecast based on our best knowledge of the atmospheric CO2 distribution. We show that it has skill to forecast the largest scale CO2 patterns up to day 5.
F. Klappenbach, M. Bertleff, J. Kostinek, F. Hase, T. Blumenstock, A. Agusti-Panareda, M. Razinger, and A. Butz
Atmos. Meas. Tech., 8, 5023–5038, https://doi.org/10.5194/amt-8-5023-2015, https://doi.org/10.5194/amt-8-5023-2015, 2015
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Measurements of atmospheric carbon dioxide and methane total vertical column abundance from onboard the research vessel "RV Polarstern" in March / April 2014. Along the journey on the Atlantic from Cape Town (South Africa) to Bremerhaven (Germany) we could reproduce the interhemispheric gradient of the target gases, and we compared the measurements with satellite and model data. Future campaigns could use the new mobility to characterize sources and sinks of carbon-dioxide and methane.
H. Lindqvist, C. W. O'Dell, S. Basu, H. Boesch, F. Chevallier, N. Deutscher, L. Feng, B. Fisher, F. Hase, M. Inoue, R. Kivi, I. Morino, P. I. Palmer, R. Parker, M. Schneider, R. Sussmann, and Y. Yoshida
Atmos. Chem. Phys., 15, 13023–13040, https://doi.org/10.5194/acp-15-13023-2015, https://doi.org/10.5194/acp-15-13023-2015, 2015
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Atmospheric carbon dioxide concentration varies seasonally mainly due to plant photosynthesis in the Northern Hemisphere. We found that the satellite GOSAT can capture this variability from space to within 1ppm. We also found that models can differ by more than 1ppm. This implies that the satellite measurements could be useful in evaluating models and their prior estimates of carbon dioxide sources and sinks.
R. J. Parker, H. Boesch, K. Byckling, A. J. Webb, P. I. Palmer, L. Feng, P. Bergamaschi, F. Chevallier, J. Notholt, N. Deutscher, T. Warneke, F. Hase, R. Sussmann, S. Kawakami, R. Kivi, D. W. T. Griffith, and V. Velazco
Atmos. Meas. Tech., 8, 4785–4801, https://doi.org/10.5194/amt-8-4785-2015, https://doi.org/10.5194/amt-8-4785-2015, 2015
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Atmospheric CH4 is an important greenhouse gas. Long-term global observations are necessary to understand its behaviour, with satellite observations playing a key role. The "proxy" retrieval method is one of the most successful but relies on the contribution from atmospheric CO2 models. This work assesses the significance of the uncertainty from the model CO2 within the retrieval and determines that despite this uncertainty the data are still valuable for determining sources and sinks of CH4.
V. Duflot, C. Wespes, L. Clarisse, D. Hurtmans, Y. Ngadi, N. Jones, C. Paton-Walsh, J. Hadji-Lazaro, C. Vigouroux, M. De Mazière, J.-M. Metzger, E. Mahieu, C. Servais, F. Hase, M. Schneider, C. Clerbaux, and P.-F. Coheur
Atmos. Chem. Phys., 15, 10509–10527, https://doi.org/10.5194/acp-15-10509-2015, https://doi.org/10.5194/acp-15-10509-2015, 2015
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We present global distributions of acetylene (C2H2) and hydrogen cyanide (HCN) total
columns derived from the Infrared Atmospheric Sounding Interferometer (IASI). C2H2 and HCN are ubiquitous atmospheric trace gases with medium tropospheric lifetime, which are frequently used as indicators of combustion sources and as tracers for atmospheric transport and chemistry. We show that there is an overall agreement between ground-based and space measurements, as well as model simulations.
R. Checa-Garcia, J. Landgraf, A. Galli, F. Hase, V. A. Velazco, H. Tran, V. Boudon, F. Alkemade, and A. Butz
Atmos. Meas. Tech., 8, 3617–3629, https://doi.org/10.5194/amt-8-3617-2015, https://doi.org/10.5194/amt-8-3617-2015, 2015
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The future satellite missions Sentinel-5 and its precursor will monitor methane column average dry air mole fractions. The ambitious accuracy required on regional scales demands a characterization of the systematic error sources in which spectroscopic uncertainties are crucial. This study investigates how methane and water vapour spectroscopic errors propagate into retrieval errors, showing that spectroscopy-induced errors exceed 0.6% in large parts of the
world and are regionally correlated.
G. Mengistu Tsidu, T. Blumenstock, and F. Hase
Atmos. Meas. Tech., 8, 3277–3295, https://doi.org/10.5194/amt-8-3277-2015, https://doi.org/10.5194/amt-8-3277-2015, 2015
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Intercomparison of precipitable water vapour from ERA-Interim, Fourier transform infrared spectrometer, GPS and radiosonde over complex topography of Ethiopia was made for the first time over a data-void region of eastern Africa. The study reveals weakness of ERA-Interim reanalysis in capturing diurnal and to some extent seasonal variabilities. The weakness can be improved through additional data assimilation, adaptation of convection and land surface modules to the reality in the region.
F. Hase, M. Frey, T. Blumenstock, J. Groß, M. Kiel, R. Kohlhepp, G. Mengistu Tsidu, K. Schäfer, M. K. Sha, and J. Orphal
Atmos. Meas. Tech., 8, 3059–3068, https://doi.org/10.5194/amt-8-3059-2015, https://doi.org/10.5194/amt-8-3059-2015, 2015
M. Frey, F. Hase, T. Blumenstock, J. Groß, M. Kiel, G. Mengistu Tsidu, K. Schäfer, M. K. Sha, and J. Orphal
Atmos. Meas. Tech., 8, 3047–3057, https://doi.org/10.5194/amt-8-3047-2015, https://doi.org/10.5194/amt-8-3047-2015, 2015
A. Ostler, R. Sussmann, P. K. Patra, P. O. Wennberg, N. M. Deutscher, D. W. T. Griffith, T. Blumenstock, F. Hase, R. Kivi, T. Warneke, Z. Wang, M. De Mazière, J. Robinson, and H. Ohyama
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-20395-2015, https://doi.org/10.5194/acpd-15-20395-2015, 2015
Preprint withdrawn
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We find that stratospheric model-transport errors are common for chemical transport models that are used for inverse estimates of CH4 emissions. These model-transport errors cause latitudinal as well as seasonal biases in simulated stratospheric and, hence, column-averaged CH4 mixing ratios (XCH4). Such a model bias corresponds to an overestimation of arctic and mid-latitude CH4 emissions if inversion studies do not apply an ad hoc bias correction before inverting fluxes from XCH4 observations.
J. Heymann, M. Reuter, M. Hilker, M. Buchwitz, O. Schneising, H. Bovensmann, J. P. Burrows, A. Kuze, H. Suto, N. M. Deutscher, M. K. Dubey, D. W. T. Griffith, F. Hase, S. Kawakami, R. Kivi, I. Morino, C. Petri, C. Roehl, M. Schneider, V. Sherlock, R. Sussmann, V. A. Velazco, T. Warneke, and D. Wunch
Atmos. Meas. Tech., 8, 2961–2980, https://doi.org/10.5194/amt-8-2961-2015, https://doi.org/10.5194/amt-8-2961-2015, 2015
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Long-term data sets of global atmospheric carbon dioxide concentrations based on observations from different satellite instruments may suffer from inconsistencies originating from the use of different retrieval algorithms. This issue has been addressed by applying the Bremen Optimal Estimation DOAS retrieval algorithm to SCIAMACHY and TANSO-FTS observations. Detailed comparisons with TCCON and CarbonTracker show good consistency between the SCIAMACHY and TANSO-FTS data sets.
A. J. Turner, D. J. Jacob, K. J. Wecht, J. D. Maasakkers, E. Lundgren, A. E. Andrews, S. C. Biraud, H. Boesch, K. W. Bowman, N. M. Deutscher, M. K. Dubey, D. W. T. Griffith, F. Hase, A. Kuze, J. Notholt, H. Ohyama, R. Parker, V. H. Payne, R. Sussmann, C. Sweeney, V. A. Velazco, T. Warneke, P. O. Wennberg, and D. Wunch
Atmos. Chem. Phys., 15, 7049–7069, https://doi.org/10.5194/acp-15-7049-2015, https://doi.org/10.5194/acp-15-7049-2015, 2015
R. A. Scheepmaker, C. Frankenberg, N. M. Deutscher, M. Schneider, S. Barthlott, T. Blumenstock, O. E. Garcia, F. Hase, N. Jones, E. Mahieu, J. Notholt, V. Velazco, J. Landgraf, and I. Aben
Atmos. Meas. Tech., 8, 1799–1818, https://doi.org/10.5194/amt-8-1799-2015, https://doi.org/10.5194/amt-8-1799-2015, 2015
C. Piesch, C. Sartorius, F. Friedl-Vallon, T. Gulde, S. Heger, E. Kretschmer, G. Maucher, H. Nordmeyer, J. Barthel, A. Ebersoldt, F. Graf, F. Hase, A. Kleinert, T. Neubert, and H. J. Schillings
Atmos. Meas. Tech., 8, 1773–1787, https://doi.org/10.5194/amt-8-1773-2015, https://doi.org/10.5194/amt-8-1773-2015, 2015
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The paper shows the design and the technics of the GLORIA spectrometer, the dedicated cooling system, and the performance during operation on HALO aircraft.
S. Barthlott, M. Schneider, F. Hase, A. Wiegele, E. Christner, Y. González, T. Blumenstock, S. Dohe, O. E. García, E. Sepúlveda, K. Strong, J. Mendonca, D. Weaver, M. Palm, N. M. Deutscher, T. Warneke, J. Notholt, B. Lejeune, E. Mahieu, N. Jones, D. W. T. Griffith, V. A. Velazco, D. Smale, J. Robinson, R. Kivi, P. Heikkinen, and U. Raffalski
Atmos. Meas. Tech., 8, 1555–1573, https://doi.org/10.5194/amt-8-1555-2015, https://doi.org/10.5194/amt-8-1555-2015, 2015
J.-L. Lacour, L. Clarisse, J. Worden, M. Schneider, S. Barthlott, F. Hase, C. Risi, C. Clerbaux, D. Hurtmans, and P.-F. Coheur
Atmos. Meas. Tech., 8, 1447–1466, https://doi.org/10.5194/amt-8-1447-2015, https://doi.org/10.5194/amt-8-1447-2015, 2015
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This paper describes a cross-validation study of tropospheric δD (HDO/H2O ratio) profiles retrieved from IASI spectra (retrieval performed at ULB). We document how these profiles compare to profiles derived from TES/AURA sounder and from three ground-based FTIRs of the NDACC network (produced within the MUSICA project). We show that empirical differences are in agreement with the theoretical expected differences which are dominated by IASI observational and the smoothing error components.
C. Vigouroux, T. Blumenstock, M. Coffey, Q. Errera, O. García, N. B. Jones, J. W. Hannigan, F. Hase, B. Liley, E. Mahieu, J. Mellqvist, J. Notholt, M. Palm, G. Persson, M. Schneider, C. Servais, D. Smale, L. Thölix, and M. De Mazière
Atmos. Chem. Phys., 15, 2915–2933, https://doi.org/10.5194/acp-15-2915-2015, https://doi.org/10.5194/acp-15-2915-2015, 2015
M. Schneider, Y. González, C. Dyroff, E. Christner, A. Wiegele, S. Barthlott, O. E. García, E. Sepúlveda, F. Hase, J. Andrey, T. Blumenstock, C. Guirado, R. Ramos, and S. Rodríguez
Atmos. Meas. Tech., 8, 483–503, https://doi.org/10.5194/amt-8-483-2015, https://doi.org/10.5194/amt-8-483-2015, 2015
M. Reuter, M. Buchwitz, M. Hilker, J. Heymann, O. Schneising, D. Pillai, H. Bovensmann, J. P. Burrows, H. Bösch, R. Parker, A. Butz, O. Hasekamp, C. W. O'Dell, Y. Yoshida, C. Gerbig, T. Nehrkorn, N. M. Deutscher, T. Warneke, J. Notholt, F. Hase, R. Kivi, R. Sussmann, T. Machida, H. Matsueda, and Y. Sawa
Atmos. Chem. Phys., 14, 13739–13753, https://doi.org/10.5194/acp-14-13739-2014, https://doi.org/10.5194/acp-14-13739-2014, 2014
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Current knowledge about the European terrestrial biospheric carbon sink relies upon bottom-up and global surface flux inverse model estimates using in situ measurements. Our analysis of five satellite data sets comprises a regional inversion designed to be insensitive to potential retrieval biases and transport errors. We show that the satellite-derived sink is larger (1.0±0.3GtC/a) than previous estimates (0.4±0.4GtC/a).
A. Ostler, R. Sussmann, M. Rettinger, N. M. Deutscher, S. Dohe, F. Hase, N. Jones, M. Palm, and B.-M. Sinnhuber
Atmos. Meas. Tech., 7, 4081–4101, https://doi.org/10.5194/amt-7-4081-2014, https://doi.org/10.5194/amt-7-4081-2014, 2014
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Ground-based FTIR soundings of column-average methane from NDACC and TCCON can be combined without the need to apply an overall calibration factor. NDACC and TCCON measurements complement one another and provide valuable information for satellite validation, evaluation of chemical-transport models, and source-sink inversions. The impact of dynamical variability on NDACC and TCCON retrievals of column-average methane is reflected in different smoothing effects.
H. Diémoz, A. M. Siani, A. Redondas, V. Savastiouk, C. T. McElroy, M. Navarro-Comas, and F. Hase
Atmos. Meas. Tech., 7, 4009–4022, https://doi.org/10.5194/amt-7-4009-2014, https://doi.org/10.5194/amt-7-4009-2014, 2014
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- A new algorithm to retrieve nitrogen dioxide by Brewer spectrophotometers was developed.
- Direct sun and zenith sky data recorded at the Izaña observatory were processed with the new algorithm and compared to co-located reference instruments.
- The measurement uncertainty was thoroughly determined by using a Monte Carlo technique.
- The new algorithm can be applied to more than 60 Brewers around the world.
F. Friedl-Vallon, T. Gulde, F. Hase, A. Kleinert, T. Kulessa, G. Maucher, T. Neubert, F. Olschewski, C. Piesch, P. Preusse, H. Rongen, C. Sartorius, H. Schneider, A. Schönfeld, V. Tan, N. Bayer, J. Blank, R. Dapp, A. Ebersoldt, H. Fischer, F. Graf, T. Guggenmoser, M. Höpfner, M. Kaufmann, E. Kretschmer, T. Latzko, H. Nordmeyer, H. Oelhaf, J. Orphal, M. Riese, G. Schardt, J. Schillings, M. K. Sha, O. Suminska-Ebersoldt, and J. Ungermann
Atmos. Meas. Tech., 7, 3565–3577, https://doi.org/10.5194/amt-7-3565-2014, https://doi.org/10.5194/amt-7-3565-2014, 2014
O. E. García, M. Schneider, F. Hase, T. Blumenstock, E. Sepúlveda, and Y. González
Atmos. Meas. Tech., 7, 3071–3084, https://doi.org/10.5194/amt-7-3071-2014, https://doi.org/10.5194/amt-7-3071-2014, 2014
A. Wiegele, M. Schneider, F. Hase, S. Barthlott, O. E. García, E. Sepúlveda, Y. González, T. Blumenstock, U. Raffalski, M. Gisi, and R. Kohlhepp
Atmos. Meas. Tech., 7, 2719–2732, https://doi.org/10.5194/amt-7-2719-2014, https://doi.org/10.5194/amt-7-2719-2014, 2014
E. Sepúlveda, M. Schneider, F. Hase, S. Barthlott, D. Dubravica, O. E. García, A. Gomez-Pelaez, Y. González, J. C. Guerra, M. Gisi, R. Kohlhepp, S. Dohe, T. Blumenstock, K. Strong, D. Weaver, M. Palm, A. Sadeghi, N. M. Deutscher, T. Warneke, J. Notholt, N. Jones, D. W. T. Griffith, D. Smale, G. W. Brailsford, J. Robinson, F. Meinhardt, M. Steinbacher, T. Aalto, and D. Worthy
Atmos. Meas. Tech., 7, 2337–2360, https://doi.org/10.5194/amt-7-2337-2014, https://doi.org/10.5194/amt-7-2337-2014, 2014
B. Dils, M. Buchwitz, M. Reuter, O. Schneising, H. Boesch, R. Parker, S. Guerlet, I. Aben, T. Blumenstock, J. P. Burrows, A. Butz, N. M. Deutscher, C. Frankenberg, F. Hase, O. P. Hasekamp, J. Heymann, M. De Mazière, J. Notholt, R. Sussmann, T. Warneke, D. Griffith, V. Sherlock, and D. Wunch
Atmos. Meas. Tech., 7, 1723–1744, https://doi.org/10.5194/amt-7-1723-2014, https://doi.org/10.5194/amt-7-1723-2014, 2014
F. Deng, D. B. A. Jones, D. K. Henze, N. Bousserez, K. W. Bowman, J. B. Fisher, R. Nassar, C. O'Dell, D. Wunch, P. O. Wennberg, E. A. Kort, S. C. Wofsy, T. Blumenstock, N. M. Deutscher, D. W. T. Griffith, F. Hase, P. Heikkinen, V. Sherlock, K. Strong, R. Sussmann, and T. Warneke
Atmos. Chem. Phys., 14, 3703–3727, https://doi.org/10.5194/acp-14-3703-2014, https://doi.org/10.5194/acp-14-3703-2014, 2014
F. Hase, B. J. Drouin, C. M. Roehl, G. C. Toon, P. O. Wennberg, D. Wunch, T. Blumenstock, F. Desmet, D. G. Feist, P. Heikkinen, M. De Mazière, M. Rettinger, J. Robinson, M. Schneider, V. Sherlock, R. Sussmann, Y. Té, T. Warneke, and C. Weinzierl
Atmos. Meas. Tech., 6, 3527–3537, https://doi.org/10.5194/amt-6-3527-2013, https://doi.org/10.5194/amt-6-3527-2013, 2013
S. Dohe, V. Sherlock, F. Hase, M. Gisi, J. Robinson, E. Sepúlveda, M. Schneider, and T. Blumenstock
Atmos. Meas. Tech., 6, 1981–1992, https://doi.org/10.5194/amt-6-1981-2013, https://doi.org/10.5194/amt-6-1981-2013, 2013
S. Takele Kenea, G. Mengistu Tsidu, T. Blumenstock, F. Hase, T. von Clarmann, and G. P. Stiller
Atmos. Meas. Tech., 6, 495–509, https://doi.org/10.5194/amt-6-495-2013, https://doi.org/10.5194/amt-6-495-2013, 2013
A. Krueger, W. Stremme, R. Harig, and M. Grutter
Atmos. Meas. Tech., 6, 47–61, https://doi.org/10.5194/amt-6-47-2013, https://doi.org/10.5194/amt-6-47-2013, 2013
M. Schneider, S. Barthlott, F. Hase, Y. González, K. Yoshimura, O. E. García, E. Sepúlveda, A. Gomez-Pelaez, M. Gisi, R. Kohlhepp, S. Dohe, T. Blumenstock, A. Wiegele, E. Christner, K. Strong, D. Weaver, M. Palm, N. M. Deutscher, T. Warneke, J. Notholt, B. Lejeune, P. Demoulin, N. Jones, D. W. T. Griffith, D. Smale, and J. Robinson
Atmos. Meas. Tech., 5, 3007–3027, https://doi.org/10.5194/amt-5-3007-2012, https://doi.org/10.5194/amt-5-3007-2012, 2012
Related subject area
Subject: Gases | Technique: Remote Sensing | Topic: Validation and Intercomparisons
Assessment of laboratory O4 (O2–O2 collision-induced) absorption cross-sections at 360 nm using atmospheric long-path DOAS observations
Intercomparison of tropospheric ozone column datasets from combined nadir and limb satellite observations
Long-term evolution of the calibration constant on a mobile water vapour Raman lidar
Advancing CH4 and N2O retrieval strategies for NDACC/IRWG FTIR observations with the support of airborne in situ measurements
Atmospheric horizontal gradients measured with eight co-located GNSS stations and a microwave radiometer
Greenhouse gas measurement campaign of the Earth Summit Mission-2022: ground-based in situ and FTIR observations and contribute to satellite validation in the Qomolangma region
Joint observations of oxygen atmospheric band emissions using OSIRIS and the MATS satellite
Validation of the version 4.5 MAESTRO ozone and NO2 measurements
Performance assessment of the IASI-O3 KOPRA product for observing midlatitude tropospheric ozone evolution for 15 years: validation with ozone sondes and consistency of the three IASI instruments
Benchmarking data-driven inversion methods for the estimation of local CO2 emissions from synthetic satellite images of XCO2 and NO2
Validation of 12 years (2008–2019) of IASI-A CO with IAGOS aircraft observations
Diurnal variations of NO2 tropospheric vertical column density over the Seoul metropolitan area from the Geostationary Environment Monitoring Spectrometer (GEMS): seasonal differences and the influence of the a priori NO2 profile
Validation of ACE-FTS version 5.2 ozone data with ozonesonde measurements
Intercomparison of long-term ground-based measurements of total, tropospheric, and stratospheric ozone at Lauder, New Zealand
First evaluation of the GEMS glyoxal products against TROPOMI and ground-based measurements
Validation of GEMS tropospheric NO2 columns and their diurnal variation with ground-based DOAS measurements
Validation and assessment of satellite-based columnar CO2 and CH4 mixing-ratios from GOSAT and OCO-2 satellites over India
Using open-path dual-comb spectroscopy to monitor methane emissions from simulated grazing cattle
Greenhouse gas column observations from a portable spectrometer in Uganda
Independent validation of IASI/MetOp-A LMD and RAL CH4 products using CAMS model, in situ profiles, and ground-based FTIR measurements
Joint spectral retrievals of ozone with Suomi NPP CrIS augmented by S5P/TROPOMI
An evaluation of atmospheric absorption models at millimetre and sub-millimetre wavelengths using airborne observations
Applicability of the inverse dispersion method to measure emissions from animal housings
5 years of Sentinel-5P TROPOMI operational ozone profiling and geophysical validation using ozonesonde and lidar ground-based networks
Using a portable FTIR spectrometer to evaluate the consistency of Total Carbon Column Observing Network (TCCON) measurements on a global scale: the Collaborative Carbon Column Observing Network (COCCON) travel standard
Comparison of the H2O, HDO and δD stratospheric climatologies between the MIPAS-ESA V8, MIPAS-IMK V5 and ACE-FTS V4.1/4.2 satellite datasets
TROPESS-CrIS CO single-pixel vertical profiles: intercomparisons with MOPITT and model simulations for 2020 western US wildfires
Seasonal Variation of Total Column Formaldehyde, Nitrogen Dioxide, and Ozone Over Various Pandora Spectrometer Sites with a Comparison of OMI and Diurnally Varying DSCOVR-EPIC Satellite Data
TOLNet validation of satellite ozone profiles in the troposphere: impact of retrieval wavelengths
An uncertainty methodology for solar occultation flux measurements: ammonia emissions from livestock production
Validation of Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) chlorodifluoromethane (HCFC-22) in the upper troposphere and lower stratosphere
First validation of high-resolution satellite-derived methane emissions from an active gas leak in the UK
Ship- and aircraft-based XCH4 over oceans as a new tool for satellite validation
Single-blind test of nine methane-sensing satellite systems from three continents
Water vapor measurements inside clouds and storms using a differential absorption radar
Evaluation of the first year of Pandora NO2 measurements over Beijing and application to satellite validation
Validation of MUSES NH3 observations from AIRS and CrIS against aircraft measurements from DISCOVER-AQ and a surface network in the Magic Valley
Performance and sensitivity of column-wise and pixel-wise methane retrievals for imaging spectrometers
Methane point source quantification using MethaneAIR: a new airborne imaging spectrometer
Evaluation of total ozone measurements from Geostationary Environmental Monitoring Spectrometer (GEMS)
To new heights by flying low: comparison of aircraft vertical NO2 profiles to model simulations and implications for TROPOMI NO2 retrievals
Local comparisons of tropospheric ozone: vertical soundings at two neighbouring stations in southern Bavaria
Ground-based Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) observations of NO2 and H2CO at Kinshasa and comparisons with TROPOMI observations
Total column ozone trends from the NASA Merged Ozone time series 1979 to 2021 showing latitude-dependent ozone recovery dates (1994 to 1998)
The SPARC water vapour assessment II: biases and drifts of water vapour satellite data records with respect to frost point hygrometer records
Vicarious calibration of the Tropospheric Monitoring Instrument (TROPOMI) short-wave infrared (SWIR) module over the Railroad Valley Playa
First-time comparison between NO2 vertical columns from Geostationary Environmental Monitoring Spectrometer (GEMS) and Pandora measurements
A blended TROPOMI+GOSAT satellite data product for atmospheric methane using machine learning to correct retrieval biases
Evaluating the consistency between OCO-2 and OCO-3 XCO2 estimates derived from the NASA ACOS version 10 retrieval algorithm
OLCI-A/B tandem phase: evaluation of FLuorescence EXplorer (FLEX)-like radiances and estimation of systematic differences between OLCI-A and OLCI-FLEX
Bianca Lauster, Udo Frieß, Jan-Marcus Nasse, Ulrich Platt, and Thomas Wagner
Atmos. Meas. Tech., 18, 3393–3405, https://doi.org/10.5194/amt-18-3393-2025, https://doi.org/10.5194/amt-18-3393-2025, 2025
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Remote sensing measurements of scattered sunlight use the atmospheric absorption of O2–O2 (or O4) to derive cloud and aerosol properties. However, inconsistencies between measurements and radiative transfer simulations were found recently, and, so far, there has been no consensus on how to deal with these appropriately. In this study, long-term long-path differential optical absorption spectroscopy (LP-DOAS) observations were analysed and very good agreement with laboratory measurements was found.
Carlo Arosio, Viktoria Sofieva, Andrea Orfanoz-Cheuquelaf, Alexei Rozanov, Klaus-Peter Heue, Diego Loyola, Edward Malina, Ryan M. Stauffer, David Tarasick, Roeland Van Malderen, Jerry R. Ziemke, and Mark Weber
Atmos. Meas. Tech., 18, 3247–3265, https://doi.org/10.5194/amt-18-3247-2025, https://doi.org/10.5194/amt-18-3247-2025, 2025
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Tropospheric ozone affects air quality and climate, being a pollutant and a greenhouse gas. We analyze satellite data of tropospheric ozone columns obtained by combining two types of observations: one providing stratospheric and the other total ozone. We compare common climatological features and study the influence of the tropopause (troposphere to stratosphere boundary) on the results. We also examine trends over the last 20 years and compare satellite data with ozonesondes to identify drifts.
Patrick Chazette, Julien Totems, and Frédéric Laly
Atmos. Meas. Tech., 18, 2681–2699, https://doi.org/10.5194/amt-18-2681-2025, https://doi.org/10.5194/amt-18-2681-2025, 2025
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The use of active remote sensing instruments to sample the atmospheric environment requires accurate calibration that is stable over time so that measurements are reproducible. This is the case for measurements of atmospheric water vapour using Raman lidar, which are of growing interest in the context of climate risks such as extreme precipitation. This study addresses this issue. It is based on six campaigns spread over a period of 7 years between 2016 and 2022.
Ivan Ortega, James W. Hannigan, Bianca C. Baier, Kathryn McKain, and Dan Smale
Atmos. Meas. Tech., 18, 2353–2371, https://doi.org/10.5194/amt-18-2353-2025, https://doi.org/10.5194/amt-18-2353-2025, 2025
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This study evaluates retrieval strategies for CH4 and N2O using high-resolution FTIR observations from Boulder, Colorado. By comparing results with independent AirCore and aircraft in situ measurements, the analysis validates retrieval accuracy and quantifies uncertainties. The findings highlight the benefits of updated spectroscopy and improved a priori profiles and highlight consistent agreement with in situ data.
Tong Ning and Gunnar Elgered
Atmos. Meas. Tech., 18, 2069–2082, https://doi.org/10.5194/amt-18-2069-2025, https://doi.org/10.5194/amt-18-2069-2025, 2025
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We analyzed signal delays in the atmosphere, using eight co-located global navigation satellite system (GNSS) stations, and compared linear horizontal gradients with microwave radiometer data. A weak constraint applied when estimating gradients in the GNSS data processing, enhancing short-lived gradient tracking but increasing noise, which can be mitigated by averaging gradients from the eight stations. This approach may enhance GNSS-based atmospheric monitoring for use in weather nowcasting.
Minqiang Zhou, Yilong Wang, Minzheng Duan, Xiangjun Tian, Jinzhi Ding, Jianrong Bi, Yaoming Ma, Weiqiang Ma, and Zhenhua Xi
EGUsphere, https://doi.org/10.5194/egusphere-2025-1293, https://doi.org/10.5194/egusphere-2025-1293, 2025
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The Qinghai-Tibetan Plateau is a key system that impacts the global carbon balance. This study presents the greenhouse gas (GHG) mole fraction measurement campaign in May 2022 at Mt. Qomolangma station, including ground-based remote sensing and in situ measurements. The GHG measurements are carried out in this region for the first time and used for satellite validation.
Björn Linder, Jörg Gumbel, Donal P. Murtagh, Linda Megner, Lukas Krasauskas, Doug Degenstein, Ole Martin Christensen, and Nickolay Ivchenko
EGUsphere, https://doi.org/10.5194/egusphere-2025-493, https://doi.org/10.5194/egusphere-2025-493, 2025
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In this study, the primary instrument carried by the satellite MATS is compared to the OSIRIS instrument onboard the Odin satellite. A total of 36 close approaches between December 2022 and February 2023 were identified and analysed. The comparison reveals that the two instruments have good structural agreement and that MATS detects a signal that is ~20 % stronger than what is measured by OSIRIS.
Paul S. Jeffery, James R. Drummond, C. Thomas McElroy, Kaley A. Walker, and Jiansheng Zou
Atmos. Meas. Tech., 18, 569–602, https://doi.org/10.5194/amt-18-569-2025, https://doi.org/10.5194/amt-18-569-2025, 2025
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The MAESTRO instrument has been monitoring ozone and NO2 since February 2004. A new version of these data products has recently been released; however, these new products must be validated against other datasets to ensure their validity. This study presents such an assessment, using measurements from 11 satellite instruments to characterize the new MAESTRO products. In the stratosphere, good agreement is found for ozone and acceptable agreement is found for NO2 with these other datasets.
Gaëlle Dufour, Maxim Eremenko, Juan Cuesta, Gérard Ancellet, Michael Gill, Eliane Maillard Barras, and Roeland Van Malderen
EGUsphere, https://doi.org/10.5194/egusphere-2024-4096, https://doi.org/10.5194/egusphere-2024-4096, 2025
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The IASI-O3 KOPRA v3.0 product shows strong consistency (<1 %) for the three IASI instruments. The validation against homogenized ozone sondes reveals an overall good agreement with slight biases (3–6 %) in tropospheric ozone and a possible temporal drift but difficult to assess due to the limited number of sites. No specific trends are estimated for the tropospheric ozone column for 2008–2022, but persistent negative trends are observed in the lower troposphere.
Diego Santaren, Janne Hakkarainen, Gerrit Kuhlmann, Erik Koene, Frédéric Chevallier, Iolanda Ialongo, Hannakaisa Lindqvist, Janne Nurmela, Johanna Tamminen, Laia Amorós, Dominik Brunner, and Grégoire Broquet
Atmos. Meas. Tech., 18, 211–239, https://doi.org/10.5194/amt-18-211-2025, https://doi.org/10.5194/amt-18-211-2025, 2025
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This study evaluates data-driven inversion methods for estimating CO2 emissions from local sources, such as power plants and cities, using meteorological data and XCO2 and NO2 satellite images rather than atmospheric transport modeling. We assess and compare the performance of five different methods using simulations of 1 year of satellite images, taken from the upcoming Copernicus CO2 Monitoring Mission, covering 15 power plants and the city of Berlin, Germany.
Brice Barret, Pierre Loicq, Eric Le Flochmoën, Yasmine Bennouna, Juliette Hadji-Lazaro, Daniel Hurtmans, and Bastien Sauvage
Atmos. Meas. Tech., 18, 129–149, https://doi.org/10.5194/amt-18-129-2025, https://doi.org/10.5194/amt-18-129-2025, 2025
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Profiles of carbon monoxide (CO) retrieved from the Infrared Atmospheric Sounding Interferometer (IASI) with the SOftware for a Fast Retrieval of IASI Data (SOFRID) and Fast Optimal Retrievals on Layers for IASI (FORLI) are validated with 8500 observations at 33 airports from the In-service Aircraft for a Global Observing System (IAGOS) for 2008–2019. IASI retrievals underestimate CO, with stronger bias in the middle to upper troposphere for SOFRID and in the lower troposphere for FORLI.
Seunghwan Seo, Si-Wan Kim, Kyoung-Min Kim, Andreas Richter, Kezia Lange, John P. Burrows, Junsung Park, Hyunkee Hong, Hanlim Lee, Ukkyo Jeong, Jung-Hun Woo, and Jhoon Kim
Atmos. Meas. Tech., 18, 115–128, https://doi.org/10.5194/amt-18-115-2025, https://doi.org/10.5194/amt-18-115-2025, 2025
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Over the Seoul metropolitan area, tropospheric NO2 vertical column densities from the Geostationary Environment Monitoring Spectrometer show distinct seasonal features. Also, varying a priori data have substantial impacts on the observed NO2 columns. The a priori data from different chemical transport models resulted in differences of up to −18.3 %. Notably, diurnal patterns of observed NO2 columns are similar for all datasets, although their a priori data exhibit contrasting diurnal patterns.
Jiansheng Zou, Kaley A. Walker, Patrick E. Sheese, Chris D. Boone, Ryan M. Stauffer, Anne M. Thompson, and David W. Tarasick
Atmos. Meas. Tech., 17, 6983–7005, https://doi.org/10.5194/amt-17-6983-2024, https://doi.org/10.5194/amt-17-6983-2024, 2024
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Ozone measurements from the ACE-FTS satellite instrument have been compared to worldwide balloon-borne ozonesonde profiles using pairs of closely spaced profiles and monthly averaged profiles. ACE-FTS typically measures more ozone in the stratosphere by up to 10 %. The long-term stability of the ACE-FTS ozone data is good, exhibiting small (but non-significant) drifts of less than 3 % per decade in the stratosphere. Lower in the profiles, the calculated drifts are larger (up to 10 % per decade).
Robin Björklund, Corinne Vigouroux, Peter Effertz, Omaira E. García, Alex Geddes, James Hannigan, Koji Miyagawa, Michael Kotkamp, Bavo Langerock, Gerald Nedoluha, Ivan Ortega, Irina Petropavlovskikh, Deniz Poyraz, Richard Querel, John Robinson, Hisako Shiona, Dan Smale, Penny Smale, Roeland Van Malderen, and Martine De Mazière
Atmos. Meas. Tech., 17, 6819–6849, https://doi.org/10.5194/amt-17-6819-2024, https://doi.org/10.5194/amt-17-6819-2024, 2024
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Different ground-based ozone measurements from the last 2 decades at Lauder are compared to each other. We want to know why different trends have been observed in the stratosphere. Also, the quality and relevance of tropospheric datasets need to be evaluated. While remaining drifts are still present, our study explains roughly half of the differences in observed trends in previous studies and shows the necessity for continuous review and improvement of the measurements.
Eunjo S. Ha, Rokjin J. Park, Hyeong-Ahn Kwon, Gitaek T. Lee, Sieun D. Lee, Seunga Shin, Dong-Won Lee, Hyunkee Hong, Christophe Lerot, Isabelle De Smedt, Thomas Danckaert, Francois Hendrick, and Hitoshi Irie
Atmos. Meas. Tech., 17, 6369–6384, https://doi.org/10.5194/amt-17-6369-2024, https://doi.org/10.5194/amt-17-6369-2024, 2024
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In this study, we evaluated the GEMS glyoxal products by comparing them with TROPOMI and MAX-DOAS measurements. GEMS and TROPOMI VCDs present similar spatial distributions. Monthly variations in GEMS VCDs and TROPOMI and MAX-DOAS VCDs differ in northeastern Asia, which we attributed to a polluted reference spectrum and high NO2 concentrations. GEMS glyoxal products with unparalleled temporal resolution would enrich our understanding of VOC emissions and diurnal variation.
Kezia Lange, Andreas Richter, Tim Bösch, Bianca Zilker, Miriam Latsch, Lisa K. Behrens, Chisom M. Okafor, Hartmut Bösch, John P. Burrows, Alexis Merlaud, Gaia Pinardi, Caroline Fayt, Martina M. Friedrich, Ermioni Dimitropoulou, Michel Van Roozendael, Steffen Ziegler, Simona Ripperger-Lukosiunaite, Leon Kuhn, Bianca Lauster, Thomas Wagner, Hyunkee Hong, Donghee Kim, Lim-Seok Chang, Kangho Bae, Chang-Keun Song, Jong-Uk Park, and Hanlim Lee
Atmos. Meas. Tech., 17, 6315–6344, https://doi.org/10.5194/amt-17-6315-2024, https://doi.org/10.5194/amt-17-6315-2024, 2024
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Instruments for air quality observations on geostationary satellites provide multiple observations per day and allow for the analysis of the diurnal variation of important air pollutants such as nitrogen dioxide (NO2) over large areas. The South Korean instrument GEMS, launched in February 2020, is the first instrument in geostationary orbit and covers a large part of Asia. Our investigations show the observed diurnal evolution of NO2 at different measurement sites.
Harish Shivraj Gadhavi, Akanksha Arora, Chaithanya Jain, Mahesh Kumar Sha, Frank Hase, Matthias Frey, Srikanthan Ramachandran, and Achuthan Jayaraman
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-167, https://doi.org/10.5194/amt-2024-167, 2024
Revised manuscript accepted for AMT
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We used a ground-based Fourier Transform Spectrometer to measure columnar greenhouse gas mixing ratios and validate methane observations from the GOSAT satellite and carbon dioxide observations from GOSAT and OCO-2 over India. Both satellites provide high precision and accuracy, making them suitable for emission flux estimates. Simulations using a Lagrangian dispersion model showed that background mixing ratio variations play a larger role than local source changes.
Chinthaka Weerasekara, Lindsay C. Morris, Nathan A. Malarich, Fabrizio R. Giorgetta, Daniel I. Herman, Kevin C. Cossel, Nathan R. Newbury, Clenton E. Owensby, Stephen M. Welch, Cosmin Blaga, Brett D. DePaola, Ian Coddington, Brian R. Washburn, and Eduardo A. Santos
Atmos. Meas. Tech., 17, 6107–6117, https://doi.org/10.5194/amt-17-6107-2024, https://doi.org/10.5194/amt-17-6107-2024, 2024
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Most methane emissions during the life cycle of beef cattle occur during the grazing phase. Measuring methane in grazing systems is difficult due to the high mobility and low density of animals. This work investigates if dual-comb spectroscopy can measure methane emissions from small cattle herds. An enhancement of 10 nmol mol-1 methane above the atmospheric background was measured, equivalent to 20 head located 60 m away. The calculated methane flux was within 5 % of the actual release rate.
Neil Humpage, Hartmut Boesch, William Okello, Jia Chen, Florian Dietrich, Mark F. Lunt, Liang Feng, Paul I. Palmer, and Frank Hase
Atmos. Meas. Tech., 17, 5679–5707, https://doi.org/10.5194/amt-17-5679-2024, https://doi.org/10.5194/amt-17-5679-2024, 2024
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We used a Bruker EM27/SUN spectrometer within an automated weatherproof enclosure to measure greenhouse gas column concentrations over a 3-month period in Jinja, Uganda. The portability of the EM27/SUN allows us to evaluate satellite and model data in locations not covered by traditional validation networks. This is of particular value in tropical Africa, where extensive terrestrial ecosystems are a significant store of carbon and play a key role in the atmospheric budgets of CO2 and CH4.
Bart Dils, Minqiang Zhou, Claude Camy-Peyret, Martine De Mazière, Yannick Kangah, Bavo Langerock, Pascal Prunet, Carmine Serio, Richard Siddans, and Brian Kerridge
Atmos. Meas. Tech., 17, 5491–5524, https://doi.org/10.5194/amt-17-5491-2024, https://doi.org/10.5194/amt-17-5491-2024, 2024
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The paper discusses two very distinct methane products from the IASI instrument aboard the MetOp-A satellite. One (referred to as LMD NLISv8.3) uses a machine-learning approach, while the other (RALv2.0) uses a more conventional optimal estimation approach. We used a variety of model and independent reference measurement data to assess both products' overall quality, their differences, and specific aspects of each product that would benefit from further analysis by the product development teams.
Edward Malina, Kevin W. Bowman, Valentin Kantchev, Le Kuai, Thomas P. Kurosu, Kazuyuki Miyazaki, Vijay Natraj, Gregory B. Osterman, Fabiano Oyafuso, and Matthew D. Thill
Atmos. Meas. Tech., 17, 5341–5371, https://doi.org/10.5194/amt-17-5341-2024, https://doi.org/10.5194/amt-17-5341-2024, 2024
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Characterizing the distribution of ozone in the atmosphere is a challenging problem, with current Earth observation satellites using either thermal infrared (TIR) or ultraviolet (UV) instruments, sensitive to different portions of the atmosphere, making it difficult to gain a full picture. In this work, we combine measurements from the TIR and UV instruments Suomi NPP CrIS and Sentinel-5P/TROPOMI to improve sensitivity through the whole atmosphere and improve knowledge of ozone distribution.
Stuart Fox, Vinia Mattioli, Emma Turner, Alan Vance, Domenico Cimini, and Donatello Gallucci
Atmos. Meas. Tech., 17, 4957–4978, https://doi.org/10.5194/amt-17-4957-2024, https://doi.org/10.5194/amt-17-4957-2024, 2024
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Airborne observations are used to evaluate two models for absorption and emission by atmospheric gases, including water vapour and oxygen, at microwave and sub-millimetre wavelengths. These models are needed for the Ice Cloud Imager (ICI) on the next generation of European polar-orbiting weather satellites, which measures at frequencies up to 664 GHz. Both models can provide a good match to measurements from airborne radiometers and are sufficiently accurate for use with ICI.
Marcel Bühler, Christoph Häni, Albrecht Neftel, Patrice Bühler, Christof Ammann, and Thomas Kupper
Atmos. Meas. Tech., 17, 4649–4658, https://doi.org/10.5194/amt-17-4649-2024, https://doi.org/10.5194/amt-17-4649-2024, 2024
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Methane was released from an artificial source inside a barn to test the applicability of the inverse dispersion method (IDM). Multiple open-path concentration devices and ultrasonic anemometers were used at the site. It is concluded that, for the present study case, the effect of a building and a tree in the main wind axis led to a systematic underestimation of the IDM-derived emission rate probably due to deviations in the wind field and turbulent dispersion from the ideal assumptions.
Arno Keppens, Serena Di Pede, Daan Hubert, Jean-Christopher Lambert, Pepijn Veefkind, Maarten Sneep, Johan De Haan, Mark ter Linden, Thierry Leblanc, Steven Compernolle, Tijl Verhoelst, José Granville, Oindrila Nath, Ann Mari Fjæraa, Ian Boyd, Sander Niemeijer, Roeland Van Malderen, Herman G. J. Smit, Valentin Duflot, Sophie Godin-Beekmann, Bryan J. Johnson, Wolfgang Steinbrecht, David W. Tarasick, Debra E. Kollonige, Ryan M. Stauffer, Anne M. Thompson, Angelika Dehn, and Claus Zehner
Atmos. Meas. Tech., 17, 3969–3993, https://doi.org/10.5194/amt-17-3969-2024, https://doi.org/10.5194/amt-17-3969-2024, 2024
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The Sentinel-5P satellite operated by the European Space Agency has carried the TROPOspheric Monitoring Instrument (TROPOMI) around the Earth since October 2017. This mission also produces atmospheric ozone profile data which are described in detail for May 2018 to April 2023. Independent validation using ground-based reference measurements demonstrates that the operational ozone profile product mostly fully and at least partially complies with all mission requirements.
Benedikt Herkommer, Carlos Alberti, Paolo Castracane, Jia Chen, Angelika Dehn, Florian Dietrich, Nicholas M. Deutscher, Matthias Max Frey, Jochen Groß, Lawson Gillespie, Frank Hase, Isamu Morino, Nasrin Mostafavi Pak, Brittany Walker, and Debra Wunch
Atmos. Meas. Tech., 17, 3467–3494, https://doi.org/10.5194/amt-17-3467-2024, https://doi.org/10.5194/amt-17-3467-2024, 2024
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The Total Carbon Column Observing Network is a network of ground-based Fourier transform infrared (FTIR) spectrometers used mainly for satellite validation. To ensure the highest-quality validation data, the network needs to be highly consistent. This is a major challenge, which so far is solved by site comparisons with airborne in situ measurements. In this work, we describe the use of a portable FTIR spectrometer as a travel standard for evaluating the consistency of TCCON sites.
Karen De Los Ríos, Paulina Ordoñez, Gabriele P. Stiller, Piera Raspollini, Marco Gai, Kaley A. Walker, Cristina Peña-Ortiz, and Luis Acosta
Atmos. Meas. Tech., 17, 3401–3418, https://doi.org/10.5194/amt-17-3401-2024, https://doi.org/10.5194/amt-17-3401-2024, 2024
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This study examines newer versions of H2O and HDO retrievals from Envisat/MIPAS and SCISAT/ACE-FTS. Results reveal a better agreement in stratospheric H2O profiles than in HDO profiles. The H2O tape recorder signal is consistent across databases, but δD tape recorder composites show differences that impact the interpretation of water vapour transport. These findings enhance the need for intercomparisons to refine our insights.
Ming Luo, Helen M. Worden, Robert D. Field, Kostas Tsigaridis, and Gregory S. Elsaesser
Atmos. Meas. Tech., 17, 2611–2624, https://doi.org/10.5194/amt-17-2611-2024, https://doi.org/10.5194/amt-17-2611-2024, 2024
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The TROPESS CrIS single-pixel CO profile retrievals are compared to the MOPITT CO products in steps of adjusting them to the common a priori assumptions. The two data sets are found to agree within 5 %. We also demonstrated and analyzed the proper steps in evaluating GISS ModelE CO simulations using satellite CO retrieval products for the western US wildfire events in September 2020.
Jay Herman and Jianping Mao
EGUsphere, https://doi.org/10.5194/egusphere-2024-1216, https://doi.org/10.5194/egusphere-2024-1216, 2024
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This paper examines the seasonal variation of column Formaldehyde HCHO, Nitrogen Dioxide NO2, and Ozone O3. Ground-based Pandora spectrometer observations show that HCHO has a strong seasonal behavior that is not seen by the satellite Ozone Monitoring Instrument OMI and that the amount of NO2 pollution is underestimated by the OMI satellite observations. Pandora O3 measurements have been successfully compared with hourly satellite measurements from the Earth Polychromatic Imaging Camera EPIC.
Matthew S. Johnson, Alexei Rozanov, Mark Weber, Nora Mettig, John Sullivan, Michael J. Newchurch, Shi Kuang, Thierry Leblanc, Fernando Chouza, Timothy A. Berkoff, Guillaume Gronoff, Kevin B. Strawbridge, Raul J. Alvarez, Andrew O. Langford, Christoph J. Senff, Guillaume Kirgis, Brandi McCarty, and Larry Twigg
Atmos. Meas. Tech., 17, 2559–2582, https://doi.org/10.5194/amt-17-2559-2024, https://doi.org/10.5194/amt-17-2559-2024, 2024
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Monitoring tropospheric ozone (O3), a harmful pollutant negatively impacting human health, is primarily done using ground-based measurements and ozonesondes. However, these observation types lack the coverage to fully understand tropospheric O3. Satellites can retrieve tropospheric ozone with near-daily global coverage; however, they are known to have biases and errors. This study uses ground-based lidars to validate multiple satellites' ability to observe tropospheric O3.
Johan Mellqvist, Nathalia T. Vechi, Charlotte Scheutz, Marc Durif, Francois Gautier, John Johansson, Jerker Samuelsson, Brian Offerle, and Samuel Brohede
Atmos. Meas. Tech., 17, 2465–2479, https://doi.org/10.5194/amt-17-2465-2024, https://doi.org/10.5194/amt-17-2465-2024, 2024
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The solar occultation flux method retrieves ammonia gas columns from the solar spectrum. Emissions are obtained by multiplying the integrated plume concentration by the wind speed profile. The methodology for uncertainty estimation was established considering an error budget with systematic and random components, resulting in an expanded uncertainty in the range of 20 % to 30 %. The method was validated in a controlled release, and its application was demonstrated in different farms.
Felicia Kolonjari, Patrick E. Sheese, Kaley A. Walker, Chris D. Boone, David A. Plummer, Andreas Engel, Stephen A. Montzka, David E. Oram, Tanja Schuck, Gabriele P. Stiller, and Geoffrey C. Toon
Atmos. Meas. Tech., 17, 2429–2449, https://doi.org/10.5194/amt-17-2429-2024, https://doi.org/10.5194/amt-17-2429-2024, 2024
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The Canadian Atmospheric Chemistry Experiment Fourier transform spectrometer (ACE-FTS) satellite instrument is currently providing the only vertically resolved chlorodifluoromethane (HCFC-22) measurements from space. This study assesses the most current ACE-FTS HCFC-22 data product in the upper troposphere and lower stratosphere, as well as modelled HCFC-22 from a 39-year run of the Canadian Middle Atmosphere Model (CMAM39) in the same region.
Emily Dowd, Alistair J. Manning, Bryn Orth-Lashley, Marianne Girard, James France, Rebecca E. Fisher, Dave Lowry, Mathias Lanoisellé, Joseph R. Pitt, Kieran M. Stanley, Simon O'Doherty, Dickon Young, Glen Thistlethwaite, Martyn P. Chipperfield, Emanuel Gloor, and Chris Wilson
Atmos. Meas. Tech., 17, 1599–1615, https://doi.org/10.5194/amt-17-1599-2024, https://doi.org/10.5194/amt-17-1599-2024, 2024
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We provide the first validation of the satellite-derived emission estimates using surface-based mobile greenhouse gas surveys of an active gas leak detected near Cheltenham, UK. GHGSat’s emission estimates broadly agree with the surface-based mobile survey and steps were taken to fix the leak, highlighting the importance of satellite data in identifying emissions and helping to reduce our human impact on climate change.
Astrid Müller, Hiroshi Tanimoto, Takafumi Sugita, Prabir K. Patra, Shin-ichiro Nakaoka, Toshinobu Machida, Isamu Morino, André Butz, and Kei Shiomi
Atmos. Meas. Tech., 17, 1297–1316, https://doi.org/10.5194/amt-17-1297-2024, https://doi.org/10.5194/amt-17-1297-2024, 2024
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Satellite CH4 observations with high accuracy are needed to understand changes in atmospheric CH4 concentrations. But over oceans, reference data are limited. We combine various ship and aircraft observations with the help of atmospheric chemistry models to derive observation-based column-averaged mixing ratios of CH4 (obs. XCH4). We discuss three different approaches and demonstrate the applicability of the new reference dataset for carbon cycle studies and satellite evaluation.
Evan D. Sherwin, Sahar H. El Abbadi, Philippine M. Burdeau, Zhan Zhang, Zhenlin Chen, Jeffrey S. Rutherford, Yuanlei Chen, and Adam R. Brandt
Atmos. Meas. Tech., 17, 765–782, https://doi.org/10.5194/amt-17-765-2024, https://doi.org/10.5194/amt-17-765-2024, 2024
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Countries and companies increasingly rely on a growing fleet of satellites to find large emissions of climate-warming methane, particularly from oil and natural gas systems across the globe. We independently assessed the performance of nine such systems by releasing controlled, undisclosed amounts of methane as satellites passed overhead. The tested systems produced reliable detection and quantification results, including the smallest-ever emission detected from space in such a test.
Luis F. Millán, Matthew D. Lebsock, Ken B. Cooper, Jose V. Siles, Robert Dengler, Raquel Rodriguez Monje, Amin Nehrir, Rory A. Barton-Grimley, James E. Collins, Claire E. Robinson, Kenneth L. Thornhill, and Holger Vömel
Atmos. Meas. Tech., 17, 539–559, https://doi.org/10.5194/amt-17-539-2024, https://doi.org/10.5194/amt-17-539-2024, 2024
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In this study, we describe and validate a new technique in which three radar tones are used to estimate the water vapor inside clouds and precipitation. This instrument flew on board NASA's P-3 aircraft during the Investigation of Microphysics and Precipitation for Atlantic Coast-Threatening Snowstorms (IMPACTS) campaign and the Synergies Of Active optical and Active microwave Remote Sensing Experiment (SOA2RSE) campaign.
Ouyang Liu, Zhengqiang Li, Yangyan Lin, Cheng Fan, Ying Zhang, Kaitao Li, Peng Zhang, Yuanyuan Wei, Tianzeng Chen, Jiantao Dong, and Gerrit de Leeuw
Atmos. Meas. Tech., 17, 377–395, https://doi.org/10.5194/amt-17-377-2024, https://doi.org/10.5194/amt-17-377-2024, 2024
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Nitrogen dioxide (NO2) is a trace gas which is important for atmospheric chemistry and may affect human health. To understand processes leading to harmful concentrations, it is important to monitor NO2 concentrations near the surface and higher up. To this end, a Pandora instrument has been installed in Beijing. An overview of the first year of data shows the large variability on diurnal to seasonal timescales and how this is affected by wind speed and direction and chemistry.
Karen E. Cady-Pereira, Xuehui Guo, Rui Wang, April B. Leytem, Chase Calkins, Elizabeth Berry, Kang Sun, Markus Müller, Armin Wisthaler, Vivienne H. Payne, Mark W. Shephard, Mark A. Zondlo, and Valentin Kantchev
Atmos. Meas. Tech., 17, 15–36, https://doi.org/10.5194/amt-17-15-2024, https://doi.org/10.5194/amt-17-15-2024, 2024
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Ammonia is a significant precursor of PM2.5 particles and thus contributes to poor air quality in many regions. Furthermore, ammonia concentrations are rising due to the increase of large-scale, intensive agricultural activities. Here we evaluate satellite measurements of ammonia against aircraft and surface network data, and show that there are differences in magnitude, but the satellite data are spatially and temporally well correlated with the in situ data.
Alana K. Ayasse, Daniel Cusworth, Kelly O'Neill, Justin Fisk, Andrew K. Thorpe, and Riley Duren
Atmos. Meas. Tech., 16, 6065–6074, https://doi.org/10.5194/amt-16-6065-2023, https://doi.org/10.5194/amt-16-6065-2023, 2023
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Methane is a powerful greenhouse gas, and a significant portion of methane comes from large individual plumes. Recently, airplane-mounted infrared technologies have proven very good at detecting and quantifying these plumes. In order to extract the methane signal from the infrared image, there are two widely used approaches. In this study, we assess the performance of both approaches using controlled-release experiments. We also examine the minimum detection limit of the infrared technology.
Apisada Chulakadabba, Maryann Sargent, Thomas Lauvaux, Joshua S. Benmergui, Jonathan E. Franklin, Christopher Chan Miller, Jonas S. Wilzewski, Sébastien Roche, Eamon Conway, Amir H. Souri, Kang Sun, Bingkun Luo, Jacob Hawthrone, Jenna Samra, Bruce C. Daube, Xiong Liu, Kelly Chance, Yang Li, Ritesh Gautam, Mark Omara, Jeff S. Rutherford, Evan D. Sherwin, Adam Brandt, and Steven C. Wofsy
Atmos. Meas. Tech., 16, 5771–5785, https://doi.org/10.5194/amt-16-5771-2023, https://doi.org/10.5194/amt-16-5771-2023, 2023
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We show that MethaneAIR, a precursor to the MethaneSAT satellite, demonstrates accurate point source quantification during controlled release experiments and regional observations in 2021 and 2022. Results from our two independent quantification methods suggest the accuracy of our sensor and algorithms is better than 25 % for sources emitting 200 kg h−1 or more. Insights from these measurements help establish the capabilities of MethaneSAT and MethaneAIR.
Kanghyun Baek, Jae Hwan Kim, Juseon Bak, David P. Haffner, Mina Kang, and Hyunkee Hong
Atmos. Meas. Tech., 16, 5461–5478, https://doi.org/10.5194/amt-16-5461-2023, https://doi.org/10.5194/amt-16-5461-2023, 2023
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The GEMS mission was the first mission of the geostationary satellite constellation for hourly atmospheric composition monitoring. The GEMS ozone measurements were cross-compared to those of Pandora, OMPS, and TROPOMI satellite sensors and excellent agreement was found. GEMS has proven to be a powerful new instrument for monitoring and assessing the diurnal variation in atmospheric ozone. This experience can be used to advance research with future geostationary environmental satellite missions.
Tobias Christoph Valentin Werner Riess, Klaas Folkert Boersma, Ward Van Roy, Jos de Laat, Enrico Dammers, and Jasper van Vliet
Atmos. Meas. Tech., 16, 5287–5304, https://doi.org/10.5194/amt-16-5287-2023, https://doi.org/10.5194/amt-16-5287-2023, 2023
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Satellite retrievals of trace gases require prior knowledge of the vertical distribution of the pollutant, which is usually obtained from models. Using aircraft-measured vertical NO2 profiles over the North Sea in summer 2021, we evaluate the Transport Model 5 profiles used in the TROPOMI NO2 retrieval. We conclude that driven by the low horizontal resolution and the overestimated vertical mixing, resulting NO2 columns are 20 % too low. This has important implications for emission estimates.
Thomas Trickl, Martin Adelwart, Dina Khordakova, Ludwig Ries, Christian Rolf, Michael Sprenger, Wolfgang Steinbrecht, and Hannes Vogelmann
Atmos. Meas. Tech., 16, 5145–5165, https://doi.org/10.5194/amt-16-5145-2023, https://doi.org/10.5194/amt-16-5145-2023, 2023
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Tropospheric ozone have been measured for more than a century. Highly quantitative ozone measurements have been made at monitoring stations. However, deficits have been reported for vertical sounding systems. Here, we report a thorough intercomparison effort between a differential-absorption lidar system and two types of balloon-borne ozone sondes, also using ozone sensors at nearby mountain sites as references. The sondes agree very well with the lidar after offset corrections.
Rodriguez Yombo Phaka, Alexis Merlaud, Gaia Pinardi, Martina M. Friedrich, Michel Van Roozendael, Jean-François Müller, Trissevgeni Stavrakou, Isabelle De Smedt, François Hendrick, Ermioni Dimitropoulou, Richard Bopili Mbotia Lepiba, Edmond Phuku Phuati, Buenimio Lomami Djibi, Lars Jacobs, Caroline Fayt, Jean-Pierre Mbungu Tsumbu, and Emmanuel Mahieu
Atmos. Meas. Tech., 16, 5029–5050, https://doi.org/10.5194/amt-16-5029-2023, https://doi.org/10.5194/amt-16-5029-2023, 2023
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We present air quality measurements in Kinshasa, Democratic Republic of the Congo, performed with a newly developed instrument which was installed on a roof of the University of Kinshasa in November 2019. The instrument records spectra of the scattered sunlight, from which we derive the abundances of nitrogen dioxide and formaldehyde, two important pollutants. We compare our ground-based measurements with those of the TROPOspheric Monitoring Instrument (TROPOMI).
Jay Herman, Jerald Ziemke, and Richard McPeters
Atmos. Meas. Tech., 16, 4693–4707, https://doi.org/10.5194/amt-16-4693-2023, https://doi.org/10.5194/amt-16-4693-2023, 2023
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Fourier series multivariate linear regression trends (% per decade) in ozone were estimated from the Merged Ozone Data Set (MOD) from 1979 to 2021 in two different regimes, from 1979 to TA (the date when ozone stopped decreasing) and TA to 2021. The derived TA is a latitude-dependent date, ranging from 1994 to 1998. TA(θ) is a marker for photochemistry dynamics models attempting to represent ozone change over the past 42 years.
Michael Kiefer, Dale F. Hurst, Gabriele P. Stiller, Stefan Lossow, Holger Vömel, John Anderson, Faiza Azam, Jean-Loup Bertaux, Laurent Blanot, Klaus Bramstedt, John P. Burrows, Robert Damadeo, Bianca Maria Dinelli, Patrick Eriksson, Maya García-Comas, John C. Gille, Mark Hervig, Yasuko Kasai, Farahnaz Khosrawi, Donal Murtagh, Gerald E. Nedoluha, Stefan Noël, Piera Raspollini, William G. Read, Karen H. Rosenlof, Alexei Rozanov, Christopher E. Sioris, Takafumi Sugita, Thomas von Clarmann, Kaley A. Walker, and Katja Weigel
Atmos. Meas. Tech., 16, 4589–4642, https://doi.org/10.5194/amt-16-4589-2023, https://doi.org/10.5194/amt-16-4589-2023, 2023
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We quantify biases and drifts (and their uncertainties) between the stratospheric water vapor measurement records of 15 satellite-based instruments (SATs, with 31 different retrievals) and balloon-borne frost point hygrometers (FPs) launched at 27 globally distributed stations. These comparisons of measurements during the period 2000–2016 are made using robust, consistent statistical methods. With some exceptions, the biases and drifts determined for most SAT–FP pairs are < 10 % and < 1 % yr−1.
Tim A. van Kempen, Tim J. Rotmans, Richard M. van Hees, Carol Bruegge, Dejian Fu, Ruud Hoogeveen, Thomas J. Pongetti, Robert Rosenberg, and Ilse Aben
Atmos. Meas. Tech., 16, 4507–4527, https://doi.org/10.5194/amt-16-4507-2023, https://doi.org/10.5194/amt-16-4507-2023, 2023
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Validation of satellite measurements is essential for providing reliable and consistent products. In this paper, a validation method for TROPOMI-SWIR (Tropospheric Measurement Instrument in the short-wavelength infrared) is explored. TROPOMI-SWIR has been shown to be exceptionally stable, a necessity to explore the methodology. Railroad Valley, Nevada, is a prime location to perform the necessary measurements to validate the satellite measurements of TROPOMI-SWIR.
Serin Kim, Daewon Kim, Hyunkee Hong, Lim-Seok Chang, Hanlim Lee, Deok-Rae Kim, Donghee Kim, Jeong-Ah Yu, Dongwon Lee, Ukkyo Jeong, Chang-Kuen Song, Sang-Woo Kim, Sang Seo Park, Jhoon Kim, Thomas F. Hanisco, Junsung Park, Wonei Choi, and Kwangyul Lee
Atmos. Meas. Tech., 16, 3959–3972, https://doi.org/10.5194/amt-16-3959-2023, https://doi.org/10.5194/amt-16-3959-2023, 2023
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A first evaluation of the Geostationary Environmental Monitoring Spectrometer (GEMS) NO2 was carried out via comparison with the NO2 data obtained from the ground-based Pandora direct-sun measurements at four sites in Seosan, Republic of Korea. Comparisons between GEMS NO2 and Pandora NO2 were performed according to GEMS cloud fraction. GEMS NO2 showed good agreement with that of Pandora NO2 under less cloudy conditions.
Nicholas Balasus, Daniel J. Jacob, Alba Lorente, Joannes D. Maasakkers, Robert J. Parker, Hartmut Boesch, Zichong Chen, Makoto M. Kelp, Hannah Nesser, and Daniel J. Varon
Atmos. Meas. Tech., 16, 3787–3807, https://doi.org/10.5194/amt-16-3787-2023, https://doi.org/10.5194/amt-16-3787-2023, 2023
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We use machine learning to remove biases in TROPOMI satellite observations of atmospheric methane, with GOSAT observations serving as a reference. We find that the TROPOMI biases relative to GOSAT are related to the presence of aerosols and clouds, the surface brightness, and the specific detector that makes the observation aboard TROPOMI. The resulting blended TROPOMI+GOSAT product is more reliable for quantifying methane emissions.
Thomas E. Taylor, Christopher W. O'Dell, David Baker, Carol Bruegge, Albert Chang, Lars Chapsky, Abhishek Chatterjee, Cecilia Cheng, Frédéric Chevallier, David Crisp, Lan Dang, Brian Drouin, Annmarie Eldering, Liang Feng, Brendan Fisher, Dejian Fu, Michael Gunson, Vance Haemmerle, Graziela R. Keller, Matthäus Kiel, Le Kuai, Thomas Kurosu, Alyn Lambert, Joshua Laughner, Richard Lee, Junjie Liu, Lucas Mandrake, Yuliya Marchetti, Gregory McGarragh, Aronne Merrelli, Robert R. Nelson, Greg Osterman, Fabiano Oyafuso, Paul I. Palmer, Vivienne H. Payne, Robert Rosenberg, Peter Somkuti, Gary Spiers, Cathy To, Brad Weir, Paul O. Wennberg, Shanshan Yu, and Jia Zong
Atmos. Meas. Tech., 16, 3173–3209, https://doi.org/10.5194/amt-16-3173-2023, https://doi.org/10.5194/amt-16-3173-2023, 2023
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NASA's Orbiting Carbon Observatory 2 and 3 (OCO-2 and OCO-3, respectively) provide complementary spatiotemporal coverage from a sun-synchronous and precession orbit, respectively. Estimates of total column carbon dioxide (XCO2) derived from the two sensors using the same retrieval algorithm show broad consistency over a 2.5-year overlapping time record. This suggests that data from the two satellites may be used together for scientific analysis.
Lena Katharina Jänicke, Rene Preusker, Marco Celesti, Marin Tudoroiu, Jürgen Fischer, Dirk Schüttemeyer, and Matthias Drusch
Atmos. Meas. Tech., 16, 3101–3121, https://doi.org/10.5194/amt-16-3101-2023, https://doi.org/10.5194/amt-16-3101-2023, 2023
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To compare two top-of-atmosphere radiances measured by instruments with different spectral characteristics, a transfer function has been developed. It is applied to a tandem data set of Sentinel-3A and B, for which OLCI-B mimicked the ESA’s eighth Earth Explorer FLEX. We found that OLCI-A measured radiances about 2 % brighter than OLCI-FLEX. Only at larger wavelengths were OLCI-A measurements about 5 % darker. The method is thus successful, being sensitive to calibration and processing issues.
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